STL 2016 KIMIA

ESSAY

4. Untuk reaksi : NH3(g) + H2S (g) ↔ NH4HS(s) Kc=400 pada 27 C

Jika 2 mol masing-masing NH3 , H2S dan NH4HS dimasukkan ke dalam bejana 5L. Hitung :
a. Massa NH4HS pada saat seimbang
b. Tekanan H2S pada saat seimbang
a. NH3(g) + H2S (g) ↔ NH4HS(s) b. PH2S . V = n . R . T
7
M 2 mol 2 mol 2 mol PH2S . 5 = ( 2 - 4 ) . 0,082 . 300
B x x x PH2S = 6,15 atm
S 2-x 2-x 2+x
1 15
Kc = 2−𝑥 n=
( 5 )2 4
𝐺
20(2-x) = 5 n= 𝑀𝑟
15
8-4x =1 . 51 = G
4
7
x = G = 191,25 g
4
5. Nitrosyl Chloride, NOCl, decomposes on heating according to the below equation :
NOCl(g) ↔ NO(g) + ½ Cl2 (g)
When 100 cm3 of nitrosyl chloride was placed in a closed container at constant pressure and heated to a constant
temperature, it was found that nitrogen monoxide constitutes 40% of the equilibrium mixture. What is the total
volume of gases in the equilibrium mixture at the temperature of the reaction?

NOCl(g) ↔ NO(g) + ½ Cl2 (g)

M 100 ml
B x x ½x
S 100-x x ½x

X = 40% . (100 + ½ x)
X = 40 + 0.2x
0.8x = 40
X= 50ml

Vtotal = 100 + ( ½ . 50)

= 125ml