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INTRODUCTION
Particle technology [PT ]
A science and technology related to handling, processing and dynamics
of particles for size reduction / enlargement & powders formation.
Tendency to absorb
moisture from the air
The Impact of Particle Technology
Knowledge of the processing and handling of particles or
powders production on the bases of material properties.
Knowledge of particulate solid is necessary :
i. to Identify equipment and other system aspects of the unit
operations;
ii. to design processes and equipments to deal streams of
such solids.
Characterization and particulate systems data helps in
optimizing the entire engineering applications of particle
technology in chemical industries,
Particle Technology
Bulk Properties:
An intensive property is a bulk property, meaning that it is the physical
property of the system that does not depends upon the size or the amount of
material in the system. E.g: temperature, density, hardness of the object etc.
Intensive Properties: Properties that does not depend upon the size or the
amount of material in the system, e.g: temperature, density, hardness of the
object etc.
Extensive Properties: Properties that depend upon the size or the amount of
material in the system, e.g: mass, volume etc.
Particle Size
PARTICLE SIZE
In general, diameter is specified for equidimensional particles.
Most of the particles are not equidimensional, therefore they can not be specified
by a single dimension “diameter”.
Therefore the concept of equivalent sphere has been introduced.
Equivalent spheres in comparison with Particle
dimensions:
Based upon the measurement techniques, the particles are related to equivalent sphere
diameters by,
a. The sphere of the same volume of the particle.
b. The sphere of the same surface area as the particle.
c. The sphere of the same surface area per unit volume.
d. The sphere of the same area when projected on a plane normal to the direction of
motion.
e. The sphere of the same projected area as viewed from above when lying in a position
of maximum stability (as with a microscope).
f. The sphere which will just pass through the same size of square aperture as the particle
(as on a screen).
g. The sphere with the same settling velocity as the particle in a specified fluid.
Mixed Particles and SIZE ANALYSIS
If we have a sample of uniform particles of diameter = Dp,
The total volume of the particles will be = m/ρp, (representing mass
and density of the particles),
Since the volume of one particle = Vp,
Total volume ‘V’ of N particles = V = Vp.N
The total number of particles in sample = N = m/ ρpVp
Total surface area of the particles is given by,
Mixed particle size and size analysis
Both these equations are applied to mixtures having various sizes and densities.
The mixture is sorted into fractions, each of constant density and approximately
constant size.
Each fraction is then weighed, or the individual particle can be counted or
measured by number of methods.
Information from such a particle size analysis is tabulated to show the mass or
number fractions in each size increment as a function of average particle size in
the increment.
An analysis tabulated in this way is called a differential analysis.
The results are often presented in histogram as shown in the figure.
Description of populations of particles
Particle population is described in terms of Particle size distributions.
Cumulative Size Distribution.
Frequency Size Distribution.
Specific surface area of mixture
If the particle density ρp and Sphericity Φs are known, the surface area
of particles in each fraction can be calculated and added to give the
specific surface, Aw (The total surface area of the unit mass of
particles):
For deriving this equation, it has been assumed that Sphericity and density of the
mixture is constant.
Where xi = mass fraction in a given increment,
Dpi = average diameter (taken as arithmetic average of the smallest and largest
particle diameters in increment).
Average particle size
The average particle size for a mixture of particles is defined
in several different ways.
Volume surface mean diameter Ds:
a = volume shape factor
For sphere the value of a is 0.5236 and for short cylinder it is 0.785.
Assuming that a is independent of size, then:
Screen analysis
•Testing sieves are made of
woven wire screens.
•Openings are square.
•Screens are identified by Mesh
No.
•Mesh No. is the numbers of
opening per linear inch.
𝒅𝑺𝑻 = 1൘ µ3,𝒊
σ𝑵
𝒊=1 𝒅
𝒎,𝒊
Properties of masses of particles
Masses of solid particles, especially when the particles are dry and
not sticky, have many of the properties of a fluid.
They exert pressure on the sides and walls of a container, they flow
through openings or down a chute.
They differ from liquids and gases in several ways.
However because the particles interlock under pressure and
cannot slide over one another until the applied force reaches and
appreciable magnitude.
Interlocking
Properties of masses of particles