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In Power Apparatus Liquid Insulation is used for: Cooling and Heat Transfer Filling Agent in Voids of Solid Insulation Arc Quenching in Circuit Breakers Liquids find Application in: Transformers Cables and Capacitors Circuit Breakers Solid State Power Electronic Devices
Most Commonly used Liquids are Hydrocarbon or Mineral Oils Askerals or Polychlorinated Diphynyls Silicone Oils Synthetic Hydrocarbon Oils such as Polyolefins, Polyester Oils (eg. PETEP) High Temperature Hydrocarbon Oils (eg. HTH, Tetrachloroethelene) Most of these Oils have Specific Gravity 0.8 to 0.95 Dielectric Strength Max ~ 1MV/cm Working 150 200 kV/cm
Electrical Properties Relative Permittivity er Volume Resistivity r Power factor or loss tangent tand Dielectric Strength (kV/cm) Other Physical properties Specific Gravity Viscosity, Temperature Viscosity characteristic Surface Tension Coefficient of Volume expansion Thermal conductivity Pour point, Flash point & Fire point Refractive Index Acid Value and Saponification Value
Testing of Oils
To assess the quality of the oil following parameters are determined on samples er and tand Dielectric Strength Acid value and Saponification value Sludge Value
Other Properties are determined only for new oils or when oil is to be replaced.
Silicone Oils
Silicone Oils are obtained by replacing silicon in place of carbon atoms in paraffin chain or aromatic chain as follows:
Hydrocarbon Oils Silicone Oils
The oils have excellent electric properties, good thermal stability upto 1500C and oxidation resistant. They are nonflammable. These oils are very costly (about 10 times that of transformer oil) and hence are not widely used.
Polyester oils
Natural esters such as caster oil, linseed oil etc are widely used as capacitor oil, particularly for high frequency applications ( upto 1 MHz). They have high boiling point, high fire point etc. Recently synthetic esters have been developed viz organic esters, phosphate esters etc. These oils are biodegradable and hence do not pose problem for environmental pollution.
New Liquids
A few new oils such as high temperature hydrocarbon oil (HTH), Tetrachloroethelene etc have been introduced recently whose properties are much similar to that of transformer oil with much better heat transfer properties. They can be worked upto 2500C or more.
Cable Oil
30 kV/mm
PETE P Oil
>15 kV/mm
Silicone Oil
30 40 kV/mm
2.2 2.3
2.3 2.6
2.1
0.25 x 10-3 0.10 x 10-3 1013 1014 0.88 0.89 30 Nil
2.7
0.1 x 10-3 0.5 x 10-3 >1014 0.96 0.97 80 <0.03
2 - 73
T a n d
0.001
0.002
10-3
1 kHz
10-4
Resistivity ohm-cm Specific Gravity at 200 C Viscosity at 200 C (CS) Acid Value (mg/gm of KOH) Refractive Index
3 x 1014
0.89
30 Nil
0.93
30 Nil
1.0 1.1
10 1000 Nil 1.5000 1.6000
1.4820
1.4700
1.4740
1.4555
Saponification (mg of KOH/gm of Oil) Thermal Expansion (20 1000 C) Max. Permissible water content (in ppm)
0.01
0.01
0.01
<0.01
7 x 104 /0 C
7 x 104 /0 C
7 x 104 /0 C
0.00075
50
50
50
200
HTH
43 118 85 2.38
C2Cl2
43 -
2.365
1000 C
500 C 250 C
0.4
0.4 <10-3 285 312 -30
0.05 -
Flash point, 0C Fire point, 0C Pour point, 0C Viscosity, cSt 1000 C 500 C 250 C Specific gravity
-22 36 42 55 1.620
16 85 350 0.877