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What is a Refrigerant
• Fluids suitable for refrigeration purposes can be
classified into primary and secondary refrigerants.
• Primary refrigerants are those fluids, which are used
directly as working fluids, for example in R22 in
vapour compression and Ammonia in vapour
absorption refrigeration systems.
• Primary refrigerants fluids provide refrigeration by
undergoing a phase change process in the
evaporator.
• Secondary refrigerants are those liquids, which are
used for transporting thermal energy from one
location to other. Secondary refrigerants are also
known under the name brines or antifreezes
What are Chlorofluorocarbons (CFCs)?
These are substances containing Chlorine, Fluorine and
Carbon. Also classified as Halocarbons, ie compounds that
contain atoms of carbon and halogen atoms. The following are
some CFC refrigerants with their chemical composition:
• R11 (CCl3F)
• R12 (CCl2F2) Dichlorodifluoromethane
• R13 (CClF3)
• R113 (CCl2FCClF2);
• R114 (CClF2CClF2);
• R115 (CF3CClF2);
CFCs are now totally banned from use or production
within all countries covered by the Montreal Protocol.
What are Hydro Chlorofluorocarbons (HCFCs)?
These are substances containing Hydrogen, Chlorine,
Fluorine and Carbon. HCFCs have replaced CFCs as
refrigerants, being less harmful to the environment .
The following are some HCFC Refrigerants with their
chemical composition :
• R22 (CHClF2) Chlorodifluoromethane
• R31 (CH2ClF2)
• R123 (CF3CHCl2)
• R124 (CHClFCF3)
HCFC gases were banned in Jan 2010. General phase out in
developed countries was completed by end 2015.
What are Hydrofluorocarbons (HFCs)?
Global warming :
• Refrigerants directly contributing to global warming
when released to the atmosphere
CFC
ALTERNATIVES.
Sec A 13 Jun 13
Survey of Refrigerants
Refrigerant Group Atmospheric ODP GWP
life
R11 CFC 130 1 4000
R12 CFC 130 1 8500
R22 HCFC 15 .055 1700
R134a HFC 16 0 1300
R404a HFC 16 0 3260
R410a HFC 16 0 1720
R507 HFC 130 1 3300
R717 NH3 - 0 0
R744 CO2 - 0 1
R290 HC <1 0 8
R600a HC <1 0 8
Conclusions
• In the aftermath of the Montreal protocol HFCs have
predominantly replaced CFCs and HCFCs in RAC
equipment.
• Due to their high GWP, HFCs are not a good
replacement solution.
• The solution lies with natural refrigerants :
Ammonia, Hydrocarbons and Carbon dioxide
• Systems need to have low TEWI factor
• High efficiency with ammonia and lower power
consumption with hydrocarbons
• Sec D 14 Jun 17, Sec C 15 Jun 17 Sec A 19 Jun 17 Sec B 20 jun
17