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ISSUES TO ADDRESS...
• What promotes bonding?
Chapter 2- 1
Adhesive forces
Chapter 2-
BOHR ATOM
orbital electrons:
n = principal
quantum number 1
n=3 2 Adapted from Fig. 2.1,
Callister 6e.
Nucleus: Z = # protons
= 1 for hydrogen to 94 for plutonium
N = # neutrons
Atomic mass A ≈ Z + N
Chapter 2- 2
ELECTRON ENERGY STATES
Electrons...
• have discrete energy states
• tend to occupy lowest available energy state.
Chapter 2- 3
STABLE ELECTRON CONFIGURATIONS
Stable electron configurations...
• have complete s and p subshells
• tend to be unreactive.
Chapter 2- 4
SURVEY OF ELEMENTS
• Most elements: Electron configuration not stable.
Electron configuration
1s1
1s2 (stable)
1s22s1
1s22s2
1s22s22p1 Adapted from Table 2.2,
1s22s22p2 Callister 6e.
...
1s22s22p6 (stable)
1s22s22p63s1
1s22s22p63s2
1s22s22p63s23p1
...
1s22s22p63s23p6 (stable)
...
1s22s22p63s23p63d10 4s246 (stable)
Adapted
from Fig. 2.6,
Callister 6e.
Chapter 2- 8
EXAMPLES: IONIC BONDING
• Predominant bonding in Ceramics
NaCl
MgO
H He
2.1 CaF2 -
Li Be O F Ne
1.0 1.5 CsCl 3.5 4.0 -
Na Mg Cl Ar
0.9 1.2 3.0 -
K Ca Ti Cr Fe Ni Zn As Br Kr
0.8 1.0 1.5 1.6 1.8 1.8 1.8 2.0 2.8 -
Rb Sr I Xe
0.8 1.0 2.5 -
Cs Ba At Rn
0.7 0.9 2.2 -
Fr Ra
0.7 0.9
Chapter 2- 10
EXAMPLES: COVALENT BONDING
H2O
column IVA
H2 F2
C(diamond)
H He
2.1
SiC - Cl2
Li Be C O F Ne
1.0 1.5 2.5 2.0 4.0 -
Na Mg Si Cl Ar
0.9 1.2 1.8 3.0 -
K Ca Ti Cr Fe Ni Zn Ga Ge As Br Kr
0.8 1.0 1.5 1.6 1.8 1.8 1.8 1.6 1.8 2.0 2.8 -
Rb Sr Sn I Xe
0.8 1.0 1.8 2.5 -
Cs Ba Pb At Rn
0.7 0.9 1.8 2.2 -
Fr Ra
0.7 0.9
Adapted from Fig. 2.7, Callister 6e. (Fig. 2.7 is GaAs
adapted from Linus Pauling, The Nature of the Chemical Bond, 3rd edition, Copyright
1939 and 1940, 3rd edition. Copyright 1960 by Cornell University.
Chapter 2- 12
SECONDARY BONDING
Arises from interaction between dipoles
• Fluctuating dipoles
-ex: polymer
Chapter 2- 13
15
Chapter 2-
SUMMARY: BONDING
Type Bond Energy Comments
Ionic Large! Nondirectional (ceramics)
Variable Directional
Covalent large-Diamond semiconductors, ceramics
small-Bismuth polymer chains)
Variable
Metallic large-Tungsten Nondirectional (metals)
small-Mercury
Directional
Secondary smallest inter-chain (polymer)
inter-molecular
Chapter 2- 14
PROPERTIES FROM BONDING: TM
• Bond length, r • Melting Temperature, Tm
F
F
• Bond energy, Eo
Tm is larger if Eo is larger.
Chapter 2- 15
TM vs Bonding Energy
Chapter 2-
PROPERTIES FROM BONDING: E
• Elastic modulus, E
Elastic modulus
F L
=E
Ao Lo
• E ~ curvature at ro
Energy
unstretched length
ro E is larger if Eo is larger.
r
smaller Elastic Modulus
L
= a(T2-T1)
Lo
• a ~ symmetry at ro
a is larger if Eo is smaller.
Chapter 2- 17
SUMMARY: PRIMARY BONDS
Ceramics Large bond energy
(Ionic & covalent bonding): large Tm
large E
small a
Chapter 2- 18