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Jotun Group
Paint School
JPS-E/Cathodic/1
Corrosion of a metal or alloy
Paint School
JPS-E/Cathodic/4
Type of Products
• Sacrificial anodes
• Electrolytic descaling
• Impressed Current Cathodic Protection
Systems (ICCP)
• Electrolytic Antifouling
Paint School
JPS-E/Cathodic/5
Type of Sacrificial Anodes
• Zinc
– Noranode
– Coral Z
• Aluminium
– Coral A
– Coral A high grade
• Magnesium
Paint School
JPS-E/Cathodic/6
Type of Products
Paint School
JPS-E/Cathodic/7
Type of Services
Paint School
JPS-E/Cathodic/8
Type of Products and Services
• Cathodic protection engineering and design
• Servicing, inspection and reporting
• Sacrifical anodes
• Magnesium strips (Electrolytic descaling)
• Impressed Current Cathodic Protection
Systems
• Electrolytic Antifouling System
• Log sheet evaluation
• Grounding equipment
Paint School
JPS-E/Cathodic/9
Type of Products
Paint School
JPS-E/Cathodic/10
Type of products
Grounding equipment
• Rudder grounding
• Shaft grounding equipment
• Earthing cables
Paint School
JPS-E/Cathodic/11
Type of Products
• Magnesium strips
• Clamps
Paint School
JPS-E/Cathodic/12
For Norway
Objects to be Protected:
• Ships
• Offshore platforms and rigs
• Subsea installations
• Subsea pipelines
• Harbour facilities
• Storage tanks
• Buried tanks and pipelines (onshore)
Paint School
JPS-E/Cathodic/13
Objects to be Protected:
• Ships
• Offshore platforms and rigs
• Subsea installations
• Subsea pipelines
• Harbour facilities (Sacrificial anodes)
Paint School
JPS-E/Cathodic/14
Marine
Objects to be Protected:
• Ships
• FPSO / FSU
• Mobile rigs
• Floating dry-docks
• Barges
Paint School
JPS-E/Cathodic/15
Norwegian Sector. Offshore and Industry
Objects to be Protected:
Paint School
JPS-E/Cathodic/16
Offshore and Industry
Objects to be Protected:
• Offshore platforms
– Fixed / floating
– Concrete / steel
• Subsea installations
– (templates/manifolds/ modules)
• Subsea pipelines
• Harbour facilities
– Piles
– Sheet piles
Paint School
JPS-E/Cathodic/17
Corrosion and corrosion protection
Energy Pure metal
or an Alloy Cathodic protection
E2
Energy offered
Corrosion
by Cathodic
Refining Coating protection
reduces
corrosion rate
E1
Iron ore Rust = Iron ore
Cathode Cathode
2e- 2e-
Anode
Steel plate 2e- 2e-
Paint School
JPS-E/Cathodic/19
The Principle of Cathodic Protection
Potentials vs. different Reference Electrodes
Potential, mV vs.
Cu/CuSO4 Zn
-580 +500 Freely corroding steel
-700
-800
-1000
Steel
2+ -
Zn = Zn + 2 e Zinc
O2
Paint School
JPS-E/Cathodic/21
Cathodic protection
Impressed current system
Current Source
2 e-
Steel
Permanent anode
Current
O2
Paint School
JPS-E/Cathodic/22
Corrosion Potentials in Seawater
Zinc, Ag/Ag Cl and Cu/CuSO4 Reference Electrodes
Rapid corrosion
- 0.55 + 0.50 - 0.60
General corrosion
Some corrosion
- 0.80 + 0.25 - 0.85
100% Cathodic protection
87,5
• Design lifetime
• Coating system and condition
• Current density (Coating type and
damages)
• Current distribution
• Electrolytic resistivity
• Environmental conditions / impacts
• Ballasting period.
Paint School
JPS-E/Cathodic/26
Protective
Design criteria
• Type of structure
• Surface area to be protected
• Design lifetime
• Coating system and condition
• Protection potential
• Anode capacity
• Current distribution
• Electrolyte resistivity
• Environmental conditions / impacts
Paint School
• Safety restrictions
JPS-E/Cathodic/27
Current Density Requirement
Depends On:
Paint School
JPS-E/Cathodic/28
Sacrificial Anode material selection
Anode material selection
Main Types • Chemical composition
• Zinc • Electrochemical
• Aluminium performance
• Magnesium - Anode potential
- Stable current
- Consumption
• Anode corrosion pattern
• Price
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• Class requirements
JPS-E/Cathodic/29
Current density requirement
acc. to DNV RP B401 (1993)
Paint School
JPS-E/Cathodic/30
Current density requirement
acc. to DNV RP B401 (1993)
0 - 30
0.070 0.080 0.100 0.1201)
> 30
0.060 0.070 0.080 0.100
Paint School
JPS-E/Cathodic/31
Coating Categories
Acc. to DNV RP B401 (1993)
Category I: Category III:
One layer of primer coat, One layer of primer coat,
about 50 microns nominal plus minimum two layers
DFT (Dry Film Thickness) of intermediate/top coats,
minimum 300 microns
Category II: nominal DFT
One layer of primer coat, Category IV:
plus minimum one layer One layer of primer coat,
of intermediate top coat, plus minimum three layers
150 to 250 microns of intermediate top coats,
nominal DFT. minimum 450 microns
nominal DFT.
Paint School
JPS-E/Cathodic/32
Coating Break Down Factor
Acc. to DNV RP B401 (1993)
fc = k 1 + k2 t
Coating Category
I II III IV
Depth
k1 = 0.10 k1 = 0.05 k1 = 0.02 k1 = 0.02
(m)
k2 k2 k2 k2
Paint School
JPS-E/Cathodic/33
Protective
Design Sacrificial Anode System
A. Design criteria
C. Initial and final current
• Current density requirement requirement
– initial
– mean • I INITIAL = A * i init
– final • I FINAL = A * i final
• Design lifetime D. Anode current system capacity
• Anode material
• Anode design (shape and size)
B. Net anode weight requirement
W= Exposed surface area (m²)
• Number of anodes
i = Mean current density (A/ m²)
C= Anode concumption rate (11.2 kg/year for Zn)
( 3.39 kg/year for Al)
L = Design lifetime
U = Utility factor (0.90, normally)
Paint School
JPS-E/Cathodic/34
Jotun Anode Alloys
Coral A Noranode
• Al-Zn-In Alloy • Zn-Al-Mg Alloy
• Increased consumption rate by • Environmental friendly
increasing temperature • Mil. Spec properties below 25 ºC
• Cost effective at elevated
temperature.
Coral Z – Reduced intergranular corrosion
• Zn alloy according to U.S. Mil. – Current capacity and consumption
Spec. A-18001 rate relatively stable at increasing
• Intergranular corrosion above temperatures
approximately 45 ºC – Recommended above 50 ºC
Paint School
JPS-E/Cathodic/35
Comparison of Cathodic Protection Systems
General Advantages:
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JPS-E/Cathodic/36
Comparison of Cathodic Protection Systems
General Disadvantages:
Paint School
JPS-E/Cathodic/38
Why Choose a SACP System on Hull
• Simple installation
• Maintenance free between dry docking
• World-wide availability
Paint School
JPS-E/Cathodic/39
Lifecycle Cost of CP Systems
13000 DWT Car Carrier
90,000
80,000 Zn
70,000
60,000
USD
50,000 Al
40,000
30,000
20,000
ICCP
10,000
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Years
Paint School
JPS-E/Cathodic/40
Life Cycle Cost of CP Systems
Panamax Bulkcarrier
160,000
140,000 Zn
120,000
100,000
USD
80,000
Al
60,000
40,000
20,000
ICCP
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Years
Paint School
JPS-E/Cathodic/41
Cathodic Protection of
Ballast Water Tanks
1. Impressed current systems are not practical, and in
most Classification Societies not permitted.
2. Magnesium anodes are not permitted.
3. In cargo, or adjacent tanks where the flash point is
below 60 deg. C, Aluminium anodes are only
permitted where the kinetic energy can not exceed
27,5 kpm (275 J).
4. There are no restrictions on the positioning of
Zinc anodes.
Paint School
JPS-E/Cathodic/42
Current density
Design Criteria
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JPS-E/Cathodic/43
Example: Tanker vessel.
Clean ballast water. Upper wing tank
Net weight:
Paint School
JPS-E/Cathodic/46
Design of Sacrificial Anode System
Double Bottom and Other Narrow Tanks
Information required:
• Theoretical calculation of net weight of anodes
– From previous calculation
• Number of small compartments
Paint School
JPS-E/Cathodic/47
Design of Sacrificial Anode System
Double Bottom and Other Narrow Tanks
Calculation:
Net weight:
Paint School
JPS-E/Cathodic/50
ICCP - Log report Readings
Current Output Development With Time
Example
Amp.
System capacity
100 -
Grounding (Loss of coating)
80 -
60 -
40 -
20 -
Years
| | | | | |
1 2 3 4 5 6
Paint School
JPS-E/Cathodic/51
Cathodic protection of tanks
Current density at different coating breakdown ratio
Coating breakdown
100
90
80
70
60
50
40
30
20
Soft coat / Flow coat
10
2
0 5 10 20 30 40 50 60 70 80 90 100 110 120
Tar Epoxy
Current density mA/m²
Epoxy Mastic
Paint School
JPS-E/Cathodic/52
Ship hull: Current Density at
Different Paint Damage
Not applicable: Repaint
Paint damage, %
ICCP is recommended,
not sacrificial anodes
100
Sacrificial Anodes
and ICCP can be used
45
15
0 20 70
Current density, mA/ m²
Paint School
JPS-E/Cathodic/53
Galvanic Series in Sea Water
Corrosion Potentials vs. 3 Reference Electrodes
Metal / Alloy Ag / AgCl Zn Cu/Cu SO4
Graphite + 0.25 + 1.28 + 0.17
Titanium 0 + 1.03 - 0.08
Stainless steel (Passive) - 0.50 + 0.98 - 0.13
Copper-Nickel (90/10) - 0.23 + 0.80 - 0.31
Copper - 0.33 + 0.70 - 0.41
Brass - 0.34 + 0.69 - 0.42
Stainless steel (Corroding) - 0.35 + 0.68 - 0.43
Mild steel - 0.66 + 0.37 - 0.69
Aluminium - 0.80 + 0.23 - 0.88
Zinc - 1.03 0 - 1.11
*) Potential in seawater measured versus
Magnesium a copper/coppersulphate
- 1.60 - 0.57 reference electrode
- 1.68
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JPS-E/Cathodic/54
Interference
Anode
+_
Corrosion
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JPS-E/Cathodic/55
Impressed current system anodes
IRON-SILISIUM
Fe - 14,5% Si - 4,5% Cr 10 - 40 0,2 - 0,5
Paint School
JPS-E/Cathodic/56
Anode performance data
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JPS-E/Cathodic/57
Aluminium Anodes
Small vessels
This guide is based on a 3 year (36 month) replacement period (dry-docking interval).
Vessel Type Surface Anode Type Current Density - mA/m2 Number of Total
Area (% coating breakdown) Anodes Weight
Kgs
Tug / Small Vessels 500 A - 50 25 (15 %) 32 160
This design is for the hull only and does not allow for the seachests, thruster tunnels etc..
The calculation is the same, but with specific current densities.
Paint School
JPS-E/Cathodic/58
Zinc Anodes
This guide is based on a 3 year (36 month) replacement period (dry-docking interval).
This design is for the hull only and does not allow for the seachests, thruster tunnels etc..
The calculation is the same, but with specific current Densities
Paint School
JPS-E/Cathodic/59
Principle : Effect of using CP
Corrosion Curves depend on
- Coating condition
- CP-design
Corrosion
CP and coating
at newbuilding
CP installed
Coating breakdown
Time
Paint School
JPS-E/Cathodic/60
Steel passivation by sacrificial anodes
Steel
Paint
2-5% 10 mA/m2
5-10 % 15 mA/m2
10-15 % 20 mA/m2
15-20 % 30 mA/m2
20-25 % 40 mA/m2
25-30 % 50 mA/m2
Paint School
JPS-E/Cathodic/62
CP of ships:
Additional Areas Requiring Protection.
Paint School
JPS-E/Cathodic/66
Cathodic protection
Sacrificial Anodes or Impressed Current
Paint School
JPS-E/Cathodic/67
Location of Pitguard Anodes
Web Frame
Web Frame
Paint School
JPS-E/Cathodic/68
Type of products
Grounding Equipment
• Rudder grounding
• Shaft grounding equipment
• Earthing cables
Paint School
JPS-E/Cathodic/69
Slipring Arrangement
Silver
Graphite Earth to Hull
Brush
Shaft
Paint School
JPS-E/Cathodic/72