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Image from: F. Odeh. Polymer-Surfactant Interaction Department of Chemistry, Clarkson University. 16 Feb 2006.
Surfactants
Surfactants (Surface Active Agents) are amphipathic molecules (have a hydrophilic part and a hydrophobic part).
Image from: F. Odeh. Polymer-Surfactant Interaction Department of Chemistry, Clarkson University. 16 Feb 2006.
Surfactants aggregate in aqueous solutions at a concentration beyond a critical micelle concentration (cmc).
Image from: F. Odeh. Polymer-Surfactant Interaction Department of Chemistry, Clarkson University. 16 Feb 2006.
When polymers are introduced to aqueous surfactant solution, they induce micellization through different types of interactions.
Polymer-Surfactant interactions
Electrostatic Hydrophobic
Formation and Stabilization of Antimicrobial Delivery Systems Based on Electrostatic Complexes of Cationic-Nonionic Mixed Micelles and Anionic Polysaccharides
D. ASKER, J. WEISS, AND D. J. MCCLEMENTS
Soni, K. etal. Bactericidal activity of lauric arginate in milk and Queso Fresco cheese against Listeria monocytogenes cold growth, Journal of Dairy Sciences (2010).
Pectin Anionic biopolymer of D-galacturonides As a gelling, thickening and stabilizing agent in foods.
D. Asker, J. Weiss, D.J. McClements. "Formation and Stabilization of Antimicrobial Delivery Systems Based on Electrostatic Complexes of Cationic-Non-ionic Mixed Micelles and Anionic Polysaccharides." Journal of Agricultural and Food Chemistry (2010): A-I.
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D. Asker, J. Weiss, D.J. McClements. "Formation and Stabilization of Antimicrobial Delivery Systems Based on Electrostatic Complexes of Cationic-Non-ionic Mixed Micelles and Anionic Polysaccharides." Journal of Agricultural and Food Chemistry (2010): A-I.
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D. Asker, J. Weiss, D.J. McClements. "Formation and Stabilization of Antimicrobial Delivery Systems Based on Electrostatic Complexes of Cationic-Non-ionic Mixed Micelles and Anionic Polysaccharides." Journal of Agricultural and Food Chemistry (2010): A-I.
Addition of pectin to mixed micelle dispersions caused appreciable changes in solution turbidity.
4 C/ 2 weeks
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D. Asker, J. Weiss, D.J. McClements. "Formation and Stabilization of Antimicrobial Delivery Systems Based on Electrostatic Complexes of Cationic-Non-ionic Mixed Micelles and Anionic Polysaccharides." Journal of Agricultural and Food Chemistry (2010): A-I.
charge mapping shows that the charge became less positive with the addition of pectin.
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D. Asker, J. Weiss, D.J. McClements. "Formation and Stabilization of Antimicrobial Delivery Systems Based on Electrostatic Complexes of Cationic-Non-ionic Mixed Micelles and Anionic Polysaccharides." Journal of Agricultural and Food Chemistry (2010): A-I.
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Summary
Solution properties of LAE can be appreciably altered by forming molecular complex with non-ionic Tween 20 surfactant and anionic biopolymer pectin, with implications of extending the applications of LAE in a variety of foods and other products.
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References
D. Asker, J. Weiss, D.J. McClements. "Analysis of the Interactions of a Cationic Surfactant (Lauric Arginate) with an Anionic Biopolymer (Pectin): Isothermal Titration Calorimetry, Light Scattering, and Microelectrophoresis." American Chemical Society (2008): 116-122. D. Asker, J. Weiss, D.J. McClements. "Formation and Stabilization of Antimicrobial Delivery Systems Based on Electrostatic Complexes of Cationic-Non-ionic Mixed Micelles and Anionic Polysaccharides." Journal of Agricultural and Food Chemistry (2010): A-I. M. Bonnaud, J. Weiss, D.J. McClements. "Interaction of a Food-Grade Cationic Surfactant (Lauric Arginate) with Food-Grade Biopolymers (Pectin, Carrageenan, Xanthan, Alginate, Dextran, and Chitosan)." Journal of Agricultural and Food Chemistry (2010): 9770-9777. Soni, K. etal. Bactericidal activity of lauric arginate in milk and Queso Fresco cheese against Listeria monocytogenes cold growth. Journal of Dairy Sciences (2010). F. Odeh. Polymer-Surfactant Interaction Department of Chemistry, Clarkson University. 16 Feb 2006. Kurihara, K. Katsugari, Y. Matsoaka, I. Kashiwayanagi, M. Dorreich, K. Shoji, T. Receptor mechanisms of bittern substances. Physiological Behavior (1994). 1125-1132.
Acknowledgments
Dr. Ronaldo Fabicon Ateneo Chemistry Department Intalan Family Friends
Synthesis of LAE:
Mirenat-N (LAE) is exclusively synthesized by LAMIRSA under a patent.
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D. Asker, J. Weiss, D.J. McClements. "Formation and Stabilization of Antimicrobial Delivery Systems Based on Electrostatic Complexes of Cationic-Non-ionic Mixed Micelles and Anionic Polysaccharides." Journal of Agricultural and Food Chemistry (2010): A-I.
formation of compact spheriod aggregates at low pectin concentrations, but fiber-like structures at higher amounts.
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