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Cool in a Dessicator
Add 15 g of solid urea. Cover with watch glass. Boil for 30 minutes
Place in a dessicator
Place the NaOH sol'n to 200 mL of distilled water in a 1-L volumetric flask
Weigh individual 0.7-0.8 g duplicate samples of the dried KHP into 250 mL E. flask
Calculate the concentration of the NaOH sol'n (M). Get the average M of NaOH
Titrate with base until the pink color of the indicator persists for 30 s
Place a test tube/ small beaker over the top of the burette with NaOH
Record the initial volumes of acid and base in the burettes to the nearest 0.01 mL
Rinse the tip of the burette with distilled water from a wash bottle
Cool it in a desiccator
Determne an indicator correction by titrating 100 mL of 0.05M NaCl and 3 drops indicator.
Titrate with standardized HCl until the color changes from blue to green
Subtract any volume needed for the blank from the titration volumes
Add 2 drops of phenolphthalein indicator and titrate the sol'n with the standard HCl until a light pink color appear
To the same sol'n, add 2 drops of methyl orange indicator and titrate until the color becomes peach
From the 2 volumes of HCl, determine the components of the unknown sample as to (NaOH & Na2CO3) or (NaHCO3 & Na2CO3)
Compute the concentration of the two basic components in the unknown mixture
Experiment No. 6
Determination of Ionization Constant of a Weak Acid By Potentiometric Titration
OBJECTIVES
To be familiar with the concepts of potentiometric titration To know the proper techniques in potentiometric titration To determine the ionization constant of a weak acid
PROCEDURES
Add 1mL interval at the volume before the sudden change. Record pH.
Change 1mL to 0.5 mL interval during the sudden change. Record the pH.
Add 1mL of the titrant after the sudden change in pH. Record pH.
Determine the volume of titrant used to reach equivalence point and conc. of unknown
To the flask, add 5 drops of Eriochrome Black T indicator and titrate with 0.005 M EDTA
Pippette 25 mL aliquot portion of the CaCO3 sol'n to a 250 mL e.flask and add 10 mL of NH3 buffer
Pipette triplicate 50 mL aliquot portions of the water sample into a 250 e.flask
Add 5 drops of EBT indicator and titrate with the 0.005 M EDTA until clear blue color appears
Heat each sol'n to 8090C and titrate with KMnO4 while stirring with a thermometer
Correct the titration data by subtracting the volume obtain from blank titration
Add 5 drops of saturated bromine water and boil gently for 5 minutes
Dilute each sample solution to about 50 mL, heat to boiling, and add 100 mL of hot 6% (w/v) (NH4)2C2O4 sol'n
Add 3 to 4 drops of methyl red, and precipitate CaC2O4 by slowly adding a 6 M NH3 sol'n
Allow the sol'n to stand for no more than 30 min and then filter
Continue until the sol'n becomes the intermediate yelloworange color of the indicator.
When the indicator starts to change color, add the NH3 at a rate of one drop every 3-4 sec
Add 100 mL of water and 50 mL of 3 M H2SO4 to each of the beakers containing the precipitated CaC2O4 and crucible
The temperature should be greater than 60C throughout the titration; reheat if necessary
EXPERIMENT NO. 12
OBJECTIVES
To be familiar with the Oxidation/Reduction Titration. To determine the Ascorbic Acid Content of Vitamin C tablets using the standard Potassium Bromate (KBrO3) Solution.
Schematic Diagram
3 5 g Vitamin C Pulverize 0.04 0.05 sample (250mL Erlenmeyer Flask) Dissolve (50mL 1.5M H2SO4) 5g KBr Titrate w/ KBrO3 (Faint yellow) 3 g KI & 5mL starch indicator Back titrate (Na2SO3)
Learnings/Insights
Using Iodometric Method, one can calculate the ascorbic acid content of Vitamin C Balancing Redox Reactions Redox Titration