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Polymer Solar cell

by
Chandra Mohan Singh Negi
Dept. of Electronics
Banasthali Vidyapith ,
Rajasthan
Outline

Introduction
Background
Previous work
Traditional Cells vs. Organic
Major challenges
Applications
conclusions
Introduction

Konarka
Cons:
Pros: low ambient stability
Tailoring of opto-electronic properties strongly bound excitons
large areas Short exciton diffusion length 5-
low temperatures (RT) 20 nm.
processing from solution low mobility of charge carriers
roll to roll manufacturing μ n (c-Si) > 1000 cm2/Vs

μh (polymer) ≈ 0.1
light weight
cm2/Vs
transparent
difficult to obtain low band-gap
low cost…….maybe… materials
Background
Previous work on Solar cells

20x-100x 500x Cu(In,Ga)Se2 ~ 1-2 um c-Si ~ 180 um


How photovoltaic solar cells work?
Traditional Cells vs. Organic

100nm
100 nm
100 nm

Bulk Heterojunction
Device architecture and Photovoltaic
parameters
5

Charge separation layer


0
200nm

Current (mA/cm2)
150nm
-5 100nm

-10

-15

-20
-0.9 -0.6 -0.3 0.0 0.3 0.6 0.9
Voltage (V)

Device FF (%) VOC (V) JSC (mA/cm2) EFF (%)

100nm 61.9 .740 11.55 5.29


150nm 56.9 .750 13.74 5.87
Major challenges

Stability & Life time

Inadequate efficiency

Competition with existing Si industry


Applications

Off-grid electricity generation to the

remote location

Low-cost, environment friendly energy

solution

Space application due to light weight

Building integrated photovoltaics.


Future research
1.Ternary blends based solar cells.
2.Low band gap materials.
3.Fullerene free solar cells.
4.Tandem solar cells
Conclusions
Solar energy is infinitely available.

High production of silicon solar cell is the major

obstacle for widespread deployment.

OSCs find new niches of applications related to light

weight and flexibility.

OSCs are probably be the cost-effective solution for

our large-scale future energy problems.


References

1. G. Keru, P.G. Ndungu, G.T. Mola and V.O. Nayamori, “Bulk Heterojunction Solar
Cell with Nitrogen-Doped Carbon Nanotubes in the Active Layer: Effect of
Nanocomposite Synthesis Technique on Photovoltaic Properties”, Materials, vol 8,
pp. 2415-2432, 2015.
2. S. Jin, G. Jun, H. Jeon and S.H. Hong, “Design and application of carbon
nanomaterials for photoactive and charge transport layers in organic solar cells”,
Nano Convergence, vol 3, pp. 8, 2016.
3. P. Rathore, C.M.S. Negi, A. S. Verma, A. Singh, G. Chauhan, A. R. Inigo, and S. K.
Gupta, “Investigation of Optical and electrical characteristics of solution processed
Poly (3 hexylthiophene)(P3HT): Multiwall carbon nanotubes (MWCNTs) composite
based devices”, Materials Research Express, Vol 4, pp. 085905, July 2017.
4. D. H. Kim, and J. G. Park, “Polymer photovoltaic cell embedded with p-type single
walled carbon nanotubes fabricated by spray process”, Nanotechnology, vol 23,
pp. 325401, July 2012.
5. V. Singh, S. Arora, M. Arora, V. Sharma and R.P. Tondon, “Optimizing
P3HT/PCBM/MWCNT films for increased stability in polymer bulk heterojunction
solar cells”, Physics Letters A, vol. 378, pp. 3046-3054, August 2014.

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