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Energy Balance
m – mass (kg)
g – gravitational constant, 9.81 ms-2
v – velocity, ms-1
etc
Enthalpy balance
Change of T at constant P
Change of P at constant T
Change of phase
Solution
Mixing
Chemical reaction
crystallisation
Paul Ashall, 2008
Latent heats (phase changes)
Vapourisation (L to V)
Melting (S to L)
Sublimation (S to V)
ΔP = P2 – P1 (Pa)
Δv2 = v22 – v12
Δh = h2 - h1 (m)
F= frictional energy loss (mechanical energy
loss to system) (J/kg)
W = work done on system by pump (J/kg)
ρ = 1000 kg/m3
aA + bB cC + dD
-a -b +c +d (stoichiometric
coefficients, νi)
ΔHofA, ΔHofB, ΔHofC, ΔHofD (heats of formation)
ΔHoR = c ΔHofC + d ΔHofD - a ΔHofA - bΔHofB
Paul Ashall, 2008
Heat (enthalpy) of reaction
+ve
Qp
-ve
Note: enthalpy values must bePaul
calculated
Ashall, 2008
with reference to a
temperature of 25 deg cent
Energy balance techniques
Adiabatic temperature: Qp = 0
Reactor
Crystalliser
Drier
Distillation