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Thermodynamic Properties
of
Moist Air
Outline
Atmospheric Air
ATM. AIR – Mixture of gases, including N2 , O2 , Ar, CO2 , H2O and traces of other
Atmospheric Air
R 8314 J / kmole.K J
Moist Air ≡ Rv 462
18.016 18.016 kg / kmole kg.K
Moist Air : Variable amount, from ZERO (Dry Air) to SATURATED (100 %).
Saturated Moist Air ≡ The condition where Moist Air may co-exist, in Neutral
mv
W
ma
W
Degree of Saturation ≡ WS ≡ Humidity Ratio at Saturation for same
WS Pr. And Temp.
Dew Point Temperature (td) ≡ Sat. Temp. corresponding to the Humidity Ratio and Pr.
of the State.
Dew Point Temperature (td) ≡ Moist Air Mixture defined by P, W and t. If the Temp. is
H H a H w m a ha m w hw
Sp. Enthalpy of Moist Air ≡ Enthalpy per unit mass of the Dry Air.
H m a ha m w hw
h
ma ma
mw
h ha hw ha W hw
ma
P, W1 , t1 , ma
Water @ t2
P, WS2 , t2 , m
t 2 Dew Po int Temp1
ml , Makeup Water @ t2
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
ml m l WS , 2 W1
Adiabatic Chamber :
m a ha,1 m a W1 h w,1 ml h f , 2 m a ha, 2 m a W S , 2 h w, 2
h1 WS , 2 W1 h f , 2 h S , 2
1 2
Perfect Insulation
P, W1 , t1 , ma P, WS2 , t2 , m
Water @ t2
ml , Makeup Water @ t2
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
P, W1 , t1 , ma P, WS2 , t2 , m
Water @ t2
ml , Makeup Water @ t2
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
- 40 0.0000793 0.6597 0.0001 0.6597 - 40.229 0.192 - 40.037 - 0.1592 0.0009 - 0.1584
- 30 0.0002346 0.6881 0.0003 0.6884 - 30.171 0.574 - 29.597 - 0.1170 0.0025 - 0.1145
-20 0.0006373 0.7165 0.0007 0.7173 - 20.115 1.570 - 18.545 - 0.0765 0.0066 - 0.0699
-10 0.0016062 0.7450 0.0019 0.7469 - 10.057 3.986 - 6.072 - 0.0375 0.0160 - 0.0215
0 0.0037895 0.7734 0.0047 0.7781 0.000 9.473 9.473 0.0000 0.0364 0.0364
10 0.007661 0.8018 0.0098 0.8116 10.059 19.293 29.352 0.0362 0.0717 0.1078
20 0.014758 0.8302 0.0196 0.8498 20.121 37.434 57.555 0.0711 0.1346 0.2057
30 0.027329 0.8586 0.0376 0.8962 30.185 69.820 100.006 0.1048 0.2432 0.3481
40 0.049141 0.8870 0.0698 0.9568 40.253 126.430 166.683 0.1375 0.4273 0.5649
50 0.086858 0.9154 0.1272 1.0425 50.326 225.019 275.345 0.1692 0.7385 0.9077
sa = Sp. Entropy of Dry Air , ( kJ / kga.K ). ZERO Entropy @ 0ºC for Dry Air.
v v a v aS
h h a h aS
s s a s aS
Example 1
Moist Air exists at 30 ºC dry-bulb temperature, 16 ºC dew-point temperature, and 101.325
kPa pressure. Determine :
a) Humidity Ratio,
b) Degree of Saturation,
c) Relative Humidity,
d) Enthalpy, and
e) Sp. Volume.
30 0.027329 0.8586 0.0376 0.8962 30.185 69.82 100.006 0.1048 0.2432 0.3481
Example 1…cntd
Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
16 0.011413 0.8188 0.0150 0.8338 16.096 28.867 44.963 0.0573 0.1051 0.1624
30 0.027329 0.8586 0.0376 0.8962 30.185 69.82 100.006 0.1048 0.2432 0.3481
Example 1…cntd
Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
16 0.011413 0.8188 0.0150 0.8338 16.096 28.867 44.963 0.0573 0.1051 0.1624
30 0.027329 0.8586 0.0376 0.8962 30.185 69.82 100.006 0.1048 0.2432 0.3481
h ha ha S
30.185 0.417669.82
59.342 kJ / kg a ….ANS
v va vaS
0.8586 0.4176 0.0376
0.8743 m3 / kg a ….ANS
Example 2
Moist Air exists at 50 ºC dry-bulb temperature and 40 per cent degree of saturation.
Pressure is 101.325 kPa. Determine :
a) Enthalpy, and
b) Sp. Volume.
h h a h aS
Example 2…cntd
Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
50 0.086858 0.9154 0.1272 1.0425 50.326 225.019 275.345 0.1692 0.7385 0.9077
v v a v aS
0.9154 0.400.1272
Example 3
Moist Air exists at 30 ºC dry-bulb temperature, 16 ºC thermodynamic wet-bulb
temperature, and 101.325 kPa pressure. Determine :
a) Degree of Saturation, and
b) Enthalpy.
Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
16 0.011413 0.8188 0.0150 0.8338 16.096 28.867 44.963 0.0573 0.1051 0.1624
30 0.027329 0.8586 0.0376 0.8962 30.185 69.82 100.006 0.1048 0.2432 0.3481
h ha haS h*s Ws* W h*f h*s Ws*h*f WS h*f
Example 3…cntd
Temp Humidity Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) Ratio, m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
kgW / kga
WS Va Vas Vs ha has hs sa sas ss
16 0.011413 0.8188 0.0150 0.8338 16.096 28.867 44.963 0.0573 0.1051 0.1624
30 0.027329 0.8586 0.0376 0.8962 30.185 69.82 100.006 0.1048 0.2432 0.3481
h h a h aS
30.185 0.206269.82
44.582 kJ / kga …ANS
Water Vapour Pr. Below 6.9 kPa (1 psi) ≡ Perfect Gas Behaviour.
mw Pw V / R w T Ra Pw
Humidity Ratio ≡ W
ma Pa V / R a T Rw Pa
Ra Mw
Using; P Pa Pw &
Rw Ma
mw Pw
Humidity Ratio ≡ W 0.622
ma P Pw
Dew Point Temp (td) ≡ Sat. Temp corresponding to Vapour Pr. Pw.
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
h a C P ,a T & h w h g CP ,w T h g ,0
Title Unit
h CP ,a T W h g Cpa 1.00 kJ/kga.K
Cpw 1.86 kJ/kgw.K
hg,0 2501 kJ/kgw
h CP ,a T W CP , w T h g , 0
Ra T Ra T
v
Pa P Pw
Pw
xw ….Perfect Gas
P
xw Pw
Relative Humidity ≡
x w, S Pw, S
W *
S
W h*fg C P t t *
W
W S* h*fg C P ,a t t *
h g h*f
Total Entropy, S @ Pr. P and Temp T ≡
Δ Sa,mix , Δ Sw,mix = Mixing Entropy for Dry Air & Water Vapour.
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
T P
S a ,T , P m a CP,a ln R a ln
T0 P0
Pa
S a ,mix m a R a ln
P
T P
S w,T , P m w CP , w ln R w ln
T0 P0
Pw
S w,mix m w R w ln
P
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
S a ,0 0
& S w, 0 m w 6.7975 kJ / kgw .K m w s w, 0
This yields;
S T Pa T Pw
s CP,a ln R a ln W s w,0 CP,w ln R w ln
ma T0 P0 T0 P0
Pw
s CP ,a CP ,w W ln R a ln
T Pa
W s w,0 R w ln
T0 P0 P0
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
Example 4
Moist Air exists at 30 ºC dry-bulb temperature, 40 per cent relative humidity, and 86.60
kPa barometric pressure. Determine :
1. Dew point temperature,
2. Specific enthalpy, and
3. Specific entropy.
Example 4….cntd
Pw 1.698
W 0.622 0.622 0.0124 kgw / kga
P Pw 86.60 1.698
h g 2555.80 kJ / kgw
h CP ,a T W h g
1.030 0.01242555.80
61.79 kJ / kga ….ANS
Example 4….cntd
Pw
s C P ,a C P , w W ln R a ln
T Pa
W s w, 0 R w ln
T0 P0 P0
1.0 1.860.0124 ln
303 84.902
0.287 ln
273 101.325
1.698
0.0124 6.7975 0.461ln
101.325
0.2651 kJ / kga .K ….ANS
Example 5
Moist air exists at 40 ºC dry-bulb temperature, 30 ºC thermodynamic wet-bulb
temperature, and 95.56 kPa pressure. Determine :
1. Humidity ratio, and
2. Relative humidity.
Temp Abs. Pr. Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) MPa m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
Pw,s Vf Vg hf hg sf sg
20 0.002339 0.001002 57.79 82.90 2537.61 0.2928 8.664
Pw* 4.246
W 0.622
*
0.622 0.0289 kgw / kga
P Pw 95.56 4.246
S *
Example 5….cntd
Temp Abs. Pr. Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) MPa m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
Pw,s Vf Vg hf hg sf sg
20 0.002339 0.001002 57.79 82.90 2537.61 0.2928 8.664
30 0.004246 0.001005 32.89 124.95 2555.80 0.4340 8.4525
h g 2573.82 kJ / kgw @ 40 C
W
W S* h*fg C P ,a t t *
h g h*f
0.02892555.80 124.95 1.040 30
2573.82 124.85
0.0246 kgw / kga ….ANS
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
Example 5….cntd
Temp Abs. Pr. Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) MPa m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
Pw,s Vf Vg hf hg sf sg
20 0.002339 0.001002 57.79 82.90 2537.61 0.2928 8.664
30 0.004246 0.001005 32.89 124.95 2555.80 0.4340 8.4525
Pw*
WS* 0.622
P Pw*
1.608 P W
Pw
1 1.608 W
Pw
1.608 95.56 0.0246
3.636 kPa
1 1.608 0.0246
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
Example 5….cntd
Temp Abs. Pr. Sp. Vol. Sp. Enthalpy Sp. Entropy
(ºC) MPa m3 / kg Dry Air kJ / kg Dry Air kJ / kg Dry Air.(K)
Pw,s Vf Vg hf hg sf sg
g20 0.002339 0.001002 57.79 82.90 2537.61 0.2928 8.664
30 0.004246 0.001005 32.89 124.95 2555.80 0.4340 8.4525
Pw
Pw, S
3.636
0.4924 or 49.24 % ….ANS
7.384
Lh b
sin sin β β
Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
Lh
cot cot
W2
b α
Lw θ β
Lw
W1
Enthalpy – Scale Factor, Sh :
h 2 h1
Sh
Lh β β
Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
W 2 W1
Sw
Lw
Lh S w h 2 h1
Q' h1 h2
L w S h W 2 W1 S W2
b α
Lw
Sh Chart Scale Factor β
S
θ
where; W1
( kJ / kgw )
Sw
h 2 h1 Enthalpy – Moisture Ratio
Q '
β
W 2 W1 ( kJ / kgw ) β
Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
h 2 h1 W2 W1 h w
W1
Q hw h g
'
β β
Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
≡ Straight Lines
S
tan …for any Dry Bulb Temp line, t to be vertical.
h g ,t
h1 h2
Inclination of Enthalpy Lines…!!
W2
b α
Lw
θ β
W1
Psychrometric Chart…!!! β β
Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
hg
cot cot h1 h2
S W2
Thermodynamic Wet Bulb Temp. Lines ≡ Straight Lines
b α
Lw
h h
* θ β
W1
Q h
' * S
W W
f *
S
h*f
cot cot β β
S Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
d h C P , w 1.608 C P ,a Pv
Q '
C P , w T0 h g ,0
d W 1 1.608W 2
Ra
h1 h2
Relative Humidity Lines :
Pw, S W2
W 0.622 b α
Lw
P Pw, S θ β
W1
Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
h1 h2
hS
SHR W2
h b α
Lw
θ β
W1
β β
Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
h hL h g ,avg T
SHR 1
h h h1 h2
h g ,avg W2
SHR 1 ' b α
Q θ β
Lw
W1
h g ,avg
Q '
1 SHR
β β
Lh
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
Example 6
Moist air exists at a condition of 40 ºC dry-bulb temperature, 20 ºC thermodynamic wet-
bulb temperature, and 101.325 kPa pressure. Determine, using standard charts :
1. Humidity ratio,
2. Enthalpy,
3. Dew point temperature,
4. Relative humidity, and
5. Volume.
h = 57.5 kJ / kga h
td = 7.5 ºC
W
φ = 14 % td Φ v
v = 0.896 m3 / kga
ME 0308 SEM-VI Refrigeration and Air-Conditioning Theory T. Y. B. Tech. Mech Engg.
Thermodynamic Properties of Moist Air
Thank You !