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Carbanion
Negetively charged Organic species in which carbon
carries three bond pair and one lone pair, is known as
Carbanion. It s represented as-
Characstics of Carbanions
Hybridysation and geometry: Alkyl carbanion has
three bond pairs and one lone pair.Thus its
hybridysation is sp3.Thus its geometry is Pyramidal.
(2)
(c) Hybridyzation:
More the “s” character in hybrid orbital higher will be
the stability.
In sp3 hybrid orbital S character is 25%
In sp2 hybrid orbital S character is 33% and
In sp hybrid orbital S character is 50%.
So the Carbanion generated from alkyne is more stable
than the Carbanion generated from alkene rather than
that of Carbanion generated from alkane.
(d)Aromiticity:
In some Cabranion the lone pair of carbon is involved in
delocalization to add the aromatic charactern on the molecule
which keeps them extra stability. e.g