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WASTE
MANAGEMENT
AND
TECHNOLOGY
Mecislav Kuras
Institute of Chemical
Technology in Prague
Waste to Energy
Development of
incinerated waste
amounts (excl. mineral
wastes) by waste
category from 2004 to
2008
http://epp.eurostat.ec.europa.eu
Municipal waste treated in 2009 by country and treatment category, sorted by
percentage
http://epp.eurostat.ec.europa.eu
The incineration proces
The typical (nominal) MSW heating value is generally in the range 10 to 12
MJ/kg and the allowable variation is 8.5 to 14.5 MJ/kg. This a very broad
interval compared to systems designated for combustion of a single type of
fuel such as coal or wood chips. Reason is very variable character of waste
to be incinerated.
In the furnace, the overal result of the incineration proces is that combustible
components react with oxygen of the combustion air, releasing significant
amount of hot combustion gas. Furthermore the moisture content of the
waste is evaporated in the initial stage of the incineration proces and the
incombustible parts of the waste form solid residues (bottom ash, fly ash).
During incineration proces in the furnace, the solid constituents of the waste
undergo a range of processes as a result of exposure to heat and contact
with combustion air:
- drying
- gasification (formation of combustible gases)
- ignition and combustion of gases
- burnout of the solids.
Process and energy recovery
The combustion gases pass from the furnace to the afterburning chamber.
To ensure complete burnout the combustion gases must be retained at
least 2 second in the afterburning chamber (within the EU 850°C for
municipal waste, 1100°C for certain types of hazardous waste). No waste is
fed into the incinerator before the required temperature has been reached.
The flue gas is cooled in boiler and the presurised water is heated and in
high pressure boiler evaporated and steam may be superheated (above its
saturated temperature). The purpose – to exploit its energy contents by
expansion in steam turbine connected to power generator.
Waste incineration plants are designated to treat waste with great variation
in the composition of the incoming waste. This is the primary difference
between waste incineration and other combustion systems, and it has large
implication on the desing of the incineration plant.
The waste being led to the incineration plant often consists of several types
of waste, such as household waste, commercial and institutional waste and
some industrial waste. The different waste types received at the incinerator
have significantly different characteristics.
Tanner´s triangle for assessment of combustibility of waste
http://www.wtert.eu
Key variables in characterizing waste as fuel
The main part of the ash content of the waste leaves the furnace as a solid
residue i.e. bottom ash or slag. The remaining ash leaves the furnace as fly
ash. The fly ash is normally separated from the flue gas in the flue gas
treatment system in an electrostatic precipitator or bag house filter.
In the case of grate incinerator, the bottom ash (slag) drops from the end of
the grate into the water trap of the slag pusher. The amount of slag is usually
10-20% by weight of the waste feed, depending on the water composition.
Fly ash constitute usually 5-10% of the ash content.
Possible designs of moving grate systems
http://www.wtert.eu
Moving grate incineration
The bottom ash (slag) drops from the end of the grate into the water trap of
the slag pusher than cooled by contact with cooling water and pass to the
conveyor system. The amount of slag is usually 10 - 25 % by weight of the
waste feed.
Fluidised bed incinerator T. Christensen: Solid Waste
Technology and Management
Fluidised bed incineration
The fluidised bed incinerator is primarily used for homogenous waste typ
including liquid waste.
Rotary kiln incinerator T. Christensen: Solid Waste
Technology and Management
Rotary kiln incineration
The excess air ratio is well above that of the moving grate incinerator and
the fluidised bed. Consequently, the energy efficiency is slightly lower and
may not exceed 80 %. As the retention time of the flue gas usually is too
short for complete reaction to take place in the rotary kiln itself, the cylinder
is followed by an after burning chamber, which may be incorporated in the
first part of the boiler.
The energy recovery system of a waste fired in combined
heat and power plant
T. Christensen: Solid Waste
Technology and Management
Energy conversion technology
The energy recovery from a steam producing boiler is known from conventional
power plant technology as the Rankine process. The Rankine process allows for
energy output in the form of power, steam and various combinations of power,
steam and hot water. The energy from the hot flue gases is recovered via the
boiler and passed in the internal circuit of steam. The steam energy may be
converted to power by menas of a turbine/generator set. The superheated and
high-pressured steam from the boiler expands via the steam trurbine and the
energy content of the steam is hereby transformed to kinematic (rotation )
energy, which is further transform to electrical energy by the generator. The
excess heat of the low pressure steam is via the heat exchanger (condenser)
converted to hot water and passed to district heating network or cooled away.
In the last years the flue gas cleaning has been improved. The
current prioriry is the optimisation of the thermal process to:
- increase the energy efficiency
- reduce the flue gas flow
- minimize the development of hazardous substances like
dioxins, CO and NOx
- minimize corrosion
- improve the ash management
Emmissions from waste incinerator
NOx reduction
NOx formation
- by oxidation of nitrogen in waste
- by high temperature fixation of nitrogen in combustion air (depends on oxygen
availability, temperature, pressure and residence time of gas in combustion unit)
NOx removal
By catalytic or non-catalytic reduction with ammonia or urea.
Particulates
Removal technology depends on the particle size distribution and the
removal efficiency required
- fabric filters (baghouse)
- electrostatic precipitators
Organic micropollutant emissions from waste incinerator
There is no evidence that incineration with proper flue gas purification is the cause of
environmental and health damages, but nevertheless it remains an unpopular and
controversional waste management option.
The main concern – polychlorinated dibenzodioxins and dibenzofurans.
The process of gasification and pyrolysis, discovered at the outset of the XIX
century, has only recently (20 – 30 years ago) been proposed for use in the
treatment of wastes as an alternative to the „traditional“ thermovalorisation
based on combustion process.
Gasification is the conversion of organic fraction of wastes or biomasses into
a mixture of combustible gases by means of partial oxidation at high
temperatures (400 – 1500oC). The gas thus produced made up mainly of a
mixture of CO and H2 has calorific potential 4 – 6 MJ/Nm3 and may be used
to fuel internal combustion engines or gas turbines. In addition, the gas may
be used as raw material for the manufacturing of chemical products (e.g.
methanol).
Pyrolysis is endothermal transformation, in the absence of oxygen, of
biomasses or liquid, solid or gaseous fractions of wastes. Pyrolysis can also
be applied in the production of bio-oils with an efficacy reaching 80%.
Commercial application especially in Japan.
Waste pyrolysis
There are several variation of pyrolysis system, including rotary kiln, rotary
hearth furnace and fluidized-bed furnace. Unit designs are similar to incinerators
except that they operate at lower temperature and with less airs supply.
Several gases such as argon, helium, methane or steam can be used for
this purpose. In case of wastes the most commonly used gas is air. The air
is rendered electrically conductive by subjecting it to marked differences of
electric potential, generating a stable electric discharge (arc) between two
electrodes. Resistance afforded by air versus the flow of electrons produces
considerably quantities of thermal energy ranging from to 5000 to 10 000°C.
Plasma technology is known since 70´s. The high temperature and the
plasma arch are able to melt almost everything in seconds. Even so a lot of
research was done in the past the plasma technology never became a real
option in waste management.
For the above reason and due to the high operational costs, plasma
technologies are mainly applied in the treatment of hazardous or radioactive
wastes.
A more extensive distribution of these plants will likely occur once their
design and development has been rendered increasingly simple and
economical. In the future the system may even constitute a promising
alternative to the traditional systems of thermovalorisation, leading to the
release of gas emissions with a lower pollutant potential and vitirified solid
residue.
Refuse derived fuels (RDF)
RDF is a result of processing solid waste to separate the combustible fraction from
the non-combustibles, such as metals, glass and cinder in municipal solid wastes
(MSW). RDF is predominantly composed of paper, plastics, wood and kitchen and
yard wastes and has a higher energy content than MSW, typically in the range 12 to
15 000 kJ/kg.
Like MSW, RDF can be burned to produce heat or/and electricity. RDF processing is
often bound with the recovery of metals, glass and other recyclable materials,
thereby improving on paybacks for investment costs.
At present time RDF combustion is less common than mass burning of MSW, but it
may change in the future as recovery of recyclable materials and environmental
concerns over incinerators emissions become more important.
The major benefints of RDF are:
- It can be shredded into uniformly sized particles or densified into briquets. Easily
handled, RDF can be burned or co-fired with another fuel such as wood or coal in
an existing facility.
- Fewer noncombustibles such as heavy metals are incinerated. The high
temperature of MSW furnace can cause metals to partially volatize, resulting in
release of toxic fumes and fly ash.
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