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Thermodynamic Properties of Moist Air

Thermodynamic Properties
of
Moist Air

Refrigeration & Air-Conditioning Theory

T. Y. B. Tech. Mechanical Engineering


ME 0308 SEM - VI
Dept. of Mechanical Engineering

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Outline

• Fundamental Discussion of Moist Air.

• Thermodynamic Wet – Bulb Temperature.

• Tables for Moist Air.

• Perfect Gas Relationships for Approximate Calculations.

• Construction of the Psychrometric Charts.

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Atmospheric Air
ATM. AIR – Mixture of gases, including N2 , O2 , Ar, CO2 , H2O and traces of other

gases + Particulate matters.

Above 20,000 ft (6100 mtr), only DRY AIR…!!

ASHRAE Handbook of Fundamentals – Definition for Standard Atmosphere.

1) Atmosphere consists of Dry Air, which behaves as a Perfect Gas, PV  m R T


2) Gravity is constant at 9.80665 m / sec2.

3) At Sea Level, Pr. is 101.325 kPa, 18 ºC.

4) Temp. t (ºC) decreases linearly with altitude z (mtr) : t  t0  0.0065 z


5.266
P  Az 
5) After Isothermal Atm, (- 56.5ºC) and (11000 mtr) :  1  
P0  T0 
….A = 0.0065 K / mtr.
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Atmospheric Air

Altitude, mtr Temperature, ºC Pressure, kPa


-500 18.2 107.478
0 15.0 101.325
500 11.8 95.461
1000 8.5 89.874
2000 2.0 79.495
3000 - 4.5 70.108
4000 - 11.0 61.640
5000 - 17.5 54.020
6000 - 24.0 47.181
7000 - 30.5 41.061
8000 - 37.0 35.600
9000 - 43.5 30.742
10000 - 5.0 26.436

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Fundamental Discussion of Moist Air


Working Substance in Air Conditioning ≡ Moist Air

Moist Air ≡ Binary Mixture ( Dry Air + Water Vapour)

ASHREA Handbook : Definition of Dry Air ≡

Substance Mole. Wt. Mole Fraction Partial Mole. Wt.


Composition in Dry Air in Dry Air
Oxygen, O2 32.000 0.2095 6.704
Nitrogen, N2 28.016 0.7809 21.878
Argon, Ar 39.944 0.0093 0.371
Carbon Dioxide, CO2 44.010 0.0003 0.013
1.0000 28.966

Molecular Weight : Dry Air ≡ 28.966


Moist Air ≡ 18.016

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Fundamental Discussion of Moist Air


R 8314  J / kmole.K  J
Gas Constants : Dry Air ≡ Ra   
28.966 28.966  kg / kmole 
287
kg.K

R 8314  J / kmole.K  J
Moist Air ≡ Rv      462
18.016 18.016  kg / kmole  kg.K

Moist Air : Variable amount, from ZERO (Dry Air) to SATURATED (100 %).

Saturated Moist Air ≡ The condition where Moist Air may co-exist, in Neutral

Equilibrium, with associated Condensed Water.

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Fundamental Discussion of Moist Air


Humidity Ratio ≡ Mass of Water Vapour per unit Mass of Dry Air in Moist Air Mixture.

mv
W
ma

W
Degree of Saturation ≡  WS ≡ Humidity Ratio at Saturation for same
WS Pr. And Temp.

xw x w ≡ Mole Fraction of Water Vapour in the mixture.


Relative Humidity ≡ 
x w, S x w,s ≡ Mole Fraction of Water Vapour at Saturation
for same Pr. And Temp.
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Fundamental Discussion of Moist Air


xw
Relative Humidity ≡ 
x w, S
0.622
1
xw WS 0.622  W S
  
x w, S 1
0.622 0.622  W
W
NOTE : Neither μ nor φ are defined when Temp. of Moist Air exceeds the Sat. Temp.

of Pure Water corresponding to the Moist Air Pr.

e.g. : @ Sea – Level, ma = 0 → WS reaches Infinity @ 100 ºC, 101.325 kPa.


μ nor φ are undefined….!!!
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Fundamental Discussion of Moist Air

Dry Bulb Temperature, (t) ≡ True Temperature of Moist Air at rest.

Dew Point Temperature (td) ≡ Sat. Temp. corresponding to the Humidity Ratio and Pr.

of the State.

Dew Point Temperature (td) ≡ Moist Air Mixture defined by P, W and t. If the Temp. is

slowly reduced while holding P and W constant, then the

Temp. at which Sat. is reached is the Dew Point Temp.

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Fundamental Discussion of Moist Air


Enthalpy of Moist Air ≡ Sum of Enthalpies of the Dry Air and the Water Vapour.

H  H a  H w  m a ha  m w hw

Sp. Enthalpy of Moist Air ≡ Enthalpy per unit mass of the Dry Air.

H m a ha  m w hw
h 
ma ma
mw
h  ha  hw  ha  W hw
ma

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Thermodynamic Wet Bulb Temperature


Thermodynamic Wet Bulb Temperature, (t*) ≡ Adiabatic Saturation Temperature.

Thermodynamic Wet Bulb Temperature, (t*) ≡ Temperature at which water, by


evaporating into air, can bring
the air to Saturation adiabatically
at the same temperature.
1 2
Perfect Insulation
t 2  Dry Bulb Temp 1

P, W1 , t1 , ma
Water @ t2
P, WS2 , t2 , m
t 2  Dew Po int Temp1

ml , Makeup Water @ t2
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Thermodynamic Wet Bulb Temperature


Steady State : Makeup Water, with rate ml = Rate @ which Water added to Moist Air.

ml  m l WS , 2  W1 
 

Adiabatic Chamber :
    
m a ha,1  m a W1 h w,1  ml h f , 2  m a ha, 2  m a W S , 2 h w, 2

h1  WS , 2  W1 h f , 2  h S , 2
1 2
Perfect Insulation

P, W1 , t1 , ma P, WS2 , t2 , m
Water @ t2

ml , Makeup Water @ t2
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Thermodynamic Wet Bulb Temperature


Air leaving the chamber ≡ Sat. at P = Const. WS,2, hS,2, and hf,2 ≡ f (t2)

t2 = f (W1, h1, and P1 ) ≡ f (State 1)


≡ Thermodynamic Property (State 1)

≡ Thermodynamic Wet Bulb Temperature (t*)


1 2
Perfect Insulation  
h  WS*  W h*f  h*S

P, W1 , t1 , ma P, WS2 , t2 , m
Water @ t2

ml , Makeup Water @ t2
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Tables for Moist Air

Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy


(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
- 50 0.0000243 0.6312 0.0000 0.6312 - 50.289 0.059 - 50.230 - 0.2033 0.0033 - 0.2031

- 40 0.0000793 0.6597 0.0001 0.6597 - 40.229 0.192 - 40.037 - 0.1592 0.0009 - 0.1584
- 30 0.0002346 0.6881 0.0003 0.6884 - 30.171 0.574 - 29.597 - 0.1170 0.0025 - 0.1145
-20 0.0006373 0.7165 0.0007 0.7173 - 20.115 1.570 - 18.545 - 0.0765 0.0066 - 0.0699

-10 0.0016062 0.7450 0.0019 0.7469 - 10.057 3.986 - 6.072 - 0.0375 0.0160 - 0.0215

0 0.0037895 0.7734 0.0047 0.7781 0.000 9.473 9.473 0.0000 0.0364 0.0364

10 0.007661 0.8018 0.0098 0.8116 10.059 19.293 29.352 0.0362 0.0717 0.1078

20 0.014758 0.8302 0.0196 0.8498 20.121 37.434 57.555 0.0711 0.1346 0.2057

30 0.027329 0.8586 0.0376 0.8962 30.185 69.820 100.006 0.1048 0.2432 0.3481
40 0.049141 0.8870 0.0698 0.9568 40.253 126.430 166.683 0.1375 0.4273 0.5649
50 0.086858 0.9154 0.1272 1.0425 50.326 225.019 275.345 0.1692 0.7385 0.9077

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Tables for Moist Air


WS = Humidity Ratio of Sat. Air.

va = Sp. Vol. of Dry Air under 101.325 kPa, ( m3 / kga )

vS = Sp. Vol. of Sat. Air, ( m3 / kg of Dry Air )

vaS = vS – va , ( m3 / kg of Dry Air )


ha = Sp. Enthalpy of Dry Air , ( kJ / kg of Dry Air ). ZERO Enthalpy @ 0ºC for Dry Air.

hS = Sp. Enthalpy of Sat. Air , ( kJ / kg of Dry Air )

haS = hS – ha , ( kJ / kg of Dry Air )

sa = Sp. Entropy of Dry Air , ( kJ / kga.K ). ZERO Entropy @ 0ºC for Dry Air.

sS = Sp. Entropy of Sat. Air , ( kJ / kg of Dry Air.K )

saS = sS – sa , ( kJ / kg of Dry Air.K )

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Tables for Moist Air

Unsaturated Moist Air States ≡

v  v a   v aS

h  h a   h aS

s  s a   s aS

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 1
Moist Air exists at 30 ºC dry-bulb temperature, 16 ºC dew-point temperature, and 101.325
kPa pressure. Determine :
a) Humidity Ratio,
b) Degree of Saturation,
c) Relative Humidity,
d) Enthalpy, and
e) Sp. Volume.

Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy


(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
16 0.011413 0.8188 0.0150 0.8338 16.096 28.867 44.963 0.0573 0.1051 0.1624

30 0.027329 0.8586 0.0376 0.8962 30.185 69.82 100.006 0.1048 0.2432 0.3481

W  WS @ 16 C ….Dew Point Temperature

 0.011413 kgw / kga ….ANS

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 1…cntd
Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
16 0.011413 0.8188 0.0150 0.8338 16.096 28.867 44.963 0.0573 0.1051 0.1624
30 0.027329 0.8586 0.0376 0.8962 30.185 69.82 100.006 0.1048 0.2432 0.3481

WS @ 30 C  0.027329 kgw / kga


W 0.011413
   0.4176 or 41.76 % ….ANS
WS 0.027329

0.622  W S 0.622  0.027329


  0.4176
0.622  W 0.622  0.011413
 0.428 or 42.8 % ….ANS

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 1…cntd
Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
16 0.011413 0.8188 0.0150 0.8338 16.096 28.867 44.963 0.0573 0.1051 0.1624
30 0.027329 0.8586 0.0376 0.8962 30.185 69.82 100.006 0.1048 0.2432 0.3481

h  ha   ha S
 30.185  0.417669.82
 59.342 kJ / kg a ….ANS

v  va   vaS
 0.8586  0.4176 0.0376
 0.8743 m3 / kg a ….ANS

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 2
Moist Air exists at 50 ºC dry-bulb temperature and 40 per cent degree of saturation.
Pressure is 101.325 kPa. Determine :
a) Enthalpy, and
b) Sp. Volume.

From the Table for Moist Air;

Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy


(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
50 0.086858 0.9154 0.1272 1.0425 50.326 225.019 275.345 0.1692 0.7385 0.9077

h  h a   h aS

 50.326  0.40 225.019 


 140.3336 kJ / kga …ANS

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 2…cntd
Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
50 0.086858 0.9154 0.1272 1.0425 50.326 225.019 275.345 0.1692 0.7385 0.9077

v  v a   v aS

 0.9154  0.400.1272

 0.96628 m3 / kga …ANS

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 3
Moist Air exists at 30 ºC dry-bulb temperature, 16 ºC thermodynamic wet-bulb
temperature, and 101.325 kPa pressure. Determine :
a) Degree of Saturation, and
b) Enthalpy.
Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
16 0.011413 0.8188 0.0150 0.8338 16.096 28.867 44.963 0.0573 0.1051 0.1624

30 0.027329 0.8586 0.0376 0.8962 30.185 69.82 100.006 0.1048 0.2432 0.3481

 
h  ha   haS  h*s  Ws*  W h*f  h*s  Ws*h*f   WS h*f

h*s  W s*h*f  h a 44.963  0.01141366.13  30.185


 
h aS  WS h*f 69.82  0.02732966.13
 0.2062 …ANS
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Example 3…cntd
Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
16 0.011413 0.8188 0.0150 0.8338 16.096 28.867 44.963 0.0573 0.1051 0.1624
30 0.027329 0.8586 0.0376 0.8962 30.185 69.82 100.006 0.1048 0.2432 0.3481

h  h a   h aS
 30.185  0.206269.82
 44.582 kJ / kga …ANS

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Perfect Gas Relationships for Approx. Calculations


Tables for Moist Air ≡ Atm. Pr. only.

Water Vapour Pr. Below 6.9 kPa (1 psi) ≡ Perfect Gas Behaviour.

mw Pw V / R w T Ra Pw
Humidity Ratio ≡ W   
ma Pa V / R a T Rw Pa
Ra Mw
Using; P  Pa  Pw & 
Rw Ma
mw Pw
Humidity Ratio ≡ W  0.622 
ma P  Pw
Dew Point Temp (td) ≡ Sat. Temp corresponding to Vapour Pr. Pw.
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Perfect Gas Relationships for Approx. Calculations

Ideal Gas; h a   C P ,a dT & h w   C P , w dT

Assumption : ha = 0 @ 0 ºC & hg,0 = Enthalpy @ 0 ºC

h a  C P ,a T & h w  h g  CP ,w T  h g ,0

Title Unit
h  CP ,a T  W h g Cpa 1.00 kJ/kga.K
Cpw 1.86 kJ/kgw.K
hg,0 2501 kJ/kgw

h  CP ,a T  W CP , w T  h g , 0 

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Perfect Gas Relationships for Approx. Calculations


Sp. Volume ≡ Volume of the Mixture per unit Mass of Dry Air.

Mixture, Dry Air and Water Vapour ≡ Occupy SAME Volume….!!!

Ra T Ra T
v 
Pa P  Pw

Pw
xw  ….Perfect Gas
P
xw Pw
Relative Humidity ≡  
x w, S Pw, S

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Perfect Gas Relationships for Approx. Calculations


Using the Equations derived above;

W *
S 
 W h*fg  C P t  t *  
W
W S* h*fg  C P ,a t  t  *

h g  h*f
Total Entropy, S @ Pr. P and Temp T ≡

S  S a , 0   S a ,T , P   S a ,mix  S w, 0   S w,T , P   S w,mix


Sa,0 , Sw,0 = Entropy values @ Ref. States for Dry Air & Water Vapour

Δ Sa,T,P , Δ Sw,T,P = Entropy changes during Ref. State to State P, T.

Δ Sa,mix , Δ Sw,mix = Mixing Entropy for Dry Air & Water Vapour.
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Perfect Gas Relationships for Approx. Calculations


Perfect Gas ≡ Const. Sp. Heat & P0, To as Ref. States;

 T P
 S a ,T , P  m a  CP,a ln  R a ln 
 T0 P0 
 Pa 
 S a ,mix   m a  R a ln 
 P
 T P
 S w,T , P  m w  CP , w ln  R w ln 
 T0 P0 
 Pw 
 S w,mix   m w  R w ln 
 P
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Perfect Gas Relationships for Approx. Calculations


T0 = 0 ºC & P0 = 101.325 kPa

S a ,0  0
& S w, 0  m w 6.7975 kJ / kgw .K   m w s w, 0
This yields;

S T Pa  T Pw 
 s  CP,a ln  R a ln  W  s w,0  CP,w ln  R w ln 
ma T0 P0  T0 P0 
 Pw 
s  CP ,a  CP ,w W  ln  R a ln
T Pa
 W  s w,0  R w ln 
T0 P0  P0 
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Example 4
Moist Air exists at 30 ºC dry-bulb temperature, 40 per cent relative humidity, and 86.60
kPa barometric pressure. Determine :
1. Dew point temperature,
2. Specific enthalpy, and
3. Specific entropy.

Temp Abs. Pr. Sp. Vol. Sp. Enthalpy Sp. Entropy


(ºC) MPa m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
Pw,s Vf Vg hf hg sf sg
0 0.0006109 0.0009997 206.3 0.0 2500.89 0.0 9.1557

15 0.001705 0.001001 77.93 61.95 2528.47 0.2207 8.7806

30 0.004246 0.001005 32.89 124.95 2555.80 0.4340 8.4525

45 0.009593 0.001010 15.26 188.38 2582.75 0.6381 8.1640

Pw, S  4.246 kPa Pw  0.404.246  1.698 kPa


Interpolation in the Table; td  14.9 C ….ANS

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 4….cntd
Pw 1.698
W  0.622   0.622   0.0124 kgw / kga
P  Pw 86.60  1.698

h g  2555.80 kJ / kgw

h  CP ,a T  W h g

 1.030  0.01242555.80
 61.79 kJ / kga ….ANS

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 4….cntd

Pa  P  Pw  86.60  1.698  84.902 kPa

 Pw 
s  C P ,a  C P , w W  ln  R a ln
T Pa
 W  s w, 0  R w ln 
T0 P0  P0 

 1.0   1.860.0124 ln
303 84.902
 0.287 ln
273 101.325
 1.698 
 0.0124  6.7975  0.461ln 
 101.325 
 0.2651 kJ / kga .K ….ANS

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 5
Moist air exists at 40 ºC dry-bulb temperature, 30 ºC thermodynamic wet-bulb
temperature, and 95.56 kPa pressure. Determine :
1. Humidity ratio, and
2. Relative humidity.
Temp Abs. Pr. Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) MPa m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
Pw,s Vf Vg hf hg sf sg
20 0.002339 0.001002 57.79 82.90 2537.61 0.2928 8.664

30 0.004246 0.001005 32.89 124.95 2555.80 0.4340 8.4525

40 0.007384 0.001008 19.52 167.26 2573.82 0.5712 8.2562

Pw*,S  4.246 kPa @ 30 C

Pw* 4.246
W  0.622 
*
 0.622   0.0289 kgw / kga
P  Pw 95.56  4.246
S *

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 5….cntd
Temp Abs. Pr. Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) MPa m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
Pw,s Vf Vg hf hg sf sg
20 0.002339 0.001002 57.79 82.90 2537.61 0.2928 8.664
30 0.004246 0.001005 32.89 124.95 2555.80 0.4340 8.4525

40 0.007384 0.001008 19.52 167.26 2573.82 0.5712 8.2562

h g  2573.82 kJ / kgw @ 40 C

W
W S* h*fg  C P ,a t  t *  
h g  h*f


0.02892555.80  124.95  1.040  30
2573.82  124.85
 0.0246 kgw / kga ….ANS
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Example 5….cntd
Temp Abs. Pr. Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) MPa m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
Pw,s Vf Vg hf hg sf sg
20 0.002339 0.001002 57.79 82.90 2537.61 0.2928 8.664
30 0.004246 0.001005 32.89 124.95 2555.80 0.4340 8.4525

40 0.007384 0.001008 19.52 167.26 2573.82 0.5712 8.2562

Pw*
WS*  0.622 
P  Pw*
1.608 P W
 Pw 
1  1.608 W

Pw 
1.608 95.56 0.0246
 3.636 kPa
1  1.608 0.0246
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Example 5….cntd
Temp Abs. Pr. Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) MPa m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
Pw,s Vf Vg hf hg sf sg
g20 0.002339 0.001002 57.79 82.90 2537.61 0.2928 8.664
30 0.004246 0.001005 32.89 124.95 2555.80 0.4340 8.4525

40 0.007384 0.001008 19.52 167.26 2573.82 0.5712 8.2562

Pw, S  7.384 kPa @ 40 C

Pw

Pw, S
3.636
  0.4924 or 49.24 % ….ANS
7.384

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Construction of Psychrometric Chart


Thermodynamic State of Moist Air ≡ Barometric Pr. + 2 Independent Properties.

Tradition : Std. Sea – Level Pr (101.325 kPa).

Richard Mollier (1923), from Dresden, Germany ≡ Enthalpy + Humidity Ratio, (h – W)

Enthalpy ≡ Oblique Coordinate h1 h2

Humidity Ratio ≡ Rectangular Coordinate


W2
b α
Lw
Goodman’s Procedure : θ β
W1
Sine Rule :

Lh b

sin  sin  β β

Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Construction of Psychrometric Chart


 180     
sin   sin      sin  cos   cos sin 
Lw
b
sin  h1 h2

Lh
cot   cot  
W2
b α
Lw θ β
Lw
W1
Enthalpy – Scale Factor, Sh :

h 2  h1
Sh 
Lh β β

Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Construction of Psychrometric Chart


Humidity Ratio – Scale Factor, Sw :

W 2  W1
Sw 
Lw
Lh S w h 2  h1 
Q' h1 h2
 
L w S h W 2  W1  S W2
b α
Lw
Sh Chart Scale Factor β
S
θ
where; W1
( kJ / kgw )
Sw
h 2  h1 Enthalpy – Moisture Ratio
Q  '
β
W 2  W1 ( kJ / kgw ) β

Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Construction of Psychrometric Chart


Q' Lh
cot   cot   
Lw S
General Equation for construction of various lines on Psychrometric Chart.

Inclination Angle, β, of Enthalpy Line


h1 h2
≡ Fixed by some Property Line,
considering it to be Vertical…!! W2
≡ Dry Bulb Temperature…!!! b α
Lw
θ β

h 2  h1  W2  W1  h w
W1

Q  hw  h g
'
β β

Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Construction of Psychrometric Chart


Dry Bulb Temp. lines ≡ hg = f (Temp)

≡ Straight Lines
S
tan   …for any Dry Bulb Temp line, t to be vertical.
h g ,t
h1 h2
Inclination of Enthalpy Lines…!!
W2
b α
Lw
θ β
W1

Grid of h and W lines may then be constructed…!!!

Psychrometric Chart…!!! β β

Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Construction of Psychrometric Chart


Saturation Curve ≡ Locus of points representing Sat. Air.

≡ hs & Ws @ various Temp.

Dry Bulb Temp. Lines ≡ Straight Lines

hg
cot    cot  h1 h2
S W2
Thermodynamic Wet Bulb Temp. Lines ≡ Straight Lines
b α
Lw
h h
* θ β
W1
Q h 
' * S

W W
f *
S

h*f
cot    cot  β β

S Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Construction of Psychrometric Chart


Volume Lines ≡ ALMOST Straight Lines

d h  C P , w  1.608 C P ,a   Pv 
Q '
    C P , w T0  h g ,0
d W   1  1.608W 2
Ra  
h1 h2
Relative Humidity Lines :

 Pw, S W2
W  0.622 b α
Lw
P   Pw, S θ β
W1

Enthalpy – Moisture Ratio Protractor :

≡ Direction of straight lines of various values of Q’ β β

Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Construction of Psychrometric Chart


Sensible – Heat – Ratio ( SHR ) Protractor :

Sensible Heat Ratio ( Process 1 → 2 ) :

≡ Sensible Enthalpy Change divided by Total Enthalpy Change

h1 h2
 hS
SHR  W2
h b α
Lw
θ β
W1

β β

Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Construction of Psychrometric Chart

Relation bet. SHR & Enthalpy – Moisture Ratio :

 h   hL h g ,avg  T
SHR   1
h h h1 h2

h g ,avg W2
SHR 1  ' b α
Q θ β
Lw
W1
h g ,avg
Q  '

1  SHR
β β

Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Construction of Psychrometric Chart

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.


Thermodynamic Properties of Moist Air

Example 6
Moist air exists at a condition of 40 ºC dry-bulb temperature, 20 ºC thermodynamic wet-
bulb temperature, and 101.325 kPa pressure. Determine, using standard charts :
1. Humidity ratio,
2. Enthalpy,
3. Dew point temperature,
4. Relative humidity, and
5. Volume.

W = 0.0066 kgw / kga

h = 57.5 kJ / kga h

td = 7.5 ºC
W
φ = 14 % td Φ v

v = 0.896 m3 / kga
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air

Thank You !

ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.

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