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621.791.3:669.248.8



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tesma@mts-nn.ru
07.11.2011

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4 + 3 2 2 2O3.
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3 NiO + 2 B = 3 Ni + B2O3
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1. :
2 [Au(CN)2]- + Ni = Ni2+ + 2 Au + 4 CN-.
2. :
2 [Au(CN)2]-+RNHNH2 = N2 + 2 Au + 4 CN- +
+ RH + 2 H+.
3. :
2 [Au(CN)2]- + N2H5++ 2 H2O =
= 2 Au + 4 CN- + 2 NH3OH+ + H+.

45% , .

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0.2 /(2)
, 11 26

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NiB (1, 3) NiP (2, 4)
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143

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80).

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2.44.9

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= 270 /2

0.020.06

,
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15
7.09.0 11.014.0

1.7
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1.7

4.05.8

6.79.4

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0.8
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8.612.0

5.07.6
9.016.0
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5


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3.58.0
86240
24

0.14.5

2.78.0

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(B10H102-- )

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36

1012

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(R)
2040%.
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2.53.0
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0.5
[8, 17].

,
.

. 35.

1. .. // . . .
, , , 2001. . 95.
2. .., .., .. .
// . . 7. . 1980.
5 (102). . 3233.
3. .., .., .., ..
// . . . , , 1988.
. 5659.
4. .., .., ..
. .: , 1975.
408 .
5. .., .., .. //
. . 1981. . 24.
9. . 11281130.
6. .., .., .. // . . 7. .
1987. . 1 (140). . 34.

7. .., .., .., .. //


. .
. , 2003. . 39. . 1. . 7071.
8. .. NiB
// . 2007. 3. . 2226.
9. .., .., ..


// . .
1983. . 26. 5. . 638639.
10. .., .., .. .

// . 1985. 9. . 976978.
11. .., ..

- // .
. . 2006. . 79. . 9. . 15661567.
12. .., .., ..,
.. -

147

//
. 1996. . 4. 4. . 2227.
13. .., .., ..

//
. 2000. . 4. 4. . 2227.
14. .. ,
// . . . 2008. . 5.
. 554558.
15. ..
//
. . . 2008. . 4. . 554558.
16. .., .., ..
// . 1991. . 1011.
. 2830.
17. .., .., .., ..
// . . 7. . 1987. 1 (140). . 3132.

THE USE OF BORON-CONTAINING ADDITIVES TO PRODUCE NICKEL-BORON FUNCTIONAL


COATINGS FOR VARIOUS PURPOSES

V.V. Rogozhin, M.M. Spasskaya, E.Yu. Ananeva, E.I. Yarovaya, A.M. Abramov
We consider main boron-containing additives and conditions of their application for depositing functional nickel-boron coatings for various purposes. Principal functional properties of coatings are determined and some recommendations for their practical use are given.
Keywords: nickelboron coatings, boron-containing additives, functional properties.