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Oleh :
Bobby Fadillah
Rakhmat Hidayanto
Ferlyandi
Jesrel Tobing
F. Asisi G Naibaho
Arie Pratama
Aditya Heryadi
Outline Presentation
Mechanism Diffusion in Solid
Diffusion Under the Influence of a
Composition Gradient
Darkens Equation
Temperature Dependence of Diffusion in
Solids
Appliccation of diffusion in solid in
metallurgy
Refrence
Mechanism Diffusion in Solid
• Glass tube filled with water.
• At time t = 0, add some drops of ink to one end
of the tube.
• Measure the diffusion distance, x, over some time.
• Compare the results with theory.
to x (mm)
t1
t2
t3
time (s)
xo x1 x2 x3
Diffusion Mechanisms (I)
5
Mechanism Diffusion in Solid
Diffusion, simply, is atoms moving from one lattice site to
another in a stepwise manner
◦ Transport of material by moving atoms
Two conditions are to be met:
◦ An empty adjacent site
◦ Enough energy to break bonds and cause lattice distortions
during displacement
What is the energy source ?
◦ HEAT !
Diffusion Under the Influence of a Composition
Gradient
In an alloy, atoms tend to migrate
• Interdiffusion:
from regions of high conc. to regions of low conc.
Initially After some time
Adapted
from Figs.
5.1 and 5.2,
Callister 7e.
DIFFUSION: THE PHENOMENA (2)
• Self-diffusion: In an elemental solid, atoms also migrate.
C
C
A D
A
D
B
B
4
Darkens Equation
Hubungan kenaikan difusi melawan gradien
konsentrasi
D = (XABBKBT+XBBAKBT)
BINE
M
CO
Temperature Dependency !
BINE
M
CO
Temperature Effect !
æ Qd ö
D = Do expç- ÷
è RT ø
1500
1000
600
300
T(C)
10-8
C
D (m2/s)
in
Ci
na Dinterstitial >> Dsubstitutional
g-
-Fe
Fe e i
C in a-Fe Al in Al
F
Fe
10 -14
C in g-Fe Fe in a-Fe
n
i
ng
a-
Al
Fe in g-Fe
Fe
in
-Fe
Al
10-20
0.5 1.0 1.5 1000 K/T
Adapted from Fig. 5.7, Callister 7e. (Date for Fig. 5.7 taken from E.A.
Brandes and G.B. Brook (Ed.) Smithells Metals Reference Book, 7th
ed., Butterworth-Heinemann, Oxford, 1992.)
Application of diffusion in solids in
metallurgy
Pack carburizing
Solid solution Hardening
Presipitation Hardening
Reference
Geiger. G.H Transport Phenomena in
metallurgy
www.fen.bilkent.edu.tr/~bengu/chem201/.../
Chapter_05_avi_erman
www.amazon.com › ... ›
Science & Mathematics › Mechanics