GC-MS

PROCESS AND
LIMITATION
PRESENTATION
OUTLINE THINGS TO COVER TODAY

Combined GC-MS.
GC-MS use to measure amounts
of chemicals in the air.
Limitation
Sample Preparation
KIMIA ANALITIK

KOMBINASI GC-MS
A VERY
POWERFUL AND
SENSITIVE
INSTRUMENT

PICOGRAMS
THE GCMS CAN DETECT CHEMICALS IN
AMOUNTS AS SMALL AS A PICOGRAM.
KECEPATAN
Cepat membentuk kesetimbangan antar
fase.

SENSITIF Mengapa GC
Mendeteksi senyawa dengan ukuran
sampel yang kecil.
dapat
PEMISAHAN
mengidenti
Pemisahan komponen berdasarkan titik
didih dan retensi.
fikasi
ANALISA
Hasil hadir dalam bentuk kromatogram.
Dapat kuantitatif juga kualitatif.
 LIMITATION
GC-MS

WAKTU TAFSIR SPEKTRUM

Waktu penganalisaan tidak tepat menafsirkan
cukup lama. spektrum massa. 5000+
spektrum.

PEMISAHAN JENIS SENYAWA

Tidak memisahkan senyawa Hanya terbatas untuk
spesimen sepenuhnya. senyawa volatile.
SAMPLE COLLECTION
Sample collected on a catrige

PRE-TREATMENT
GC-MS samples often contain dirty,
PREPARASI
labile, and volatile compounds that
sometimes need further processing
before they are introduced into the
SAMPLE
gas chromatograph.

EXTRACTION
To separate sample components,
remove interferences, or fractionate
the sample matrix. .
PRE TREATMENT
There are many treatment
methods of micropollutants. EXTRACTION (SPE)
These are coagulation-
The sample itself will
flocculation, settling,
typically (although not
filtration, etc.
always) be in liquid form.
To separate sample
components, remove
interferences
REFER • Douglas, F. 2015. GC/MS Analysis. [online] Available at:
http://www.scientific.org/tutorials/articles/gcms.html.

ENCES •
[Accessed 4 Desember 2019].
Thermofisher.com. 2019. Gas Chromatography Mass
Spectrometry (GC/MS) Information. [online] Available at:
https://www.thermofisher.com/id/en/home/industrial/mass-
spectrometry/mass-spectrometry-learning-center/gas-
chromatography-mass-spectrometry-gc-ms-information.html.
[Accessed 4 Desember 2019].
• Anonim. 2017. Gas Chormatography Mass Spectrometry.
[online] Available at: http://www.bris.ac.uk/nerclsmsf
/techniques/gcms.html. [Accessed 4 Desember 2019].
• Day R.A. dan A.L. Underwood, (1999). Analisis Kimia
Kuantitatif. Jakarta: Erlangga.
TERIMA KASIH