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..
,
2012,
4 (1),
. 140147
, ..
, .
..
,
.. ,
..
140
621.791.3:669.248.8
2012 .
.. , .. , .. , .. ,
..
. ..
tesma@mts-nn.ru
07.11.2011
.
.
: , , .
( (), (),
-- ())
.
, (, ),
, [1].
,
,
- .
,
,
, .
.
(37)% =
= 1314. .
, ,
,
:
4 + 3 2 2 2O3.
, , .
, (G)
3 NiO + 2 B = 3 Ni + B2O3
535 /,
.
,
[2].
,
, ,
.
.
, ()
[3]. . 1,
, 3 -
141
1
-
, *
1 , .
,
,
2.5
0.34
1
0.05
3.0
0.65
18
0.16
5.0
0.79
33
0.6
* 0.25 .
. 1. , TlNO3 (, )
NaCNS (, r). , 1000; , 5000
. 2. , TlNO3 () ()
;
.
.
(, , ).
, , , .
,
cos ,
(
). cos > 0,
< 90 [4].
n
,
cos' = ncos.
( < 90) cos' , , ' . , ,
, ,
.
, ,
,
, , [5]. ,
( , , , ) ,
, (. 13).
142
.. , .. , .. , .. , ..
. 3. , TlNO3 () NaCNS ()
,
,
. (NaCNS)
.
.
1314.
,
(, , , ).
, .
,
,
.
, (
).
[6] ,
.
, ,
,
.
.
2.53.0 ,
.
, [7]:
1. :
2 [Au(CN)2]- + Ni = Ni2+ + 2 Au + 4 CN-.
2. :
2 [Au(CN)2]-+RNHNH2 = N2 + 2 Au + 4 CN- +
+ RH + 2 H+.
3. :
2 [Au(CN)2]- + N2H5++ 2 H2O =
= 2 Au + 4 CN- + 2 NH3OH+ + H+.
45% , .
, (. 4, 1),
(. 4, 3) . 1 2 .
0.2 /(2)
, 11 26
. 4.
NiB (1, 3) NiP (2, 4)
(1, 2) (3, 4)
143
. 5.
-: 1- ; 2 - ,
, ,
,
, 1.52.0
2.53.0 .
.
,
( ) 56%,
[8].
,
,
.
, .
, , . ,
[9].
,
[10] , ,
(34 /).
Ni(tart)22-.
,
1215 /,
(7585).
- , [11] (. 5).
,
,
, ,
, .
(311) , (70
80).
144
.. , .. , .. , .. , ..
/
. .
*
2
J = 2 A/ ,
/ 2527/5060 65120/2535 2527/2527 53/38
t = 1825/3555,
/(2)
0.035
0.040
0.040
0.038
. ,
/(2)
0.085
0.120
0.050
2 /2
/()
40100
5070
5070
2030
t = 95, 2
*
.
, , . ,
(23
). ,
..
.
0.3% 56 , .
, ,
[7].
(, ,
) -
.
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.
, ,
-
(620 /),
, , , -
.
.
, , :
;
, ;
;
.
, ,
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.
, .
,
[12, 13].
(2912)
(Na2B10H10). -
145
3
, ,
/(3 ) *
/
0.05
625
1314
(4) (NaB4)
0.05
28
511
(CH3)2NHBH3
-
0.5
3.59.0
(10102- -)
*
.
. 6.
, /2: 1 1.0; 2 2.0; 3 3.0; 4 4.0. t = 45
,
,
, ,
.
. 3 [14].
, .
, .
.
(. 6).
,
,
-
, . ,
,
, , .
,
[15].
,
, ,
,
.
, [8, 16].
[8].
0.30.6%.
146
.. , .. , .. , .. , ..
4
-
, %
3.58.0
(H4)
(NaBH4)
0.14.5
(CH3)2NHBH3
0.030.4
opa
0.92.4
2(B10H10 -)
2.44.9
, /,
= 270 /2
0.020.06
,
300,
15
7.09.0 11.014.0
1.7
0.30.6
1.7
4.05.8
6.79.4
0.1
+0.7
3.9
0.8
0.4
4.05.6
6.78.6
8.612.0
5.07.6
9.016.0
10.619.0
5
,
-
, %
( ),
3.58.0
86240
24
0.14.5
2.78.0
812
(B10H102-- )
0.030.4
36
1012
1% ,
,
, . ,
.
,
.
(R)
2040%.
, , . ,
2.53.0
. ,
0.5
[8, 17].
,
.
. 35.
1. .. // . . .
, , , 2001. . 95.
2. .., .., .. .
// . . 7. . 1980.
5 (102). . 3233.
3. .., .., .., ..
// . . . , , 1988.
. 5659.
4. .., .., ..
. .: , 1975.
408 .
5. .., .., .. //
. . 1981. . 24.
9. . 11281130.
6. .., .., .. // . . 7. .
1987. . 1 (140). . 34.
147
//
. 1996. . 4. 4. . 2227.
13. .., .., ..
//
. 2000. . 4. 4. . 2227.
14. .. ,
// . . . 2008. . 5.
. 554558.
15. ..
//
. . . 2008. . 4. . 554558.
16. .., .., ..
// . 1991. . 1011.
. 2830.
17. .., .., .., ..
// . . 7. . 1987. 1 (140). . 3132.
V.V. Rogozhin, M.M. Spasskaya, E.Yu. Ananeva, E.I. Yarovaya, A.M. Abramov
We consider main boron-containing additives and conditions of their application for depositing functional nickel-boron coatings for various purposes. Principal functional properties of coatings are determined and some recommendations for their practical use are given.
Keywords: nickelboron coatings, boron-containing additives, functional properties.