Академический Документы
Профессиональный Документы
Культура Документы
Science and
NCTU 11 CSDLab
Outline
n
Introduction
Material Properties of GaN Application Advantages Issues of GaN grown on Si substrate MOCVD growth of GaN on Si
n n n
NCTU 22 CSDLab
Introduction
NCTU 33 CSDLab
Why GaN ?
Material Properties
Large direct band gap
Device Implications
High breakdown voltage, high temperature operation, UV optoelectronic devices High sheet charge concentration without intentional doping, device applications Microwave devices easily fabricated
High melting point, physically Easier to process and handle hard material
NCTU 44 CSDLab
Key features of GaN High breakdown voltage nWide Band gap nHigh current density - High electron velocity - High sheet carrier density
n
NCTU 55 CSDLab
NCTU 66 CSDLab
RF electronics
Laser Diodes
Power electronics
NCTU 77 CSDLab
NCTU 88 CSDLab
Thyristor
1MW
Train
SiC
100kW
IGBT
Vehicle
10kW
GaN
Solar Inverter IH Cooking Power Source for PC 1 bit Audio Amp.
Si
1kW
MOSFET
0.1MHz 1MHz 10MHz
100MHz
1GHz
10GHz
Frequency
NCTU 99 CSDLab
2014: IGBT with 3-D trench and field stop approach GaN HEMT has larger breakdown voltage and smaller on-resistance * GaN-based device has better power handling capability NCTU 1010 CSDLab
Application Advantages
Automotive
Manufacturin g apparatus
Home Appliances
Electric Vehicle Configuration modules to DC/DC boost converter and DC/AC inverter are key
drive the AC high power motor from battery energy. DC/DC buck converter is needed for the accessories.
power devices. Therefore, power devices are key components for electric (IEDM Data from Toyota Central R&D Labs. 2010) vehicle.
Breakdown voltage: It is needed to over 1000 V, taking the surge capability into considerations. On-resistance: It is as low as possible to reduce the power loss, to minimize the size and to reduce the cost. Normally-off: E-mode is required for the simple inverter control board and the fail-safe viewpoint.
AlGaN/GaN HEMT
S G AlGaN GaN Substrate D
2DEG
Ec= 68% Eg
Unlike other HEMT structures, 2DEG charges in GaN HEMT is induced by: Polarization field & surface traps
Origins of spontaneous polarization: i) Lack of inversion symmetry of the wurtzite structure ii) High electronegativity of nitrogen atom A For AlxGa1-xN pseudomorphically grown on GaN: N AlGaN l Ps Pp Spontaneous: (tensile) A Psp p z Cm-2 (x) = -0.090x 0.034(1-x) + 0.019(1-x) N l Piezoelectric: Ga N Ppz (x) = -0.0525x 0.0282x(1-x) Cm-2 GaN Psp Ga (relaxed) N
Net fixed polar charge at the AlGaN/GaN interface: = Ppz + Psp - Psp
AlGaN GaN
AlxG1-x N
Epz
Net polar charges induce electric field Epz in AlGaN Electrons at the surface are driven into the channel by the strong Epz
Without material doping in AlGaN or GaN, formation of 2DEG as a result of polarization field and surface traps
- source: UCSB
2DE G
- source: UCSB
ns = surface states
Surface potentia l, s
Minimum thickness
3. t > tcrit ( > Et) electrons transfer to channel s 2DEG 4. tcrit depends on the Et and Epz.
- source: UCSB
E t
Film cracking
1.
When Al% increase polarization field increase, ns increase. Al% increase, mobility decrease due to i) alloy scattering, ii) interface roughness Al>35%, large stress in AlGaN, film crack, mobility drops abruptly.
Source: National Research Council Canada
2.
3.
Lattice mismatch l lattice mismatch between GaN and Si is 17% l High dislocation density in GaN layer(1010cm-2) Meltback etching l At high temperature Ga and Si form an alloy leads to deterioration of the substrate and the epilayer
Meltback etching
GaN layer shows a rough surface Deep hollows in Si substrate
mismatch
Thermal mismatch between GaN and Si is 54% High tensile stress cause cracks in GaN when
cooling from high growth temperature Cracks and GaN thickness is trade off.
Epitaxy Process
GaN reactor cleaning and conditioning
Using long bake-out at 1050oC for 30 minutes in hydrogen between each GaN deposition run to remove the Ga from the susceptor and chamber and gas lines
Pre-treatments of Si substrate
The Si(111) substrates were chemically cleaned by H2SO4: H2O2: H2O (3:1:1) and BOE HF(20:1) before being loaded into the reactor
In situ cleaning
NH3
1050
1035
1035
H2
860
300 torr
550
800
HT/LT/HT AlN
50m
50m
The FWHM of the XRD rocking curve decreases when the AlN thickness increases. This means that to reach a high quality AlN film, enough AlN thickness is necessary.
Also confirms that in order to grow high quality GaN films, high quality AlN buffers are necessary.
1
Single HT-AlN
2
*MultilayerAlN
3
*MultilayerAlN
4
*MultilayerAlN
5
*MultilayerAlN
6
*MultilayerAlN/ AlGaN
*Multilayer-AlN:HT-AlN/LT-AlN/HT-
Layer thickness, composition and induced strain for sample A~D with different buffers * multilayer AlN(High Temperature/Low Temperature/ High Temperature AlN)
Sample GaN Thickness (m) *AlN Graded Thickness AlxGa1-xN (nm) Thickness (nm) Fixed AlxGa1-xN x fraction Fixed AlxGa1-xN Thickness (nm) AlN strain (a) AlN XRD (004) FWHM (deg) GaN strain (a) GaN XRD (004) FWHM (deg)
A B C D
XRD -2 scan of GaN films grown on various types of multilayer AlN/graded AlxGa1-xN/fixed AlxGa1-xN composition buffers NCTU 3737 CSDLab
With the combination of multilayer AlN and AlGaN buffers, high quality
NCTUs GaN on Si
NCTU CSDLab
3838
The values of the tensile stress in the GaN films sample A = 0.162 GPa sample B = 0.209 GPa sample C = 0.139 GPa sample D = 0.069 GPa
*Guha, F.Shahedipour, R. C.Keller, V. Yang and B. W. Wessels, Appl. Phys. Lett. 78,58(2001)
Reciprocal space mapping for GaN with AlN/AlGaN buffer on Si (111) substrate
afilmGaN=3.1928 , afilmAlN=3.1203 abulkGaN=3.189 ,abulkAlN=3.111
Growth of high quality GaN film on Si substrate by using AlN and Graded AlGaN Buffer Layers
GaN
Al0.07Ga0.9 3N Al0.29Ga0.7 HT/LT/HT AlN 1N
Si Substrate
The dislocations density in GaN film is much lower than those in AlGaN and AlN films. Double AlGaN buffer layers can reduce threading dislocation propagation.
0.4 m GaN on Si
1.2 m GaN on Si
Dislocation density is reduced from 5.88109 to 2.04108 cm-2 by increasing GaN thickness from 0.4 m to 1.2 m. Low dislocation density GaN film can be obtained using double AlGaN buffer layers.
Si Si
Process Flow
Source Drain
AlGaN GaN Substrate Substrate
Source
Drain
AlGaN GaN Substrate
AlGaN GaN
Ohmic
Mesa
Gate
v
Substrate
AlGaN GaN
v
Substrate
AlGaN GaN
v
Substrate
AlGaN GaN
Passivati on
Nitride Via
AlGa N AlGa Ga N N Ga N
A u M o A l T i
Rc (mm)
Ti/Al/Mo/Au
88 8 Anneal Temp. C
Multi-layer structure (Ti/Al/Mo/Au) Smooth surface morphology up to 850 C Low Rc of 0.4 mm achieved (by 1/5) NCTU 4545 CSDLab
Gate Lithography
evaporation
substrat e
Mushroom Gate
Gate resistance is an important parasitic resistance source Rg = Zg/A, where Z g is the gate width and A the crosssectional area of the gate Increasing cross section area of the gate is essential in reducing gate resistance for sub micron gates
Large device can be connected Department Au air bridge by electro-plated of Materials Science and Engineering
Vma x
Maximize I Maximize nS, Maximize nS Maximize PSP, PP Maximize Al mole fraction without strain relaxation Maximize Minimize effective gate length Minimize Lg and gate length extension Maximize Minimize dislocations Smooth interface
- source: UCSB
- - - -- - - -
g G
Electrons in surface states and/or buffer traps deplete the channel causing gate length extension
D C
Id (5 mA)
Severe consequence:
Dispersion between small signal and large signal behaviors because of the large trap time constant
Vds (V)
- source: UCSB
Depletion layer S
ON-state
0 Current collapse
Drain Voltage
Pulsing gate with 200 ns pulse have been plotted to get the i-v curves under conditions similar to RF
A Si3N4 passivation layer improved power performance After passivation usually perform at 60 70 % of the expected power level
--source: Green, et al, IEEE Electron Device Lett., June 2000, p. 268
ID (mA/mm)
h : Thickness of sample J0 : Deformation in the center L : Length of sample In this work, yy = 1.4710-4 = 2.8210-4 = 3.9410-4
VD (V)
Tensile strain would degrade the transient drain current due to the additional surface states
Stress
Figure. Schematic conduction band diagram for an AlGaN/GaN HFET showing the various space charge components.
Polarization Charges
Additional states ++ + ++ + + + + + + + + + + + + + + + + + + + ++ + + + + sp pz SIP AlGaN - - - - - - - - -- - -- --- --- -- - -- - - - - - --- -GaN Substrate (SIP: Stress-Induced polarization)
Donor-like surface states are a likely source of 2DEG electrons in AlGaN/GaN HFETs.
NCTU CSDLab
Field-Plate Technology
Gat e Sourc e Ti/A l
2.
Field Plate
Function of fieldplate:
1.
AlGa N Ga
Relaxed Electric Field by Field Plate - Suppress Current Collapse - Enhance Breakdown NCTU 5858 CSDLab Voltage
+Vg
Without field plate (Vg=2V)
FP Gate
without FP with FP
SiO2 S 0V 0V 60V 30V 90V Al0.2Ga0.8N GaN 100V D S 0V 30V 0V 60V 90V 100V D
Multi-Step FP
Slanted FP
0V
100V
D S
0V
100V
0V
30V
60V
90V
0V
30V
60V
90V
--source: UCSB
Inverter (DCAC)
Fig.2 Boost Converter
GaN HEMT
Low on-resistance Fast switching High breakdown voltage High Temperature stability NCTU 6666 CSDLab
Switching Characteristics
ID,max= 367 mA/mm (Vgs=2V) Ron,spec = 3.6mcm2 44x lower than the Si-limit The Breakdown voltage = 940V Power efficiency = 94.2% ( 1MHz)
--source: Toshiba Corp., Japan
Advantages:
Simplified circuit reducing size & cost Reducing power consumption Providing fail-safe
AlGaN S
P-GaN cap D S
AlGaN
AlGaN
F-plasma treatment G
F-
GaN
i-GaN Substrate
Substrate
Si3N4 layer
D-mode
20 N/A 5
210 1.4
NCTU CSDLab
100 7575
Si3N4
16
High-k gate insulator improved gate leakage current towards high-turn-on voltage High Von characteristics could improve output current density without limiting by gate leakage phenomenon
Triple cap layer increases Ns of 2DEG by 80% High current density High-k gate insulator modulates Vth up to 3V -- Source: Fujistu Laboratory, Japan
Replace conventional Schottky gate with p-GaN hole injection gate Vth shifts to +0.45V Low on-resistance (3.4 mcm2) due to 2DEG
-- Source: Meijo University, Japan
+ Vth
0.01 0.00
Source: Marlodt, et al., J. Appl. Phys., vol.48 , 2009, Kambayashi, et al., IEEE Elec. Dev. Lett., vol. 28, No. 12, 2007
Vertical Device
G S HTS AlGaN n--GaN SiO2 p-GaN p-GaN n-GaN substrate D
Source: Toyota Central R&D Labs. (JJAP, Vol. 46, No. 21, 2007)
UCSB(2004), Toyota Motor(2007), ROHM Co.(2008) and Sumitomo Electric Industries(2010) have reported the vertical devices. Advantages: ease of packaging with heat release, reduction of wafer area, free of the surface traps (current collapse). The current collapse becomes remarkable under high voltage operation
Challenges: 672 V 7.6 m-cm2 +0.3 V App. Phys. Express 3 (2010) Electric Cost of GaN substrate Epitaxial quality (threading dislocation) Vertical devices have a great potential for power switching
applications; however, the development of the vertical devices is quite primitive, making it impossible to evaluate the vertical device performance precisely.
Summary
GaN electronic devices on Si substrate are promising choices for future high power switching applications. AlGaN/GaN heterojunction possesses high electron concentration due to its strong polarization effect and high breakdown due to the large bandgap. Multiple AlN and AlGaN buffer layer structure is useful to reduce the stress and to improve the crystal quality of GaN grown on Si substrate. Field plate technique helps to reduce current slump and to increase the breakdown voltage. High efficiency power electronic circuits using GaN HEMTs as switching devices have been demonstrated. Enhancement-mode HEMT is required for EV power device applications. New GaN device structures have been demonstrated for future E-mode power applications 8585
NCTU CSDLab