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II|

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|HIIA, KaHAr4AarxI4MLItIecKLIxHayK (OC);

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(1)

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(2)

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(3)

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(4)

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( 5)

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(5)

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BaHO Ha OnpeAeneHI4LI CKOpOCTI{naAeHI4s,UtapIlKA B }KI4AKOCTI{.

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Pnc. 9.1 . Ilpn6op Ane onpegeneHlte cogepxaHue cnupra grtrnoBoro

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(1)

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(2)

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(3)

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2. llpu HaJrvrrr4vr pacrBope BbrcoKoMoneKynqpHoro B BerrlecrBa3a ero MonrpHyro Maccy 6epercx cpeAHrr MoneKynrp Hafl. MaccaSpaxqulr. 3. fngporap6oHaru npll pacirere ocMoJrrpHocrrr yrrr4ThrBarorcr coJruoJHoocKaK Hosuofi Kr{cJrorbr.

orrpEAErEHI4E OCMOLfl pHOCTr4BOAHbTXPACTBOPOB (?KCIIEPI,IMEHTAJIbHA_fl OCMOIfl pHOCTb) ocMorrpHocrr4 Moryr 6urr ucnonb3oBaHbr rpr4 lnx uparrxqecKofo orrpeAeneHuq -fprrt. N{eroAaKpr4o : cKorrr{uecxufi rretr6paHuar u napoBar o cMoMe , 1 ocuonr Ha KLInolpaMM BoAbrnoHuxaer roqKy 3aMep3aHrrs 1,86 oC u noHr.rua xaer AaBneHue napa Ha 0,3 uu pr. cr. npu TeMrreparype "C. tr4:lrepeHr,re 25 3Trrxr43lreneurail nex{I{T B ocHoBe KprrocKonurrecKoro MeroAa u MeroAa naponofi ocMoMeTprrfi. 1. KpuocxonnrrecKlrfi ueroA MeroA ocHoBaHHa rloHl4xelr^vrpr rorrKr.r 3aMep3aHurpacrBopoB no cpaBHeHr.rrc c qncroro pacrBoprrrena.lauHlrfi naero4HalreJrcaMoe rxr4poKoe roqxofr 3aMep3aHlrt npaKTuqe cKoenpz MeHeHr{e Aocraror{Ho yHuBepc KaK irJrbHbrfi roqsufi . u 1. OnpedeneHue ocilonnpHocmu c ucnoilb3onaHueJrt mepMortempa Eexntana. Onpe4eneHuereMrleparypbr3aMep3aHnr rrpoBoArr Ha ycraHoBKe,ra:o6paxesuofi Ha pnc. 13.1. Vcranoercacocrour r43cocyAa A 4nauerpou 30-35 MM rr atruuoit oKoJIo200 rvrlr,KyAa IroMellaercq llcnbrryeMrrfi pacreop (u.rrnpacrBopr4rens); rlacrb cocyAa paclxr4peHa 3aKpbrBaercrnpo6rofi c AByMr orBepcrnrM}r BepxH-f,fl r{ rns rlorpyxeHu-srepMoMerpaF v MeilraJrKr{ cocya A ecrasreH e 6oree ttrrrpoB; Kyro eMKocru (f) TaK, qro He Kacaerct ee creHoK unkr A:na: TepMoMerpraKx{e He Kacarbcq creHoK unrr rua cocyAa A, yponenb oxnax{IaFoilIefi cMecr4B eMAon)KeH Kocrll f 4olxeH 6urr He HI{}Ke ypoBHs rrc[brryeMoro pacrBopa B cocyAe A. llpu npoBeAeHr{r4 3KC[epr{MeHTa pacrBop (utu pacrBopr{relr) AonxeH

Pnc. 13.1 . Ycrpoficreo npr,r6opa Sexuaxa A - cocyAAnr r.rcnhrryeMoro pacrBopa; E - replronrerp Eerurlana; B - ueuralra; f - euxocru c oxnaxq4aroqefi cuecrrc; reMneparypbroxnaxlaroqefi clrecu Arr H3MepeHrrr .{ - reprraouerp

rlpl{KpbrBarbocHoBHo[ pryruui pe3epByaprepMoMerpa. Tervrnepa;Wa oxJraxlarculefi cruecu.qoJIxHa 6utr na 3-5 oC nraxe reMneparypbr 3aMep3aHr.ur pacrBoprdreJrt
EIII

(lls6ulucrlrnnupoBassofi BoAbr: MtrHyc3 ao unnyc 5 .C); KoHTponb or unuyconofi TeMneparypbr ocyuecrBJrrercs MxHycoBbrMTepMoMerpoM! c qeHoil Aeteuus 0,5 "C. Cocras oxillaAl4TeJrtsofi cMecu: neA + :r^arpvflxJropnA Kprrcrannlr.{ecrafi. YcraHosxy repMoMerpa EeruanaHa KprroMerpHr{ecKue rrccreAoBatzre.frpor.r3BoArr nyreM no46opa KorprqecrBapryrlr B ocHoBHoM pe3epByape raK, .no6rr npu qvcroro pacrBoprrrenx (6ugucrr.rnJrr.rpoeaHnofi 3aMep3aHlru nogu) MeHr{cK pryrr{ B KanI,IJIJItpe HaxoAlrncq y nepxuefi qacrr4 rrrKairbr v3MepeHu flpu SToMBo3x. MO)KHa pefIrcTpaIIHA olI(Il1J.aeMOfO froHt4)KeHilrreMfleparypbr 3aMep3aHvfl Bo[\pacTBOpa. HOrO r{r4croropacrBopr4MeroA n rc flnx onpereneHu.areMneparypbr 3aMep3aHr4q a. TeJIt noJlb3yrorct cJreAyIoqlIMnprreMoM:Aaror xrnAKocrr{nepeoxna4urucx (oxnaxAaror 6es nepenaellnBaHl{t),n xor4a repMoMerp noKa3brBaer reMneparypy ua 0,2-0,3 oC HI4xe o)KlrAaeMofi roqxu 3aMep3aHlu, rrepeMerrrr,rBaHr{eM Bbr3brBaIOT BbInaAeHVe KpLrCTannoB pacTBopr4Tenr; [pr4 3ToM)KHAKOCTb HafpeBaerot TOiTKH 3aMep3aHr4-[. MaxcfiN.{anbHyro AO reMneparypy (cpeaHnfi pesynbrar rpex r{3MepeHrrfr, orlrugarorluxcr ne 6o;ree qeM Ha 0,01 oC), Koropyrc rroxa3brBaer TepMoMerpnocne Har{araBblnaAeHrr-s KpvcTauroB, perncrpHpyror KaKTeMneparypy 3aMep3aHufl pacrBopurenx (f1 ). B nrrcyureusufi cocyA A na;runaror AocraroqHoe KoJrr4qecrBo rrcrrbrryeMoro BOAHOTO paCTBOpa; OnpeAeneHl.re roqKkr 3aMep3aHr4r [poBoArT, KaK onHCaHO BbIIueInt qucroro pacrBopr4Tenr;cpeguuit pe3ynbrar rpex onbrroB perr{crprrpyror KaKreMfleparypy 3aMep3aHlrq HcnbrTyeMoro pacTBopaneKapcTBeHHofo Beqecrna (22). Ocvro.rrrpuocrbpacrBopa paccqnrbrBarorno $opuyne:

(rz- r)
Co.r. : K ql4croro pacrBoplzTent,rpalycrr I{e.rrtclla; fAe: 12 - renrneparypa 3aMep3aHIIt 71 - renneparypa 3aMep3aHr4r HcnbrryeMoro pacrBopa,rpagycrr IJe:nclrr (oC): ( - xpuorvrerpnr{ecKa-f, rocrosHHar pacrBop'Tenx (4:rx BoAbr:1,86). 2. OnpedeneHueocilonnpHocmu pacmsopor c ucnoJtbsoBsHue"u unmowamuqeqecKo?o o cMoMempa. flalan:';rfi Bap:aaHT cKozo Kpu o cKon a nperyc Marpr{Baer npu\re HeHueaBToMarvr{ecKl4x ocMoMerpoB, Hanp}rMep, MT-2, MT-4 (npouseo4r.{TeJrb HlIl] <BypenecrHuK)), Canxr-llerep6ypr). tr4cruryeusrfi pacrnop (o6rruHo 0,2 vr.rr) noNreiqaror B creK.rlsHHrrfi cocy,t. rlorpyxeHnrrfi B BaHHyc KoHTponlipyelrofiTeMrepar\,pofi. Tepvonapy wnu6parop rroMellaror rroAr{crrbrryeMbiM pacrBopoM,TeMilepar,vp] e sariuoii cHux{alor Io ilepeoxnax.qeHr{rpacrBopa. Bxlroqaror eu6parop r{ tsbi3brFar*ii K;r11crat"J1.r 3auuro Bolbr B i{crrbrT}/eM0M pacTB0pe;BbrAeJ]HBrueec_g Ten-rlo nc-l_ ]{!'{lviaeT Ta..-,r.ri" i.T,vlil'pacT,qopa ror{KH3aMep3aunq. :arbilxcilponasecii riirrK. ilo l]o 3afr,ieplaFi?i{ p?"creopafacel{p{TbiBaFor ocMonspHocrb.llpil6op rann6pyrcr c irovl0illblo CTa:{;apTH},IX paCTFOi}CB HaTpi.ifi.u|Ikth<aJu4fl, XnOpI{Aa, KOTOpr,IelepeKpbrBarOT 1 -?. 1 ). orip eAenff r:rLil"l in4aua3cli c cnf cnspi{o crn ira6n.

x 1000 (nOcu/xr),

(4)

-Ht
6. 3ax. 2768

Ta6nuua 13.1 Cran4aptnue cnpaBo,tHbtegHa.teHnf,noHuxeHns reJtneparypw saMep3aHnf, n eQQenuBHocru ocMoruqeexofr xox4exrpaunu BoAHbrx pacrBopoB xnopuAoB Harpue n Kannfl

AHarurnqecKafl KOHrIeHTparIrrflcoJrrr p, r/xr H2O

Ilonuxenne reMnepar)?br 9QQerrnBHafl (ocruorn.recrcar)KoHrIeHTpaqHfl 3aMep3aHrrt lT|ua, R ftirptlal/lo.rrr/rr H2O Pacmopn Harprlr xJropr.rAa

5,649 6,290 9,188 9,51 I1,13

0,3348 0,3720 0,5394 0,5580 0,6510 0,7440 0,930

PacrnoprrKaJrur xJropu,qa

180 200 290 300 350 400 500 180 200 290 300 360

r2,75
16,00 7,253 8,081 I1,83 12,25 14,78

0,3348 0,3720 0,5394 0,5580 0,6696 0,930

20,7r

s00

2. Merol MeM6pannofi ocMoMerpnr MeroA ocHoBaHHa rdcrroJrb3oBaHr.rr4 cBoficrB [oJrynpoHlrrlaeMrrx MeM6paHrz:,6vpaTeJrbHo Berrle rrpofiycKaTbMoJreKyJrbr cTB. cr.urofinpoqecca flBJrrercfl rrpoqecc ocMoca. PacrnopnreJrb tlpoHuKaer lnnxyuefi paBHoBecu1'Bo3HraKarcrqee groM Aonpv B r{cflbrryerraufipacrnop Ao ycrauoBJreHr,r-fl paBHoocMorprqecKoMy npu6nr{)KeHHo troJrnlrreJrbHoe rrdApocrarl{qecKoe,qaBnenue AaBnenrrror4Mo)Ker6rrrr paccqurano no $opnayne:

To"*.xPr

r.:PxgxLh,

(s)

rAe: Tocu. - ocMoTllqecKoe AaBJIeHLTe;

P r*r. p g Lh q

rr,rApocrarr.rqecKoe AaBneHlre ; nJroTHocTb xQrAKocTr,I; ycKopenue ceo6o.unoro naAeHr,rr; Bbrcora cro;r6axr4.rlKocrr4.

Ocuonxpuocrb Moxer 6rrru paccqr.rraHa $oprvryne: no

Co"r.:Toe*.lRx T,

(6)

rle: R - yHvBepcalrbnafl, fa3oBat nocrotHHaq (8,314,{xclrvronrK); Z - a6conrorHar reMrr epurypu KenrsraH. flpuueuaune. ,{annufi MeroA npuMenr4M ToJrbKo AJrr pacrBopoB BbrcoKoMoJreKyntpHbrx BerqecrB(104-106 r/rvronr).flprE auaru3e pacrBopoB,coAep)Karrlrix eneKTponvrbr r4 Apyrlre Hra3KoMoJreKyJrrpHbre BerrlecrBa, 6yget olpe.qeJrsrbcs roJrbKo
OCMOTI4qeCKOe AaBneHLIe, CO3.4aBaeMOeBbICOKOMOIeKyJUIpHbIMLIKOMIIOHeHTaMkI pa-

cTBOpa. MeroAuxa. I,Icnuryelrufi pacrBop c rroMorrlblorunpuqa (puc. 13.2) c ,qnunsofi urnofi BHocqr B c[eq]rzrJrbHoe .f,.refi Kanu6pon{y ilpoorBepcrne r.I3Mepr{Tenruofi xu. BoArr c noMorrlbroycrpoficrBa, HaxoArrrlerocs n npn6ope. flponogxr He MeHee rpex pe3ynbraroe Heo6xoAurrra rr3MepeHr.rit. npo6a lna nonyqenur Bocnpou3BoAraMbrx o6renaou He MeHee1.2 v'l.
,l

Pnc. 1 3.2. Ycrpoicrao r,rer,r6pa x Horo ocMoMerpa I - ucnuryeuufi pacrnop; 2 - uarucrpanr noAsoAa,/yAarenvl HcrrbrryeMoropacrBopa (neperarcvareJrb <nruepeHue>>); rrsroxoBycraHoBJreH noJroxeHue B 3 - r"reu6paua; 4 - pacrnopureJrb, noABoAuurril uo m4emuofi Marr.rcrpturu; 6roxr.r; 5 - repuocrarnpoBaHHLre 6 - xopnyc rvefixr.r; 7 - larttux AaBJIeHrur.

3. Merol napoBofi ocMoMerpnn pa3Hocru reMneparyp repMncropaMrd (qyBcrBrdMero.q ocHoBaHHa lr3MepeHr.ru TeJrbHbrM[ TeMnepaTypeco[poTHBJreHn K rMu) ncne4croile pa3Jr]rqurr Mex(Ay AaBrrepacTBopuTeJreM. HUeMlrapa HaApacrBopoM BeruecrBaH rrr,rcrbrM flpn naHecelf.ilvld.a o6a reprvrucropaKanJrupacrBopnreJu pa3Hocrb reMrreparyp paBHaHyJrro. Ecnu oAHy IiEI

rr3 KaleJrb 3aMeHqrorKanJrefiucnbrryeMoro pacrBopa, To Ha lroBepxHccrrr sToro repnapa panapoB pacTBop[TeJIt, TaKKaKAaBJreHUe nponcxoArrTKoHAeHCarUrtr Mr.rcTopa fl cTBopI4TeJI HaE 3Tofi noBepxHocrblo MeHbIIIe. llpr'r erou TeMnepaTypaKaIIJTIT AO llpoqecca KoHAeHAAu.UV TeX crleT SK3OTepMUqecKofo pacTBopa[oBbIIIIaeTCg.3a qficroro pacrBopl'ITent pacrBopa I,I AaBneHI,Ie flop, noKa AaBneHrlerrapa HaA KarrJrefi Passocrr B rqefiKe He CpaBHtIoTct.Ha6nroAaeMatpa3HHIIaTeM[epaT)ipI'r3MepreTcfl. pacrBopa. TeMreparyp [paKTuqecKr,rnpo[opqploHaJlbHaMoJItJIbHofiKOHIIHTpaIII4I{ trpl,t MeroAnrca. B npegeapllrenbHo TepMocTaTI'IpoBaHHyio TeM[epaType He HPIxe rapaMr.rpacrBopllrent (BoAbI)rvefiry Ha o6a repMucropa Ha25 oC r,rHacbrrrreHgyro BoAbI(puc. 13.3). Hoctr ro KaIIJIe

Pr,rc. 13.3. Ycrpoficrso napoBoro ocMoMerpa I - uslrepnrenrnrrff soH.r; 2 - runpNII; 3a 3 - orHa Anfl KoHTpoJUI cocrotHl{eu rqeftrlt He (np[cyTcTByrcT Bo BcexMoAejI'x napoBblxocr'louerpon)l I,ITepMI,IcTopoB - repulrctoprt; 4 5 - urvepnrelrnar aveftra; 6 - 6,'roxnArt repMocrarnpoBaul4g.

rpl4npu6opa $rKcrpylor. AaJIeerpoBoAtr KiuII{OpoBKy llonyueuHbre noKa3aHr.rlr KoHIreHTpaIIufi.llepe4 Kax,[bIM I'ISMpacrBopaM HecKoJIbKI4x 6opa uo sTztJroHHbrM
peHr.reM oAr4H H3 TepMr4CTOpOBnpoMbrBaloT tII4cTbIM paCTBOpI'ITeJIeM II HaIIOCflT KaIJIIO

pacrBopa I{ ql4croro pacrBoprrreJrtAotI}KHbI pacrBopa. O6reurr HauocnMbrxKaneJrb xaln6poeotlHblx pacrBopoB TaKxe AonlKHbI6rtrr o6beMbrKaneJrb 6rrrr onr4HaKoBr,r; paBHbI. Tel\{[epapa3HI'IqbI llo peeynsraraM Kanlr6poBKr{crporrrct rpa$I{K 3aBI4clIMocrI,I qltcroMy pacrBoHyueaar rolrKa - roKa3aHlatnpl46opa no Typ or ocMoJrsnbHocru. pacrBopoB. OcMoJitJlbHocrbHaxoA-f,T pi{TeJrro. l{a,lee rpoBoArr a*anva r4clbITyeMbIX rpaouKy. rro Kanr{dpoBoqHoMy

14.nOHOMETPI,Ifl (O<DC2-0048-07) 4
Ha MeroA HoHoMerprruocHoBaH orrpeAeJreHr.ru arouBHocru (xonqexrpaqnu) onpesneKTpoaon(ZC3). LlouocenerAenreMbrxuoHoB c noMorrlbrorroHoceJreKrr4Bubrx rprsHrrfi 3neKTpoAo6raAaer us6uparenrHofi qyBcrBnTeJrbuocrbroK onpeAeneHHblM B HortraM, coAepxaHr{r Koropbrx 3aBr4cr,rr noreHrlrzaJr. ocnoay onpeAeneurlfl ero or ,B I{3MepeHHI,I rroJroxeHrrpuHrlr{n rroreHrlrloMerpuqecroro aHaJrrr3a,3aKJltoqa}o:o;lutrte (uonopa3Hocrr{ noreHrlniuroe (enercpo.uBuxyqeit cu:r.st- 3AC) I43MepureJrbHoro Koroporo tiocroflHeH. cpaBneHr.rr, rroreHrruaJr ceJreKTHBHoro) snerrpo4av SJreKTpoAa nocncreubr or aKTuBHocrLI cnru gJrercrpoArrofi 3asucfiruocrb SJreKTpoABraxyuefi HepHcra: reHrlrluuronpeAenqrcqero oHa ouucbrBaercr ypaBHeHLIeM fl

RxT E:Eo+2,303 zxF lga, (l)

u BcIIoMorareJIbHbIM rAe: E - pasnocrb rroreHrlnanoBMexcAyr43Mepr.rreJrbubrM 3neKrpoAaun(3AC), MB; Eg - 3Haeenue3!C gnercpoAHofi cucreubr B Haqirnrnofi roqxe Anana3oHa (cran4apruoe 3Haqenue3!C), rurB r{3MepeHrrfi ; - rasoaar nocrorHHar; R T - a6coaroruar reMnepurypa; F - qlrcro (Dapagex; z - 3apfl.LonpeAen'IeMofo lroHa; B a - aKTr,rBHocrb rrJrr,r oQ$exrunHat KoHIIeHTpaIrutceo6oAHux I,IoHoB pacrBope, cBt3aHHatc KoHrleHTpauuefi coorHorueHlaeM:

a:fxC. r[e: C -lronxpHar KoHueHTpauurr; f - xoe$QuqlreHr aKrr,rBHocrn.

(2)

6r}rsor K eArr,{nx ouenr pa:6aueuHbrxpacrBoponxoeQ$uuueuraKTr4BHocne

HI{IIe H aKTLIBHOCTb IIOHOB paBHa KOHUeHTpaIIflI'L

HepnEcru roe$$Erlr,reHTaKTlrBuocrr{rroAAepxsBaercr nocrosHHbrM,ypaBHeHI4e BprA: cTa npr{HrrMaeT

E : E o + -7 x l g f x C ,
RxT roeSSnqraenr. rae k : reMneparypurtfr r

(3)

N Teran ar-vpHrrfi e$$ nrlrEenrk npu,rro6oii reMnepar,vpe roxeTobrTbpaccqnxo ep rau ro $oprr,tyne:

x + k: 0,05916 0,000199(t _ 25 .C)

K rrpr.rBeAeH s ra6r. 14.1.

(4)

Eg

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Sxaqenus k npu pasnnqHb,x reMneparypax

oC Tervrneparypa,

t5 20 25 30 35

0,0572 0,0582 0,0592 0,0601 0,0611

Bo (f) aKTr4BHocrr,r cvuraercr nocroqnHblM,ecnu rpu I,I3MepeHI,Iqx KoeSSr.rqHeHT u Bcex anaJrrd3rrpyeMbrx xanufpoBoqHbrx pacrBopax rloAAepxo{Baercs,oAHHaKoBa.n K BbrcoKofiuonHofi cLIJrbI pacrBopy Ao6aBntrcT pacrBop r.roHnar cvna.,Ilrg cosAaHr.rr sneKrponura ($onorufi pacrnop) c reu, .Iro6H pa3nuqHbleKoranar.rssepeHrHoro Ha rroHa He BJrrrrJrr{ I{oHHyro cuny pacrBopa I{ roeQQuJrr{qecrBa a:Flankrs*rpyeMoro eMofo lloHa ocraBilIcq fl ocrotHHblM. OnpeAeJrf TIHeHT aKTT.TBHOCTI,I

k Ecnu Eo + - x l g f : E o ' E: z ro rAe S - rpyrusHa oJleKrpoAnofi Qynrcquu,

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(5)

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flpu uacrux u3MepeHr4rx nepvoAlrqecKu rrpoBeprrcr cra6umsocrb orKJrr,rKa JrHH sefiHocru xarr6ponoqHofi xpr,rnofiB Araarra3oHe KoHrleHrpaqufi rdcnbrryeMoropacrBopa. B nporunuoM cJryru{ae npoBepKy [poBo.urr [epeA Kax,qbrMrr r{3MepeHr,rrrMr.r. 1. Merol rpaAylrpoBoqHoro rpaQnKa MeroA rpaAyrapoBoqHororpa$rara 3aKJrrotraercq nocrpoeHr.ur rpaQlrxa 3aBvctrB Mocrr.r3[C enexrpognofi cncreMbr or KoHrIeHTparIuu cranAaprHbrx pacrBopoB c r43eecrHoft KoHrleHTparluefi no cneAyroqeM HaxoxcgeHr]H u KoHrleHTparlr4rr [cnbrryeMoro pacrBopa no i43MepeHHoMy HeM 3HaqeHrlro B lpaayu3!C enerrpogHofi cracreMbr. ponovnufi (xanu6ponouHnfi) rpa$nr crponrcs Mr{KponpoqeccopoM u3Mepr.rrenbHoro npeo6pasoBareJrraBToMaralrecKil ocHoBeBBeAeHHbrx Hero sHaqenufi 3!C e.uexHa B rpogttofi clcreMbr rr coorBercrByrourrx uM 3HarreHufi upu xanu6poBKer{oHoMepa pX B craHAaprHBIxpacrBopax (aeyx u 6onee). flo46op KonrleHrpaqufi cran4aprHhrx pacrBopoB AonxeH coorBercrBoBarbAuarra3oHy KoHueHTparlufi lrcnuryeMbrx pacrBopon : rcpafi e 3HaqeHr4r Hpr KoHrIeHTpa ucnwryeMbrx pacrBopoBAonx(HbrHaxoAltrbct ryuit BHyrplI nnnefirrofi o6racru xaru6ponoqHoro rpaQnra. 3Ha.reHr,re e ucnuryeMoM pX pacrBope HaxoArlTcr aBToMarr,rrrecKrr[cnoJrb3oBaHr{eM c rpaAyr,rpoBorrHoro rpaQHra no rr3MepeHHoMy (E) 3HaireHrrro 3!C enexrpo.qnoficr4creMhr - puc. 14.1.

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2. Merol craHAaprnux Ao6anorc xa-urz6poeoqnofi xpunofi. MeroA rrprrMeHrrM nusefinrrx o6Jracr.f,x n do6aeorc 2.1. Memod uuoeorcpamHbtx KaKyKiBaHoB qacrHofi $aprvraxonefiB ucuuryeuuft pacrBop, nprrroroBneHHrrft, (no nofi crarre, BBoAflT HecKoJrbKo xpafinefi ruepe rpu) nopuufi o6reuorr,tV.r. pacrBopa c rr3BecrHofi xonrleurpauuefi olpeAeJrfleMofo voHa, co6.nrcAasycnoBl4e uonsofi crrJrbr pacrBope. Irlsrrepxrcr noreHul4iul Ao I{ ilocne xaxAofi AoB Her.r3MeHHofi I{ pa3Hocrr AE Me)K,{yrr3MepeHHbrM rroreHur{arloM rloreHuuzlrloM 6aeKu [r Bbrr{HcJurror pacrBopa. flo;ryueHHar BenllqnHacBf,3aHa KoHrleHTpagueit o[peAec HcrrbrryeMoro nreMoro }roHaypaBHeHr{eM:

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(10)

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cpeAcrBax,BbIAenpoBoAflTB neKapcrBeHHbIX OnpegeneHr{e coAep)KaHvrfl.6ema Hn[ 6norexno:ror[qecKrrMlr MeroHcroirHr4KoB nonyqeHHbrx .ueHHbrx rrpr4poAHbrx H3 AaM}{. KoMrIocpeAcrB,B Koropbrx6e;rxu He rBJltlorct ocHoBHbIMI{ lnx nexapcrBeHHbrx HeHraMr4 r{JrurrMetor seo6uqny}o repBuilHyro crpyKrypy (uanplruep, nporattuHu), Mero.ur{Kr{ olpeAeneHux 6enrca,yxaMoryr r.rcrrojTb3oBarbcfl.lroauSraqupoBaHHbre peB 3aHHbre r{acrHbrxQapuaxonefiHrrx crarb{x, B Koropblx Moryr 6urr I43MeHeHbI pacrBopa 6e,'rKa uluttu o6leurr HcrlblTyeMoro KoMeHAyeMue o6:racur KoHueHTpauuit C B 14 r{ peaKT}rBoB HeKoTopbre .upyfne ycnoBrr-f, cooTBeTcTBI4I4I'rHIr4BLIIyanbHbIMI{ neKapcrBeHHoro cpeAcrBa. ceoficrsaN{r.r 6erxa ucironb3ylor cneAyloilrue Mero.ubl: orrpeAenesNs lrx xo;ruuecrBeHHoro lpoBontr npl{ 1. CuercrpoQoronrerpuqecr[e MeroAr,r,B Koropbrxlr3r\{epeHlre (uemod A) vrttr rprr AByx AnlrHax uottu (uemod E). Cnexrpoolnofi AnuHe BoJrHbr Ha cBerorloMerorbr olpe.IleneHus 6etrca ocHoBaHbI I{3MepeHIrLI $oronaerpnr{ecKr4e ruoxreHuq pacrBopoB 6e:rxos npr{ 280 HM (nor:rouleHlre apoMar[r{eoKHX Nrz aMr4HoKrrc,ror) e o6racru 205-220 un (nomoilIeHrre ilerlrurHblx rpynn). 2. Ko,ropnMerpr{qecKHeMeroAbI or MaJro3aBvrcr4T npl{MeroA yHxBepcaneH, 1. Mero,u c 6fiyperoelrl,{ peaKr[soN,{. poAbr6e,rra, Ho r.rMeer HH3Kyro iIyBcrBHTeJIbHocrb. 2. Meroa ,floypn. llpeanryruecrBeHHor{cronb3yercfi l^nfl$epueurHblx nperapaHo ros. OrrHqaerc.f, errcoxofi qyBcrB[TeJrbHocrbro, o[peAeneH[ro MerlrarorMHorI{e oca}KAe* BeulecrBa.B noclelueM cnyirae rrplrMeHxrorN{eroAc npeABapI{TerIbHbIM HeJltrHeituax, or Hr4eM 6elxa (B).3anucuMocrb rrornorueHul^5etrca ero KoHueHTpaIIHI{ ee KoHueHTpaqufi MoxHo cqurarb rurueiiHofi.OnpeAe.neHue oAHaKo o6racrn Mtlrrbrx e rpaQzxy, nocrpoeHHoMy rlo pacrBopaM craHAaprnpoBorsr no xanr,r6poBot{HoMy [pI4 KaxAoM aHaJ]H3e. noro o6pa:ua 6elra, roropufi Bocnpolr3BoAsr uac3. Merol Epel0opaa Hcnonrsyercfl. r,nfl,6emos u rerrrrrAoBc MoneKyJrxpHofr r{yBcrBureJrbHocrb, crerleHb cBq3blHo BbrcoKyro cofi 6onee 3000 !a. Mero.q r.rMeer csoficre or Balavr Kpaclrrent B 3Har{HTelrHoficreneHr{ 3aBrrcr4T r4HrvrBr4AyanbHblx 6erxa. Mero.ty Jloypu, Ho orJlrrKrac,Torofi iurbrepHarr{BeH 4. Merol c 6uuraHxouuHosofi qaercr 6olee strcorofi cra6nnrnocrbro peafeHTa,r{eMpeaKTIas @oruHa, Ianteururei or 3aBr4cr4Mocrbro [pupoAbr 6ema u corlyrcrBylouux coeAunenufr. MeroAbIrpe6yror cneKTpoQoronaerpr{qecKrre rr Kolopurr,rerpuqecKue HeKoropbre HcrroJrb3oBa*r4s. cra*AaprHoro o6pasqa.B xaqecrse craHAapruoro o6pasua6eilxa Hcnonb3yror: craHAaprnufi o6paaeu [pucyrcrByrou]ero B rlpelapare 6enra, utw 6st'ruia BblcyilreHHble vrilvtcbrBoporor+rsrfi a.nr6yMlrHqeJIoBeKa, cbrBoporor{uufi a.rrt6yMr4H, nepeArrcnbrraHr.reM nocrorHHofi lraccsr (craH4aprnufi o6paseu u ycnoBl4t BblcyAo noA BaK}yMoM B DfvtBanvs.yKa3brBalorr{acrHofi Sapuaxonefiuofi crarbe: B DKcl{Karope B Haa $oc$opa(V) oKcr4AoM, BaKyyMHouruxaQy npu 60 "C unn B repMocrare

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BOA9, yo pacrBope Harp]lrfl 0,9 xnopuAa nnr46y0epHoMpacrBope Ao KoHrIeHTparILlr, .racrHoi $apuaxonefinofi crarbe. yxasaHuofi s 3. MeroAu orrpeAe,'renuq de,rrcarro coAepr(aHrrroa3ora - rl4Tpl{Merpuuecrufi (A - rr,rurpoMeroA, - o6parHoe rr4l. Meroa Kteruaan-f, B rpoaaHue). 2. Meroa c pearrunou Heccnepa (xonopnuerpuvecxufi). B rauecrBe craHAaprHoro o6pa3rla, co.4eplxarrleroa3or, r{cflonb3y]or aMMoHHrcy;rrSar. lpelaparoB, coAepxanlux Apyrrre BerrlecrBa, cocraB B filx ltuoroKoMnoHeHTubrx KoTopbIX BxoALIT a3oT,[epeA onpeAeneHueM 6elra ueo6xo4NruonpeABapr4TeJrbHo rIpoBo.4I{Tr npo6onoAroroBKy: ocDxAeHrrerpuxnopyrcycnofi unu Soc$opHoBonbxucnorofi. $parraonofi 4. Mero.q olpeAeJreHus 6e.nrca aMnnoKucJrorHoMy cocraBy. rro 1. CTEKTPOOOTOMETPILIECKIIE METOAbI Pesylrrarbl AocroBepHblB o6racrn .nuneisofi 3aBr{cuMocruoflrur{ecrolZ n;rorpacTBopaoT KOHTIeHTqa\VV HOCTr.r 6enXa. Memod l. Meroa ocHoBaHna cnoco6nocrr4 apoMaruqecKr4x aMrlHorucror (rupo3l4Ha, rpunroQaHa Ir B nteHrureficrerreHrr$euu.ualaHnua) B MoneKyJre 6elra norJrorrarb ynrrpaQuoJrerosrrfi cBer rrpr4AnrrHeBoJrHbr oKoJro280 nrra. IIpr Hn:rl{x KoHIIeHTpaIII4tx 6erox aAcop6vpyerc-f,Ha creHKax KroBerbr,rrro MOIKeT npHBOArrTb 3aHr{X{eHHbrM K pe3ynbTaTaM; 9TOM {ae B paCTBOp B Cn) npenapaTa HeIroHHbIfi yKa3aHHrrfie qacrHofi Sapvraxonefinofi crarbe, Ao6aerqlor 4erepreHT, rrnv rrpeABapr4renbHo KoHrleHTpr{pyror r{crrbrryeMufipacrnop, vs6erar.ueHarypaur{H 6erxa. loroeqr ucnbrryeMufi pacrnop c coAepxaHr.reM 6erxa 0,2-2 nrr/rvr.u. Memodurca.Bu4epx[Baror rIpH KoMHarnofireuneparype ucrrbrryeMrrfipacrnop, pacrBop craHAaprHoro o6pa:ua H pacrBop cpaBHeHurB reireHue trOunn. 6erxa B pacrBope Bbrqucrsror c !;rx srtcoKooquueHnrrx 6e;moBKoHrleHTparlurc v cnoJlb3oBaHueM yAenbHororroKa3aTeJrr norJrorrleHut. Paccesnue cseta. Toqnocrr orpeAeneHur coAep)Kanufl. 6erxa s VO-o6racru rracrr{u, cpaBHr4M6rx yMeHbrxaercs.,ecJr,v 6enxu B pacrBope cyqecrByror B Br.rAe no pa3Mepyc AnI4Hoft sorHH I{3MepteMorocBera (250-300 Hlr). PaccerHrde cBeTOBOTO nyqa npIrBoAlITK yBenr.rqeHrrro norJrorrleHr,rr vcrrbrryeMoro pacTBopa,no3TOMyAOTIOJIHI4TeIbHO BbIqIrCJrrrOT OnrvrrecKyro rrJroTHocrb pacTBopanpr,rAnrrHe BoJrHbI280 qenbronpoBoArr orrpenll, o6yclonneHHyropacce-f,HueM cBera.C srofi orlTlrqecKofi nnornocrl{ I4cnbrryeMoropacrBopa npr{ Anr.rHax AeJIeHHe eonu 320, 325,330,335,340 z 350 nnr. Crpoxr rpa$Hx 3aBrrcrrMocrrr norapv$rraa(1g) ouruqecxofr nJrorHocrn or lg coorBercrByroqefi.qJrHHbr BoJrHbr. 3xcrpanonr4pyror Kpr{ByIo Ao lg 280 HM Ir orpeAentlor lg onruuecxofi nnorHocrrr. Anruloraplr$M ororo 3HaqeHut coorBercrByer ortrl,I.Iecxofi nnorHocrll 3a cqer paccefl:r^vfl cBera, Koropoe BbIq[TaIor z3 orlTl4rlecKoft nrorsocrrr pacrBopa, [onyqeHnofi upu 280 HM,AJrt pacrrera r{crtrHHofo coAepxanus 6enra B rrcnbrryeMoMpacrBope.

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KonqeHrpaqurc 6erra B ucrbrryeMoM pacrBope (C) e rrar/*r.n Bbrrrucrrror no Sopnryne: C : C.r. x A-lA.r. , rAe: C.r.- ronqeHrparlur 6elra B pacrBope craHAaprHofo o6pasqa, n ur/ul; A N A.r. - 3HarleHr4r onrzirecxofi nnornocrr{ HcnbrryeMoropacrBopa kr pacrBopa craHAaprHoro o6pasqa npu AnrrHeBoJrHbr 280 nu coorBercrBeHHo, nocne BbIqL{TaHrIfl onr}rqecxofi n;rornocrrz 3a cqer pacceAnufl, cBera. Myruue pacrBopbl nns yMeHblrreHrrr cBeroBoro paccefl:aLrfl nepeA oflpereneHlreM qepe3 $ranrrpu r.r3 coAepx{aHnx6erxa $u,rrrpyror rroJrHBr.rnululeHQropr4Aa vnvy:rraqacrHofi Qaplraxonefinofi crarbe c pa3MepoM 3aHHbIe s rrop 0,2 uxvr, ue a4cop6r.rpyroqre 6eror, rnu ueurpu$yrupyror. Memod 5. Mero.q rl3MepeHrrq onri{qecKofi n,TorHocrr{pacrtsopoBrrpu AByx AnHHax BOJIH vcronb3yror KaKArTfl pacrBopoBqr,rcrbrx6elxon, TaKu !.nfl. cuecefi, s o6ravx crl4 KoHueurpauuii0,0015-0,0450nnrhm,ecnu lre yKa3aHo r{Har{e n.{acrHoii $aprraaxonefisoii crarbe. foroeqr cepnrc pa3BeAeHI,Ii.i MeHee (He rpex) o6pa:ua neKapcrBeHuoro cpeAcrBac paBHbIMH LIHTepBanaMr4 r4r43MepsroT OnTI4rIeCKyrO pacTBOpOB ITJIOTHOCTb rronlrqeHHbrx rIpI4AnI4Hax BoJIH 215 uu u 225 ulr. KouqeHrpaurro 6e;rra (Ct) u Kax{AoM pacrBope n nrr/un Bbrr{rrcrsrorno Qopuyre:

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rAe: Azts w A zzs- orruqecKafl rrJrorHocrbpa3BeAeHHoro pacrBopa npu215 su u 225 HM coorBercrBeHHo: P1- pasne4eHr{e; 0,144 - 3MnupnqecKl{BblrlucrenHrrfi xoo$@nqzeHTAnr 6erxoe rpu r.r3MepeHlrr4orlrllqecKofr nrornocru pacrBopoB rrplr AnrrHax sorH 215 nrrau 225 llw. Pacc.r[rsrBaror cpeAHee 3HaqeHr{e. 2. KOJIOPI{METPI4I{EC KI{E METOAbI l. Merol c 6uyperoBbrM peaKTr.rBoM MeroA ocHoBaHna o6pasoBaHnr B rlerorrHofi cpe4e oKparrreHHoro KoMrrneKca HoHoBAByxBaneHrsofr ue.qu c flerrrruHbrMu cBq3rMt4 MoneKynrr6e.nxa. Memodurca.K 1 nr,rI4crrbrryeMoro pacrBopa, [pr{roroBneHHofo pacrBopeHrzeM r.rcnblTyeMofo BeulecrBae 0,9 o/opacrnope Harpr4flx,Topr4Aa, coAep)KaHr.reM c 6e,rxa or 2 ao 8 rtr npH6anrqror 4 xnn6uyperoBoro peaKTlrBa, nepeMerrruBaror ocraB"rrsror r,r npl{ KoMHarsofireMlreparype Ha 30 nrun. llsuepmor olr[qecKyro rnorHocrb pacrBopa npLIAnrrHe BoiIHbI yr<a:aHsofi 540 uu (z"rrra s.{acrHofi Qaprraaxoueftsofi crarbe, B rrpegenax 540-650 uu). BrayperonyrcpeaKuxro HeJrb3fl npoBoArrrbB rrpucyrcrBar{ conefi aulronufl v34a o6pasonaHnfiMeAHo-aMMI4arIHbIX KoMrrneKcoB, raKxe c pacrBopaMrt,B Koropbrx a noxBJlf,erct MyrHocrb Lrrfiro6pa:yercr ocaAoK. fitn yc;lpaHetr4r BrrvrflHufl rrocropoHHI4xBeulecrB rlpoBoAqr ocaxAeHne 6ema r43pacrBopa ucnbrryeMoro o6pa:qa

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o6pasqa npu6arnxror 0,1 cneryroquM o6pa3oM:x 1 o6renry pacrBopa Hcnr,rryerr.roro yAansror HaAocaAoqnyro )KI{Ao6rena 5A % pacrBopa rpr,rxnopyrcycHofi Kr{cJrorbr, Kocrb Ir pacrBop*or ocaAox e He6orbruoMo6relre 0,5 M pacrBopa Halpnn rl4ApoKcr{Aa. lkuyueuHufi pacreop ucnonb3y}or rns npr4roroBireHr4qprcnbiryeMoro pacrBopa. c MeroA Moxer ucnoJrb3oBarbcr pa3rur{HbrxBaprraHTax: nocrpoeHuev xaru6B poao.ruofi xpunori nilu c ucnoJrb3oBaHneM craH4aprHoro o6pa:qa. Kanubponoqnufi rpaQux crporr xaxArifi pa3 npr4 nprrroroBneHvrrHoBbIXpeaKTr{BoB r{nu ucloJrb3oBaHr{rr,qpyforo cnerrpoQoroMerpa, Ho He pe)Ke 1 pasa s 3 ltec. 2. Merot "lloypll MeroA ocHoBaH 6liyperonofi peaxquH 6erxoB c coJItMrInaeau(Il)B nleJroqHoM rra pacrBope r4BoccraHoBJreHnu $ocQopnouoru6Aeno-nonr$paMoBoro pearrnna (uru (Don*rua)B rerepoMoru6AeHosrrfi xpacureJrbc MaKcIrMyMoN.{ peaKTr{Ba noHIoIIIeHi{J{ apoMarrrrrecKr{x aMr.rHoKr.IcJIor npr,rAnr.rue BorHbr 750 nrraB pe3yJrbrareoKr.rcireHrrr a 6enxa (ruannuna o6pasolarr.rpo3nHa, raKxe rpnnro$aHa u $eHurailanvna I,IB MeHbqepe32A-30 tvtuu urefi creueur4rrr4crertra).Parnurr.re oKpacKuAocrr{raer MaKcrrMyMa nprl KoMHarnofireuneparype, s AamnefirueM nAer yMeHbrueHLIe IrHTeHcuBHocrH. ee CreneHr oKparrrnBaHnfl3aBuer.rr npr{poAbr 6enra. OnpegereHuro MeIIIaIor HeKoor yDreBOAbr, Jlr.rfrr.rAbr, Her4OHHhre opTOpbIe coJII,I, ThOJIOBbIe COeAI{HeHLI', AeTepreHTbI, pacTBopr{TeJrr{, KoMrrJreKcoHbr Apyfr4e coeAr.rHelj'vfl,.,{nryrraenbrrreHr4Jr r,r faHr{qecKr.re pa3BeAeBrrwflHrls. BeilIecrB, Merrralorrlfix oflpeAeneHrilo, [poBOArT Ao[oJrHr.rTeJrbHoe pacrBopa HnHocax(AeHue Hr,re 6emos rpuxnopyKcycnofi nucnorofi. (6ez npedeapumerybHozo Memod A ocatrcdeuun 6eaxa). K I u;r ucrrbrryeMoro pacrBopa, coAepxaqero 0,020-0,100 ur 6ema; r 1 nm Kax(AoropacrBopa craHAapruoro o6pasqa 6erxa u r 1 MJrr4crroJrb3yeMoro rrpnroroBreHnq ucnblTyeMoro Anr pacrBopa pacrBopr.rreJr.rr, B rroMeilreHHbrM orAenrHsre npo6upxH, npu6aBJrrror rro r4 5 lrn pearrusa B. Co4epxlrl.roe npo6npoK nepeMerrrr4Balor ocraBJrrror Ha 10 unn npu KoMHarHofi revneparype. 3areu B Kaxryn npo6r.rpry npu6aerxror 0,5 nanQocpeaKTuBa, par6ae.rrenHoro nepeA ynorpe6ne$opnorvlo.uu64euono-no.rr$pal,roBofo r,r Hr{eMsoAofi n 2 pasa,6ucrpo u rrrlarenbHo rrepeMer[r,rBaror ocraBiurror Ha 30 rr.run npr,r KoMHatrofi renueparype. Ztraepxror onrr4qecKyrc nJrorHocrb r.rcnbrryeMoro H BoJIHlr750 su B KloBerax craHAaprHbrxpacrBopoB Ha cuerrpoQoroMerpe npr.rAJrr4He pacrBopa cpaBHennfl,. c roJrrrlrrHofi croq 10 nru orHocr{TeJrbHo flpnnre.rannr 1. IlpuzomorrHU peaKmusal. B ruepnyroxon6y BMecrnMocrbro 100 ul IIoMerrlaror 2 r uurpun xap6oHara,pacrBopnor s 0,1 M pacraope Harpr.nr rr{ApoKcr,rAaH rox{e BoA-f,T o6terraAo MerKr{3Tr{M pacrBopoM. Cpor roAHocrr{ pacrBopa - 1 rraec. 2. Ifpuzoma*reHue peaKmusa 5. ts uepnyro xo.n6yBMecrl4Mocrblo100 nanroMeTaprpara, rrlaror 0.5 r lrelu cyrr$ara r4pacrBoprlor B I oh pacmope: Ka.Jrr{r-Harpkrfl yrlrkr HJwr Harpur raprpara ) Harprrr ruarpara (4onxuo 6rrrr yKa3aHon uacrHofi Qaplraronefrsofi crarre). Cpor roAHocrr4pacrBopa - 2 vec. cMerrir.rBaror lrl peaxrura A 50 3. IfpueomosneHuepeawnuBa B. llepeg aHaJrr.r3oM n I ur peax'rura E. @

Memod E (c npedsapumeflbHdwr.ocauedeHueu 6awa). Mero.q peKoMeHAoBaH nnt neKapcrBeHHbrx Bnrrrrro[I]{eHa pei-vJrbrarbr cpe.rlcrB,coAeplr(aui4x KoMf,ror{eHTbr, aF{a(Seuoir, apoMarzr{ecKr.re .rr-rsa lplic-6y$ep, uHcreHH,rlrirr4orpe}rroJr, aMHHoKHcJrorbr, acxop6lruoBaflKncJrora,sTHJreHAr{aNrrrHTerpaauerar, Tpr,rroH X-100, rnwu-2}, coJrx, caxapatdnp.)" Memodurca. B uesrpu$yxnyro lpo6upry noMerlator I nar Hcnbrryel{oro pacrBopa. coAepxaruero 0.10-0,30 rvrr6erxa. npa6ae.n.aror lr.ri 20 oiopacrBopa rpfiI xnopyKcycHofi r<lrclorbr rr fiepeNreurHBaror. llpo5-v" ocraBn.fl]or Ha 18-20 v npir oC. OcaaoK orAenrlor qenrplrQyrlrpoBanr{eM reqeuue 30 uun TeMneparype 4-B B oC ri cKopocrri BpauIeHHr2000 o6lr'rnH,nporurbrnaror urr rrpr4reMneparype oKoJro I 5 IA % pacrBopa rpr4xxopyxcycHoii Kr.rcirorr,r, B ueHrpr.{@yrupyror Tex )Ke,vcnoBpr.rrx" pacrBopfitor ts x{r{nKocrb,ocraBuuitcx oca.uoK Oc'ropoxso c:ruBarorHarlocaAoriHyro 0,2 vn 0.i i\,f pacrBopa Hal.pnfrnrApoKcuAa i{ AoBon.fi.r o6rem pacrBopa BoAofi "qo pacrBopa,colepx(aruero0.050-0,150ur 6e.nxa. 1 u-rr" 0,5 HurilonyqeHHoro K npu6apu BoAbr,rrepeMerrrfiBaror, BJr.f,ror BHocrr 5 rrr peaxrrasaB u Aanee flocrvrraror" 0.5 KaKo[HcaHo Bbririe N{eroleA. e B xa.{ecrnepaorBopa cpaBueHr{fi Hcrronb3y}ornpo6y, coAep)Karuyro rtan 0,1 0"1 M pr0,5 n.n pa:6aureuuoro pacrBopaHarpprq pearruea B Borbr,5 rr,ra rlarpoKcuAa,A,9N,r,rr peaKrlrBa. n 2 paza Soc$opuovo,'rn6.uesoeo-eomQpaMoBoro IlpHrreuaruue" [Ipu.omo1reHue 20,o4tpacmsopa mpuxropyxcycuoti Kltcrombt pacrBoparr.rrpyror no,ryueHHoro QXy). 150 r TXY pacrBopflrorn 100 Mn BoAbr.I rr,r;r 1 N{ pacraopoM Harpxfl rrrApoKcrr.{a r{HAi{Ka'ropoM c Seno.n$ra-nenr v paccqurbrtsaror pacrBope (nplr6rusraxnclorbr B iroiryrreHHoM KoHqeHTpaurrro rpr4xxopyKcycHorl pacrBop rpxxropyrcycuofi ruc;roru). reJrbHo8A % 1 v;r I M pacrnopa Harpr{.fi frrrpoKc}ula coorBercrBver 0,1634 r rpr{xnopyxcycnofi
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Memod 3 npl{roToBneHpacmeop. l0 Mn pacrBopa ficnblryeMofo o6pasUa' tr4cnutmye.yait CTarbe' B HOfO,KaKyKa3aHo qacrHofi QaprraarolleilHofr pacrBopa xene3o(Ill)-uoua 3mattouuutu pacmsop. K 3 nn craHAaprHoro (l .vxe/un) rpu6aBnflror 7 ul BoAbI' IIo upu6an-n.ffoT 0'5 Mn xnopI4CTOpacTBopaM K ucnnrryeMoMylr cTaH.4apTHoMy nepcynlsara u 1,5 lrl 10 ruclorrr KoHUeHrpI{poBaHHOfi' rr.lraMMOHnq BOAOpOAHOfr oKpacKypaII nepeMeIIII',IBaroTCpaBHlIBaloT THOUUaHaTa, 15 %pacTBopa aMMOHr4r
cTBOpOB. Onpege.neHlle COJlefi x(eJle3a B 36JIbHOM OCTaTKS OpraHI'rqeCKI{x gOeAIIHeHIII{

HaBecpacm6op. 3onr,n'fi ocraroK' flonyqeHHufi nocne cxuraHut tr4inurmyeubtLi o6pa6aruBaroT KoHIIeHTpI{poBaHHofi' Kr{ r4cnblryeMoroo6pasUac cepHofi Kl'IcnoTofi KoHUeHTpI4Kt{cJIoTbI x.nOpIIcTOBoAopoAHofi 6age 2 rr'tn Ha lpr{ HarpeBaHl{}t BOAsHofi poBaHHofiu npn6a*nstor 2 MJrBoAbI' npoecnr{ HyxHo, su:rsrpyloT B ilpo6upKy, TufeJIbn Qunrrp T1{rJr.f,, co.uepxral,roe x BOAbI $N:Ibrpary' PacrnOpHefrTpanpoMbIBHbIe 3 MbrBarOT MI soAlt, npI4cOeAI4Hsq O6teu pacrBopa BoAofilo 10 W' r{ BOAHbTMAOBOATT nr{3y}oTaMMr4aKOM 83flB KI{CnoTy KOlUqecTBe' 3mattouuatitpacmeop. B rnrenr noMeilIaroTCepHylo V O6pa3IIZ, AaneeilOcTyIIarcTKaKc ucIIbITyeMbII{ ToM Ant clIOIfaHI{t I4cnbITyeMorO Uero npu6aBJI{FOT BOAOfi 9 Mn, IIOCJIe AO lpefiapaToM, HOO6lervlpacTBopaAoBoAflT (30, 10 utu 3 MKzhtx 6 3aqLlcuvocmu I n:r craHAaprHofo pacrBopa xe:re:o(Ill)-uoua om .\^emodaonpedeneHun). OIIpeAeneBbIIUeMSTOAOB rrpoBoAtTnIo6bIM I13OIIUCaHH6IX .{anee onpeAeneHfie CpeAcrB' B Hr4t )I(ene3a pacrBopax neKapcTBeHHbIX (I I I) -uoHa Cm and apmHblep acm sopbt ucawto CmaudapmHdil pacmeop 200 MKe/Mracetteso(Ill)-uoHa xene3a(III) aurloHtlx 0,8634 r xene3a(Ill) aMuonl4t cynboaravlrrrKoJll{qecrBo no paccr{I4raHuoe cyln$ara (X), cooreercrBylouee 100,0 Mf x(ene3o(Ill)-uoua, B xeJleso(Ill)-uoHa B MIIJITIIIfpaMMax X:100,0/Q, rAe Q - coAepx(aHlle soprr,ryne pacrBoptlor s 25 N\n xene3a(Ill) atrltonuq cynboara (cu. flpulteuaHre), I rparurvle repeHocflr Ko9,8 oh npu HafpeBaHI{I'I' pa3BeAeHHOfi pacTBopacepHofi KrrcJrorbr 500 *rn, AoBoAqro6reru pacrBopa ruqecrBeHHo B MepHyroKon6y BMecrrrMocrbro BOnofiAo MerKu I{ nepeMelrl4Baror'

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Cm au d apmu util p a cmeop 3 0 u rce trcenezo (I I I) - uo Ha /.+t't pacrBopa (200 urcz/un trceneso(Ill)-uona) repeA r{cronb3o15 nn craHAaprHoro BaHr{eM rroMerqarcT MepHyroxo;i6y BMecrr{Mocrbro100 rrrr, roBoAsr o6renaeoAoft B r{ AOMeTKLT nepeMelrrHBarcT. /,tt:t Cm aud apmu util p a cmeop 2 0 n rcz aceneso (I I I ) - uo Ha 10 rrn cranAaprHoro pacrBopa (200 urcz/"ttit crceneso(III)-uona)ilepeA rrcnonb3oBaHlreM noMexlaror B MepHyroxor6y BMecrrrMocrbro100 rran, AoBoArr o6tent nogofi H AOMeTKL{ nepeMelrrr4Ba}OT. en C ma ud apmuait p a cmeop I 0 a rcz t crc ezo (I I I ) - uo Ha /.tt 5 u:r crauAaprHoro pacrBopa (200 nrcz/un crcercso(Ill)-uoua) nepeA vcrronb3oBaHrreNr floMeilIaror B MepHyroxon6y BMecrr.rMocrbro u.n, AoBorqr o6relt eolofi Ao 100 MeTKrrr{ [epeMerrrr4BaroT. Cmau dapmu uit p a cmeop 3 nrcz/"tt:ruc e.a o (I I I) - uoHe es 15 nn craH.uaprHoropacrBopa (20 .ttrcz/un trce.teso(III)-uoua)nepe4 I4cnorlb3oBaHrreMrroMerrlaror MepHyroxon6y BMecrr4Mocrbro B 100 un, AoBorqr o6relr eo.qofiAo MeTKrr ilepeMelrr{BaFoT. rr /.tt:t trceneso (I I I) - uoHa Cma u dapmu wii p a cmeop I urcz 5 nr.rr crasAaprHoro pacrBopa (20 nrcz/"untrce-teso(III)-uoua)nepeA Llcnonb3oBaHHeMrroMenrarcT MepHyroxon6y BMecrrrMocrbro100lrn, AoBoArr o6tenasolofi Ao B MeTKr{ ilepeMerrrHBa}oT. r{ )KeJre3o(III)-Noua xenesa(Ill) aun ilpnuevaHue. OnpeAeneHflecoAep)KaHr4r MoHr4.f, cy:rr$are. Oxoro 2,5 r xe,re:a(Ill) alrnroHuxcynr$ara (rovHax Haeecra) pacrBopqrcTB BoAen nepnofi xo:r6e BMecruMocrblo 100 u.rr,roBoAtr o6lerr pa20 crBopa eo.{oii.4o MerKHH [epeMerxrrBaFor. lr:r flonyqeHHoropacrBopa fiepeHo10 crr B xon6y c rpr{reprofi npo6xofi, npu6aBJr.f,ror vrn xnopr4cronolopo4noit Mecre KrrcJrorbr 2 r rcatux itolula. Cnaecsss6a,Trrrsaror H ocraBnqror B TeMHoM u BoAbrH rurpyror 0,1 M pacrBopoM Harpr4fl. ua 30 Mr{H,3arena npu6au*or 50 rnr:r ruocynr$ ar a (unauKarop - xpaxnaa.n). 1 u;r 0,1 M pacrBopa Harpvfl ruocynrQara coorBercrByer 5,585 Mr xene:o(III)-roHa.

24.2. T fl)KEJIbIE

ME TAJIJ'IbI ( O @C 42 - 005 9- 0 7 )

rqxeJrbrx MeTaJIrvreToAbr coAepxaH:/lfl.npnMecefi onHcasHrre HrDKe orrpeAeneHr4r lon (cnuHerl,pryTb, Br{cMyr,cypbMa,oJIoBo,rcantruil,, cepe6po, MeAb,lro,ru64eH,naHa uaguit, pyreHuli, rrJraruHa,nar'tap.uit) n nexapcrBeHHbrxcpelcrBax ocHoBaHbI 3ireMeHToB oKpaueHHbre o6pa:onauuu oKpaueHHbrxcynr$u4oe. KponreyKa3aHHbrx oAIr MbrrrrbrK. cynr$lr4sr Aaror xer're3oB Koruqecrne 6oree 0,05 B raqecrBe r4croqHuxa cyns$IrAoB r{cnonb3yror pacrBop Harpprfl,cy:mQu4a (rr,rero4 irrra rrroaqeraMuAnufi peaKrrlB(ueroa 2). 1) peaKrlr{u }rHTeHcr.rBHocrb rrcrrbrryeMoropacrBopa llocle [poBeAeHn.f, oKpacKr4 B cpaBHr4Baror oKpacKoliera,ronsoro pacrBopa. OxpacKa,rrorBr4Butaflcfl IrcrlblTyec pacTBopa. paCTBOpe, AOnX{Ha npeBbrrrraTb oKpacKy3TaJToHHofo MOM He pacrBope Ha6;rrc4aecJrr B 3TaJroHHoM Onpe4eneHr.{e cquraercr AocroBepHbrM, pacrBopoM. no c ercs cla6oe KopuqHeBoe oKpaur4BaHr4e cpaBHeHr4ro KoHTponbHbIM

cpeAcrB Bo3B Onpe4eleHr.rerflKenbrx MeraJrrroB pacrBopax neKapcrBeHHbIX MoxHo 4nx cy6craHqrai, o6pasyrour4x npo3par{nrre, 6ecqBerHblepacrBopbl pI He KoMrroHoBMeraJrJroB cynr$u4-uoHoM BcJIeAcrBr{e c Ha BJrr{rrculr4x B3arlMoAeficrnue ilpoBoMT ]r3 cynbnlercoo6pa3yloilIr4x ceoficrs. B ocra,rrHbrx cnfrarx o[peAeneHple Qarnofi 3onbr vrril rocJre Apyroro cuoco6a Ml4Hepanltsawlr ucrlblTyeMoro crarbe. B cpeAcrBa,orrr4caHHofo qacrnofi $apnaaxonefiHofi neKapcrBeHHoro MeroA vlcnbrrarrvfl vI rrxeJrbrx MeraJIJIoB, Ilpege,rruo AorrycrrlMoe coAepxaHr.re n ycnoBrr.rr rroAroroBKr{Hcnbrryeuoro o6pasrla AonxHbr 6rt:rs yKa3aHbI .racrnofi Sap*raronefinofi crarre. B brx Onpe4e.n eHue rfl lr(eJr MeraJrJroB pacrBopax JrenapcrBeHHbIx cpeAcrB I'Icnutmyeuutilpacmeop. I0 Mn pacrBopa r{cnbrryeMoro o6pa:qa, rp}IroroBneHB Horo, KaKyKa3aHo qacrHofi $apuaxonefinoft crarbe. (5 craHAaprHoro pacrBopa cBl4Heu-uoHa arce/un) 3manouuait pacmeop. K 2 rran npn6au*or 8 un BoAbr. Koumponuuutilpacmeop. l0 Mn BoAbI. rrclbrryeMoro pacrBopa uclonb3yerct Ilpnue.raHue. Eclu npu npuroroBJreHr.rr4 granoHnrrfi, ronrponruufi v crau.qapruufi opranuuecxnfi pacrBopuTenb, To Tofo xe pacTBopl,ITent. pacTBopbr roToB-f,T ilcnonb3oBaHr{eM c cBr{Herl-uoHa pacrBopaM npu6an;r.rror no 1 Mn yKcycHofi xxcnoru Memod 1. K nonyqeHHbrM rr pa3BeAeHHofi Yo,2 xannu 2 o/o pacrBopa Hilpr4s cynr$rEga, nepeMeIIIHBaIor 30 irepe3 I lruH cpaBHlrBarcr oKpacKypacrBopoB. cna6aq oflanecqeHlll{t or BbIAeB cpanuunaeMbrxpacrBopax AorrycrrrMaJrrrrrrb nzeruefics cepbr. Memod 2. K nonyqeuHbrMpacrBopaM npu6an.rixrcrno 2 Mn allerarHoro 6ySeppeno npu6an.rraror I Mn rr{oaqeraMplAHoro Horo pacrnopa pH 3,5, nepeueurr{Baror, oKpacKypacrBopoB. rl aKTr.rBa, [epeMerrrr4Balor rlepe32 ttuu cpaBHuBaror B ocrarne Onpe4eneune rflll(ed'IblxMeTaJIJIoB 3oJIbHoM cpeAcrB opraHnqecKHx JreKapcrBeHHBIx pacmeop. 3olsurrfi ocraroK, noryqennufi rrocJle cxuraHuq I r Irlcnatmye.,vani (ecnu He yKa3aHo rrHaqee qacrHofi $apruanonefiHoficrarre) ucnblryeMoro o6pa:ua o6pa6arblBalorrrprrHarpeBaB npr4cyrcrBr4rl cepHofi rnclorbr KoHueHTpr4poBaHHofi, rruu Ha cerKe 2 tw nacsrrleHHoropacrBopa aMMoHr{rallerara, uefirpann:oBaHHoro pacrBopoM Harpvrfl, npulanr.qrcr 3 Mn BoAbIz Qranrrpyror e npo6l4pKy rr4ApoKcr4Aa, rrepe3 6es:oruHrrfi $nnrrp, npeABapnreJrbHo npovrrrrrfi I oh pacrcopoM yrcycHofi BoAbI,[poilyKr{cJrorbr, 3areMropavei soAofi. Tnrem u $unrrp [poMblBalor 5 rran a qepe3 ror x{e Qunrrp B Ty }Kenpo6npry. cKar ee Smanouuutil pacmeop. B rurenr noMerrlarcr cepHylo Kl4cnory KoHIIeHTpI{poBaHHyro B KoruqecrBe, B3rroM Anr cxuraHlrq [clbrryeMoro o6pa:qa, v Aaneeilocrynaror, KaKc ncnbrryeMsrrra o6pasqoM, Ho [poMbrBaHne rvffIrfl,u Qunrrpa npou3BoA-f,T Jrrlrrrb3 rr.rn soArr, rocJre qero K Sunrrpary npz6ae.nxror 2 vl craHlaprHoro pacrBopa cBrrHerl-uona (5 nrxz/un). Koumponuuutilpacmeop. fotonsr raK xe, KaKIi HcrlblTyeuufi pacruop, Ho 6es uc-

nbrryeMoro o6pasqa.

,{anee olpeAeneHr,reflpoBoA.flrrro6rrN4 rr3 orrucaHHbrxBbrrrreMeroAoB onpeAeneB cpeAcTB. Hr,rrTrxeJrbrx MeraJrnoB pacTBopaxJreKapcrBeHHbIX ocrarKa Haruvue Tqxerbrx MeraJrJroB 3oJrbHofo r,r3 llpHueuanne. OnpeleneHr.rrc corefi xeJre3aB rrpenaparaxHe Melrlaer. Cmaud apmHue p acm sopbt c6u Heq-uoHa pacmeop 100 urcz/an csuHeq-LtoHa Cmarudapmuutil u 500,0 rr,rn HHTparanoMerrlarcrB MepHyroror6y BMecrl,IMocrbro 0,0799 r cBr4HrIa pacrBoprrcr e 50 MJrBoAbrc 4o6aereHneM0,5 ur a:ornofi Kucnorbl KoHueHTprrpo14 nannofi, AoBoArr o6relr pacrBopa soAofi Ao MerKr4 [epeMeIxLIBaIor. pacmeop 5 arcz/un cruHeq-uoHa Cmaudapmuuil csuHer4-uoua)nove5,0 u,r craHAaprHoropacrBopa cBuHrIaHr,rrpara(lA0 ar<e/.un 100 nn, AoBoAsr o6relr pacrBopa soAofi Ao urarcTB MepHyroron6y BMecrr4Mocrbro MerKr4 nepeMerxr.rBarcr. ir Cpor xpaHeHrs - 1 cyr.

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pacrBopuTeJreM coorB rperapar paerBoprlor rrpr{JraraeMblM Cyxofi neKapcrBesHrrpi Ha BeTCTBT{r{ C yKa3aHrrflMv 3TI4KeTKe. cocraBnxet 7 cyt. xpIBorHbIMH flepuoa sa6nroAesns.3a qacrnofi Qapuaxouefinofi crarbe AaHbrr4Hbre yKa3aHvfl, cneAyror HM. To Eclr.r e HIa ecJII,I y o,{Horo H3 xplJlexapcreenHoe cpeAcrBo BbiAepxuBaer r,rcfibrraHvre, N He r4HToKcr.rKauur4 6yAer orMeqeHoyMeHbIleHrIe Borubrx He nporBrrcfl rrpn3HaKr4 cpeAcrBoHe BblAepxuMaccbrrerTa.Ecttu o6a xueornrrx norn6Hyr, neKapcrBeHHoe pIHToKcLIKalloru6Her, flpotBsrct [pI{3HaKL{ Eclu oAHo)Kr4BorHoe Baer r4crrbrraHue. \twnrrtit 6yaer o'rMeqeHo cH[IxeHHe Maccbl TeJIa, To IacnbITaHI{enoBTopgror. I{3 r4crrbrraHr4e, ecJIrIHIt oAHo)KI,IBorHoe BToJlerapcrneHHoe cpeAcrBo BbrAep)Kr4Baer I,I HHToKcr4KarJvrrHe 6yAer orpofi rpynnbr He rroril6ser ulu He nporBrrcr npr{3HaKH MaccblTeJIa neptroAsa6lroAesur. 3a MeqeHoyMeHbrrreHr,re

I -07) 26.rruporEHHocTh- (o@c42-006

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,{la roro, qro6u onpeAenl,rrb,noJrHocrbroJrH orMbrrbr uev6paHu or $ulrTpyeMoro npelapara, o6tagarcruero aHTuMt4Kpo6nrrrr,l AeicrsueM, rrocJre$nnrTpa\wr pacrBopa B nocneAHroro flopqu]o ilpoMbrBHofi xn4rocrtr BHocrr rro orAenbHocrr{ 1 M,rs:eecz B.subtilis ATCC 6633 u C.albicansATCC 885-653, rro coAepxauefi or 10 ao 100 xononueo6pasyroilIux eAr4Hnu (KOE) n i lrr. Pocr recr-TIITaMMoB $nnrrpax noATBeplxAaerorcyrcrBlre anrNtrrarpo6Ha uoro AeficrBns JreKapcrBeHHoro cpeAcrna. Hanporr.rB,orcyrcrBr{e pocra olpeMrIKpoopraHr43Ma cBr{AereJrbcrByer coxpaHeHlawaHTLllrrxpo6uoro o .qeneHHofo Aeitcrsus neKapcrBeHHofocpeAcrBa B orHorreHur{ AaHHoro BHAaMuKpoopraHH3MoB. :rolr cnyqae r4crronb3yror B crreuu$nvecxue prJrfi Hecrrequ$uuecrlre prnil y Be nlrqrrBaror o 6r eu np oMbrB o fi xuAxo cru. r,r HaKTr.rBarop br H XnArcocrn AJrfl npoMbrBannr Qn.nrrpoB Pacrnop Harpprflxnopr4Aau3oroHr.rqecKoro o crepr{nbHoro pH 7,0. 0,9 )I{udrcocmuNs L' 1 r uxcuoro nenroHa pacrBopr}or B 1000 rvrnBoAbr,SunrTpyror HJTI4 ueHTpusyrupyror Anr ocBerneHHr, pa3nrrBalorBo $Jraxouu H crepunr.r3yror. pH nocle creprrnrz3arrLrLr7,0 +.0,2. Htudxocmu J,/b I Nrr rszHa-80 ao6aBJr*or x 1000 Mn )rcprAKocru 1, pa32: J\b nr4Baror Qraroubr u creprrnr43yFor. noc:re creprrnr.r3a\Hvr 6,9 + 0,2. )(ulpH no KOCTb nprrMeHtrcT,ecJrr{B cocTaBerrpefiapaTa HMeeTc_s Maclo. X{udrcocma 3: 5 r uscsoro flenroHa, 3 r MrcHoro oKcrpaKrau 10 r rsr.rna-80 Np pacrBoptrcr e 1000 Mn BoAbr. Pasrr4saror no $laroHbr r{ crepr{nr.r3yror. nocne pH - 6,9 + 0,2. creprrnr43a\uvr 3.2.3. MeroA naz6olee BeposrHbrx lrncen (HBr{) Irlccneayerr.mrfi o6pa3erl foroBqr B BuAe pacrBopa, cycneH3r4r4 r..rJrr.r sMynbcwrr B pa3BeAeHr{-sx 10, 1: 100, I : 1000, r4cnonb3yrno.qxoArtrlnfipacrnoprlrenb. XzaI: Kyro nl{rarenbHy}o cpeAy pa3nr{Barote 12 crepnJrbHbrxnpo6upoK, rro 9 Mr e xaxAyro. [Ipo6upxu craBtr B rrrrarr{Bz 4 pxga no 3 npo6r4pKr{. B nepnufi pxg npo6zpoK BHocrr no 1 MJrr.rcnbrryeMoro o6pasua B pa3BeAeHr,ru 1 : 1 0 , n o n r o p o f i p f l A - r o 1 u r B p a 3 B e A e s n v l : 1 0 0 ,n r p e r n f i p f r L - n o I M n s pa3BeAeHlrn l:1000. B npo6upKrrqerBeproro prra BHoc{r no I vr paz6anurenn, roropufr 14cnonb3ylorAnr pacrBopeHvrr, cycneHAr.rpoBaHlas, gMynbrrrpoBavtrv uux o6pazqa. flocenu uury6zpyror B reqeHue ue 6olee 5 cyr. Vqer pe3yJrbraroB Orueqaror qr4cJro npo6npor B nepBoM, BTopoMr.rrperbeM pflrax, B Koropbrx Bu3yanbHo sa6ruoAarorpocr MHKpoopraHr43MoB. Cpe4a n rpo6upxax qerBeproro pxza (xonrporr paz6anurenx) 4onxHa ocraBarbcr crepransnofi. Ilo.nyueuuoe rrrrcJro Tpex3HaqHoe coorBercrnyer Hav6onee BepoqrHoMy KonnqecrBy x(r43Hecnoco6Hux Mr4KpoopraHu3Mon 1,0 | vrvt n 1,0 Mn neKapcrBeHHoro r cpeAcrBa, rrpr{BereHHoMy ra6ri. 32.5. n

Ta6nnUa 32.5
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flpn nrIaerrenuvt Enterobacteriaceae Moryr 6rnr BbrAeJreHbr 1axrepnit ceNreficrsa HanprrMep,5axrepuvr pola Apyrr{e noAo6urre HM Br{Abr Mr{KpoopraHH3MoB, Aeromonas pora Pseudomonas. v 4.1.I. BuAereuHe 6axrepufi
noBpexAeHHbrx Bo xl43Hecrroco6nocruMr4KpoopraHr43MoB, .{rx noccraHoBJreHu.fl BpeM.fl TexHoJrofuqecKoro npoqecca, uc[onb3yror npeABapuTenbHyrouuxy6aquro o6pasua e xraAxofi nurareJrbHoficpege. 10,0 r ranu 10,0 Mn r.rccneAyeMoro o6pasua nepeHocrr s 100 MJrnaKTo3Horo uuutry6upyror B reqeHrre, KaKrrpaBr{no, 6ynroua (cpe4aJ\b 11), nepeMerxnBaror AByx qacoB,Ho He 6onee ilflTvr.Ioc,re uHry6aquu nepeMerxr4Baror coAeplcuMoe$raxoua (rouoreHar A) u nepeuocsr 10 lu (xonuvecrBo, coorBercrByloqee 1 r u;rr I rvrn o6pa:ua) e 100 Mn cpe.qbl o6oraulesux (6ynroH Moccerx, cpeAal\b 3). noces uury6upyror B reqeHr.re 18-48 q. llpu nosBJreHrru pocra Aenaror nepeceB 6arrepuonornrecxofi neuefi Ha nnorHyro cpeAy (arap Moccerr, cpeAaJ\e4), Koropylo r{HKy6upyrornpu rofi }KereMneparype B rer{eHue18-24 \. flpn ucnuranr4lr rrnrpo6uoJroruirecKofi .{zcromr rpaHcrepMaJrbHbrx n;racrrrpefr 10 nracrupefi noueuaror B 500 nanrraKro3Hofo6yrroHa (cpeaa J\b 11), ocropoxHo BcrprxrrBaror, zr6erar BcneHr,rBaHufl cpeAbr, B Te\reHr4e MeHee 15 uun. 50 un He cMbrBanponycKaror irepe3 crepr{nbHbrfirraeu6pannrrfi$u:rrrp vrs HLrrpararlenn}oJro3br c.unaMerpoMnop 0,45 uru, xoropufi nepeHocrr e 100 Mn cpeAbro6oraqesns (6ynron Mocce;rx, cpeAaJ\&3) u mrydnpyror B rer{eHue 18-24 u. IIpu laarrulr'vftrpocra s xzArofi cpeAe rrepeceBaror ner:refi Ha rrnorHyrocpeAy (arap Moccena, cpeAaNe 4), Koropyrc raHry6upylor rrprr rofi xe reMrreparypeB reqeHue 18-24 q rns, BbrAeJreHr{t Mr{KpoopraH}r3MoB. enrepo6arr epuit u Apyrr4xrpaMorpr4rlareJrbHbrx IossreHrae Ha nJrorHofi cpege xoronnfi rpaMorprruareJrbHbrxrraJroqeKflBrrflercfl. Toro, irro uccneAyerr,rufi BblrxeyrroMtHycBlrAerenbcrBoM o6paseqKoHTaMr{HHpoBaH TbrMr4 6arrepzxnru. 4.1.2. KonzqecrBeHHoe onpeAeneHrre 3 .{rx noceea ucnonrcyror rprr npo6zpxr.rc 9 lrrt 6yrroHa Moccerq unu cpe4u Jtlb s raxAofi. louorenar A s rorra.recrBe I run (coorBercrByer 0,1 r o6pasqa) nnocxr n nepByro upo6zpry, rrrlarenbHo nepeMerrruBaror nepeHoc.sr 1 ur (coornercrryer rl 0,01 r o6paeqa) Bo Bropyro npo6upry, cHoBa nepeMerxnBarcrr4 rrepeHocqr 1 rar

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12. 3aK.2768

nJrorHbIXcpeAax Ml,IKpocKorrr4pyror. llpu o6napy)KeHur,r Ma3KaxrpaMorprrrlarenbB HbIX naJIorIeK orAenbHbre KoJroHr.rH orceBaror Ha cxourenHrrfi B npo6upxax coeBo-Ka3el*rosrrfiarap (cpe4y Nt 1) n nnxy6upyror B retreHrre18-24 q. l4cnonb3yror6uoxurrauqecKr{e recrbr. Za npo6rapoxc qucrofi ,{lx no4rnep)K.qeul4t xynrrypofi AenarornepeceBbr arap Culruosca (cpeaaNr 14) r{ coeBo-KageuHoerrfi Ha 6ynroH (cpega Jt 15), a raKxe rrpoBoArr recr Ha :r'aJwrrrue Seplrenra urrroxpoMoKr{epes 18-24 u HHry6aqr4rr cI4Aa3bI. pocr r{Jrr4 orcyrorMeqaror 6arrepnatrc:r^stia ero (cpe4a l\lb 14). Vrurusauuro rltrrpara ycraHaBnr.rBaror crBl4eHa arape Craulronca rro pH-cpe4rr B urenoqHyrocropoHy (n:lreHeHnrorlBera cpeAbr rr33eneHoro cMeIIreHI,Iro n cunufi). Haru'rue r.rHAona olpeAenqKlr no rrorBneHr{roKpacHofo Konbua Ha rroBepxHocrl{ coeBo-Ka3er.rHoBoro peaKrr{Ba 6yrroua (cpe4u llb 15) upu 4o6aeJreHprr.r Kosaqa. Eclu n o6pasqe o6napyxeHbl rpaMorpurlarenbHbre Hecnopoo6pasyroure raJror{KI,I, o6raAaroqr4e QeplrenroM uprroxpoMoKc[rAa3a yrprnLcr.rpyrcutrerIHTpar He , He rrro neKapcrBeHHoe Harpr4fl o6pasyroulile uHAoJr, N clrr{Taror, cpeAcrBoKoHTaMprHr4poBaHo E.coli. 4.2.1. KorxqecrBeHHoe onpeAeneHne E.coli KonnqecrBeHHoe olpeAeneHvre E.coli lpoBorrr raKrrMxe o6pa:oM, KaKKoJTr{qecrBeHHoe onpeAenegrre Apyrrrx aHrepo6axrepuii(pa:4en 4.1.2), renafl nepeceBr43 foMofeHara A e npo6upxN c 6ynronou Max-KoHKr{rrrrlrcpe4oil J\b3. B cnyqae paBHoMepHoro rIoMyrHeHI4.s cpeAbr npo6uprax Inr noArBepx(Aenr4flHaJrvtqpr-s las n E.coli r<ax4ofi npo6rlpxu Aenaror nepeceBneuefi Ha rrnorHylo cpeAy (arap Max-Konxn, cpeAa}ib 4). lloceebr unxy6upyror B rer{eHHe18-48 u (arap Max-Konxu) utu 18-24 't (cpe4aJt 4). llose,TeHlleHa cpenax xapaKTepHbrx E.coli ronouzfi rpaMorpxrlareJrbHbrx rraAnr roqeK (pasae,r4.2) nnnterc{ nonox{rrreJrbHbrM TecroM, orcyrcrBue pocra 3Tr4xKo- orpl{IIareJIbHbIM ;roHufi TecroM.Haz6onee BepoflTHoe KonuqecrBoKJreroK E.coli s I r ulu s 1 r.uro6pasuaorpelenqro't no ra6rr.32.6. 4.3. BsrqnrreHne6axrepufi poAa Salmonella 10,0 r Nrz 10,0 Mn HccJleAyeMoro o6paaqanepeHoc{Te 100 Mn coeBo-Ka3er4Honoro 6ynroHa I4JIIT cpeAbrJ\b 8, repeMeruprBaror lrury6upyror B reqeHpre18-24 s. n flpu naruqrru pocra I nr-rr nocre nepeMerxnBanvrs. lepeHocrr n 10 lrn rerparr{orraruoro 6yltroHavrwt cpe.itbr 12 u nury6npyror B Ter{eHne J\e 16-24 v. lenaror repeceB nernefi MlrHI4MyM Ha2 us 4-x nrorsbrx ArrarHocrr4qecKux cpe4 (fiesoKcr{xonar-rlr,rrpar arap, Kcunosa-rr43uH-Ae3oKcr4xoJrar Arap c lputuruaHToBbrM arap, :eneHrrlr, $e- cpeAaJ\&5) u HoJroBbrM KpacHbrM, naxrosofi n caxapo3ofi,Buclryr-cynr$nr arap c uuxy6upyror B reqeHue 24-48 q. Ha ,{eeoxcuxonar-urrrpar arape 6arrepun H3 poAa Salmonella o6pasyror xopotuo pa3Br{rbre 6ecqeernrre KonoHr.ru. Kczno3a-rrr43vr+Ha pa3BrrTbre arape - XOpOIIIO KpacHbre KonoHHr{ qepHbrMuueHTpaMrr c Ae3OKCI{XOnaT unu 6ez slrx. Ha Arape c iputumaHToBbrM 3eJreHbrM, c $euolonuru KpacHbrM, JraKrosofi u caxapo3ofi- ltenrue, 6recrqrune, 6ecqnerHbre, po3oBbre lrri{ oliuoso-6emre qacro oKppxeHHbre KoJIoHHH, po3oBoit unu xpacuofi goHofi. Ha Bucuyr-cynr$ur qepHbre arape (cpe4a l\b 5) 6axrepr.rur{3 poAa Salmonella o6pasyro! KaKnpaBr.rno, KoJToHLIHxapaKTepHbrM c Merarrr4rrecKr,rM 6recrou, npr{ SToMyiracroK cpeAbrnoA xononuei npoKpamuBaercr n uepurrfi rlBer.

EI

KoloHull, noAo3ppITeJIbHbIe rrpuHaAne)KHocrb poAy Salmonella, Mr.rKpocKoHa K rrlpylor. flpu o6nap6eHvrr B Ma3KaxrpaMorpuuareJrbHbrx franorreK2-3 xapaxrepHbIe KoJIoHua(rax4yro orAeJIbHo)lepeceBaror Ha rpexcaxapHrrfi arap c con-sMu xeJre3a(cpe4a J\b 13), HaHoct 6o;ruroe KoJruqecrBo Kynbryprr nernefi cHaqaJra Ha qacrb arapa, a noroM yKonoM n crol6ux, He Kacascb cKolrreHHyrc npo6npxu. AHa rlepes 24 u nut<y6a\uu orMellaror [r3MeHeHr4e rlBera n3 KpacHoro B xeJrrbrfi n cron6urcenurarelrnofi cperbl llouepueur4e cpeAbrcBr.rAerenbcrByer o6paso Ba1uv ceo6 poBoAopo4a- TvrrrvrrrHoM npr{3HaKe B}rAoBpoAa Salmonella. flapannenbHo craBrr Tecr Ha Hanr4qvIe ((qllToxpoMoKcr{Aa3a)), r4crroJrb3yrqucryro Kynbrypy co Qepuenra cKorlreHHoro coeBo-Ka3ellHoBoro arapa prnv cpeAbrJ\rsl. Ec;ru rpe6yercx AononHvTeJIbHoe noITBeplK.qeHLIe, MoxHo Hcllonb3oBarb rloAxoAflu\pre 6aoxz1an.Iec6lre cev ponofHr{ecKHe TeCTbI. Eclu s o6pasqe o6uapyxeHbl rpaMorpr{rlarenbHbreHecnopoo6pasyrcrlpre naJrotIKI4, e o6lraAaroque $epruenroM ((rlrrroxpoMoKcr.rAa3a)), epuenrupyrcque H He $ pI caxapo3y I'I naKTO3y BblAen-f,roulr4e cepoBoAopo.4, crrrrraroT,qro neKapcrBeHHoe cpeAcrBoKoHTaMr.rHHpoBaHo 6axrepzxu v pora Salmonella. 4.4. Br;tsn'JreHne Pseudomonas aeru ginosa tr{ccnegyeuufi o6pa:eq, pa3Beresnufi crepr.rnbHbrrra 6yQepHbrM pacrBoporvr I:10, nepeHoctr B KorLtqecrse l0 run (coornercrByer l r ulu I un) s 100 Mn )Kr4AKofi rmrare;Ibnofr cpeAbl(coeno-xaseznonrifi 6ynroH, cpela J\b8), [epeMeruBaror u ,rHKy6npyror B retleHple 24-48 q. llpu Harrvruavr pocra rrepeceBaror reuefi Ha ceneKTrrBHylo nurarenbHyro cpeAy .4nr BbrAeneHnr crrHeruofinofi narorrKr.t(uerpzuu4nufr arap, rlerrrnnupu!.ulr.uirxnoprrA GnD arap - cpera Ns 16). Brrpocuze KonoHrIIl rpaMorpllqareJlbHhrx naror{eK rrepeceBarorHa cpeAy Ns 9 lr.{ BbrqBreH7t cl'IHe-3eneHoro rvrMeHTa nuoqvraHvrH.llocesHuHxy6lrpylor B TeqeHue24-48 q. lnx no4rnepxAeHllt rlrAoeofi npHHaAJre]KHocrn ucnonb3yror 6uoxuun.recxufi Tecr Ha Haruque $eprr,reura (IIHToxpoMoKcr4Aa3a))crroco6uocrr sHnereHHofi z Kynbrypbl pacrl{ Ha coeBo-Ka3eLrHoBovr 6ylroue vril cpeAe Jllb8 npu reMreparype (42 + 1) "C B rer{eHue18-24'r. npr ucnrtraHulr rranxpo6uorort4qecxofi qncrorrr rpaHcAepMaJrbHhrx nracrupefi l0 nnacrupefi norraerqaror 500 nrn Soc$arnoro 6ySepnoro pacrBopa, ocropo)KHo B BcrpsxuBalor B TerreHue MeHee 15 uun. 50 ul cMbrBanpo[ycKaror r{epe3creHe punrHrtfr ueu6paHurrfi $unrrp H3 Hlrrpara rlennrcno3br Ar{aMerpoM c nop 0,45 uxu, xoroprrfi ilepeHoctr s 100 Mn coeBo-Ka3er.rHoBoro 6ylrouavrlr cpeAbrl\b 8 H rrHr(y6upyror B TeqeHlre24-48.I. flocre raHxy6aqut, rrpvt Harrvrquu pocra, nepeceBaror - Ilerpr,rMrr1u:';rfinnu IIIIX-araprr. neuefi Ha ceJreKrI4BHbIe cpeAbl laltHefigryrc u4enruQzKaunrc [poBoArr, KaKyKa3aHoBbrrrre. Ecnu s o6pasqe o6HapyxeHbl rpaMorpr{rlarenbHbreHecropoo6pasyrcrque raJrotrKr{, o6pasyrorq}Ie cl{He-3enenufinLrrMeHT nuour{aH}rH, o6na4arorqueQepueHToM (<IIpIToxpoMoKcr{Aa3a) r{ pacryrurdenpu reMneparype (42 + l) .C, cqr4Taro!rrro ne_ p.aeruginosa. KapcrBeuHoe cpeAcrBoKoHTaMr.rHHpoBaHo 4.5. BsrqnJreHreStaphylococcus aureus llcclegyeuufi o6paeeq,ptrBeAeHHrrfi creprrnbHbru6y$epuhrM pacrBoponal:10. rlepeHoctr B KoJrrrqecrse rral (coorrercrByer I r unu I un) e 100 MJr)Kr4AKofi l0 nurarenrnofi cpeAbl (coeno-r<aseranoeHfi 6yrron ruu cpeAallb 8), [epeMerl7Ba]or H

pocra [epeceBarcr neuefi Ha ceJIeKlrHKy6r4pyror TeqeHue24-48.r. llpu learwuLrv B TrrBHbre rrr4rareJrbHbre cpeAbr:arap @orenx-.{xoHcoHa, Eepaa-flapKeparrJrr{cpeAy rpaMrono24-48.r. 9epuue 6recrsulue KoJroHrrH Ns 10 u uurcy1upyror B reqeHr.re )KeJrrbrMr{ )Kr4TeJrbHbrx KoKKoB, oKpy)KeHHbre 3oHaM[, Ha cpeAeOore.nx-.{xoHcoHa, qepHbreKoJroHrrr{ cpeAe Eepaa-llapKepa r{Jrra KoJroHr.ru, oKpyHa 3onorrrcro-)KeJrrbre xreHHbre Ha o S.aureus. )KeJrrbrMH 3oHaMr4, cpeAeJ\b 10 cBraAerenbcrByror laarwurrvr -uvlcrofi xynrpeaKrluro rrJrur3MoKoaryrsrlr4r c lnx u4enna$uraqnn r4crroJrb3yror Typofi cra$uroroKKa, orcefisuofi Ha coeBo-Ka3er.rHoBbrfi nnz cpe4y Nr 1. arap .rucrorrr rpaHcAepMiurbHblxnnacrrrpefi, IIpr rcnrrranvru unrpo6uoJrorrrqecKofi l0 nracrrrpefi noueuaror B 500 rran Soc$arHoro 6y$epHoro pacrBopa, ocropo)KHo Bcrprxr.rBaror B TeqeHr.re MeHee15 rr,rus. He 50 rrancMbrBarrporycKaror qepe3 creprlnbHbrfi rvrerr,r6passufi QrEnrrp us Hvrpara rleJrJrrono3brAr4aMerpoM uop 0,45 MKM,Koroprrfi nepenocrr B 100 rrarcoeBo-Ka3ec rruoBoro 6ynroua Hnr cpeAbrl\b 8 u unry6npyror B reqeHrre 24-48.r. llocre uHI(y6auuu rrpu Harwqrlu pocra nepeceBaror nerJreit sa arap (Dorerx-[xoncoHa, Eepaa-llapKepa rrrrr{ cpeAy J\b 10 Arrr BbrAerreHu-f, S.aureus. Ecnu r o6pasqe o6napyxeHbr rpaMnoJroxuTeJrbHbre KoKKr.r, QeplreHrlrpyroul4e (cpe4a @orenx-lx(oHcoHa, cpeAaNe 10), o6raAarcune $epuenroM KoaryMaHHr.rr Jra3a, S.aureus. cqr.rraro! rrro neKapcrBeHuoecpeAcrBo KoHTaMr.rHr,rpoBaHo 5. EnoxurvuqecKr.rerecrbr AJrfl rrAeHTuQnxaqnrr MHKpoopraH[3MoB 5.1. Tecr Ha HaJrrrqueqrrroxpoMoKcrrAa3br Peaxrzs: lo/o pacrnop N,N-gurr,rerfiJr-rapa-Qenunen4vra[uHa ALIrLIApoxJIop[Aa. Pacrnop xpaH.rrr rrpr{TeMrreparype 4lo 10'C no QnaxonaxHefirparbHoro cBeor To3arrlr{THofo creKna. Pacrnop AonxceH 6rns 6ecqserHHr.r. fharuHosofi netnefi florocry Sunrrpona.nrnoft 6yuarv cMaqrrBarorpeaKrr4Borvt. qrcryro Kynbrypy uccneAyeMblx uJrr{ creKJrsnsofi uaro.mofi HaHocrr 24-uacozyrc arape r4nr4 6arrepufi, BbrpocrrrxxHa coeBo-Ka3er,rHoBoM cpeAeNe 1. Terv{Ho-KpacHoe qotBntrculeect B TerreHlle 1 uuH, cBplAereJlbcrByero noJIo)KLITeJIboKpaIlLIBaHrIe, uofi or<cu4asuofipeaKqr{r. lloroxmeJrbHbrM KoHTpoJreM cnyxr,rr Kynlrypa P.aeruginosa, orpr,ruarenrHbrM Kynbrypa E.coli. 5.2. Tecr Ha HaJrrrqne rrHAoJIa Peaxrns Kosaqa: r,rJrr4 rr3oaMrrnoBoro C nHpra aMr.{JroBoro I1apa-g nruerun aMHHo6eHsa,rr g errrAa - 75 *tt

5r

- 20 rran Xropr.rcroBoAopoAHofi xncnorrr KoHrI. Haaecry rlrrb.[eru.qapacrBoprrcT B crurpre npr{ nerKoM HarpeBaulrlr (Ha eoAsHofr 6aHeupu 50-55 'C), ocryxarcT Ir MeAJreHHo Ao6asirxror Kr{cirory.Pacrnop xpaHrr B 3aurilxleHHoM cBera Mecre npr{ TeMfleparype 4 4o 10 "C. Pearflie roJDKeH 6um or or )KeJrroro xpaHeHr{H rlBer peaKTrrBa craHoBnTcfiKopurrHeuBera. fIpH HenpaBnJrbHoM
BbIM, I{ peaKTHB HenpXfOAeH Anfi r{CIIOJIb3OBaHVfl.

B upo6upry c coeBo-Ka3erdHoBbrM 6ynsoHou wnv aa cpe4ofi JS 15, n roropofi nupocna uccneAyeMaflKynbrypa, BHocrr 0,5 ur peaKTr4Ba Kosa.ra pr cJrerKaBcrpfixr{BarcT. {epes HecKoJrbKoMr4Hyr rrpu Hanw&u4 r4nro.na sa6.nrcAaror rrosBneriue

@I

KpacHoroKonbIIaHa roBepxHocrr.rcpeAbrB [po6]rpKe. floloxlzreJrbHbrM KoHTponeM {BJltercr Kynbrypa E.coli, oror4rlarenbHhrM KyJrbrypa S.abony. 5.3. Tecr Ha rirr,,rllqne KoaryJraru (peaKur{f rr!'ra3MoKoarynrqnu) Cyxyro Irl4TparHyroKponuqbro nJra3Mypa3BoAqr conracHo npunoxeuuofi uncrpyKIIuII 0,9 o crepl{nbHblMpacrBopoM Harpur xnopnAa rd3oro}rurrecKr4M pa3r tILIBarorno 0,5 Mn B creprrJrbHbre npo6upxa. B npo6upry rroMeularcr 1 neuro cyrovHofi Kynbrypbl BbrAeJreHHbrx KoKKoB, BbrpauleuHhrxHa coeBo-Ka3erlHoBoM arape vru Ha cpeAe Ns 1. Iloro)KrrreJrbHbrMKoHTponeM cnyxr.rr Kynbrypa S.aureus, - Kynbrypa S.epidermidis. Heo6xoAllMo nocraBrrrb raKxe KoHorpl4llarenbHblM Tponb HeKoHTaMIaHI{poBaHnofi nnasuu. [Ipo6uprn unxy6upyror rrpr{ TeMneparype (32,5 + 2,5)'C. Peaxqnro nJla3MoKoaryrqrlr4r.r orMeqaror qepe3 xaxAufi trac B Teqenue 4-6 q, cJrerKa HaKJroHrr npo6upry, Ho, He BcrprxlrBar ee. flpu orcyrcrBvlu noJloxrrrrenrsofi peaKrlr4r.r rrJra3MoKoarynrrlnr.r yAnnrrrror BpeMt r.rnry6aqHurc 24 q Anr nonfreHr4JroKoHqareJrbHbrx pe3ynbraroB. Tect ua Harru.ave Koaryna3blcqlrraercr rroJro)Kr.rreJrbHbrM KoaryJrfliJrrrr rrpr4 rrJra3Mbr. 6. IfnrareJrbHble cpeAbl. Onpe4e,reHne pocroBbrx lr ceJreKTuBHrrxcsoficrn cpeAcrBHa crepr4nbHocrbu uurpo6uorornqeclnn ucnwrauils, neKapcrBeHHbrx rrucrory ucnonb3yror rrrarareJrbHbre KyIo cpeAbroreqecrBeHHorounu zapy5ex(Horo frpor43BoAcTBa. loroenrr [LITareJIbHbIe cpeAbl cneAyer, crporo npnAepxuBarcb fip]rBeAeHnofipeIIerITypbI,a cyxkre rrr4TaTeJrbHbre cpeAbr- corJracHolrHcTpyKrlurl no ilpr4MeHeHulo -u3f oroBlrrenr. He o 6xolulmrfi pH nuTareJrbHbrx np eAnpl4tru-fl cpeA y cr aHaBn r{Ba}or (25 +2)'C. Cpe4ri creprlJrn3ylor aBroKnaBe reireHue15 nrun npll reMlreparype B B rlpv reMneparype I2l oC, ecJlr4 rpyrlrx yra:auufi, npu ycJroBr4uBanr4qauuu Her rpoqecca cTepunv3a\Lil4. pocroBbrx r4 ceneKTr4BHrrx Onpe4eneHl4e csolicrB [poBoArr.unr raxAofi cepr{ra KoMMeptlecxofi cpe4u (cyxofi n roroeofi K [cr]oJrb3onauuro),a rarurce4la rax1ofi naprvru cp e.rlbr, r{3roroBJr sofi e,r a6opa r opvu. es flnraremnhle cpeAblAonnrHbr o6ecneqnearbpocr vpa3Burrre MuKpoopraHr.{3r\{oBKOHTaMLIHaHTOB neKapCTBeHHbIX CpeACTB.

pacrBopbr r{ nr{Tare,rrbHbre 6.1. PercomeHgyeMbre cpeAbr o (Docfuamnwil fyQepuutit pacmnop c Hampun xtopudo*t u nenmoHoru pH 7r0 Karuq QocQara oAHo3aMerrregHoro 3 , 6r Harpur $oc$ara ABy3aMerqeHHoro 7,2r Harpux xnoprdAa 4,3r flenrona (uxcHoro uilu Ka3evtnonoro) 1,0 r Boarr oqnurenHofi 1000un

o ffonyucudxufi azap dnn xpaHeHunmecm-JvuKpoop?aHuwor llaHxpearr4qecKoro ruAponr{3ara Ka3er4na 8,0r Harpux xJropr.rAa 5,0r Arapa 5 , 0r Bo,quo.ruueHHofi 1000 un pH nocnecrepr{nn3arluu 7,0+0,2

o Coeeo-xuseuruoeotil (Casein Soya Bean Digest Agar) azap

llanxpeauqecKoro rr4Aponrd3ara Ka3er4Ha 15,0 r flanaunosoro rr4Apo rrv3ara 6o6os con 5,0r Harpux xnoprrAa 5,0r Arapa 15,0 r BolsI oquuennofi 1000 un pH uocle crepvlrv3ar\uv 7,3+0,2 OmeqecmeeHHan cpeda dna eurpat4unaHufl aepo6uutx6arcmepuit cpeda Ng I dna rco mponn uurcpo6 uo it saepns euu o cm u, cyr an. p asnuqu affi npo u3eod umene;t. u u o Azap Cafypo c zJtwrKosoft aumuduomuxa.uu (Sabouraud Glucose Agar u

with antibiotics) Ilenrosa (uacuoro r,rKa3ezHonoro) ft roxosrrMoHorr.rApara Arapa Bolst o.Il,rulennofi pH nocne cr epurvsarJnvr

r 10,0 40,0r r 15,0 1000 rr,rn 5,6+ 0,2

OmeqecmeeHHafl cpeda dnn eupau4uneHttfl dpocrcxeebtx u MecHerdx zpu6oe cpeda l'/b 2 (azap Ca6ypo c ennrcosoil aumuduomurcauu) dnn xoumponanurcpo6uoil u 3a?pn3HeHHocmu. cvxafl. Da3nuqHbtx noouseodumen eit. flepeg ynorpe6neHr{eM Ao6aersror 0,1 r uarpuerofi conr 6ensr.rnneHr4rlr.rnrvrnavr 0,1 r rerpaqr,rKJrr,rHa 1 n cpeAbrB Br{Aecrepr{nbHbrxpacrBopoB rrJrr{ Ha Ao6asrsror (nenorr,ruqeruna) 1 n cpeAbrnepeAcrepualrbrepHarr4BHo narx,roparraQeHr{KoJra 50 na ilasalluefr. o Eynuoru Moccenn dnn odozauleHufl enmepoduxmepuft (Enterobacteria Enrichment Broth - Mossel) llanrcpeau4rrecKororrrAponrr3ara )Keirarr4Ha r 10,0 |rrrcrcossrMoHorr.{Apara 5,0r Err.{refi xeJrqr{ cyxofi r 20,0 Karug QocSara oAHo3aMerrleHHoro 2,0r Harpux Qoc$ara ABy3aMerrleHHoro 8,0r Epu.ruuauroBoro 3eJreHoro 0,01r 5 Bo,uu oqnruennofi 1000 un

pH 7,2+ g'2 HarpeBaror 100oCs re.reHue MrrHc rrocneAyrculuu 6ucrpbrM oxCpeay npu 30

JIAX,IICHHCM.

OmeqecmeeHHafl cpeda o6ozat4euuadna eumepo6axmepuit - cpeda Ne 3 dna rcoump uurcoo6uoii sazpnsueuuo u, c))xaa, asnuuuutx npouseodumeneil. p onn cm

o Azap Moccenn (Crystal violet, Neutral Red, Bile Agar ) 3,0 r ,{poxxeeoro gKcrpaKTa flanxpearrrtrecKoro rr{Aponr.r3ara Ka3er4Ha 7,0 r Conefixenqu 1,5r JlaxrogrrMoHorrrApara 10,0r Harput xnoprAa 5,0 r |rtrcrogrI MoHorrrApara 10,0r Arapa 15,0r HefirpanrHoroKpacHoro 0,03 r EZ

Kpucrannlrqe KoroSuoneronoro c Bo,uuo.ruueHHofi pH

0,002 r 1000 un 7,4+ 9,2

Harpenaror Ao KHneHnx.Hennsfl HarpeBarb B aBToKJraBe. OmeqecmeeHHat cpeda dna eadeneHufloHmepo6arcmepuil cpeda JW4 dnn xonmpoM MuKpo6Ho il 3azpts HeHH cmu, cw ar, p a3nuqHbtx np o u3sod umeJt o eil.

o Eyntou Max-Kouxu (MacConkey Broth) flaHrp earv rrecKofo rlrAponr{3ar xenarr.rHa a Jlax:rosrrMoHorr{Apara Euqrefi x{eJrtrr4 cyxofi Fporr,mpesoJroBoro nypnypHoro

BoArr oqurtleHHofi pH noc,re crepnnv3atfnlI -ge)g OmeuecmeeHHat cpeda o6ozaryeuundna eumepo6arcmepuil

20,0 r 10,0 r 5 , 0r 10,0 r 1000 un + 9,2 7,3

Nr_3ixz

o Aeap Max-Roruxu (MacConkeyAgar) llaHxpearuqecKofornAponrr3ara xeJrarr4na flenrosa (rraxcuoro Ka3er4Honoro) rr Jlarrosrr MoHorvApara Harpua xnopr.rAa Conefi xeJrtrlr Arapa HefirpanrHoroKpacHoro Kpucrar.nuqecKoro Quoleronoro Bo4u oqurqessofi pH uocle crepvrnv3a\uvr

17,0 r 3 , 0r 10,0 r 5,0r 1,5 r 13,5 r 0,03 r 0,001 r 1000 rran 7,I+ 0,2

Ilepe4 crepunr,r3aquefiKrrnrrrr I lruH, rocroqHHo Bc-tpflxrrBar^. omevecmeeHHafl cpeda dnn eutde",teHufl oHmepo6arcmepuu cpeda l,& a dna rcou-

o fletoxcaxonam qumpam azap (DeoxycholateCitrate Agar) gKcrpaKTa M.scHoro 10,0r MscHororenroHa 10,0r Jlarrosrr MoHolv.qpara 10,0r Harpua ur.rrpara 20,0 r Xeresa qrrrpara 1,0r Hatpua Ae3oKcuxonara 5,0 r Arapa 13,5r Hefirpa.nrHoro KpacHoro 0,02 r BoAu o.runlenHofi 1000rr,rn pH 73 +0.2
KvneHI{t Ha MeAneHHoM orHe I{ Kr{Iltrtr B TeqeHue I unu, oxJra}K"{onogxr Ao oC pasluBalor u B qaurKr4flerpu. Herrss HarpeBarb B aBToK!'raBe. Aalor ao 50

o Kcunosa,nuluH, desoxcaxonam azap (Xylose,Lisine, DeoxycholateAgar) Kclanosrr 3,5 r L-nuzuua 5,0 r

------I@

Jlaxrogu MoHorr4Apara 7 , 5r 7,5r Caxaposu Harpux xnopr4Aa 5 , 0r 3 , 0r 3KcrpaKra lpoxxenoro 0,08 r @eHononofo KpacHoro 13,5 r Arapa 2 , 5r Harpux Ae3oKcrrxonara 6 , 8r Harpun ruocyns$ara 0,8r Xerega aulroHufirlr4Tpara run 1000 Boau oqnueHHofi + 0,2 pH 7,4 oC u pa3nr{Baror qarrrKrr B flerpu. Hernsq 50 oxJra}KAaror.qo !ono4-rr Ao KrrrreHr{rr,
HarpeBaTb B aBToKJraBe. o Azap c dpunnuaHmogbrJtt 3eJteHbtmt Qeuonoet M KpacHbrm, ilaKmosofi u c(Na-

potoit (Brilliant Green Agar Medium) 10,0 r Ka3er.rHonoro) Ilenroua (naacuoro14 gKcrpaKTa 3 , 0r ,{poxxenoro 5 , 0r Harpnr xnoplrAa 10,0 r Jlaxrosrr MoHorr4Apara 10,0 r Caxapo:u r 20,0 Arapa KpacHofo 0,08r @enorosoro 0 , 0 1 2r 5 Bpn:uraaHToBoro 3eJreHoro 1000 vrn Boarr oqurueuuofi pH noc.ne crepvnv3arJurrr 6,9+ 0,2 Knnqrsr I rrHu. Zcnonrsyror cpa3y rrocne aBToKJraBLIpoBaHIrt.

o Bucnym-cyntQum azap (Bismuth Suljlte agar)

M-f,cHorogKcrpaKTa M-f,cHoro nerrroHa hrorogrr MoHorr{Apara Harpua SocSara rBy3aMeureHHofo Xeresa cynrQara Epur;rnauroBoro 3eJreHoro Bracrrayra cynr$rara Arapa Boau o.{uueHHofi

pH

5 , 0r 10,0 r 5 , 0r 4,0r 0,3r r 0,025 8,0r 15,0 r run 1000 7,6+ 0,2

IIBera. IlpuroroureHHar cpeAaMyrHaq, 3eJreHoro CpeAy He aBToKJraBr{pyror. - cpeda N, 5 dxn.KoHmporfl ca"trb.t4oHerr OmeqecmeeHHan cpeda dnn eutdeneHun gazpngu euu o cmu, c))x p a snura u x np o uzeodumeneil. u u uxp o6u o i an,

o Eynuouc ?nruKosofi (DextroseBroth) MqcHoro[errroHa

MqcHoro 3KcrpaKTa

Harpux xnoprrAa ftroxosH MoHoruApara Epourpesona nypilypHoro Boau o.rnureuuofi

r 10,0 3 , 0r 5 , 0r 10,0 r r 0,02 1000 nn

pH noc:re crepunr43a\vv 7,2+ 0,2 cpeda d.nnudeumuQurcaquusumepo1arcmepuit cpeda Np 6 dna OmgaecmeeHHen

KOHmpOrlt.MUKpO6HO;I 3Azpn3HeHHOCmU, C))XAL.pA3"TUqHtflXnpoL36od%mene;t.

o Humpamuotil fynoon (Nitrate Broth) 8 , 6r MqcHoro [enroHa 6,4r Harprlx xnopr{Aa 1,5 r Karnx Hlrrpara 1000ur Bolrr o.rnueHHofi pH no c:re cr epvnfi3arrutl 7,2+ 0,2 cpeda dnn ttdeumuQurcaquueumepo6axmepuii- cpeda Np 7 dna OmeqecmeeHHan rcoump .v urcp 6u o it sazpnsu euu o cmu, qtxan, p a zt u qu atx np o useodumeneil. otn o o Coeeo-xaseuHoeuil fyntou (Casein Soya Bean Digest Broth)

f Ka3e[Ha llaurpearuqecKoro rrAponu3ara flanazHosororr{Apo nvaara6o6oecou Harpur- xnoprAa Karuq QocQara ABy3aMerrleHHoro ftrorogrr MoHoruApara BoArr oquureHuofi pH nocnecrepr{nrr3auur4

17,0 r 3 , 0r 5,0r 2,5r 2,5r 1000nn 7,3+ 0,2

6arcmepuil cpeaa yp t ann rcoumponn cpeda dna eatpat4unaHufl OmeqecmeeHHatt pailuquau npouzeodumereil. .uuxpo6uoilnzpnzueuuocmu.c.vxan, o ltempu*tuduttfi azap (Cetrimide Agar) r xenarrrHa 20,0 flaHrpearnqecKoro ruAponr.r3ara 1,4 r MarHuq xnoprrAa 10,0 r Karuq cy:n$ara ABy3aMeureHHofo 0,3r I{erpnun4a (uernrn vpk14vrHr4fl oura4a) 6p 13,6 r Arapa 10,0 lr,r |rlraqepnna 1000 rvrn BoArr o.{fiueHHofi pH nocne creprlnpr3aur{u 7,2+ 0,2 Omerr ecmeeHHancpeda dna eutd eneHun cuHezuoiluoitnanoqKlt - 4IIX-azap dnn eutd euun cuuezuo;tuoilnanoqrcu. c),xan. en o ITIIX-azap IenroHa cyxoro QeplreHrarvBHofo Karus cepHoKr{cnoro Maruus cepHoKr4cnoro ceMr{Bo.qHoro CoArr Kanbrlr{HrrponaHHofi Oeuogan-xucnorbr qilX (N-uerunn vplarr4:r^ztfl, xnopl{croro 1-nogHoro) Arapa Boau o.ruueHHofi

pH
Cpeay He creprJln3ylor.

20,0r 7,6r 2,4r 1,0 r 0,2r 0,3r 8r 1000 u.rr + 0,2 7,2

. Azap dnn euneneHun nuoquaHuHa Pseudomonas (PseudomonasAgar Medium for Detection of Pyocyunin) flaHrpearnqecKororr{Aponra3ara )Kenaruna 20,0 r Maruu.sxJropr{Aa 6esno4uoro 1,4 r Karur-{cynrSara 6esao4Horo 10,0 r Arapa 15,0 r ftuuepuua 10,0lrn BoArr oqlrueHHofi 1000 run pH nocre crepvrvrcarJkrkr 7,2+ 0,2
Bce xounoHeHTbl,KpoMernldlleprrHa, pacrBopnor B BoAe.Harpeearor npr{ [epeMerrrr.rBaHr4vr vt r.vnflTflr 1 uus. ,{o6annxror rJ[rqepHH r4crepunr{3yror. o meqecmeeHH cp eda dnn ud eum uS urcaq cuueeu o itu o il nanoqrcu- lpg) a_NeJ_ an uu

o Azap Eepda-Ilapxepa (Baird-Parker Agar) flaHxpearlrqecKoro rrrApoJrr.r3ara Ka3er.rHa MrcHoro oKcrpaKTa ,{poxxenoro oKcrpaKra IIurus, xnopr.rAa Arapa |rtrEuusa HarpHx rrr4pyBara Bo,uuo.ruueHHofi pH nocne crepr4nrr3arlrdr.r

llocne creprrJlrl3aul4pl oxJlaxAalor Ao 45-50 oC u go6aBJrrror10 rran crepr4nbHoro | %opawnopa Kanut rennyplrra u 50 rr,l.rr KoMMepqecxofixenro.rHofi gMyJrbcnrr. o Aeap (Doeenn-flucoHcoHa (Vogel-lohnson Agar Medium)

10,0 r 5,0r 1,0 r 5 . 0r 20,0 r 12,0 r 10,0 r 950un 6,8t 0,2

llaHxpeau4rrecKoro ruAponrl3ara Ka3eHHa gKcrpaKra ,{poxxesoro MauHzra Kanus Soc$ara ABy3aMerrleHHofo nurus xnoprrAa ftlruuna Arapa @enorosoroKpacHoro Bo,uuo.ruueHHofi pH nocne crepr{Jrrr3arlLr lr

flocle crepl{nl{3aul,Il4oxnax(Aarcr Ao 45-50 oC n Ao6aBJrrror20 un lo/o crepntspacTBopaKanr.r{ HOrO Tennypr{Ta. -lpe)_a N9J_0OmeuecmeeHHan cpeda dnn eatdeneHufl 3oJtomucmozo cmaQuaorcoKKa

10,0 r 5 , 0r 10,0 r 5 , 0r 5,0r 10,0 r 16,0 r 0,025 r 1000 ur 7,2+ 0,2

o Jlaxmozuutfi fyntou (Lactose Monohydrate Broth) M.scHoro gKcrpaKTa flaurp eau4rrecKoro rrr Aponr43ara xeJrarrrHa Jlarrogu MoHorr{Apara Bolu oqurueusofi pH no cre crepr.rJrr,r3arlnr{
EIiI

3 , 0r 5,0r 5 , 0r 1000 rran 6,9+ 0,2

IIo cre cr epunr43arlnr.r cneAyer 6ucrpo oxJraAr{Tb cpeAy. OmevecmaeHHat cpeda dnn npedeapumerbHozo o6oeauleHun aumepo6aKmepuil - cpeda Ns I I dnn rcoumponn uuxpo6uoil sazpfl3ueuuocmu,q)xan. pe3nuquarx npouseodumeneil. o TempamuoHamHuu ileenqnuu fynoon c dpunnuaHmorbu|isereHu.u (Tetrathionate Bile Brilliant Green Broth) llenroHa 8,6r Fuqrefi xenqu cyxofi 8,0r Harpu-a xJroprrAa 6,4r Kansqrq xap6ouara 20,0r 20,0 r Ka-nus rerparr{oHara EpxnnuanroBoro 3eneHoro 0,07 r 1000 un BoAu oqHulesnofi

pH

7,0x 0,2

r Harpenarcr KrrneHux. Herssr neperpeBarb.llepeg ynorpe6neHr{eM1000rvrr Ao (6 cpeAbr Ao6asrxror20 ranpacrBopailora c lrurvs.fioAuAola r fioaa MeriuIJII,IqecKoro, 5 r rarlrq fiolu\a,20 lrn BoAbr o.*rqenuofi). - cpedaNg I2 dnn rcoumponn cpedad"qn eatdeneHufl canb.r4oHenry OmeqecmeeHHafl qtxan,pasnuquuxnpouseodumen .uuxpo1uoil zazpasueuuocmu. e;t. o Tpexcaxapruurt azap c coilnfitu ilceilesa(Triple Sugar - Iron - Agar) MscHoro3KcrpaKTa 3,0r gKcrpaKTa 3 , 0r .{poxxenoro lleurosa (xa-:euuonoro rvrxcuoro) rr 20,0 r Harpux xnopr.rAa r 5,0 r JlarrossrMoHorrrApara 10,0 10,0 r Caxapo:rr |rrrorosrI MoHorr{Ipara 1,0 r Xereso-auuonufi qr{rpara 0,3r Harput ruocynrQara 0,3r OeHoroeoroKpacHoro r 0,025 Arapa r 2 , 0r run BoAn oquulesnofi 1000 +0,2 pH uoc.rre 7,4 crepr{nu3arlflpr n HarroJrns.fl ua l13 o6reua. flocne crepvrrvsavrx Cpeay pa3nr.rBaror npo6vpKr4, qro6s o6pasoeanucr rlr{r4 raKrrM rr cpeAycKarrruBaror o6pasonr, cron6r4K KocrK. cpedadna udeumuQurcaquu canbMoHenncpedaJllb dna xonI3 OmeqecmeeHHan mpon uxpo6uoil sazpns euuocmu. c),x p asnu,a oE npouseodumeneil. n,+t u an, u o l{umpamnoit azap Cu.u.uouca Ha:rpuxxnopr.rAa Marsux cynrQara gNrzgpoQo Qara ArurraoHr.f, c Karrq ru4po$oc$ara Harpux qrrrpara EponarnuonoBoro clrHero Arapa Bo.quoquuleusofi

5,0r 0,2r 1,0 r 1,0 r 3 , 0r 0,08 r 20r 1000un

@

pH nocne crepunn3a\nv

7,2+ 0,2

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: t r

rF)

C)

o = E S

e
C)

H H

(.)
tt

a ai

6 !!
o
I G
I

tr, I s

(n
c-l
' = z . ( I ( o )

A c)

x
F 0 6

i E 3 F
A

o
cn at( )

5 c ) >ii < A i J
^ * S
v ) !

' t o

E E F c..l 1 c.) 1 o

E{-

E
) ( y 4

s 1
q)

( O F o + 1
I

H ) l A a

X F O l

s
x
! E

x E
v A

r<A = '

q t ls x ts
A

v
, r a

z
(.)

i$[[!E;ts;r s
: 5
A

AgR,x E

* E* E^ g_

E
*

( ( A

H F
+ ' ^
H

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> (
A

i:g F x HE S
4

+ E
O

5 E
E i E{iJ g o

f 5 q
g

E ar,. ( ! v
g " .

i ) 5 t r

! 1= X >. Ltz

o iE l a r {

f i E X t r I

B E = 5
| J F F

X ( g ! ) l

* g Rx
i F s
v E a < - * H

tr* x E
O.X
= r t ts L t

tiE
o o F E
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E8 = <
0() *$
E

+ gFRE H H9
3

F g E E = F ?
V

c) a
v

E
V

=
9

i
v

( ) > 9 i - 3 =I < 6
v

o E 9 H C * 6 =I *
co

c.'l

P = 5 = E F - I i F . i o -

gr $ E i , $ =
r r l

g i l a t
s

E9
X
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i
o

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nsq?sHg
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g O

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C C =

h i g X tr s
0 :
H

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f s gEi , F g E !
Pil9 g => : ! r EE =
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F Z E { : s i8i D 5 i PHEn .: + i EE
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z c e
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: : 4

I = n F'iX'r, H E E Ti V- : C O ^ + 4

? = , D F Y R -

8 F =? . Q d X Y 1 1
cd 5 6 d
1

a . )q 0 c . l : z ^ >

= g * : : r E F F - FE.=
*

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E

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b:H

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6 ! =

z
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m R \ H \ 4V t V , V l ' H r H
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D-u*: (3ds+ 2d4+ dr - d1): 5,

no KoropbrM 3areM crposr craHAaprHyro Kpr4ByloHa nonynorapuSruuuecrofi cerxe pacqera 6raonornqecroii aKTilBuocru asru6uorr{KoB, orKnaAbrBafl, ocu a6cqucc Ha - cooTBercrByrouue r4MKoHrIeHTparIr4r{ pacTBopoB BeJrrrqr.rHbr Ha ocr4 opAr{HaT 3oH, craHAaprHoro o6pasqa. Pa:soc:rb MexAy HafiAenHuMr{ BeJrrlrrr.rHaMr4 cpeAHuMrr 3oH yrHereHr.rrpocra recr-MrrKpo6a pacrnopoM r{cnbrryeMoro o6pasqa rr pacrBopoM KoHrpomuofi KoHueHTpaqun craHAaprHoro o6pa:ua u3 Tex xe qarueK npu6auruor r

Eq

3HaqeHuloBeJII{vLIHrI3oHhI, coorBercrByroueft KoHTponbHofi rosqenrparlutr Ha Kpr,rnofi (D3). 3arerra rpunofi HaxoA.flT no KoHIreHTparI[F, coorBercrByroqyro Hafi4ennofi BeJIlIqIrHe 3oHbI.VuHoxenneM rlonf{eHHofi KoHrIeHTpa\nv Ha crefleHb pa3BeAeHr,rt rroryqarcT aKTLIBHocTs I IvIr ocHoBHoropacrBopakrrru e 1 rar [cflhrryeMoro o6Pa3Ua. II p u M e p.Cpe4nuft pa3Mep AJU{ pacrBopaprcn6rryeMoro 3oH o6pasqanpprpa3BeAeHr{r,r 1:300cocraBJrrer 18,7uu, cpe4nuftp:r:Mep 3oHAJrrpacrBopa crauAaprHoro o6pasqa, co(ronrpomua.f, KoHrIeHTparIm) Tex xe trarueK- 18,5 irarra. Aepxaluero 2 rr.mr/rran r.r3 CreAosaTeJIbHo, ptBHocrb cocraBJl{er*0,2 uu. 3ry pasnocrr upu6auaror K BeJruqr,rHe 3oHbr AJrt pacrBopa KoHrleHTpat\uu2 B urcr/run cranAapnroft ro rpueofi, roropax paBHa D3: 18,6urvr, u nonyqalor BerI.ItIuHy18,8 rrtru. HaxoA.srua rplrnofi KoHrleHTparlr4ro, coorBercrByroqyro - 2,36 vtrrllan. 3ry BenLItILrHy pa3Mepy 3oHbI AaHHoMy yr{Ho)KarcT creneHbpirBeAeHr,rt Ha Ir rroJlyqarcT coAepxaHl{e aKTI,IBHoro Berrlecreae 1 MJI ocHoBHoropacrBopa, T.e. 2,36 rvrcrlunx 300: 708 uxr/un, Tar xar KoHIIeHTpaIIIdTI pacrBopacocraBJuna1 vr/ul, To aKTHBHocrb ocHoBuoro r,rcrrbrTyeMoroo6pasqapaBHa 708 rr,rrr/vrl: I ur/un: 708 uxr/ul. Onpege,renlre aKTrIBHocrrr rlcrlblTyeMoro o6pa3rla pacrrerHbrM nyreru. KpzBat, orpaxarcqzu 3aBI{cI,IMocrb MexAy aKil.rBHocruo anru6uorl{Ka r.rpmMepoM3oHbr yrHeTeHlrt pocTa TecT-MI,IKpo6a, (ororapusu ronnocne flepexoAa K KoopAr4HaTaM - ArraMerp 3oHbr(D)> npeo6pasyercr B rrprMyro, ypaBHeHr{eKorleHrparlru (lgo ropofi: D:e+bxlgC, r1e:.a- cno6o4urrfi vreu; b - yrnonofi roe$$rqueHr. flo ucnpaBJreHHbrM 3Haqegr,rrM BeJrr{rrlrH AuaMerpoB 3oH dr, d2, dq, ds Arrx pacrBopoBcraHraprHoro o6pa:qa c KoHrleHrpaurrMr{cy c2, c+ Csr.ro6rqefi cpe4nefi BenI{qLIHe Al{aMerpa 3oHbrd3, coorBercTByroqefi xonrponrsofi c3, peccgraTbrBaroT BeJIITqI,IHbIu b c [pI{MeHeHI4eM a Mero.{a Har,rMeHbrrrr4x KBaAparon.Tar KaKKoHrIeHTpaII[I4 Cy C2, C3, C4, C5 cocraBntlor reoMerpllqecKyrc [porpeccuro, Sopuynbr Anf, Bhlqr.rcJreHur roeSQnq[eHToB a w b Moryr 6rrrr 3anncaHhrB Br,rAe:

t : 1- 2dt - dz+ dq+ 2d)lt0 x lgz;

a:d -b lgc3,

rge Z - 3HaMeHareJrb nporpeccvn pa3BeAeHr{r; d - : ( d r + d 2 + d z + d a , +d ) l ' .

II p u M e p. llycrs 3HaMeHareJrb npolpeccilv pasBeAeur.rr Z: 1,25; C3: 5,0; a cpeAHrre 3HaqeHr,rr (e urra) paBHbr: 3oH d1: I7,64; dz: 18,15;Q: 19,03; Ar{aMerpoB da:19,58; ds:20,09.

TorAa:
=

+ o : (1. 17,64 18,15 19,58 2. 20,09) (10 x lg 1,25): 6,33:0,969: 6,532; + : 4 - : ( 1 7 , 6 4 + 1 8 , 1 5 1 9 , 0 3 1 9 , 5 8 2 0 , 0 9 ) :5 : 1 8 , 9 0 ; + + + : a: 18,90 6,532x 0,6990 14,33. EclH B onbrrec oAnofrcraHAaprHofi xpunofi npoBe.qeHo ro nvcrrbrraHlrfi o6pasqa, norapuQrvr cpeAHero 3HaqeHlrr KoHrleHTparlr4r.r ucnbrryeMoro B o6pasqa onbrrepaccrrr,rrbrBaror Qoprvryne no : lgCu= lgC r+(cl - d'1t b, " pa6ouefi rre: Cry- cpegHee rouqeHrpa\HurrcnbrryeMoro ro3HaqeHrae o6pasqa,
nyr{eHHoeno 14 IIcnbITaHuflM;- cpeguee3HalreHue pocra, rronyqeHHoe n rrano d,, AuaMerpa3oH3aAepxKrr pannenbubrM HcrrbrraHurM(3n uaruxalr); 3HaireHue coorBercrByrouleroAxaMerpa.unrKoHTpo;tHofirond, - cpep'uee (no 3n.raulru). IIeHTparIuu, rroJrf{eHHoeB Tex }Ker4crrbrranuflx B e n r . r . { u H yK o H u e H T p a \ u u C u B b r r r r 4 c J r r } o TK a K a H T r . r n o f a p r a $ u : Cu: antilg(lgCy). crr.r Cg ,{rx n o;ryr elr^vflaKTlaBHo v cnbrryeMoro o 6pasqa (A BenHqHHy ylrHoNaror ") -Y Ha ero pa3BeAeHrre ofibrTe 1l. B Ilpuuep.l. llycrr n:l; C3:5,0; dr:18,61 tr drr:18,44 nprTr:160.

I Torra: o, - du 18,44; ,' - ds: 18,61 vl + l g C u : 0 ,6 9 9 0 (1 8 ,44 18,61) 6,532:0,6730; : :0 ) ,710; . Au: 4,710 160:754. C r,: a n ti l g (0 ,6 7 3 4

Ifpuuep2. flycrc n:3; C3: 5,0;ds, : 18,6i;ds, : 18,3; : 18,12; dr, 18 d .,l: 1 8 ,4 4 ;6 1 1 2 : ,1;dur : 18,3tr ptry u.:160. Tor'a: a , : ( 1 g , 6 1 1 g , 3 1 g , 1 2:)3 : 1 g , 3 4 ; + +
-

d , : ( 1 8 , 4 4 +1 8 , 1 1 8 , 3 ) : 3 : 1 8 , 2 8 ; +

+ IrCu: 0,6990 (18,28 18,34)6,532:0,6990 0,0092:0,6898; :

: Cu : antllg(0,6898) 4,896; Ar,:4,896'160: 83. 7
EIIIiI

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+* Onrr.rqecrule Bbrrrycrarorcrr{ paccbrralorcafoclpapcreeuHblM HayqHono Myrr{ocrlt H }rHc'rp}'Krlr.rr nx ucnoJlb3oBaHr.rro craH.(agrbr 6uo:ronrqecrux npenaparoBsu. JI.A. Tapacenuua. HccneAoBarenbcKHM uHcrl{TyroM cra*raprv3at\rrprH KoHTpomMeArrrlrrHcKr.rx

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BO.IIE.

Arapora-.{3A3 Anf ronoo6ueHuofi xpoMarorpaQnn flonepe.rHo-cul{Tatarapo3a, 3aMerrleHubrMr,r c rpyn[aMra, Ar{gruJraMr{Hogrr.rJrbubrMr.r B BvAeurapoo6pasHbrx rpaHyJr. Arapora/no[eperrno-crunrrrfi [onuaKpnnaMnA Araposa B flonepevuocluurofi uonnarp[JraMnAHofi rr,rarpnqe. pasI4cnonrsyro Arrs. r mo6ynrpHnx 6erxos c MoreKyJrrpHbrMr{ MaccaMr{or 2 x lOa Ao AeJreHHr x 104. 35 A.qeno:nH. C10H13N5O4. (M.u. 267,25). 6-Arrauuo-9-p-D-pn6oSypanosul-9HnyprrH. Kpncrzurn crcuir uqe noporuor 6enoro rlBera. Ma.uopacrBopr.rM BoAe,[paKTr,rtrecKn B HepacrBopr{M arleroHe,cnupre 96 o/o B n eQupe;pacrBoprercr B pa3BeAeHHbrx pacrBopaxKr{cJror. gt

Teunepamypo nna*neHun. Orcono 234'C. (M.rra. AAnnnnoBaflKncJrora.C6H19Oa. 146,14). Kpracrannbr Br,rAe B [pH3M. Jlemo pacrBopllMa MeraHone, pacrBopr,rMaarleroHe, B B npaKTr.rqecKr,r HepacrBopr.rMa B rerponefisona e$upe. Tu,'tnepamypa nna*neHun.Orono I 52 "C. ArouernH H. ClTHt2NNaOsS2. (M.r'r. 445,4).Harpnx 4-rragpoxcu-5-(2-ruyporcr.r6eusunngenarvruno)-2, 7-na$ranungucynr$onarrucasrfi. 6ecqeernuit uttu 6enufi Kpr,rcrrlrrnuqe nopofiroK. crufr Pacrnopurr.r BoAe cutrpre 96 %. B r{ AsoMerrH H pacrnop 0,45 r a3oIvIerI,IHa N I r acrop6uHosoi Kr.rcJrorbr H pacrBop{rcTB BoAe npu cna6ona HarpeBaur,ru AoBoAlrr r{ o6rerupacrBopareM }KepacrBopr,rreJreM 100 nan. Ao Aror. N2. (M.u. 28,01).Asor npounrrrfi r.rBbrcymenHHfi. Aso'r oco6ofiqncrorbr. Co4epxur HeMenee 99,999% (o6lo6) N2. !'znepoda ^4oHooKcud. 6olee 5 ppm. He Rucnopod He 6onee5 ppm. Asor ArrflxpoMarorpaQnu.Co4epxrrr HeMeHee 99,95% (o6lo6) N2. Aror, cnodolHrrfi or rlrc.nopoAa qepe3pacrBoptruporalrnona Asor oquulalor or Kl{cnopoAa qeroqnponycKan[eM sofi. Asora 3aKr.rcb. NzO. (M.u. 44,01).Cogepxur HeMeHee 99,99% (o6lo6) NzO. AsamaMoHooKcud. 6olee I ppm. He Veuepoda.^4oHooKcud. He 6onee1 ppm. Asora MonooKcrrA. (M.r"r. NO. 30,01).Cogepxur HeMeHee (o6lo6)NO. 98,0a/o A:oruas Kr{cJrora KoHueHTpr.rpoBaHnax. HNO3.(M.vt.63,01).Co4epxur HeMeHee (u/u) u ue 6o.iree 63,AoA 70,0oh(rv/u)HNO3. flpospa.trar, 6ecqrerHafl,vJTLr noqrfi 6ecqneruaq xuAKocrb,cMerr]r{Baercfr. c no4ofi. d,i . Or 1 ,3 8 4o 1 ,4 1 6 . l Pacrnop 10 r/n flBJltercflclrnrnofi xuc.rrorofiH EaerpeaKrlr{rc Hlrrparbr. Ha Ilpospauuocmb.AsorHaqKprcJrora 6rrrr npo:pavuoil. lo.lilKHa Ifeemuocma. Oxpacraa:oruofi Kr.rcnorhr 6rrrr Her4HTeHcr.rBHee oraroua Y6. Aonx{Ha a/o Xnopudut.He 6o.nee 0,00005 (0,5 ppm). K 5 r agornofiKr.rcnorbr KoHrleHrpt4poa/opacryopacepeopa eaHHofi npu6aelxror 10 nrnBoAbI u0,3 rr.rr1,7 Hr4Tpara, BhrB TeqeHlre rvmu 3auluqeHHoM cBeraMecre.llolyueuuufi pacreop 2 B or Aepx{LIBaIor BbIAepxI{Barb LtcrIbITaHve xJropr,rAbr. Ha 3ra-uosroroBrr c r{cnoJrb3oBaHr,reM AonrKeH cMecla 13 MJI BoAbI, 0,5 MJI asorHofi Kr.rcJrorbrKoHrleHTpr.rponannofi, 0,5 rra;r pacrBopa 3raJroHHoro (5 xnopr{Aa pprn Cl) u 0,3 ul I,7 oh pacrBopa cepedpa
Hr4TpaTa.

CynaQamur.He 6onee 0,0002 % (2 ppm). K 10 r asornofi KlrcrrorbrKoHrleHrpr{posanHofi npu6anrmrcr 0,2 r Harpus rap6onara v BbrnapvBaror locyxa; ocraroK pacrBoptror B 15 trn BoAbI ErcrvnnrporaHHofi. lloryueHnrrfi pacrBop Aonx(eH BblAepxxBarb I4cIIbITaHue cynr(raru. 3raros roroBrr c r{crroJrb3onanNeu un Ha 2 pacrBopa cynr$ara (10 ppm SOa) u 13 rra-rr 3raJloHHoro BoAbrntrcrvrnvpoaaHHofi. o (a,02 ppm).K 50 r a:oruofi Kr4crrorbr Muutaarc (rraero4 A). i{e 6oree 0,000002

KoHueHTpI4poBaHHofi [pu6aBnrror 0,5 rr,r.n cepHofi KrrcJrorbr KoHrleHTp]rponauuofi u ocropoxHo HarpeBarorAo [orBneHr,rs 6enux fiapoB; K ocrarKy npu6anlxror 1 un pacrBoparLIIpoKcvJIaMIIHa I0 %o rllApoxnopl4AaA AoBoAtr no4ofi Ao o6telra 2 wn. lloryueuHrtfi pacrnop AonxeH Bbrrep)Kr.rBarb r{cnbrraHneHa MbrrrrbrK. Srarou roroBrr c r{cnonb3oBaHueu Mrr3TaJrouHoro 1,0 pacrBopa Mbrrrnrxa (1 ppm As). Tatrcen'te ueme;t.tbt.He 6o;ree0,0002 % (2 ppm). 10 l,r:rpacrBopa,npr4roroBneHHoro Ha AJIxI4cnblTaHufl, )Keire3o, AoBoArr roIofi Ao o6reua 20 wl 12 wn ilonyqeHHoro pacrBopa AoJI)KHbI BbIAepxI{Barb r{crrbrra:a:ae rtxeJrbre MerarJlbr.Sralos roroB.rrr Ha pacrBopa cBr.rHua ppm Pb). c HcnoJrb3oBaHr4eM (2 ?ranoHHoro X{e"ueso. 6onee 0,0001 % ( 1 ppm). Ocagox, nonyrreHHbrir He npu HcrrbrraHr4r4 cynbHa $aruyrc 3ony, pacrBoptror n 1 n.n xnopr{croBo4opogHofi KrrcJrorbr pa:negeHuofi 7,3 o H AoBorqr o6reu pacrBopa soAofi ao 50 nn. 5 Mn nonyrreHHoropacrBopa prcAoBonrr soAofi Ao o6beMa 10 u;r. llo.rryueHurrfipacrnop AonxeH BbrAepxr{Ba-rb
NbITAHI4E HA XCJIC3O.

Cy-nuQamuan 3o,1a. 6oree 0,001 %. 100 | Kr4cnorbr He asorHofi KoHrleHrprrponaunofi o cTopoxHo BbrnapuBaroT clxa ; o cTaToK cMaquBaroT cKoJrbKrrMrr He KafrJuruucepuofr Ao KHc JrorbrKoHrleHTpuponaHuofi HarpeBarorAo 6ne4Ho-rpacHoforlBera. H KotuqecmneHHoe onpedeneuue.K1,50 r KrrcJrorbr asornofi KoHrleHTprrponauHofi npnyrc6an;rsrcr oKono 50 un BoAbr r.rrr{rpyror I M pacrBopoM :uarpvrs. rr4ApoKcr.rAa, pacrBopa MerrrnoBofoKpacHofo. rronb3yr B KalrecrBe r.rHAr4Karopa ur 0,05 o/o 0,1 I ur i M pacreopaHanplg,fl rr4ApoKcrrAa coorBercrByer 63,0 ur HNO3. XpaHxr B 3aruvueHHoM cBeraMecre. or AgorHas KncJrora, ceo6oAHafl or cBrrHua A:orHa.f, Kr4cJrora KoHqeHTpHpoBaHHar AoirlxHaBbrAepxr{BarbcneAy}ouee AononHUTEJ]bHOE I4CNbITAHIIC.

K 100 r asoruofi Kr4cJrorbr KoHrreHTpr{ponauuofi npn6ae:rrrcr 0,1 r Harpvrs rap6onara 6eseoAnoror{ BbrnapnBaror Aocyxa; ocraroK pacrBopqror B BoIe npll cna6oMHarpeBa:r'uLr .uoBoArro6r,eu pacrBopa reM )KepacrBopr.rreneM 50,0 lr:r. Co4epxaHrae i{ Ao cBI{HIIa onpelen{rcT MeroIoM arouso-a6cop6uHouHofi cnexrpoN{erpnn.I4ureHcusHocrb non-rouleHurv3Mepnrornpr{ Anr{HeBoJrHbr 283,3 HMHJrrr ,0 HM,Hcrtorb3yq 2I7 B KaqecTBe rrcToqHHKa vr3rlyseHfifl, naMny c noJrbrM cBHHrIoBbrM KaToAoM Bo3AyrrIHor4 auernneHoBoe nnaMr. He 6o:ree0,0000I Yo(0,1 ppm Pb). A:ornas KrrcJrora, cno6oAnas or cBrrHua r{ KaAMr.rfl Agoruaq Kr.rcnoraKoHueHTprrpoBanHafl cneAyrorlue AononAonlr(HaBbr.qepxr.{Barb
H HTEJIbHbI E IjCNbIT AHVIfl,,

Irlcnurmyeuau.i pacmeop.K 100 r asorHofixuc;rorbrKoHueHTprponauuofi npu6annntor 0,1 r narpnx rap6oHara 6eseoAHoro,BbrrrapuBaror Aocyxa; ocraroK pacrBoprror B BoAenpr4 cra6orr HarpeBaHr4u AoBOAsro6revr pacrBopa reM x{e pacrBopr.rreneM r{ ur. Ao 50,0 Kad.+ruti. 6o;ree0,00001 o (:0,1ppm). Co.uepxaHne He KaAMr.rr orpeAen.f,ror MeroAoM arovso-a6cop6unoHnofi cnerrpoMerpprr{.I,IsrescnBHocrb nornoxleHr4r r43Mep*or rrpr4rnr4He BoJrHbr 228,8 HM, rrcrroJrb3yq KaqecrBerdcrorrHr4Ka B r43nyqeHurnaMny c rrorrbrM KaAMrreBbrM r{ KaToAoM Bo3AyrrrHo-aueTr{neHoe Bo3AyrlrHo-nponaHoBoe I{IrH
IIJIAM,f,,

(0,1ppm). Co4epxanue Ceuuery. 6onee0,00001o/o He cBHHua onpeAenrrcr MeroAoM

eEg

llHreHclteHocrb rlorJlolrleHrrt lr3Meptror aroMHo-a6copqrroHuoficnexrpoMerpr4r4. naMrly c flonblM cBI4HIIoBsIM 217,0 HM, rrctrroJlb3yt 283,3 HM rrJrrr rrpr,r Ant{HeBoJrHbr lraMs. KaTOAOMBO3AyrrrHO-aIIeTHneHOBOe I{ AsorHaq Kl{crlora. Colepxur 3l-34 % HNO3. r CNleruusaror1 r asorHofi rvcrorbl KoHueHTpI'IpoBaHHouuI Borbl. [Inomuocma.1,186- 1,210. 12,5 o/o.Corcpxl{r oKono I25 rlt HNO3. Asoruafi KHcJIora pa3BeAeHHan 20 r rzc.rroTbla3orHofi rouqesrpupoBaHHofi 4ono.UxrnoAofi Ao o6leua 100 ul. o/o. Asoruaq Kr{cJrorapa3BenenHas16 o/o.CorcpxHT a3orHofi ruc.nors 15,5-17,0 Claeurusaror 1 r agornofi xHcnorut H I I BoAbI. Ilnomuocma. I,087 -1,096. Arornag Kr{cJ'roranbIMflrtlaq xenroBarofo IIBera, AbIMqIrIatHa Bo3Ayxe. cJrerKa Ilpospauna.fl)KHAKocrb, d;; .Oxoro 1,5. AsorHofi KHcJrorbI 2 M pacrrop 193,8 MJr asorHofi KI{cJIorbI KoHIIeHrpI4ponaHHofipas6auxror eoAofr Ao o6relra i000,0 un. AsorHofi Kucr'rorbl 0r1 M pacrBop paslastmor soAofi Ao o6beMa1000,0un. 9,7 r asoruofi xucnorbr KoHrIeHTpr4poBaHHoit Arcpn.nauuA.C:HsNO. (M.u. 7 1,08).llponenarr,rug. EecqeerusreHilvr6eloro rlBera xronb.f, HILI KpucrarruqecKufi uopolrox 6eloro unN nor{Tn6e;roro uBera. B O.{eHsnerKo pacrBopr,rM BoAerr MeraHone,JretKopacrBoplrMB 3TaHoJIe. 'C. TeunepamypaMarneHua. Axoto 84 (29 aM Axpu.nam nA-6nc arcprrd'r r.rAa :l) 30' p acrBop pacrBoptu n 1 I BoAbIu $unr290r aKpr{naMr4lauI0 | Merr4JreHlucarcputaMr41a

rpyror.

(3615: 30 oh pacrBop 1) ArcpnrauuA-6ucarcpl{JraMl{Aa 292r aKpr.rnaMruau 8 f Merr4JreH6ucaxputauv4apacrBop;{Fors 1r BoAbIu Qu.urrpyror. Bl.rHnluy72,06).llpon-2-eHoBasKIrcJIora. Arcpn.ronaq Kncrora. C3HaO2 (M.rur. paBbrrHarKI4cJrora. 0,02 o pacrBopoMMoHoMeCogepxur He MeHee99 % C3H4O2.Cra6utmzlrpoBaHa
TprJroBofoeQupa fI{ApoxHHoHa. 6 e cuserHa fl, prlrvlcn ef Ka xeJrroBara fl. e rKafl xI,IAKo crb.

c CMeurusaercq nogofi,cnuproM96 % u eQuporra. B Jlerro ronlrMepr{3yercq nplrcyrcrBul{Kr{cJlopoAa. d]i . o*ono 1,05. n',',. o*ono r,421. KuneHufl. Orolo 141"C. Teunepamypa Teunepamypa MerreHua.Or 12lo 15'C. KI,IcJIora. n. 3 B-A.nann Crra. -Arul{HorlponuoHoBat (M.t. 304,42).(9RS, 10RS)-9,10,16-TpuAneypnnoBanKrrcrrora.Cl6HzzOs.
fr4ApoKcr{feKcaAeKaHoBatKtrcnoTa.

vEE

B lloporuox 6eroro rlBera,xnpHrrfi Haoruynb.Pacreopul,ra MeraHone. 'C. Teanepamypa ntazreHun.Oxono 101 (M.u. 360,26).Harpux I,2-AurunpoKcl{aHrpaArnsapun S. C14H7NaO7S'H2O. xznoH-3-cynr$ouar, MoHorr.r.upar. Harpua 3,4-gurugpoxcn-9,10-4uor<co-9,10MoHorrrApar. Arrrr,rApoaHrpaqen-2-cyrrSouar, rlBera. Ilopourox opaHxeBo-xeJrrofo n xroJlerxopacrBoprrM BoAe cnr{pre96o , ilpaKTnqecKu B 14 HepacrBoprrM6eu3one, poQopneu sQnpe. Anu:apuuosrrfi rcpacusrfi Cnr.A.nnrapnnS C. I A,rusapnnaS pacrnop 0ol o/o.Pawsop r/n. Peaxrusu3MeHser or I.Icnutmauue qyscmsumerbHocmb. Ha oKpacKy xe:rrofi Ao opaH6apu.n nepxnopara. xeBo-KpacHofi ycraHoBneHril4-rvrpa M pacrBopa npu 0,05 pH3,7-5,2. flepexo4oKpacKr4 xenrofi.ao$uoreronofie r4HrepBane or (M.na.309,21). Harpueea.f, A,rurapnnosrrfi xe,rrrrfi. Ct3H8N3NaO5. com 5(N-HurpoSeuun)aso xucnomr. caJrr{rlunoBofi TeMHo-Kopur{HeBoro KpacHor{nr{ Kpucra,r:ru\ecxvia noporroKcBerno-Kopr{r{HeBoro,
Kopr{qHeBofo rIBeTa. Ma.no pacrBopr4M BoAerr clrrpre 96 oA,nerKo pacrBopr4M B rrpr{ HarpeBaHrrh. pacrBopaor cBerrro-xerrofi K KpacHo-opauxenoftB r{HrepBarcpH llepexoa oKpacKr{ Ha Pacmeop uudurcamopa. 0,1 oh paclop. PacrnopeHr{enpoBorflr rrpn HarpeBaHI4I{ sol-ruofi 6aHe. A.irronunnfi. Al. (A.n. 26,98). Mxrxnfi, xoexufi MeraJrJr 6e;roro c rony6onarbrM orreHKoM rlBera B Br4Ae 6pycxoe, JrrrcroB, noporrrKa, JreHTbr rrnv npoBoJroKr4. nos.uyxe Ha o6pa:yerc.f,oKI4cHatIIJreHKa, KOTOpar 3aUIUUIaeT MeTaJrJr KOppO3rrU. OT qr4crorbr. AHa,ruru.Iecrofi Anronruunfl -KaJlrrfl cy.nrQar. A,rrouorcaJlueBble KBacubI. AIK(S 04) 2' I2H2O

or 10,0 12.0. rc

(M.*. 474,4). He Co4epxur MeHee oA se 6oree100,5 AIK(SOD112H2O. 99,0 u %

lpauynHpoeauHrrfi noporxoK Hrlr 6ecqserHar KprrcrannrqecKa{ Macca. Jlerxo pacrBopnM B BoAe,or{eHbnerKo pacrBopr4MB Krrnrurefr soAe, pacrBopl4MB B rnnuepr4He, npaKTr{qe HepacrBop}rM 3TaHoJre. cKr{ (M.u .375,I5). AnronauHnx A.nrounxnq Hnrpar. A1(NO3)3'9H2O. Hurpa1 HoHarlrApar. pacnnbrBaroilIilecrHa Bo3Ayxe. Kpr.rcra,ubr, pacrBoprrMB BoAeH crrr{pre 96 o , oqeHbMaJro pacrBoprrMB arleroHe. Oqeur JrerKo Xpanxr B Bo3AyxoHenpoHrrrlaeMoM xoHrefiuepe. Arrouunnfl oKcHA6esnogHufi uaAnronrunHqoKcrlA,cocrorurli,t nz y-,\12O3,o6esnoxeHnrrfi v arTLrBuposaHHrrfi - or 75lo 150 uxrvr. rpeBaHHeM. Pasuepqacrurl Alrorrnnnfl oKcrr.uocHonHofr Aruounuur oKcr.r.{ 6e:soAHHfi ocHoeHofi Soprrmr[pnroAeH Anr xpoMarorpa$nueCKI4X KOJIOHOK.

pH. Or 9 ao l0 (cycneusnr, noJryqeHHar Bcrprxr,rBaHr4eMr c 10 Mn BoAbrB reqe1 uHe 5 rr.rraH).

AmouuHufl oKclrAnefirpa,rrHufi. Al2O3. (M.pr. 102,0). fpauynnpoeaHHrrfi roporxoK 6e;roro rlBera. O6aeuuaa eMKocmb. 1,00 r rrpoKarrHa rr{Apoxnopr.rAapacrBoprror B cnr{pre (90 o , o6lo6) r.r AoBorflr o6reu pacrBopa reM )Ke pacrBopureJreM ao 100 un. 20,0 lrn nonyrreHHoropacrBopa z 5,0 f HcnbrryeMofopeaKTr4Ba noMerrlarorn xon6y BlvlecrnMocrbro 100 rrrnc npr{Teprofi crexn-flssofi npo6rofi, BbrAepxnBaror TeqeHpre B 15 uuu, nepnoAlatlecKl.r BcrpflxprBafl, Sunrrpyror. K 10,0 rr,rn n $unrrpara npu6anoApacrBopa 6pouQenoJroBorocr{Hero r,rrrrrpyror rqror 10 u.rr BoAbr,0,05 un 0,05 0,1 M pacrBopoM xnopr{croBo4opolnofi Kprcnorbr,[o 3eneHorooKparr]lrBaHns.. OxpacKapacrBopaAonxHa u3MeHr{Tbcfl.rrpu pacrBopa npn6an:reHvrHe 6oree 1,4 lr,r 0,1 M xnopr{croBo4opo4nofiKrlcJrorbr. Bodopacmsopuubtesel4ecm6a.He 6o:ree0,2o .I4cnoruayror xpoMarorpaQruecr<yro KonoHKyc BHyrpeHHr{M roneu xoropofi AuaMerpoM I cm, 4nzuofi 40 cM, HHXHr4fi cylreH Ao AnaMerpaor 2 rc 3 nrna cHa6xeHnoprrcrbrMcreKJUrHHbrM n Snnrrpola (100) I{Jrr{ xJrorrKoBbrM TaMrroHoM Bbrrle cyxeuHofi qacrn. Konouxy 3anonHrror 10,0 r ucnbrryeMoro peaKTr{Ba 25 MJrBoAbr,3nror4pyrorBoAcfi Ao ilonyqeuuq 20 Mn rrpou 3par{Horo3Jrroara, xoropufi BbrnapnBaror cyruur npv reMrreparype 150 oC; naacca u ocrarKa He AonxHa npeBbrrrrarr20 lrr. Pacmeop S. OcraroK, [onyqennufi B r.rcrrbrraHuu <BoAopacrBopr{Mbre BexrecrBaD, pacrBoptrcr nprr HarpeBaHurz BoAe,Qunrrpyror H AoBoAmo6reu $unrrpara nogofi B ao 100 u,r. Xtopudat. He 6onee0,05 o . I ur pacrnopa S AoBonsrno4ofi Ao o6leva 15 na;r. lloryueHnrrir pacrBop AonxeH BbrAep)KrrBarb ucrrbrraHrr Ha xnoprrnbr. e oh. 1 ur pacrnopa S AoBoArrnoAofi.qoo6reua 15 rr:r. floCynaQamul. 6onee0,7 He pacrBop AonxeH Bbrlep)KirBarb .rryveHuufi vcfrbrraHr{e cynrSaru. 3rarori roroB.f,T Ha pacrBopacy:m$ara (10 ppm SO+). c ncnonb3oBaHrreM lrn sraJroHHoro 10 XpouamozpaQuuecrcan pasdennnu4an cnoco6Hocmb. Xponrarorpa$uuecryro KonoHKy, onr{caHHyro r4crrbrrasuu B <BoAopacrBopr{Mble BeurecrBa)), ucnbrryeMbrM 3arronHrrror peaKTlrBoM Bbrcorbr5 cu. 9epe3 KonoHKy nponycKaror 5 u.n pacTBopa aso6eHsora r]o u 5 u.n MeroKclra3o6eH:ora,3areM npoMbrBaror20 lrn cMecr.r pacrBopr4Te:refi 6eu- nerporefiuufi eQlrp (l:a). B nepxHefi .vacru KoJToHKH 3oJI o6pa:yercs cloit Merorczago6eu3ona .f,pKo-)KeJrroro or 3 .uo 5 uu, a Hr{xe efo uBera roruusofi ria6lroAaerc"s c;rofi aso6eHgora6reAso-xenrofo rrBeraroluluHofi 2 ctt. A,rroruruns xr'roprrA. AlCl3 ' 6H2O. (M.u. 241,42). A:nouvnuq xnopnA reKcarrrApar. Cogepxur He MeHee 98,0 o AlCl3 ' 6H2O. Kpucra:r.rru.{ecxufinoporxoK or 6eroro .qo cnerKa )KeJIToBaroro uBera, rI4fpocKonur{eH. Jlerxo pacrBoplrMB Bo.ue crrr4pre96 o , pacrBopr.rM e$upe. r4 n XpaHar B Bo3AyxoHerrpoHnrlaeMoM xonrefiuepe. pacrBop A.nroprlruufl x!'ropr{Aa pacrBop-srcT BoAer.rAoBor-flT 65,0 r arrovtprnvrr xnopr.rAa B o6reu pacrBopa reM xe pacrBopI,ITeneM 100 u:r. flpu6antxror 0,5 r yurq aKTr{Br{poBaHHoro, nepeMerx[BarcT Ao B reqeHue 10 uun u Qu.rnrpyror. K Qu.rrrpary rpr.r HerrpepbrBHoM nepeMerrrnBaHvwr oh pacrnopa Harpr.rrrn.{poKcr4Aa (oxono npn6an;rrrcT AocraroirHoe KonuqecrBo I 60 un) Ao nonyqenux pH orono 1,5.

I 5 . 3 a K .2 7 6 8

@t

peaKTI{B Ar romnnnfl xJ'roplrAa (o6lo6) pacrBopayxcycHofr Ittzc2,0 r amourrnLrfl xnoprAa pacrBop{nr n 100 wn 5 o/o Jlorbr:reAqnoft B MeraHone. Arrorruuufl x,'roprrAacrrnproBofi pacrnop 5 7o BMecrHxnopuAa pacrBopmor e 40 N{r cnrrpra 96 % n uepuofi xo.rr6e 5 r amouprHrrs Mocrbro 100 u.rrrr AoBoArr o6relt pacrBopa reM xe cnuproM Ao MerKLI. A;rrouururfl xJIopHAac[r{proBbIfi pacrnop 2 "h 2 r antowunr{fixnopuAa pacrBop*or e 40 Narcilrrpra 96 % n nrepuoli xol6e BMecrI'IMocrbro 100 un n AoBoAtr o6lenr pacrBopa reM )KecllrproM Ao MerKrr. A.nrouHHHqxroprAa pacrnop 1 %o cnr{pra 96 % n uepHofi xo;r6e BMecru1 r a;nounHr{flxnoprrAapacrBopr}or s 40 N,{,r o6rerr pacrBopa reM xe cnuproM Ao MerKH. Mocrbro 100 HrnH AoBo.q.f,T 0105M) A.nrounnuff x,rroprrAa crr{proBbtfi pacrnop (orco.uo xnopr{AapacrBoprrcr s 100 Mn crrr4pra96 % 14 12,5 r aJrroMr{Hnf, AoBoAtr o6reru pacrBopareM xe cnuproM lo 1000,0un. llpoeepru rr4rpa He rpe6yercx.

(M.u. AuuAo-qepnrrfi 10B. C22H1aN6Na2OeS2. 616,5).[unarpux 5-aunuo-4rHApoKcr{-6-[(4-nurpo$euu.rr)a:o]-3-(Senuna:o)ua$ratmu-2,7-AncynsQonar. flopourox or reMHo-KopLIr{HeBoro qepHoro IIBera. Ao Ynepeuno pacrBopuM B BoAe;pacrBopl{M B cnrrpre 96 %. AlruAo-qepHoro LOB pacrnop 0r5 7o Pacrnop 5 rlt awuto-qepHoro 10B e cMecu pacrBopl{renefi 30 Yo yxcycuofi rucrrorbr- MeraHorr(10:90). n-Arrrroenrfi cnupr. Cn. [IenraHoJr. rI mp em - Arvrlr,roe fi crrrlpr. Cv'. mp e m-fleHru.u on sr fi cn npr. (M.pr. 130,19).Anunoerrfi:Qup yncycHofiKrcnorbl. Auu.nauerar. CH3COOC5H11. EecqserHa.f,rrpo3paqHatx{IrAKocrr c SpyxroBblM 3aIIaxoM. , u cMellrlrBaerct c eoAofi 0,18 : 100. Xopouro cMerurrBaerctc 3TaHonoM eQraporr.r;

d,i . o,gl9.
TennepamypaKuneHun Oxo,ro 148 "C. Arrunoaro6enso,'r.CrzHr 1N3.(M.u . I97,24). 4-(@eHuraso)auunuu. Zronrqarrre Kpncriurnbr Kop[qHeBaro-)KeJrroroc rory6onarblM orreHKoM IIBera. Mano pacrBopr{MB BoAe,JIerKopacrBopl{MB cnl4pre 96 % u e$upe. TeunepamypennarneHun.Oxono 128 'C. 4-AnrunoaHTrrrrupI{H. Cru. auuuollapa3onoH. 4-AuuHo6ensofinaq Krrcrlora. C7H7NO2.(M.vt. I37,14). Kpucra-nnr,rqecxufi [oporroK 6eroro uBera. HepaMano pacrBopuMa B BoAe,JrerKopacrBoprrMaB cnr,rpre96 oh, [paKTIzqecKLr sQupe. crBopnMaB nerpoJrefisorr,r Teunepamypanra6r eHun. Oxotto 187'C. Xpanrr B 3auruqeHHoMor cBera Mecre. 4-Aunno6ensofiHofi KrrcJrorbrpacrBop yrcycnofi xucnorrr 6egrucnoru pacrBoprror B cMecrz18 rran 1 r 4-arraHso6eHsofiHofi u no4nofi, 20 wl BoAbr 1 ur QocSopuofi rucnorrr KoHIIeHTpI{ponaHuofi.

c nonyqeHHurl pacreop cMel[I4Baror aIIenepeAr{crroJrb3oBaHr,reM Henocpe4crBeHHo (2:3\. roHoM 2-Arvrnno6engofiHaqKrrcJrora. C7H7NO2. (M.r"r. 137,14). AurpauuloBat KrrcJIOra. KpucrarrH.recxnfi noporxoK or 6eroro Ao 6leAno-xenroro uBera. VuepeuHo pacrBopr4MaB xonoAHofi soAe, JrefKo pacrBoprrMa B rop.flr{eil eoAe, crrr{pre96 oh,:Supe n rnuqepl4He. o6HapyxnBalor Pacrnopu B cnr,Ipre96 % uru e$upe r e oco6eHHocrlrB rnI4IIepHHe Quoneronyro QnyopecueHuuro. 'C. TeanepamypannazreHun. Oxono 145 Auuno6yraHoJr. C4H11NO.(M.vr. 89,14). 2-Aunuo6yraHon. crb. Macn.sHucrat xfl.InKo CMeurzsaercqc no4ofi, pacrBopl{Me 96 oAcwlpre.

4]i . Oxolo0,94.
n', . Oxolo 1,453. Teunepamypa KuneHunOxoro 180'C. 6-AnunoreKcaHoBaq KlrcfloTa. C6H13NO2.(M.u. l3l,l7). 6-AunnoranpoHoBat Kr{cnoTa. EecqeerHrreKpncraJrnbl. HepanpaKTl4qecKu B Jlerro pacrBoprrMaB BoIe, yMepeHnopacrBopr4Ma MeraHoJIe, crBopl{MaB 3TaHOne. TeanepamypaMartreHun. Oxono 205 "C. AunHoruApoKcnnaQra.nuucy.trQouonafl Krcrlora. C 1sHgNOaS. (M. lr . 239,24). 4-Auuno-3 -rlrgpoxcnua$rarun- 1-cyrrQoHoBaq Kucnora. cBera npuo6peKpr4crannrr6enoro anu ceporo rrBera,noA .ueficrBueM tr4ronr.rarure Taror posonufi uBel s oco6eHnocrl{ BJra)IGbIe. u B flparruuecKrz HepacrBoprrMa BoAe,cnllpre 96 o/o oQupe,pacrBopl{MaB pacrBopax pacrBopax Harpl{s.weta6ucylr$Hra. il MeraJrJroB ropttrl4x urenoqHbrx rr{ApoKcr4AoB Mecre. or Xpauxr B 3axrHIqeHHoM cBera ArrnnoruApoKcuHaQra,ruHcy,rrQononofi KncJIorbl pacrBop ClreurHsaror 5,0 r Harpnfl,cynrQura 6essoAHoro,94,3 r Harpuq rnApocynbSura u rHcroru. 1,5 r [onyqeHnofi cttecH pa0,7 r alrnHorr.rApoKcr{Ha$raruucynrQouosofi Ao crBoprror B BoAer{ AoBoArr o6rerr pacrBopa reM )KepacrBopplTeneM 10,0 u.n. - I cyr. Cpox roAHocrrr pacrBopa Kucrlora. C9H10N203. (M.r"r. 194,19). (4-Aunno6eHgAnnHorurrypoBaq auu4o)yxcy clnar Krrcnora. lloporuox 6eroro r{JIIrrotrrrr 6e,corouBera. pacrBopuMa B pacrBopr{Ma BoAe,pacrBoprrMa cnrrpre 96 o , oqeHbMaJIo B Yrr.repenno n eQupe. 200 "C. TeunepamyparuarreHua. Orcono Aunnorunnyponofi KucJ'IorbI peaKTr{B pacrBoptrcr B cnl4pre Kr{cJIorbI 3 r $ranenofi xlrcnoru u 0,3 r aMr4Horr{nnypoeofr 96 % lr AoBoMr o6relt pacrBopa reM xe pacrBopl4reneM 100 ul. Ao KncJlora. C19Hl5NOB' 2H2O. AuuHonerl{JlaJru3aprHAlryKcycHafl (M.r. 421,4). 2,2' -l(3,4-,{urn4poxcuaHrpaxpruori-3-zn)Merr4neHHurprano]auyxcy cllas. Kr{cJroTa, rrApaT. Auf

uetr

nopouroK or cBerJrofoKoprlqHeBaro-)KeJlTofo opamKeBoMemoxpr.rcrulJrJrrrqecxufi Ao Kopt4rrHeBoro rIBeTa. IrIeJIoqB B flparrnuecKrr HepacrBopr4Ma BoAe,pacrBopr4Ma pacrBopax rr4ApoKcr{AoB
HbIX METILIIJIOB.

Teunepamypanna*reHun. Oxolo 185 'C. He Ilomepn B Macce npu 6btcyu,tu6aHuu. 6o-rreeI0,0 yo. Onpe4eneHne [poBoAtr

us 1,000 r KncJrorbr ArrnuouernJraJrrr3aprrHArryKcycHofi pacrBop

xucnorbl pacrBopflIor n 6 rr.rn cBe)Kenpu0,192 | aMr4HoMernnaJfiBaprrHAr{yKcycnofi rtpu6antqrcr 750 MJIBoAbI,25 un roroBJreHHoro M pacrnopa Harput rLIApoKcHAa, 1 0,5 cyKrlnHarHoro6y$epHoro pacrnopa pH 4,6 u no KaTIJIIM M pacrBop xnoprcroBoAopolHofi xlrclorrr Ao r{3MeHeHuq oKpacKr{pacrBopa or Quoreroeo-xpacnoil 4o xerrofi (pH or 4,5 go 5), sareu upu6annxrcr 100 Mn aueroHa Ir AoBoAtr o6teu pacrBopa eoAoft ao 1000 un. KncJIorbI peaKTIIB ArrHHouerr{JraJrrr3apnHAr.ryKcycHofi qepux(Ill) nurpara pacrBoprrcr B BoAer{ AoBoArr o5relt pacrBopa Pacrnop I. 0,36 r TeMxe pacrBopr4TeneM 50 u,r. Ao Kr{cJIorbIcycrleHAl{pyror B Pacrnop II. 0,7 r aMHHoMervranvsapr{HAr.ryKcycuofi KoH50 rrair BoAbr,npu6annxror Ao pacrBopeHr4roKoJro0,25 un pacrBopa aMMI{aKa rleHTprrpoBaHHoro, 3areMnpN6an;rxrot0,25 Mn yKcycnofi xrEc;rorrrreAssofi Ir AoBoAqr o6reN{pacrBopa soAoil ao 100 un. BoAbr, npu6annnor 11,5 Mn yKPacrnop III. 6 r Harpvs auerara pacrBoprrcr s 50 MJr reAssofi rr AoBoArr o6rela pacrBopa soAofi ao 100 rra,c. cycnoii Kr{cJrorbr K 33 rran arleroHanpu6auarot 6,8 ur pacrBopaIII, 1,0 Mn pacrBopaII, 1,0 run pacrBopa I u AosoAqr o6senrronyrreHHoro pacrBopa no4ofi ao 50 run. K ItlcnatmauueHa qyqcmsumerbHocmb. 1,0 nr sTanoHHoropacrBopa Qropnaa (10 pprn F) npn6aursror 19,0 u:r BoAbr 5,0 Mn peaKrrrBa u aN{r4HoMerr{nanll3apl4HAr4yKcycHofinucnorsr. 9epes 20 rrrns AonxHo norBr4Tbcqrony6oe oKpaI[IrBaHrIe. Cpox roAHocrrr pacrBopa* 5 cyr. 1-Auuso-2-HaQro,r-4-cynrQoHoBas Kucrrora. C I 0H9NO4S.(M.vr. 239,2). Kpncran.rru or 6eroro Ao xeJrroro rlBera. Jlerxo pacrBopprMa BoAe,pacrBopuMaB 3TaHoire. B 242,23). 2-Arvruno-5AuHnonnrpo6eu:o$enoH. Ct3H10N2O3. (M.u. nurpo6ensoSenoH. Kplrcra.n:ur.re cxufi noporrroK)KeJrrofouBera. pacrBop}rMB TerparrApotpypaue, M&rIopacrBoIlpaxruuecKr{ HepacrBoprrM Bo.qe, B pHMB MeTaHOJre. Te-,vnepam1'pa H,ta6iruun. axoto I 60'C. rrpoBoAqr npu AnHHe BoJIHrI 233 nu, HcIroJIbA't".r,t'".Or690 rc 720. Onpe4eneHue 3yfl pac'rBop0,01 rh s r\4eraHoJre. Aunsouupa3oJroH.Cl1Hl3N3O. (M.u. 203,24).4-Arvruno-2,3-ruwerlrn-1-Qeuu,'r-ou. rrurpa3onuH-5 4-AuusoaHTunrrpuH. Irlronl.rarsr e Kprrcran rrbrrurv nop o [roK cBerJro]rceJrrorouBera. pacrBoprlM B B Yuepeuuo pacrBopr{MB BoAe,nefKo pacrBopr4M c[rrpre 96 o , MaJro eQupe.

w,

Tennepamypa nnaBneHun. Oxotro108"C. pacrBop 0rl o/o. A*runonnpa3oJroHa pacrBope 9,0. pH PacrnopI r/n s 6y$epnorrr Aprnnono.uueQnp. (M.u. 376,49).4,7,I3,16,2I,24-fetcca-orca-1,10Cl8H36N2O6. Auasa6wturno[8,8,8] rexcaroraH. Becqneruu e KpncraJrJrbr 6enrrfi Kpr,rcranJrn.r rrJrr.r ecxufi noporxoK. Hepacrnopr.rMBoAe, pacrBoprrM crnpre 96 %. B MilJro B Teunepamypa Ma*reHua.Or 70 rc 73'C. (M. 7 3-AruunouponaHoJr. C3H9NO. r"r. 5,I I). 3-ArrannouponaHI -ol. flpospauHax, 6ecqne rHafl,Br3Kar)KHAKocrB.

d',i . o*oro 0,99. nll . Oxono 1,461. Tennepamypa nna*neHun. 11 Oxono 'C. (M.ru. 10). p-AnaHraH. 3-ArvruHonponr{oHoBafl KncJrora. C3H7NOz. 89,
Cogepxxr HeMeHee % C3H7NO2. 99 Kpucrarnuqecrlrfi noporxoK 6eroro rlBera. JIerxo pacTBopr4MaBoAe, pacrBoprrMa crrrrpre96 o/o, B MaJro B [paKTr4qecKr{ HepacrBoprrMa arreroHe s$upe. B u Tennepamypa nna*neHun. Oxono200 "C c pa3noxeHrreM. AunnoyrccycuanKuc,.rora. H2NCH2COOH(M.u. 75,07).Lnuxorol. lnuquH.
Eenrrfi KprrcraJrnr,rqecxufi [oporuoK. Jlerxo pacrBopr,rMaB BoAe; HepacrBoprrMaB e$upe; oqeHb N{aJro pacrBopnMa B cnrrpre 96 %. Teuneparnypanna*reHua. Ottc.to 234'C c pa3noxeHueM. AnrunoyxcycHas 6yQepuan cMecb Pacrnoprror B BoAe8,4 r uarpHr rvApoKap6onara, 10 r ra-nzs rn4porap6ouara,7,5 r aMr{HoyKcycHofi xnclorur,4 Mn pacrBopa aMMr4aKa KoHrleHTprrpoBaHHoro H.uoBoArr o6reu pacrBopaeoAofiao 100,0nrr; pH oxolo 8,3. 4-AuunoQenor. C6H7NO. (M.u. I 09, 13). Fe.nufi HnHcJrerKa oKparxeHHrrfi xpncrairJrlrqecKrrfi nopouor. pacrBopr4M BoAe,pacrBopr4M STaHo.rre. VruepeuHo B B Teunepamypanra*neHua, ONono 186 "C c pa3noxeHr{eM. XpaHrr B 3arrlr4rrleHHoM cBera Mecre. or AmnHox.itop6eHroQeHoH. C13H1gCNO.(M.r"r.231,68).2-ArvrNno-5-x-rrop6eu:oSeHoH. Kpucrariru.recxnfi noporxoK xenroro rrBera" llparruuecKi{ HepacrBopr{Nr BoAe, JrerKo pacrBoprrM B arlerone, pacrBopuNr B B cnlrpre 96 %. TeanepamypanraBnerus. Crono 97 "C. Xpauxr B 3auIXrIer{HoN{ cBera Mecre" or A*r*rnar noAnrIft. Anr*ruara pacrBop noHrlenTpr{poBarrnbrfi25 %, NH4OH ih{.u. 35,05). Co4epxur or 25 Ao 28 9'o NH3. Secqeernar, npo3par{Har xira4Kocrbe xapaKTepubrM ocrpr,rM(pe:runr) sanaxolr. G6paruaTbcrc ocropox{Hocrbro. AmuHarca pacrBop. Cogepxur He MeHee 17 % (i70 ri,r) H He 6oree 18 % (180 r/n) NH3 (M.u. fi,A3).

KoHueHrpr,rpoBaHHoro 67^r pacrnopa aMMr4aKa AoBonxr noAofi Ao o6reua 100 u:i.

d," . or 0,931 0,934. to

)Kecorep)KaHl4e s Avuaara pacrBop, ucnonb3yenaHfr ucrrbrraHr{rrHa npeAeJrbHoe cneAyrouee AolonHrrreJlbHoe rpe6onauue: 5 lr.rrpaBbrAepxr4Barb Jre3a,AoJrx{sH Bbrnapr{Balor Ha soA.f,uofi 6ane 4ocyxa. K cyxonry ocrarKy crBopa aMMr4aKa rncloru, 0,1 tul rIrofJIHBoAbr, wItr20 o/opactnopa JrpIMoHHofi 2 npu6auxror 10 Hr.n r{ xo:reeofiKr{cJrorbr pacrBopaaMMrraKa nlenoiruofi peaxql4l,I, AoBoAtr o6telr noAo n nyqeHHoropacrBopaeoAofi rc 2A Mn. Pacrsop He AonxeH oKpalrruBarbc.f,posonufr
UBCT.

20 XpaHxr [pr.r reMneparype HI{}I(e "C,3au]I4lrlat or yrnepora ArroKct{na. Auulrarca pacrBop l0 " KoHueHrpr4poBaHHoro 41 r pacrnopa aMMHaKa AoBoA.rrsoAofi Ao o6relta 100 u.n. Au*ruaxa pacrnop 5 %o pas6aultror no4oti Ao 1000,0 u.rr. 500 nn l0 o/opacrBopaaMMHaxa Auuuarca pacrnop 1 7o KoHueHrpnpoBaHHoro 4 r pacrnopa aMMr4aKa AoBoAqrsoAofi Ao o6reua 100 ul. oh. CoaepKLIrHe MeHee3,3 % (33 r/:r) u ue Anunaxa pacrBop pa3BeleHnufi 3 6oree 3,5 o (35 r/rr) NH3 (M.u. 17,03). soAofi Ao o6reua 100 wt. KoHueHrpupoBaHHoro.uoBoAqr 14 r pacrnopa aMMuaKa 0118"/o. Cogepx(Hr He MeHee0,16 oA Arrnruara pacrBop pa3BeAeHHsIfi (1,8 r/n) NH3 (M.nr. 17.03). (1,6 r/n) n se 6o.iree 0,18 o/o KoHueHTprrpoBaHHoro 0,7 r pacrnopa aMMr4aKa AoBoAqrsoAofi Ao o6reua 100 ul. 32,0o4 (uht) %o. AunrHarcapacrBop r{oHrleHTplrpoBaHHbrit32 Coaepxl4r He MeHee N H 3( M . u . 1 7 . 0 3 ) . llpo:pauuaq, 6ecqnerHat )KnrKocrb. d'', . Ot 0,883Io 0,889. xuconpede:teuue.50,A lrn 1 M pacrBopa xnopl4croBoAopoAHofr. Ko"tuqecmneHHoe npu6aBJr.f,ror JrorbrnoMerrlarorn non6y c npr{Teprofi npo6rofi, touno B3BeIIrr{Baro1 Turpyror I M u KoHrIeHTpr{poBaHHofocHoBaB3BellrrrBaior. 2 w pactnopa aMMr4aKa 0,5 HcloJrb3yqB KaqecrBel{HArrKaropa lrrr cMelrraHpacrBopoM :aarprts, rr4ApoKcr{.rla, HOfOpacrBopa Merr{noBoroKpacHoro. xucnorbl coorBercrByer 17,03 rur NH3. 1 un 1 M pacrnopa xiropucroBoAopoAHofi Xpauxr [pr,r reMneparype He BbIIrIe20oC,3arII4rIIat or yrJlepoAaAvoKcvra. Auuuarca pacrBop 1315M pa:6annxror eo.uofiao 1000,0 trl. Bo.qHoro 920,0 MJraMMr{aKa pacrBop 10 M Arrrnrnarca BoAHoropas6annxroreorofi Ao o6re*ta 1000,0 rran. 681,2 Mn aMMr.raKa Aunrnaxa pacrnop 6 M soAofi Ao o6rerta 1000,0 un. BoAHoropas6ann.sror 408,7 Mn aMMrraKa Aunrnarca BoAHo-cnnpronufi pacrBop c cMerxrrBalor 9 rral crll4pra 96 %. KoHueHTprrpoBaHHofo I nr pacrnopa aMMr{aKa Arrr*rnaqnufi 6yQepnufi pacrnop 54 r arvruoHnrxnopr{Aa pacrBoprror B BoAe n uepnofi ror6e BMecrllMoctrto I ;r, t4 KoHrIeHrpL{poBaHHoro AoBoAqr o6rett npu6auruor 350 Mn pacrBopa aMMr,raKa pacrBopa soAofi Ao MerKr{.pH nonyueHHofo pacrBopa or 9,5 ao 10,0.

Annronnii a3orHoKr{srsrfi. Cu. AuuoHrrfl Hrrrpar. Anrlronnfl arlerar. CH3 COONHa(M.rr,r77,09). Alruouufi yKcycHoKr.{c.rrufi. .
6e cqsernue Kprrc'ranJrbr, orreHbJrefKo paclnbrBaroqnec-flHa Bo3lyxe. Oqesr nefKo pacrBopr{MB BoAer{ cnr{pre 96 %. Xpauxr B Bo3AyxoHerrpoHrrrraeMoM roHrefi uepe. oh AuuoHus aqerara pacrBop 15 150 r alrlroHruI allerara pacrBop*or B BoAe,rpu6an:r-aror 3 lrr yxcycnofr Kr4cJrorbr Jrep:'rtoit H AoBoArr o6reu pacrBopa sorofi ao 1000 u-n. Cpor foAHocrn -7 cyr. AMMonuq auerara HacbrrrleHHufipacrnop Pacrnopxror.rlocraroqHoeKorurqecrBo yKcycHoKucnofoB BoAeAo nonyqeaMMoHHr o aMMoHr{ryKcycHoKvcJroro. Hr{r pacrBopa, coAep)Karuero MeHee61,5 He AMMonHq auerara HacbruleHnuft pacrnopo uefirpaJrn3oBauHrrfipacrBopoM HaTprls rrrnpoKcnna AnrnaoHnq pacreop Hefirpa,u43yrorcHarrara30 % pacrBopoM auerara HacbrrueHHrrfi Harpfln rlrrpoKcl4Aano po3oBorooKparuuBalnvr QeHo.n$TaneHHy, no 3areMr.is6rrrox FiATPI4' |I{,IPOKCIUIA UCITTPAII{3YIOT HACbIIIIEHHbIT,I AMMOHV' AUCTATA AO PACTBOPOM cria6o-po:oBoro oKpaixnBaHu.fl . Ampronuq BaHaAar.NH4VO3. (M.u. 116,98).AMMoHpr.fl (V). rpproKcoBaHaAar Avruosuii BaHa.ilueBor<uc:rlrfi Mera. Alrinlorius BaHanarNrera. Kpucrar.rru.{ecxktfirroporxoKor 6eloro .qocnerKa xeJrroBarofo uBera. Ma.nopacrBopr4M Bore. pacrBopr.rM l0 oApacrBopeaMMHaKa. B s oh Arrprorrllq BaHaAara pacrBop lr2 1"2 l antltoHnfl Banalara pacrBopflror n 95 lr,r Bo,[brr.rAoBoAqro6leu pacrBopa cepuofi ruc:rorofi ronueHrpupoBaHuoii lo 100 nr.rr. Auuonus BanaAara pacrBop 0rS o/on cepHofi Knc!'roreKoHqeHTpuponaHnofi pacrBopqror n 10 ur cepuofi Kr4clTorbr 0,05 r aMMoHn.f, BaHaAara KoHueHTpHpoBaHHofi. Anrnronuq rrrApoKap6onar. NH4HCO:. (M.vr. 19,06). Co4epxlrr He MeHee99 % NH4HCO-l. EecueerHrre Kpr.rcranJrbr 6eluii Kpr{criunnqe crufi nopotrroK. [Jrr{ Ilemo pacrBopt4M xonoAHofino4e, pearr.rpyere ropruefi Bore, npaKTuqecKr{ B HepacrBoprrMB cnr{pre 96 % r{ arleroHe. AMMoHHqaurnapoQocQar. (NH4)H2POa.(M.n. 115,03).ANrMonu-s $oc$ar oAHo:aruerterisuil. Kpucrar:ru.recxufi nopoixoK 6eroro rlBera uJru 6ecueerHbreKpucrannbr. ,llerxo pacrBopr{MB Bo.{e. pFL Oxono 4,2 (2.3 % pacraop). ( 1R)-(-)-AMMoHnn I 0-rcauQopocy"rnQonar.C 1 I eNO4S.(M.r"r.249,32). sH CogepNrar MeHee He 91,0 oh C10H19NO4S. Becueerulle Kpr{cranrrbrurr*t 6enrui Kpacrannn.{e crnfi [oporxoK. Ilerr<o pacrBopr4M Bo.ue, yMepeHHo pacrBopr4N,rcnrrpre 96 %. B B ,(5 o/o pacrnop). lal .18 "+ 2 (NH4)2CO: (M.rtr.96,09). Auuonufi yueruc.nufi. Annroung rcap6oHar. SecqnerHue MeJrKrre Kprrcrannbr,B Macce6eroro rlBera.

B Oqesr nerKo pacrBopr4M BoAe,pearr4pyern ropxuefr BoAe,[paKTurrecKuHepacrBopr{M B cnr{pre 96 % AnMouHq rcap6ouara pacrBop l5r8 oh. Pacrnop 158 r/.ri. AMMonrq rcap6ouara pacrBop l0 o BoAbr,uplr6auxror 10 lr.rr l0 o/opa10 r arruonux rap6oHara pacrBoprror n 30 rran pacrBopa eoAofi ao 100 rran. crBopa aMMrraKapr AoBoA{r o6rerr,r pro.nn6Aar. (NH4)6MotOzq' 4H2O. (M.r"r. 1235,9).Anuonufi nolu6leAnMonHq nosoxr4cmrfi. EecqserHrte Kprrcranrrbrvtrrt Kpllcrannbr or cJIerKa)KeJrroBaroro 3eJleHoBarofo ro uBeTa. HepacrBopr{M crrrrpre 96 %. B Pacrnopuu B BoAe,rrpaKTuqecKrr pacrBop l0 o . Pacrnop 100 r/.rr. AnMonlrq nro,rn6Aara AMMonuq nonH6Aara pacrBop (pH 7r0) pacrBopqlor rtpu HarpeBaHr{u 30 MJIBoAbI,3areM oxn 5,0 r arruonur rrao.nn6Aara pBBeAeHHbIM o/o,o6reM no3 na)K.uaror AoBoArr pH ao 7,0 pacrnopoM aMMI4aKa 14 pacrBopaAoBoAflT soAofi.qo50 un. nyrreHHoro u6Aara crrrrproBofi cepnoxuc,rnr fi p acrBop AM Monuq *ro.ir pacrBoprror npr4 HarpeBaHvIrr 20 NarBoAbI. s N,roru6Aara Pacrnop I. 5 r arr,rrraoHras 150 na:rcrurpra 96% co 150 Mn BoAbLlIpN oxnaxAeHl{I4 Pacrnop II. Crr,relrHBarcr KoHrleHrpr{poeauuofi . npz6aenxror I 00 u.rrcepnofi KucJrorbr K Heuocpe4crBeHHoilepeA rrcnorrb3oBaHr4eMpacrBopy I npu6aBJr{rorpacrnop II n coorHorrennu 20:80. AlrrroHlrq lro,rn6Aara pacrBop B arleroHe pacrBop.rrror BoAe,AoBoA-f,T )KepacrBopl.{TeneM B TeM 1,0 r alruonu.s r.ro;ru6Aara Ao xnc.rrorsl r.rAoBoAtr o6reua 40 lrr, npu6anr*or 3 n,r 25 % xnopr{croBoAopoAHofi pacrBopaarleroHoM 100lrn. o6sen ao B 3arrIHrueHHoM cBera Mecre. Xpanrr or 1lrec. CpoxroAHocrr{AuuoHlrs lro.nn6Aara pacrBop s 15 o cepnofi KrrcJrore pacrBopsror e 40,0 rr,rn % (o6lo6) pacrBopacepuofi ttzc15 1,0 r anuonz-s N{o,.ru6Aara . JrorbrKoHueHTpr.rpoeaunofi CpoxfoAHocrrr- I cyr. no ArrMoHuq rrorH6Aara peaKTHB.llocregoBareJrbHo cMerxuBaror I o6reuy 2,5 oA o/opacrBopa acxop6uuosot rzcrorst u 29,45 Yo pacrBopa aMMoHHruonu6Aara, l0 pacrBopa cepnofi Kr{cJrorbr, 3areMnpu6auxrcr 2 o6renaaBoAbI. Xpaum no Qnarouax oparuKeBofo creKi.ra. Cpor<foAHocrr4- I cyr. (pearpacrBop n cepnofi Kncr'roreKoHrleHTprrpoBauHofi Auuonns nro.un6Aara run Opege) KoHrIeHrpHpo0,1 r anruoHnr r,rorn64ara pacrBop.f,rorB 100 w cepuofi Kt4cJrorbr saHHoit. Xpanrr e 6anKax opaHxeBoro creKJra. Cpox roAHocrr{ - 6 rr,rec. AMrrronuq uo.un6Aara pacrBop s a:orHofi KucJrore Pacreop*or 6,5 r MenKopa3Apo6reunofinro:rn6AeuoeofiKucJrorbrB cMecu 14 nrn pacrBopa KoHueHTprrpoBaHHoro. Pacrsop oxnaxAaror I{ rroBoAbr 14,5 MJraMMr{aKa u pacrBopa npra6annxrorK cMecu 32 wt oxJra)KAeHHoro crerreHHorrpn nepeMeLrrvrBanvru

EZ

LI u BoAbr ocraBr-srct sa 40 q, 3areMpaa3orHofi KncJrorbrKoHueHTplrpoBaHHofi 40 rvr.rr pacrBopa Bbl.uenrrrct crBop Sunrrpyror r{epe3nnornufi Qn:nrp. Ecru rpr xpaHeHr.rn atluei't. ocaAoK,ero orAerqror AeKaHT AprMonuq Hrrrpar. NH4NO3. (M.r"r.80,04). Kpucra,l.nxqecxufi [oporroK 6eroro rlBera uru 6ecqserHbreKp]rcrannbl; frrrpocKofIVqEH.

Oqesr .rrerKopacrBopxM B BoAe, nerKo pacrBopr{M B MeraHone,pacrBopuM B cnrpre 96 %. xourefiuepe. Xpauxr B Bo3AyxoHe[poHr4rlaeMoM ' HzO. (M.r"r. 142,12).Alruonzfi rIaBeneBoKLIcAprMonrq oKcaJrar.(COONH4)z

.nsrfr.
BecqserHrre Kpprcra^rrmr. PacrsopuM B BoAe. pacrBop 4 o/o.Pacrnop40 r/.lr. AMMonrq oKcaJrara AlrMonuq uepcynrQar. (NHa)2SzOs. (M.u. 228,20). Aurraonufi HaAcepHoKuctr:r,rit, Eenufi Kprrcrannu.{ecxufi[oporroK. Jlerxo pacrBop]rMB BoAe. AMnonuq nepcy.nrQara pacrBop 20 oh B 20 r anuoHuq repcynrSara pacrBop.rrrcr Bore r4AoBoAtr o6reu pacrBopa soAofi ao 100,0 Nrr. Pacrsop AonxeH 6urr cBexerrpl4roroBJreHHblM. (M.ru. |64,29). ANlMonn-s Aprvronus rrppoJlrlAl{HAlrrrloKap6auar. C5H12N2Sz. 1- n npp o.rrn 1vnun 1r4rxoS opuar. Kpucra:rnxqecxufi flopouroK or 6eroro Ao cBerno-]KeJlToro uBera. pacrBopr,IM cnnpre 96 %. B Vuepeuuo pacrBop[M B BoAe,orreHbMzIJIo XpaHar s xoHrefiHepe,coAepxaueM se6onruroe Kor[qecrBo aMMoHuxxap6ouara n
IIOJIOTHfl HOM MEIIIOqKC.

Aunouuft ryprypHorcnc.nrrfi . C8H8N6O6'HzO. (M.vr. 302,20).Myperor4. Ananaofi HlaeBafl.om 5,5' - nr.rrpxnoAr{6 ap6ury p oBo ru crorbl, MoHofulp ffi . c KpacHo-Kopl4r{HeBoro MelxorpHcrarrnr{ecxufi nopouroK nypnypHo-KpacHofo r4Jrrr MeraJlJrrrqecKraM 6necrou. rlBera c xapaKTepHbIM 3eJreHoBarbrM pacrBopr4M BoAe. Mano B c llpu pH > 11,0 pacrBop MypeKcr.uarrMeer Suoneronyro oKpacKy,a efo KoMrIneKc rroHoMKanbrlr{r B Tex xe ycnoBr{rx opaHxeBoro uBera. r r{oHoBKiulbl{uflor opaH}Kesofi Quonellepexo4 oKpacKrr npn [prMoM Tr.{TpoBaH}rr{

rosofr.
H IrIudurcamopHafl cMecb. 0,25 r rrHArrKaropa 25 r uarpl4q xnoprAa pacrl,Ipalor B crynKe r4nepeMerxr{Baror. Anr*ronnq pefinercar. NHalCr(NCS)4NH3)zl ' HzO. (M.*. 354,44). Al,rrraonrqrerparr{o{i{aHaroArraMr{H xponaar(Ill), uoHorn4par. KpacHoroIIBera. floporuor r4nnKpr{craJrJrbr B no4e, pacrBopr{Mn ropxuefi BoAer{ cnr4pre96 %. VuepeHuo pacrBopr4M xoJroAHofi pacrBope pa3naraerc{ c BbrAeJreHr{eM BoAopo.IIa ceo6oAHoroqrraHr.rcroro B soAHoN{ (ocropoxno!). pefinercara pacrBop I o/o.Pacrnop10 r/n. ANrnroHHq forosqr Herro rrepeAr4crronb3oBaHr{eM. cpeAcrBeHHo Aprlronufi poAaHrrcrrtfi . Alruonllfl poAaHul. Cv. Alrpronnq rnouuaHar.

EEE

AMMonrq poAaHnAapacrnop 5 7o 5 r aulronlafl.po1ankr4a(anruoHuflTvto\uaHara) pacrBop.rrlorB Bo.{e14 roBoA-sr o6t,eu pacrBopa. AM*ronus cy,rr$auar. NH2SO3NH+.(M.u. 114,12).Auvoslrfi cynr$arranHoBoKl{crufi . AuuoHr{t cynbQarraunar. KpNcra:ulr.{ecxufi [oporxoK 6eroro rlBera urpr 6ecuserHbreKpvcrannbr: rr4rpocKoilI{qeH.

pacrBopr4M crrripre 96 %. B B O.{eur nerKo pacrBopr4M Bo.[e,MaJro Te.unepamvpa nlaz:teHua. Oxolo 130 "C. r<oHrefi Hepe. Xpanxr B Bo3.qyxoHenpoHr{rlaeMoM AMMoHun cynrQar. (NH+ )zSO+.(M.r'r. I32,14). Annaosrfi cepuoxuc:rufi. BecueerHrre KpH cran rrbrrurrt rpaHynbr6e:roro rrBera. B HepacrBopuM aueroHeI{ crlnpre 96 o,1o. B O.{eur nefKo pacrBopr4M Bore, [paKTlrqecKu pH. Ot 4,5 [o 6,0 (5 % pacreop). He C.v.tuQamuafl 3o.7a. 6onee 0.I %. poAaHr{A. AMnoHr.rqrr.rourraHar.NHa SCN. (M.lr. 76,I2). AnrMoul.rq pacrrJrr,rBaarur4e Ha Bo3Ayxe. 5e cuserurre KpH cranJrbr, cfl. pacrBopnMB cnr4pre96 %. pacrBopr4M BoAe, B Oqens JrerKo noHrefiHepe. XpaHrr B Bo3nyxoHerrpoHnqaeMoM AMMoHraq rr{oqr{aHara pacrBop 716o/o.Pacreop76 rln AMnoHuq Qopuuar. CH5NO2.(M.u. 63,06). Pacn.lrlrsarouluecrKpucrannbr vrrv rpaHynbr. O.{eHr JrefKopacrBoprrMB BoAe,pacrBoprrMB cnr4pre96 %. Tetmepamypa n.loz:reHun. 119 ao 121 "C. Or xoHreftuepe. XpaHn B Bo3AyxoHerrpoHr4uaeMoM AprlroHuq SocQar. (NH4)2HPOa.(M.ru. 132,06)..{uaunoHux ruapo$ocQar Kpncra:u br prilprrpaHynbr6e.norouBera: rnrpocKorrnrreH. HepacrBoprrM crrnpre 96 %. B O.{eHr nefKo pacrBopr{MB BoAe,[paKTr4qecKn p1L Oxo:ro 8 (20 % pacrnop). r<oHrefi XpaHrr B Bo3AyxoHerpoHr4rlaeMoM Hepe. AMnrouuq xroplrA. NH4CI. (M.u. 53,49).Annrosufi xropucrufi. Berufi KpncrannnqecxnfinoporxoK. Jlerro pacrBopr{MB BoAe,pacrBopuM B c[Hpre 96 %. pacrBop l0r7 o/".Pacreop I07 rln AMMonuq xJroprrAa pacrBop l0 o AMMouuq xJroprrAa l0 r anrlroHrrr xnopuAa pacrBopsror B Bo.uer4 AoBonrr o6reu pacrBopa soaofi

un. ao 100,0
AMMonr.rqqepua(IV) Hurpar. (NHa)2Ce(NO:)0.(M.rr. 548,2). Kpucra:uuqe cxlrfi noporxoK opaHxeBo-x{enrororlBera Hnr4 npo3par{Hbre Kpr{crannbl opaHxeBofouBeTa. PacrnopltruB Bone. '2H2O. (M.u. 632,6). Anruonns qeprr(IV) cy;rnQar. (NHa)aCe(SO+)+ Kpucrarruraecxrrir noporxoK Hnr,rKpr.rcraJrJrbr opaHx{eBoro-x{enroro uBera. MeAresso pacrBopr4M BoAe. B Annonng rlurpar. C6HI 4N2Oz.(M.u. 226,19).,{nanruoHuqruApour4rpar.

Apruonufr r'IHMoHHorcuc.nrril fi rIHTparABy3aMeuIeHABv3aMeilIeHnu . AMNToHH' sufi. Kpucralrn u\e crcufa noporrroK6eloro uBera Hllr 6ecunerHbreKpncrannbr. Jlerxo pacrBopprM BoAe,MaJro pacrBopr{MB crrr{pre 96 %. B pH. Oxorc 4,3 (2,26 % pacrnop). Aurn4pn4 yxcyurufi. Cnt. VncycHsrfi aHrr{AprrA. Anrr.r4pula yKcycHoro pacrBop 12 oh (o6lo6) s 6e:soAHoMrruprrArHe 12 wt yKcycHoro aHrvEpHJ\a cMerrraBaror 88 un 6e:eo4Horo rruprrAaua. c Xpanxr e 6aHxax opaHx(eBoro creKJra npureprulru npo6KaM[. c Aurn4pH4 Qra,renufi. Cn. (Draresrlii aHrHAprrA. AHero,r. C 10H I 20. (M.rr. | 48,20). 1-Meroxcir-4-(npou- 1-H.rr)6eH:on. Kpucra.ruuqecKar Macca 6e.norouBera npn reMneparype rc 20-21 oC, npz reMreparype Bbrrrre 23'C - xr{nKocrb. llpaxru.recKu HepacrBopuM Bo.ile, pacrBoprrM sTaHoJre, B -rrefKo B :$irpe, 3TanaqeTare rr rrerpoJrer"rHonr oQupe. d,, . Oxolo 1,56. TeanepamypaKuneHti"z. Oxo"no230 "C. qr{cro'ra aHeroJra, XpoltarorpaQu.re cnat ucnonb3yeMoroB ragosoii xpoMarofp a$uu, 6rrrr He MeHee 99.0 Yo. AoJr)KHa (M.vr. 148,20). (Z)-1-Meroxcu-4-(nponeHHn-1)-6eH:o:r. C1sH120. 4uc-Amero,r. Kpucra,r"ur{rrecKar Macca 6e,qororrBera rrpu reMrreparypeN 20-21 oC, npu reMleparype Bbrrrre 23'C - )KpuKocrb. flpaxrnuecKn HepacrBopnr,r BoAe,:rerKo pacrBopuMB 3TaHo,qe, B pacrBoprrM a$xpe, n 3rr{nauerare r4nerponefiHopre$upe. n'i . Orcoto1,56. TeunepamypaKLtneHun Oxolo 230 "C. XpouarorpaQuvecxar r{Hcrora quc-aHeroJra, uclonb3yeMoro B ra:osofi xpoMaroo/o. rpa$uu, ronxHa 6ltrt He MeHee 92,0 n- Artuzttiln n. C 7H9NO. (M. n. I 23,15). 4-MeroKcr.raHr4rrr4H. Co4epxur He MeHee97.0 % CTHeNO. Kpzcrar,ru 6e:roro uBera. Y u e p e n n o p a c r B o p r { MB B o A e ,p a c r B o p r r MB 3 T a H o n e . B H sbrn a er p a3Apax{eHr.r Ko)Kr.rc ewcu6utr{ 3aro p . e ; X p a H x r B 3 a u r u q e H H o Mo r c B e r a N , { e c r er p n r e M n e p a r y p e o r 0 A o 4 o C . r flpu xpauerv,r4 n-aHA3HAlrH TeMHeer BcneAcrBne oKr{cneHar. Oxuc,renHrrfi n-aHvr3rrryr4H Mo)Ker6rrrr BoccraHoBJreH o6ecqneqeu cne4yrorqvMo6pasou: u 20 r n-auu3urkrHa pacrBopsror e 500 MJrBoAbrnpr{ reMrreparype 75 "C, npu6aBJItror I r uarpux cy.rmQHra 10 r yrnt aKTr4Br.rpoBaHHoro, ra nepeMerrrlrBaror TeB qeHkIe5 ulrH Ia Sunrrpyror. flonyveHnufi oxnalrrraror 14orcranBaror $u:rsrpar nprl TeMneparypeoKono 0 oC ne MeHee4 u, sarelr $nnrrpyror, rroJryqeHHbre KprrcraJrJIbI rlpoMblBarorne6o.rmrur{M KoJrrrqecrBoM BoAbr,oxna)K.qeHuofi reMrreAo oC, n cyrrar B BaKyyMeHag parypbr 0 oKcrrAoM. Soc$opa(V) AHu.nnn. C6H5NH2.(M.rur. 93,13). Eengonauun. E ecrleerHafl,Lrrv xteJITo aroro rlBera xuAKo crb. B Pacrnopuu B BoAe,cMerxrrBaerc{co cnr{proM 96 % u eQuporrr.

-20

d,, . Oxono 1.02. Teunepamypa KuneHufl. Or 183 ao 186'C. Xpanxr B 3arrluqeHHoM cBera Mecre. or Annonoo6MeHHafl cMoJra rpyrrnbl Crrlora B xnopnAHofi Sopue, coAepxar\afl qerBeprurrHbreaMMoHr.reBbre peruerKe, cocrorqefr us noJrrrK [CH2N. (CH:):], npucoeAr4HeHHbre noJrr4Mepnofi o/o iloueper{Ho-crrHToro2 Bnrryzcra}or B Br.rAe rpaHyn, piBcrr.rpoJra Euenl,jlrEr6ensora. qacrHbrx crarb-flx. Mep Koropbrx Aorrlxeu 6rrrr yKa3aHB Claony npoMbrBalor Ha creKJUrHHoM $nnlrpe (40) 1 M pacrnopoM Harpu.f,rr{ApoKpacrBope, 3areM npocla4aAo orpr{rlarenrnofi peaxrlr4n Ha Mopr4Abr B nporlrbrBHoM peaKrluu B upouunuofi BoAe. MbrBalor eogofi .{o nonyrreHrr.f,uefirpamuofi eoge, cso6oAHoli or aMMr.raKa, 3arqrlrrlaror u CycneH4upylor B cBexenpr4roroBJreHuofi yrnepoAa ilvoKcv/J.a. oT AnnonoodMeuHaq cMoJra cr{JrbHoocnoBHafl feneo6pa":Hzur aMMoHr.reBbre rpyrrnbr cMoJra OH-QopNre,coAepxailIar rrerBeprr4rrHbre n K [CH2N- (CH:):, run I], rpr4coeAuHeHnbre nonr{Mepuofi peurerKe, cocroqilrefi rg o/o nonr4crr{pona II on epeqHo-cilruroro 8 Lusut{rl;i 6eHsora. llpospauubre rpaHynbrKopilqHeBororlBera. Pasnep qacrr.rq:or 0,2 Ao 1,0 nau. Bnazu.Oxoro 50 %. Codepcrcauue (COE). He uesee 1,2 uoxn/un. Cmamuqecrcaa o6ueHHane.tutKocmt AnuoHoo6MerrHafl cMoJracHJrbHoocHoBHaq AJrflxpoMarorpaQun rlerBeprxr{HbrMrr rpynnaMn, npr4coeAr.rHeHHbrMu K perrrerKe Cuo;ra c aMMourreBbrMr4 gunuuut6eu3oJroM. JrareKc n onepeqHo- crurrroro a AHucoeufi a.nrgeruA. C8H8O?.(M.u. t3 6,I 4). 4-Meroxclr6eHsanrAeruA. Mac[qHncrar xr{.rlKo crb. pacrBoplrMB BoAe,cN,reur{Baercs crrrproNr 96 % u e$upou. Oqesr Milro co TeunepamypeKltneHufl.Oxo;to 248'C. e Xpouarorp aQnuecxax qncrora aHr4 coBoro aJrblerrr.qa, ucnoJrb3yeMoro rasonoft xpoo . vrarorpa$uu, AoJrxHa6uru He MeHee99,0 pacrBop yxcycHonuc,rsril B MelaHoJre Anuconoro aJrbAerrrAa flocreAoeareJrbHocMerrrr4Balor lrrr anrlcoBoro ilrbrern.ua, 10 rrr yrcycHofi xuc0,5 n KoHrleHTpr4ponauH,ofi. Jrorbrre.u.snofi,85 lr.rrMeraHoJra 5 un cepnofi KrrcJrorbr p AH ncosoro aJr bAerr.rAa acrBop cnrrprotssrft c epuorcucr rrfi npn6arlxrcr 10 na;raHrrcoBofo axbAerr4AacMerur{Barorc 90 Mn cnnpra 96 otto, KoHueHTpuponannofi nepeMerrri{Baror. u 10 na;r cepHofi KucJrorbr Ano,rnr Airrr r{3o3renrpoSoxycnpoBK}r pH or 3 ao 5 (0,1 M pacrBop Kr{cnorbrrnyraMrrHotsofr,v M pacrnop Kr{crrorbr 4,5 $octpopHofi) B npir6an.nxror33 lr;r Soc$opHoii K pacrnopy I4,7 | r nTyraMr{rioeofiKr{cJrorbr Bo.ue, pacrBopa eoAofi ao 1000 nan. Kr{cnorbrKoirrleHTpnporauHor.i AoBo"qrro6rena il

' Anruuosrrr'ra Karrrrfiraprpar. CaHaKOTSb 0,5 H2O. (M.u. 333,93).Ka;rns

area[raprparo(4-)-O 1,02,O3]-aHrr4MoHvar(IiI), no.riyrirApar. lpauyrupoeanurrfi nopotrioK 6eroro rlBera r4nr4npo3paqHbre,6ecqserHrie Kpr4CTAJIJIbI.

Paersopul,r B BoAen rnrrqepuHe,JrerKopacrBopr.iM Knnrrlefi no4e, npaKTr{qecKn B

@

HepacrBopHMcrrpTe 96 Yo. B peaKrlr4rc. Bo4nsrfi pacrBopuMeercna6oKr,rcnyro (M.*. 178,22). AnrpaqeH. Cr+Hro. Kpncrannu.{ecrHfi noporroK6eroro rlBera. pacrBopr,rM x-rropo$opue. llparruvecKn HepacrBopr.rMBo.qe, B Ma,rro a Teunepamypa nna+neHua. Ot<olo218 "C. AHrpon. Ct4Hl0O.(M.u. 194,24). 9-(10H)-AHrparreHoH. Kpucra-nln.recxzfi flopouroK rlBera. cBerno-xeJrroro pacrBopr,rMcrrrrpre Yo,pacrBopr,rM6eHsore. Hepacrnopr{M BoAe, B B 96 n Teunepamypa nnarreHua. Ot<ono155"C. (M.ru.150,13). Apa6nno:a.C5H1sOs. L-(+)-Apa6uHoga. Kpucrairnuqecxufi [opo[roK 6eroro rlBera. Jlerxo pacrBoplrMa BoAe. B B A,A5ohNHl). coAepxauefi oxo.no la| . Or +103go +105 ' (5 ohpacrBop BoAe, Ap6yrnH. Ci2Hl607. (M.r"r. 272,25).Ap6yrosnl,. 4-lutpoxcH$euun-B-D-r.nroroIlupario3r4A. MelxrEe, 6recr.guxe, r4ror'Ibqarbre Kpr{craJrnu6eroro rlBera. Jlemo pacrBopr{M B Bore, oqeHb JrerKopacrBoprrM n ropa.refi BoAe,pacrBopr.rMB crrr4DTe o/o, rpaKrr,rqecKr{ HepacrBopHM aonpe. n 96

-64" tali . Orco.rro (2 % pacrnop). Teunepaml,pa nna+reuun. Oxolo 200 "C. Apron. Ar. (A.u. 39,95). Co4epxur HeMer{ee 99,995% (o6lo6) Ar. (M.v. 176,12). Acrcop6nnoBafl Krrc,'rora. C6H8O6. Eerufi HrH roqrr4 6erul"rKplrcrannu.Iecxfifi [oporxoK uru 6ecqnerHbre KpprcranJrbl, r43MeHf,ror rroA oKpailrr4Banue nosAeficrsrreM cBerav Brafv. pacTBopr{Maclr4pTe yo,flpaKTr,rqecKr,r JlerxopacTBopr4Ma B B BoAe, 96 HepacTBopr,rMa n eQape. pacrBop 0rl o Acrcop6nnoeofi KrrcJrorbr 50 ur acxop6unosofi xucrorbr pacrBop.rrror0,5 lur BoAbr AoBoA-sr n r4 o6relr pacrBopa 4urvrerunsopMaMr.rAovr nrl. lo 50 (M.u . 280,28). L-Acnaprun-L-QeHrrrrarraHr{H. Ct3Hl6N2O5. (S)-3-Auuuo-N-[(S)- -rap6orcu-2-Qeuutrerun]rHrapHar 1 Krrcnora. lloporuox 6eroro uBera. Teunepaml'pa nna*neuun. Oxoto 210 oCc pasrox{eHueM. (M.r"r. Aqera.rrr.C6Hl4O2. 118,17). AueranrAerrrAa 1,1-lneroxcllAu?rrrnauerarrb.
9TAH.

llpospa.ruax,6ecqnernae,,neryqaq ]Kr4AKo crb. Cueruunaercrc soAoitH cnprproM %. 96

dli . onono 0,824.

n,, .OKorro 1,382. Teunepamypa KuneHufl. 103"C. Oro.rro AqeranrAerrrA. CH3CHO.(M.u. 44,05).3rauam. flpospaunax, 6ecqne"rHafl) BocrrJraMeH.f,rorqarcr )KHAKocrb. Cl.reunreaercr sonofi u c crr4proM %. 96
20

wz

dli . o*ono0,788.
ltu . Orono I,332. Teunepamypa KuneHufl. Ororo 2l'C. Aqeru,raueraMrrA. C4H7N (M.*. 10 1,11). 3-Orco6yr auavug. 02. B r4 JlerxopacrBopr.rM3TaHone arlerorre. Teunepamype nraz.teHun. 53 ao 56'C . Or (M.u. 100,1l). 2,4-IIenraHAHoH. Aqeru,raueroH.CH3COCH2COCH3.
xr.rAKocrb. Eecrleernas,,Nrvr cJrefKa xeJlToBaroforlBera, JrefKoBoclJraMeHAwilJafl.efl. oA,:$uporraI4 yKJlerxo pacrBopr{MB BoAe,cMerrruBaercs arleroHoM,cnr{proM 96 c cycuofi xuc.norofi .neA-ssofi . 20 n u . O r I , 4 5 2a o 1 , 4 5 3 . Teunepamypa KuneHunOr 138 4o 140 "C. Aqeru,raueroHa peaKTr.rB K 100 Mn pacrBopa aMMoHrrrarlerara npu6anrino't 0,2 vt auerr.rnaqeroHa. Aqeru,rupyrcuafl cMecb ClremHsaror 1 .racrb yKcycHoro aHrr4Apu6av 3 qacru nepefHaHHoro nupvArrHa ($paxuux c reMneparypoff runeuvfl ot I14 ao I15 "C). Cnrecr AonxHa 6urr 6eccBexenpr4roroBneHsofi. O6parqarrcq c ocropoxuneruofi. Cuecr npr4MeH.f,ror
HOCTbIO.
20

N-Aqern"r-t-KarlporlaKraM. C8H13NO2. (M.*.

JIAKTAM.

155,19). N-Auerranrexcau-6-

BecuserHar )KrlnKo c crr. CMerur.rsaercr STaHonoM.

d,l . Onoro1,100.
/1, . Or<ono 1.489. TeunepamypaKuneHufl. Oxoro 135 "C. N-AqerunHeypaMuuoBafl KIrcJIora.CttHrq NOs. (M.vt. 309,27).O-CHa,'Ioeas,KvtcJIOTA.
20

llrorrqarue Kprrcranmr 6e;roro rlBera. pacrBopr{Ma cnrrpre 96 o/o, MaJro B [paKTHirecKr.r HePacrnopul,raB Bo.Ue hreraHoJre, r4 pacrBopr4Ma arleroHen a$upe. B
-

-36" ( I % pacrnop). Lal" . Orco,ro Teunepamype ntazrertun.Orcoto186"C c pa3no)KeHLIeM. Aqerurrupo3nHaorulonrrfi eQup.Cr:Hiz NO+ 'HzO. (M.n. 269,29). N-Aueru,r-L-rnpo:HHa srrrJroBufi eSup, MoHorrrApar. 3run-(S)-2-allerarrau4o-3-(4ru4porcuQeunn)upounoHar, MoHorr.rApar. Kpucrar,ruqecrufi nopoilroK6eroro rlBera;rrpraroAeH KoimilecrBeHHofo olpeAnr
xHMOTpnncuHa. AeneHH.f,
-t0 B lal., .Or +21 ao *25" (l o/opacrcop cnupre96%). -

-20

278 B BoJrHbr ttrvt crupre 96%. 4r,,",. Or 60 ao 68. OnpeaeneHrrenpoBoArr rrpu nJTuHe

lc"

Aqern,rrupo3nHa sTrrd'roBoro rQnpa 0r2 M pacrBop 0,54 r auerr4nrr4po3r{Ha 3rr{JroBoro r@NpapaclBop.flrorB cnupre 96 o/ar,rAoBoArr o6len pacrBopareM )KepacrBopnreneM 10,0 un. Ao N-Aqeut,rrpunroQan. C13H1a NzO:' HzO. (l\4.u. 246,26). 2-AqerHn-auuso-3-nn)nponzoHoBa.s (uH4on-3 Kr4cnora. flopourox 6eroro HJrr{ ror{T}r 6erioro uBera zrr{ 6ecqserubreKpr{crannbr. pacrBopax rr4ApoKcr{AoB Ma;ro pacrBopr4M Botre,pacrBopr4M pa3BeAeHHbrx B rrleB
.]IOI{HbIX N{CTAJIJIOB.

Teanepnmypa nnaz.iterurx. Ororo 205 "C. (M.u. 78,48). Aqern"rx,ropul. CH3COCI. Aueru,rxropucrsrii.
flp ospauHax, 6 ecqn erHae^, cnnaMeHflrouJaflc )KlrAKo Bo fl crb. oA,cMerrrr.rBaercxoQuponrn 6eHsoJroM, pacrBopr.rM Paglaiaercr B BoAer{ cnr{pre 96 c B aueroHe. xropo$opMe r.rronyone. O6paqarrcr c ocropox{Hocrbro" d,i . Oxono 1,10. Te,vnepamypuure npedenbt nepezoHra. Or 49 rc 53 "C; AonlKHorreperoHrrbcq He MeHee %. 95 (M.u. I 8 1,66). Aqeur,rxo,'rr{HaxJropHA. C7H16C1NO2. Kpncra,r,ruqecrufi noporxoK. Oqeur JrerKopacrBopr{MB xonoAHofi eoAe 14cnr4pre 96 o , npaKTnqecKnHepacrBoprrM B oQupe; pa3naraercr B roprqefi soAe rr pacrBopax rqero.refi. XpaHxr npr4reMrreparype-20'C. AqerursnreHorr. Ct2H14O3. (M.r. 206,23). 2-Merorcu-4-(2-nponenra:r)$enunauerar. MacnqHr.rcrar)Kr{nKocrb xeJrroro uBera. Jlerxo pacrBopr4M B crrr{pre 96 % pr eSupe, npaKrr4qecKlr HepacrBoprrM
B BOAe.

l ? , ,. O x o l o 1 , 5 2 1 . TeunepamypaKuneHLtn 28 | rc 282 "C. Or qrrcrora arlerrrJr3BfeHoJra, Xporvrarorpa$u.recxax ucnonb3yeMoroB rasosofi xpoMao . rorpaSHu, .uonxga 6urr He MeHee98,0 Aqerou. CH3COCH:. (M.u. 58,08).llpouan-2-ou. EecqserFras, npo3paqHafl, JrefKoBocllrTaMeHtrcxratct)Klr.qKocrb xapaKTepHbrM c 3anaxoM. TeunepamypaKuneHun.56,24 oC. Pacrnopulr n xnopoSopMe, cMerrrvBaercrc soAofi, 96 % clr{proM u e$upou. llpn Heo6xoArrMocrlr [cnonb3ylor aIIeroH oco6ofi ql{crorbl. O6paqarrcq c ocropo)KHocrbro. Aqeron 6essoAHsrfi cynrSaronr laarpvfl e re.{eHue 12 .{. ArIeroH cyrxar HaA 6essoAHbrM AueroHnrpn.n. CH3CN. (M.u. 41,05). MerurqnaHuA. SranHrrrpr{rr. llpospauuax, 6ecqnerHar xr.rAKo crb. r4 CNaelrInsaerc.f,no4oft, arleroHoM,oQuporra MeraHonoM. c

dii . onoro 0,78.

EEE

Z, . Oxono1,344. peaKIII{rc naKMycoBofi 6yno HeiirpanbHyro rrMeer Pacrnop100r/:r aueroHrrrpirna

Mafe.

oC; He Or nepezoHKu. 80 ao 82 TennepamypHbre npede:tur Ao:rxno neperoHflrbc.s MeHee %. 95 cJIeBbl.uepxr{Barb Auerosurpr{Jr, ucrolr:yelmrfi Arq cneKTpoQorolrerprrLr, AonxceH ucrIbITaHI4e. Ayrouee AonoJlHllrenbHoe npoBortr B o6nacru /InIrH MttuuaanbHoe nponycKaHue.98 %. Onpe,ueneHr{e pacrBopa cpaBHeHut xuAKocrlr B BorrHor 255 ilo 420 HM, r{crroJrb3yq KarrecrBe soAy. Aqerouurpr{r'r A!'rs xpoMarorpaQnu cneAyrouee B AueronurprrJr, HcrroJmsyenatrfixpoMarorpa$uu, AonxeH BbIAep)i(HBarb
NONONHHTEIbHOC UCIIbITAHIiC,

[poBoA.ur Irpu nnl{He BoJIHrI MuuuuanaHoe nponycKaHue.98 %. Onpe4e;reHr{e pacrBopa cpaBHeHI{tBo.qy. 240 utvt,r{cilonb3yr B Kar{ecrBe oA. MuuttuatuHan qucmoma.99.8 C4H4NzO:. (M.lr. 128, 1). 1H,3H,5H-llnpurran4uu-2,4,6Eap6nrypoBar KI,Ic,'Iora. TpnoH. oKraruEapnn rr{ApoKcl{4. Ba(OH)? ' 8H2O. (M.r"r.315,48). Bapux rrrApooKircb, APar. Bemre HJru6ecueerHbreKpucrannbl. Pacrnopn*r B Bone.-fAoeNr. Eapur rHApoKcIrAapacrBop 4,73 %o.Pacrsop 47.3 rln. Eapnr rrrAponcnAa pacrBop 5 "h. Eapuronafl BoAa oxnaxAeHes6amrrBalor co 100 MJIcBe)KelrpoKnrtqr{eHuofru 5 r 6apux rr4ApoKcnAa .f ror uofi eoArr. Pacrnop npr4MeH.fl cBexenpllf oroBJreHHbIM.AosHr. Fapua rcap6oHar.BaCO3. (M.u. 191,35). Bapuir yr:rernc:rufi. Macca. flopourox 6eroro qBera vrfir paccbrrlqara.fl B B flpaxruuecKr{ HepacrBoprrM BoAe,cnr{pre 96 o , pacrBopl4M aMMoHI{txnopl'IAe. Eapur Hrrrpar. Ba(NO3)2. (M.ru. 261,35).Eapufi a:orsoxuc:rufi. B Pacreopr4M xonoAHofinole; JrefKo pacrBopl{Mn ropxuefi BecqeerHHeKpucra-rrJm. flAosrar. Bo.qe. EapHr H[Tpara pacrBop 5 oh. 5 r 6apux Hvrpara pacrBoptrcr B BoAe Ir AoBortr o6renapacrBopa no4oii.uo 100 Nrn.Pacrsop Snmrpyrcr. -flAosur. . Eapnr cy.rrrQar.BaSOa. (M.vr. 233,40). Bapuir cepuoxnc.nrtfr Eenufi noporxoK. B flpaxruuecKr{ HepacrBopr{M BoAe. xlopucrnfi. Eapur xJroprrA. BaCl2'2H)O. (M.r"r.244,28).Eapnr ArrxnopvA.Bapuir KpIr EecqserHrre rtpo3par{Hble craJIJIbI. pacrBopl{MB cnl.Ipre 96 %. flrosur. pacrBopr{MB BoAe,MaJIo Jlerxo o . Pactnop 6l rln Eapnn xrropnAa pacrBop 6rl Eapun xJropnila pacrBop 3165oh. Pacrnop 36,5 rlrr Eapnr xJropnAapacrnop 5 %o o6reu pacrBopa soAofi ao 100 nan. 5 r 6apux xrropuAapacrBop.srorB Bo.uerr AoBoA-f,r Pacrrop $u:nrpyror. -flAonur.

(M.r"r. Eenla,rrAernA. I06,13). C6H5CHO. EecqserHaq rlBeraxr4AKocrb, npenoMnr}oruat cBet, LIJII{ cJIefKa xeJlToBaroro cr,rJrbHo
c 3arraxoM fopbKoro il{vrH4anfl,.

M?Io pacrBopr.rMBoAe, B cMerrrrrBaercr cnrrproM96 % u eSupolr. co dr, . Oro,ro 1,05.

z' . O*ono 1,545. He neperoH-srbcs Teunepamypuarcnpede.irbt nepezoHrcu, 177 to 180 "C; AorrlKHo Or MeHee %. 95 XpaHxr B 3arIuilIeHHoMor cBera Mecre. EeHsamAerrrAapacrBop nacrrulenHnrfi c 1 MJr6ensanbreru.uans6anrHsaror B cKJrrHKe 250 un BoAbr.CnaecrocraBn.glorAo cJrnBaror cneAylorqefo AHq, BpeM.fl BpeMeHues6arrrrnar. llepeA [pr.rMeHeHLIeM or npo3paqHyroxrlAKocTb. Pacreop npnMeHrror cBexelpuroroBileHHblM. BeHsrArH. NH2C6H4C6H4NHz.(M.u. 184,24). M arbl crannbl. Eemre HJrrrcJr erKa )KeJrroBarbre eJrKouroJlbtl e KpI4 B flpaxruuecKr.{HepacrBopuMB BoAe,pacrBopr4M cnrrpre 96 % u a$upe. O6paqarrcr c ocropoxHocrblo. EeHsrr. C14Hl0O2.(M.r. 210,2).luQenuneraHAl{oH. Kpncrarrn.recrilfi noporuoK xenroBaroro uBera. rr HepacrnoplrM B BoAe,pacrBopr{MB cn}rpre 96 oh,3TIlJIaIIerare ronyone. oC. Teunepamypan.ra6neHun. 95 212,24). FeH:ur6eH3oar. C 1g,H2O2.(M.rur. HJrrr6ecuserHafl vlrv no.Itu 6ecEecqserHrte vilvr noqrlr 6ecqeerHHe KprrcranJrbr
UBETHA' N{ACJ]'HIICTAq XI4.[KOCTb.
20

llpaxuruecKrr HepacrBopr4M BoAe,cMerxrrBaercrco cnrlproM 96 o , s$zpotvt,MerLIB MacnaMlr. neHxnopr{AoM, )Kr{pHbrMrr eQupHuMLI rz c

-eHoar. -$enunnpon-2 238,27. EeHsrar-3 Fensr,'rrcoplrvnufirQnp. C t 6H1 ) 4O2. (M.rur.

BesgunuuHHaMar. rlBera Kplrcranilbl Becqnernrre vrv )KeJIToBaroro B flparruuecKr{ HepacrBopnMB BoAe,pacrBopr4M crrnpre 96 % u e$upe. TeunepamypamarneHem.Oxono 39 "C.

(M.u. 108,13). EengH,ronufi cnnpr. C6H5CHzOH.

at llpoap auHar, 6ecqn ernafl, xonopxlar ) v'acIrflluprcr xIrAKo crb. u co Pacrnopuu B BoAe;cMerxr.rBaercr cru{proM 96o6,:Supou, x{HpHbIMIr eQupnuuz
MACJIAMH,

Co4epxur He MeHee 98,0 o C12H11N. Xn.urocrr x(eJrrorolrBera. TeunepamypanrarneHun. Or 13 ao 16 "C. EeHsou,raprlrHuHa sTnJroBoro eQupa

rrApoxJlopr{A.

Cl5H23ClN4O3.

(M. r'r.342,83).N-Eensoxr-L-apruuprH rrrApoxnopu4. 3run( S)-2orr4noBoro aSrEpa -ryaHr,r1t4 rr4ApoxnopuA. HoBanepara 6ensaN{raAo-5 Kpucrannu.recrufi[oporroK 6eroro uBera.

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r [paKTr4qecKl-r HepacrBopl{M eQnpe. B O.reHr JrerKopacrBoprdM BoAer,roraHoJre,

.

pacrBop). Lal, . Or -15 ao -18 " (1o/o Teunepamypa ntra*reHut. Onoro I29 "C.
.tv.

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A,.n . Or 310 Ao 340. Onpegeneur{enpoBoArr rrpr AJrI{He BoJIHbI 227 :av',rcrloJlb3yt 0,001 Yopacrtop. EeHsorrxJropr{A. C6H5COC1.(M.ru. 140,57). EecuserHar, cre3ororrr,rBat)KLIAKocrb. PacrnopuruB 9$upe, piBnaraercs B BoAeI,Icrrtlpre 96 %. O6paulamcr c ocropoxHocrblo.

dii . o*ooo1,21.
I97 "C. KuneHunOxo.rro Teunepamype (M.t. 212,25).2-fi,rgporcu-1,2-gu$eHrrrlsraHoH. BensorH. C6H5CHOHCOC6H5. IIBera. )KeJIToBaroro Kpracrannbr cJIerKa pacrBopuM ropflqeM pacrBopr{M arleroHe, B B B JrerKo Oqesr MaflopacrBoprrM BoAe, pacrBoprrM asupe. n crr.rpre96 yo,yr!{epeHHo I37 "C. Teunepamypa nra*reHua. Orcono (M.u . 122,12). Eenrofinan KrrcJrora. C6H5COOH. nopourox. r,rJrr{ KprrcrttrrJrhr 6enrrfi MenKoKplrcrannuqecrufi EecqnernrrefifoJrbrrarbre B pacrBoprdMacur,rpre % n pacrBopl4Ma xJIoB 96 B JrerKo Mano pacrBopr.rMaBoAe, poQoprvre 6esgore. u Tavnepamypa marneHua.Or I2l to I24"C (M.u. 78,12). Eenro.rr. CeHe. ct xI{AKo crb. llposp avna.s, cqserHar, BocrrnaMeH.lrcula.f, 6e co B flparruuecKrr HepacrBopI,IM BoAe,cMeIIILIBaerct clllproM 96 % u sQupoM. Teunepamypa KuneHun Oxono80'C. (M. Fen:oQenoH.(C6H5)zCO. r"r.| 82,22).,{ra$eHunlreraHoH. KpncrannbrB Br.rAe npr{3M. pacrBopnM cnrlpre 96 % u e$upe, paB B JrerKo flpaxruuecKr{HepacrBoprrM BoAe, e crBopt4M xropoQopue. 48 Teanepamypa merneHua.Orcono "C. (M.*. 108,10).n-Xuuou,n-EeHsoxuuon. I{ur<noreKca1,4-Benroxr{HoH. C6H4O2. 2,5-aueu-I,4-Auou. Xenrosarbre [prr3Mbr[nr,r KpucriurJrlrqe cKIrfinopourox. pacrBopl{M crlrrpre96 % u eSupe. pacrBopr4MBoAe, B B O.{eHrMaJro ' HzO. (M.t. 466,1).BeHsurAlav'erun-12-12EeHsrronrrnxnopna. CztHqzClNO2 xnoplrA,MoHorI{l4-(I,1,3,3-rerpalrerzr6yrun)QeHorcH]eroxcu]-sru;i]-aMMoHns APar. M e l x o rp p rcra rrr{q e crn i nopo[r oK 6er or o r lBer a unu 6ec\Ber HbleK pI{CTANJIbI.

pacrBoprlM sQnpe. n PacrnopnlrB BoAe crrr{pre96 oh,Maj'Io r4 Teunepamypa nna*neHar. Ororo 163'C. Xpanxr B 3arrruqeHHoM cBeraMecre. or

(M.vr. 216,18). 5-MeroKcr{rcop.ureH. BepranreH. C12HsO+. Eecqneruue KpucrilJrnbr. pacrBoprrMB crr{pre 96% r.rMilIo paflparruuecKu HepacrBopr{M BoAe,yrvrepeuHo B crBoprrMB yKcycHofi rncrore reAqHofi. TennepamypannaBneHua. Oxolo 188 "C. Bepro.neroBa coJrb.Clr. Kannq x!'Iopar. ' Euc6eHsruus. C25H27C13N6O5 H2O. (M.r. 624).4-15-[5-(4-Merldnrunepa3lrHneHraru1-ur)6eusurturazon-2-un]6ensuvurazon-2-u;r]SeHo;ra rpvr:a4,poxJropr4A, Apar. Erc6eHsHMHAa ucxoAnufi pacrBop 0,005 7o pacrBoprror B Bore r{ AoBoArr o6reu pacrBopa reM xe pacrBo5 ur 6uc6eH3rrMkrAa pureneM ao 100 rrrn. Xpanxr B TeMHoM Mecre. Enc6eHruMrAa padovnfi pacrBop 100 Henocpe4crBeHHo nepeAr4cnonb3oBaHzeM mxn ucxoAHoropacrBopa 6uc6eusuMv;la AoBoAqr SocQarHuvr sa6y$epeHHbrM $ra:uonorrqecKrM pacrBopoM pH 7,4 100 run. Ao o6ser\aa (M.u. 103,09). Enyper. C2H5N3O2. Kpzcra-n:rsr 6eroro rIBera ; rnrp o cKorILIqHbI. pacrBopuM B pacTBopr.rM cnr4pre 96 yo, oireHbMaJro B Pacrnopuu B BoAe,yMepeHHo eQupe. Teunepamypanna*neHun.Or 188 ao 190 "C c pa3noxeHr{eM. xoHrefiuepe. Xpanxr B Bo3AyxoHerrpoHr{rlaeMoM Bnyperonrrfi pearcrnn raprpara pacrBoptrcr s 500 Nar 1,5 r ue4N(II) cym$ara v 6,0 r xanun-Harptrfl. o/opawnopaHarpplfl rHApoKcl{ga,cno6oAHoro oT BoAbr,npu6annxror 300 rran10 xap6oHaroB,AoBoAqr o6reM pacrBopa reM xe pacrBopnTeJreM 1000 MJIr4neao peMerxr{BaroT. EnQenu,r-4-ot. CI2HI0O2. (M.pt. I1 0,20). 4-@enunQeHon. Kpucrannuqecrufi noporxoK 6eroro rlBera. B flparrnuecKrr HepacrBopr{M BoAe. Teunepamypama+neHu* Or 164 to 167 "C c pa3noxeHl,IeM. Eopa Qropna. BF3. (M.u. 67,81). 6opa rpr$ropu4. BecuserHrrfi ras. Eopa Qropng B MeraHorre14 oh. Pacrnop 140 rln B MeraHorle. Eopa xrroprrA.BC13.(M.r. 117,18).Eopa rpl{xrropl4A. FecqnerHufi rag. FypHo pearrdpyer c eoAofi. tr4cnorrsyrcr B BIrAepacrBopoB B reKcaH, felrraH, noAxoArtrlux pacrBopuren.f,x(2-xnoperaHoJr,Merr4JreHXnopHA, uerauor). Torcptqeu, Bbr3brBaer Koppo3lrro. TeunepamypaKuneHu.fl. Oxono 12,6 oC.

nT . Oxono 1,420.
Eopa xJropnAa pacrBop B MeraHoJre12 ah. Pacrnop 120 rln B MeraHoJre. Xpanrr B 3arrlrrueHHoM cBeraMecre nplr reMfleparype-20oC, [penMylqecrBeHHo or
B AMNYJIAX.

EEE'

(M.u. 61,83). Eopnan Kucrrora.H3BO3. Eecqnerurre,6recrnque, cJrerKa )Kr{pHbIe orqylr .reuryftrv uilv uemwfi rpuHa crtlltruqecxufi noporuox. pacrBopr.rMa cnupre B Jlerro pacrBoprrMa roprqefi eoAe(100 'C), Hrr.rqepr.rue; B o oqeHbMzLilo pacrBopr,rMaarleroHe. 96 , B oh EopHofi Kr{qrrorbrpacruop 4 I,I 4 r 6opHofi rucrorrr pacrBoprrcTB BoAefiprl HarpeBanvtv, oxJrax,{arcT AoBoA{T soAofiao 100 rr,rn. EopHofi KrrcJrorbr M pacrBop 016 pacrBopnor npr{ HarpeBaHr.ru250-300rvfi soArr, paz6as 37,098r 6opnofi Kr,rcJrorbr BJrrror soAofiAo o6sel,ra1000,0nan. EopHofi KrcJrorbr0r2 M pacrBop pacrBoprrcrrrpu HarpeBaHrrpr 12,366r 6opnofi KrcJrorbr s 100-150Mr soArt,paz6aBJrrroreoAofi Ao o6servra 1000,0prn. 2. Eopneor. C l 0Hl 80. (M. r"r.154,24). 3Hgo-1,7,7-Tpnrueuar 6utlurcnol2. l ] -renran2-on. Fecqrernue Kpr,rcraJr.nrr. Jlerro cy6nnrvrupyercr. pacrBopr{M c[llpre 96 o/o, B IlparruvecKr{ HepacrBopr{M BoAe, B JrefKo e$upe u nerporefiHoru rftrape. Teunepamypa 208 nnarneHua. Or<ono "C. MeroAoM XpottamozpaQun. npoBoAf,r rosrocrofinofi xporuarorpaQuu, Onpegeneurre HcrroJrb3yr KaqecrBe B roHKofo crroflcvrrvtKareJrb Ha JrnHr.rro G. crapra xpoMarorpayo pacrBopaB ToJryoJre. Xporr,rarorpaouHaHocrr 10 rrrxn0,I Suvecxofi nJracrr{HKr.r pyror n xnopo$opue. Kor4a $poHr pacrBopr,rrenx npofiger 10 cM or rrvtnnvr crapra, pacTBopoM rrJracTr,rHKy 14 BbrHrrMaroT KaMepbr, r{3 cy[raT Ha Bo3Ayxe onpbrcKr,rBaroT aHr4coBoro anrAerrrAa,pacxoAyr 10 un Ha rrJracrr,rHKy rrJrorqaAbro vrrr,r2, 200 cyurar oC s reqeHue10 uus. Ha xpoMarorpaMMe rrpr.r reMneparype 100ao 105 or AortlKHo nrrHo. o6napyxuBarbcr roJrbKo oAHo ocHoBHoe EopHn.nauerar. C2H20O2.(M.rur. 196,28).Snao-1,7,7-Tpurvrerur6uquwol2.2.Ilrenr-2-un auerar. EecqserHu e Kpr{crtlrrrrbrr4rrr4 cqe erHar xI4AKocr6. 6e Oqesr MarropacrBoplrMB BoAe,pacrBoprM B crrrpre 96% u eSupe. TeanepamypannarneHun.Oxolo 28'C. Xp oaamozpafuun. OnpegeneHue rpoBoArr MeroAoM roHKocnofi nofi xpoMarorpa$uu, ueflonr3yr B KalrecrBeroHKofo clrofl cr4nvKareJrb Ha Jrr{Hrrro G. crapra xpoMarorpaHanocflr 10 naxri4,2o pacrBopa B Tonyone.XpolaarorpaQuSnvecrofi rrJracrr{HKu pylor e xnopo$opMe. KorAa $poHr pacrBopr.rrenx npofi4er 10 clr, rrnacri.rKy BbrHHMaror KaMepbr, r.r3 cy[rar i{a Bo3Ayxeu olpbicKr,rBarorpacrBopoM aHHcoBofo pacxon-vfl10 nanHa [i]acruHKy flnouarbro 200 rr,ru2, a-ribAer'IrAa, cy[rar npr{ TeMr]eoC s re.{enHe 10 r,rvu. Ha xpoMarorpaMMe palype or 100 ao 105 ronxHo o6napyxnBaTbctToJTbKo o.4Ho ocHoBHoe [tTHo. EpunnnaHrosnrfi cnHnfi. Cu. Kuc,rolHrrfi cnnnfi 83. Epou. Br2. (M.u. 159,82). KpacHo-6ypar nerKo neryqar xrrAKocrb c yAyrirnr4BbrM 3arraxoM. Ma"rropacrBopxM B BoAe,pacrBoprrMB cnllpre 96 % u s@rlpe.

ETE

O6paqarucr c ocropoxHocrbro. BpomapacrBop reM pacrBop.rrrorBoAe AoBoAtro6reu pacrBopa B I{ r,r 30 r 6porvla 30 r KlTrvrfl,6porrluga xe pacrBoprrreneM 100vrrt. ao Bporunanno4a BcrptxuBarorco 100 Mn BoAbIAo HacbIIIIer'vs. 6porr,ra 3 rran c creKJIa rpllreprofi npo6rofi, r Xparur HaAvg6urxou 6povras 6aHre opamr(eBoro
OT npoxnaAHoM 3aITII4IIIeHHOM CBera MeCTe.

6poua pacrBop cnnpromrfi 250 vn roMerllaror 90 nn cnupra 96 o , npu nepeB ronnqecryro ron6y eMKocrbro nbAoM ocropoxuo, nocreneuno upu6acHapyxflr MerrrrrBaHrrr,r u oxJraxAeHvrilxor6rr 6poua. BJrrrorl0 rran orMepeuuoroq[JII4HApoM nposarprnofi npureprofi npo6rofi, B TeMHoM, creKJra, Xpanxr s 6aHreopamr(eBoro
XJIA.IIHOMMECTC.

(M.u. 307,11). 5-Bpou-l-(2-aeorcn-BCeH11BrN2O5. 5-Bpou-2'-seorcuyplrAuu. -,[I4oH. I H, D-spurpo-neHroSypaHorun)- 3H-unpuu*rgun-2,4 Oxono 194 "C. Teunepamypa nnaBneHun. rucnorrr 30 7o pacrnop EpouncroBoAopoAHofi B BoAopoAa yKcycsofixuclore leA-suofi. 30 % pacrBop6porrallcroro e co,qepxuMo ocropo)KHo IIep e.qBcKpbrrr{eM Aera3lrpypr. KncJrorapa3BeAeHHaq FporvrncroBoAopoAHas Bo noMelrlaror Qnaxonrt ruc.rrorbl 5,0 nal 30 % pacrBopa6polrucroBoAopoAHofi npo6yKynopfiBaror arrvroc$epe aproHanoJIIrgrItJIeHoBbIMIr B creKJra, r,r3 TeMHoro nepeAI'Icor KaMrr xpaHrr B 3aIrIi{UeHHoM cBeraMecre.Henocpe4crBeHHo r{
vI loJrb3oBaHLIeM upH6ae;rxror 5,0 MJI yrcycHofi KucnoTbl leAssofi rrepeMeIur.rBaroT. Mecre. Xpanrr B TeMHoM EporuncroBoAopoAHofixnc.nors 47 o/opacrBop B 6polrucroro BoAopoAa Bo,ue. Pacrnop 47 % (nr/na) pa3BeAeHHas 0179ah. Co4epxrat 7,9 rlrHBt" EpouncroBoAopo5nafi KI{cJIoTa xncirotu pacrBoptlor B Bo,{eH,{oBopacrBopa 6pouuc'roBoAopoAHoil 16,81 r 47 0/o A.sr o6rev pacrBopa reM xe pacrBopl{reneMAo 1000 nan. 698)" C"1F{1aBraO5S. (M.n. Spourrcpe:onosufi se.uenufi {cunufi). 4,1'-{3H-2, i -Een:oxca-ruol-33'"3",5',5"-Terpa6poM-.1r-Kpe3onc,v:u$oSraJIeI{H. ucl2.6- w6pou-3 -uerun$eHol] - S,S-:lroxclal. rannaeH)-6 orreHKoMIrBera. trloponror 6eroro c KopHr{HeBarbIM pacrBopax rI4B pacrBoprrMB BoAe,pacrBopr4r\,{ crir{pre 96 % il pa3BeIeHHbIX Izla.iro ulenoql{bIx MerairJroB .{poKcr{AoB " Epourpeao!'IoBoro 3eJfeuoropacrrop 0,05 o/G pacrBop.flror 0,'72nrir0.1 M pacrnopa Harpn.f rI4s 50 nar6poltcpe:onoBorc 3eJreHoro ,4poKcilrau 20 r"rn96 % cnt4pr1,aoBoAsro6tent pacrBopa eo.Eoliao tr00 u:i. cso6onnofi or yrxepora.fHoKK 100 Mr Bo,qIlI. Ha f4cwbtmauue uyncruBumerlbHacmb. npu6an.uxrotA,2 xt;t paarBopa 6pol,mpe:onoBoro3eneHofo;riotBnsercs cltHe DnAa, Koropoe ilepexoArir B ;,Kerroe upa nplidaBireHt{I{ire 6o:iee 0,2 tut:l orparur.{BaHne, 0.02 h4 pacreopa xnopi4croBr:4cpoglroilKi.{cilcrE.

Eret

flepexo4oKpacKr4 xenrofi Ao cunei B r{HTepBaJre pH3,6-5,2. or oh EpourcperoJroBoro (cnnero) pacrBop 0104 3eJreHoro pacrBoprror s 7,I5 rral0,02 M pacrnopaHarpa eAKoror4Ao0,1 r r4HAr4Karopa BoAtr o6reu pacrBopa cBe)KerrpoKruqqeHuofi oxnaxAennofi no4ofi v 250 rran. ao pacrBopa xenrofi r cusefi B r{HrepBa^rre 3,8-5,4. flepexo4oKpacKr.r pH or o (cuHero)pacrBop 0rl EponxperoJroBoro 3eJrenoro pacrBoprrcre 50 Mn cnrpra 96 % r{ AoBoArro6reu pacrBopa 0,1 r uugnKaropa soAofiao 100un. pacrBopa xenrofi r cuseff B rlHrepBaJre 3,8-5,4. flepexo4oKpacKr{ pH or BpourcperoJroBoro 3eJreHoro MerrrJroBoro H KpacHoropacrBop 0,15 r 6pouxpesoJloBoro pacrBoprrorB 3eJreHoro 0,1 r Merr.rJroBoro u KpacHoro 180rvrn3TaHo.rra AoBoAf,T pacrBopa r{ nogofiao 200 ur. o6lerr,r Fpolrrcpelonosrrfi :e;renufi (cunnfi) BoAopacrnopu*rufi. C2lHlTBraNO5S (M.u. 715,0).Alruonr.rfiHa{ coJrb ,3",5',5"-rerpa6poM-rr-Kpe3oncynr$o$Tailevna. 3' rrepHoro flopourox rlBera.Jlemo pacrBopuM BoAe. B pacrBopa xe.rrrofir cuuefi B r.rHrepBaJre 3,8-5,4. llepexo4 oKpacKn pH or Pacmeop uudurcamopa. %o 0,04 pacrtop. Eponnpegonoerrfi ryprypHbrfi. C21H16Br2O5S. (M.r"r. 540,2) 3',3" -[w6pouo-Kpe3oncynrQo$rarrer4H. 4,4'-(3H-2,1-Eeurorcaruon-3-unra4en)-6uc-(2-6pot'r-6vrerurQenon)- S-4uoKcLrA. S, flopourox po3oBaroro rlBera. IlparruvecKrl HepacrBopr4MBoAe, pacrBopr{M clprpre 96 % r4pa3BeAeHHbrx B B pacTBOpax rr,rApoKcr4AoBfiIenoqHbrx MeTaJrJroB.

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Bponrcpe:orroBoro nypnypnoro pacrBop 0105%o 50 r 6porraKpe3onoBoro rypnypHoro pacrBoprFor 0,92 ur 0,1 M pacreopa:rrarptts, s rlrApoKcrrAau20 crrrpra 96o , AoBoA-f,r Mn pacrBopa o6rerr,r eo4ofiao 100rvrn. I,Icnatmauue qyncmsumerbHocmb.100MJr Ha K BoAbr, cno6oAsofi yrnepoAa or Ar,roKcvI&a, npr6aumor 0,2 unpacrBopa6porrarpesoJroBofo rryprrypHoro 0,05 rran u 0,02 M pacrBopaHarpus.ri{ApoKcr,rra; norBnrercr cr,rHeBaro-$uoneroBoe oKparrrr4BaHr,re, KoTopoe repexoAr{T B xenroe rtpa npu6anleuuu He 6onee 0,2 MJr 0,02 M pacrBopa xrropr4croBoAopoAHofi xucnorrr. flepexogoKpacKH xerrofi Ao cvHeBaro-$noleroeofi HHrepBulrre 5,2-6,8. or pH s o Eporvrrpero.nonufi nyprypnbrfi pacrnop 0rl r uu4ltKaropapacrBopf,rore 50 Mn cflI,tpra96 % npr,rHarpeBannpr no4xuofi 0,1 na 6aueu nocJre pacrBopaeoAoftao 100 un. oxJrax(AeHr.ur o6reu ,uoBoA-f,r flepexo4oKpacKr.r pacrBopa xenrofi K rypnypHofi s raHrepruepH 5,2-6,8. or Eporurcpero.nonufi rypnypu brit 0 r04oh pacrBoprrcrs 9,25 ul 0,02 M pacrnopaHarpaeAKoro AoBoArr 0,1 r nn4uKaropa r.r pacrBopacBex(enpoKr.rurqeHHofi o6rena n oxnaxAeunofi so.{ofi ao 250 rvrn. flepexo4oKpacKr.r pacrBopa xelrofi K ryprypHofi n unrepnane 5,2-6,8. or pH Eponrrcpeto.irosrrfi nypnypnrrfi BoAopacrnopnnufi. C2lHl9Br2NO5S.(M.r'r. -Kpe 5 57,3).Aurraonufi coJrb " - gu6poM-o 3oncynr Haf, 5',5 Qo$riurerrua. MenrorpucrulJlJll,Iqecrufi nopouroK TeMHo-KpacHoro reMHo-Kopr,rrrHeBoro r.rJrr,r rlBera. Jlerro pacrBopr.rM BoAe. B

. '.4:.

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pH pacrBopa xelrofi K nypnypHofir unrepnane 5,2-6,8. or flepexogoKpacKI4 o/o Pacmeopuuduxamopa.0,04 pacrnop. (M.r"r. 624,4). 3',3"-[u6poMruMonEpo*rrnnonosHfi cnuufi. C2TH2sBrzOsS 4,4'-(3H-2,1-EeHsoxcarnor-3-unu4en)-6uc-(2-6potra-6-usonpuncynrso$rarrer4H. -rraerun$euon)- -AIroKcI4A. S,S 3 IIBera. llopouror or KpacHoBaro-po3oBoroKopllqHeBaroro Ao papacrBoprlM cnl{pre 96 % H pa3BeAeHHbIX B B HepacrBopr{M BoAe, flpamnuecKr.r
crBop ax f rlAp oKcrIAoB IueJIoqHbIX MeraJrJIoB.

crlHero pacrBop 0104oh EporvrrnnroJroBoro 0,02 M pacrropa Hmpktfl,Tvr0,1 r 6povrrnlroJroBoro clrHero pacrBoprrcr s 8 rrr.n H ApoKcI4Aa AoBoAqro6relt pacrBopa soAofi ao 250 un pH pacrBopa or xe;rrofi x cuuefi B HHrepBane 6,0-7,6. flepexoa oKpacKI4 o Epolrur*roJloBoro cnHero pacrBop 0105 pacrBop-f,IorB cMeclr 4 tu 0,02 M pacrnopa Hacr.rHero 50 ur 6porr,rrnuoJroBoro o/o, .[oBoAtT o6lertt pacTBopa no4oft TpLrflrr4lpoKcla La u 20 un crplpTa 96

ao 100u;r.
K Izlcnotmauue rtyncmsumenbHocmb. 100 MJIBoAbI,cso6oAHofior yrnepoAa AuoKHe cvqa, npu6an:raror 0,3 lu pacrBopa 6pouruuoJroBofo cl{Hero, noqBntercq x{enroe Koropoe nepexoAr{TB cI,IHeeupn npu6aBnennv He 6olee 0,1 un oKparur{BaH}re, rI{.qpoKcI,IAa. 0,02 M pacrBopa le'anplafl or flepexoa oKpacKI4 xelrofi r cuuefi B lrHrepBanepH 5,8-J,4. crrHeropacrBop I oh n gnuernlQopMaMnAe. Pacrnop l0 rin e Eponarnlro.rroBoro 4uueru;rQopMaMIrAe. 5po*rrnuoJroBoro cnHero pacrBop 0104o cnupronufi upu6anrxror 3,2 *ut 0,05 M pacrBopa Harp*rflrvrK 0,1 r 6pourulrorroBoro cr.rHero o HarpeBarorAo pacrBopeHrra,noJryqeHHblfi pacraop oxu .{poKcr{Aa 5 ul cn[pra 90 , nalrc4alorr{ .xoBoAtr cnl4proM90 % ro o6beMa250 vl. Spournuo,ronrrfi cnnufi pacrBop 0rl oh cnnpronuil Ha 0.1 r unaHKaropa pacrBopqrcr s 50 Mn crrrpra 96 % rpl4 HarpeBanvtu eoAxHofi eorrofi Ao o6leua 100 run. 6atte u fiocJreoxnaxneHl4t .uoBoA-gr pH flepexo4 oKpacKI{or xelrofi x cusefi B r{HrepBa.rre 6,0-7,6. Sponruno,ronufr cnHnfi BoAopacTnopuvrtfi. C27H3Br2NO5S. (M.u. 64I,4). Awl lroncynr$oQra,reuna. MonuirHa.fi corb 3',3 "- gu6porvlrv Ao Me.nxoxpr.rcrarnuqecxufinoporuoK or reMHo-Kopnr{HeBofo qepHoro qeera. PaB cTBOpr4M BO.4e. flepexo4 oKpacKltpacrBopa or xelrofi x cusefi B llHrepBanepH 6,0-7,6" A,04 otopacrnop. Pacmeop uudurcamopa. BRP-uHarrKaropa pacrBop cuHero,20 vr Meri{noBoroKpacHorou0,2 r $eHon$raneuna 0,1 r 6pourr.rNro.rroBoro pacTBopaTeM x(e pacTBopl4TeneM Ao pacTBop-flror 96 Yo cnnpte, AoBoArTo6r,eNa s i00 ul lr $nnrrpyrot. (M.rtl. 670,0). 3',3",5',5"-Terpa6porraBpouseuo.nonrrfi cunHfi. C19H1gBr+OsS. $eHoncynr$o$raneuu.4,4'-(3H-2,1-Fengorcaruon-3-unlr4eu)-6nc-(2,6-gu6poNr$eHon)-S,S-AuoxcuA. -}Kenroro ilBer a. o floporu or cBerJrof opaHx{eBo 3g

Oqenr MzLIro pacrBopktMB BoAe,Mano pacrBopr{MB crrr{pre 96 oh, nerKo pacrBopr.rM B pacTBopaxfrrApoKcrrAoB rrlenor{Hbrx MeTanJroB. BpouQeuoJroBoro cnnero pacrBop 0rl oh 0,1 r 6ponrQeHonoBoro pacrBoprrcr B cMecr.r ur 0,1 M pacrBopa Hacr4Hero 1,5 Tpkrfl. fnApoKcx ra kr 20 rvm 96 % cnvpra, AoBoArr o6teu pacrBopa soAofi ao 100 rran. I,IcnutmauueHa qyscmrumenbHocmb. 20 MJrBorbr, cno6oguofi or yuepoAa K npu6ant-sror 0,05 r\,{n pacrBopa 6pour$eHoJroBofo Ar.roKcr4Aa, crrHero u 0,05 un pacrBopa xnopucroBoAopoAHofi xuc;rorbr; rorBnserc{ xeJrroe oKparr1x0,1 M Baur4e, Koropoe nepexoAplT cr{HeBaro-$uoreroBoe rrpu npz6aaleHuu He 6onee B 0,1 M pacrBopa Harprlr rr{ApoKc[Aa. flepexog oKpacKrlor xenrofi Ao cuHeBaro-$uoleronofi s r{HTepBiure pH2,8-4,4. BpouQenuJroBoro cuHero pacrBop 0105oh 50 nr 6pou$euuJloBofo cl4HeropacrBoprrcTnpr.rocropo)KHoM HarpeBalLrvtB3,T3 wt 0,02 M pacrBopa :c.arprrfl rrrApoKcprAa AoBoArr no4ofi Ao o6rerr,ra 14 100 un. EpolrSenoJroBoro cr{Hero pacrBop 0r2 o cnupronsrfi 0,2 r 6ponr$enolonoro crrHefopacrBopsrcTnpr4HarpeBaHrrr 3 N,rr0,1 M pacrBopa e o ronyqeHHrrfi pacreop oxnaxraror r4 HarpvrflrI{ApoKcI{Aau I0 Mn crrrpra 96 , AoBoArr crr{proM 96 % 4o o6reua 100 vn. Epou0eHo.uonrrfi cnnr.rfiBoAopacrnopHurrfi. CreHl3BraNo5S (M.r"r.687,0). Avuouufrsas colr 3,3',3 ",5',5" -Terpa6povr$euo,rcyns$o$ranenua. MerxoxpucraJrJrrrqecrufinopouoK rrepHororlBera. Jlerro pacrBopr.rM BoAe. B flepexo4 oKpacKr4 pacrBopaor xenrofi x cusefi B nHTepBanepH3,0-4,6. Pacmeop uudurcamopa. 0,04 Yo pacryop. Epyuun. C23H26N2 4' 2H2O. (M.r"r.430,5). I 0, 1I -lnueroKclrcrpaxHrrH. O Eecqserurre Kpncrannbr. Ma,ro pacrBopr4M BoAe,nerKo pacrBopr4M crrprpre96 % u e$upe. B B TeunepamypamarreHun. Oxono 178 'C. Eypa. Cru. Harpux rerpa6opar. Bypu pacrBop. Cna. Harpnr rerpadopara pacrBop. ByraHonafl KrrcJrora. Cu. MacJrffHafl KrrcJrora. 6yrauon. CH3CH2CH2CH2OH.(M.rur. 74,12). ru-Byranor. 1-EyraHon. llpo:pa.ruar, 6ecqnerHa{ )Kr.rAKo crb. Pacrnopulr B BoAe,cMerurrBaerc-fl cnrrproM 96 yo, e$Hpona. co d,i . Ot<olo 0,81. Teanepamypa KuneHunOr 116 ao 119 'C. 2-EyraHo"n. cH3cH2cH(oH)cH3. (M.u. 74,12). emop-Byua.irosuficnlrpr. llpo:pavnaq, 6ecqeerHaq)KuAKo crb. IIeSxo pacrBopr4M BoAe,cMerrrnBaerc-s clraproM 96 % u eSzpovr. B co d,i .Ot<olo 0,81. Teunepamypruute npedenu nepezoHrcu. 99 to 100 "C; Aon)KHoneperoHsrbcr He Or MeHee %. 95 2-Eyranou. Clr. Mern.nrrnJrKeroH.
.:

(M.r. 73,14).1-ByrauauuH. Eyrura*run. CaH11N. EecuserHaf, xrrAKocrr.CnenuBaercr c no4ofi,cnnproMu96 ohsQraporvr. ,lj . ono,to l,4ol. Teunepamypa KuneHutOrono 78 "C. fleperoHxroru uclonb3yrorB TeqeHr.re I ruec. mpem-ByurJr aMrrH. Clr. 1,1-lu MerHJrsTrrJraMHH. (M.rnr. Eyrnraqerar (1). C6H2O2. 116,16). flp ospavnar, 6ecqnernas,,BocnnaM roularcq x{r.rAKo crb. eHfl M?Io pacrBoprrM BoAe, B cMerrrraBaercr crrproM 96 % n o$upolr. co d', . Oxo:ro 0,88.
lto .Oxono 1,395. Teunepamypuutenpedenbtnepe?oHrcu. 123 lo 126 "C; AonxHo reperoHflrbcq He Or MeHee %. 95 Eyruraqerar (2) flpospauHax, 6ecqne'rnafl.BocnJraMeH*ouarc.f, )KHAKocrb. ) Maro pacrBopr4M BoAe,cMerur4Baercr 96 % cnuproM u aSupona. B c
20

dii . o*oro 0,883. nii .6*ono 1,395.

Eymauon. He 6oree 0,2 yo. Onpe4eneHr4e rrpoBoArr MeroAoMra3oBofi xponarorpa-

Q^.
u-EymutQopiruam. He 6onee 0,1o . OnpegeneHr,re rpoBoAqr MeroAoMra3oBoli xporuarorpaSuH. u-EltmutnponuoHem. 6onee0,1oA. Onpe4eneHrre He npoBoA-flT MeroAoM ra:onofi xpouarorpaSuu. Boda. He 6o.rree 0,1Yo. KonuqecmleHHoe He onpe.deneuue. MeHee99,5 o C6H2O2. OnpegeneHuenpoBoAtr MeroAoMrasoeofi xpoMarorpa$uu. ByrH;r6opHas Krrcd'rora. CaHlrBOz. (M.*. 101,94). 98 Co4epxur He MeHee % C4HltBO2. TennepamypannaBneHua. 90 ao 92'C. Ar mp em-Eyrvrr rr.rApoKcrrepoKcna. CaH 1602. (M. na.9 0,12). 1,I -!vueurnsTr4nrr.rApoKcrrtrepoKcr{A. Bocn;ralreHqroqa-scq )r(r4AKocrb. pacrBoprrreJrrx. PacrnopunrB opfaHur{ecKr4x d,i . Oxono 0,898.

1 2,f . Orco n o .4 0 1 . Te.unepamype KuneHufl. 35'C. (M. Fyrnn rugpoKcLrrorryo,r. 15H2aO. u . 220,3 . n -ByrutrcuApoKcl4ronyon. 4) C
Ferufi rrJrn)Kenrosaro-6emrfi rpucrannu.{ecrufi [oporxoK. llparruvecKlr HepacrBoprrMB BoAe, or{eHbJrerKopacrBoplrM B arleroHe u oQnpe, nerKo pacrBopuM B crrrrpre 96 % u pacrr{TeJrbHbrx Macnax. mp em -Byr r.rJrMernJron eQup. Cu. 1,1-{HM errrJr3TuJrMernronufi rQnp. ufi

)o

ztEl

Eyrn.nnaparuApoKcrdeHsoar. C6H4OHCOOC4He.(M.r"r. 152,14). Byrut-nrngporcu6eH3oar. Byrulorurfi e$up raparr.rAporcu6ensofi ru cnoru. Hofi Eenufi r.IJrpr [orrrrr 6enrrfi KprrcraJrnr,rqecxnfi rroporroKunu 6ecqeerHbre Kpr.tcrarrnbr. pacrBopr4M BoAe, pacrBoptrM cnrrpre96 %. Oqenr MaJro B JrerKo B oC. Teunepamype nra*reHun.Or 68ao 7l mpem-Eywr,rosrrfi c[npr. Cu. 2-Me:rnn-2-nporraHoJr. (M.r. 86,09).!uru4po-2(3H)-SypaHoH.l-EyrnponaKroH. EyrnponaKroH. C4H6O2. Macnxsucra.sx{r4rKo crb. Cltenunaercq c ro4ofi, pacrBopr,rM MeraHoJre, B e$upe, arleroHe, 6eusoreprqerbrpexxnopu yrnepoAe. cToM n ", .Orco n o1 ,4 3 5 . Teunepamypa KuneHun Oxono 204"C. pa6ovne lr o6parqoBbre pacrBopbrArrflerercrpoQope3a. Harpnn EyQepHue Crvr. AoAeurrJrcy.nrQar. Basennx flonyxu4xaq cMecbyrneBoAopoAoB, {eHHaflv3 non) neSru u o6ecqseqeHHaf,. flparoA,pacrBop}rM eQnpen rrerponefisov ruqecKltHepacrBoplrM BoAe crrr{pre96 B H n o$upe; pacrBopHHorAa o6uapyxrEnaer c.na6yrc onirlre cqeHrluro. Baser[HoBoe MacJro EecuserHaq, npo3paqHa.f, flHvrcrafl. xrrAKocrb,6e: SnyopecueHrlr,r u npv nHeB, MacJr
HOM OCBEIIIEHIjLI.

flparruuecKll HepacrBoprrMo BoAe,yMepeHHopacrBopnl,ro B cnr{pre 96 o./o, B ctvrerrjrrBaeTcr yrneBoAopoAaMrr. c Ba.nepHanoBafl KncJrora. C5H1 . 3). 9O2.(M.rvr 102,1 lleHraHoBar Kncnora. BecuserHaflxr{nKocrb. pacrBoprrMaB crrr{pre 96 % u e$rape. Pacrnopulra B BoAe,JrerKo d', . Orolo 0,94.

nii . O*ono1,409.
TeunepamypaKuneHut Oxo:ro 186 "C. Banasun(V) orccn4. VzOs. (M.pr. 181,88). B auaguenrrfi aHru4p ug. fiunauaAlrq n eHroKcr.rA. Co4epxu:r He MeHee 98,5 o VzOs. lloporuor or xeJrro-Kopr{qHeBofo opaHxeBaro-KopuirHeBoro rlBera. Ao Mano pacrBoprlM B BoAe,pacrBopt{MB KoHrIeHTpHpoBaHHbrx MrrHepaJrbHbrx KucnoTaxn pacrBopax rr4ApoKcrlAoB ureJrorrHbrx MeraJrJron o6pasoBaHueM c colefi. BanHnnH. C6H3(OHXOCH3)CHO.(M.u . 152,15). Eelue ultu cla6o-)KenroBarbrer{rJrbrc 3alaxoM Ba:a:arrn, TeMHeroilIveHa Bo3Ayxe. pacrBopr4M BoAe,JrefKopacrBopr4r,{ cnr.rpre96 o/o,a$upe u xnopoOqesr MaJro B B Qoprrae. TeanepamypannarreHua. Or 81 ao 83 "C. Bann"nnHapeaKTnB K 100 rvrn I oh pacryopa BaHI4nvrHa crrr{pre 96 % ocropoxHo rro KarrJrxunpir6anB Jr.f,Ior ur cepHofi xucnorbr KoHrleHTpnpoeaHuofi. 2 CpoxroAHocrrr-2cyr.

E@

BaHu.nusa pacrBop n QocQopHofi xuc.nore pacrBop.ulors 25 Mn clr{pra 96 o , npn6aalaro't 25 wt BoAbII{ 1,0 r nauulrvrHa . 3 5 rvrn cQopnofi xucroru KoHlleHrpuponaHHofr Qo BannrnHa pacrBop n cepnofi Krrcd'rore KoHrleHTpuponauHofi. pacrBoprrcr s 10 ur cepuofi KrrcJrorbr 0,1 r naHurrr4na Pacrnop npr{Meurror cBexelpuforoBJleHHblM. Bann.nn na p acrBop B xJloprlcroBoAopoAnoft rcnc.nore 0,2 r zanulrvna pacrBoprrcr s 10 Mn xnop[croBoAopoAnofi rzcnorbl KoHIIeHTpHposaHHofi. Pacrnop npuMeHsrorcBexenpuroroBneHHblM. Bnnu.raqerar. C 4H6O (M.t"t.86,09). 2. EecqserHas xuAKocrb. r,r c B YrygpennopacrBopl4Ma BoAe:cMellrl{Baercfl, 3raHoJIoM oQupolr.

d', . Oxono0,930. Teunepamypa KuneHun Ororo 72'C. (M.*. 105,14). C7H7N. 2-Bnnnnnnpr{ArrH. Xn,urocrr xeJrrofo rlBera.Clreuureaerctc eoAofi.

dii . o*ono 0,97.

rt, . Oxono 1,549. 1-BnHnrurpporrrrAlrH-2-on. C6HeNO. (M.pt. 111,14). Cogepxur He MeHee99,0 oAC6H9NO. crb. Ilpo:pa.+rar, 6ecqnerHaqxr4AKo Boda. He 6onee 0,1oh (nonynaraxpouero4). Oupe4eneHue [poBoAqr r43 2,5 r, xc[onb3yr B KarrecrBe pacrBopvrrelrs.cMecb 6yruponarrona. MeraHona6essoAHorou 10 rr.rn 50 rr,rn Ronuuecm6eHHoe onp edeneuue. fIp oso,rqr MeroAoMra3oBofi xp ouarorpaQ ur'r. xpoMarorpaSe c nJIaMeHHo-HoHLI3aXpouarorpaSuponanrre rpoBoAflT Ha rzl3oBoM B uuoHHbrM AeTeKTopoM cneAyIorIIHxycnoBrltx: - KoJroHKa Mapa3Meporr,r u x 0,5 MM, noKpblTat cJroeM KanuJrn.f,pHar 30 KBaprleBar Kporona 20 000 r:omrlusofi 1,0 vrxrra; - ra3-Hocxre;n rennfi Ar-trxpoMarorpaQlrz; - reMreparypa 6roxa BBoAa upo6n 190'C; - TeMrreparypyKonoHKr{ Bbl.qepxllBalor TeM[pofpaMMr.rpyror cneAylouurrao6pasoNa: oC co cKopocrbto 10'C I reparypy 80'C B TeqeHrae uuu, 3areM floBblrlrarcrao 190 TeMfleparypy 190 oC s te.IeHue l5 rranu. B Mr,rH BbrAepxrrBarcT n Xporuarorpa$upyror 0,3 lrxn r4cnbrryeMoro BerrlecrBa,perynupyt cKopocrb roroKa rlrrKa,coorBercrByloraxr,rnro6pasou, .mo6u BpeMf,yAepx{HBaHr.rf, ra3a-HocHTeJIt cocraBJrtJrooKono 17 uula. Co4epxanue C6H9NO rrlero 1-sr.rnurur.rpponr,rAr{H-2-ony, orrpeAenrrcT MeroAoMBHyrpeHHefiHoprualu3aIIHI,I. oKTaAeIIHJIclIJrrrJrbHsIfi xpoMarorpaQuu Bunn.nnoJrr.rMep Anq qacrr.rqrr (5 rr,rrcrvr) Br4Hr4noBoro cflupra, cBt3aHHoro oKTaconoJrr,rMepa CQepuvecKrde .ueuuncl4naHoM. Co4epxur 17 o/oymePo4a.
20

3Et

(M.r"r. Bnnn;rx"ropnl. C2H3CI. 62,50). BecuserHrrfi ras. pacrBoprrrerqx. Ma:ro pacrBopktM opraHuqecxrdx B (M.u. 150,09). Bnnnas KrrcJrora. BzHnoravreHHar Kr4cJrora. C4H6O6. EecqserHrre Kpr.rcrilrnbr. pacrBopr{Ma pacrBopraMaBoAe, B MaJro Jlerxo B crrrrpre96 o , pacrBopr.rMaaqeroHe, r e$zpe. pacrBop 20 oh BuHnofi KucJrorbr 2 r euHHofi xucnoru pacrBoprrcrs 10 MJr BoAbr. Pacrnopnpr{Menrror cBexeilpnroTOBJIEHHbIM.

Bucuyra Hnrpar. Bi(NO3)3 ' 5H2O. (M.rur.485,1). BrEcuyr(III) asorHoxucrufi 5-soAHHfi. llpospaunrre, 6ecrreerHbreKpr{craJrnbr Macce 6enoro rlBera. Pearnpyer c noAofi. B Jlerro pacrBopnM e a3ornofi Kt4cJrore. Bncrvryra Hnrpar ouroenofi. [4BiNO3(OH)2BiO(OH)]. (M.u. 1462). He Cogepxur He MeHee 7I,5 % u ne 6oree 74,0o/oBI4cMyra; MeHee14,5 Yon ue 6oree oh Hr{rpara, B repecqere Ha arora(V) oKcrrA(NzOs). 16,5 flopouror 6eroro uBera. flparrHuecKr4 HepacrBoprrM Bo,qe. B Bncnryra Hurpara ocHoBrroro pacrBop KoH5 r nnclryranvrpara ocHoBHoropacrBoprnr B cMecu 8,4lrr asorHofi KIrcJIorbI rieHTpr4posaHnofi 50 rr,r"n o6renapacrBopa soAofi lo 250 MJIId,ecJIi,I u BoAbr, AoBoAtr Heo6xoArEr,ro, Sunrrpyror. Rucnomuocmu. K 10 nar BrrcMyra Hr{Tpara ocHoBHoro pacrBopa npuiawrror 0,05 lrn 0,1 cuuproBoro pacrBopa MeriaJroBoro opaHxeBoro; oKpacKapacrBopa rrpurnpu6arueHnrr or 5,0 un lo 6,25 rr,rn M pacrBopa Harprrfl I Aonx{Harr3Meur,rrbcr rr4ApoKcuAa. Boga. Cu. (DC Boaa oquulennas. Bo4au cso6oAHaff or aMMrraKa ileperoK 100 $rn BoAbrnpN6anr*or 0,1 un cepnofi KriclrorbrKoHueHTpr{ponauirofi, Hrror, acnonb3y.s npir6op rrfi onpeAeneHrr reNrrreparypnbrx rpeAenoB neperoHKlr, or6pacuealor nepBbre10 ran raco6lrparor cneAyroqlre 50 l.r:r. Bo4a, ceodoAuafl or IrHTparoB K 100 Mn BoAbr npu6aenrror HecKoJrbKo Mr4JrrurparvrMoB Karrlifl fiepl{ar{raHara lI reMrreparyp6apun ru.upoKcpillaneperoHrFor"acronb3yr up n6op rnri onpeAeJreHus ; prn u cof,upataT cnelIyrolllze Hblx ilpeAenoB neperoHKH,or6pacuearoT flepBbre 10 50 ivrLr. Bo4a, ceodoAnafi or yrJrepoAaAuoKcnAa Mi4Hyr,oxJrax.qalo'r. BoIy Knrr"aur B TeqeHHe HecKoirbKidx Xpau x1 3aruuruaflor a:rlroeSepHoro so:,4efi crens. Bo.ua,csodoAnag or rtacrgq BoAy $a;nrpyror iiepe3,^,reu6paxeufi$u;rurp c pa3x,repoM 0,22 riicra. rrop EoAa AncrE"r r"rrE{FGBsHI{afi Bo4a, nor,-t)1geHHafl eI,{ileperoHKt{. ily'f Boaa AJrrrHHbencqmfi. Cnr. qDCBoaa n"rlfi Edgt"ercusii.

eEz

Bola AJrfl xpoMarorpaQnn BoAa,rrMeroularco[porrrBJreHne MeHee0,18 MOrvr rra. He .{euonHsupoBaHuafl Bolopoa AJrnxpoMarorpaQnil.Hz. (M.u. 2,016). Co4epxur He MeHee99,95 % (o6lo6)H2.

Bo4opogarepoKclrA.HzOz.(M.u. 34.01).fleprr.r.qponr. BogopoAa repoKcutapacTBOpKOHrIeHTpr4pOBaHHbrr4. Co4epxaxxe [epeKr4cr,r BoAopoAaB peaKTnBe((x.rr.>) He MeHee30 u ne 6onee o/o; ((rr.A.a.D He MeHee u se 6oree 32 %; (cr.))- He MeHee %. 35 29 29 Eecqseruas, [po3paqHar xr,rAKocrr 6es 3aflaxa rrJr]rco cna6rrrra cnoeo6pasHbrM 3arraxou, cna6oxncnofi peaKrlufi, nerKo piBJrararcqaflcfl, e BbrAeJreHr,reM Kr,rcJropoaa. Bo4opoga neponcrrAa pacrBop pa3BeAennrrfi. Pacrsop nepeKrrcrr BoAopoAa. 10 r nepruAponr pacrBop{rcr B BoAea rrrepnoft ror6e BMecrr.rMocrbro100 run r{ AoBoArr o6reu pacrBopa soAofi Ao MerKr,r. BoccraHaBJr[Baroruaff cMecb nocJreAoBareJrbHo cMerrrr,rBaror [peABaprlTeJrbHo ,.{nx uonyveHr,rr oAHopo4uofi cMecr.r peaKTrEsrr: Mf KEUrr.rJr r,r3MeJrbqeHrhre 6poun4a, 0,5 r rn4pa3vtna cyrrSara u 5 r sa20 Tpr4r xJropr,rAa. Ianarrora. C6H12Oe. (M.r'r. I 80, 16). D-(+)-fa-uaKro3a. Kpucra.nrlr.recrufi nopo[roK 6eroro rlBera. Jlerro pacrBopnMa B BoAe.
-

LGl, . Or *79'Ao +81' (10 %opacrzop B BoAe,coAepxalqeft oxolo 0,05 yo NHr). laJr.ilosas Kr.rcrrora. C7H6O5'HzO.(M.u. 188,13).3,4,5-Tpuru4porcu6esgofisas Kr.rcJroTa, MoHorrrApaT. Kpucra-ulu.recrfifi noporroK vnu p;r,u:anabre r.rroJrbirarbre Kpr.rcriurJrbr, 6ecqserHHevrlrvl cJIerKaxeJrroBaToro uBera. Pacrnopul.ra B BoAe,JrefKopacrBopr.rMa roprqeft no4e, cflupre 96 % t,t ilrrlrlepr{He, B MiuropacrBopr.rMa eQupe. n fannosas Kr,rcJrora reprer Kpr,rcrilrrnx3aurroHuyro BoAy rrpr4reMneparype 120'C u fiJraBr.rrcr [pr.r reMfleparype oKoJro 26A'C c pa3noxeHueM. Iapnarorna. C2aH3oOr. (M.u. 494,5). r Kpucrar-rrnqecruft nopoilroK 6eroro rlBera, oqeHbrnrpocKonr.{qeH. Pacrnopuvr B BoAeH crrr{pre 96 %. Teanepamypanna*reHun. Or ll7 to I2l "C. Xpauxr B Bo3AyxoHe[poHr4rlaeMoM ronrefiHepe. Inafi ary.neH.C 15H 1s. (M.*. 198,29). 1,4-luuerr.rr-7-Hsonporuna3yneH. xrrrAKocrbcuHero rlBera. KpNcra.rr:rbr reMHo-crrHero rlBera r{Jrr4 pacrBoprrMB Bo.ue, r.r Oqesr Mano cMerrruBaercrc xnpHbrMr{u :$npnuMr4 MacJraMu oA,pacrBopr,rM 50 oApaBa3eJrr,rHoBbrM MacnoM,yMepeuHopacrBopr4M c[r{pre 96 B v o/o(u/u) u crBope cepHofi Kr{cJrorbr 80 SocSopnofi xlrc:rore c o6pasonasNeu 6ecpaCTBOpa. TIBeTHOTO Teunepamypeltt7e6JtHar. Oxoro 30 "C. XpaHar B 3arrlr4rrleHHoM cBera r.rBo3AyxaMecre. or feasrconaff cMo!'Ia ?r3 Cvoria, ronyqeHHafl. cepArleBr{Hbr AepeBaGuaiacum fficinale L. u GuaiacLtm sanctum L. TeepAue, fnaAKrle Qparrreurbr KpacnoBaro-KoprrqHeBoro rrBera Hnrl 3eneHoBaro@

-20

pa3Mrrqaercr. KopnqHeBoro rlBera, 6;recrsr Ha v3noMe.llper HarpeBaHnr.r Hepacrnopr4M BoAe. B ferccaAuuerpr{Ha 6po*ru4. (C13H3gBrzNz)n. 1,5-[urr.rernn-L,5-gua3ayHAeKaMerlrJreH flonuMero6pour.r4. llonu(1,1,5,5-rerpauerun-1,5-a3oHux-yHAeKaMerxJIeH 4u6porrau4). Arraop$nufi nopolror 6eroro uBera, rlrrpo cKonl4qeH. Pacrnopuu B BoAe. xourefiHepe. XpaHxr B Bo3AyxoHenpoHr4rlaeMoM (M.pr. 3 66,70). Iexcaxo:au. C26H5a. EeclfserHue vIrur6eroro uBera xJrorrb.f,. B IlparruuecKr{ HepacrBopr.rM BoAe,pacrBop}rMB sraHone n eSnpe. TeunepamypanxaB)reHun. Oxolo 57'C. Ierccauer lz;lr*rcurrarran.C6H 19NSi2. (M. r"r.I 6 1,40). flpospauHa.fl6ecunerHar )KrrAKocrb. ,

d,i . Oxono 0,78. rzii. onono1,40g.

TeanepamypaKuneHun Oxo.no125'C. XpaHn B Bo3AyxoHerrpoHurlaeMoM rourefruepe. ferccapreurrreHrerpaMrrH. C6H12N4.(M.*. 140,20). fexcauuH. 1,3,5,7-TerpaBarpnrrrrKrro[3.3.. 13'7]4ercaH. 1 EecqserHrrfi xpncrannu.{ecxufi [opoIIJoK. O.ieHr JrerKopacrBopr{MB Bore. ferccau.CoHr+.(M.u. 86,18). E ecqserHaq, BocrrJI eHqro rla.flcr xr,rAKo crb. aM u flqarrn.recKr4 HepacrBopzMB BoAe,cMerxuBaercrc STaHonoM eSuporra.

d.i . or 0,659ao 0,663. , ' ] . O , 1 , 3 7 5o 1 , 3 7 6 . t Teunepamypuute npedenbt nepezoHxu. 67 lo 69 'C; AonxHoneperoHtrbctHe Or MeHee %. 95 BbrAepxr{Barb cneAyroqee fercau, ucnonb3yelrufin cnerrpoQoroMerpnu, AoJrxeH
e HorrbrTaHr4e. AOnOnHr{TeJrbHO ilpoBoArr B o6nacrH AnIrHBoJIH or MuuuuanuHoe nponycKaHue:97%. Onpe4ereHl,Ie pacrBopa cpaBHeHr4r soAy. 260 lo 420 uw, rcnonb3yr B KarrecrBe (M.u. 101,19). fexcanauun. Iexcu"rauun. C6H15N. BecueerHaqxu.rlKo crb. M?^nopacrBopr4M BoAe,pacrBopr.rM cnupre 96 % rEeQupe. B B d', . Orono0,l66.

,til . O*ono 1,418. Teunepamypa KuneHufl. 127ao 131'C. Or Ienufi AJrfl xpoMarorpaQlr*r. (A.u. 4,003). He. Co4epxur HeMeHee 99,995% (o6lo6)He. (M.r. 100,20). IenraH. CzHro. BecqserHax, cnJraMeHtloxlatct Bo xI{AKo crb.

wg

B c HepacrBopr{M BoAe,cMeIrILIBaerct 3TaPacrnopzu r xnopoSopMe, rrpaKTr4qecKr,r HoJroM e$uporvr. n

dii . or 0,683 0,686. ao nli,. or 1,387 1,388. ao

Or Teunepamypuutenpedenbt nepeaoHrcu. 97 rc 98 "C; AoJI)IGoreperoHtrbct MeHee %. 95 He

(E)-3,7-[uMerl{rloKra-2,6-aueu-l-utr 196,28). lepannora arlerar. CnHz1O2.(M.ru. auerar. co EecqserHasuttw cta6o-xeJrroro rlBera xr.rAKocrb, cra6rrM 3a[axoMpo3bl v ilaBaHAbr. Oqenr Miuro pacrBopr.rM B BoAe, JrerKo pacrBoprrM B graHoJle;cMeIIrLIBaercr c eSupona.

di|,. or 0,896 0,913. ao

/t, . Oxono1.463. KuneHun Teunepamypa Ororo 138'C. qncrora repaHr{ona B arlerara, r{cfloJrb3yeMororasoeoftxpoXporr,rarorpa$uuecxax yo. 99,0 6rrrr HeMeHee rr,rarorpa$upr, AoJrx(Ha fi.rlparxn corItHoKLIcIn4parnna rr{Apoxrropul. NH2NH2 ' 2HCl. (M.r"r.104,96). rrrfi. nopo[roK. Eenufi Kpr{crarrnu.{ecrnfi pacrBopllMB cll{pre 96 %. -flAonur. pacrBopr.rM BoAe, B MaJro O.reHrJrerKo ' H2SO4. (M.u. 130,12). fia4pasuncepHoxuc.rrufi. NH2 NH2 In4pasuna cy.rrrQar. EecuserHrre Kprrcrtlrrnbr. pacrBopuMB xonoAHofi soAe,pacrBopl4M roptilefi eoAe(50'C) u B YrraepenHo B pacrBoplrM rHnqrqefiBoAe, npaKTlrqecKrr HepacrBopr{Mc[I{pre 96 %. n JrefKo (M.u. 138,13). llaparuApoKKrlcJrora. C6Ha(OH)COOH. 4-IngporccrbensofiHan
a. cu6ensofi Har Kr.rcJror n-lugpoxcu6ensofi Hat KI,IcJIora. Kpncrarru.recrt,ri ilopolxoK. Oqesr Mano pacrBopr{MaB BoAe,or{eHbJrerKopacrBopl{MaB cnrlpre 96 oh, pacrBopr{MaB aueroHe u e$rape. TeunepamypaMe*reHuz Or 2I4 to 2I5 "C. 4-IngponcunroQrarleBar KrlcJrora.HOC6H3 (COOH)2. (M.t. 182,14).4-fia4porKucJlora. cu6engor-1,3-4raxap6oHoBat I4ronrqarrre vJrwB Br{AenJracruHoKKpI,IcraJrJrbI. B Oqesr MarropacrBopr,rMa BoAe,JIefKopacrBopnMaB crll{pre 96 % u a$upe. Orcoto 3I4'C c pa3noxeHueM. TeunepamypantraBtteHua. fn4poxcnrraMHHa rrrApoxrroplrg. NHaClO. (M.u. 69,49). Kpucrar:ruqecrrfi roporroK 6eroro uBera. B B Oqeur nerKo pacrBopt4M BoAe,pacrBopl,IM crrrrpre 96 %. p acrBop ( 1 M) Iu4ponclrr'raM[Ha rrrApox,'Iopnl a rr4Apoxnopr{AapacrBop{ror s 50 l\ar BoAbIn rr,tepuofixon6e 6,95 r rr{ApoKcr,rnaMrr*a BMecrr4Mocrblo 100 un r{ AoBoAtr o6reu pacrBopa eoAofi Ao MerKH. In4porccuJr aMr{Ha rrrApoxJropnla p acrBop crl{proB bIfi (0r5 M) pacrBop*or e 95 N{r cnldpra 60 % (o6lo6), rr.rApoxnoprrAa 3,48 r rr.rApoKcrrnauu:aa B opaH)KeBofo cnupre 60 % (o6lo6) 0,2oA pacrBopa MerrrJroBoro npu6auxrcr 0,5 rvrn
t5

EEH

rI AocrarorlHoe Konr{qecrBo0,5 M pacrBopa KaJrvtA rprApoKcr4Aa cnr{pre 60 % (o6lo6) B qerKoro xeJrroro oKparxnBaHrrr, Ao noryrreHr.rr AoBoArr crrr{prou 60 % (o6lo6) rc o6reua 100 run. Iu4porccllJraM[Ha rqe,roqnofi pacrsop 7 %o paBHbre Heuocpe4crBeHHo[epe.q r{crroJrb3oBaHr{eM cMerrrr.rBaror o6reuu l4 % o/opacrBopa ]li.arprr'. pacrBopa fr4ApoKcr..rrraMlv],j.a fHApoKrr,rApoxnopvI.an l5 cvna. In4poxcuJraMr{Ha ure.noqnofi pacrBop 5 o/o. l0 % pacrBop rr4ApoKcr4naMrrHa rro/o pacrBopoMHarpr4rrrrApoKcu.qa coorHol0Jeuun B l:2 ApoxnopzAacMerrr[Barorc l0 (no o6renry). IugporccuJraMuHa pacrBop rqenoquofi B MeraHor're Pacrnop A. 12,5 r rr{ApoKcvrraMnHa rr4Apoxnopvp'apacrBoprrorB MeraHoneH AoBoAsr o6relr pacrBopa reM xe pacrBoprireneMAo 100 un. pacrBopruor B MeraHorre AoBoA-f,r paPacrnop B. I2,5 r Harpur rr{ApoKcr4Aa u o6rerr,r crBopa reM )KepacrBopr4TeneM 100 u;r. Ao HenocpelcrBeHHo nepeA r.rcnoJrb3oBaHr{eM cMe[rr{Ba}orpaBHbreo6reuu pacrBopoB A u E. Ilr4poxcn!'raMuHa rnApoxJropnAa pacrnop 5 %o 2,5 r ruypoKclrJraMrzHa ru4poxnopr{Aa pacrBopr}or n 4,5 Mn roprqefi no4u, npu6asrsror 40 un cnupra 96 oh,0,4 lrr 0,2 oA pacrBopa 6porra$enoJroBoro cr{Hero LrAocraror{Hoe KoruqecrBo 0,5 M pacrropa Kanvr fr{ApoKcr{.ila cnr4proBofo Ao o/o 3eJreHoBaro-xenroro oKparrrr4BaHr.rr, AoBo4xr o6reu pacrBopa cnrrproM 96 lo 50,0 rvrn. In4porccuJraMuna cyrrQar. IngporccuJraMrrH cepHoKlrc.nsrfi.(NH2OH)2 H2SO4. (M.r't. 164,14). FecqsernHe Kpucrannbr. ilerxo pacrBopr4M BoAe,pacrBopnM n eQupe, HepacrBopr{M cnr4prc 96 o/o. B B fngpoxcuuernr$ypQypo.n. C6H6O3.(M.u. 126,11).5-fuapoKcr4Merr{rr$yp$ypor. Irlronr.{aruI e KpncrilInbr Jlerxo pacrBopr{MB BoAe,arleroHer4cnr4pre96 o , pacrBopriMe e$Npe. TennepamypannarneHua.Oxoto 32 "C. (M.u. Iugporccuua$ro"ironoro crrHero HarpneBafl coJrb. CzoHt1N2Na3O1153. 620,5). TpNHarpnn2,2'-ruru.uporcu-1,1'-asoua$ranuu-3',4,6'-rprcynr$oHar. 12-InapoKcncreapnHoBafl Kucrrora. ClsH36O3. (M.rur. 300,47). 12-fir4porwroKTaAeKaHOBar KUCIOTa. lloporuox 6eroro rlBera. flparruuecKr4 HepacrBopr.rMa BoAe,pacrBopr.rMa 3TaHoJre, B B xnopoSopMe u eQupe. Teunepamypa nnaBneHua. 7l lo 74'C. Or S-Iu4poxcnypaqlrr. C4H4N2O:.(M.u. 128,09).I4zo6ap6nrypoBar Kr4crrora. Ilupnttuguu-2,4,5-rpuon. Kpvcran.rru.{ecx[fi noporxoK 6enoro rlBera. TeunepamltpannarneHun.Ot<olo 310 "C c pa3JrolxeHr{eM. Xpauxr B Bo3AyxoHenpouurlaeMoM rourefiuepe. fir4poxcnxrHoJrrrn. C9H7NO. (M.*. 145,16).8-fir4porcrcxnHorrr.rH. Xvuorus-8-or.

EI

Kpucrannuqecrcufi noporxoK 6eroro r{JrvxeJrroBarofo rlBera. pacrBopr{MB arleroHe,cnupre 96 % u pa3BeAeHHbrx Malo pacrBopr{MB BoAe,JrerKo MrrHepanbHbrx KLIcJIoTax. TeunepamypaMe*reHun. Oxoto 75'C. Cynufuamnan 3ora. He 6o.rree 0,05 o . (M.vr. 110,1 FeHgor-1,4-guot. In4poxnnoH. C6Ha(OH)2. 1). BecrleerHHe vrru 6eroro rlBera, rroJrbr{arbre, MeJIKLIe Kp}rcrannbl,TeMHeIoq[e rroA Aeficrsuela Bo3Ayxar{ cBera. Pacrnopurvr BoAe,crr4pre 96 % u a$upe. B TeunepamypannarneHun.Oxoto I73 "C. XpaHxr B 3arrlr4ureHHoM cBera r{ Bo3AyxaMecre. or (M.u. 464,4). 2-(3,4-!uruApoKcr40enu;r)-3-B-D-raraxroIuneporun. C21H20O12. - 5,7- gr4 r.rAp Kcrdxpona u - 4 - ou . rrr4p o3r{n oxcu aH r o e tr4ronrqarrre Kpr{cranJrbr erJro-x{eJrrororlBera. cB Pacrnopuu B MeraHone. oA lal, . -8.3 " (0,2 pacrBopn nupuauHe). Teunepamypa ntarleHun. Oroto 240 "C c pa3no)KeHrreM. fnnorccaurnn. C5H4N+O.(M.u. 136,12). 1H-llypuu-6-on. Kpncrarru.recrHfi noporroK 6eroro uBera. pacrBopr{MB BoAe,yMepeHHo pacrBop}rMs xfiu-flueft BoAe,pacrBoprrM O.reHr MtLrro pacTBopaxfr4ApoKcr4AoB B pa3Be.4eHHbrx Kr{cJroTax pa3BeAeHHbrx rr rleroqHbrx MeTAJIJIOB.

Pasraraercr, He nJraBrcb,rrpr{ TeMrreparype oKono 150 "C. InnoQocQnra pearcrlrn (pearrnn Tune). 10 r uarpur runoQocQHra pacrBoprror npu cra6ou HarpeBaHuu 20 MJrBoAbr s ir AoBoArr o6reru pacrBopa xnopr{croBoAopoAHofiruc.rrorofi roHueHTpr{posaHHofi ao 100 MJr,orcrauBaror r4 AeKaHTr{pyror utu $untrpyror rrepe3creKnoBaTy. func. Cnr. Ka,rrqlrr cyrrQar.

fncrugnua rrrApoxrropn.q (RS)MoHornApar. C6H16CIN3O2'HzO.(M.r'r. 209,64).

2-Arr,rzno-3-(unrragason-4-n.rr)nponr{oHoBofi rzcnorbr rr4ApoxnopHr,MoHorr{Apar. Secqnerurle Kpr4cran rurLrKprrcrannr4.recxnfi rrbr noporxoK. Pacrnopulr B BoAe. Teunepamypama*reHun. Oxolo 250 "C c pa3nox{eH}reM. In u roxo.n. C rr,r. u HoyKcycHafl Krrc!.r a. Arvr or Lr nrconenaq Kucror a. C2HaO3. (M. u. 7 6,05). 2 -fir4poxcr4yKcycHasKr{cnora. EecrlserHHe Kpr4crannbr. PacrnopHua B BoAe,arreroHe,cnr4pre96 Yo,e$upe u MeraHoJre. Teanepamypanra*neHun. Oxono 80 "C. I"rnoxca,rbrr{AporccnaHuJ'r.Cl4Hl2N2O2. (M.u. 240,26). Lnuoxcanr6uc(2-rugpoxcuaHun). Kpucrarmr 6eroro uBera. Pacrnopuu B roprqeM cnrrpre 96 %. TeunepamypannerneHua. Oxolo 200 "C.

11 3aK.2768

wz

40 Lruorca.nfl pacTBop 40 o . Co4epxrar oKoJIo % (u/v) uILIoKcaJIt. onpedeneHue.1,000 r pacrBopa rJrl{oKcant noMelllaror B Kon6y c Konuqecm7eHHoe rrprrreprofi creKJrrHHofinpo6xofi, rppl6aBnstor 20 Mn 7 yo pacTBoparI4ApoKcI{nB rr{ApoxJropv1akr50 rvrnBoAbI,BblAepxl4Baror TeqeHue30 rvrnnI4 THTpyIor aMr,rHa ucor 1 M pacreopoM Harparfl,rr.rApoKcr,rAarrepexoAa oKpacKI4 KpacHofiK 3eJleHofi, Ao KpacHoro. pacrBopa MerLIJIoBoro I r,rHAr4Karopaul cMeIrraHHoI'o nonb3yr B Kar{ecrBe flapannenbHo rlpoBoAtr KoHrponrHufi onblr. (C2H2O). 1 rran1 M pacrnopa:aa'tpurrnApoKcaAa coorBercrByer 29,02 Mr rJrI4oKczLJU{ Lnnqepun. CH2OHCHOHCH2OH (M.u. 92,10). Ha B 14 98,0o/o He 6onee 101,0o/onponau-1,2,3-tpuona pacqeTe Co4epxur He MeHee 6e:no4nyro cy6cranqnro. crb EecqeerHat, [po3parrHaq,fycraq xcI.IAKo ; rl4rpocKorutlHa. oA,MaJIopacrBoprlMB alreroHe,HepacrBoplrM B c CNre1nueaercr ro4ofi, clprproM 96 cQupe. MeHee83,5 o (nln) u rre 6onee l,rHqepHn 85 oh. Bolnrlll pacrBop, coAepx(arqufi.ye 88,5 % (r/n) nponau-L,2,3-rpuona. orreHb vIfir IrorITI{6ecqserHas,npo3paqHafl, Cuponoo6pa3naflxr{AKocrb, 6ecqserHafl.
fl4rpocKorlnrlHag. CMeur[eaeTgr C nOlOfi u Cn]IpTOM 96yo, MaJIo paCTBOpIIM B aIIeTOHe' IIpaKTpIqeCKI'I

I,r HepacrBopulr e e$upe, )KI,IpHbIx oQupnrrx MacJrax. Inuqnn. Clr. AnrnuoyKcycHafl KlrcJrora. f.nnqnpperl{HoBaff Kncd'Iora. C30H46O4.(M.r*. 470,7). I2,13-[ugerla4po-3B1 rrrApoKcr4-1-orcoonean-30-oeat KrrcJrora. Cuecr o,- z B-r:ru[upperIIHoBbIXKucnor, n xoropofi npeo6na4aer B-usouep. llopourox or 6e;roro Ao xenroBaro-KopvqHeBarorouBera. H B B llparruvecKrr HepacrBopr{Ma BoAe,pacrBoprrMa gTaHone yKcycHofiruclore neEsuoft. +145 ao +155 ' (l oApacrBop n eranore). t"]1) . Or cnofi Hofi xpoMarorparpoBoAflr MeroAoM ToHKo Xp ouam o zpaQun. Onpe4eneHr.re KoroGF Qnu, ucnonb3yr B KaqecrBe roHKofo cJrot cIrJrI4KareJIb zs+,cycneH3pllo o (o6lo6) pofo roroBtr, r{cnonb3yt pacrBop 0,25 $ocQopnofi rucloru. Ha oApacrBopa rnrrul4pperrrHoHaHocflr 5 ur;r 0,5 xpoMarorpaQuuecxylo rrJracrrrHKy Xpouarorpasofi rucrorbr B cMecu paBHbrxo6relaos xnopo$opMa LI MeraHoJra. - xnopoSopu (5:95). Kor4a Qponr Snpyror B cMecI,IpacrBopl{releft l\,IeraHon pacrBopr.rrenefinpofiaer 10 cM, xpoMarorpaMMy rlpocMarprlBarcr s Y(D-csere rplr o6uapyxrzBarbct reMHoe [trHo BonHbr254 latt. Ha xporr.rarorpaMMe AoJrx(Ho Anr,rHe ntrHo (Rpoxono 0,3), coorBercrByroqee B-rnraqupperllHoBofilclrclore, I,IMeHbIIree (Rg orono 0,5), coorBercrByrouee o-rnl{qupper}rHosofi KI,IcrIore.lllacrunry pacTBopoMaHrrcoBoro anbAefrlAa LI HafpeBaloTnpu TeMnepaType onpbrcKrrBaroT oC n reqenue l0 uun. O6a rqrHa AoJIxHbI6rtrr oKpaIrIeHbI cI{B or 100 ao 105 AonycKaercfl rralwtvve MeHbIIIefo rltrHa Henaro-QuoJrerosrrfi rlBer; Mex(Ay HT.IMI,I cr.rHeBaro-Quoreroeoro uBera. LrryraunHoBaq Krlcrlora. CsHs NO+. (M.n. I47,I3). CogepxHr or 98,5 Ao 100,5 o C5HgNOa n nepecr{ereHa cyxoe BeIIIecrBo.

KpucTa-llnbl n9p6lxoK lrlz 6eCqseTHble Eelufi Kpl{CTannu.IeCrufi soAe; npaKTur{epacrBopi{MaB xoJroAHofi B Jlerxo pacrBopr{Ma Kurlqulefi eoge, MaJro o B HepacrBopr{Ma crll4pre 96 ,30l{pe u aueroHe. cKII,I (M.u. 100,11). Lnyraponrtfi amAeru4. C5H3O2. Macrquucras )KuAKocrt. PacrsopuM B BoAe. Oxolo 188 "C. TeunepamypaKuneHufl. InroKosa 6ernognar. C6HI 206. (M.rur.180,16). D-(+)-urcKonl{paHo3a. Eenrrfi Kpucrannuqecruft ilopollroK cnaAKoroBKyca. pacrBoprrMaB crrkrpre96 %. Jlerxo pacrBopr{MaB BoAe,yMepeHHo MoHofl4Apar. Lnroxora. C6H1206'HzO. (M.r'r. 198,I7). D-(+)-littoKonl'IpaHo3a, BKycoM. rropolxoK co cnaAKIrM Benufi Kplrcrannuqecr<nfr pacrBoprrMaB cnl'Ipre 96 %. B Jlerxo pacrBoprrMa Bore, yMepeHHo C6HI4CINO5. (M.na.2I5,62). D-lnrcxosaMzHa rI4rrrApoxJ'ropnA. IrrorcosaNrrrHa ApoxnopHA. Kpucrarru. Pacrnopuu B BoAe,rpaKruqecKl4HepacrBopllMn eQupe. go +100 o, cHuxcaroueect *47,5 o uepes30 lrun (10 % pacreop). 14! . D-InronypoHoBaq Kncrlora. C6H10O7' (M.tut.194,1). oh BbIcy[IeHCo4epxur He MeHee96,0 C6H'0O7 , B ilepecqereHa cyxoe BenlecrBo, HOeB BaKyyMe. Pacreopuua B BoAeu crltpre 96 %. .^ +36'3o. O6uapyxllBaer Myraporalll4lo: lal', +t\,7o' pacrBoptrcr IrpII onpedeneuue.0,l50r D-mroxypouonofi KHcJIorbI Konuqecm7eHHoe r{ 6esnoAHoM Trrrpyror 0,1 M pacrnopoM Terpa6yruB MeraHoJre nepeMerx1aBa1v17r noreHrlr{oMerpllqecKu,3aulurUaqpacrBop or sos.4eficrsllq rr4ApoKcr{Aa JraMMoHr.rr ylnepoAaAIIoKcI4AaBo3AyXaBoBpeM'pacTBopeHuflk|TuTpoBaHI,''. coorBercrByer 19,41 rrr 1 rur 0,1 M pacrnopa rerpa6yru;ralruoHufl rH.ItpoKcI{Aa c6H1oo7. oxcna. Ho2O3.(M.r. 377,86)..{urolruur rprroKcr{A. Iorrnur(Ill) lloporuox )KenroBaroroIIBera. B IlparrnuecKl{ HepacrBopr{M Bore. 0 pacrBop 4'/r. Pacrnop 40 rltronslrux(Ill) orcuaa r 14,1 o IorrMrq repxrropara pacrBope (HCIO4) xnopHofi KHcrIorbI. CH5N3 ' HCl. (M.r"r.95,5). IyaHuguna rrrApoxr'IoPnA. Kpncra:rnu.Iecruf ilopolxoK. B Jlerro pacrBopl.rM BoAeIr cnl4pre 96 %. I IyannH. C5H5N5O.(M.r"r.151, 14). 2-Arrauno-'7 -aurugpo-6H-nypuu-6-on. noporuox 6eloro IIBera. ArraopQHrrfi B B flparruuecKr4 HepacrBopt4M BoAe,Miulo pacrBopl{MB cnl4pre96o/o,pacrBop}rM paMeTaJIJIOB. IIIeJIOqHbIX pacTBopaxfLIApoKcLAoB u aMMrraKa pa3BeAeHHbrx cTBOpax ,{aHrpoH. Cl4H8O4.(M.r"r.240,20).1,8-,{uru4poKcl'IaHrpaxnH-9(10H)-ou' noporxoK opaHxeBoro IrBera. Kpucran.ru.Iqecxufr xlopo$opMe r4e$upe. Mano pacrBopr{MB BoAe,pacrBoprrMB 3raHoJre, nnarneHun.Orcoto 195 "C. Te,vnepamypa
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geftrepnpoBaHHar. . .{efi repnr oncrrA.'HzO (M. r"r.20,03).Bo.qa CrenensgefirepupoBaHvs.HeMeHee 99,7o/o. d,. . Oxo ro 1 .1 1 . n'] . o*ono 1,328. Teamepamypa KuneHun 101 Or<ono 'C. .{efi repnpoBannaffyncycnafl Krrcrrora.C 22H4O (M. rrr.64,08). 2. TerpagefirepoyKcycHa{ Kr.rcnora. Vrcycuar-d3 rucnora-d. - He CreneHr 4efirepupoBanr4fr. Meuee99,7 o/o. llpospavHar, 6ecqnerHa{xr,rAKocrb. Jlexo cMerrrlrBaercr no4ofi, c[rrproM 96 % r,rsQuporrl. c

d'ri. o*ono1,12.
Teamepamypa KuneHufl. Oxoro 115'C. Teunepamypa nna*reHun. Oxono 16'C. (M.r"r. 64,13).Aqeron-do.(Ho)-ArIeroH. .{efirepuposannrrfi arleron. C32H6O. o. CreneHr 4efirepupoBanr4s. MeHee He 99,5 flpospavHas,6ecuserHar)Kr,rAKocrb. graHoJrou, CMe[[saercr c no4ofi, gurvrerurQopMaMr.rAoM, s$uporur,rMeranonoM.

nii . O*ono 1.368.

dii . O*ono 0,87. n'] . o*ooo1,357. Teunepamypa KuneHun Oxono55 "C. Bodau deilmepun orccud. 6onee He 0,1o . C22H6O ArrMerrrrrcy.nrQorccng. S. (M.u. 84,18). .{efirepupoeannHfi (2H6)-.{r,rueruncynsQoKcuA. flznaerNncynr$orou4-d6.

Crenesr gefirepvpoBa*r4fl. He MeHee99,8 a/o. Bx3xar, npaKrr,rqecrn 6ecqsernafl, crrJrbHo rurpocKonvrrlnafl.)ro.rAKocrb. gTanoneu oSupe. Pactnopuu B BoAe,arleroHe,

dii .o*ono 1,18.

Teunepamypanna*reHun. Orcono 20'C. Boda u deilmepunorccud. 6onee 0,1o . He XpaHxr B Bo3AyxoHenpoHr,rqaeMoM rourefiHepe. Merauol-d4. .{eftrepuposanHsrfi MeraHorr. C2H4O. (M.rrr. 36,07). (2Ha)-MeraHorr. CreneHr 4efirepupoBanr4fl. He MeHee99,8 Yo. llpospaunaR, 6ecqnerHaflxr.rAKo crb. Clreulrsaercr c eo4ofi, cnr{prolr 95 % 14 Merr{reHxJ.roplrAoM.

dii . O*ono 0,888.

Taunepamyp KuneHun: e 65,4oC. (M.r"r.12A39).(2H)-Xnopo$opu. Xno.{eftrepnposaHnrrfix,ropoSopu.C2HCI3. po$opu-d. - He Crenenr aeirrepupoaaHr4fl. MeHee 99,7a/o. llpo:pavHa.x, 6ecqaerHar xr4AKocrb.

nii .o*o,ra1,326.

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dii . O*ono 1,51.

tr'j.O*onol,44S. Teunepamypa KuneHun Orono 60'C. Boda u deiimepun oxcud.He 6onee0,45 yo. CrcHzz.(M.u. 142,3). ,{ercaH. Eecqneru )Kr4AKo Ilparruqe cKfi HepacrBopr{M Bo.{e. ar crr. B ftu . Or<ono l,4ll. Teunepamypa KuneHufl. Orono I74'C. (M.v. I58,3).ru-.{eqnnorufi C10H22O. cuupr. ,{exano.n. BsgxaqxorAKocrb, 3arBepAeBaroruru reMneparype nplr 6'C. pacrBopr{M cnrlpre 96 % r s$zpe. flparruuecKrrHepacrBoprrMBoAe, B B 20 /?" . OxonoI,436. Teunepamypa KuneHu*Oxoro 230 "C. .{excrpan 2000 cnunft |oronsr rr3AeKcrpaHa, vMeroIqero cpeAnroro MoJreKyJrrpHyrc Maccy2 x 106, nregeHtreM noJrrrqlrKnurrecKoro xponaoSopa, oKparrrr{Bauqero BerrlecrBo culnptil n uBer. - 0,A17. Brrcyurunaror Creuenr 3aMerrleHr,r s npn 3aMopaxu BaHytu. pacrBopflercfl BoAe BoAHbrx Bucrpo lr noJrHocrbro pacrBopax. B v coJreBbix pacrBope 7 zrr.reer pH 0,1oApacrBope $oc$arHov 6yQepnoM MaKcr{MyM norxorle:avrs, rrpkr.{nHHe BoJrHbr80 srra. 2 ,{erccrpan ilonepeqHo-curnrsrfiAJrffxpoMarorpaQnn (1) fpaHynu urapoo6pa*rofiSopMbI,npnroAHbr renrr{Aos fi 6emoe Anr pa3AeneHr4r c MoJIerqrJUrpHbrMLr MaccaMrr 15 x 102 30 x 103. or Cyxue rpaHynbr r,rMelor Ao AHaMerp or 20,qo80 rrarna. xpoMarorpaQran(3) ,{ercrp an rorepeq Ho-cruuru ii Ar'rfl lpanynu urapoo6pasHofi renrr{Aos u 6emos Arrr pa3.qeneHr{r SopMlr npuroAHbr c MoneKynrpHbrMr4 MaccaMlr 4 x 103 l5 x 104.CyxnerpaHyJrbr or r4Meror ao AHaMerp or 40 ao 120 rr.mna. Lnrorcosa. .{erctpora. Crvr. 2'-.{eorccnyprArrH. CeH12N2O5.(M.vr. 228,21). 1-(2-,{eoxcu-B-D-opr{rponeHroQypaHosun)I H,3H-nzpuuunus-2,4-AHoH. Teunepamypa nna*neHua. OxonoI 65'C. .{uaropeaKTrrB 5 ur pacrBopacynbQaHuronofi rucnoru (4,5 r cynrQanurosofi KrrcJrorbr 45 vn u xJropr{croBolopoAHofi Kr4cxorbr KoHueHTprrponauriofi r 500lrn sogrr) BHocrr n xon6y, oApactBopaHarpltfl :alaTpu-ra. nocraBJreHnylo reg, npu6aBJrflror wn I0 Ha 2,5 Cueor HanbAy B TerreHr4enauu, 3areM npu6arnaror erqe 10 u;r I0 ok paocraBnrrcT 5 crBopa Harpnfi Hrrrpvra, ngGanrsrsaror, ocraBnrror HanbAy B TeqeHue uuH raAo5 BoA.trr solofi ao 100 rur. o6reu pacrBopa Xpanxr HanbAy'. llpuneHxrcTcBexenp[foroBneHHbrM, coxpaHflr nbAy. Ha r 50 .{narorupoeaHnrtfi cynrQaqun.T r cynQaqH.rr-HarptrfrpacrBopr}or MirBoAbr, npu6auxrcr 9 run xnopr4croBoAopoAHofi xuc;rorrr KourleHTpr{poranuofi AoBoArr r{
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o6teu pacrBopa noAofi Ao 100 ur. 1 nr ronyqeHHoro pacrBopa noMeilIaror B xo.rr6y, rlocraBneHHyloHa le4, upu6aBr.f,ror50 un BoAbr, 0,2 wt l0 o/opactBopaHarpus.HvrTpHTa, repeMeilr[Baror H AoBoArr o6relr pacrBopa BoAofiao 100 un. Pacrnop lpuMeHqror cBex{enpvroroBJreHHbrM. . 3r3'-{nauuHo6enlnauna rerparuApoxJropr.rA. C12HIsC14N42H2o. (M.r"r.396,16). 3,3',4,4' ilra$enunrerpaMr{H. llopouror roqrr.r 6eloro rrJrrr cnerKapo3oBoro rlBera. Pacrnopnlr B BoAe. TeunepamypantazreHun. Orcoto 280 "C c pa3nolxeHr.reM. Inaronrur Menxufi rpaHynl{posaHHrIfi [opoilroK 6eroro lrru rtor{Tlr6eroro rlBera, noryveHurrfi rr3KpeMHl{cruxo6onoqeKoKaMeHeBrxux Bolopoc teit ulu r4xocKonKoB. Ar4aroMoBbrx flparrnvecKr.r HepacrBopr{M BoAe,cnupre 96 % n eQnpe. B I,Igeuru$uqilpyror c noMorrrbro x5 Mr{KpocKo[arpn yBenurreHr4r.{ 00. AJrr ra3oBofi xponrarorpaQun luarounr Menrurfi lpaHynl{poeaHHrIfi nopoilroK 6e,roro rrJrrrfror{Tr.r 6eroro rlBera, nonyrennrrfi H3KpeMHl4crrx o6onoqeKoKaMeHeBITIHX BoAopocteft:/rliuilx ocKoJiKoB. Ar4aroMoBbrx flpanruuecKr{ HepacrBoprrM BoAe,crrr4pre96 % lr e$upe. B I44enrxQnu[pylor c noMolllbro MkrKpocKona rrpn yBenrr{eH[lr x500; o.{ruIarcr o6pa6orrofi xnoprrcroBoAopoAHofixuclorofi xouqesrpnpoBaHHofi u npoubrBaHrreM nogofi. Pasntep qacmu\. He 6onee 5 o/o lotrxHo ocraBarbcr Ha cure Ns 180 u se 6o;ree 10 o% lonxHo npoxoAr{rb qepe3 craro Jtlb125. {narovrur A!'rfl ra3oBofi xpouarorpaQuu (1) Menxufi rpauynl4posaHHstfiflopouroK 6e:roro ]rJrr4 rroqrx 6eroro rlBera, noryreuuufi H3KpeMHHcrrtx o6onoqeKoKaMeHeBIrI[x BoAopocIreituLuux ocKoJrKoB. lr4aroMoBbrx flpaxruvecKr.r HepacrBopuMB BoAe,crrrpre 96 % u a$npe. tr4geuruSurrl4pyror noMolrlbro MI,IKpocKona x500; ovurqaror o6c npu yBenr.{rreHrapr pa6orrofi xnoplrcroBoAoporHofi xuc,rorofi xouqenrprrpoBaHHofiu npoubrBaHneM

Bo,uofr.
Pasuep uacmul|. He 6o.rree5 o/o lonxHo ocraBarbcr Ha czre J\& 250 u se 6olee 10 % aonxHo rpoxoAurb qepe3curo J\b 180. .{naronrHr A!'rflra3oBofi xporrlarorpaQnH (2) Me.rrnzfirpaHynr{posagHrrfiropouroK 6eroro rrn noqrr.r6eroro rlBera, c yAenbHofrn,roulaAbrorroBepxHocrr.r oKoJro0,5 xf lr, [onyr{eHHrri Hs KpeMHucrbrx o6o:roqex oKaMeHeBrlrrrx BoAopo i't unn r4xo cKonKoB. cne Ar.raroMoBbrx flpaxruuecKrl HepacrBopr4M BoAe,cnr{pre 96 % r.ro$lrpe. B I44enrn$urll4pyior c rloMorllbroMr.rKpocKona x500; ovlrrqarcr o6npr4yBenr{qeHura pa6orxoft xnopplcroBo4opoAHofirvcnorofi ronqeurprrpoBaHHofi u nporr,rbrBaHneM BoAofi. Pas.ttep qacmu\. He 6onee 5 Yo loilxHo ocraBarbcfl Ha c?rre Ns 180. He 6onee r{epe3craro}ib 125. 10 % aonxHo rrpoxoAr4rb aHrr3[rpoBaH brfi A.ttqrasoso fi xpoMaro rpaeuu H [u arotrur cr{!'r fa3oBofi xpouarorpaSuu, cunaHv3uposaHHrrfi luarouzr Ant ArrMerr4nAuxnopcunaHOMHJrrr HMr{ noAxoArrrlLIMIj cr4ra}lH r{pyroquMH p eaf eHTaMr4. 3 Apyf
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d1i . Orcono 0,77.

l?" . Orolo 1,399. r4crrbrraHr{s neHa He neperoHrror, ectu lu6yrnroerrfi a$up He Bbrrep)KlrBaer poKcrrAbr. Ilepoxcudal. 8 ur pacrBopa KpaxMzura lrrauTLTA c fioAu.qon noMerrlarorB rlilnr{H4p c rpureprofi crexnsnuofi npo6xofi, BMecrl4Mocrbro 12 MJr v Ar{aMerpoM oKoJIo 1,5 cu, nonHocrbro 3anonHslor r{cnbrryervrulr npo6xofi v nepeeQupoM,3aKpbrBaror Me[ruBaror. Brr4epxprBaror B TeMHoM Mecre B TeqeHrre rrnH; He AonxHo [oqB30
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HagsaHuer{ KoHrreHTpaqNx nro6oro Ao6asreHHofo cra1ullugaropa AonxHu 6srm yxa3AHbI HA 3THKCTKE.

(M.r"r. 278,34). fin6yrunleHsor-1 ,2-guxap6oKcr{nar. [n6yrn,rQra!'rar. C6H22O4. Ilpospauua-a, 6ecqnerHafl,vrirLr MacnrHncras,>lslAKocrb. c;ra6o oKparrreHHaq pacrBopr{MB BoAe,cMerrrr4Baercr arleroHoM,crrrrproM96 o/o sQnpou. n Oqesr Mairro c

d,i . or 1,043 1,048. ao

to n - " .Or 1 ,4 9 0 1 .4 9 5 . (M.u. 238,28).10,11-!uru4po-5H10,11-{nrugporcap6aMa3errr.rH. C15H14N2O. -rap6oxcaun4. 5 au6euzolbflasenuHTeunepamypa nnazneHun. 205 ao 210 "C. Or (M.r"r. 160,16).fluru4poxcuuaSra:ruH. HaQ1,3-AurnaporccunaQrarrnH. C10H8O2. raruu- 1,3-ruo;r. Kpncrallu.{ecxufi iloporxoKKopr,rr{HeBaro-Qr,ro.neroBoro uBera. pacrBoplrM Bore r4crrlrpre96 %. Jlerro B Teunepamypa rua*reHun.Oxolo 125"C. (M.r"r. 60,16). HaSranuu-2,7 yuon. 2,7-InruapoxcnHaQrarruH. 1 C 0H8O2. 1
I4ronrqarue Kpr,rcrannbr. Pacrnopur,rB BoAe,cnrrpre 96 % u e$upe. Teunepamypanra*n eHua. Oxotro I 90'C. 2 r7-[nrugporccnHaQraJrHHa pacrBop 10 rrar2,7-AururpoxcnHa$ralrvtHapacrBoprrcr e 100 nr cepnofi Kr{cJrorbrKoHrreHTpr{poBaHHofi srrgep)KuBaror go o6ecqr o<uBanus,. n
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CpoxroAHocrr{-2cyr. 1229).38-tO-B-D-frroronHpaHo3Hn-(1---+3)-O-B{ururoHun. C56He2Ozs.(M.N{. -O D - r a n a x r o n r p a H o: u n - ( I - - - + 2 ) - [ B- D - x c r . r n ou p a Ho s u n - ( 1+ 3 ) ] - O - P- D r ranaKronr4paHo3r4n-(1---+4)-O-B-D-ranaKrorrupaHo3r4noxcu]-(25R)-5crcnHpocran-2a.,1 B-gNor. 5 Kpncrannbr vrilu Kprrcrannfiqecxufi loporxoK 6eroro uBera. llpaxrvvecKl{ HepacrBopl{M BoAe,yMepeHHo pacrBopr{MB graHoJre, B pacrBoMaJro prrM B crrr{pre 96 Yo,npaKTzr{ecKrr HepacrBoprrM eQupe. n {u4o4eqn.n-3,3'-rnogrrporrroHar. C36H5 3OaS.(M.u. 5 I 4,8). Kpncrannuqecxufi [opouroK 6e:roro rlBera. llpaxruuecKl{ HepacrBopnMB BoAe,JrerKopacrBoprrM B arleroHe r4 rrerponefiHolr eQHpe,MiuropacrBopr.rM cnupre 96 %. B Te.unepamypa ruralreHun. Oxoto 39 "C. lnuro6yrurrKeroH. CeHl 80. (M.rur.141,23). llpospa.ruar, 6ecqnerHar xr4AKocrb. Matro pacrBopr{MB BoAe,cMerxuBaercr c 6orsuruncrBoM opraHuqecKuxpacrBopr{re.rrefr. n'', . Oxolo 1,414. Te.unepamypa KuneHufl. Oxolo 168 "C. [r.ruronponr.uonufi eQup. C6Hl4O. (M.*. 102,17). llpo:paunar, 6ecqnerHar xrrAKocrb. pacrBoprrMB Bo.qe, OqeHs MaJro cMerxrrBaercrco cnuproM 96 % n a$upolr. Te.unepamypa KuneHun. 67 ao 69 oC . Or He neperoH.f,ror, ecnn Akrtrgorrponunoerrfi e$Np He BbrAepxuBaerr.rcnbrraHr4r rreHa poKcrr.[br. Ileporccudar.8 ur pacrBopa KpaxMiua c KanrrflfioArEAor,r rroMerrlalorB ur{nr{HApc rpnreprofi creKrtHHofi npo6r<oiiBMecruMocrbro12 wt H AuaMerpoMoKoJTo cnr,no;r1,5 Hocrblo 3arIoJIHtIorI4crrblTyeuuna aQHpoM,3aKpbrBarcT npo6rofi u nepeMerrrr{Baror. BsIgepxzBalor B TeMHoM Mecre B Ter{eHr{e naun.He Aolxuo no.f,BJrrrbcq 30 oKpaIIII,IBAHHE.

d,i . Or 0,723 0,728. to

HaseaHue KoHlleHTpa\r4flrio6oro H 4o6auenHoro cra6Hrr,r3aropa AonxHbr6rnr yxa3AHbI HA STI4KETKE,

XpaHm B 3axlnueHHoMor cBera Mecre. {nrca,rua rnApoQocQar. K2HPOa. (M.na.174,18). Kpucrarruqe cxufi nopolrroK 6e.lrororlBera, rrzfpoc Korrxr{eH. ' Oqesr JrerKopacrBopnM B Bone,Mano pacrBopraM crrupre 96 %. B XpaHxr B Bo3AyxoHenpoHr.{uaeMoM roHrefiHepe. rnApox!'ropll,I. C2gH26C1N2O6. (M.r'r. 461,3). 4,4'-14,4'-Anav'r4flnrcap6orccr{ArrHa - gtrur)auoxcr]4n6yrauonofi ruc:rorbr ArrrrrApoxnopuA. nolr.rQennt-3,3' [uuernrcon llpe.ucrasrqer co6ofi nonu-(4ulrerr,rncunoKcau), uo,ry.{aeNarrfi rrpr4rnAponr43e rron nLIKOHAeHCA\UU rr xnoprpHMerHJIcr.rJIaHa; CTeneHb froJrr.rMeAI4XIOpAr{MerHirCr{JrAHa prz:a;{;zLr (n:20400) o6ecneulrBaerKr.rHeMarrrirecKyro Br3Kocrb or 20 mm2 x s-r. llpo:pa.ruaa, 6ecqnerr{ar }Kr4AKo c pa3nuqHofiB.s3Ko crb crbro.

llparrrrvecKlr HepacrBopuMB BoAe,oqeHbMaJro pacrBopr{MAo rrpaKTuqecKu HepacTBopHM B 3TaHOne; CMeIII[IBaeTC' C gTVnaqeTaTOM, MeTHJr3TI{JIKeTOHOM,TO-

nyonoM. funern.nauuno6en3ar'rbAerrrA. C9H1lNO. (M.r"r. I49,I9). 4-fluxrerunaMnHo6eHgalrre rug. n-[uMerr{naMr4Ho6ensamAerrrA. Kpucrarmr 6eroro vnu )KeJrrosaro-6erororlBera. Pacrnopurr,r clrrpre 96 % u pa3BeAeHHbrx B Kr{cnorax. Teunepamypentra+ireHun. Oxono 74 "C. c[rrproBu fi p acrrop {u*rernn au nHo6en3aJrbAerrrAa 0,2 r ArrMerrrnarr,rltro6eHsanbAerlrAa pacrBoprror s 20 N{r cnupra 96 oA,rtpIa6aerqlor 0,5 ur 25 % xnopr4croBoAopoAHofi xucrorbr, noJryr{enuufi pacrBop BcrprxrrBalor c yrneM aKTuBr,rpoBaHHbrM u Sunrrpyrcr. OxpacKa pacrBopa He 6 u r r r { H r e H c r r B H eo K p a c K r r 0 , 0 0 0 2 5 M p a c r n o p a i r o g a . e Aon)KHa foro nsr Helo cpeAcrBeHHo rrepeAHcrroJrb3oBaHr,reM. o/o [unrerH,rauuHo6en3aJrbAerrrAa pacrnop 2 0,2 r gurvterlrJlaMplHo6eusamgerl{Aa pacrBopqror 6es HarpeBaHr{rB cMecr{ 4,5 tut BoAbru 5,5 rr.rrxnopr{croBo4opogHofiKucnorbr KoHueHTpuponauuofi. foronqr Herro cpeAcrBeHHo nepeA rrclonb3oBaHr{eM. .{lrnrern,raunno6eu3aJrbAerrrAa pacrBop (peaxrua Onnopra) 0,I25 r rrzMernJralruuo6en3anbAerr.rra pacrBopqror B oxnalKAeHnofi cuecu 35 un BoAbru 65 un cepnofi Kprcnorbr KoHrleHrpr4ponaHuoii, rtpu6aynqlor 0,1 nrn pacrnopa xenesa(III) x"rropuga. flepeg I4cnonb3oBaHueM BbrAep)r{prBatot q B 3axrHrrIeHHoM cBera Mecre. 24 or Xpauxr npu KoMHarnofireuneparype 7 cyr.; B xoJroArrnbHr{KeB TeqeHueHecKonbKI4X MEC,f,UEB.

[n*rerunarrnno6eH3a.rlbAerr.rAacrrnproerrfi pacrBop B xr,ropncroBoAopolnofi

KIICJIOTE

1,0 r 4uuerHJraMHHo6eu:a,rnAefHAa pacrBoprror e 50 Nar25 o/o xnoptrcroBoAopoAnofi KucJrorbr npulantqior 50 Mn cnlrpra 96 %. w XpaHxr B 3arquueHHoM cBeraMecre. Cpox foAHocrr4 I uec. or pacrBop B cMecu Qoc$opuofi u yrccycnofi nncnor [nnrern,rarrruHo6en:a!'rr,Aerr.rAa 0,25 r AuMerl4Jrarr,ruuo6en:anbAernra pacrBopnor B cMecu 5 r 85 % Qoc$opnofi xucJrorbr,45 r soltr u 50 r yxcycnofi Kr.rcJrorbr 6eseo.[Hoii. forosqr HenocpelcrBeHHo rrepe.rl rronb3oBaHpreM. Hc n-[u*reru,ralruno6eH3a!'rbAer[Aa pacrBop B KoHueHTpr{poBanHofi cepHofi rclrcJlore. I r nNnerurantuso6eH3aJrbAernAa cMaqzBaror KarrqM[ BoAbr npu6anlnor 4 u 3 nn cepnofi rucnorbr KoHrreHTpnponaHHofi. 4-luuerruraMnHoKopu.ru srfi arrbAerr{A. I I H I 3NO. (M. u. l1 5,22). C 3-(4-!uxreru!raMI{HoSeHu:r)npon-2-euarr. 4-fluxreruJraMuHouHHHaManbAerru. Kpncral,rbr ultLt fiopolxoK or opaH)KeBoro opaHxeBo-Kopxr{HeBofo r{Bera. .{ysAo cTBUTeneH cBeTy. r( pacrBopaM B BoAe,Mano pacrBopr,rM STaHoJre aQupe. OqeHs Ma,To B u Teunepamypa maztreHls. Oxo:ro 138'C. 4-[u nreru!'raMu HoKopurl Ho ro a,rl bAerr{Aa p acrBop 2 r 4-guverxJraMnHoKop[rrHofo anbnefuAa pacrBop.rrrorB cMecr4 100 u,r 25 %

xnopplcroBoAopoAHofi KktcJrorbr 100 MJr3TaHona. H XpaHxr B npoxnaAHoMMecre. Henocpe4crBeHHo rlepeA ircrroJrb3oBaHr4eM pacrBop pa3BoArr gTaHoJroM B 4 paza. Xpanxr B rrpoxnarHoMMecre. luuern,raunHoHaQrarrrrHcyrrrQouu"ux,roprA. Cl2H12CINO2S. (M.v . 269,14). 5-.{uvreruJraMr4HoI -na$rannHcynr$onunxnopuA. Kpucra"ruzqecxufi floporxoK xenrofo rlBera. Mano pacrBoprrMB BoAe,pacrBopr4M MeraHone. B Te"unepamypa a*reHua. Oxoto 7 0'C. n:t Xpan-ar B [poxnaAHoM Mecre. HH. luu eru.rranrrJr C6H5N(CH:)2. (M. r. | 2 l,l 9). N,N-.{nlrernnaHr4rrrrH. flpospaunafl,, Maclrfl:nr4crafl. xu4Kocrb. CeexeneperuaHHbrfi- noqru 6ecqserHrrfi, npr4xpaHeHurr TeMHeeT KpacHoBaTo-KopuqHeBoro Ao uBeTa. IpaxrxuecKr4 HepacrBopr{M BoAe,nerKo pacrBopr4M crrrrpre 96 % u o$upe. B B n , , . O K o r r o1 , 5 5 8 . TeunepamypuutenpedenbtnepezoHrcu. I92 lo 194'C; AoDKHoneperoHrrbcr He Or MeHee %. 95 2,6- lu*rewrrr aHHrrrrH. C 6H5N(C H3)2. (M. vr. | 2 l,I 9) . 2,6 -Kcvrlrvt rkrH. EecuserHar xr{AKocrb. pacrBopr{MB BoAe,pacrBopr4M crrr4pre96 %. Yry^epenHo B d,i . Oxoto 0,98. 2,3-{urrerrrJr aHrrrrrrH. C6H5N(CH3)2. (M. rrl. I2l,I 9). 2,3 -Kculnuguu. Xugxocrr )KenroBarofouBera. YrygpeuHopacrBoprrMB BoAe,pacrBopr{MB cnr{pre 96 %.

dii . Or 0,993ao 0,995. n ' ] . O r co n o ,5 6 9 . 1 Teunepamypa KuneHufl. Oro;ro 224'C. C4H9NO.(M. r"r.87,I2). N,N-lrEnaerunarleraMuA. flnu ern.irarleraMnA. Co4epxur HeMeHee 99,5o C4H9NO. EecqeerHax xrlrKocrb. Crraeruueaercs c no4ofiu 6olruuHcrBoM opraHuqecKrrx pacrBopureleil. dli . O*oro0,94. n,l .oronol,437. Teunepamypa KuneHun 165'C Oro.rro (H3CC:NOH)2.(M.r"r.116,12). 2,3-ByrauArroHArdoKcrrM. ,{uuern,rrJrr.roKcrrM. Kpucraruln.recxufi nopolroK 6e.rroro rlBerau.nz6ecqnerHbre Kplacralrrnbr. 'IparruvecKv HepacrBopr{M xonorHofi ro4e, oqeHbMuuro B pacrBopr{M rznsuleii n pacrBopr.rMcrrrrpre96 % u e$zpe. BoAe, B Teunepamypa nna+reHua. Ot<olo240'C c pa3noxeHr{eM. CynaQamuan sotte:He 6onee0,05 o/o. pacrBop. 1 r 4zuerr.rJrrnuoKcr{Ma pacrBoprrors 100 vn 5 oh .{nnrern.urJrl{oKclrMa pacrBopallaTpnfl. rr{ApoKcr.rAa. (M.r. I 85,35). N,N-lnlrerunAerlunaMr.rH. C 2H27N. flulreur.nAeunrraMlrH. 1 o/o Co4epxnr HeMeHee 98,0 (nalu)CI2H27N. Teunepamypa KuneHu.fl. Oxolo 234'C.
EIIII

(M.t. 90,08).lnuerNronrrfi sQnpyromuofi Kr{crrorbr. {nuern,rrcap6onar. C3H6O3 Secqneruatx{IuKocrl. Hepacreopr{M BoAe, B cMerxuBaercr cn}rproM %. co 96 d,- . Oxo:ro1,065. / ? , . Oxo ,ro .3 6 8 . 1 Teunepamypa KuneHu.fl. Oxono90 "C. 225,29).4-fluweruLralruuo6es:o;r. Me{unern"rosrIfi xe,rrufi. Cl4Hl5N3.(M.r"r. rlrnoerrfrxe.nrufi.
Merxze Kpl4crannbl x{eJrrofo IIBera r.rJrr.r xJrorrbfl xeJrrofo r{Jrr{opaH)KeBoro l l p a x r u u e c K L rH e p a c r B o p l r M B o I e , o r { e H bN r a J r p a c r B o p r { MB c l n p r e B uBera. o 96 %. XpoaamozpaQun. Onpe4eneHlre [poBoArr MeroroM roHKocnofiHofixpoMaror-pa$uu, rlcronb3yr B KaqecrBeroHKofo crrofl. crlrrr4Kafenb Ha xpoMarorpa$nuecxyro rrJraG. o pacrBopa crIrHKy HaHocsr 10 nrr 0,01 xeJrrofo B MerrrneHxJroAr4Mern,rroBofo pr4reu xpoMarorpa$upyror B sToMxe pacrBopuTene,$poHr pacrBopr4Tenr AonlKeH npofiru He MeHee10 cu; Ha xpoMarorpaMr\{e.qon)KHo o6HapyNlrBarbcq rorrbKooAHo ocHoBHoe nrTHo. Xpanxr B Bo3AyxoHerrpoHnrlaeMoM nourefiuepe. {urreruloBoro xeJrroro u opaueroBoro crrHeropacrBop l0 vrr AHMerIrJIoBoro xenrofo u 10 lrr oparleroBoro crHero B pacrnopqror B 300 lrn \reTrrJreHxnopr{Aa. p [u nrern.noBoro)r(eJ.rroro acrBop o pacrBopB cnrrpre96 %. l. 0,1 pacrnop e 6eHsore. 2. 0,1 %o flepexo4 oKpacKr4 pacrBopaor KpacHofir xelrofi n uHrepnanepH 3,0-4,0. N,N-[nuerr{JroKTrr,ralruH. Cl0H23N. (M.r"r.157,29).OxrulAuuerr4JraMr4H. EecueerHar )KprnKocrb. pacrBopuM B Bore, pacrBopnM B graHoJre aSupe. Oqesr MaJro H d.. . Oxono 0,765. lu,, . Oxo'rroI,424. TauneparnypaKuneHufl. Orolo 195 'C. 1,3-frauerun-2-wwuAo3odrrrAr{HoH.C5Ht0N2O. (M.rur. I14,15). N,N'-ArrMerr{JrfTI,IJIEHMOI{CBV HA.
:0

ll,, . Oxoro 1,4i20. Teunepamypa KuneHun Oro;ro 224'C. (M.ru.114,19). C6H1aNz. 1,4-fiuwerr.rnnnnepa3rrH. ,funern,rrrurrepa3rrH. Eecqneruar)Kr4AKocrt. CnreuruBaercqeo4ofirdcrraproM %. c 96 d,i . Ono,'to 0,85.
i?, . Orco:ro 1.446. TeunepamypeKuneHu.n Oxoro 131 "C. (M.rr,r. 11,54).N,N-luuernncreapr4 rraM:at. 3 luuerurcrepr{rraMug. C2gHa1NO. Tneplar Macca6eroro HJTr4 rlorrru 6e.rroro rlBera. Pacrnopurr s 6omurrancrBeopraHr{qecKr,rx pacrBopr{Te,refi, BKmoqa.f, arleroH. 'C. Teunepaml;panne+lreHun. Oxoto 51
20

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CHj S(O)CH3.(M. ru. 8,14). 7 .{uu ern.ncynrQoxcrrA. flpoepa.rnaa,6ecqnernafi, Mac JrrHtrcrar,rurpo cKorrutrH xu.qKo ar crb. Crraeruirnaercrao4ofiv crurproM %. c 96

d]i . o*ono1,10.
Teunepamypa KuneHufl. Oxolo 189"C. Boda. He 6onee10 rl.rr. B lnuernlcynrQorcuA, ucnoJrbsyeunfi cneKTposorouerpr4rl, AoJrxeH BhrAep)Kr4Barb rpeoonaHuu ArrflAr{MerrrJrcylrQoxcuAa, c ApyrHM co.qepxaHr{eM Ho
BOAbI, nprIBeAeHHbIM HI{Xe, H, KpOMe TOrO, .{On)KeHBbrAepxl4Barb cne.qyrcque AOnOIHA TeJIbHbre IdQnbrTAHufl,. MuuuaanbHoe nponycKaHue. l0 % npn il\JrrrHeBoJrHbr262 nrv,; 35 % npr{ AJrr{He

BorIHbI 270 uvr; 70 % npr{ ArrrIHe BorrHbr 290 nu; 98 % npr{ Anr.rHe BorrHbr nrra 340 l.r6oree. oupegeneHr4e npoBoAsr, r4cnoJrb3yrKaqecrBe pacrBopacpaBHeH:afl B BoAy. o (rrllu). Boda. He 6onee0,2 Xpan-arB Bo3AyxoerrpoHr,rqaeM roHrefiHepe. H oM (M.r'1. 94,13). ,{nruernrcynrSoH. C2H6O2S. Kpucrannu.recrzfinoporxoK 6eloro uBera. pacrBopr,rM BoAe, Jlerro pacrBopr4M arleroHer4crrr{pre96 %. B B Teunepamypa nnarneHun. 108 ao 110'C. Or (M.r*. 241,45). C16H35N. N,N-luuerr.rnrerpaneqnn,{nueru.urerpareurrrraMrln.
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Coaepxnr He MeHee98,0 o (uirvr)u ue 6oree 101,0 % (wrlw)Cl6H3sN. llpospauHafl,vtrnnoqrl4 npo3parrHas,6ecqnernafl,vnvlKenroBaroro uBera xr{AKocrb. flpaxruvecKlr HepacrBopr.rM Bo.qe, B cMerurdBaercr aueroHoM,cltrproM 96 % r{ Mec
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J; 9:
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dil . O*ono 0,80.

TeunepamypeKuneHufl. Orolo 26A'C. oh (u/u). Boda. He 6onee 0,3 RonuuecmreHHoe onpedeneuue.0,200 r pacrBoprror B 10 un cnprpra 96 % yt'tuTpyror 0.1 M pacrBopoM xnopucroBoAopolHofi Kt4 cJrorbrIo KpacHoro oKparrrr4 ok pannopa MerrlnoBofo eAHtrfl,, lrcrronb3yq B KarrecrBenHAuKaropa 0,1 rr,rn 0,05 KpacHoro. I rtl 0,1 M pacrBopa xJlopLtcroBoropogriofi Klrcnorbr coorBercrnyer 24,15 ur Ci6H3_5N. 2,6-!nverunQeuo.n. C6H3OH(CH:)2. (M. r"r. 122,1 6). BecuserHrre [rorbqarbre Kpr4craJrJrhr. Mano pacrBopr.tM BoAe,JrerKo B pacrBopr{MB cnr.rpre96 % raeSzpe. TeunepamypaKuneHufl. Orolo 203 "C. TennepamTtpa mnzJleHun.Or 46 ao 48 "C. 3,4-.{u*reru"nSeuo.n. C6H3OH(CH) z. (IvI.ru. I 22,16). Kpracrannu 6eloro r{Jrr.r noqrri 6eloro rrBera. Mano pacrBoprrMB BoAe,JrerKo pacrBopr{MB cnr4pre96 %. TeunepamypaKuneHun Orolo 226'C. TennepamypennaqreHun.Or 25 xo 27 "C.

Gtglil

HCON(CH: )2. (M.u. 73,10). ln*rern.n$opnaarvrna. flpospaunar,6ecqaeruar)Kr{AKocrb. Crraenrprnaerc.f, c noAofiu cn[proM 96 %.

dii . o, o,g4g 0,952. to

Tennepamypa KuneHutOxono 153"C. Boda.He 6onee 0,1o . C7Hl7NOz. (M.r"r. 147,22).N,N-,{anre.{nrretnnQoprvrarunlagrr3TrrJrauerarrb. rluQoprrraMr.rAa Ar4arlerarrb. n,, . Orolo 1,40. Teunepamypa KuneHun 128ao 130'C. Or (CH3)3CNH2. (M.r. 73,I4). 2-Auuno-2-rqerunnponaH, 1,1-.{nnretnJrsrr{JraMuH. mpem-ByrHJraMr.rH. Xu.uxocrr. CMeruueaercr cnuproM96 %. co

d',i. oxono0,694. n1l.O*ono 1,378.

Tettnepamypa KuneHun Oxono 46"C. (M.u. 88,I 5). 1,1-.{nruernrr3rrrrrMernnonrrft eQnp.(CH3)2CHCH2OCH3. mpem-ByrllJlMernnonrrfi o$np. BecqserHas, flpo3paqnar,BocnJraMer{rroilIarcr }Kr{AKo crb. pacrBopr.rM BoAe, O.{eHrMaJro B cMerrrr,rBaerc{grauoJroM oQuporra. c N n') . O*ono 1.376. MuuuuaauHoenponycKaHue. rr.teHee % upraAJruHe He 50 BoJrHbr uv'; He MeHee 240 8A % npu Anr.rHe BoJrHbr uwl'HeMeHee % rpri AnuHe 255 98 BoJrHbr nrra. 280 pacrBopa Onpe4e.rreHr.re npoBoArr, Hcnonb3yr KarrecrBe B cpaBHeHur soAy. .{uueroxcrnponaH. CsHnO 2. (M. u. 104,I 5). 2,2-fluueroKcr{rponaH. Eecqsernat xI,IAKocrr. Pasnafaercqno4 geficrBueMBJraxHoro Bo3AyxarlJrr4
BOAbr.

PacrnopuM sraHonelr aQupe. B

d]i . o*ono0,847.
n',]. O*ono 1,378. Teunepamypa KuneHun Oxoro 83 "C. [wllugut 6polur4. C2sHlsBrN:.(M.u. 380,28).3,8-.{narr,rnso-5-uernn-6-QeaNnfl. Qenanrpu rr4nu 6polru4. Kpucrarrbr reMHo-KpacHoro rrBera. pacrBoprrM BoAe Maro pacrBopr.rMBo.qe reMneparype "C, ylaepeHHo B npn 20 B rpr oA,rpaKTI,rqecKH TeMfleparype "C r4cnr{pre66 60 HepacrBopr,rM n aSrape. pacrnop fnun4nn 6ponuga n cymQanoBorocrrnerocMerrraHHufi OrAe;rrso pacrBop*or 0,5 r [uMlrp'Lrfl,6porr,rH4a u 0,25 r cynrSanoBorocuHefo B granon- BoAa pacrBopr,rrerefi (1:9) u repeMerrruBarcr. pa30 nn ropx.reficMecrr O6a pacrBoplrrerefiAo crBopacMe[rr,rBaror AoBoAsr r4 rofi xe cMecbro o6reN{pacrBopa pacrBopa pacrBopal4,A o (o6lo6) 250 nn. 20 un rorryrleHHoro cMeIIrI4Baror 1an c 20 pa3BeAeHHofi cepnofi KrrcJrorbr, rrpeABapr{TeJrbHo npr.rvrepno MJr 250 BoAbr, AoBoMT noaofiao o6lena 500 *r.u. EEE

XpaHrr B 3alIu[IeHHoM or cBera Mecre. rerl[nuarpHn apceHar.Na2HAsO4' 7H2O. (M.vt. 312,0).fiunarpur. rl4ApoapceHar, Tatu4pur. Ha Kpzcrarrbr, BbrBerpr4Baloruuect Bo3Ayxe. Jlerro pacrBopr4MB BoAe, pacrBoprrM B rnrrqepr{He, MaJropacrBopl{M B crlr{pre no 96 %. BoAnufi pacrBop r{Meeruenor{Hyro peaKlrl4ro naKMycy. d'o . Oxono 1,87. TeunepamypanitaztreHun. Oxolo 5l 'C (npu 6srcrpoM Harper,auuu). ' {uuarpnn rnspoQocQar. Na2HPO+ l2H2O. (M.r"r.358,17). Harpufi QocQopno. xucrrrfi ABy3aMeulensrrfiI 2-nolnufi . Harpnn $ocQar ABy3aMerrlesnufi llpospa.rHue, 6ecunerHbreKpucrannbl. BunerpuBalorc-s Ha Bo3Ayxe. pacrBopl{MB crllrpre 96 %. Jlerxo pacrBopnM B BoAe,oqeHbMaJro oh.Pacrnop 90 r/n. {uuarpHn rngpoQocQara pacrBop 9 lnHarpnr rn4poQocQara pacrBop 0,2 M ru4po$ocQara rrrrvrpara pacrBopqror B AocraroqHoMKonI4rIe35,598 r Ar4Harpr{x u crBe BoAbr pas6auslor o6rela pacrBopaeoAofi.qo1000,0N{r. {uHarpnn rn4poQocQar 6e:noanufi. Na2HPOa.(M.pt. 141,96). cKorrnqHrtfi . 6e;rsrfi Kpr,rcrannuqe cxufi noporrloK,rl4l-po pacrBoprrMB BoAe,or{eHbJrerKopacrBoplrMn rop.xuefrBoAe,oqeHbMtulo Vuepenuo pacrBopuMB cnr4pre96 %. ' lHnarpua rn4poQocQar; 4uruApar. Na2HPOa 2H2O. (M.u. 177,99). Ha BblBerpl4Barorct Bo3Ayxe. FecqserHHe KpucranJrbr, Pacrnopuu B Bo.[e,orreHbJrefKopacrBopuM n ropxuefi BoAe. ' .{unarpun rrApolllrrpar. C6H6Na2O7 1,5 H2O. (M.r'r. 263,11). Harput ql{rpar rucrrrfi. lunarpux 2-ua4poxcnnponaH-1,2,3-rpvtxap6oxcurarxucrrrfi, cecKBHfr4Apar. Ilopouror 6eroro rrBera. qeM B 2,ractsx BoAbr, B npaKTLItrecKH HepacrBopl{M crll4pre 96 %. Pacrnoplttu MeHee Harpnn cynr$n4. {nnarpun cynrQrg HoHarrrApar.Crvr. ,,{nHarpur rerpa6opar. Eypa. Cna.HarpHn rerpa6opar. .(unarpnr rerpa6opara pacrBop. Clr. Harpur rerpa6opara pacrBop. (NO2)2C6H3COCI.(M.r"r. 230,56). 3,5-!uuurpo6eu,{nnurpo6enson,'rxr'ropr.rA. 3Orrnxnopr{A. KprrcrannblB Kpucrallz.Iecx[fi fioporxoK cBerno-xeJrrofo rlBera rrnprxeJIToBarbIe
BHAE IIIJI.

'

Pacrnopnu n e$upe; B BoAeH cnlrpre 96 % pa3raraerc-f,. Teunrp o*ypa nna6n eHua. Oxolo 68'C.

(M.u. 212,12).3,5-fiuHurpofnnnrpo6eHsofiHan Kncrlora. (NO/2C6H3COOH. 6eHsofiHas Klrcnora. Kpucra;ubr [or{Trr6ecqretme. B B nerKopacrBopuMa clulpre 96 %. Malo pacrBopr4MaBoAe, oqeHb Teanepamypa nrazreHua.Oxono206 "C. pacrBop 2 o/o.Pacrnop r/.nn cruprc 96 Yo. 20 [nunrpodeHsofiHofi rcuc.uorsl (M.tnt. 1,3-[uuurpo6euson. u-fiuHl4rpo168,11). [nnurpo6euso,'r.C6H4(NO2)2. 6eHsor.

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Kpzcrarnuqecrafi iloporroK r{Jrr4 Kpr{criurJrbr )KeJrroBaroro rlBera. flpaxru.recKr,rHepacrBoprlM BoAe,Ma;ropacrBopr{MB cflr{pre 96 %. B TeunepamypamazreHun. Oxono 90 "C. {uHurpodensora pacrBop. Pacrnop 10 r/n B cnr4pre96 %. .{Hrurrpo$ennrrnspa3nH. (NO2)2C6H3NHNH2. (M.r"r. 198,15). 2,4-!nHrrrpo$enunrulpa3rrH. Kplrcra.rrnbr KpacHoBaro-opaHlKeBofo rlBera. O.{eHr ManopacrBopr4M BoAe,MilJro pacrBopr.rM cnr4pre96% u a$upe;pacrBopr4M B B B 3TVnaUeTaTe. Te.unepamypq ma+reHun. Oxolo 203'C c pa3no)KeHrreM. pacrnop {uHnrpoQeHn.irrn4pa3rrHa yKcycHo-xJroprrcroBoAopoAHbrfi 0,2 r Ar.rHurpo$eHrlnrtrApalraa pacrBoprror s 20 MJr MeraHorra, rtpu6aBJrrror 80 lrn cMecII paBHbIX o6revon yrcycHofi KrrcJrorbr pa3BeAeHHofi o/ou ,-,Iopucro30 BoAopoAHofi rncnorrr 25 % u nepeMerirnBaror. I-oronqr HenocpeAcrBeHHo lepeA HcrroJrb3oBaHr{eM. lnnnrpoQeHrrJrrr{Apa3r{Ha xJroprrcroBoAopoAHufi pacrnop pacrBopqror rpr.{ HarpeBanvrpt xnopr4croBoAopoA0,50 r guHurpoQeHl{nrl{Apa3rrHa B o/o, uofi xprc,rorepa3BeAessofi8 Aosolxr o6rev pacrBopa reM xe pacrBopnTeneM Ao 100 run, oxnalcAaror z Su.rmrpyror. lorosqr He[ocpeAcrBeHHo flepeA prclonb3oBaHr,reM. 2 r$-luttnrpoQeHn;rrunpa3HHa crrrproBbrfi pacrnop 0,5 r 2, -grznurpoSeHlrnruApa3r4Ha cMerxrrBaror 6 ul xnoprrcroBo4opo4uofi xucc JIorbIKoHTIeHTpI{ponauuo[ rlepeMe[rr,rBaror Hcire3HoBeHrrr H KpacHo-opaH)KeBoro Ao oKpalxt{BaHl4-s ocaAKa.lTpu6ayJrrror20 un sTaHoJra, HarpeBarorcMecb Ha eoAqHofi 6ane Ao nonyrreHvfl fipo3par{HoropacrBopa, oxnaxAaror H AoBoArr gTaHonoMAo 100 vrn. flonyveHusrfi pacrrop xpaHrr B xonoAHoMMecre. Cpox roAHocrr4- 3 rraec. 2,4-!nuurpox.nop6eH3orr. CIC6H3(NOz)2.(M.r"r. 202,55). 1-Xnop-2,4-sunurpo6eriso,'L B:reAuo-xeJlToBarble Kpllcrannbr. [Ipn 6ucrpola HarpeBaHrrr.r Bbrcorofi reuneparo Mo)KeT B3pbrBaTbc_s. rypbr llparruuecKr{ HepacrBopr.rM BoAe,pacrBopr.rM 3raHoJre eQvpe. B B u C26H42O (M.rnr.4 18,6). {unonn,rQralar. 4. Becqsernafl.Hrrv cBerJro-xeJlToro uBera Bq3Katxn.rlKocTb.

dii . or o,97 0,98. ao

r 1,, r 1 ,4 9 2 o 1 ,4 9 9 . .o 4 Boda.He 6o,ree oA. 0,I (M.r"r. 1). 88,1 1,4-!uorcau. [norccau. C4H8O2. llpospaunaa, 6ecqnerHar x{r.rAKocrb, cra6rru nprrrrHbrM co 3anaxoM. Cn4eurueaercrsoAofiH 6onrurnHcrBoM c pacrBopurenefi. opraHr4qecKux
20

d]i . o*ono1,03.
Teunepamypasameepde*aHun. 9 ao 11 'C. Or oh. Boda. He 6onee0,5 He neperoHqror, ecJrI{AI,IoKcaH BbrAep)KHBaer He rrcrrbrraHr,rr nepoKcr4Abr. Ha pr"upacrBopa KpaxMana c Kailvfl, fioAulou rroMeuraror B [Ieporccudut. 8

III4nrrHIp c npl4reprofi crexJrquHofi npo6xofi eMKocrbro 12 rvt 14 Ar4aMerpoM oKono 1,5 cu, 3aflorHqlor noJrnocrbrollroKcaHoM rr nepeMerrusarcr. BrrIeplI(IrBaIor B TeMHoMMecre B TeqeHrle30 rvrxH. He lolxso o6Hapy>y.vrBarbcfl oKparxuBaHII_S. ,{noxcan, ucnonb3yellrtfi.q,r-sxl4AKocrHofi cqzurulrrrflr\Lrvr, AoltlxeH6rtrr coorBercrnyrcrqefr creneHu qilcrorbr. [Horccana ucxoAusrfi pacrBop 0rl o/o 1,00 r AI4oKcaHa pacrBoptrcT B BoAev AoBoAsr o6relr pacrBopa reM )KepacrBopr4TeJreM 100,00 vr. 5,0 Mn nonytreHHoropacrBopa AoBorrr eoAofi 4o 4o o6reua 50,0 *rl (1,0 ur/un). {uorccaua pacrBop 0r0S oh 50,0 ur r4cxoAHoropacrBopa Ar{oKcaHa AoBoA{T no4ofi 4o o6rerr,ra100,0 un (0,5 rr,r/lan4noxcaua). lnorccaHa pacrBop 0r0l oh 10,0 rran 0,05 yo pacrBopa llroKcaHa AoBoAtr nogofi Ao o6renaa50,0 lrn (0,1 rr,rrlu,r 4r.roxcaua). {H(oxrageqH,r)-3 13'-ruo4unporrroHar. C 42HB2O (M. na.6 g3, I ). 45. Kpucrannuqecxufi iloporroK 6e;roro rlBera. rlparra'recKll HepacrBoplrM Bore, JrerKo B pacrBoprrMB MerrrJreHxnopr{Ae, yMepeHHo pacrBopr4M aueroHe, crrr4pre96 % u nerpo-refisou eQrpe. B TeunepamypannerreHun. Or 58 ao 67 'C. 212''flu(orcTaAerIHJrorccu)-5r5'-cnupo6n(l13r2-gworccaeoceapunan). c4rH82o6p2.

s
:4

(M.r'r. 733,0).

a *

Tnep4oe,aocxoo6pa3Hoe Berqecrso 6eroro rlBera. IlpaxruuecKll HepacrBopl4M BoAe,pacrBoprrMB pacrBopax rr4ApoKap6oHaron. B Te.wnepamypa maztteHua. Or 40 ao 70 "C. [uoxragerlnrArrcyrrrQna. C 3 6H7 2. (M. r. 57 l,l). 43 llopouron 6eroro rlBera. flpaxruuecKr4 HepacrBopr{M BoAe. B .C. Te.vnepamypa nrazteHua. Or 53 ao 58 [HcynrQnH cuuufi. Cna.Cy.nreaHonrrfi cunnfi. (M.u. 256,33). 1,5-luSenurrnorap6a3on. lurueou. C13Hr2N4S. flopourox cl{HeBaro-ilepHoro I4nuKopr4rrHeBaro-trepHoro, irepHofo qBera. flpaxznu TrzrrecKu HepacrBopr4M BoAe,pacrBoprlMB cnr.rpre96 oh. B XpaHxr B 3arrluqeHHoMor cBera Mecre. lururoHa pacrBop 0105o . Pacrnop 0,5 r/n n xnopo$oplte. loros-sr HenocpeAcrBeHHo nepel Hcnonb3oBaHrreM. '{nruloHa pacrBop 010012o/o 40,0 rrar pacrBoprrcr n x.rropo0opMe AoBoMT o6reu pacrBopareM x{e pa_ Alrrr43oHa r4 crBopr'rreneM 1000,0un. 30,0 Mn nonyqeHHoro Ao pacrBopa.4oBorrrxnopo$opuou 100,0 nr.n. Ao o6senaa Vcmauoerca mumpa. Koru'recrno pryrn(Il) xnopvAa, sKBr.rBaJreHTHoe 0,1354 r HgCl2, pacrBoptror B cMecr{ paBHbIXo6reNros cepnofi KrrcJrorbr pa3BeAeHsofi 9,8 o/ou soIJ;I I'I IoBoA-sr o6reM pacrBopa rofi xe cMecbropacrBoprrrelefi ao 100,0 wn. 2,0 Mn nonyqeHHoropacrBopa AoBoArr cMecbropaBHbrx o6reMos cepnofi Kr4cJrorbr pa3BeAeHHofi oh u nogrt.qo o6reua 100,0 vr"rr 9,8 (pacrnop co_

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20 B Aep)KLIT ppm Hg). 1,0 un ronyileHHoro pacrBopa rroMerrlaror AenlrrenbHyro o/o,140Mir BoAbr BopoHKy, npu6annnor 50 ur cepuofi KncJrorbr pa3BeAenHofi 9,8 ra 10 un pacrBopa 200 rln rI{ApoKcI{JIaMLrHa rr{Apoxnopul,a. Turpyror npnroroBneHHbIMpacrBopoM ALITH3oHa; rrocne Ka)KAoronpu6aeleHlafr 'tlaTpaHTa cMecb
BCTp-f,XUBaIOT ABaAqaTb pa3, K KOHIIy TI4TpOBaHUT CMeCb OCTaBJTTTOT Anq pa3Ae-

Jrerl'las, cJIoeB,3areM or6pacrrnaror xnopo$oprvrHrrfi cnofi r4npoAonxaror ruTpoBaTbAO CHHeBaTO-3eJIeHOrO OKparXr{BaHr4t. KonuqecrBo pryrl,I (3) s MI{nnHrpaMMax,3KBr4BaneHTHoe coAep)KaHprro ruTIr3oHaB oAHoM l.lttlrlrvrnlaTpe pacrBopa, BbrirucJrrror no Qopruyne: 3 :201Y, rle V - o6telt pacrBopa AurI{3oHa, r43pacxoAonanHrrfi rHTpoBalaue,B MrlJrHa nr4nuTpax. 5,5'-.{nru o6uc(2-nnrpo6enrofi Hafl KrcJrora). C l 4H8N2O3 (M. ru. 25 6,34). 52. -Kap6orc u- 4 -uurp o$ euz.u4ucynr u4. Pearrus 3.rnuaua. D TNB . 3 Q llopourox xeJrroro rlBera. Yuepeuuo pacrBopr{MaB cnr.rpre96 %. TeunepamypannaBneHun. Oxolo 242'C. (M.r"r. 156,25). Tonyol-3,4-guruon C7H8S2. 4-Merut6eHson-1,2[nrnor.
APITI{OJI.

Kpucrar.rrrr 6eroro rlBera, f r{rpocKorruqHbr. Pacrnopuu B MeraHoJIe pacrBopax rrrApoKcnAoB r.r rrleJrotrHbrx MeraJrJroB. Teunepamypenna+neHua. Oxoto 30 "C. XpaHxr B Bo3.uyxoHenpoHr{rlaeMoM rourefiuepe. {lrruo.na peaKTr{B I r 4urrEola pacrBopsrcr s 2 MJIKr.rcnorbr rr,rorJruKoresofirr AoBoArr o6reu pacrBopa 2 Yo pannopoM HaTplr1^A rHApoKcIrAaAo 250 rvrn. foros-f,r Heno cpeAcrBeHHorrepeA r.r c[oJrb3oBaHrr eM. (M.r'r. I54,24). mpeo-I,4-lr.rvrepxanro6yrau-2,3-guon. {uruorpel{rorr. C4H10O2Sz. qHbr I4ronr.rarH e cl a6o rurpo cKorrr4 e Kpr.rcrannbr. ,Ilemo pacrBopr4M BoAe,aueroHe H STaHoJre. B XpaHxr B Bo3AyxoHerrpoHr4uaeMoM rourefiHepe. (M.r. 169,23). luQenu"rraMnH. NH2C6H4C6Hs. Kpucrarrur 6e;roro rlBera. Ma-uopacrBopr{MB BoAe,pacrBoprlMB cnr4pre96 %. Teamepamypa nnaBreHua.Or<olo 55 'C. Xpauxr B 3aqr4rrleHHoM cBera Mecre. or pacrBop .{uQexu.naMrna pacrBopttor B cMecrr 10 u.rr cepnofi KrrcJrorbr 0,05 r 4uQeHunaMI,IHa KoHrIeHTpt4posaHHofi u2un BoAbr. o/o [nQennraMrrHa pacrBop 0rl Pacrnop I r/rl n cepnofi KxcJroreKoHrleHTpvponauHofi. Xpanxr B 3axIHrrIeHHoM cBera Mecre. or lnQeun.naMrrHa pacrnop L %o Pactuop 10 r/.rrn cepuofi KtlcJroreKoHrleHTpr.rponauuofi. Pacrnop AonlKeH 6urr 6ecIIBETHhIM.

1 8 .3 a x .2 7 6 8

.{nQennraMr{Ha yKcycHornc;ruft pacrBop pacrBoprrors 100MnyKcycHofi rucroru remnoft z upN6aanxror I r 4r,r$eHraJraMr,rHa . 2,75 rrl KrrcJrorbr cepuofi KoHIIeHTpI4poeanHofi [epe,q forossr HerrocpeAcrBeHHo ucnoJlb3oBaHrleM. CzoH a. (M.u. 330,40).9,10-[uQeHrIrIaHrpaIIeH. lr.rQeun.naHrparlen. r Kpncrannuqecruft loporxoK or xeJrroBaroroAo xenroro IIBera. nerKopacrBopllMe e$npe. B flparru.recKr,rHepacrBopr,rMBoAe, 248 nnaaneHua. Or<ono "C. Tettnepamype [uQenn.rrdenrnAnn. C24H20N2. (M.r"r. 336,42). N,N'-!uQenur6eHsLIAHH. uut-4,4'- arIaMLIH. N,N'-,{zSenun6nQe IIBera.llpaxorreHKoM Kpr,rcralln.recruii nopo[roK6enorouru 6eroro c cepoBarblM pacTBopI,IMaIIeToHe crIHpTe %. 96 B I4 B BoAe, MulJIo Tr.rqecKr,r HepacTBopr,rM Tu,'tnep amypamaln eHua.Orcoto248' C. or Xpanxr B 3arrr[qeHHoM cBeraMecre. (M.u. 225,09). KrrcrrorbraMl{Ho3rl{lonufi rQup. C14H16BNO. .{u$eHn.n6opHofi xreJrroBaroro IIBera.flparrnuecrz cJrerKa Kpucraruruqecrnfi noporxoK6eroro HJrr.r o/o. pacrBopllM cnl,Ipre B 96 HepacrBopuM BoAe, B 'C. Teunepamypa nna*neHua. Oxono 193 Cl3Hl3N3.(M.u. 211,27). NrN'-[uQeHr{JrryaHr{ArrH. -x(enroro IIBera. cB MenxoxpracrarJrr4qe uoponror 6eroro rdJrr{ erJro cxufi pacrBopl,IM pacrBopr,rM cnrlpre 96 o , MaJIo pacrBopr4M BoAe, B B JrerKo O.regs MaJro pacrBoprlM xnopo$oprr,re. n n e$upe,yrv{epeHHo (C6H5NHNH)2CO.(M.r"r. 242,28). 1,5-,{u$enumap6ou.{nQeHH.nxap6aur4. I.ufr44pa3v4. po3oBeer Bo3Ayxe. Ha O.IeHr Kpncrzurlu'aecKuia nopouroK 6eroro rlBera,rrocrerreHHo ohu yrcycnofi KLIcJIore JIepacrBoprrM arleroHe, pacrBoprrM BoAe, B crrupre96 MaJro B
l-ffsofi. Tentnepamypa Ma*rewls. Ororo 170 "C. 3ona.He 6onee0,1oh. Cyna$amuafl Xpanxr B 3arrIurIeHHoM cBera Mecre, B cocyAax opamKeBorocreKJra. or lnSeuu.nrcap6arnga pacrBop reAsHoft Ir AoBo0,2 r 4uQeuulxap6a,:v4apacrBoprror s 10 r,rr yxcycHofi KLIcJIoTbI pacrBopa crr{proM 96 % lo 100 rran. A-sro6reN,r nepeA I,IcrIoJrb3oBaHI4eM. foroesr He[ocpeAcrBeHHo ). [uQenn,rrcap6a:on. C I 3H I 2NaO. (M.u. 240,27 1,5-[uQenumap6asoH. Kpracrannuqecrnfi flopouroK opapKeBo-xeJlToroIIBera. xnopoB flparruvecKr,r HepacrBoprrM BoAe,oireHbJrefKopacrBoprrMB crlrlpre 96 o/o, Qopue u 6eHsore. TeunepamypamarreHun. Oxono I57 'C c pa3JrolKeHLIeM. npI,IHapacrBop B crr{pre 96 %. PacrnopeHHe npoBoA.f,r Pacmeop undurcamopa:I o/o Cpor roAHoFpeBaHr{H BoAsHoft6ase. Xpanar no Qraroxax opaHxeBoro creKJra. Ha crr4 - 15 cyr. .{uQeHn.nrcap6aroH-pry'rnuft peal<rnB Pacreop I. 0,1 r 4uSenunrap6asona pacrBopsrcr B crr{pre 96 oh r{ AoBoAtr o6terr,r pacrBopa reM xe pacrBopr,rreneM 50 ur. Ao

pacrBopnor B crr4pre 96 % r4AoBoArr o6aevrpaPacrnop II. I r pryru(Il) xnopraAa crBopa reM xe pacrBopr.rreJreM 50 rr.rn. Ao paBHbre pacrBopoBI u II. Clreruusarcr o6reurr a3orr. C r sH r 1 NO. (M. u . 22I,25). 2,5- [u$eur,rJroKc a3on. .{uQenu;roKc floporuor 6eroro rlBera. yrdepeHHo pacrBopr,rM llpaxrzuecKr4 HepacrBoprrM BoAe,pacrBopr.rM MeraHoJre, B B B u re4xnofi yrcycuofi. Ar.roKcaHe Kr,rcJrore TeunepamyparuaaneHun.Oxono 70 "C c pa3noxeHueM. l'.., . Oxono 1260. Onpe4eneHr4e npoBoArr rrpn AJrrrHe BoJrHbr r4crronb3yr B 305 nrra, pacTBoplrTeJrr KaqecTBe MeTaHoJr. ,{uSennnoKca3oJr, ucnonb3yeurrfi Ars xr{AKocrHofi cqzurnrilflr\vtvr, AonxeH 6uru coorBercrnyroqefi crerreHuqlrcrorbr. {uQeHn.nQenn.rrenoKcnAanoJrnMep. llonuuep 2,6-guSenun-n-$euuJreHoKcxAa. flopucrue rpaHynbr lrapoo6pasHofi Qoprr,ru 6eroro r{Jrr{ilolrrr4 6eroro qnera. PasMep rpaHyn yKa3brBaroT HcnbrTaHrr'.x, KoTopbrxoHr4krcrronb3yloTcr. B B (M. flnx.nop6eH3orl. C 6H 4C12. r"r.| 46,99). 1,2-fiuxtrop6eusor. Eecqneruafl , MaclrflHvrcratxlrAKo crb. flparrvvecKr4 HepacrBopuMB BoAe,pacrBopuM B sraHone u eSnpe.

dii . o*oro1,31.
Teunepamypa KuneHufl. Oxono 180'C. .{ux.uopueraH. Cu. MernJreHxJroprrA. (M.u. 22I,0). 2,2-fiux:l.opBprnvilrLnrrerunQoc$ar. {ux.rropoQoc. CaH7Cl2O4P. XHArocrr or 6ecqserHofo Ao KopuqHeBaro-xeJrroro rrBera. Pacrnopuu B BoAe,cMerrJr{Baercr 6onrruzncrBoM opraHur{ecKzxpacrBopurenefi. c

/?" . orono 1,452. Krrcrrora. CHCI2 COOH.(M.r"r. 128,94). [ux.nopyrccycHan Becqnernar xlrAKocrr. CuerunBaercq c no4ofi, cnrrproM % u e$zpona. 96 dii .O*ono1,566.
n,, . OKorro1,466. TeunepamypaKuneHut Oxoro 193 'C. {nx.rropyrccyurofi KrrcJrorbrpacrBop 67 vn Ar.rxnopyKcycHofi Kr{cJrorbr AoBoArr eoAofi Ao o6reua 300 nar u uefirpanr{3yror pacrBopoM aMMr,raKa KoHrIeHTpr{poBaHHbrM cnHeil naKMycoBofi6yrvrare. no Ox.naxrr Aaror, upu6auxror 33 rr,rn AlrxnopyKcycuofi Kr{cJrorbr AoBoAsr soAofi Ao o6rena 600 un. {nx;ropQeHorruHAoQeno,ra HarpHeBafl corrb. Cl2H6CI2NNaOz' 2H2O. (M.r. 326,1). Harpux 2,6-guxnop-N-(4-rHapoxcu$enu.rr)-1,4-6eusoxnHoHMoHorrMrrH) rytrr{Apar. 2,6-luxlop$ eHonuHgoQeHonr r HarpLrfl,. flopourox reMHo-3eneHoro rlBera. Jlerxo pacrBopuMaB BoAeu crrrpre 96 %. pacrBopa Bolsufi pacrBop rdMeerreMHo-crrHroro oKpacKy,Koropa-s npn no.qKr{cJreHrrr{ nepexoAHrB po3oByro. 2r6-[uxtropQeHo.nungoQeno,rar Harp]rfl. Cu. [nxropQeHoJ'rrrHAoQeHo.na HaTpneBafl coJrb.
20

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rnrpoBaH n u[ p acrnop {ux.rropQeHoJrr{HAoQeHona 50,0 nr 4nxnop$euonuH4o$eHonauarpzenofi conrapacrBopfltor e 100,0 MJIBoAbILI SHnrrpyror. mumpa.20,0 rvr acrop6unonofi KtrcJlorblpacrBoptrcr e 10 MJrcBexeVcmauoerca 20 npr.rroroBneHHoro % pacrBopa (200 rh) ueraQocQopHofi KIrcJIorbIIr AoBoAtr pacrBopa6ucrpo rl4rpylor o6reu pacrBopaeoAofi ao 250,0 ur. 5,0 Mn rroJrlrqeHnoro pacrBopoM4vxnop$eHonuHAon$eHona unrpo6roperKlr c IIeHofi us rrprrroroBneHHbrM 10 B He Ao AeneHnr0,01 rran po3oBorooKparuuBanvrfl, ucqe3arcrrlefo TeqeHI,Ie c, npelrx Pacreop 4Iaxnop$eHonllHAon$enonapasrr{TpoBaHr4q AonxHo 6rrrr se 6oree 2 rvru:e^. BoArr nogofi Ao [onyqeHr{r pacrBopa, I Mn Koropofo coorBercrByer 0,1 rr,tracKop6nnosofi Klrcrlorbl (C6H8O6). [epe.qI4c[oJIb3oBaHreM. HerrocpeAcrBeHHo Cpor roAHocrr.{ 3 cyt. TrarpycraHaBnnBaror 2r6-fiuxnopQeno,'ruHgoQeuo,'Inra Harpnfl pacrBop 0,001 M. Cu. llrxlopQeHorrrrposaHHrIft pacrBop. nnngoQeHoJra .{ux.rropQnyopecuerrH. C20H10Cl2O5.(M.rur. 401,2). 2,7-[uxtropQ.nyopeclleuH. 2-(2,7 -fiuxnop-6-rn4porcu-3 -orco-3 H-xcasres-9-un)6ensofi Har KLIcJIora. flopourox or xeJlToBaro-KopuqHeBoro )Kenro-opaHxeBoroIIBera. Ao pacrBoB B Ma;io pacrBopr.rM BoAe,JrerKopacrBopr4M crrrrpre 96 % H pBBeAeHHbIx pax frrApoKcr{AoB c ulenoqHbrx MeraJrJroB o6paeoeaHl,IeMpacrBopa c xeJlToBaroHepacrBopuMn eSupe. sereHofi QnyopecueHquefi,npaKrI4qecKI,I 2r6-fwxlopxrrHoHxrloprrMl{A. C6H2CI3NO. (M.u. 210,45). 2,6-[uxtropxllHou-4xxopuMaA. 2,6-[uxlop-N-xnop- 1,4-6eusoxI{HoHMoHoHMttH. IIBera. Kpucralln.{ecruii noporuoK or cBerJro-}KeJrroro 3eneHoBaro-)KeJlToro Ao paB flpaxur.recKu HepacrBopuMB BoAe,pacrBopr,rM crrrrpre 96 % 14pa3BeAeHHbIX qenotlHblx MeraJInoB. crBopax fl4ApoKcH,uots TeunepamypannqlreHun. Orcoto 66 oC. pI3 2r6-[ttxlopxrrnoHxJroprrMrrJla pacrBop. 0,02 r [epeKpr{craJIJII{3oBaHHoro aIIe6yrurosa 2.6-Er{xnopxr{HonxnopuMn[apacrBopqror s 50 N,rrcBex{eleperHaHHoro c[I{pTa. JroBofounn r{3onpolrl4JloBofo XpaHxr Ha xonoAe n 6asxe opaHxeBoro creKJIa. pacrBop K rrpIiMeHeHLIro npuroAeH. He flpu noxuoarfir po3oBoro oKpaurr{BaHr4r .{ux.noprr aw. l r2-ltrxJropsTaH. 3rH.nen xJroprlcrbl fi . C u. 3rr,r.ltenxloPul. f r.rx;roprran, HacbrrrleHHufi BoAofi eHW 1:2, auepruquo Bcrpqxusarcr 15CMertrl,tearcT ,[uxnopgraH c eoAofi B coorHorrJ croeB. Or6uparcr AllxnopgraHosrIfi clofi. 20 rr,run ocraBJrrrorAo piBAeneHL.Is rr rrepeAHcIIoJIb3oBaHI4eM. forossr Henocpe.qcrBeHHo (M.vr. 181,31).N,N-[uqI,IKrIoFeKcHrIaMI{H. [nqnx.noreKcrrJlaMnm.C;.2H23N. Eecunernas x{r,rAKo crb. pacrBoc B YlrepeuHo pacrBopr,rM BoAe,cMerrrrrBaercfl o6rr.rnul,{r4opraHI,IqecKI{MI4 pH-renrMr,r. /7, . Oxono 1,484. KuneHut Onono 256 "C. Te,trnepamypa Teunepamypa 0-1'C. sameepdeaaHufl. ,{uqur.noreKcr{JlMoqeBrlHa. C13H24N2O. (M.*. 224,34). 1,3-IuqurJIofeKcLIJIMOqEBI,IHA.

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Kpzcrannrnqecrufi roporuoK6eloro rlBera. Teunepamypa ma*reHun. Oxoto 232'C. (M. traHon. ,{HsraHonaMnH.(C2H5)2NH. r"r.I 05,14). 2,2'-klwruuo6uc Ilpospa.rnafl,Bfl3KaA xl4AKocrbcJIerKa xeJrroBarororlBerar{Jrr{ pacrrJrhrKpr4craJrJrbr, BaronluecrHa Bo3Ayxe, rrJraBrrcrflpu reMrreparype oKono "C. 28 o/o, cMeruusaeTcr soAofiH clr4pToM c pacTBopr{MarleToHe sslrpe. 96 JrerKo B rE d]i . o*ono 1,09. pH. Or 10,0.qo 11,5(5 olopacrnop). (C2H5)zNH. (M.r. 73,14). .{ne:rn.rannH. llpospaunaa,6ecqnernafl., BocnJlaMeHrr]oqarcr xrr{rKocrb.I4lreer cnnbnorqeno.rHyio peaKrlr{rc. Crr.reuunaercr golofi r cru{proM %. O6parqaruc.socropoxHocrbro. c 96 c

dli . O*ono 0,71.

TeunepamypaKLtneHun Oxono 55 "C. gTrrJrA er(crp a H ,{Horur arr rrHo Aunosoo6MeHHar cMoJra $oprvre n rrrApoxJropr4Aa. floporuor, o6pasyrorqufic no4ofi relr. NrN-[nrruJlaH[rrrtrH. C6H5N(CzH)z. (M.r"r. |49,24).N-Oenung]rerr.rnaMr.rH. Ilpospavnar, 6ecqnerHafl.ullu cJIerKax(eJrroBararBocrrJraMeHrroqascr x{rrAKocrb, qenoqHylo peaKrlr4ro. uMeeTcr.rnbHyro llparrxuecKr{ HepacrBopr4M BoAe,JrefKopacrBopr{MB cnr{pre 96 %n e$upe. B

d1i. O*ono 0.938. Teunepamypa KuneHut Oxono 'C. 2I7

Teunepamypannqrneffilt. Oxolo -38 'C. C21H3sO. (M.r"r. 390,54). [u-(2-erurrexcun)6eH3on[w(2-trnurercclr,r)Qra,rar. - guxap60 Kcr.rJr I .2 ar. flpospauH afl, v'acrflHilcrafi. xctrAKocrb. flparrlluecKl4 HepacrBoplrM BoAe,pacrBopr{MB opraHrrqecKrrx B pacrBoprrreJrrx.

d,i . o*oro 0,98. nll .O*ono1,486. Basrcocmo. Orolo 80IIa.c.

C4HI 0O3.(M. r. | 06,12).2,2' -OxcvrAneraHorr. {nrrunenrJ.rrrKoJrb. Co4epxur HeMeHee 99,5 o (u/vr) C4H10O3. flpospauHax,6ecrlnerH rurpo cKon a.rr, vrrnafl. )ntrAKo crb. CMeuusaercrc no4ofi,arleroHoM cnuproM96 %. u

dii .O*oro ,118. 1

n') . O*oro 1,447. Teunepamypa KuneHu.n. 244 ao 246'C. Or XpaHm B Bo3AyxoHenpoHr{rlaeMoM roHrefiuepe. (M.ru.262,32). cy.nrQar. C10Hl8N"OaS. N,N'-!uarun.{neru.rrQeHnJreHArraMnna
r -$ euur eu Enavrvlaa cynr $ ar. N,N' -fluarun6eugol - 1,4- guarvu.rucylr$ ar. a floponror 6eroro uJrlr cJrerKaxeJrroBaroro rlBera. PacreopHu B BoAe. Tuanepamypema*neHar. Orolo 185 oC, c pa3no)KeHr{eM. Xpanxr B 3anlr4qeHHoM cBera Mecre. or

lurrn.rrSeHrrJrenAlraMrrna cyrrQara pacrBop u KoHlleHTpl,Iporannofi 25 v.tr K 250 Mn BoAbrnpz6aenrrcr 2 ul cepnofi KHcJIorbr 0,02 M pacrBopa :aa^rpvfl. sAerara. B noryuenHoM pacrBope pacrBopttor 1,1 r guerxnQeunneHlr.raMrtracynr$ara x AoBoA;IrsoAofi Ao o6reua 1000 un. Irlcnonr:yror roJrbKo6ecqserHrrfi pacrrop. or Xpauxr B rrpoxJraAHoM, 3arrlrrueHHoM cBera Mecre. Cpor roAHocrI.I- I rrlec. C6Hl6Nz. (M.rnr. IL6,21). N,N'-Auerute'rau-I,2NrN'-.{uorrrJrsrHJreHArIaMrIH. Cogepxrar He MeHee % C6HI6N2. 98 AHaMHH. Clerxa MacnrHr.rcrat xl{AKocrs, 6ecqnerlaaflvrrn cJIerKaxeJlToBaroro uBera, c cvurbHbrM3anaxoMaMMr,raKa. Oxa:Hsaer pa3Apaxarcrlee AefrcreIle Ha Ko]I(y,Dra3a14clrr43r{crbreo6oro.Ir[.

dii . o*ono 0,827.

TeunepamypaKuneHufl. Or 145 go 147 "C. o/o. rpoBo4:rr rr30,500 n Boda. He 6onee I,0 Oupe4eneHl,Ie [uororccurerparl{ApoQypaH. C8Hl603. (M.u. 160,21). 2,5-fiueroKcr4rerparuapoQypas. Cuecr quc- prmpaHc- LI3oMepoB. crb. flp ospavnaq, 6ecqse rnas, vtilv cJIerKantenro Baroro IIBer a )KI{AKo o sSupe n 6onrurunB flpaxruvecKr,r HepacrBopr{M BoAe,pacrBoprrMB cnr{pre 96 , pacrBopllTelefr. crBe Apyrrlx opraHrrrrecKnx

d]i . o*ooo 0,98. n') .Onono ,418. 1 -Aol ercano.rr. rr,r. on 1 C Jlayp n.rr rI fi cnnpr. ,{orcyrar Harpufl. Cu. Harpnfl Aol(y3ar. (M. 4 lorpuarcoHraH. C zzHeo. r"r. 50,9). ru-[orpzaxoHraH. llnacruHru 6enorouBera. B ManopacrBoB BoAe, flparru.recKr{HepacrBopr4M WepeHHopacrBopr4M feKcaHe, prlMB aQzpe. nnarneHun. Oxolo 69 'C. Teunepamype ra3oBofi xporraarorpanpoBoArrMeroAoM Ilpuaecu. He 6o;ree0,I oh.OnpegeneHr4e

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Kamunr oKcn.rl. )Kxenaq rr3Becrb. Crr,r. XenaruH (rnn A) rIJrr{IueKI,IcJrorHoM Oquuesuufi nporeuH, flonyqaeusrff [ppr qacrI,IrIHoM Moxer npeAcraBJrtrb co6oil rorrHoM (rzu E) ruAponr,r3exr{BorHoro KoJrJraresa. cMecbAByx Tt4rroB. rlBera rBepAaqMaccaB BI{Ae Or ceerro-)rceJrrofo cnerKaxeJrroBaro-KopuqHeBoro Ao nonyflpo3paqHbrx rrJracrr{H,cTpyxeK, rpaHyn unr{ IlopolxKa. flpaxru.recKr,r HepacrBopuMs o6rr.rHrrx pacrBoplrrentx. B xoroAsofi eoAeHa6yxaer, rrpr4Harpe Banvrvo 6p aryer KonJI HAHnrfip acrn op. o Xe.n arn n rrlApo,'rn3oeanHsr fr rrapoMB O6pa6arrrBarorHacbrIqeHHbIM 50 r xenau{Ha pacrBoprror s 1000 MJrBoAbr. 90 npr.{ aBToKJraBe reMneparype I2l "C B TeqeHI4e uzn u rnoSull,I3llpyror. )Ke.nesa(III)aurrvroHnr cynrQar. FeNHa(SO+)z'l2H2O. (M.vt. 482,2).Xenesa aNIHI4 e. ar. MoHr.rq4r.rcynrS ar AoAeKarr,IAp Knacqbl xeJle3oaMMo eBbI Kpncrarnu 6reAuo-Suoneronoro uBera, BbIIIBeraIorIueHa Bo3Ayxe.

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pacrBoprrM BoAe, Oqesr JrefKo B rpaKrrrrrecKr{ HepacrBopnM cnrrpre96 %. B oh.Paqsop 100r/n. Xerera(III) anruoxnr cynrQara pacrBop 10 llepea r4cnoJrb3oBaHr4eM, neo6xoAuMo, ecnn $unrrpyror. Itere:a(III) a*rlronur cy.nrQarapacrBop B a3oruofi rclrc.uore Bcrpxxunaror30,0 r xe.ire:a(Ill)avrrnroHux cynrQarac 40 Mrra3orHo[rzcnorrr ronrleHrpr.rpoBassoitAoBoA.f,r rr o6reu pacrBopa eo.uofi 100 ul. Ecln pacrBopMyrAo Hufi, ero ueHrpra$yrnpyrorurn $umrpyror. XpaHxr B 3arrlktrrlennoM cBeraMecre. or Xerera(III) anruoHnncynrQara pacrBop B cepHofixuc.nore 20 r xeresa(Ill) aMMoHrrs cynr$ara pacrBoprrcr s 75 MJrBoAbr, npz6auxror o (o6lo6) cepHofiKrrcnorbr pacrBopa 10 nn 2,8 KoHrleHrpr{poBaHHofi z 4oeo4rr pacrBopa o6terrr soAofiao 100rran. Xe.ue:a(III) nurpar. FeQIO3)3' 9H2O.(M.rur. 404).Xeresa oKucHoro Hnrpar.Co' HeMeHee 99,0 oh(u/u) Fe(NO3)3 9H2O. Aep)Kr4r Kpucranrbr vtrvtKpr{crannuqecKar Macca cBerno-po3oBoro rlBera. pacrBopr.rMBoAe. Oqeur JIerKo B (n Ceo6oduan Kucroma.He 6onee0,3 o/o nu4eNOr). Xerera oKncHoroHHTparapacrnop 5 7o pacrBoprrcr B BoAe AoBoA-f,r 5 r xere:a(Ilf Hr4rpara r.r o6reu pacrBopanoAofiAo 100,0rvrn. Xe.rrera(Ill) cymQar. Fe2(SOa)3' xH2O.Xenesa(III)rpucynr$ar no4uufi. lloporuox xeJlToBaro-6eroro pa3naraercrHa Bo3rlBera,cunbHorr4fpocKonraqeH,
AYXC. Malo pacrBoprrMB BoAeH crrkrpre96 %. XpaHrr B Bo3AyxoHenpoHr{rlaeMoM xourefiuepe, B 3arrlrrnreHHoM cBera Mecre. or ' 6H2O. (M.pr. 270,30). Xeresa rpraxnopuA.reKcaruXe.nera(III) xropug. FeCI3 Apar. Xere3a oKrrcHoroxnopktA. pacnnbrBaroKpucranruqecKar Maccaxenro-opaHxeBoro rrnrr Kopr{qHeBoro r.IBera, il\Lfrcfl Ha Bo3Ayxe. O.{eHr nefKo pacrBoprdM BoAe,pacrBoprrMB cnlrpre 96 % u e$upe. B IIoA AeficrBr4eM cBera xenesa(Ill) xnopra4u ero pacrBopbrlracrr.rrrHo BoccraHaBJrltBaIOTCT.

Xpauxr B Bo3AyxoHenpoHr{rlaeMoM rourefiHepe. t/o.3 r xenesa(Ill) xropnAapacrBoprrorB BoAer,r Xere:a(III) xnopnAapacrBop 3 pa:6arnrror no4ofiao 100rr,rn. pacrBop 10,5oh.Pacrsop105r/n. Xe.ne:a(III) x,ropnAa pacrBop 1,3 oh. Pacrrop 13 rln Xe.nera(III) x"ropnAa )(erera(Ill) x,ropuAacrrrproeufi pacrsop 2 o/o pacrBopqrcr crnrpre96 o/o AoBoArro6reu pacrBopa 2,0 r xereea(Ilf xnopr{Aa B rr TeM pacrBopt4TeJreM.[o vrn. xe 100 Iterera(Ill) x,ropr.rAa cnrrpronufi pacrnop 1 oh. I r xenesa(Ill) xnopngapacrBopqror s 100Mn cnrrpra96 %. Xte.uesa(Ill)xropuAa pacrBop l0 oh. Pacrnop100r/rl. Xtenera(Ill) xropnAa pacrBop I th. Pacrnop10 r/n. Xterera(Ill) x.rropuAa cyJr H bQaultronofi xuc.norbrpeanTrrB
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xpacuufr uner. pacrBop.Crnr. Kamqnfl rrrApol(crrAa HsnecrrcoBafl BoAa. Ka"rrqnq rr.rApooKrrcn

pacTBop. Hgnecrs ror(enar. Cvr.Kamqr.rfl oKcHA. I OH. (M.ru.88,I 5). 3-Mernn6yraH--ol. Llroapru.uoerrfi cnupr. C5H11 EecueerHar xrunKocrb. co Mano pacrBoprrM BoAe, B cMerrruBaercq cllrproM 96 % u e$Hpou. Teunepamypa KuneHun Oxo;ro130"C. aHoJr. Hro6yrn,ronufi crr{pr. Cu. 2-MeruJrrlporl (+)-I4:orrreHron: (1S,2R,5R)-2-uzonporll4rr(M.rvr. 156,26). Hrouenro,r. C1sH2eO. -lrerurttluKJroreKc 5 aHoJr. qacrefi (1S,2R,5R) (1R,2S,5S)-2-n:onponun-5paBHbrx n cMecb 1+)-ZsoueHrorr:
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EecqeerHrre Kpr.rcraJrJrbr. nerKo pacrBopr4M cnlrpre 96% u eQupe. B B flparruuecKr,r HepacrBoprrM BoAe,orreHb +24'(I0o/opawnop B cnr,rpre96%). oKorro loli . (+)-I,I3oMeHrorr: Teunepamype KuneHun (+)-I4sorraeHroJr: oKono +218 "C. (+)-tr{soMeHroJl:oKoJIo -218 "C. (+)-I{sonaeHron: +80 "C. (+)-I4roueHron:oKono+53'C. oKorro (+)-ll:onreHroH. Cl0H1sO. (M.u. 154,24). (lR)-quc-n-MeHraH-3-ou. (1R)-t4uc-2-I4zonponur-5-Merr{Jrrlr.rKrrofeKcaHoH. KoJrl4qecrBa MeHToHa. Cogepxur pa3nuqHbre EecqeerHas )rcr4AKo crb. B B Oqenr MarropacrBopr.rM BoAe,pacrBopl.IM cnllpre 96 % u e$upe.

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-20

20

d]i . Onoro0,850. nl .OxonoI,435. I4tonpon onrrfi crrrpr. Crra. u"r 2-IIponaH oJr. 4-I4ronponn,rQeHo.n. I20. (M.r"r. 36,I 8). C9H 1
Co4epxrErHe Menee98 % C9H12O. Teunepamype KuneHufl. Orolo 2I2'C. TeunepamypantaBneHun.Or 59 ao 6l 'C. lluHtaso"rr. C3H4N2.(M.r"r.68,06). KpucrannHqecxufi [oporxoK 6eloro uBera. PacrnopurrlB BoAerr cnnpre 96 %. TeunepamypannarreHun. Orcoto 90 "C. lrnrHnogn6eHsnr. Cl4H13N. (M.r"r.195,25).10,11-luru4pogr6eusfbflazenuu. Kpncrallnqe cxprfinoporxoK 6le4uo-xenrofo rlBera. llparruuecKr{ HepacrBoprrM BoAe,JrerKo pacrBopr{MB arleroHe. B TeunepamypannarneHun.Oxono I 06'C. I{nAnrorcapMuH.C I 6HsN2Na2O3S2. r"r.466,3). (M. -4raorco-2,2' -6ucr.rHAonrrAen-5,-4lrcynr$onar. E 132. 5' lunarput 3,3' O6rr.rHo coAepxr.rr Harpvfl xnopr4A. flopouror or cLIHero QuoreroBo-cr,rHero rlBera rrnu rpaHynbrcrlHero rlBera c MeA4o nurr.r6necxou. pacrBopr,rM BoAe,npaKT[qecKr{HepacrBoprrM cnrrpre 96 %. OcaxgaYrraepeuno B B eTcr r,r3BoAHoIo pacTBopaHaTpvrfl xnopr,rAoM. Pacraopu rrHA[roKapMr{Ha cLIHefo rlBera, noA BIHTHVeMBoccraHoBrdreJrefi o6ecuBeql,rBaroTct. flepexo4 oKpacKr pacrBopa or cnHefi x xelroi B r.rHrepBiure 11,6-14,0. pH o/o Pacmeoput uuduxamopa:1.0,f pacrBop.2.0,25 pacrnop. PacrnopeuuenpoBoAtr B ropqqefi no4e.Kar orucrrrreJrbHo-BoccraHoBr{renrnrrfi lrrrAl.rKaropilprrMeHrror 0,25 %opacryop. llngurorapMlrHa pacrBop pacrBopflror B cMecn l0 un xnoprcroBoAopoAHofi xrEcnorrr 0,2 r uwguroKapMl{Ha GEg

v990 xucrorrr, cso6oAnoft KoHrleHrprrpoBauHofi v'r20 % (20 r/n) pacrropa cepHofi

or a30Ta. Pacmop Aon)KeH BLrAepxI-IBarrcneAyrculee t,tcrrblTaHrle : Hr{rpara B 10 rr,rn nonyqeHHoro pacrBopa uplr6aBJrnor K pacrBopy 1,0 Mr KaJrr,rr cepHofi Kr.rcJrorbr cso6o.qHofior a3ora v Ha10 rr,rn BoAbr,Torqac upN6annxror 20 rr,rn pacrBopa AorrrrHoHcqe3uyrb B TeqeHrre rpeBaror Ao KHneHr4s. CHuee oKpailrr{BaHue I uun. HnAnrorapMlrHa pacrBop 0r4 o nopqlrtMlr Ao 4 r uururoKapMnHa pacrBoprrcT B BoAe,tpu6anntx BoAy orAeJrbHbrMr,I u KoHlleHTpl{ponanuofi o6reua 900 rr.u, 3areM npn6auxut 2 ul cepnofi Kr4cJrorbr pacrBopa soAofi ao 1000 un. AoBoArr o6rerra Vcmauoerca mumpa. 10,0 rr,rn oriuloHHofo pacrBopaHvrpara (100 ppm NOr) cMeIIrupacrBopa I,IHArrroKapMLIHaToTqacnpu6aBnarcr I4 Baror c 10 nn BoAbr,0,05 rnrn o/o 0,4 (sa o4un pa3, Ho ocropo)KHo)30 ur cepnoft KracJrorbr llonyKoHrleHrprrponanuofi. oh pacrBopoM HHAI,ITo.reHHsrfipacrBop HeM eAJreHHo rr{Tpyror rrpuroroBneHHblM0,4 KapMrrHa cra6zmnofi cuHefi oxpacru. Ao pacrBopa r{HAr{roKapMHHa, r,r3pacxoAoBaHHoe rLITpoHa KonuqecrBo Mr4JrJrr.rJrHTpoB BaHr4e, coorBercreyer 1 vr NO3. LlngoQenoronsrfi cnnnfi. Cl8HI6N2O. (M.u. 276,33). N-[4-(!uruerurauNuo)Senvrr)]- 1,4-naSroxr4HoHMoHoIrMHH. B flopouror $uonerono-qepHoro rlBera. llparrnvecKrr HepacrBopl{M BoAe. rrpoBoA-rrr MeroAoM ronrocnofinofi xpotuarorpaQulr, Xpouamozpafuua.Onpe4eneHr4e B G. Hcnonb3y.f, KaqecrBeroHKoro clrofl.cprlrvrKareJrb Ha xpoMarorpaQnvecrylo nJIa14 xpoMarorpaQupyror crrrHKy HaHocrr 10 rr,rrn 0,01oA pacrBopa B Merr{JreHxJropr4Ae (Dponr pacrBopr4TeJrr groM xe pacrBopr{Tene. B Aonxen npofiru He MeHee10 cu. Ha xpoMarorpaMMe AonxHo o6napyxuBarbcr roJrbKo oAHo ocHoBHoerqrHo. AonycKaeTct [qTHo Ha cTapTe.

iloa. Iz.(M.r. 253,80).

Kpl,IcriulnuqecKl4e 6recxorr.r Cyxze rffKerbre Qnorerono-qepHbrec MeriurJrr{qecKr{M r.rJrrr MeJrKoKplrcrannn.Iecrufi flopolroK. Jleryr nplr KoMnJIacTLIHKI{vllrr4KycorrKr.r, ) uarsoft reMreparype. MaJropacrBopllM B rnl4lreO.reHr MaJropacrBopuM B BoAe,pacrBoprrM B 3TaHoJre, pacrBopax fiogngoe. prrHe,orreHbJrerKo pacrBopr4M KoHIIeHTprIpoBaHHbIx B

trIoaapacrBop 0,005M
I,I K 10,0 nar 0,05 M pacrropaitop:a npn6anrxror 0,6 r Karrtrfr.iro1u1a AoBoAtr o6reu pacrBopaeoAofiAo 100,0lrn. forossr HerrocpeAcrBeHHo rrepeAr,rcnoJlb3oBaHlreM.

froaa pacrBop 0,0005M Ir AoBoAtro6rena K 10,0rr,rn 0,05 M pacrropafiora npu6auxror 0,6 r :rraJrvrs.itotug.a pacrBopa soAofilo 1000,0rr,rn. foroeqr Herro nepeA racrronb3oBaHr4eM. cpeAcrBeHHo trloaapacrBop0,0001M no4ofiAo o6rerua100,0ur. 2,0 wt 0,005M pacrnopairopla AoBoAflr loronqr Herro rrepeA cnoJrb3oBaHr{eM. 14 cpeAcrBeHHo

Ylota pacrBop 74 r irola pacrBoptrcr s 100 ul 40 o/opacrcopa lrralrvtr itoguga, npH6aararor 1 un KI4cJIorbI pa3BeAeHHoitT,3 n{osoryr xnopHcroBo.qopo,qsofi %ou o6ren pacrBopa eoAofi ao 1000run. Xparur B 3arrIHnreHHoMcBeraMecre. or Pacrnop fiota crrnproBbrfi| oh. Pacreop10 r/n B crurpre96%. Xpanxr B 3airlurqeHHoM cBeraMecre. or lloarpaxlraJrbHafl 6ynaara florocxn Qr.rnrrpoearuHofi pacrBopa 6warn norpyxarcr s 100 MJr KpaxMaJra, cBoyAa6o.qnoro fioAuAoB, or coAepx{aqero r xanrax 0,1 itogata.I,Is6Hror xrEAKocrrr Jrrlor. Cyruar B 3arrlrr[reHHoM cBeraMecre. or (M.na. i4oaa6ponrug. IBr. 206,80). Kpucrannbr clrHeBaro-r{epHoro Kopr.rrrHeBaro-qepHoro or rlBera. Ao JlerxopacrBopr4N{ B BoAe, cnrrpre96 yo,eSupeu yKcycHofi rucnore reA-sHofi. Teunepamypa KuneHun Orono i 16 "C. Teunepamypa nra*neHun. Oxono40 "C. Xpanxr B npoxnalHoM, 3arrI[uIeHHoM cBeraMecre. or trloaadponnga pacrBop pacrBop*or B yKcycnofirncnore JreA.f,Hofi 20 r iro2.a 6porr,ru4a r4AoBoArro6reu pacrBopareM xe pacrBopureneM 1000lr.rr. .(o Xpanxr B 3arrl{ueHHoM cBeraMecre. or VloaaMoHoxropua.ICl. (M.u. 162,35). Kpucrarrbr rrepHoro rlBera. yrcycHofiKrrcnore cnupre 96%. Pacrnopuubr Bo.qe, B r.{ oC. Teunepamypa KuneHufl. Oxoro 97,4 XpaHrr B rrpoxnarHoM, 3aururueHHoM cBeraMecre. or pacrBop. PacrnopitogaMoHoxnopr{Aa Vlola MonoxJroplrAa roroBsr oAHr4M orrurr3
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1.I,4 r fioAaMoHoxnopnrapacrBoprror yKcycHofi B rucrore neAsHofi AoBoArr rr o6relt pacrBopa reM x(e pacrBopureJreM 100 rran. ao II. 13 r MeJrKopacreproro pacrBoprrcrnpr BcrprxrrBanuyt cMecr{ i'r,ota B 300 rran yilIepoAaqerblpexxnopr{croro 700 Mn yKcycHofirucrorbr neArHofi.K 20 un u pacryopa Kanvflito!,u!.a, 100 runBoAbr sroro pacrBopalJ'pu'aB.nxror run l0 o/o 15 r4rr{rpyror 0, i M pacrBopoMHarprrsruocynr$ara. 3areu qepe3pacrBoprporlycKalorcyxofr rasoo6pasuufixnop Ao rex [op, rroKa rrrrpoBasne20 MJr Ha rropacrBopa nyrleHnoro 6yler pacxoAoBarrcs KoruqecrBo, He6omuree, Ho AeofiHoe " rlrocynrQara Harpufl. pacrBopnor s 200 Mn yKcycHofirucnorrr ;re4xnofi,paIII. 8 r fio4a rpr.rxnopLtAa qerbrpexxnopncroro.cMerrJr{Baror pacrBoptlor 9 r itoaa n 300 Mn yfJrepoAa o6a crBopalr npx6annrroryKcycuofirnclorbr neAruofi ao 1 "u. PacrnopfioAartoHoxJlopr,rAa xpaHrrrB 3aKpbrroM cocyAeB npoxJraAHoM Mecre. (M.r"r.233,26). VloaarprrxJ'ropnq. ICl3. Kpacuoraro-opaHx{eBbre Kprdcrannbr. flplrrorosreHne fioaa rpuxropnla. Haa fio4oru,oxJrax(AeHHbrM cMecbro cyxoro JrbAa c alleroHona -78 oC,nponycKalorrasoo6pasnrrfixrop Ao norBneHHr)r(eJrr6rx KaAo EEg

rIeJreK I,B6bITo'{Horo xJlopa.Pearqnounyro cMecbocraBJr-rrror qacoB errle Ha HecKoJrbKo B oxJlDKAessofi6aue, nocJleqero neperoHrror npr4KoMHarHofi reuneparype Bo BTopofi cocyl. froaa(v).oKcr.rA rrepenprrcraJ.rrrr.r3r{posaHHrrfi. (M.rrr.333,80). [ufiol ueHIzos. roKcr{A. fr oasrrfi anrn1prr1. Co4epxnr He MeHee99,5 ohI2Os. Kpucralluqecxprfi noporlroK 6e;roro riBera krnrrrpaHyJru or 6enoro Ao cepoBaro6enoro rlBera. filrpocronfitreH. O.ieHr nerKo pacrBopr4M BoAec o6pasonaHueM B HIO3. X p a n r r B B o 3 A y x o H e r I p o H I 4 I I a e M o Ms r e f t s e p e , B 3 a r r l a q e H H o Mo r c B e r a xo MecTe. 2 -iloailewsofi Haq Kncrrora. CTH5 IO2. (M. r"r. 24g,0l) . Kpucrarnuqecxufi nopo[roK or 6eroro Ao cBerJro-xeJrroro rlBera. Malo pacrBoplrMaB BoAe,pacrBopr,rMa ctrfipre 96 %. B TeanepamypannarneHun.Oxono 160'C. 2-ilounnnrrypoBan Kr{cJrora. CeH8INo3 . 2H2O. (M.r"r. 341,I). 2-(2-iIot6eH3aMr44o)yrcycHa{ Kr.rcnora. Kpucrannuqecxufi loporxoK 6enoro r{Jrufloqrr,r6e;roro rlBera. YuepeuHo pacrBopr,rMa BoAe. B Teunepamypqn),te6neHun. Oxono I 70'C " lloArcrosoAopoAHas KncJrora.HI. (M.u . 127,9I). fro4ucrosoAopoAHyloKl{cnory IreperoHrror HaAKpacHbrM rporycKar Bo $ocQoporra, BpeMt neperoHKlryrnepoAaAlroKcr4A r4nva3or.l{cnonrsyror 6ecqserHyrc r,rru [or{TX 6ecqnernyro,Kurlttuylo rpu rocrorHHofi rerr,rneparype cMecb(or 55 ao 58 o/o HI), ne.C. peroHrlotqyrccr rprr reMneparype or 126 to I27 KHc.uoryrloMeruarcre He6omuze $.rraroHbr creKJra rr3 KopurrHeBofo rlBera, rrpeABaplrrenbHo npoAyrble yrJrepoAa Hrrh A[oKcr.r.qoM a3oroM,co creKJrxHHbrMr{ tpo6rauz, repMeru3r4pyror napa$HHorvr. Xpauxr B 3aururrleHHoM cBera Mecre. or frogrcpaxnraJrbHafl 6ynara. Clr. KpaxMaJr pacrBopuuufi. froaHas Kr{cr,rora.H5IO6. (M.,"r. 227,g4). EecqserHrre pacnnbrBarollr4ecrKprrcranJrbr. Jlerro pacrBoprrMaB BoAe,B crnrpre 96 oh, eSupe. TeunepamypaMarneHun. Oxoto I22'C c pa3no)KeHrreM. r"r r4oIHOrr n yKcycHon K[croTbr pacTBop 0,446 r Harplrt nepfio4ara pacrBoprrcr n 2,5 rrrt25 % (o6lo6)pacrBopa cepHoii rucJIorbI KoHlleHrpl4ponauHofi IoBoItr o6revr pacrBopa yxcycuofi xucnorofi leA-sriofi I{ 100,0 prn. ao llonnJrar[ Hara peaKTrrB K 3 ir,rn l0 % pacrBopa xnop[narr.rnoeofi KrrcJrorbrnpr6arnrrct 97 MJr BoAbr rr 100 rran 6 o/opacruopa Kuurrrfiroliu/La. XpaHxr B 3arrruueHHoM cBera Mecre. or frogcepnHcrufi pearffrrB Ycrpoficrno AJII flpplroroBJleHrlqpeaKruBa, cocrorrqee H3 KpynroAossofi xon6rr errKocrblo 3000-4000 Mn c rpeMt BxoAHbIMLI orBepcrtrflMuArtx MeruaJrKr.r, TepMoMerpa

z rpyOKI{,3anonHeHuofi ocyruureJleM, 6urr 3aKpbrrbrM cyxnM B npoqecce r,r AoJDr(Ho noAroroBKr.r. ron6y rroMerrlalor 700 Mn [r4pr4A[Ha 6essoAHoro u 700 MJrMoHoB Merl4noBoroaQupa grprrreHrurlrKoJrr, upu6annxror npn nocroqHHoM nepeMerrrltBar zvt 220 r MeJIKoIr3MenbqeHHoro fio4a, npeABaprrrenbHoBbrcyrreHHoro HaA npoAonxalor Ao roJrHoro pacrBopeHr.rt $ocQopa(V) orcugou. fleperr,reullaBaHl4e fiola (orono 30 rvrun).3areu oxnaxAaror ron6y Ao reMneparypbr -10 'C u 6rrcrpo npz6aBJrtlor npl4 nocroqHHoM nepeMerrnlBalavrrzr r cepbr Ar{oKcilAa.Terr,r190 neparypa peaKlll4oHnofrctr.tecr{ AonxHa [peBbuuarb 30 'C. flo oxon.raHvpl He npu6arneHr{r cMecb oxnaxAaror. Vcmauoexa mumpa. Ororo 20 tv'nMeraHona6esno4HororroMerrlaror cocyA Ans B THTpoBaHnfl v'rvrpylor [pHroroBJIeHHun io4cepHr,rcrbrMpeaKTraBorr.r (onpegeJIeHI4e nogrr). llpu6ar:nxror rorrHo B3BerrreHHoe AocraroqHoe KoJr[qecrBo BoAbrr.r noBToptrcT orlpeAeneHr.Ie BoAbr.Brt.Iucrtlor KoJrrlrrecrBo BoAbr,B Mr4JrnrlrpaMMax, coorBercrByroulee 1 rran fio4cepHr{croro peaKTHBa. I un fio4cepHucroro peaKruBacoorBercrByer KaKMITHHMyM ur BoAbr. 3,5 lo.rrxHu 6urr nplrHrrbl MephrnpeAocropoxHocrr4 AJrr ilpe4orBpailIeHr{xros4eficrBvrs. pacrBoprr arlaocQepnofi BJrarH. Ha Turp ycraHaBnr{BarorHerrocpeAcrBeHHo rrepeAHcnorb3oBaHr{ eM. XpaHar B cyxoM xourefiuepe. frogyrcycHan Kncrrora. C2H3IO2.(M.u. I 85,95). EecqserHrte nilu 6enoro rlBera Kpr{crulrrnbr. PacrnopHMaB BoAer{ cnupre 96 %. TennepamypamarneHun. Or 82 rc 83 "C.

(M.rnr. ,98).5-lIoa-1H,3H-uupuuuguu-2,4-Ar.roH. S-Hoaypaqu;r. CaH3INzOz. 237

Temnepamypa nrasneHun. Oxolo 276'C c punnor(eHrreM.

(M.r"r. froAerau. C2H5L 155,96).

Xu4xocrr or 6ecqserHoro Io cJIerKa xenroBaroro rlBera, uoA AeficrBrreM Bo3Ayxa r4
CBETATCMHEET.

CMeurusaerct co crLtproM 96 % u 6omuuHcrBoM opraHuqecKr{xpacrBopnrelefi.

dii .o*ono ,95. 1

t?, . Oxono1,5i3. Teunepamypa KuneHufl. Orolo 72"C. Xpanxr B Bo3AyxoHenpoHurlaeMoM xourefiuepe. lloHoo6rreHHafl cMo,'racrrJrbHoKtIcJIorHafl Cuora B nporoHuponauuofi Soprrae rpynrraMu cynrQoHoeofi xucrorbr, lpucoeAr.rc pelxerKe, cocrorrqefius noJrucrr{pona,noneperrHocurr4Toro8 oh LusuHeHHbIMrr K nun6eugona. Bunycxaror B BHAerpaHyn rxapoo6pasHofiSopnnr; ecJrr.r Her Apyrux yxaraHufi, pa3Mepqacrr4rlcocraBJrrer or 0,3 4o 1,2 rmr. Cmamuuecrcan o1ueHHafle.MKocmu (COE). Or 4,5 4o 5 uuolrlr npu coAepxaHr.rr4 o . Bolbl or 50 no 60 flpnrorosreHne roroHxn. Ec-rru Her Apyrrrx yKa3aHrrfi, ucnoru3yror rpy6xy c BrrJraBJIeHHrIM BHyrpb II{cKoM r{3noprrcrofo creKJra BHyrpeHHr{M 4nuHofi 400 rr,rnl, AvaMerporra 20 MM n sHcorofi 3anonHeHr4roKoJro 200 rtaru.Cuony npeABapureJrbHo cMelxrrBarotc no4ofi, lonyr{eHHy}o B3Becb BBoA-trTrpy6xy, He AorrycKaro6pasonar HHt ny3blpbKoBBo3AyxaMe)rqy qacrr4rlaMr{. nperr.r.a pa6orn x{r.rAKocrb AonxHa Bo He orlycKarbcs HHIKerloBepxHocrll cMonbr.Ecmr cMoJraB nporoHt4ponannofi Qoprr,re,
20

EEq

rrpoMbrBaror BoAofi Ao rex nop, rroKa AJrr HefiTparrv3alg:avr nrn uorpe6yercf, He 50 r4cnoJrb3yr KatrecrBeraHAr,rKaB 6onee 0,05 lrn 0,1 M pacrBopa Harpr.rr rr.rApoKcr,rAa, o/ocnuproBoro pacrBopa Merr4JroBofo B ropa 0,1 lrl 0,I opam(eBoro. Ecnu cMoJra HapereHepaqrru, qepe3 KoJroHKyMeAJreHHo rpueeofi $opue ililr4 Hy)KAaercr B nponycKaror oKoJro100 un cMecr{paBHbIxo6relaos KrrcJrorbr % xJlopllcroBoAo25 po.qnoff r,rBoAbr,a 3areM flpoMbrBarornogofi, KaKorrprcanoBbIIrre. Kalunfi. Cd. (A.u. 112,40). Ere crsurufi iraerzurrcepe6pucro- 6eroro rlBera. llparruvecKlr HepacrBoprrMB BoAe,JrerKopacrBopr,rMs a3ornofi Kr,rcJrore ropaueft u xnop[croBoAopoAHofi rucrore. KaApus xrropr{A. CdCl2 ' 2,5 HzO. (M.u. 228,34). Kaauufi xropucrufi. Kpr{cranJrr4qecKr.rfi noporuoK, B Macce EecqeerHrIe nony[po3paqHbre Kprrcrannbl uJrr,r 6e.nororlBera. B B cna6o pacrBoplrM Oqeur JrerKopacrBopr.rM BoAe,WepeHHo pacrBopr.rM MeraHoJre,
B gTAHOJIE.

nonyqeHnbrx MoJroKa. r43 Ka:enH. Cuecr poAcrBeHHux QocQonpore[HoB, AuopSHrrfi noporuoKr.rJrr.r rpaHyJrbr 6eroro IIBera. pacrBopr4M BoAe HelorqpHbrxopraHuqecKux pacrBopr,rreJrsx, pa14 B O.renr MaJro xosuesrp[poBaHHofi o6pa3oBaHr.reM crBopr{MB KrrcJrore xnoprrcroBoAopoAHofi c 6ne4no-$lroJreroBoro oKparrrr4Banr,r.f, . 14 O6pasyercoJruc Kr4cJroraMr4 ocHoBarusMvt. pH HaxoAI,ITcq 3Har{eHuu ororo 4,7. ilpr{ llsoarerrpuqecKarroqKaKa3euHa I{elovnrre pacrBopbr eror neBo BparrleHrlnnocKo ilo nflpv3arJvru. r{M crr.r e e Ka;ru eAKoe. Karnfl rrrApoKcnA. Crr,r. (M.u. 98,15).KatmiryKcycHoKrrcmrfi. Karnq arlerar. CH3CO2K pacrurbrBaroulne HaBo3Ayxe. Eecqeerurre Kpr{crrurJrbr, cfl. pacrBopr.rMcnl,Ipre oA,HepacrBoprarra B n e$npe. JlerxopacrBopr4M BoAe, B 96 oh pacrBop B yrccycHofi Karnq arlerara l0 rcnc.nore neAsnofi l0 r arlerara :rarrvrfl. cMelrr.rBaror 50 Mn yKcycHofi c xvcrorrr reAqHofi,ocropo)rcHo nepeMerui{Baror nonHoropacrBopeHvfl ar\eraraKanvrfl, r,r AoBoArro6reu pacrBopa Ao rncrorofi neA-rHofi. ,qo100Mn yKcycHofi Kannfi a3ornoKrrcnsrfi. Cu. Ka.iruflHrrrpar. Karns 6urcap6onar. Cu. KaJrtlqrnApoKap6oHar. MeraHoJrbHufi. Ka.nns 6urap6onara pacrBop HacbrrrrenHufi Cu. Karnr rlrAporcap6onarapacrBop HacbruIeHHufi nrerano.nsnufi. Karrq 6ucy.nrQar.Cu. Karnff rrrApocyJnQar. pacrBoprrorB BoAe rr.{ApocynbQara KaJruq6ucyrrQara pacrBop l0 o/o.10r xa-uu.s pacrBopa H AoBoArro6rerra eorofi ao 100rran. Kanrlq 6uxpolrar. Cnr.Ka.nuflAuxpoMar. pacrBoprrorB BoAe Aokr Ka.nns 6uxpolrara pacrBop 5 th. 5 | KaJrrr.f, 6raxpouara BoArr o6reu pacrBopa eoAofiao 100rrar. Ka.rrlrq6nxpouara pacrBop n cepnofi Kr.rcJrore pacrBoprrorB 60 un BoAbr ocropo)KHo I r ranrq 6uxponaara r{ rrprlnrdBaror lrn 7,5 KoHrleHTpr{ponaunofi cepnofiKucJrorbl.

EETI

Karrq 6pouar. KBrO3. (M.rnr.167,01). Karyts 6ponrHoearoxuc;rrI. Kpucrarr br vtrrr Ip aHynl{posaHHHfiIIop orroK 6el oro IIBera. PacrnopuruB BoAe,Mano pacrBoprrMB cnl,Ipre 96 %. 119,01).Kanui,t6pouucrufi. Ka;rus 6pouuq. KBr (M.rr,r. nopouox. EecqserHue Kplrcriul lrbrrrru MeJrKoKpl{crannl4qecrHfi pacrBopuM B crll4pre 96 %. Jlerxo pacrBopr{MB BoAe,MuLIIo Kanur 6pourlg, Hcrronb3yeMHie un$parpa*rofi a6cop6qr.rounoficnerrpoQoroueI{cIIbITaHI{e. cneAyrorueeAoIIonHI4TeJIbHoe Tpvftr,AoJrxeHBbIAepxr{BaTb BblcyronrqrrHoit 2 v'v', npeABapHTeJIbHo I,IK-cnerrp AucKa Karus.6porr,ru4a 'C B TeqeHLIe1 u, rrreHHoronpl4 TeMnepaType250 AoJIxeH I,IMerbrIpaKTI{r{ecKr,r or B poBHy}o6asoryrc JrraHrrro r.IHTepBaJIe AIL{H BoJIH 4000.uo 620 crr.r-'. 6onee 0,02 ual,6asoeofi ruc MaKcr{MyMoB rrofJroilIeHr4eM He AonxeH r,rMerb rIpI4AnIrHax BorIH3440 cu-r u MaKcr{MyMoB uueit 3a r.rcKJrroqeHueM Ant Bo.qbl 16 3 0 c u - 1 . Ka.rrns 6ponrnqa pacrBop l0 o 10 r ranur 6poura4a pacrBoprror B BoAe r AoBoAtr o6reu pacrBopa soAofi Ao B 100 un. Xpauxr s 6aHrax c ilprrrepruuu npo6KaMH 3aulnqeHHoMor cBera Mecre. Ka.unfl Taprpar. Ka.nufi BnHHoKrlc;rufi. Crra. Karuq reKcallranoQeppar(Ill). Cu. Kalur QeppnulraHrlA. Kanufi AByyrKarlrs rlrApoKap6onar. KHCO3. (M.r"r. 100,12). Ka:rux 6rExap6onar. rexncnrrfi. flpospauHrre, 6ecqserHbleKplacrannbl. B HepacrBopl{M cnlrpre 96 %. B Jlerro pacrBopr.rM BoAe,npaKTuqecKu Kar ns f llApoKapoon ara p acrBop Hacbl lrleHnsrfi rrreraHonbllbtfi Ha 0,1 r xanur rnApoKap6onara pacrBoprlor n 0,4 Mn BoAbIrlprr HarpeBaHvpr BoAtKpyroBbIMI{ H Hofi 6aue, npu6auxrot 25 wtltMeraHoJra nepeMeruIrBaror ABIDKeHTTTIMII, ilpoAonxaq HarpeBaHl4e pacTBopeHl4q. Ao [epeA HcnoJIb3oBaHr{eM. foroesr HenocpeAcrBeHHo Ka.uns ruApoKap6onara H KaJrrIflrapdonara pacrBop 4 r rcalus rngporap6oHara pacrBoprrcr s 15 MJrBoAbr(npu narpenauuu),npu6aBn.flror2,5 r xpucraJrnuqecKoro Kiurlrr rap6onara rr AoBoAtr o6rervtpacrBopa soAofi

ao 20 u;r. Kaln Kanus, rl{ApooKrrcr. eAKoe. KOH. (M.r"r.56,11). Ka,ursrrrApoKclu.

rrnrdrpaHynbr c KpucrarnzqecKofi crpyxrraJrorrKrr rlunr.rHApr{qecKue Belue KycKr4, Typofi Ha rr3JroMe. firrpocronuqeH. pacrBopllM B crlupre 96 oA,rpaKTnrlecKu pacrBopnMB BoAe,yMepeHHo O.renr JrerKo n eSHpe. HepacrBoprarra pacrBop l0 Vo Karrq rHApoKcHAa 10 r rarnq ruApoKcr{AapacrBoptror B Bo.qeu AoBoAqr o6reu pacrBopa eoAofi Ao npo6xauu. 100 rran. Xpanrr B creKrqHHblxcocyAax c KayqyKoBbIMI{ oh Kanns rrApoKcrrAa pacrBop cnrlproBsth S pacrBoprror B 8 ur no4u tr AoBo.qtr o6reu pacrBopa cnl4p5 r ralur rr.rApoKcr4Aa or rorra96 Yo, cso1o4HbrM anbAerrlAoB,Ao 100 un. ,{eranrupyror npo3pavuufi pacrBop. Pacrnop AonxeH 6urr noqrr{ 6ecqseilIHll.

Ka,rnq rrrAporccnAa pacrBop cnrrproBstit3 Vo 3 r rarn-s rI4ApoKcI4Aa pacrBoptlor B 5 ur nogrr 14 pacrBopa cnzpAoBoArro6rerra o/o, rou 96 cso6o4HbrM anbAerr.rAoB, 100 *m. ,{exaurvpyror flpo3pavuufipaor Ao crBop.PacrnopronxeH 6urr [orrru 6ecqserHrrN{. oh Karnq rr{ApoKcuAa pacrBop cnuproBwft A166 6,6 r t<anu-fl ruApoKcv!.apacrBoprrore 50 Nar BoAbr AoBoAqr r.r o6ren pacrBopa sraHonoMao 1000un. Karus rr{ApoKcrr 2M pacrBopcunpronufi aa 12 r xanut ruApoKckrra pacrBoptlor s l0 ilar BoAbr r{ IoBorrr o6rerra pacrBopa cnlrproM96 % ao 100 u:r. Karns rrApoxcn.qa0r5M pacrnop cunpronufi 28 r ranvq rnApoKcuAa pacrBoprrorB 100 irrncrrnpra96 % r4roBoArr o6levr pacrBopasolofi ao 1000na:r. Karuq rlr.qpocyrlrQar.KHSO4. (M.r"r.136,17).Katmx 6ucyrr0ar. Kanufi cepHoxucnnfi xuc:rufi. llpo:pauHue,6ecqnerHbre, rr{rpocKonr4rrHbre Kpr4crannbr. Jlerro pacrBopuM BoAe o6paeoraHr,reM B c pacrBopa. cr{JrbHoKr4cnoro Xpauxr B Bo3AlxoHerrpoHr.ruaeMoM uepe. rourefi Kanns rrrAporaprpar. C4HsKO6.(M.rur.188,18).Karu.s rnapo-(2R,3R)-2,31,4 Ar4rr{ApoKcu6yrau-- guoat Kprcra-n.rru.Iecxufi noporxoK6enororlBeraHr[ 6ecqserHbre, cJrerKa MaroBbre Kpr4CTAJIJIbI.

Mano pacrBopl{M BoAe, pacrBopr4M Kurrrrlefi sore. oqeHbMaJro B B pacrBoplrM B cilr.rpre %. 96 Karuq rnAPo0ra.nar. CsH5KO4. (M.rur. 204,23). Katmx rzgpo6euson-1,2guxap6oxcnnar. Kalufi Sranenoxuc:nrfi ruc;rufi . Kpucrallrt 6e.noro IIBera.Pacrnopuna BoAe, B pacrBopr4Mcnrrpre96 %. MaJro B Karnq rngpoQraJrara0r2N{ pacrBop Pacrrop Rantrr, rugpo$ranara coAep)Kur40,84 r, B repecqere Ha CgH5KOa,e 1000.0MrrBo.rrbr. Ka.rrufiAByyrJreKn rlfi . Crra. ufl rrrApoKap6onar. c.n Ka,r Ka.nufiAByxpoMoeoKncrsrfi. Ka"rllq duxpouar. Cu. Ka.unflArrxpoMar. Kanns 4uruqpoQocQar.Crvr. Kannr QocQar oAHo3aMeuleHHrrfi. Karrq gurugpoQocQara M pacrBop. 0,5 68,050r KuMI4t B KoJrrrtrecrBe Borbrr{ 4uru4poQoc$arapacrBoprrcT rocrarorrHoM pas6au*or o6rerra pacrBopa soAofiao 1000,0vrn. Ka.nnqArrrApoQocQara0,2 M pacrBop 27,220r Karuq gurla4poQoc$ara pacrBop*or B AocraroqHoM KorvqecrBeBoAbr r{ pa-:6auxrcr o6rerupacrBopa nogofiao 1000,0rvrn. Ka.rrnq4urrgpoQocQara 001M pacrBop. Cn. Ka,run QocQaraoAHo3aMeryeHHoro pacrnop 0r1M. KarHq AnxpoMar.K2Cr2O7. (M.*. 294,19).luxrumx Ar,rxpoMar. Kanus 6uxporraar. Kanufi AByxpoMosoxzcmrfi .
itpr4cTannbr opaHlKeBo-KpacHoro rIBeTa. Pacrnopuu B BoAe,npaKruirecKnHepacrBoprrM cnnpre 96 %. B

19.3ax. 2768

coKanus AlrxpoMar, r{cnonb3yeMHftAr-s ra-nlr6ponru c[eKrpoSorouerpoB, AoJI]KeH o/oK2Cr2O7, [epecqere Ha cyxoe BelrlecrBo,Bblcy[reHHoe B Aepx(arbHe MeHee99,9

130'C. npr.r reMreparype pacrBoptror B BoAeIr Ao1,000| KaJrr.rfi KonuqecmneHHoe onpedeneuue. Ar.rxpoMara paronyqeHHoro reM xe pacrBoprrreneM 250,0vrn.50,0 MJI BoArr o6reu pacrBopa Ao crBopa rroMerrlalor B ron6y BMecrplMocrblo 500 Mn, upu6ae;rrrcr pacrnop, cocro.f,Irrui't 4 r rcanus ilo1ura,2 r uatpux ruuz cBexcenpuroroBJreHHrrfi s 100 KrrcJrorbr KoHrleHTpr{poeanHofi N,{r aporap6onarau 6 un xnopprcroBoAopo.qHofi B 3arrl[qeHHoM cBeraMecreB or upo6roft, BbrAep)Kr.rBaror BoAbr. Kon6y 3aKpbrBaror B ruocyrr$ara, I{crloJrb3yt KareqeHve5 lrus r{ Tr4Tpyror M pacrBopoMHarpLrs 0,1 qecrBer4HAr{Karopa pacrBopa KpaxMuLIIa, or 1 rur cso6oAHoro fioAnAos. 4,903 vrK2Cr2O7. coorBercrByer 1 un 0,1 M pacrnopaHarpvrs.ruocynrSara o . Pacrnop106r/rr. Kannq ArrxpoMarapacrBop 1016 pacrBop 0rSoh. Pacreop rln. 5 Ka.nusArrxpoMara . Cvr. Ka;rnfi )r(eJre3rrcrocrrHepoAncrsrfi Kannn QeppouuaHrlA. ?r(eJre3ocr.rHepoArr. Cu. Ka,rus Qeppnqu anH4. crrrfi Ka;rufi fioguoearorucnrtfi. 214,00).Kanr.I-s Karnq fiotar. KIO3. (M.r"r. Kpncrarnu.recrufi nopouroK 6eroro IIBera. pacrBopraMroprvefi soAeiHepacrBopr{McflIrprc 96 oh. B e PacrnopnuB BoAe, JrerKo o .I r Karr{r itolarapacrBop*or B BoAe AoBoA-flr H o6rerr,r Ka"nnqfioAarapacrBop I pacrBopa eorofi ao 100un. Kanr.rqftogara pacrBop 0,005M Ia KoruqecrBe BoAbI pas6au*or B 1,070r Kanur ircEarapacrBoprrcT .qocrarolrHoM pacrBopa eorofi ao 1000,0rran. o6rervr Ka.unfifioAncrufi. Kanns fiolnt. KI (M.u. 166,00). Ee.lrrre Kprdcrulrrnbr 6er'sir [opolroK. uttu B B JrefKopacrBopr.rM rnI4IIep[He,pacrBopllMB O.reHr JrerKopacrBopr,rM Bo.ue, cnr{pre96 %. Karns fioluta pacrBop 16,6 o . Pacrnop166 rln Kanns fioAnAafio4nponannrrfi pacrBop pacrBopepacrBop*or e 10 MJr BoAbr, rocne rroJlHoro 2 r iaola n 4 r xattux i,to4u1a pacrBopa soAofiao 100nan. HHrAoBoAsr o6rerrr pacrnop HacbrrrleHnrrfi Kanns fi oAHAa HacurqeunrrfipacrnopKanpur ito4ula B BoAe, cso6oftrofi or yrnepoAa Ar4oKcHAa, AoJI)KeH COAepXCaTbH ep aCTBOpe HHbre KpLICTtLIIIbI.

pacrBopaKaJrr{fl xnopoilo4u4a cMerlrrrBalor 30 MJrcMecl4 c 0,5 ul HacbrrrleHHoro - 12 % yKcycHarKr{crrora (2:3), npn6annxror0,1 r.tn0,I YopacrBopaKpaxSoprnr
MaJra; ecJrr,r [otBnfleTct cplHee oKpar[LlBaHHe, oHo Aon)KHo I4cqe3HyTb rlpu

rl4ocynbQara. npz6anneuuu 0,05 ur 0,1 M pacteopaHarpIr.a Xpanxr B 3arrl[ueHHoM cBeraMecre. or Kanufi fi oAracrrrfi. Cl,r.Ka.nus trrcau[,. Ka.nns fio4nAapacrBop l0 Vo. 10 r xa:ruqirogugapacrBopnor B cBexeilpoKr{rr.renHofi oxnax(Aesnofi r4 o6rerupacrBopa roAofi ao 100un. Pacreop r{ BoAe AoBo.urr 6rrrs 6ecqeerHrIr,L AoJrxeH XpaHxr s 6anxax opapKeBoro creKJrac nplaTeprrrlrn npo6KaMI{B 3arrlrqeHHoM MecTe. oT cBeTa gI

Ka.nufi fi oAHonaro-rurclufi . Crr,r. Ka.nns fi ogar. Karns fi oAonncpryrara pacrBop K 0,85 r BHcMyra Hr,rrparaocHoBHofo npu6aerxror 40 un BoAbr,10 rran yxcycuofi KrlcJlorbrneA,f,Hofiu20 vn 40 % pacrBopa KaJrrrrito1u4a. Karuq fioAoerclryrara pacrnop (1) 100 r nuusofi Kr,rcJrorbr pacrBopsrcr e 400 MJrBoAbr, npH6auxror 8,5 r BvcMyra Hr{Tpara ocHoBHoro,BcrprxuBarcT B TeqeHHeI u, npu6anr-sror 200 rvrn % pacrBopa 40 lrlarvIfl. fioAuAar,rgHepruqHoBcrpsxuBalor. Bu4epxuBaror 24,ru Qunrrpyror. Xpauxr B 3arquqeHHoMor cBera Mecre. Karuq fioAosrcilryrara pacrnop (2) pacrsop. Cycnen4upylor 1,7 r nucuyra Hr4Tpara I,Icxo.uHrrfi ocHoBHorou 20 | Br{Hsoi xucnorH s 40 MJrBoAbr.K cycneusuunpn1awr*or 40 u;r 40% pacrBopa :rraJwffi. fioguga,BcrprxuBaror B reireHue I q u Qrnrrpyror. Cpor roAHocrr.rpacrBopa - HecKoJrbro Anefi, npv xpaHeHilrrBo $rarouax opaHxeBoro
CTCKJIA.

Pacrnop nrs onprrcxzeaHr,rq. Henocpe4crBeHHo rrepe.{ucnoJrb3oBaHneM cMerur.rBaror 5 vr ucxoAHoropacrBopa c 15 vrn BoAbr. Ka"ruq fi oAonncpryrara pacrBop pa:ne4ennsrfi 100 r euHHofi KrrcnorbrpacrBoprrcr n 500 Mn BoAbru npn6aanqlor 50 Mn pacrBopa Karrvts. ogonucvryrara ( I ). fi Xpanxr B 3aururleHHoM cBera Mecre. or Ka.uns rcap6onar. K2CO3. (M.u. 138,21). {nxanHx xap6ouar. Kanufi yuexnc.nufi. lpaHynuponaHHrrfi noporuoK 6eroro rlBera. furpo cronr4rreH. O.reHr nerKopacrBopnMB BoAe,[paKTuqecKr{ HepacrBop}rM crrprpre oh,arleroHe. B 96 Xpanxr B Bo3AyxoHenpoHrrrlaeMoM xoHrefiuepe. Karnq-Harprrfl raprpar. CaHaKNaO6' 4H20. (M.pr. 282,23). Kalufi-Harpuir, uuunoxucnufi 4-eoAHHfi.CeHrerosa conb. Eecqneruue, npkr3MaruqecKr4e Kplrcrannbr. pacrBopnM B cnr.rpre96 %. Jlerxo pacrBopt4M BoAe,oqeHbMaJro B Karnfi MapraHuonorcncnsrfi.Cvr. Ka.nufl nepMaHraHar. Karnfi HaAcepHoxuc.uufi. Crra. Karur nepcy.nsQar. Ka.nug Hrrpar. KNO3. (M.u. 101,11).Ka;rufi asorFrorxcmrfi. EecqserHrre, ilpo3parrHbre Kpr{criurJrbr. O.IeHr nerKo pacrBopr,rM roprvefi BoAe,nerKo pacrBopr.rM BoAe;oqeHbMiuro pan B o/o, crBopI,IM cnlrpre 96 B e$upe. Karnq uepfiogar. KIO4. (M.pr. 230,0I ). Kanufi fio.qsorucnufi . Kpucrannnqecxzfi nopouroK 6eroro rlBera uru 6ecqnerHbreKpncrannbr. Maro pacrBopr{M B xoJroAHofiaoge, pacrBopr{M n ropxuefi BoIe; oqeHb Mano pacrBoprrMB crrr4pre96 %. Karrq QeppuuepfioAara pacrBop pacrBopa I r ranu-{ nepfio4ara pacrBopqror s 5 l{r 12 % cBexenprlroroBJreHHoro oh pacrBopa xenesa(Ill) Karwls, rnrpoKcrrAa,npu5anlstor 20 Mn BoAbrn 1,5 un 10,5 pacrBopoM Kanr4rrr4ApoKcnAa xnoprrAa, AoBoArr 12 % cBexenpuforoBJreHHbrM Ao o6reua 50 ur. Ka.nnfi Qra.nenorcnc.nrrfircucnufi . Cu. Ka.rrnn ru4poQraJrar.

EE[,

Kaflnq repMaHranar. KMnOa. (M.u. 158,04). 6necrou. PaKpr.rcraJrnbrcrrHeBaro-craJrbHblM c rrorrrll qepHbre Tertro-QuoJreroBbre, cilI{pre n crBoprdM B xonoAHofi no4e, JrerKopacrBopr.rM ropxvefi BoAe,MeraHoJIe, o arleroHe. 96 , Ka.uns nepMaHrarrara pacrBop 3 o/on QocQopttoft rcnstore pacrBoprror B cMecu 15 rvrn 3 r xarus nepMaHraHara $oc$opnofi rncnorrr KoHIIeHrpr.rpoBanHoiauT0MiI BoAbI,AoBoMr o6reu pacrBopa soAofi ao 100 rvrrl. Ka;rus repMaHranara pacrBop 3 o/o. Pacrnop 30 r/;r. Karuq repMaHraHara pacrBop AJ o/o 0,1 r xanur nepMaHranarapacrBoptrcT B BoAeu pas6annxrorsoAofi ao 100 rr.t-u. or npo6ralru B 3aIrII4IrIeHHoM cBera 6aixax c Epr{TeprbrMr,r Xpanrr B creKn.f,HHrrx Mecre. Karnq [epMaHraHara pacrBop Hacrtulennufi LI 100 9 r raruq [epMaHraHara gaJwrBaror Mn roprqefi so4rr, rlepeMefiri{BaFor ocraBcreKJIac npl4n irsror ua 1 .r, nocJreqefo ocropolffio cJruBarcT 6anry opaH)KeBoro reprofi npo6xofi. or Xpanxr B [poxnaAHoM, 3aIIII4IIIeHHoM cBera Mecre. o Karr.rq ilepMaHFanarapacrBop n SocQopnofi rlrcnore pa3BeAennoft10 3 r xalns nepMaHfaHarapacrBopnor rrpr4HarpeBannu s 100 nr.rr Qoc$opHofi xucI0 iiorbr piBBeAeHHoi'r Yo. Kanun neppeuar. KReOa. (M.,"r. 28934). roporxoK 6eroro IIBera. Kpucra.rr"riuqecrufi pacrBopl4M clrl{pre 96 o/o, B MeraHonerI [porIHneHrJILIKoJre. Pacrnopul,rB BoAe,MaJTo Karus nepcynnQar. K2S2O3.(M.N{. 270,33). luxaxux repoKcuAllc-vnr$ar. Kanuit HaAcepHoKucrufr. fiopolxoK 6eroro IIBera. Kpr4cranJrr{.{ecxnfi FecqserHue Kpr{crannbr r4rrr4 P a c r n o p r r MB B o A e ,n p a K T u q e c K nH e p a c r B o p u MB c r l u p r e 9 6 % . B o g u u e p a crBopbr pa3nararorcq npu KoMHarHofireuneparype, 6rtcrpee * rtpLt HarpeBAHVIId.

Mecre. Xpauxr B rrpoxna,{HoM Karuq nl,lpoaHrnMoHar. KSb(OH)6. (M. pr. 262,90) . Karug reKcarr4ApoKcoaHruMo}IVIUI.

pacrBopl,IM B Kpncra.ri.nbrvrrliKpr{crannx.{ecr[fi nopoilroK 6eroro IrBera.YnrepeHuo

BO,IIC.

pacrBop Ka.uHsflHpoaErrr{Mouara pacrBoprrcr e 95 Mx roptqeft eo4rt, 6ntcrpo oxnaxnaro! ri,rpoaHTr{MoHara 2 r rcaxus H s 50 BoAbI, i ra;ipa2"5 npu6ae:r*or pacrBop,conepx(aruvit | :rraJrv,ArlrApoKcrrAa MJI 24't, B pa3BeneHuoro %. BsI4ep)KHBaror TerreHfie 8,5 crBopaHarpi{sruiApoKct{ra 150 nan. $u;*rp1,ror r{ roBoAsreoaoii Ao o6lenaa pacrBop Kanms n"rronrdnra ri{rpoKclrAapacrBop.sEor rlr,rrpara 50 r Karrvrs. r.r 1,7 r cnusua(Ii) arlerara, 3,4 | Karrrrfr, pacrBopnreneM 100ul. reM )ICe B BoAe AoBoAsr r{ o6reu pacrBopa Ao Cv. xucnufi" Ka,rHn 6r.rcynr@ar. Kanilq ruApocyJlrQar. Ka.uufi cepnoxnc,rrrft Kanraft cepHoKr{crrufi. Ka.irnscy,rrQar. K"SO4.(M.*. 174,27). {uxanraxcytmQar. Kpr{craJlnbl. FecqserFrHe

wz

pacrBoplrMn ropxvefi BoAe,ilpaKTurlecKla HepaPacrnopunrB xonoAHofisoAe,JrerKo oA,alleroHe. crBoplrM B cnrrpre 96 Ka.nus raprpar. C4H4K1O6' 0,5H2O. (M.u. 235,35). luxatmx (2R,3R)-2,3l,4Ardrr.rApoKcu6yran- gurcapdoKcuna! reMrIrLIApar.Katmfi, gHHHorucrHi. 6eloro IIBera. lpanynuposaHHrrfi fl opo rrroKvnrl KpLIcriIJrJrbI pacrBoplrMB ctll{pre 96 %. pacrBopr{MB BoAe,otleHbMaJIo Oqenr JrerKo pacrBop Kanus rerpafi o4oMepKypara pacrBoprm e 50 MJrBoAbr, npn6aar*or 5 r ranus,itol^u4a 1,35 r pryru(Il) xnopr.rAa r{ AoBoArr o6reu pacrBopa no4ofi ao 100 run. noft pacrnop Ka.nns rerp afi ogoMeprrypara rrleJrorr 11 r xanuq fiog;u4au 15 r pryru(Il) i,to1u4apacrBoptrcr B BoAe, AoBoArr o6rervrpacrBopa reM xe pacrBopnreJreM 100 ur. HenocpegcrBeHHorrepen llcrlonb3oBaAo HHeM no;ryvenHufi pacrBop cMeIuIaBaIor c pacrBopoM 250 rlt Harprtfl (1:1). rr{ApoKcuAa Karraq rerpafioAoMepxypara(Il) ulenoqnofi pacrBop. Peaxrun Hecclepa. s 1. K pacrnopy 10 r Karrnr itop.ugLa 10 rr,{rBoAbrrrocreneHHonpn6anntnr npu noHacbrrqeHHoi pacrrop pryTrd Ar4xJropnAa rlotBneul4t ororHHoM nepeMerur4Baunvr Ao KpacHoroocaAKa.llpu6awmror 30 | KaiIlI eAKorou nocJle pacrBoHeucrre3arcruero - eue I Mn HacbrrlenHoro paerBopa p'ryru Ar{xnoprlAa.Pas6aerqrcr eoAofi peHHfiero npo3parlHylo xcnAKocrbcirlrBaror. .uo200 MJr,ralor orcrorrLct, 14 ll. 21,5 r ralus ito1,u1a pacrBoprlor s 50 Mn BoAbr n ror6e BMecrl4Mocrbro 300-500 u;r, npu6aBrrslor 39 r pryru(Il) fioauaa n nepeMerrrr{Baror nonHoro paAo pacrBoprrcT B orAenbnofi xon6e e 200 Mn BoAbIH crBopeHur. 150 r Kanr{ eAKoro ocropoxHo npunlrBalor B cMecb pacrBopoB Karrrt fia1ura u pryru(Il) ftoluaa. PacrBop oxnaxAaror, nepeHocxr a ro;i6y opaHxeBoro creKira BMecrl{MocrbroI I u AoBoArr o6reu pacrBopa noAofi .qo MerKr4.Pacrnop orcrauBalor B TetleHue7 cyr. go crb o cBerJr eHnr. Ilposp auHyro )Kr4AKo cJruBalor. Hecc:repa, pacrBopa aMMHaKa npn6ar;rarcr 3 ranml peaKTIaBa K 10 un 3raJroHHoro
TOTqaC Xe AOJTX(HO nOtBIlTbCt XeJirOe OKpaIlI{BaHpIe.

B c Xpanxr B cKmHKaxopaHlreBorocreKJra ilprrreprblMll npo6xarrall 3arII4IrIeHHoM MecTe. or cBeTa '2H2O. (M.t. 254,20). Kannq rerpaoKcaJrar. C4H3KO8 Kpucrarruqecxufi ropouroK6eriorouBera. B Vuepeuuo pacrBopl,IM BoAe,pacrBopl{MB KanflIrlefi eoAe, MaJIopacrBopllM B crrr4pre %. 96 97,18). Karrq rrrorluanar.KSCN. (M.r"r.
c 6 ecqseilrrI e KplrcraJrJlbl,pacIIJIbIBaIonIuefl.Ha Bo3Ayxe. cnupre 96 %" Oqerlr nerKo pacrBoprrMB BoAe14 roHrefinepe. XpaHrr B Bo3.tryxoHenpoHl4lraeMoM oh, Pacrnop 97 rlr, Ka.rrns rr{oqrranara pacrBop 907 Kannq xapdonar. Ka.rrufi yrureKr{cJnrfi.Crra. Ka.unfi yKcycHoKuc.nrrfi. Cna.Ka.nus allerar. 329,26). Karus reKcalll4aHo-Qeppar(Ilf. Kanils QeppnuraHua. K3[Fe(CN)6]. (M.rur. . KpacHar KpoBrHar coJlb. Karivfi )KeJle3ocl4uepo,4ucrufi Kplrcra.nrbr KpacHoro rlBera.

Jlerro pacrBopr,rM B BoAe, pacrBopr.rM B arleroHe, oqeHb Miulo pacrBopllM B cnrrpre 96 %. KarIlrq QeppnqnaHnAa pacrnop 5 7o BoAbr,pacrBoptlor B 3aausarcr 5 r ranus Sepplrqlranr41a ne6onrurnM KoJrr{qecrBoM BoAerr AoBoAqro6reu pacrBopa reM )KepacrBopr,rreJreM 100 nar. Ao prcrroJrb3oBaH[eM. loroesr He[ocpeAcrBeHHo nepeA Ka.irnn QeppnqrlaHlrA. KpacHan KpoBflHafl coJrb.Crra. Karnn Qeppoqnanna. Ka[Fe(CN)6] ' 3H2O. (M.u. 422,42). Karurs reKcaIII{aHo3-soAHrrfi. conb. Kanufi xene3rrcrocr.rHepoArrcurfi Seppar(Il). Xenras KpoBqHaq rlBera. llpo:p aunbre Kpr{cra^rrJrbr )KeJrroro HepacrBoprrM crr4pre 96 oh, pacrBopllM B B Jlerxo pacrBoprrMB BoAe,npaKTr4qecKu aueroHe. pacrBop 5r3 o , Pacrnop 53 rlr' Karrq QeppoquaHrr.ua Kanns QeppoqnaHnAa pacrnop 5 7o 5 r raru.rq Seppoqxa*Vra pacrBopruor B BoAerdAoBo.qflT o6rerr,rpacrBopa eorofi Ao 100 rran. Karrq QocQar ABy3aMerrrennuft.K2HPO4 ' 3H2O. (M.rnr.228,23). Kanufi Qoc3-noAnsrfi.Kanwit Qoc$opnoxzcmrfi ABy3aMeIIIeHQopuoxncnrrfi 4ny:aMexleHHbrfi urrfr, rpurwqpffi. Eenufi KpucrtllrnIlqecxufi nopoilroK rrnH KplrcraJrJrbr. Ka.nnq QocQara ABy3aMerrleHnoropacrBop. 1 r xaru-fl QocQara ABy3aMexIeHHoro pacrBoprrcr e 33 tr. BoAbr. Ka,rlrq QocQar oAHo3aMeulennufi. KH2PO4. (M.r"r. 136,09). Karnfi QocQopttorcuc.lrrrfi oAHo3aMeuIeHsrrfr . B EecqserHHe KprrcraJrru. Jlerro pacrBopr{MB BoAe,otreHbJrerKopacrBopr4M roprB uefi noge, npaKTnqecKr.{ HepacrBopr4M crnrpre 96 %. pacrBop 0,1 M Karns QocQara oAHo3aMerrlenHoro rr3 r{ Karlus Soc$ar oArro3aMerrlensrrfi [epeKpucrrurJrrl3oBbrBaror Bo.qbr BbrABaxcAbr cyurrrBarornpu 110 "C Ao nocrorsnofi Maccbr. 1,36 r repeKpr.rcrannugosaF{Hbro pacrBoprrcr B BoAerr AoBoAtr o6rert pacrBopa Karrvfl, $oc$ara oAHo3aMeueHHoro eoaofi ao 100 un. Ka;rnfi Qr a,renorcnc.irsr . Cu. Ka.nnn rryIpoQraJr ar. fi Ka.rrrq xrropar. KCIO3. (M.,". 122,55). Kannfi xnopHoBaroxucnufi. Eeprorerora
coJIb.

flopourox r{nu rpaHynbr)r4rrpr Kpr{crannbr6eroro rlBera. B Pacreopulr B BoAe,nerKo pacrBopr.rM Kr.rnrurefisoAe, oqeHb MaJropacrBopr,rM B cnupre 96 %. Karrq xJropara pacrnop 5 %o 5 r xall.usxnopara pacrBop.rrrcr BoAeH AoBoArr o6reu pacrBopa soAofi ao 100 u.r. B (M.u . 74,56). Ka.rrufixropHcrrrfi. Karrq xrropnA. KCl. Ferrrfi Kpr{cra,'rn[qecrnfi noporxoK. n Jlemo pacrBopnM B BoAe,oqeHbJrefKopacrBopprM ropxuefi BoAe,orreHbMaro pacrBoprrMB crrlrpre 96 %. Karuq xnopr{A, r{cilonb3yeurrfi Arx HHSpaxpacuofi a6cop6uuoHnofi cuexrpo$oroMerpr,rv,AonxeH BbrAepxr.rBarb cneAyroqee AorronHr4TenbHo e rpe6onanue.

EE

tr{K-cnexrp AI4cKaKanus.xJropl4Aa rorrqzHofi 2 ww, rpeABapr.rreJrbHo BbrcyrueHHoro npLITeMrleparype250 "C B TerIeHHe v, 4onxeH HMerb rrparffHqecKu I poBHyro6asoByro nriHllro B I{HTepBauIe He AnrrHBonH or 4000 ao 620 ctvt-t. Ao.nxeHr.rMerbMaKc}rMyMoB c nornolqeHneM 6oree 0,02 HaA 6asonofi r,'uuneit, 3a lrcKJnoqeHr{eM MaKcr{MyMoB.qnr BoAbrrtpv rnillaax BoJrH 3440 cv-'ln 1630 cu-l. Karrq xJropr.rAa pacrBop 0r1 M Pacrnop Karryrs. xnopu/Ia coAepxrrr 3KBrrBaneHr 7,46 r KCI s 1000,0 Nar. Kanus xpollar. K2CrOa. (M.r"r. 194,20). lnxatmn xpoMar. Kanufi xpoMoBoKuclufi. Kpvtcra,r:rbr )rceJrroro uBera. Jlerro pacrBoprrMB BoAe,npaKTuqecKri HepacrBopr.rM cnr.rpre96 %. B Ka;rns xpoMara pacrBop 5 oh.Pac'rnop50 r/n. Ka.nufi xpoMoBoKuc,rrrfi. Cu. Ka,rnfl xpoMar. Karns xpoMar-pacrBop r.r p HArrKaro a. 5 oh pacrBop. Karrq qrraHrA. KCN. (M.v. 65,12). Kpzcrannu.re crllfi noporxoK rrrrv Macc rrilurlpaHynbr 6eloro qsera. .flr. a, Ilerxo pacrBopr{MB Bo.ue, Mano pacrBopr{MB cn}rpre 96 %. Karrq urraHuAapacrBop l0 o . Pacreop 100 r/:r. Karnq rrnrpar. HOC(COOK) (CH2COOK)2.(M.rur. 324,42). Tpuxarzena.f, conb 2-ru-xap6ouonofi Kucrrorbr.Tpuranufi nrrMoHHoKuclrrfi 1,2,3 .upoKcrrnponan. Eenufi rpaHynl{poeaHHrtfiroporxoK Hnr{ npo3parrHbre Kprrcrannbr;rurpocKonuqeH. O.IeHr nerKo pacrBopnM B BoAe,npaKTr{qecKrr HepacrBopr.rM cnr.rpre96 %. B Kalrunou. C30H15N4Na5O22S6HzO (M.r"r. 1108,8). flenranarpr4eBa-s conb "-rerpaoxcn-(8,2' ,8' ,2' ' -6uc-asorpuua$ranuu)-3,6,3' -rexcacynb1,1',1",8 ,6' ,3'' ,6" MoHorr4Apar. Qoxzcrorbr, 9epHufi c $uoleroBbrM orreHKoMrropoilroK. Pacrnopuu B BoAe,npaKTuqecKrr HepacrBopr4M aueroHe, 6eH3ore, cnr4pre 96 %. B B unrepnane pH I 1,0- 13,0 lrMeer clrHrorooKpacKy, ero KoMnJreKcbrt4 a c oHoMKitJrbqrl.rlB Tex x{e ycJloBtrrx po3oBofo IIBeTa. llepexo4 oKpacKr4 pacrBopa npr4ilpqMoMTr.rrpoBaHr.rr4posonofi r cusefi. or o/opaunop. Pacmeop uudurcamopa. 0,I Cpor roAHocrrr pacrBopa - 1 vrec. Karrurq rrrApoKclta. Ca(OH)2. (M. r'r. 74,I0). Kamquq Ar{rHApoKcr4A. floporuox 6eroro rlBera. IparrnvecKrl HepacrBopr.{M BoAer.{crr{pTe 96 o/o, B pacrBopr{MB pacrBopax MrrHepanbHblx KI{CJIOTLI paCTBOpe aMMOHI{' XnOpLIAa.

Kanrqns rrrApor(crAa pacrBop CnexerpnroroBneHHufi HacurueHsufi pacrBop. Ka,rrulrs rrlAporccr.rAa pacrBop. I4:necrKoB afl Bor a 1 q. xxeHofruzsecru racqr 5 .I. sorH; raruuqeo6pa3Hyro MaccynepeHocqrn 6yrunr, npn6auxrot 15 q. BoAbI,cIrJIbHons6airrrrsaror lr ocraBJrmor na 4-5 qacoB. 3areu BoAy cnl4Baror ot6pacunaror. Ocraror o6nunaror 50 q. xoroAHofi no4rr, ss6anrrru Baror,yKynoprlBaror6yrunb rr ocraBJr-sror rrpoxnaAHoM B Mecre Ha HecKoJnro4nefi, BpeMqor BpeMeHH sg6a,rrrreas. BoAy no Mepe Ha4o6uocrr4 cJrr4Baror ocaAKar4 c ,I[nx ynorpe6;reuus I43BecrKoByro o6reua; $nnrrpyror, a K ocaAKy BHoBb npulayrrxror BoAy ro nepBoHaqarrbHoro @

yKynopeHHofi 6yrruru rr B36anrbrBaror ocraBrqFor B npoxnaAHoMMecre B TulareJrbHo noAu. Anr nonyqeH[q HoBofi nopuuz H3BecrKoBofi Karsqrq xap6oHar. CaCO3.(M.pt. 100,09). Eenufi noporroK. B flparrnuecKr4 HepacTBopIrM BoAe;pacrBopuM B pacTBopaxaMMoHI{txnopl{Aa. I,Igsecrr xxeHat. Ka.rruuq oKcrIA.CaO. (M.r"r.56,08). Kalrqux oKlzcb. Ha B Belue KycKr{unu [opouoK, cJrr4rraronluitcs.KoMKrr. nos4yxe norJloqaer BoIy u yDrepoAa. AByOKrrcb Pacrnopnlr n ropr.refi eo4e 0,66:100 npra80 "C. Pearnpyer c Kr{cnoraMr{. 2H2O. (M.rr. 172,17). Ka;mqufi cepnoxucnufi Ka.nrqrq cymQar. CaSOa -so 1ustil K anrqH fi c epHoKl4cn ntit, ruru4par. f irnc. 2 Eenrrfi MenKoKpllcrarruqecrHfr nopouror. KI{cJIorax,Harpldt rLIopacrBopuM B BoAe,pacrBoplrM B Mr4HepanbHbIX O.reHr MaJIo cyrrQare, coJrrx aMMoHrr{,rJll,rueprrHe. KanruIlq cy;rsQara pacrBop nacuulennrrfi 0,4 r ralruux cynrQara es6ambrBalor co 100 Mn BoAbIIr ocraBntror Ha 24 u, npevx ns6arrsreas. PacrBop nepeAynorpe6reHl4eMocropoxtHo AeKaHTltpylor. or BpeMeHu Karuqun cy.rrrQar.CaSOa' 0,5H2O.(M.r"r.145,15).Kalruns cynr$ar, nonyruApar. Kamuu.fl cynrQal reMl{rl{Apar. llopourox 6eroro uBera. Pacreopuna ilpl{MepHo B 1500 ilacrtx BoAbI, ilpaKrurlecKr HepacrBopl4MB cilr.rpre96 %. Maccbl KanbIIHt cyilbflpu crueurvBanr4yr no4ofi, Macca r<oropofi paBHa rroJroBr{He c B noprcryro Maccy. rrpeBpaurarcb TBepAyro Sara, noporxoK 6rrcrpo 3arBepAeBaer, Ka.rrurq cy.usQara reMlrrrrApara pacrBop ns6arrbrBaror co 100 Mn BoAbIe reqeHue I q n 5 r xalruux cynrSara feMrrrr4Apara Qnnrrpyror. fi Karrqnq x,'ropnA6esnoAHrI . CaCl2.(M.r"r.110,99). oh CaCl2, B repecilere Ha cyxoe BeulecrBo. Co.qepxur He MeHee98,0 lpanynrr 6eroro rlBera, pacnnblBarculuect Ha Bo3Ayxe. pacrBopr4M BoAe,JrefKopacrBopuM B cnl{pre 96 % H MeraHone. B O.reHr JrerKo Ilomepn 6 Macce npu rrrtcywu*aHuu.He 6onee 5,0 oA.Onpe4ereHl4enpoBoAtr B cyrrrrrrrbHoM umaSy nprareMrreparype200 "C. xoHrefiuepe, 3anlrlrlat or Bo3AefrcrsusBJraM. XpaHxr B Bo3AyxoHerrpoHr{rlaeMoM o/o. 20 r xanrqnt xnoplrAa pacrBopttor B BoAeI{ KaJrsqnq xJroprrAapacrBop 20 AoBoAqro6reu pacrBopa noAofi ao 100 ul. pacrBop 7r35 oh. Pacrnop 73,5 rlt. Karrunq xd'roprrAa pacrBop 0,02 M Kanrqrq xJroprrAa pH 2,94 r Kanbrlr{r xnopula pacrBoprrcr e 900 MJrBoAbI,ycraHaBJrl,IBaror pacrnopa go 6,2 rr AoBoAf,T o6reu pacrBopa eoAoft lo 1000,0 Ivrn. B rrpeAenaxor 6,0 'C. Xpanxr nprr reMneparype or 2 .qo 8 KaJrsrlrq xJropr{AapacrBop 0101M xnopuAa pacrBopmor B BoAer4AoBoArr o6seN{pacrBopareM xcepa0,147 r KaJrbrrr4f crBopr.rreneM 100,0 rr,rn. Ao

Ka.nrurq xr'ropr{A rerparr{Apar.CaCl2' 4H2O.(M.u. 183,04). 0,05ppm Fe. Co4epxur se 6onee Karsuufi xd'roprrcrbrfi . Cnr.Ka,rrq[q xJIopLrA. KavreAr6o6ospolr(KoBoro AepeBa Ceratoniasiliqua L. Taub. tr{:N.rerr.reuuufi sHAocnepM $pyrronux Kocror{ex o/opacrnopuuofi BoAe B cMoJrbI, coflopourox6eloro rlBera, coAepxaqufior 70 rc 80
croquefr B o cHoBHoM LI3f aJraKToMaHHorJII,IKoHa.

KavrQopa. I oH160 (I 52,24). . C [opouroK c KycKr{u.rru6ecqsernufi Kprrcrannu.Iecrufr BensreKpucrannuqecKne

cr,rJlbHbrM xapaKTepHbrM 3arraxoM. pacrBoprrMa cnrpre 96 o/o aSzpe, u B B O.reur ManopacrBopr{Ma BoAe(0,1: 100),JrerKo pacTBopr4Ma arleToHe. B s ucnonb3yen4ofi rasoeofi xpoMarorpaSuw, Xpouarorpa$uuecraa qucrora r<anQoprr, .rlonxHa6urr He MeHee98,0 %. Kao.unn,rerxufi rrrAparupoBaHHufi.Co4epxHT rIoAXoAtOquqesurrfi upupoAHrrfi aJuoMocr4JruKar ulufr Aucneprarop. crleKlxl{xct qacruu, Mac,rlerxufi noporuoK 6eroro rlBera, He coAepxax]uft TBepAbrx nsluuctstit Ha oqyrrb. KrrcJlorax. B flpaxruvecKr{ HepacrBopr{M BoAeH MI{HepanbHbIX qacmutlbr.He 6oree 0,5 o .5,0 r raonNHarroMeulalorB IIHnrrHAp rIpHTepc Rpynuute npo6xofi Arr.rsofi oKono 160 unr r{ AuaMerpolr 35 u*r, npu6aB-Jltror rofi crexnqHFrofi o/opawnopaHarpuflnuposocQara, sHepfHr{Ho B Bcrprxr{Barorrr orcraHBaroT 60 un I Ha Terregr{e lrus. C nolrourro nurrerKn or6uparor 50 prn )KLIAKocr}r ypoBHeoKono 5 5 cu Huxe noBepxHocru u or6pacbrBaror.K ocrasurefics xurKocrl4 upH6auxrcr 5 BcrprxuBaro! orcrarrBaror B TeqeHLIe uun v y[anfrwr 50 rul, KaKoIrI450 nrn Bo.rlbr, e caHo Bbrrrre. 3ry ofiepaquro noBToprrcTAo rex nop, rroKaHe 6yler yAaJIeHo o6uefi qaurKyAn,xBblnapr4BarvIfl, B cno)KHocru400 nrn.llepeuocrr ocraBrxyrocr cycneH3l{ro BbrrrapuBaror soA.fiHofi Ha 6aHe4ocyxa u cyrxar Ao nocroxrrsofi Maccbl[pI{ TeMnepa6urr se 6oree 25 ur. rype or 100 ao 105 "C. Macca ocrarKa AonlKHa qacmulbt.5,0 r rao:rvHa rvcileprupylor s 250 MJIBoAbIrrpll sHeprI,IqHoM Menrcue B Bcrprxr{BaHwvtB TeqeHrre2 wun }r rorqac BbrJrr{Baror creKirtHnrrfi qu.lruHApAL{aMerpoM 50 lrnr. C nououlrrc rrnerKn or6uparcr 20 ltr, rroMeularorn QapSopoBylo r{ailrKy,Bbrnapr{Ba}or soA.flHofi Ha 6aue 4ocyxa H cyrrrar Ao nocrotsnofi Maccblnpu 'C. Ocraror cycrreH3rrrr orcrarrBaror npu reMneparype reMneparype or 100 ao 105 'C B Ter{eHr4e q n c noMorrrbro yAi]nrror 20 rrarHa ypoBHero.{uo 5 cN4 rrunerKpr 20 4 B3MyrruBatoca.4oK.Ocraror rloMelqaror n $ap$opoBylo Hr,rlxenoBepxHocrz, He qarrrKy,Bbrnapr{Baror Aocyxa u aywar Ao nocrorHsoil Maccbl npu TeMleparype or 'C. Macca Broporo ocrarKa 70 100 ao 105 AonxHa 6urr He MeHee % or MaccblnepBO|O OCTarKa.

Kanplr.nonsrficnupr. Crr,r. r{ercano.n. Kap6aro,r.C I 2HeN.(M.r'r.| 67,20). [n6eHsonuppon. pacrBoplrM alleroHe, MaJIo B B JrefKo Kpncran,rsr. IpaxruqecKrr HepacrBopuM BoAe,
pacTBopHM B sTaHOJre. Teunepamypa lLilazreHus. Oxolo 245'C.

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Kap6arona pacrBop 0r5 oh 0,5 r xap6asona pacrBoprrcT B cnr{pre 96 o/oe trepnofi rol6e BMecrnMocrbro 100 rran AoBoArr o6reu pacrBopa crruproM 96 % Ao MerKlr. r,r Kap6olrep llonepevuo-cruuurfi flonl{Mep arpn,ronofi Kr4crrorbr, nocJreBbrcyur.rBaHr{r nprr reMneparype 80 "C B reqeHrle 1 u coAepxnr 6omuoe KoJrnrrecrno rap6orcr4JrbHbrx rpyrn (-COOH, or 56 rc 68 o/o). Cpe4nrr MoneKynrpHafl.Macca oKoJro x 106. 3 plL Oxono 3 (I% cycnensnx). Kap6oQenoruoH. CllHl6ClOzPS:. (M.r"r. 342,84). O,O-,{u:rur-S-[[(4-xnop$eHlrn)rzo] uerun] - So c Sop.uuruoar. XuAxocrr x(eJrroBaroro rlBera. llpaxruuecKu HepacrBopr4M BoAe,cMerrrr{Baercq opraHnr{ecKr4Mr4 B pacrBoprrrec
JtgMvt.

d1' . or<otro 1,27. Kapnarcpo.n.sH1aO. (M.rvr.50,21 5-I4souponun-2-uerurQeuor. C1 | ).

XnAxocrr Kopr4qHeBarofo rlBera. llparruuecKH HepacrBopuMB BoAe, oqeHb JrefKopacrBopr4MB c[r4pre 96 o/ou

a$upe. dii . O*ono 0,975. n') . oxono 1,523.

Teunepamypa KuneHu.fl. Oxono 237'C. rrl4crora KapBaKpona, XpovrarorpaQuuecxax rrcnoJrb3yeMoro ra3osofi xpoMarolpas o . Srzz, 4onxHa 6rrrr He MeHee95,0 KapnoH. Cl0H140. (M.r"r.150,21).(S)-n-Menra-6,8-4ueH-2-on. -2-Mernr-5-(1(+) -2 MerrdJr3TeHun)quxnorerc-eHou. Xlr4xocrr. IlpamuuecKr{ HepacrBoptrM Bo.qe, B cMerrrr4Baercq cnrrproN{96 %. co

dli . O*ono 0,965. n',1 oxono1,500. .

Ldl,, . Oxolo +61 ". TeunepamypeKuneHltfl. Oxono 230 "C. Xpouarorpa$Nvecxax qr4crora KapBoHa, r{cilonb3yeMoro ra-:osofi xpoMarorpa$uu, B oA. AoDKHa6urr He MeHee98,0 . Karexns. C15H14O6 xH2O. (M.*. 290,26,4rx 6eseo4uoro). (+)-(2R,3S)-2-(3,4,{nua4poxcuQeunn)-3,4-rurulpo-2H-xpouen-3,5,7-rprroJr. Karexol. I-{nauu4auol. I{uauugor. E ecqeerHrr e Kpncran rrbryrrvt uroJrbq arbre o 6p asonauzx. Pacrnoputr,t BoAeIr crl{pre 96oh, Mzulo pacrBopr{Mn e$zpe, oqeHbMirJro B pacrBopr.rM B aueToHe. Karuouur cna6urfi. Karuonnr cna6oocnosHrrfi Crvrona IIoJIItMeraKpr{noBar cna6orHcnaq, coAepx au\afl xap6oxcz.nbHbre rpynrrbr B nporoHrrposaHnoilQoprvre.
. r2o

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Pasuep uacmuq.Or 75lo 160 narrra. npedanu pH. Or 5 ao 14. Irlcnonusyentorc . BaHufl I20' C. me amypa ucnonb3o MarccuuanbHar 4nep KarnoHoo6*renHaq cMoJra c Cuola B nporoHlrpoeauuofi Qoprr,re rpynnaMracynrQonoeofi xucrorbl, nplacoeAllcocTorlqero LI3non[cTl,Ipona noflepeqHo-cullToro K nonr4Mepa, HeHHbrMr,rperrreTKe 8 o/o lusuHHr6ensora. Brrnycr<aroTB BuAe rpaHyn, pa3Mep KoTopblx yKa3blBarcT B OH peaKTI{Ba r4crrbrraHvIflx) KOTOpbTX IdCIrOJIb3yeTCS. B rrocJle Ha3BaHI..''fl Karuonoo6rrrennaq cuora (1) Cuola B rrporour4ponaHuofi $opue c rpyrrraMu cyrrQonosofi rucrorbl, npI4coeALInonllMepa, cocTosrqeror43ilonl{cTktponanollepeqHo-cllrHTofo HeHHbIMH perrreTKe K o/o 4 lusunun6engola. BrrnycKaroT B BuAe fpaHyn, pa3NrepKoTopblx yKa3blBaroT
rlocJre Ha3BaHr,It peaKTI4Ba B I,ICIIbITaHkTflX) B KOTOpbIX OH I,ICnOJIb3yerCt.

Karnonoo6*rennas cMo,'IacrIJIbHafl(rcalrqnenan Qopua) Crrlola B KanbrluenofiSopue c rpyilnaMu cyrmQoHosofixlacrorbl, rIpI4coeAI4HeHHbIMLI K perrrerKenonr4Mepa, cocroqrrlero H3 nonlrcrllpona flonepeqHo-curllToro8 Yo !.usuqacrurl yKa3brBarorrrocJle Ha3BaHvIfl. peaKTI{BaB qacrHblx Pasrr,rep HtaJr6eHsora. cTaTb.f,x. pH Karo.nur Arrfl rr3osJrerrpoQorcycrrpoBKrr or 3 Ao 5 (0r1 M pacTBop B-alaHnHa) pacrBop.f,ror BoAe14 B 8,9 r B-a:laHrrHa AoBoArr o6ren pacrBopa reM )KepacrBoprrreneM.iro1000un. Cru. )Ke.ne:a(III) Ksacusr )KeJre3oaMuonHfinrte. Knacurr xeJre3oaMMoHrreBbre. aMMoHnfl cy,rrQar. pacrBop. Cu. )Ke,rera(Ilf aMMoHrrflcy.nsQara paKnacqos xeJre3oaMMoHueBbrx crBop e asorHofi KrIcJIore. pacrBop rcnc,rsrfi 012oh Knacqos )Keire3oaMMoH[eBblx pacrBop.rrror BoAe,noAKl{cnt}or 6 un pa3BeB 0,2 r rnacuoB xene3oaMMoHr4eBbrx Aennofi asorHoii KI{cJIorbI16 You AoBoAqro6telt pacrBopa BoAofi.qo 100 N{r. ' I{nanrcarop. FeNH+(SO+)z l2H)O. (M.u. 482,2). Ksacqrr xerre3oaMMoHlreBble. -runoBbre npo3paqHble Ha KpHcranJIbI, Bo3/IyxeBblBerpr{Balorct. B;reAuo HepacrBopLIMbI crlr{pre 96 %. B Jlerxo pacrBopr{MblB BoAe,npaKTur{ecKl{ BoAHsrfipacrBop lrMeer Kr{cnyrcpeaKrlHrolr c pacrBopaMr po.qauirAoB Aaer reMHoKpacHoeoKparxrrBaHr{e. pacrBoptrcr e 100 Nar x{ene3oaMMoHI{eBbIX 30 Pacmeop uudurcamopa. | KBacuoB 16 BoAbr,K pacrBopy upu6aurxror a3orHyroKr,rcnorypiBBeAeHHyro oh go nepexoAaKopu.ruenoft oKpacKr4 xenroBaro-3eneHylo. B cnl4pros.B efo cocraBe Keroc'reapu.uonufi cnrrpr. CvrecsrBepAbrxannQarNvecKl{x (C13H33O; creapunoBoro crr{pra He MeHee 40 % Aon)KHo 6rtrr M.u. 270,48); cynua creapr4noBofocrlrpra I{ IIerrJIoBoro cnl4pra (C16H3aO; 90,0 Yo. M.v.242,43) ao,rxna 6rnr He MeHee xJrorlbt I4nHrpaHynbl. Beraq rrJrr.r cBerJlo-xenrat nocxoo6pa:HaqMacca,rrJracrr{HKLI, pacrBopllM a eQupe,pacrBoprrMB cnl{pre B llparruuecKu HepacrBoplrM BoAe,JrerKo BaMacJraMH, cocrorHr4ncMeurrrBaercrc )Kr{pHbIMrr 90 % (o6lo6); B pacnnaBJieHHoM
3EJII{HOBbIM MACJIOM.

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Kuremryp G
Cocrour H3Kn3elrBrypa, o6pa6oraHHoroxropr4croBo4opogHofi rucnorofi r{ KaJrbqHHr4poBaHHoro npz6aBJreHrreM oKoJro15 %oxantqux cyrroara nonyru4para. Menxr,rfi noporroK cepoBaro-6enoro uBera; npr pacrkrpaurilr c eoAofi ceprrfi urer craHoBrrrc-f, 6oree BbrpaxeHHrru.Cpe4nnfi pasuep qacrr,rq- or 10lo 40 nmru. yKa3aHHbrM cr.rnraxare.nf, Ranu4ua cyna$am. Oupe4e.neHr4e iipoBoA-f,T Mero.uoM, G. AJrr pH. Or 7 ao 8. ?lsuepxror pH cycnen3vrvr,noryqeHHoi ncrprxr,rBaHrreM1 r n 10 nn BoAbr, cso6oAHofior yrnepora AnoKcr.rAa, TerreHue uaH. B 5 p Xp ottamozp a Quuecrcan asd enanul afl cn o co6ru cma. Onpe4eneHuenpoBoAtr Meroo AoM ToHxocrofiuofi xpoMarorpa$uu. llnacrnnrr4 roroBrr, ucflorb3y.tr B3BecbKr,r3enbrypa G c pacrBopoM 2,7 rlll Harpufl arlerara. Ha JruHrrro crapra xpoMarorpaQuuecrofi rrnacrr.rHri4 HaHocrr 5 iurn pacrBopa,coAepxaqero no 0,1 r/n JraKTo3br, caxapc3lr, rirlo(o3br n Spyrrosbr B fllrprr,qnHe.XpomarcrpaSzpyror B cHcreMe pacrBopurerefi eoAa- 2-nponaHorr- arr4narlerar(12:23:65). Bperrax rpoxo)K40 oKoJro r,altr. llnacruuxy cyrrrar .4eHI,It $poura pacrBopr4rerefi sa paccro{Hue 14 crra pacrBopoMaHr{coBoro pacxoAyr oKoJrol0 un Ha Bo3ryxe, onpbrcKr4Balor anbAerr{.ua, u HarpeBaror rrpll reMneparype or 100 .Eo 105 oC B reireHne 5 unu. Ha xporvra:rorpaNrN{e xopolxo pa3* o6napyxuBaTbcfl ireTbrpetreTKr.rx, AoJrrKHbr 6e3 ntrHa. AeJIeHHrIX, <<xaocroB>, Knre.rrrryp A.rn xpoMarorpaQun Jlerrufi roporuoK 6eroro HJrrr xeJrroearo-6eroro uBera. flparrvvecKr{ HepacrBopr{N{ BoAe,pa3BeAeHHbrx paB Kr.rcJrorax opraHr{r{ecKr{x v cTBOpHTensx. Crcop cmu Qtunamp quu. l4cvonb3yror xpoMarorpa$uuecxyro KonoHKypa3MepoM o at (100) 14,{Byvrr 4,25 *rx 10 un c nracrr4Hxofi fls roprrcroro crerJ,-ra orrvrerKaMr.r BbrHa core 0,101r ir 0,20 M HaArrJracrrrHKofi. Kononry 3afloirHrrorucnbrryeMbrM BcrrlccrBoM go neprofi orMerKr{, a Ao BTopofi orlrerrlr 3arroJrHs}or soAofi. Korla nepBbreKanJrr4 Haql4Haror BbrreKarbr{3 KorroF{Kr{. cHoBa3anoJrHrrorAo BTopofi oruerrn soAoli yr vr3Mepsror BpeMr BbrreKanrir r{3 KorronKrr flepBbrx 5 nu nogu. Cxopocrr rroroKa AonxHa 6urr He MeHee1 rvrn/unn. Iteemuocma. 3nroa:r, noJryrreHHufinpu ucnlrraHrrr{ Ha cKopocrr $unrrpaqr{r{, AoJrxen 6rrm 6ecqsergrrrvr. Kucnomuocmb unu Lt4enoqHocma. 1,00 r npn6annxror 10 MJrBoAbr,gHeprrlqHo K es6arrrIsaror r.rBbrAepxuBaror B TerreHr{e lrHn. Cycneusuro $nnrrpyror qepe3 5 nponaurrrfi ropa.refi so.qofi 4o Hefirpamsofi peaKuvr{ B $u;rrrp, ilpeABaprrreJrbHo rrpoMbrBrrofi noAe.K 2,0 nn Sn;rrrparanpndaBJrrror 0,05 run 0,05 a pacrBopa Mern.rroBoroKpacHoro; na6moAaercr xceJrroeoKparur.rBaHr4e.2,0 ur Sunrrpara npn6aK BJItIor 0,05 un I Yo pacrnopa QenorSrareuHa; IonycKaercr cra6o po3oBoe pacTBopa. oKparrrr4BaHHe BodopacmsopuMbte 6eulecm6a.10,0 r iloMeurarorB xpoMarorpaQzvecKyroKoJroHKy pa3MepoM0,25 lr x 10 uu, snlonpyror eo4ofi, co6upaa nepBbre20 wutgJrroara,BbrrraplrBalor Aocyxa, ocraroK cyrxar npn reMreparype or 100 Ao 105 oC. Macca ocrarKa 6rlrr ue 6oree 10 ur. aoJDKHa )I{eneso. He 6onee 0,02 o (200 ppm). K 0,50 r upu6augror 10 Mrr cMecr paBHbrx o6reiuos 25 % xnoplrcroBoAopoAHofi rracnorrr r.rBo.(br,gHeprrarrHoBcrprxr{Baro!

EE

BhrAeplcprBaror Terrerrrde rrlrs u Qxnrrpyror. B 5 1,0 ur $nnrrpara Aon)KeH BbrAep)KrrBarb r.rcnbrraHue xeJre3o. Ha ITomepn 6 Macce nocne npoKarunauua. He 6oree A,5 o . Bo npeua npoKurJruBaHr4t (600'C) BerrlecrBoHe AoJrxHorrMerb Kopr,IqHeByro qepHyrooKpacKy. vrvt

Knuropos. 02. (M.rra32,04). . Cogepxnr HeMeHee 99,99% (o6lo6)01 Asom u apzoH. 6o.uee ppm. He 100 Vznepoda duoxcud. 6onee10ppm. He Vznepoda MoHooKCud. 6oree 5 ppm. He Kucnornsrfr cHHufi1. Cna. Cy.nrQaHonufi cnnnfi. (M.rtr.825,9).Epr.r:r;rnanroenfi Kuc,rorusrfi cnnr.rft83. C4sH4aNqNaOTSz. cunuit. Kyr',raccn 6pulimauroerrfi cunuit P25A. llopourox KopprrrxeBoro uBera. papacrBopi{M Knrrrxlefieole I{ granoJle, B HepacrnopuM xoJro.qnoir B BoIe, N{ano pacrBopax n reAxHofin pa3Be.{eHHhrx clBoprrM cepnofiKr.{c.rrore, vxcycuofi KrrcJrore rnApoKcprnoB ulenoqHbrx MeTaJrJroB. Kynaaccn Kpacfirrtrrfi pacrnop pacrBopr{re.rreii yrcycuar Kr4cJrora Pacrnop1.25rl.n KucirorHofo cl{Hefo83 e cnrecia (i:4:5). Ou.rirrpyror. nenflHefr MeranoJr BoAa pacrBop OSecueeqreatorurrfi yrcycHas (l:4:5). Kr4cnora neArr{afl MeraHon BoAa CuecupacrBopr4Tenefi (M.u. 854,0). Kuc,rormsrfi cnHrnfi C4rH$NINaO7S2. 90. Harpnfi L4-ll4-ig-eroxcN@euu;r)auuuol$euarl[[4-(:rur)(3-c;.'.ur$onaro6es:irn)anaauo]$euN;i]rrreru,teH]uNr<norexca-2,5-rfier{I -urru4eu](eru:i)-(3-cyruQoiraro6ensun)aulr osnfi . Kylr accr.r6putnuavrosrifi cunui"rG. qaFlopourox reMr{o-Kopi{r{FieBoro c Suo;rercerrr\,{ 6recroMr4c BxpalJreHFibrMrl uBera
crllllaMr{, IrMeroulr{MIaMerailJlll.{ecKtlfi 6necr. Pacrnopnu B Bo.{era3TaHoJre. [Iomepn B ilacce npu sbrc.vuruBaHuu. 6onee 5,0 o/o.0,500r cytuar B cyuLrJIbHoM He ruxaSy rrpu reMneparypeor 100 ao 105 "C. ,,{',,, Eo,ree 500, B [epecqere Ha cyxoe BerrlecrBo. npoBonfiTnpu . Onpe4e,reHple pacreop e 6yQepnoMpacrBopepH 7,0. 577 uv, ucnonb3yr 0,001 %o Anr{HeBorrHbi (M.na. 695,6). Kyuaccir cpruuir,. KncnorHuft cnnnfi 92.C26HrcN3Na3O1653. Aria:oren-Harpnfi. Tpunarpax 8-ruapoxcu-4'-($eHarauuHo)asoua$ranuu-3,5',6rpucynrQoHar. Kpucrar.rrbrreMHo-craHefo rlBera. Mano pacrBoprrMB crir{pre 96 oA,pacrBopr4MB BoAe,B arleroHe r,rMoHosrHJroBoM :Qupe gTr4ireHrJrr,rKoJrr. Kncnornoro cnnero 92 pacrnop ne4rHofi, 0,5 r ruc;rorHoro crrHero92 pacrnoprlor B cMecr{10 u.rryxcycHofi KHcJIorbI ,45rr,rn cnr{pra 96 % u 45 wt BoAbI. (M.vr. 461,4). HaKuc,rorssrfi xpou .repxuft crerlr4arrbnufi. C20H12N3NaO7S. rprreBaflcom 1-[(1-rr4ApoKcr4-2-ua$run)aso]-5-Hurpo-2-na$ro::-4-cynrQoKr{cnorbr. 3puoxpol,r uepnrrfi T. llopourox qepHoro unn KopuqneBorouBera.

EIIII

B Torcuqen. PacrnopnuB cnr.rpre oA,ManopacrBopr.rMBoAe. 96 pH c KiurbB uHrepaa-ue 9,5-10,0uueer cuHroro oKpacKy, efo KoMnneKcbrrroHaMlr a qrdr,MarHrrfl, rrrrnKa Tex xe ycnoBrirrx xpacHo-Qr4oJreroBoro rrBera. u B r cnnefi. Ilepexo4oKpacKr{ rprMoM Tr{TpoBaHrrr,r npu or xpacHo-SrEoneroeofi u I'IndurcamopHan cMecb.0,25 r r{HArlKaropa 25 r narpu{ xnopr{Aapacrvpalor B cT'ynKe nepeMerrrr,rBaroT. r4 Pacmeop uudurcamapa. o/o 0,2 pacrnops 95 yo cnl4pre. Knc.rrorHrrfi xporvronrrfirerrtro-cunnil. Cu. Xpouosrrfi lelrHo-cunnfi. (M.u. 467,0).21-Xnop-9-$rop-1l!,l7K.no6era:orra nponuoHar. C2;H32CIFO5. -I,4-Lues-3,2}-guoy- 7-nponnonar. 1 i 6B-uerrrnnperHa Ar4rnApoKcuKpucrannuqecrufiropo[roK 6eroro rlBera. pacrBopt4M crrnpre96 o/o arleroHe. B 14 Hepacreopr4MBoAe, B o (n 4uoxcane). [a]') . Ororo +104 Teunepamypa nnarneHun. Oxono 196'C. Ko6amra Hrrrpar. Co(NO3)2' 6H2O.(M.r. 291,06).Ko6anrr (II) asornorucrufi arr{Ap ar. 6-noAnufi. Ko6a.rnr (II) a:orno xuetrstit,reKc B Eypo-xpacHbre KpvcrrurJrbr. firrpocxonuqeH.Oqesr nerKopacrBopuM BoAe. Ko6a.urra HHTparapacrnop 5 7o pacrBopaeoAofi Ao 5 r xo6anbraHr{rparapacrBopsrorB BoAer.rAoBoArr o6rerr.r 100rran. Ko6a.nrra xrroprrA.CoCl2 ' 6H2O.(M.vr. 231,93).Ko6anrr xropr{crbrfi6-norurufi. Ko6anrr xnopr4crhrfirexcarul4par. , rlBera. Kpncrarrz.{ecxufi iloporxoKKpacHoro reMHo-KpacHoro uBerar{nr{KpncraJrJrbr pacrBopr4M BoAe, pacrBopltM cnr{pre96 %. B B Oqesr JrerKo pacrnop 5 7o Kodarrra xd'roplrAa pacrBoprrcrB BoAe, npnnr.rBaror rvrt25 % xnopucroBoAo0,2 5 r xo6anrraxnopr.rAa po.quofi pacrBopa Krrcirorbr AoBoA-f,r r.r soAofiao 100un. o6lerra (M.u. KoHro rcpacusrfi. C32H2rN6Na2O6S2. 697,7). - 4 ,4 '- guur r 6uc - 2,2'- azo) 6 v c ( I - ar ru s o n a$r anuu- 4 a l u n a r p u fi ( 6 u S en u t cyrrQoHar). rlBera. floporuor Kopr4r{HeBaro-KpacHoro PacrnopuuB BoAe. Konro KpacHoro6ylrara florocxn $unrrponarssofi 6yuaru rorpyxaror HaHecKoJrbKo MrrHyrB pacrBopKoHro KpacHoro. Brrcymunaror. pacrBop Konro KpacHoro pacrBoprrorB cMecr{ prncnrrpra 96 % r.rBoAbr AoBoArr 20 14 0,1 r ronro KpacHoro o6rerupacrBopa noAofiao 100un. K I,Icnutmauue qyrcmrumenbHocmb. 100 MJrBoAbr, Ha cso6oAriofior yrnepola upu6annxtot0,2 Mn pacrBopaKoHfoKpacHoro 0,3 ur 0,1 M pau Ar{oKcr4Aa,
rr{ApOKCH.qa; no-f,Bnf,eT9fl. Cr{Hee KoTopoeIIepexocTBOpaHATpVTA OKparrrr4BaH}re, se 6oree 0,3 ur 0,1 M pacrBopa Harprfl Au'r B po3oBoe npu rpu6aBJreHurr rrrApoKcr{Aa. pH Ilepexo4 oKpacKH cusefi Ao po3oBofin unrepna.rre 3,0-5,0. or

(M.*. 132,1). Kopuunufi a,rrAernA.C9H8O. 3-OenurnponeHarrb.

MacJr.sHr.rcrar xnAKocrb or xenroBarofo Ao 3eJleHoBaro-xeJlTofo uBera.

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Mano pacrBopl{MB BoAe,orleHbJrerKopacrBopl'IMB crl{pre 96 % il e$upe.

dii . o, 1,048 1,051. lo

ft, . Oxono1,620. or 3alrruqeHHoM cBeraMecre. Xpauxr B npoxnaAHo\{, (M.*r. 180,15). (E)-3-(3,4-,{urngpoxcu$enun) CeH8O4. uar Krrcrlora. KoQefi Kr4croTa. lponrroHoBaq
[otITI4 6eloro uBera. 6enoro LUILI rIJIacTLIHKI{ Kpucrannbr ITJILI oA,yMepeHHo pacrBopl{MaB xonoAB Jlerro pacrBopr4Ma rop.f,trefisoAe H crnlpre 96 Hoft eoae. 'C c pa3Jro)KeHHeM. Orcoto 225 TeanepamypannanneHua. CeexenpuroroBJreHHsrfipacraop c pH 7 ,6 utvreet4Ba MaKcr{MWa nornouleHrrfl npvr sorfir 293 nu u 329 nu. AJrr{Hax Kpacnan KpoBflHafl co,'Ib. Cu. Kannx QeppnuvanfiA. n. Kpaxuan pacrBoprprstfi. (C6H10O5) (M.u. 162,14)n. lloporuor 6eroro UJII cnerKa KpeMoBaroroIIBera. B flpaxru.recKr{ HepacrBopr.{M crrrrpre 96 o , pacrBoplrM n xnnqulefi BoAec o6pasocnefKa ollanecqupyroulefo pacTBopa,He 3acTblBalolllero [po3patrHoro rrJrr4 BaHUeM npn oxnaxAeHr4lr. pacrBoprrMofocMeIIruBarcT 5 Iul BoAbIAo [Ioc I Pacmeop uudurcamopa. r KpaxMana rlptl nocrof,HHoMpa3BJIHBaIoT ranuqbr H cMecb MeAneHHo nyrreHr4q oAHopoAHofr Ao e Merrrr4BaHlru 100 trl xunsulefi BoAbr.Knnqrsr B TeqeHI{e2 ry'ulg^ nonyr{eHlr x{I4AKocrH. cnerKa olanecq[pyroureft Cpox roAHocrrr pacrBopa - 3 cyr. I{3 flpunevauue.lTpu npr{roroBneHvtrpacrBopa LIHAr{Karopa Kapro$elruoro KpaxHarpeBbrrrre o6pasou, AoIroJIHLITenbHo xneiicrep, [onyqeHHufr yxaaaHHbrM MaJra q. npn I20'C s reqenlle I Baror B aBroKnaBe frodxpaxsre.TbHar1yuaza. O6essoreHuue 6yrvraxHble Sunrrpu nporl{TblBa}or paHa rIoMeIrIeHHI{ Bo3Ayxe, froAuAou r{ cylxar B TeMHoM crBopoM KpaxManac :rtarrprfl. napoB KHcJror.Eyrrrary pa3pe3arorHa rIoJIocKI,I IJILIHofi orolo He coAepxcaxleM oxo;ro 6 vru. florocra fio4rpaxtralrHofi 6yvraru He AonxHa ror50 lrrvr14Lrrrrpkruofi qac cr4Herbrrpn cMar{HBaHuvr 1 rannefi 0,1 M pacrBopa xnopl{crosoAopoAHoi ee
KI,ICJIOTbI.
20

creKJIa c nplrreprofi npo6frogrpaxuanbHyro 6prary xpaHrr s 6ariKaxopaH)KeBofo rofi s 3aruuueHHoMor cBera Mecre. Kpaxua,ra pacrBop 0rl o pacrBopnMoro pacrrrparor B noporxor c 5 MJIBoAbI,ronyqeHHylo 0,1 r xpaxMaJra s BJIITBaIoT 100 ul xunsulefi rrpi{ flocroflHHoM nepeMerrruBaHvrur cMecb MeAneHHo pryru(Il) fioauaa. BoAbI,co.{epxaqefi 10 rnrr peaKTrrBa raxIufi pa3 [poBoAtr IrclbITaHVeHa rryBcrBurenbflpu ucnoJrb3oBaHuu
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pacrBopaKpaxMiula, Crtecl, cocrotlqat us I N,Ir I.Icnumanue He qyscmsumerybHocmb. oKono 50 rrlr Karrr4fliloln!,au 0,05 un 0,005 M pacrnopairoga, Aon]r(Ha 20 vrn Bo.ubr, oKpalII{BaHI{e. LIMeTb Cr,rHee pacrBop 0r5 o/o Kpaxrvra.na xonoAHofi c I r rpaxuana pacrBopr{Moro cMerrrr{Barot se6orblutrM Konl{qecrBona EIIEI

BoAbr.flonyueHHyro cMecb npu6annrror K 200 vr:r xunquefi Bo.qbl,upu6an,raror oxJra}K,4aror. B 3 250 vrr cannrlunoBofirucrorbr, KHIIxT{T TerreHr{e unH u HeMeAneHHo pacrBopa npn reMneparype or Cpox foAHocrrr - or 2 Ao 3 neAenb npr{ xpaHeHrrr{

4 ao 10"C.
Csexufi pacrBop KpaxManaforoBrr B ToM cryr{ae, Kofla B ToqKe3KBIlBaJIeHTHocrI{ or nepexoAoKpacKr.r cznefi x 6eclleernofi irepesxufi. npu6auxror K Irlcnwmauue Ha uyncmgume.irbHocmb.2 un 0,5 o pacrBopa KpaxMana 20 vn BoAbr,oKoJro nar Karvriroaul.a u 0,05 v:r 0,005 M pacrnopafi.o\a; nony50 .{eHuHii pacrBop Aon}I{eH oKpauuBaHl{e. I4MerbcLIHee oh, coAeplr(auufa 0r2 7o cy.rrrQanrunosofi KrrcJrorbt Kpaxrra,ra pacrBop 0rS c 1 r xpaxtrana pacrBopr{MorocMerxr{Baror 10 MJrBo.{brAo [onyqeHuq oAHopoAnofi rrpvr nocTotHHoM pa3MeurvBaH[Ll B Kallrurlbr u cMecb MeAneHHo B,rII4BaroT 200 un rzn.f,rleii BoAbr. flo6ann*or 400lrr cynr$aNrnriosofiKrrcnorblI{ npoAonxaror 2 KunrqeHr4e eue B Ter{eHr4e wutt. Pacrnop AonxeH 6rrrr cBexeilpI4foroBJIeHHbIM. pacrBop, cno6o4Hufi or fioAnAon Kpaxvrara o pacrBopa KpaxMaJIa, 6es pryrn(Il) fiorio forossr pacrBop, KaKyKa3aHo An-r 0,1
AIjNA.

nepeA [cnoJrb3oBaHrreM. forosqr HerrocpeAcrBeHHo Kpaxnrara pacrBop c KaJrHflfioAngou Har-peBaror KI{neHLIxunpu6aitorurapacrBop-srcr e 100 MJrBoAbr, 0,75 r Karrvrs. ro pacrBop 0,5 r rpaxMaJlapacrBoprlMoro B 35 nn BoAbI. Brqlor rrpn [epeMeilruBa:an*r 2 Knu.f,rsr B TeqeHI4e wu*t lr oxJIDKAaFor. qylcmrumerbHocmb.Cuecr, cocroflrrras. 15 na:r pacrBopa Kpaxuz Ha tr4cnutmauue fioAuAorvr, 0,05 un yxcycHofi KrrcJrorbl reA.fiHofi n 0,3 nar 0,0005 IvI paMaJra :rzurprr c crBopa fr.oga, .qoirxHal4Merbcl{HeeoKpalxrrBaHrre. Kpeso.u.C7H8O.(M.*. 108, 1). o-Kpeaol. 2-Meru;r$eHorl.4-Ororronyor. CueHa xr4AKocrb,TeMHelorqat cBery L{Bo3Ayxe. Kpucrallu unu nepeoxna)KreHHar pacrBopl{M flpuMepno e 50 qacrtx BoAbIv paH rrrrrBaercr c sTaHoJrorr oQupoM,
cTBOpax f IIApoKoI4AOB IqenOqHbIX MeTaJIJIOB.

d,., . Oxono1,05. n - ). O , I , 5 4 0 l o 1 , 5 5 0 . , KuneHufl. Oro:ro 190'C. Teunepamypa He Teunepamypa sameepdeBaHun. suxe 30,5'C. 0,I He nocre 6unapu6auua. 6o:ree o (u/u). Burapnnalor Ha eoA.f,riofi Ocmamorc or 6aHe, cyrrar rrpr{reMrreparype 100ao 105"C. KucnopoAa Bralz Mecre,nepeAlrcnorlbv or Xpauxr B 3aurHrIeHHoM eosAeiicrBuq
3OBaHLIeM nepefoHqror.

Kpero.nonrtfi rcpaurrrfi . C2l H r aOsS. (M. r'r. 382,41). 4,4' -(3H-2,|-EeHsorcarlrorlo-Kpeso.rrcynrQoQrilIeuH. 3-n.nu4eu) 6uc(2-rurenEn$enon)-S,S-Auoxclr4. Kpucrarru.recxufi noporxoK KpacHoBaro-KopuqHeBoro uBera. pa3BeAeHHbIX pacrBopax rI4B Ma,ro pacrBopr4M BoAe,pacrBopnM B cnr4pre96 % 14 MeraJInOB. UIenOqHbIX .4poKcHAOB Kpero.nonoro r(pacHoro pacrBop 0rl "h 0,1 r xpe:onoBoro KpacHoropacrBopslor B cMecr{2,65 ru 0,1 M pacrBopaHarprrr.rno u ApoKcr4Aa 20 rvn crr{pra 96 , AoBoAtr o6reu pacrBopa eoAofi ao 100 tr.n. @

tr{cnatmauue uyncmsumenbHocmb. MJr Ha K 100 BoAbr, cso6oAHofi yrnepoAa or Ar{oKcvr\ npu6an:rxror ur pacrBopa 0,1 Kpe3onoBoro KpacHoro 0,15 vrn 0,02 M pan
cTBOpa HATpprA TLIApOKCHAa; nOrBJUreTCr nyplypHo-KpaoHoe OKparrrHBaHr.re, KoTopoe nepeiru B xelrroe nprEnpu6aBJreHr4r4 6onee 0,15 lrn 0,02 M pacrBopa ue IonxHo xnoplrcroBo4opogHofiKucnorhr. tr4gueueHne oKpacKuo:r xenrofi Ao KpacHofin uHrepnanepH 7,0-8,6. Kperononoro KpacHoro pacrBop 0104oh pacrBoprrcr n 13,1 un 0,02 M pacrnopaHarprrr ruApoKcr,rAau 0,1 r uH.uuKaropa AoBoAtr o6reu pacrBopa cBexelpoKr4rrrqeHHofi oxnaxAeHHofieoAofi ao 250 rrln. u flepexog oKpacKI4 pacrBopa or KpacHofix xenrofi n nnrepua,repH 0,2-1,8 pror )KeJrrofi r nypnypHo-rpacuofiB rrHrepBalepH 7,2-8,8. Kpero.nonoro Kpacnoro crrrprosrrfi pacrBop 0rl o/o 0,1 r xpe:orroBofo KpacHoropacrBopruor s 50 MJrcrrr.rpra % u .qoBoArro6rerr,r pa96 crBopa eoAofi ao 100 rran. Kpe:oronufi rcpacHufi no4opacrBoprrMsrfi C 1 . S. 2H21NO5 (M.r 399,46). Alrrr,rouui,*tax conb o-Kpeao,rcynr$oSraleuHa. floporuox KpacHo-KopuqHeBoro rlBera. Pacrnopuu B BoAe. flepexog oKpacKr4 pacrBopa or KpacHofir xerrofi B r4HTepBa;le 0,2-I,8 rr or xeJrpH rofi x ryprypHo-xpacuofi B r4HrepBale 7,2-8,8. pH o/opaxnop. Pacmeop ttudurcamop 0,04 a. Kpero.nonrrfi nypnypnsrfi. C21H18O5S. (M.r'r. 382,4I). .rz-Kpeso,rcynrSoHa$ra:reuu. Kpucrarllr.{ecxufi nopotuoK oJrnBKoBo-3eneHoro uBera. Malo pacrBopuM B BoAe,pacrBopuM B crrupre 96 o , yxcycnofi KucJrore;reA.sHofi n MeTaHOne. Kpe:o,ronoro nyprypHoro pacrBop 0,1 " 0,1 r"rz-rpe3onoBoronypnypHoro pacrBop*or B 13 rral0,01 M pacrBopa laarprrflrtro6reu pacrBopa eo,uofiao 100 Mn r{ nepeMeur.rBarcr. .[poKcr{Aa, AoBoA.rrr flepexog oKpacKI4 KpacHoi 4o xemofi e HHrepBane pH 1,2-2,8 rr or )KeJrrofiIo or Snoreroaofi e nurepna,repH 7,4-9,0. Kpero.uonufi nypnypnufi pacrBop 0,04 oh 0,1 r unruKaropa pacrBopmor n 13,1 u.rr0,02 M pacrnopa:aarpzrflrr4ApoKcraAav roBoAtr o6reu pacrBopa cBe)KerrpoKr.rilrqeHHofi u oxlaxAeuHofi solofi ao 250 u,r. llepexoa oKpacKH po3oBo-xpacnofix xe;rrofi B HHrepBane pH 1,2-2,8 u or xeJror rofi r Slroreronofi n uHrepnanepH 7,4-9,0. Kpero.nonufi nypnypHrrfi cnnproBbrfi paclnop 0,1 o/a 0,1 r,,r.r-rpe3oJloBoro rryprypHoro pacrBoprror B 50 nr cnrrpra 96 oh u AoBo.qrro6renr pacrBopa no.uofiao 100 lr-rr. Kperononsrfi uypnypHufi BoAopacrnopHnrufi . C21H2 1NO5S. (M.na 399,46). Aw. Nronrfinaq conb "4,r-Kpesoncynr$o$raneuna. MerrorpucraJrJrr4qe crufi nopouroK KpacHo-Kopr{r{HeBoro K-opr4qHeBoro vrr4 uBera. flepexo4 oKpacKlrpacrBopa or po3oBo-rpacuoli r xe.irroft B r{HrepBa.ue 1,2-2,8 n pH or xenrofi x Qnoleroeofi n r{HTepBaJre pH7,4-9,0. o/opannop. Pacmeop uudurcamopa. 0,04

20.3ax.2769

gE

HaSiWnOqo' xH2O. Klrcd'Iora. KpennenonrQparvroBar Ha xenroraro-6enofo rrBera,pacrlJlblBaroul4ec-f,Bo3Ayxe. Kpucralllr 6eloro r{Jrr.r B Ir Oqesr nerKopacrBopnMa BoAe crll4pre96 %. rourefi XpaHarB Bo3AyxoHerlpoHrrlraeMoM uepe. rcucrorbl pacrnop 1 7o KpenrHeno,rrQpanrosofi 14 B xucrorbr pacrBop.sror BoAe AoBoAtro6teu pacrBopa 1 r xpeuHeeonr$pauosofi 100 soaofi.uo lan. 40 Kp ncra"u"rr nqecrcnfiQuoneronrrfi . C25H30ClN3.(M. r"r. 8,0). fercalterunrapapoXnOplIA. 3AHI"j.TTId}IA

IIBera. noporlroK TeMHo-3e,TeHoro Kpncrarrbr Lrrrkr Pacreopulr B BoAeIr cnr{pre 96 %. Kpncra,r,ruqecKoro Qlro,reronot:opacrBop 0r5 7o 0,5 r rpracraJrJruqecKoro $uo:reroBofo pacrBoptror B yKcycHoit xrtc;rore 5esso.{F{oia u .{oBo4qr o6reu pacrBopa reM x{e pacrBopr{reneM"qo 100 rl"rr. yrcycnofi 6e:eoAlroli npn6aK I,IcnwmauueHa qyncmsun'rctbHocmb. 50 run Kr4cJTorbI Brr.flIor 0,1 Ht:ipacrBopa KprrcrannvqecKoroQuoreronofo; rloflBnf,ercxroly6oBaror{oropoe ilepexoAHT n roriy6oBaro-3eneHoeIipI{ Quoleroeoe oKparrrr4BaHr{e, npn6aereHnwA,1 ur 0,1 M pacrnopaxnopHofrxtlc:rornt" Kpncra,rnllqecKoro Qno;reronolo pacrBop 0rl a/o.4,1r uuAlrxaropapacrBoptlor xe o6renapacrBopa3TrrM pacrBopr{Tene}I H Jrer-{Hoii "4oBoA.f,T rlo n yNcycuoii Kr.{cJrore

100 u;r.

rnrpoBanr4rror Quo:ierosofi (irlerovuar) qepe3 npn HeBoAHoM flepexo4 oKpacKi.I (rncnaa). (ueiirpa.nruar) K 3eJleF{oBaro-)KeJlroii cr4He-3eJreHyro KcaHrruApo,r. C 13H1602.(M.u. 198,2). 9-KcaHreuo:r. 9-OxcI{KcaHreF{. 90,0 o/aCl3Ht0O?. Co4epxrar He MeHee flopourox or 6enoro Ao cBerno-)Kenrofo{Bera. pacrBopr.rM BoAe,pacrBopuM B crrrrpre 96 oA,oQirpe H yKcycHoli xl.tcB OqeHr MaJro rore reA.sHoii. B or /{ocryneH raKx{e B Bure pacrBopa, conep)Kanrero 90 ao 110 r/:r KCaHrrI4Apo"iIa
METAHOJIE.

Oxo:ro I23 "C. Te.unepamypan.ira6./reHtz.s. or XpaHxr B 3arrluiqeHnor\{ cBera Mecre. Ecnn rrc[onb3yForMeraHontsrri.rpacrBop, To xpaHrr n He6onnnrnx repMerxr{Ho 3aKpbirbrx aN{nynaxv ilpv Heo6xo.uuntocrn rrepeAr4crronb3oBaHr4eM $u:rsrpyiot. Kc anrrHApo.n oco6ofi qucrorr'r I{ KcaHTrHApoJ]a cneAyrcuee .donorHl4Tenbrpe6oeanvfl nrrfl. [o.rrxeH Bbr.ilep)KrrBart uoe rpe6oBaHi{e. C13H10O2. Co4epxur He MeHee98,0 o/o onrrfi p eaKTItB Kc anrruApo,'r a p acrBop. KcasrruAp o.ir K 100 Mn yKcycnofi nuc:rortr 6essoAHofinpu6aurrlor 0,1 tr,tr l0 oApacrBopaKcaHrli KoHlIeHTpl{ponauuofr rr{Apona B MeraHone, I ul xnoprrcroBolopo.qnofr KrrcJrorbl 24'r. BbrreplxnBarct (M.u. 760,6). Terpauarpuit 3,3'Kcu,renonrrfi opaHxenstfi. C:rHzs N2NaaO13S. (3H-2,1-6ensoxcaruan-3-u.ruraeH)6lrc[(6-rrEapoxcn-5-uerur-3,1-SenuneH)treru.rreHrrMr{Ho6uc-ailerarlS-lnorcua. S,

hpucrannnrrecKufi rroporxoKKpacHoBaro-Kopr4qHeBaroro rlBera. Pacrnop'r,r B BoAe,flpaKTLrr{ecKx HepacrBopr'M clapre 96 %u esnpe. B B uHrepnanepH 5,0-6,0 KcnneHoJlonrtfiopanxeerrfi oKparxeHB nuMoHgo-xe:rgrfi uBer. a ero KoMnJIeKC t'lOHOM C BIrCMyraB Tex )KeycJroBlrrx KpacHororlBera. B qe'-Ior{Hblx pacrBopax I'rH.qlrKarop }IMeer Suolerono-KpacHy}o oKpacKy. flepexog oKpacKH npl4 np.sMoM KOMrIJIeKCOHOMerpkrirecKoM TtrrpoBaHr4r4OT XpaCUOfi B .THMOHHO-Xenryro. Kc n,reHo.noBoroop aHlr(eBororrHAr.rKaropHafl ecb cM Pacruparor B nopouox 1 qacrr KcnneHoJroBoro opaHxeBoroc 99 \aqsMr4 KsJrr,rr Hr.rrpaTa IdJrvHaTpuflxnopula. tr4cnatmauue qyncmnumenbHocmb. 50 un BoAbr Ha K npu6annxror 1 u,r yrcycuofr rzc-lorhl pzBBereHHoit12 oh, 50 Mr lrHrlrKaropnofi cMecv KcrrJreHonoBoro opaHx{eBoro rr 0,05 n'rr3,3 %opacrnopa cnuHqa(Il) nurpara. flpn6annrror feKcaMerr.rneHrerpaMr.rH -lo Tex nop, tloKa oKpacKa pacTBopa H3MeHrITctoT xenrofi 4o He SuoneroBo-Kpacuoii; nocle npz6anneuux 0,1 ul 0,1 M pacrnopa Harprr-rr 3Aerara oKpacKa pacrBopa ]onxHa II3MeHUTbCT )KenTyro. Ha Kcu,reno.noBoro opaHxeBoro pacrBop 0.1 % pacrBop. rlepexo4 oKpacr(r4 <<Kcu"'eHoerrfi cu. opanxeerrfr>>. - 14 cyr. Cpox roAHocru Kcn.rosa.CsHt0O5.(M.r"r.150,l3). D-rcunoga, Kpucran,ru'recxafi nopouroK6e;roro uBera z.rru6ecueerHbre uronbqarbreKpr4crannbr. nerKo pacrBopnMaB BoAe,pacrBopr{MaB rop.sqeMcnr4pre96 %. 9":#" lql, . oxoro +20" (10 o/opacrnopqepe3 l0 q nocre ero npuroror.rreuur). Kcnnon. csHto. (M.r"r.106,16).[uwerun6eH3on. cnecr o-, M- r4 r?-Kcr4nonoB. flpo:pa.lHax, 6ecqnernas,, BocnnaMeH flror\aflcfl xrrnKo crb. flpa*uuecKr.r HepacrBoprrM BoAe,cMerraBaerc.s crrr4proM B co 96 % n a$Hpov. r/' . Orcoro0.857. lr., . Oxono 1,497 , Te.vnepamypa KuneHufl. Oxoro 138 "C. o-Kcn.no.n. CsH r o. (M. rrr.106, I 6). 1,2-fim,rerrlr6eHeor. rlpospavnar, 6ecqner*ae,) BocnJraMeHrloruarcr x{HAKocrb. flpaxrnvecKr.rHepacrBopuMB BoAe,cMerrrvBaercrco cnr{proM 96 % u e$upou. d,., . Orono 0.881.

i r u. g * o n o 1 , 5 0 5 .
Te.vnepamype KuneHufl. Orono I44'C. -25'C. TeanepamypnnarreHun.Orcono a .y-Kcn.no.n. ro. (M.r"r.I 06,I 6). 1,3 -flraruerlrn6ensor. CsH flpo:pauuax,6ecqne rHax BocnnaMeHqrorlaflinuAKocrb c, ) flparr_zuecKr.r HepacrBopt4M B BoAe, cMerrruBaercr cilrrproM96 %u e$rEpolr. co d,, . Orolo 0.884. r?" . oxono 1.497. Teanepamypa KuneHltfl. Oxolo 139.C. Teunepamype mazreHua. Oxoto Mr,rHyc 47"C.
20

Kyuaccn cnHufi. Cu. KHc.norHrrfi cuttutrr92. Kymaccn crrHeropacrBop. Cnr.Kucnornoro cnHero 92 pacrnop. (M.ru. 368,37). I,7-Euc(4-rnApoKcrr-3-nteroxor$eirun)-renraKyprcynrun. C"1H2sOo. 1,6-Auen-3,5-AraoH. ilopoilroK opaHxeBo-Kopl4qHeBoro Kprecran.nfi.recxufi uBera. B B flparrlruecKr4 HepacrBopt4M Bore, pacrBopr,rM yKcycHofirHc,rore leA.suofr,trpaKn THqecKuHepacrBoparra :$npe. TeunepamypanrazreHun. Or<ono183'C. oKpalxenaB tpKo-xelrriff 6urr paBHoMepHo Kyprcyuonan 6ytrara. EyvraraAox)KHa uBeT. pH Ilepexol oKpacKpr 6y"*laruor xelroii r 6ypo-rcpacsoiiB l4HrepBa-qe 7,4-9,2 u ot pH 6ypo-rpacuofi x opaHxeBo-xerirofiB I4HrepBane 10,2-11,8. - 2 rola. Cpor foAHocrr,r (M.u. 154,24).2-tr4sonponesur-5-rraeriurrerc-4-es-1-on. C1sH1gO. JIasaHAoiro.n. 3anaxoM. c MacrssrEcrar )Kr.rAKocrb xapaKTepHbIM d,i . Orcoto0.875.

lxo . arcono 1,407.

B r4cnonb3yeMoro ragoeoft xpoMaroXpouarorpa$uuecrar qucrora naBaHAoJroJra, o . rpaQuu, AonxHa 6rrrr He MeHee98,0 (M.r'r. 196,28).2-llsouponesul-5-uerulrerc-4JlananAo.norra arlerar. C12H26Oz. eu-1-ur auerar. 3anaxoM. c EecqeerHar )KrrAKocrb xapaKTepHbIM

20

10,2"C. tal') . Ororo MIrHyc

dii . O*ono 0,911. ni;'.O*ono1,454.

I4cnoJIb 3yeMoron ra:onofi xpo arleTaTa, Xporraarorpa$uuecxar qucToTanaBaHAonona 6urr He MeHee93,0 oh. rr.rarorpa$urr, AoJDKHa Al,ruonuftHat corlb JlarcuouA. Cl2HgNO:. (M.rtl. 2I5,21). Pesopuunossrfi cuttuir,. -oHa. 7-rz4porcu-3H-SeHorcasuH-3 lloporuor qepHoro uBera. PacrnopurrrB BoAe,crrupre 96 oh, alleroHe, yrcycnoft Kl4cnoreleAsuoft. pH Ilepexo,uoKpacKupacrBopa or KpacHofix cnsefi B I4HrepBa-re 4,4-6,2. o/opaunop B crrrpre 96 %. PacrropeHre rpoBo.U-f,r npLI Pacmeop uuduxamopa. 0,2 Ha HarpeBaHrrr{ BoArHofi 6ane. JlarcnrouAHan6yuara clrHrfi B oKpameHa cepo-rony6ofi IIBer. Byrr,rara 6rrrr paBHoMepHo Aon)KHa 1yuaru or 6re,qso-Suo.nerosofix cepo-roJly6ofi s LlHrepBane flepexog oKpacKr4

pH 4,0-6,4.
-2rota. CpoxroAHocrLI JIarcrvryc (Dparlreuru cuue-SuoJreroBororlBera, [onyqeHHbre LI3pa3nI,Ir{HbIX BI{AoBRocella, L ecan o r a vnv [pytr4x nuurafi HI,IKoB. HepacrBopuMB crll4pre 96 %. Pacrnopuv B BoAe,[paKTIlqecKL.I Ilepexo4 oKpacKr.r KpacHofiAo cusefi r uutepnane pH 5,0-8,0. or @

Jarclryconar 6yrvraracuHqq 10 qacrei rpy6o Ll3MenbrreHHoro JraKMyca:xurrfl-tsrco 100 qacr{Mr.rcnr{pra 96 o/a s rer{eHueI v. Cnupr AeKaHTprpyro! ocraTKy npu6auxroT cMecbuz A!.{acrefi 96 % K cnnpra r 55 .racrefi no.qu. 9epes 2 gun ilpo3parrHyro lternKocrb AeKaHTr.rpyror, rponr4TbrBaror noJrocKlrSansrponalrsofi 6yvraru r4cyuar. tr'IcnumauueHa qyncmsumeitbHocmb.Ilo.lrocxy Su:nrponalssoi 6yuarra pa3MepoM 10 x 60 NIMnorpyxaror B cMecb 10 u.rr0,02 M pacrBopa xnopncroBolopo4Hofi rncnorbl n 90 u:i BoAbI. flpu ncrpxxvtBanvrrl6yuaraAoirxHa npno6pecu4 KpacHoeoKpairII4BaHIre re.{eHue45 c. s "Tlaxlryconan 6yuara KpacHaq K cuuerraysKcrpaKTynaKMyca rtpn6aenxtor rro KanJrstt 7,3 oh paunop xJroprrcroBo.UopognofrKlrcJlorbl Io nepexoga cuueir oKpacKr.r KpacHyro.flo.rrocrr QlrirrrpoB earsHofi 6yuaru [ponr4TbrBaror [onyqeHHbrMpacrBopoMr.{cyrxar. tr4cnum auue Ha uyscmsumenbHo cmb. Iorocry $unrrponanrHofi 6yvaru pa3MepoM i0 x 60 MMnorpyx(aror B cMecb 10 u.rr0,02 M pacrBopa Huparflrr{ApoKcr{Aa 90 un u BoAbI.fIpH ncrpxxvlBanvrr 6yrraara npuo6pecu4 crrHeeoKparuilBaHneB TeqeAonxHa :e.ue c. 45 JlarcrodnonoBas Kncrrora. C nH22O D. (M.rut. 5 8,30). 3 Kplrcralluqecrnfi noporxoK 6eloro uBera. rlerxo pacrBopuMaB BoAe,lpaKrr,rirecKia HepacrBopnMa crrrrpre 96 %. B TeanepamypanrarneHua. Oxono 115 "C. jlanraHa(Ill) nnrpar. La(NO3)'6H2O. (M.rur.433,0).Jlas:rasarpr4Hr4rpar feKcarrrApaT. Fecqnerurre KprrcranJrbr, pacnJrbrRarorlue Ha Bo3ryxe. cs. ,IlerHopacrBopuM B BoAe. XpaHar B Bo3AyxorierpoHhrlaeMoM xourefiuepe. Jlaurana(Ill) unrpara pacrBop 5 oh. Pacrnop 50 r/n. JIanraHa(III) orccua LbO3. (M.r. 325"80).Jlaurasa rprroKcru. . AuopQnrrfi nopouroK rloqrr 6erioro uBera. llououaer yrnepo.uaAr4oKcrrA Bo3H3 Ayxa. llparruuecKr HepacrBopl{MB BoAe,pacrBopr4M pa3BeAeHHbrx B M}rHepanbubrx KHcnoTax. Kanw4ui. He 6onee 5 ppm. IaHraHa(III) x,ropn.qapacrBop K 58,65 r JIaHraHa(III)oxcuaa MeAneHHo npu6ar.n-sror100 Mn xnopr4crono4opo4Hori Kr.rcnorbrKoHrleHTpraponaHHofi, HafpeBalor Ao KHneHnr, oxJraxAaror H AoBoArr pacrBopano4ofi ao 1000,0un. o6reu Jlaypnronrrfi cnupr. C nH26O. (M. r'r. 186,33). 1-tro.uexauo-ti.

dll . Onono0,820. Teunepamypa KuneHun. 24 ro 27 oC. Or ,TuuoneH. CroHro. (M.r'r. 136,23). D-Jlimoses. (+)-r-Meura-1,8-ArreH" (R)-4-?I:onponeHr{Jr1-lreru-rrqvxlorexc--eH. I EecueerHar )Kr{Arocrb. IlpaxruuecKuHepacrBopr{MBo.{e, B pacrBopr4Nr B cnr.rpre %. 96 dr, . Oxono0,84. -@

1 n : . a r 1 , 4 7 A o1 , 4 7 4 .
-

lul, . Or +96 4e +106"

Teunepamypa KuneHufl. 175 to I77 "C. Or qncrora Jrr4MoHeHa, vcloJrb3yeMoro s ragosofi xpoMarorpaXponrarorpa$rEuecrax oh. Quu, 4o.nxHa6rrrr He MeHee99,0 JlnnroHHaflKrrcJ'rora. C6H3Ot 'HzO.(M.r"r. 210,I4).2-Oxcunpouas-1,2,3-rpurcap6ouonaxKr4cJrora, MoHorr{Apar. ranu 6enrrfi rpucrannuqecxufi nopolxoK. EecqeeruHe, lpo3par{Hbre Kpr{craJrJrbr paOqesr JrerKopacrBoprrMaB BoAe,nerKo pacrBopr{MaB cnnpre 96 oh, yMepeHHo crBopnMan e$npe. flpn ucnoJlb3oBaHr4r.I B r.rcrrbrraHvwr xeJle3o JIHMoHHat Ha KIrcJIoraAonlKHaBbIAeprrbrraH e. xlrBarb cJreAyroqeeAononHI4TeJI e r4c bHo 14 pacrBopflror s 10 MJrBoAbr, upn6annnor 0,1 ur rl4orJrr{Ko0,5 r ruuoHsofi Kr.rcnorbr KoHrIeHTpr{poBaHnpz6aurrcT pacrBop aMMrraKa resofi Kr4cJrorbr, nepeMerxuBaror, srrfi .qo urenoquofi pearqu[ r.rAoBoAqr o6reN{ ronyqeHHoro pacrBopa eo4ofi 4o B 20 wl Pacrnop He ronxeH oKpaurr{Barbcr po:onufi qner. Jlnrronnafl KucJrora dessoAHar.C6HsOz.(M.u. 192,13).2-Oxcunpor'au-1.,2.3:rpurap6onoBar Kr4cJrora. Benrrfi Kpr{crannu.recr[fi [opoilroK, 6ecqnerurre Kpr{cranrrbr vrrv rpaHynbl. paB O.{eHr nerKo pacrBopr.rMa BoAe,JrerKopacrBoprrMaB crurpre 96 yo, yMepeHHo crBopr.rMa aQupe. n flnaeirrcs oKono 153'C c pa3nox{eHr{eM. Jlnprounofi rcuc.noru pacrBop OrLM BoAbr 19,210 r JrnMoHHofi xuc;roru 6eseoAHoitpacrnopxror B AocraroqHo Konr4lrecrBe pacrBopa soAofi lo 1000,0 un. upaz6aylqrcr o6reN,{

-20

(M.r"r.196,28). (RS)-1,5-Auruerlrn-1-szHr4merc-4arlerar. C2H20O2. "llnHa,rn,ra

eHr{JI a[eTaT. EecqserHafl rl[rv cJrerKa ]KeJrrar xr,IAKocrb c cIrJrbHbIM 3arlaxoM 6epraruora v raBaHAbr.

d , . Or 0 ,8 9 5 0 ,9 1 2 . ro
lto . Or 1,448Ao 1,45I . TettnepamypaKuneHun Ororo 2I5'C. flonb3yeMoro B raso noit xpo Xpolrarorp aQuve crax rrrlcrora rwtnanvna ar\erar a, r4c laarorpa$uv, AoJr)KHa 6urr He MeHee95,0 yo. -3-on. Jlnna.nor. C10HI80. (M.r"r.|54,24). (RS)-3,7-Ar4Merr.rJroKra-l,6-rues u C rue n AByx crep eor.r3oMep (nnxapeo nra Kopvan4pona). c on B n XuArocrr. flparru.recKu HepacrBopr4M BoAe,pacrBopr.rM e@upe. d,i . Oxoto 0,860.
20

/1, . Oxono1.462. Te*tnepamypq KuneHun Ororo 200'C. irrrcrora JruHaJrona, ucloJrb3yeMofo ragosofixpoMarorpae Xporraarorpa$uvecrar o/o. 96,0 Suu, 4onxna 6urr HeMeHee

20

-ilurnfi. Li. (A.u. 6,941). Mqrrvfi MeriurJl,Ha cBelKeM cpe3e cepe6plrcro-ceporo rlBera, ilprr KoHTaKTe Bo3c AyxoM 6rtcrpo craHoBl4rct rycKnbrM.Eypno pearvpyer c nogofi c o6pa3oBaHr.reM BopacTBopanuTkrfl, r..r fr4ApoKcuAa. AOpOAa Pacrropnu B MeraHone c o6pasoBaHr4eM BoAopoAa14pacrBopa rwrvtfl MeroKcrrAa; rpaKTr4rrecKrr HepacrBoprrM eSupe u rrerponefiuorr.r n e$rape. Xpaurr noA nerponefinuu e$upou rrJrrr xrrAKuu napaSuuolr. Jlrrufl rrrAporccrra. LioH'Hzo.(M.*. 41,96).IrurttsruApoKckrA, MoHorr4Apar. lpaHynl4poBaHuufi uoporuox 6e.noro rlBera. flsrsetcs cprnurofi ilIeJroqbro,6ucrpo nornorqaer BoAy rr yrJrepoAaArroKcr{A. PacrnopunrB BoAe,yMepeHHo pacrBopr4M cflr4pre96 %. B Xpanxr B Bo3AyxoHelpoHrrrlaeMoM roHrefinepe. "llnrns rcap6onar. Li2 C 03 .(M. u. 7 3,89). luturun xap6onar. Jlerrufi nopoilroK 6eloro rlBera pacrBopl{MB BoAe,oqeHbMaJro YnaepeuHo pacrBopr4M cnr,rpre96%. Hacrrqenuufi B pacrBop npr{ reMneparype 20 "C coAepx}rr oKorro13 rlr' Li2CO3. nrus mera6op ar 6e:nognuf . LiB O2. (M. rur. 49,75). IIuruf 6opnorucluf . Eerue TprlKnrrHt4qecKrre KplrcTannbr. Mano pacrBopr.rM xoJroAHofi B pacrBoprrMn ropauefi BoAe. no4e, JrerKo 'C. Te.wnepamypa ruazneHuz Oxono 840 128,0).luturux cynn$ar, MoHorlrApar. "llnrrq cy.nrQar. Li2SO4.HzO. (M.rur. Fecqnenrue KpucraJrJrbr 6e.uufi Kp[crannr4qecxufi noporuoK. rrJrrr Ierro pacrBopr{MB BoAe,rpaKTr{qecKr4 HepacrBopr4M cnupre 96 %. B Jurrq xrropnA. LiCl. (M.r"r.42,39). Kpucrannu\ecruit iloporroK r4Jrr4 rpaHynbr, vtrrwry6lruccxr,re KprrcraJrJrhr; pacrrnhrBaercr Ha Bo3Ayxe. ,Ilerro pacrBopnM B BoAe,pacrBopr.rMB arleroHe H crnrpre 96 %. Bo4urre pacrBopbr riMeror HefrrpalrHyro urfir cna6o ilIeJroqHyropeaKuvro. Xpana:r B Bo3AyxoHenpoHr4rlaeMoM xonrefinepc. Jrcronq pacrBop 1 r fioAa u 2 r xastus itoltu4a pacrBoprrct s 17 MJrBoAbr,xopomo nepeMerrruBalor. MarHeuaJrbHafl cMecb 5 r uaruur xnoprrAa n 7 r aMMoHrrrxnoprrAa pacrBop*or B BoAe, npu6auaror 35 un l0 o/opacrBopa aMMI{aKauBoAbIAo 100 nan.OrcrarrBaror B reqeHr{e3-5 cyr u

Sunrrpyror. . M a r He so HX C . C 1 6 H tg C l N2NaO5SHzO. ( M .r ' r . 418,8) . Har puer a- f, B cor 2-rngporcu-3-l(2-ruApoKcIi-1-uaSrua)aso]-5-xnop6eHsoncynrsoxr.rcJrorbr, MoHOflrApaT. flopouror KpacHo-Kopr,rqHeBoro rlBera. Mano pacrBopl,IMB BoAe,cnlrpre 96% r4arleroHe, npaKTr.rqecKrr HepacrBopr,rM xJroB

po$oprr,re u e$upe. B nHrepaale 9,8-1l,2urvrcet pH cune-$uoneroByro oKpacKy, KoMnneKc a ero c rdoHoM

MarHr,rrB Tex x(e ycJroBHrx rpKo-KpacHoro rIBeTa. flepexoA oKpacKll npu npflMoM THTpoBaHvruvro:aavrarnvfl. rpKo-Kpacnofi K cLrHeor 6uonerosofi.

EII

Pacmeop uudurcamopa. 0,01 o/opacrnop B alleroHe. Cpox roAHocrr{ pacrBopa * 2 rqec. Marnufi. Mg. (A.u. 24,3I). Jleura, r4nrrcrpyxKa, vrvt [poBonoKa cepe6pucro-6eroro uBera, I{nu rroporuoKceporo rIBeTa. pacrBopr{MB contx aMMoHrrt;HepacrBopI,IM Kr.rcJroraMr4, Pearlrpyer c MrrHepaJrbHbrMr4
B IUEJIOTIAX.

Marnrq arlerar. (CH: COO)2Mg '4HzO. (M.vt. 214,46). Marnnq Auallerar, rerparr.rApaT. pac[nbrBa]ouluecs.Ha Bo3Ayxe. Jlerxo pacrBopllM B BoAer{ BecqserHrre KprrcranJrbr, crrr{pre 96 %. xonrefiuepe. Xpauxr B Bo3AyxoHerpoHktrlaeMoM ' 6H2O (M.vt. 256,43). MarHus Hl{rpar reKcaruApar. MarHnq Hr{rpar. Mg(NO3)2 paclnblBaloquect Ha Bo3Ayxe. Eecqnersrre, [po3paqHbreKpr{craJrJIbI, pacrBopr.rM BoAe,JIerKopacrBopuM B cnl4pre 96 %. B Oqeur JrerKo rourefinepe. XpaHxr B Bo3AyxoHenpoHr.rqaeMoM Maruus Hrrrpara pacrBop B Hrrrpara pacrBoprror npu ocropoxHoM HarpeBauvwt 5 tul eo4rr, I7,3 r MarHr4-fl u upu6aunor 80 un cnfipra 96o , oxnaxcAaror AoBoAqro6renr pacrBopareM xe pacrBopr4TeneM 100,0vrn. Ao MgO.(M"r"r.40,31).Eensrfi, uelrnfi, nemufi nopolxoK 6es gaMarnr.rq oKcLrA. fIaxa. Ipaxru.recKr{ HepacrBopuMB BoAe,c xoropofi Aaer urenoqHylopeaKllurc na QeKrrcJroraxc JrerKr,rM rrrureHl4eM. uolQraler,rH, pacrBopuM B pa3BeAeHHbrx '7H2O. (M.r. 246,48). Marnufi cepHoKrrcnrtfi 7-eoAHHfi. MarHHq cynsQar. MgSOa Marnnfi cepHoKr4 cnufi , renrarrrApar. Ha Kpr{crannbl,BblBerpl4Barcnruecs Bo3l(yxe. EecqserHrre flprr3MarrrrrecKrze HeJlerxo pacrBoprlMB BoAe,oqeHbnerKo pacrBopr{Mn roprvefi BoAe;npaKTl4r{ecKrr pacrBopr.rM cnr.rpre96 %. B MarHnrr cy"rrsQaraHacbrrrleHuufi pacrnop 100 r MarHrrr cylrSara 3anvBaror 100 lrn BoAbrH ocraBJltror Ha 24 u rryu qacroM ss6arrrrnaHrau.Pacrsop Sunrrpyror. MarHuq cy.nrQara pacrBop l0 o/o 10 r uarsur cynr$ara pacrBop.rllor B BoAe r{ AoBoArr o6renr pacrBopa eoAofi ao 100 rvrn. Marnrq xrroprrA.MgCl2 ' 61120.(M.u. 203,31). Marnufi xnopucrrrfi 6-no4untfi, Marnufi xnoprlcrbrfi , rercaruApar. pac[nbrBarorc.n. Ha Eenrre Kpr4crannbl, Bo3Ayxe pacrBopr{MB crrlrpre 96 %. O.reHr nefKo pacrBopnM B BoAe,JrerKo o Manrnq xJroprAa pacrBop l0 10 r uarsvfl xnopr,rAapacrBopqror B BoAe I4 AoBoAtr o6reu pacrBopa soAofi Ao 100 nan. Marnnq nepxrropar. Mg(ClO+). (M.r"r.223,20). MarHnft xnopHoKl{cnHfi6eseoAHrlfr. fpanynrr 6eloro rlBera. llpenapar vpesnuuafiHo nprrqrrlBaer Bnary, npl4 HalpeBanvIvr

C OpTaHLIqeCKI,IMI{BeIIIeCTBaMI4 MO)KeT AaTb B3pbIB.

,rlerxo pacrBoprrM B BoAe,oqeHb nerKo pacrBopllM B roptqefi BoAe,pacrBopl{M B aIIeToHe. CIII{pT9 yo, MeTaHOJIe, 96 200. Marcporo.n 200. flonuerrrneHrrrr{Konb crb. flp ospauH 6ecqn ernafl. vuru rroqrr{ 6ecqn erHa.f, Bt3KaqxorAKo ar, , [paKTpIqecKH ,rlerro pacrBopr{MB BoAe,arleroHe,crrr4pre96 % r,rMerrlneHxJropnAe, HepacrBopzn a eSupe r4xr{pHbrx MacJrax.

dli . or.on 1,127 . o

z" . Orono 1.450. Marcporor 200 oqrarqeHuufi xon6y BMecrI,IMocrbIo 500 MJr MaKporona200 noMenrarorB KpyrnoAoHHyro 6 rlpv reMneparype 'C B reqeHr{e u, uc60 1000nrn,orroH*or neryqre BeulecrBa r,r rronb3yrporarrrroHHstir ucnapvtreJrb BaKyyM 1,5 Ao 2,5 rlla. or 300. Marcporo.n 00. llonra3ruJreHrnr4xom Cvr.MaxporoJlbl. 3 400. Marcporo"r400. Ilonu3Tr{JreHrJrr4xonr Cn. MarcporoJlbl. 1000. Marcpororrbl. Marcporo,rI 000. llo.nueruneHrJrr4Korlb Crra. I5 Marcporo;r1500. llonnsrrlreHrJrr{Konb 00. Cru.ManporoJrbl. 20 Marcporo.rr 0000.llonuernneHnruKoJrb 000. Cnr.ManporoJlbr. 2 20000 2-uurpoMarcpororu 20000 2-nurporepeQra,rar. |IonusrlrJreHrJrrrKons repe$ranar. o6pa6orrofi 2-uurporepe$ranenofi Marporor 20000, rvro4u$nquponaHHrrfi xucnorofi. rIoqrLI6eroroIrBera. TnepAar, Macca 6e:roror{JrI{ nocroo6pa3Hat Pacrnopul.r arleroHe. B (M.u. 364,90).V-lla-(AulaerurarrazHo)Manaxnroerrfi sereHrIfi. C23H2sClNz.
xnoprA. 1-urn4en]4urvrerrrnaMMoHl4q QeHun]$eHrrJrMeruJreH]-unr.norerca-2,5-AueurlBera c MeraJIJII,IiIe cKI{M6re cxolr. Kpircrar.nbr 3eJreHofo pacrBopacr{HeBaro-3eneHofo pacrBoprrM BoIe c o6pa:onaHr{eM B OqeHr JrerKo uBera, pacrBopr{M crrr{pre96% n MeraHone. B Pacrnop 0,01 rl:r s crrrpre 96 % I4Meer MaKcI{MyMrlofnoueHufl npv AnrrHe BoJrHbr uw. 617 pacrBop 0rS oh. Pacrnop 5 rh n yrcycuoil xucnore 6esMa,raxnroBoro 3eJreHoro eoAuofi. Ma,raxHroBoro 3eJrenorocnr{proBbrfi pacrnop 0rl o/o o6relr pa0,1 r uanaxr{roBoro3eneHofopacrBopqrcr s 20 Mn cnrrpra 96 oh u AoBoA.sr crBopasoAofi ao 100 ur. MarensoBafl Krrcd'rora. CaHaO+.(M.u. 116,07). Eenufi Kpr{crannx.recrufi [oporxoK. pacrBopl{Mn e@upe. Jlerro pacrBoprrMB BoAer{ crr{pre 96 o , yMepeHHo Ma,reunonrtfi aHI'rrApLIA.C4H2O3. (M.u. 98,1). Eyreu4Iaouonufi aHrrrAplu. 2,5-QypauArloH. Kpucrannrr 6enoro rlBera. xuc:rorbr, o.reub JIerKopacrBopuM Pacrnoputrl B BoAec o6pa:onaHr4eM MaJrer.rHoBofi grr4naqerare,JrerKo pacrBopr4M Tonyone,pacrBopldM cilI4pre 96 o/o c B B B aueroHe u o6pasonaHr{eM cJro}KHoro aSupa, otreHbMruropacrBoprrMB rrerponefinou e$Hpe.
20

EEI

TennepamypannarneHua.Oxolo 52'C. Jlro6ofi ocraroK, He pacrBopnl,rufi B Tonyone, He AoJDKeH rrpeBbnuarr 5 o/o(watrevHOBaq Kr4CJrOTa). ManeunoBoro aHrr{AprrAapacrBop 5 yo 5 r lta.nensoBoro aHrn\pr41apacrBop{rcT B Tonyone r4AoBoAf,r o6reu pacrBopa reM )KepacrBopr{reneMao 100 nrn. Cpor roAHocrr4- I uec. Pacrnop B cnyqae noMyrHeHHa $unrrpyror. Mannnr. C6HI4O6.(M.*. 182,16). Felufi rrJII4 noqrl,t 6enufi KplrcraJrJrr{.recrzfinoporxoK, JrerKr4e rpaHynbr. Jlerro pacrBoptrMB BoAe,oqeHbMaJro pacrBoprrMB cnr4pre96 %. MaHnoga. C6H1206. (M.r". 180,16). D-(+)-MaHHo3a. Kpzcranluqecxnfi IIJrIIMeJlKoKpr{crannfl.{ecxufi noporxoK 6eloro rlBera. Ove+r JrerKo pacrBopr{MaB BoAe,MaJro pacrBoprrMa oraHone. B +r3,7 go +14,7 ' (20 yopacrBop B BoAe,coAepx{auefioxoro 0,05 YoNHr). la[ . or TeunepamypannqBreHun.Or<olo 132'C c pa3noxeHueM. Mapranqa(Iv) oKcrrA.MnO2 (M.rvr.86,94). MapraHqa AByoKr4cb. Teruuo-xopu.rHesrrfi iloporxoK. HepacraoprrMB BoAe,asotHofi KI4cJIore arleroHe.Pearupyer B xnopficroBoAopoAil nofi rucnore. MapraHqa(Il) cynr0ar. MnSo4'H2o. (M.r"r. 169,02).Maprauqa cynr$ar, MoHorr.rApar. Kpncranrprqecxufi [opo[roK r{nrr Kpr4criurJrbr 6neaHo-po3oBoro rlBera. Jlerxo pacrBopr4M BoAe,npaKrr4trecKu B HepacrBopr{M crrupre 96 %. B Ilomepa GMacce nocne npoKanusauu* Or 10,0 ao I2,0 o . OupegeneHr.re rpoBoArr us 1,000r npr4reMreparype 500'C. Macnsnafl K[cJrora. C4H8O2.(M.r"r.88,10). Eyranonar Kr4cJrora. Cogepxur He MeHee99,0 C4HBO2. Macnsnucrar x{trAKocrr. CueruvrBaercfl, ro4ofi, crurproM 96%. c

d',i. ooono 0,96.

Fr,,. OKoJro 1.399. Teanepamypa KuneHufl. Orono 163'C. Mean(II) allerar. Cu(CH3Coo)z'H2o. (M.r"r.199,65). Mear(II) yKcycHoKr{cral. KpucrannbrvrrvtnoporroK roly6oraro-3eneHororlBera. Jlerro pacrBopl{M runf,ilIefi BoAe, s pacrBoprrM BoAe clprpre 96 oh,MirJro B r.r pacrBopr.rM e$upe u ilrr.rqepuse Yo. B 85 Meau(II) arterara pacrnop 5 7o 5 r Irae4u(II) aqerara pacrBopflIorB BoAe, [oAKr4cJreHnofi HecrorbKnMr,r MvrrrlryrrvtrpaMvyrcyurofi KrdcJrorbr,AoBoArro6reu pacrBopasolofi ao 100 rr,ra. kt Merur saxncnofi xrroprrA. CuCl. (M.rur. 99,00).Melr oAnoxrroprcrat Ceporaro-6enufi rrJrr.repoBaro-3eneHbrfi c nopouror. Hepacrropl4M BoAe, pacrBopr,rM xnoprrcroBoAopoAHofi B B rucnore KoHrleHTprrpoeaHHofi pacrBopeaMMr{aKa r{ KoHrIeHTprlpoBaHHoM. garcr.rcnofi MeAn xJroprrAa pacrBop K I,25 r MeAusarllcnofi xnopr{Aanpu6arrxnr I r Harpvfrnaera6ucynr$urau 100 rr,rn oh pacrBopa l0 aMMoHrdr xJropr{Aa.
20

Etr|

Megr(Ir) Hrrrpar. Cu(No3)2 '3H2o. (M.rur.241,62). Me4n Avrnr4rpar, rprrrr{Apar. Mear(II) a3orHoKrrc rrar-3 -uoguan. Kpncrannbr cr4HeforlBera. oqess JIefKopacrBopl4M BOAe, B C[r4pre96 YoetKr4cnore asorHofipa3BeAeHHOfi. BOAurri pacreop rrMeer cr.rJrbHo Kr4cJryro peaKrlr4ro. Xparur B Bo34yxoHerrpoHr{rlaeMoM xourefiHepe. Megn(II) HrlTpara pacrBop 5 oh. 5 r uean(Il) Hr.rrpara pacrBop*or B BoAerr AoBo4rr o6reu pacrBopa no4ofi ao 100 ul. MeAn orcucHofi xJropr{A. Me,tr AByxJropncras 2-eoAHafl. MeAr x.iropHar. Cu. Mean(II) xJropnA. MeAu orcncuofi xJropr{AapacrBop Pacrnopnot 0,75 r MeAI.I orucHofi xnopvAa u 1,5 r aMMoHr{fl xJropr4Aa se6orsruorr,r n KoJII'{qecrBe BoAbI.K pacrnopy npu6arnsrcr 1,5 v,r KoHuenTpprpoBaHHoro pacrBopa aMMrraKa AoBoAf,ro6rerra r pacrBopa no4ofi lo 25 rran. Meau(Ir) cy.nn0ar. CuSoa . 5H2o. (M.rur.249,68). Mear(II) cepHoKr.rcnar 5-noguax. Me4r(II) cepuoxnclras, neHrarurApar. flopouron unrr KprrclaJIJIbI cLIHerorlBera. MeAreHno BbrBerpr{Baercfl. Bo3Ayxe. Ha Oqeur nefKo pacrBopr,rM BoAe,MaJro B pacrBopr4M cflrrpre 96 %. B Mean(II) cy.nrQara pacrBop 12,$ oh. Pacrnop 125 rlt. Meau(II) cynrQara pacrBop l0 o/o.Pacrnop 100 r/,r. MeAn rerpaaMMrraKara aMMr{aqHbrfi pacrnop 34,5 r ueau(Il) cynrSara pacrBopqror e 100 MJrBorbr, npn6anrrror npu repeMeIrrHBaHlII4 KanJrtMpacrBop aMMr4aKa rro KoHrleHTprrpoBaHHufi pacrBope4o uux olpa3oBaBrxerocq ocaAKa. llo44epltvrBas, reMneparypy Hvxe 20 "C, npu HerIpepbIBHoM BcrptxvIBaruu npw6antxror rro KarrJrrM30 nr,r pacrBopa narpvfl rr.rApoKcrrAa KoHrleHrpr4poBaHHofo (20 %). (Drl-urrpyror qepe3 crexlguurrfi $unrrp (40), npovrblBalorsolofi Ao ronyqeHrir npo3par{Horo Sulrrpara. Bcrprxr4Barorc 200 Mn pacrBopa aMMHaKa KoHrIeHTpHpoBaHHoro$ra;lrrpyror trepe3 H creKJIrHHufi $unrrp, 3areru rroBTopHoSurlrrpyrcr, .rro6sr yMeHbrrrurbocaAoK AO MrrHrrMyMa. Meau(Ir) xrroprrA. cucl2 '2H2o. (M.rur.110,49).Me4raxnopr4A,rurr4rpar. lloporuox r{nkl KpucraJIJrbI 3eJreHoBaro-ro,ry6oro rlBera, pacrrnbrBarolluecr Ha Bo3B Ayxe, BbrBeTprrBaroTcrcyxoM Bo3Ayxe. Jlerro pacrBopt{MB BoAe,clrrpre 96 oh u MeraHoJre, yMepeHHo pacrBopr4M arleroHe, B pacrBopr4M eSupe. MaJro n XpaHrr B Bo3AyxoHerrpoHr{rlaeMoM rourefi Hepe. Me4u 3Aerara pacrBop K 2 prn 2 oh pacrnopa nae4n(Il) aqerara upu6auxror 2 rw 0,1 M pacrBopa Harprrr 3AeTaraH AoBoArr o6renr pacrBopa soAofi lo 50 vrn. Me4Ho-raprparHrrfi peaKTrrB(pearrun (DenraHra) Pacrnop r. 34,6 r rraean(Il)cynrsara pacrBoprrcr B BoAe,AoBoArr o6reu pacrBopa reM xe pacrBopr.rreneM 500 un. Ao Pacrnop II. I73 r KanI,It-HarpLI{raprp ara rr 50 r Harpur rnApoKcrdAa pacrBopnor B 400 rr,rn BoAbI.HarpenarcT Ao KrrleHr,rfi,oxJralrAaro! AoBoArr o6reu nonf{eHHoro pacrBopa no4ofi, cno6o4nofi or yurepoAa AlroKcr4g&, 500 rvln. Ao

HenocpegcrBeHHo nepeAIlcnoJrb3oBaHr4eM parHuii o6retru pacrBopoB cMerrrr4Baror InlI. 5 ntn pearcrusaOeruHra pa:6aurrror 5 ur nogu 14 HarpeBalorAo KxrreHr{r.Pacrnop npo3paqHbrM He BbrAentTb 14 ,{onxeH ocTaBaTbcr Aax{ecneAoBocaAKa. MeAHo-raprparuslfi pacrnop (2) ClreruHsalor 1 u-rr pacrBopa, coAep)Karqero rfu nreau(Il) cynrQara u I0 rlrr Karwtfl 5 rapTpara, c 50 rran 2 ot'a pacrnopa HaTpr4x xap6oHara. foloesr He[ocpeAcrBeHHo nepeA HcnoJrb3oBaHrreM. Me4no-raprparnrrfi pacrnop (3) Cuerunnalor paBHrIe o6reurt pacrBopa 10 r/n Nregu(II) cynrsara u pacrBopa 2A rlt Harpknrraprpara" K 1,0 MJinonyqeHHofopacrBopa npa6annxior 50 un pacrBopa :narpkrfl rap6ouara. foronsr HenocpeAcrBeHHo irepe.q trcnoJrb3oBaHueM. MeAHo-raprparuufi pacrrop (4) Pacrrop I. Pacrnop 150 ri.rrueau(Il) cynr$ara. Pacrnop 11.2,5 r Harpuq xap6ouara 6essoAHoro,2,5 r KaJrr.rr-H arpufl "raprpara, 2,0 r HarpvrflrllApoKap6oHara u 20,0 r Harpnr cy;ii,$ara 6esno4noro pacrBoptlor B BoAe,AoBoAtr o6leu nonyqeHHoro pacrBopa reM xe pacrBopr4TeneM .uo 100 lrn. HenocpegcrBeHHonepeA r{cnoJIb3oBaHHeM pacrBopu I H II n coornocMerrrr.rBaror

mer.uvr T:25. Melno-uurparnufi pacrBop 25 r rrae4u(Il) cynr$ara, 50 r nuuouuofi Kr{cJrorbr 144r Harpur rap6oHara u 6eseoAHoro pacrBoptror B BoAeil AoBoArr odrelr pacrBopa reM xe pacrBoprrreneM .uo1000nan. MeAno-rlHrparuuft pacrnop (1) 25 r Megu(II)cynrSara,50 r:ururor*rofiKr.rcnorbr 144r Harpr4r u xap6oHara 6esnoAHoro pacrBoptlor B BoAea AoBoArr o6ren pacrBopareM xcepacrBopt4TeneM Ao (ucnuryelrufi pacrnop). 1000rran PacrnopKoppeKTr4pyror qro6rr oH BbrAep)KHBan raK, cneAyroulue rpe6oeaurx: A. K 25,0 Mn ucrrblryeMoro pacrBopa npu6annxror r ranux iaogu1a,3areM 3 ocropo)KHone6onrruuMll nopquxuu npu6aBrqror25 vn pacrBopa % (u/rra) 25 cepHofi KlrcJlorbl TI4Tpy}or M pacrBopoMHarpLrs r{ 0,1 rnocyirn$ara, HcfroJrb3yf, KaqecrBe B xH.4nKaropa ul 0.1 % pacrBopaKpaxMaJIa, 0,5 xorclpufi upu6ar;rxrorB KoHUe rr4TpoBaHr,rff. Ha rurporaHr4eilonxHo 6si:rr ra3pacxoAoBaHo 24,5 ao25,5 vn 0,1 M pacrBopaHaor rpr.rr rr{ocy;rtSara. 5. 10,0 Mn HcnbrryeMoro pacrBopaAoBoAsrsoAofi.qo o6reva 100,0 Mn 14rrepeMerirrrBalor.K 10,0 Mn nonyqeHHoro pacrBopa npu6auxror 25,0 ul 0,1 M pacrropa xnopncroBogopo4HofrKl{cnorbrHarpeBarorHa BoArHofr6aue B TeqeH}re or,oxlax1 .4aro! AoBoAtr noAofi.qo Harlanbsoro o6reMa prrr.rrpyror 0,1 M pacrnopoM Harpr4rrr4I4crronb3.vt KailecrBel,rHAuKaropa lrr pacrBopa Senon$rafleuna. B 0,1 ApoKcr{Aa, Ha rurporanr.{e Aonxso 6urr r{3pacxoAoBaHo 5,7 go 6,3 rrar0,1 M pacrBopa Haor Tprrr rr{ApoKcr4Aa.

GII

B. 10,0 Mn I{cnblTyeMoropacrBopa AoBoAfirBoAorlAo o66eMa 100,0 MJr14rrepeMeIrIHBaror.10,0 un noryqerlHoro pacrBopa rr{Tpy}or 0,1 M pacrBopoMxJroptrcroBo:opo4uofr KucJrorbr, ncilonb3yq B KaqecrBe r{HAr4Karopa 0,1 un 1 o/o pacrsopa Senon$rzureuna. Ha rur:ponaHr4e or Aonxuo 6rrrr r43pacxorToBauo 6,0 Ao 7,5 wn0,l M pacrBopa xJroprrcroBoAopo4Hoii Kr{cJrorbr. lVlelu. Cu. (A.u. 63,55). Oolma oqldilIeilHafl,crpyxma, rrpoBonoKa urrr4Merannfiqecxufi nopolroK 3neKTporr.ITI4qe cKori qncrorri. MerurnnoKcr{A. C6HI0O. (M.r"r.98.14). Metrzrnenr-3-en-2-on. Orlrcs Me3r{rr{Jra. EecqgerHas,MacJrsHl,Icrar xnAKocrb. Pacrnoplrnt e 30 qacrsx BoAbI,cMeuruBaercr c 6oriruruncrBoM opraHaqecKr,rx pacreopurelefr.

d,, . Orono 0,858. Teunepamypa KuneHun. 129ao 130'C. Qr Me;raunH.C3H6N6. r'n. -rppraMrrH. (M. I26,t 4). 1,3,5-Tpzas uu-2,4,6 AuopQHufi nopourox 6eloro rlBera. Oqesr MaJro pacrBopr{M BoAe crrnpre96 %. B r4 MeHrnrallerar. CnH22Oz. (M.r. 198,30). 2-Lbonponul-5-rr,rernnrrr4KnoreKcr4aueTaT. Eecqsergax )Krr.uKocrb. N{q5opacrBopnM Bo.qe, B cMerrrrrBaercr crrlproM 96 % u e$uporr.r. co dii . Oxono 0.92. r,i .OrcoloI,447. Tennepamypa KltneHun Orolo 225'C. qucrora MeHTr4Jrarlerara, Xporr'rarorpa$uvecrax r4crronb3yeMoro B ra:onofi xpoMarooh. rpaQur.r, 6rrrr HeMeHee 98,0 .uonxHa MeHrol. Crr,r. JlenolreHToJr Meuro.u parleM[qecrcufr u Xpouarorpa$uvecrax ql4croraMeHToJra, rrcronr3yeMoro rasosofixpoMarorpaSuw, B 6u:rr HeMeHee 98,0o . AoJrx(Ha MenroH. Cr0Hr80. (M.r'r. r54,24). (2S, 5R)-2-?Isonporrrin-5-rraeru:rrIr.r oreKcaH H. (-) -mp auc-n- M eur aH 3- os. Kn o Co4epxzr pasJrr4qHbre Korl,rqe crBa r,r3oMeHToHa. EecqnerHax xrzAKocrb. pacrBopl4M BoAe, O'reHrMiuro B pacrBoprrM crrtrpre96 % u sQupe. or{eHb JrerKo B d,i . Oxono0.897.
/7n . Orolo 1,450. Xpouarorpa$uvecxaa rll4crora MeHToHa, rdcrroJrrcyeMofo rasosofi xpoMarorpa$uu, B o . AoJrxHa6rnr He MeHee90,0 MeHroQypau. cr0Hl4o. (M.r"r. 150,21). 3,9-onorcu-n-MeHra-3,8-ruen. -.{u vrer un-4,5,6,7-rerp arr{Ap 6en so 3,6 o aH. S.yp Xu4xocrr cJrerKacr.rHeBaroro rlBera. O.{eHr MiLJro pacrBoprrMB BoAe,pacrBopprM crrrpre 96 %. B
20

/li . Ororo 0,965. nii . Orono1,480.

r r2o

Lal., . oxono *93o TeunepamypaKuneHun Orolo 196 "C. Xpouarorpa$v.{ecKas qucrora rvrenroSypaHa, r{crroJrb3yeMoro ra:osofi xpoMaron yo. fpa$r4v, AonxHa 6urr He MeHee 97,0 2-MeprcanrosraHorr.C2H6OS.(M.r"r.7 8,I3). Xra4rocrr. Crraerurasaercr soaofi. c d l l . O n o n ol , l 1 6 . TeunepamypaKuneHun Oxolo 157'C. MeraxpHJloBafl KncJlora. C4H6O2.(M.r"r.86,09). 2-Mernlnpon-2-euoBar KrrcJrora. EecqnerHaxxz4Kocrb. Pac'rnopunaa BoAe,cMerulrBaerc.fl sraHonoMn eQuponr. B c . Oxono 1,431. ho Tentnepamypa KuneHut Oxono 160 "C. TeunepamypailraznHun. Orcono16 "C. Meraun,ronufi xe,rrufi . C t 8H l 4N3NaO3 (M.r'1.375,37). Harpux 3 - [4-(QenunS. anauHo)QeHr.rnaso] 6eHsoncynr$oHar. floporuox KopurrHeBaro-)Kenroro rlBera. o/o, Pacrnopnlr B BoAerr cm{pTe 96 oqeHbMano pacrBop}rMn e$upe. Merann"roBoro )r(eJ'rroro pacrBop 0rl oh. Pacrnop I f/n s MeraHone. I,IcnarmauueHa qyacmrumerbHocmb. 50 un yrcycHofi Kr{cJrorbr K 6e:no4uofi npu6aBJl-f,ror 0,1 ul pacrBopa MeraHIrJIoBoro x{eJrroro; rrorBrrflercfl po3oBaro-KpacHoe oKpailrl{BaHne, Koropoe AonxHo uepefiru n SnoneroBoe rprr npn6aueuuz 0,05 un pacrBopa xnopHofi Kucnorhr. 0, 1 M llepexog oKpacKuor Kpacnofi 4o opamreBo-xeJrrofi n r4HrepBane I,2-2,3. pH MeraHol. CH3OH. (M.r"r.32,04). Merasol-x4. Cnzpr Merunosufi. llpo:p a.rH 6ecqn ernafl, BocnnaMeHfltorr\aflcflxrrAKocrb. ar, CMerulreae'rcfl no4ofi r{ cn}rproM 96 %. c TeanepamypaKuneHufl. 64lo 65 oC. Or Merano"u oco6ofi qucrorbr rpe6oBatufl, Anr MeraHoJra cneAyrouee AononHr{TenbHoe u ,{onxeu BbIAep}KIrBarr
IICTIbITAHIIE.

d1i. or o,Tgt 0,793. to

MunuuanaHoe nponycKaHue. % npr4A.lllrHe 20 BoJrHbr 210 uv; 50 oh npwAnr,rHe BoJrHbr 220 uw;75 % npl4 ArrIrHe BorrHhI 230 uru; 95 % rpr4 AnuHeBonHbr 250 Hrra; o/onpu 98 BoJlHbr 260 uv u 6oree. Anr4He Onpe4eneHr4e npoBoArr, r{cnonb3yr B KaqecrBe pacrBopa cpaBueHr.{r BoAy. Merano.n AJrfl?rorAKocrnofixpoMarorpaQnu Merauol,I4cnonb3yerr,tufi n )Kr{AxocrHofixponaarorpa$uu, AonxeH Bbrgep)KrrBarb cnencnbrTallvfl. Aylorqlr e AorronHr{TenbHbre Cogepxr.rr He MeHee99,8 o/o CH4O. Onmuvecrcan momHocma. He 6onee 0,17. klsnreprror rrpr4Anr4He BoJrHbr n*r, uc225 goAy. noJrb3yrB KaqecTBe pacTBopacpaBHeHrrr
Ellil

\ Ierauo.n rroAKr.rcJreHHufi 1.0 rr,r 25 % xJrop[croBoAopoAHofixucrorbr AoBoArr MeraHonoMAo o6reua 100,0nan. Merauo.n 6essoAHHfi 1000 rvrn MeraHoJIa o6pa6aruearor 5 | MafHHr. Ecnz ueo6xo4nrr,r LrHpur4vtpyror peo, aKqr.rro, npulantxt 0,I lrri 5,4oA pacrBopapryru(Il) xnoprrAa.flocre npeKparrleHut BbIAeJIeHLIflra3a xnAKocrb [eperoHflro! orroH co6uparor a cyxofi r<ourefiuepu sau_lHUIaloT oT BJrafr4.

Boda. He 6onee0,3 rAr. \{eraHo.no cno6oAnufi or aJrbAerHAoB 25 r iaoaapacrBop{rcr n 1 .rrMeraHoJIa, nonyqeHHrrfipacreop npNdanrrror rrpr4rrocrorHI{oN,I noMclrllBautrrrK 400 nrir I M pacrnopa Harplrfl rrrApoKcr4Aa, 3areMupra6a(Du-rrlrpyrcT14KrrrrflTflT o6parHr,ru BJLf,ror 150 ran BoAbIi,I ocraBJrtrtor ua 16 .r. c \o"rIoAuJrbHi4KoM ucric3FioBeHirq 3arraxafiogosopMa. Pacrnop noABepfaror spaxA0 uuosHofrnepefoHKe. Co4epxnr He 6o:ree0,001 o/oantheruAoB n KeToHoB. Merarro,r, oqlruleHnsrfi or rcap6ounncoAep)ffaulnxnpunreceft i ,r lteruroBoro cr{}rpra HafpeBaior 3 .{ c lA r 2,4-alnrlrrpo$eHr{nrr4Apa3una rvtn 2 xiropr{croBo4opo4i+oir KucJrorbrKoHrlerrrpr{poeauHofi odparuuM xononuJrbHr.{KoM c Ha Kirlr.fliuclieogxHoit 6ane. 3areu Merr.rJToBbrii cnirpr 2 paza ueperoHslor, co6*rpax oC. npu Sparqnz, Kr,rrrflulr4e 64,5 2-{ rnl cn'Hpra rloMeluaror e ro:r6y BMecrI4MocTbFo lr:r, npu6anlxror 75 nn;r 300 pacrBopa 2,4-7t'ruvtpoSerunrililpa3n:na,HarpeBarorlra BoI.sHoit6ane c o6parHtlM xoJorHnbHr{xaw24 q, crlr.tpr orfoH-fi]or,pa3BoArr ao 200 wt 2 %opacrBopoM cepHofi Kllcirorbl I{ ocraBrtlor Ha 24 q. He Ao.nxuu o6pa:onbrBarbc.s (anr4eKpr4clannbr ru4ri). \Ierancyrr,$ononax Kr{c,rora. CH4O3S.(M.nr. 96,09). flpoepa.iuan.6ecqserHasxlaAxocrb, 3arBepAeBaroular TeMneparype [pr4 oKoJ]o 2A'C. Cliefirlaeaerct c Borofi, rraro pacrBopr,rMa Tonyone,rpaxTr4trecKu B HepacrBopaMa B feKcaI{e. c/]l . Onono 1,48. It,, . Oxono 1.430. MeraSocSopnafl Kr.rcrrora. (HPO3)x. gFrHoe Crerl onn4HbleKOMor{ :aIrr4 :rcr4 naJroqKr4, coAepxarqueonpeAeJr KoruqecrBo Harpu.s MeraQoc$ara. furpocxon ilqna. OqeHr nefKo pacrBoprrr\ra BoAe,pacrBopraMa crrapre 96 %. B B XpaHx:rB Bo3AyxoHerrpoHrruaeMoM xoHreffuepe. 4-Merunauu noSeHo.nacy.nr$ ar . C ruH2sN2O6 (M. rur. 44,38). S. 3 BecuserHHe Kpr4crannbr. O'{eHr JIerKopacrBopl4M BoIe, MaJIo pacrBopuM B crrr4pre96 oA,npaKTr4rrecKz B HepacrBopr4M o$vpe. e Teuneparurypa ez.neHun. nn Oxoto 260'C. Merra,ranrp aHrrd'r C 8H9NO2.(M. pr. I 5 1,I 6). Merut-2 - aMuHo6ensoar. ar. FecilserHrle KpI4cranIrbrprlrtt x{r{AKocrbor 6ecqsernofo Ao xrenroBarofo qsera. PacrBoprrMB Bore, JrefKopacrBoprrMB crupre 96 % u eSupe.

Eg

Teunepamypa nnaBleHua. 24 xo 25'C. Or Teunepamypa KuneHunOr 134 ao 136 "C. uclonb3yeMoro B raeonoft xpoXponlarorpaSuuecrax qrrcrora MerlrnaHTpaHrrilara, rraarorpa$ur4, AoJrxHa6urr He MeHee95,0 yo. Meru.napaxnAar. C 2tH 42O (M. tnt.326,55). Mernrefi xo3aHoar. 2. rlpoBoA-f,T MeroAoNa rasosofi Onpe4eneHl4e Cogepxur He MeHee98,0 o C21H42O2.

xpoMarorpaSuu. KpucranruqecKar Macca 6e:roroAo xenroro rrBera. or PacrnopnuB crrr{pre % u nerponefiuoue$upe. 96 Teunepamypa mazteHun.Oxono46'C. (M.u. 74,08). Meur.raqerar. CH3COOCH3. flpo:pauHax, xr,rAKocrb. 6ecqnerHar 96 Pacrnopuna BoAe, B cMerrrr{Baercq cnl4proM % u e$upou. co d,i . Oxono0,933. reii. onorro1,361. Teunepamypa KuneHun 56lo 58'C. Or Meru.u6ereHar. nH 46C. (M.*. 354,61).MerurAoxo3aHoar. C 2. nopolxoK. Kpncranrbrr{JrH Kpr{crannrrqecxzfi pacrBoplrM 3TaHoJIeeSnpe. u B B flpaxrlruecKr4 HepacrBoprrMBoAe, Teunepamypa Or 54 lo 55 "C. merneHun. a rLIApoxJIopItA. 1 S' Meru.u6en3oru a3oJroHrrrApa3oH C8H 0ClN3 H2O. (M.r"r. rr{Apa3oHa rr4Apoxnop}1.u, MoHoru233,72).3-Merur6eH3orr4a3or-2(3H)-oH IPar. rroqrr{6eloro HJrrl xeJrroBaroro Kpucrarru.recrufi noporuoK uBera. pacrBopr{M cilr4pre %. yMepeHHo B PacrnopurraBo.qe, B 96 Tennepamypo marreHua. Otcolo 270'C. 72,1 2-Merur6yraH. (CH3)2CHCH2CH3.(M.xl 5). I4soneHraH. o CsHtz. He 99,5 Co4epNIar MeHee
AwilJas.c )KrrAKo fl. Eecqr ers afl, Jr erKo Bo crtJlaMeH crb. z flpaxruuecr{rz HepacrBopLtM BoAe,cMerrruBaercfl STaHoJroM o$upou. B c

d]i " ororo0,627. n,'.Orono1,354. Teanepamypa KuneHufl. Oxoro 29'C. o. Boda.He 6onee0,02 He Ocmamorc nocre sbtnapunauun. 6oree0,0003%. BonHbI MuuuilauaHoe BoJIHbI nw;85 o/onpu 210 nponycKaHue. 50o/onpu,{nl4He AnrrHe 240 nrvu 6oree. 220 uwr;98% npr{ ArrrrHe BorrHbr pacrBopa B soAy. Onpe.uereHze rrpoBoArr, rrcnonb3yq KarrecrBe cpaBHeHr4r

2-Meru.rr6yr-2-en. o (M.vr.70,13). CsHr

O.IeHr JIerKoBocnJlaMeHtlorratcgxuAKocrb. flpaxruuecKr4 HepacrBoplrMB BoAe, cMerxr4Baercrco cnl4proM 96 % u aSupoM. TeunepamypaKuneHut. Or 37,5 ao 38,5 oC.

Mern.n4ercanoar. CIH22O2. (M.r'r. 186,29). Merul-ru-AeKaHoar.Merunosufi esup KanpnHoBofi rncnorrr. Co4epxur He MeHee99,0 o C1H22O2. Ilpoep a.*r ax, 6ecqner:aafl. rNru )Kenroro qBera xr.rAKo crb. Pacrnopuu B nerponefiHorra e$rape, ilpaKTutrecKr{ HepacrBoputM BoAe,nerKo paB cTBOpr.rM sTaHOJre eslrpe. B U

d,i . Or 0,871 0,876. ao n1',o, 1,425 r,426. go .

Meru.nAoKo3anoar. Crr,r. Me:rn.n6erenar. 3-o-MerurrAonaMrrHa rrrApoxrropnA. C9Hl4clNo2. (M.rra. 203,66).4-(2-Avruuo-2 -rvterorcu$eHoJra erun) rrrApoxnopr.rA. Teunepamypa manreHun.Or 213 to 215'C. -O-MerurrAorraMnHa rnApoxrropul. CeHt4ClNO2. (M.u. 203,66).5-(2-Anruno-2 -wrerorcuSeuoJra erun) rr4ApoxnopuA. Teunepamypa rua*neHun. 207 rc 208 "C. Or 2-Merul-5-HnrponMrrAa3orr. C4H5N3 (M.t"r.I27,I l). 02. floporuox or 6eroro Ao cBerno-xeJrroro rlBera. Tentnepamypa ManneHu* Or 252 ao 254 "C. Mern.nen6ncarcpnnaMnA. C7H10N2O2.(M.rur. 154,17). N,N'-Merureu6ucrrponeHaMlrA. Oqesr uelxnfi rroporuoK 6eroro rrJrLr [orrrr4 6eloro rlBera. Mano pacrBoptrM BoAe, B pacrBopr4Mcnilpre 96 %. B oCc pasloxeHrreM. Teaneparnypa maBneHun. 300 ' Merunenosrtfi cuHnfi.Cl6Hl8C1N3S3H2O.(M.r"r. 373,89). Merunenonufirory6 oir. 3,7-! t4 errrJr nHo S eHor uazuua-5 -xJr rrA. M aM op Kpucrarr nq'ecrckrir nopolroK TeMHo-3eJreHoro 6pousoBoro rlBera. unz Jlerro pacrBopt4M BoAe,pacrBopuM B cnr.rpre96 %. B MernneHoBoro cuHero pacrBop. 0,I5 oApacrBop. MernrenoBoro crrHero cnrrpronrrfi pacrnop. 0,I o/opacrcop B cnr.rpre96 o/o. Meru.nenxJloprrA. CH2CL2. (M.r"r. 84,93). lzxnopueraH. Xnopucrr;i.rMerrrneH. EecqserHas)KrrAKocrb. VrrrepenHopacrBopuM B BoAe,cMerrrkrBaercs. crrr4prow96 Yov e$uporrl. co Teanepamypa KuneHufl.Or 39 to 42 oC. Merr.u enxn opI4A,u c flonb3yenaufi n SnyoplrM erpr{ 14, onx(eH BbrAepx(r{ Barb cJr e .u l,rcrrbrTaHl4e. Ayroqee AononHuTenbHoe @nyopecqeHqun.IIpu o6nylleHr.rncBeroM c grzuofi BorrHbr365 nu nornorleHlre, LI3MepeHHoe nprl AnlrHe BoJrHbr 460 npr B KroBere c roJurlr4Hofi cnos 1 cvl, He AOIX(HO 6UTb r{HTeHCr,rBHee norJroueHr4r pacrBopa, coAepxauero 0,002 ppm xLIHI{ua 0,5 M pacrrope cepnoi KrrcJrorbr, r n3MepeHHoro Tex xe ycnoB
BI,I'X.

Mern.ueHxJroprrA noAKrrcJrenHrrfi K 100MJI MerIrJIeHXJIopv.qa npn6annxror nrnKr4cJrorbr 10 xnopr4croBo4opo4nofi rolrIleHTplIponauuofi, BcrptxrlBarcr.flocre pa3AeJreHr.rr cJroeB rrcrrorrb31rror nr,rxnufi crofi.

2 1. 3 a x . 2 7 6 8

C6H1 Meru.nrso6yrn"uxeroH. 20. (M.u. I 00,16). 4-Merut-2-neHraHoH. )KI,IAKo crb. flpospavuax,6ecqserHafl pacrBoopraHurrecKl{x c 6onrurIaHcrBoM cMerrrr.rBaercfl B Malo pacrBopr4M BoAe, purenefi.

dli . onooo0,80.
KuneHunOrolo 115'C. Teunepamypa lleperoHtlor 100 un. I,Iurepnal reMrleparypbl npedenu nepezoHrcz. Teunepamypuarc oC; He rreperoHKrr AonxeH rlpeBblllrarr 4,0 AonxHo neperoHtrbct or 1 Ao 95 un. oA.Bunapunalor Ha soAsHofi6aue, nocne 6dnapu6auun.He 6onee 0,0I Ocmamorc 'C. ocraroK cyllrar rlplz reMrleparype or 100 go 105 Meru,rugo6yrn;rreroH otluulennstfi o/oxucueruru:o6yrl4JlKeroHa BcrprxrrBaror c 0,5 utt25 50 rr,rn cBe)KeneperHaHHofo Jrorbi xnopvcroBoAopoAHofi n reqenne I uus. llocne pa3AeneHlrtcJIoeBnuxnufi cnofi or6pacblBalor. rlepeAIrcrIoJIb3oBaHIaeM. forosqr HerlocpeAcrBeHHo Meru.urcanpnHar. Cl,r. MernJIAeKaHoar. Merurnarrpnrlar. CH3(CH2)6COOCH3. (M.r"r. 15 8,23). MerunorraHoar. )KrrAKo crb. EeclfeerHafl. vtrvt }KeJIToBarat u B B llparruuecKll HepacTBopI{M BoAe;JIerKopacTBopI4M gTaHoJIe e$upe.

dii . onono0,876.
/1, . Oro.no1,417. Or KuneHun 193ao 194'C. Tet+,tnepamypa 8). Mernrrcarpoar. cH3(cH2)4coocH3. (M.ru.130,1 MerurreKcaHoar. A FecuserHa vlrvtxeJlToBaratxLIAKocrb. Ia pacTBopt{MsTaHoJIe e$rape. B JIefKo B llparruuecKrrHepacrBopl{MBoAe,
20

dii . o*ono0,885.
z, . Oxono1,405. Or KuneHun 150ao 151"C. Teunepamypa (M.r"r. 4,34). MernnAoAeKaHoar. 21 Mern.n.naypar.CH3(CH2)gCOOCH3. I o CBH26O2. rasoeofr rpoBoAtr MeroAorr,r OnpegeneHlre 98,0 Co4epxur HeMeHee xpoMarorpaQuu. crb. }KeJIToro Eecunersas rlJrr{ uBeraxI,IAKo e$rape. B Pacrnopul,r crlI4pre96 % u rlerpoJrefisorr,r
20

dll . onono0,87.
/1, . Ot<ono 1,431. Orolo 5 "C. nnArreHzz. Teunepamypa (M.u. 382,65).MerranrerpaKo3aHoar. Mernr.rrurHorlepar. CH3(CH2)22COOCH:. Xenrosarble xJrorlb{. u pacrBopl{M gTaHoJIeeQupe' B B llpaxruuecKlrHepacrBopl{MBoAe, marneHua.Orcoto58'C. Teunepamype (M.*. 294,46). Merut-t4uc,t4uc-9,12-orraAeMern.runHorlear.Cl7H31COOCH3.
KaAI{eHOar. Xerroearat MacntHucr afl. xIrAKo crb.
20

llpaxrzvecKr{ HepacrBoprrM BoAe,pacrBoprrMB graHoJre, B nerKo pacrBop}rMn a$vrpe.

d]i . ororo 0,888.

n',0,O*ono 1,466. . TeunepamypaKuneHufl. Or 207 ao 208 "C. Meru.nnnHoJreHar.C7H29COOCH3. (M.u. 292,46). Merun-quc,t4uc,t4uc-9,12,15oKTaAeKaTpn eHoaT. Xelronarat MacJItH afl,xI4AKocrb. krcr u llparru.recKr4 HepacrBopr,rM BoAe,pacrBoprrMB gTaHoJre e$Npe. B

d]i . o*ono 0,901. n',i.O*onoI,47l. Teunepamypa KuneHun Oxoro207"C. (M. Mernnnaprapar.C1 COOCH3. vr.284,47. MerunrenraAeKaHoar. ) 6H33
EecuserHHe urwt rorrrkr 6ecunerHue rIJIacrLIHKrr. n IlpaxruuecKu HepacrBopr4M BoAe,pacrBopllM B 3TaHone eQupe. B TeanepamypaMa*neHun. Or 32 lo 34'C. MernrnreranprrJrar. C3H5COOCH3.(M.u. 100,12).Merrar-2-uerr4nrrpor-2-euoar FecqnerHas xr4AKocrb. u Oqesr Mano pacrBopvM B BoAe,cMerililBaercf,c sraHoJroM e$npol,r. d,i .Orcotro 1,414. TeunepamypaKuneHun Oxoro 100 "C. TeunepamypannarneHua.Ot<otro MrIHyc48 oC. uir C o4epxnr rroAxoArrrl cr a6u nrr3lrpylouufi p earenr. MerHnrrupr{crar. C 8I127COOCH3.(M. r"r.242,39). MerunrerpaAeKaHoar. rpoBoArr MeroAorr4 rasosofi Cogepxur He MeHee98,0 Yo C15H30O2. Onpe4eneHr{e xpoMarorpa$uu. Becqseruafl.vrrrr cna6o xeJrrofo uBera xr,rAKocrb. PacrnopuM B cnr{pre 96 Yo 14nerponefisowr e$lrpe, rpaKrrr{ecKr{ HepacrBopl{M B BOAe.

dii . onoro 0,87.

lt,, . Onorro 1.437 . 20 Tennepamypa nna*neHun. Otcono "C. Teanepamypa KuneHutOxono 156"C. Mern.nonrrfi xenrrrfi . Cu. ,{nlr eru.nonrrfixelrrrfi . (M.r. 458,5). a-lla-(fiur"terurauzuo)Meru.rrosrrfi sereHrrfi. C26H33CI2N3. Seuur] [4-(Aurnrerlrn]rM]rHuoquKJroreKca-2,5-guenunz4eu]-uerNrQeuun]rpuvreTUJTaMMOHHfl I.IdXnOprlA.
20

flopouor 3eJreHoro uBera. x{eJlTorooKpan Pacrnopurvr BoAe,pacrBopr4M cepuofi Kilcnore c o6pasonaHrreM B ruvtBanvs,, nepexoAqilIefo B 3eneHoenpu pa3Be4eHnuro4ofi. MernJrosoro 3eJreHoro-fi oAoruepKyparHan6yuara ToHrue noJrocKrrnoAxoArulefi $urrrponauofi 6yrraarunorpyxarcr s 4 oh pacrBop Merr4JroBoro 3eJreHoro,cyrxar Ha Bo3Ayxe, 3areM rrorpyx{a}or ux na 1 q B pacrBop, coAepxaqufi I 40 rln Karrufl irotu1a u 200 r/n pryru(Il) fioluaa.

EEr|

Ilolocru npoMbrBarorsoAofi 4vrcrvrrrruposaHHofi rex nop, noKa npoMbrBHbre BoAbI Ao He craHyr rrpaKTr4qecru6ecueerHbrMr4, cyrxar Ha Bo3Ayxe. r{ Xpanxr B 3arrIruIeHHoMor cBera Mecre. CporroAHocrr4-2cyr. Mernnonrrfi mpaurufi. ClsHtsN3O2. (M.rnr. 269,30). 2-(4-[uuerrrlaMl4uo$eHunaso)6engofinax Kr.rcJrora. KpllcriurJrbrQuonerororo IIBgTa. floporuor reMno-KpacHoro rlBera r,IJII4 flpaxrvvecKr4 HepacrBoplrM B BoAe,pacrBopr{M B cflr4pre 96 YoIIpr{ HarpeBalF^nw, pacrBopr,rM B pacrBopax eAKktx ulenoqefi u yrneKrrcJrbrxcorefi uleJroqHbrx
MCTAJIJIOB.

Mern.rronoroKpacnoro pacrBop 01057o pacrBoprnr B cMecrl1,86 rran M pacrBopa:aarpufl u 0,1 r'rIApoKcI,Ira 50 rran 50 rrar oh,AoBoArro6rerupacrBopa ro4ofi ao 100rran. cnr4pra 96 K 100MJr 80A6r, or Irlcnumauue uyscmsumeilbHocmb. Ha cso6oAHofi yrJrepoAa AnoKrur pacrBopaMerlrJroBoro KpacHoro 0,05 ur 0,02 M pav cvra, upu6auxror 0,1 nosBr.f,ercs KpacHoe Koropoe KrrcJrorbr; oKparrrnBaHrre, crBopaxJroprrcroBoAopoAsofi HanepefiruB x(eJrroe npu6aBJreur.ru6oree 0,1 nan npu se 0,02 M pacrBopa AorrlKHo Tpr4fl, rvr4poKcr4Aa. flepexog oKpacKr.r KpacHofi xenrofi r uurepnanepH 4,4-6,0. or Ao o/o Mernronoro Kpacnoro pacrBop 0104 pacrBop*or s 18,6 rvrn KpacHoro 0,02 M pacrnopaHarpLIrrLI0,1 r Merr.rJroBoro pacrBopano4ofi, ceo6oAnofior ynrepoAaAIroKcnAa, r{ Ao ,[poKclrAa AoBoArro6rerra r 250 rran. flepexogoKpacKr.r KpacHofi xenrofi n unreprane4,2-6,2. or Mernnonoro KpacHoro crrrproBblfi pacrnop 0rl o/o.0,1 o/opawyop s 96 o/o crr,rpre. r flepexog oKpacKr.r KpacHofi xemofi n nnrepeanepH 4,2-6,2. or pacrBop Mernnonoro KpacHoro cMerrraHnrrfi pacrBoptror B 100 rran Kpacuorou 50 rur MerprJreHoBoro cr{Hero 0,1 r ueruJroBoro cnrrpra96 %. flepexo4oKpacKlr KpacHo-Suoneroaofi.qo 5,2-5,6. or sereHofiB uHrepBzlrrepH Mern.nosrrfi opanxeerrfi . C t4Hl 4N3NaO3 (M.u. 327,33).Harpnx 4' -(guverutS. -cynrQanal. anruuo) aso6eusor-4 -xeJrroro rrBera. Kpucr a,uta.re crufi uoporuoKopamreBo pacrBoprrM ropxuefiBoAe, HepacrBoMano pacrBoprlM BoAe, B JrefKo n [paKTr4rIecKIr oA,,upyrr4x prrMB cnr,rpre pacrBopr{Ten.sx. 96 opfaHurrecKl{x pacrnop Mern.uonoroopamKeBoro cMerrraHnsrfi pacrBoptlor B 20 vrr Merr.rJroBoro r4 3eJreHoro opamrceBoro 0,1 r 6porvrKpe3onoBoro u I un 0,2 M pacrnopa Harpvfl.ruApoKcr{Aa AoBoAsro6reru pacrBopa soAofi ao 100rur. pH3,0-4,4. flepexogoKpacKr4 opaHlKesoft xeJrroBaro-sereHoitr.rHTepBane B or Ao o/o Mern.nonoroopaHxeBoroc[r{proBbrfi p acrnop 0,,1 pacrBopflror 80 runBo.qbr AoBoArr B r{ o6reu pacrBopa 0,1 r ueruJroBoro opaHxeBoro crrr{proM % ao 100un. 96 K 100 BoAbr, or trIcnatmaruue qyncmnumenbHocmb. MJr He cso6oAHofi yrnepoAa AI,roKMerr,rnoBoro [orBJrrercr xenroe cvrya, npu6an.uxror ur pacrBopa 0,1 opaHxeBoro;

E4

oKpamLIBaHLIe, KoropoeAoJDKHo nepefiTr..rKpacHoe B nprr npu6aBJreHur,r 6onee He 0,1 un 0,1 M pacrBopa xnopucroBo4opo4nofi KucJrorbr. flepexo4oKpacKlr Kpacuofi xelrofi n unrepranepH 3,0-4,4. or 4o MerH.nonoroopamrceBoro pacrBop B aueroHe 0,025 r MerI4JIoBoro pacrBoprlor s 100 MJr opaHxeBoro arleroHa.PacraopBcrprxuBarorneprroAuqecKr,r B TetreHrle u, 3areu $unrrpyror. I flepexog oKpacKr.r KpacHofi xelrofi e Hurepsane3,0-4,4. or Ao Mernnonrtfi QuolerosHfi. C24H2sClNr. (M.rur. 393,94).Crraecr rr4Apoxnopr{AoB TeTpa-, neHTa- reKc r.r aMeTvnnap 3aEilrrvtHa. apo KpucrannuqecrufiilopouroKc HeoAHopoAHofi pasuepy)Sopuofi uacruq 3eJre(no Horo rlBerac MeranJrr4qecKuM 6lecrorr.t. Pacmopul,rB BoAe, KvcJrorax pacrBopaxrqelovefi. r{ llepexo4 oKpacKr{ pacrBopa xerrofi x gerenofiB r{HrepBilJre 0,1-1,5u or 3epH or :renofir Qnoleroeofi n rrHrepBane I,5-3,2. pH Merrrosrrfi Quo.rreronrrfi pacrBop 0rl oh pacrBoprrcrn 100MJr 0,1 r angnKaropa BoAbr. Merrnoeufi Quorerosrrfi yncycHor(lrc.rrufi pacrBop o pacrBopB yKcycHofi 0,1 rucrore reAqHofi.PacrnopAorrlreH 6rrrr cBexenpvroTOBJICHHbIM.

:.1

(M.r'r.296,48).Mernt-(Z)-orraAer-9-enoar. Mern.no.irear. C17H33COOCH3. o CI9H36O2. Cogepxur He MeHee 98,0 Onpe4eneHre npoBoAxrMeroAoNa rasoeofi xpoMarorpa$uu. EecqserHaxuttu c na6o-)KeJrroro rlBeraMacJrrHlrcrar xrrAKo crb. llparrzuecKrr HepacrBoprrM BoAe, B cMerrrr.rBaercrorauoJroM e$upou. c u

dii . o*ono0,88.
/7,,. OKoroI-452. Teunepamypa KuneHufl. Orono 215'C. Mernnn aJrbMrrar. C I 5H3 COOCH3.(M.*. 270,45).MerulAercaAeKaHoar. I yo C7H34O2.Onpe4eneHrre Co4epxur He MeHee 98,0 npoBoArrMero4ona ra-:onofi xpoMarorpa$uu. KpzcrarruqecKar Macca6eloro l.rnpr xeJrroro qBera. Pacrnopnu cnllpre 96o/onuerponefinou B e$upe,npaKruqecKrr HepacrBopr{M B BoAe. Teunepamypa nno*reHun.Orcono "C. 30 Meru.nnarrbMrrroJrear. (M.u. 268,43).Merul (92)-rexcaAex-9-esoar. C17H32O2. Merznosrrfi a$np 9-rercaAerlesonofi KrrcJrorbr. Xerrosarar )Kr4,rIKo crb. flpaxruuecKnHepacrBopr{MBoAe, B cMerxrrBaercssraHonoM s$npou. c u d,, . Ororo 0,876.
ft, .Oxoto 1.451.
20

20

l1l

rl
ii ;1

MerurnaparnApoKcn6eHsoar. C6H4OHCOOCH3. 152,14). Mern.rrrrapa6es. QVI.na. Merur-r,l-ru4porcu6eH3oar. Mern;ronufi e$up ilaparr{Aporcu6eHsofisofi xucnoru. Eelrrfi Kpr{crannr4.{ecxufi ilopotuoKrlu 6ecunerHbre Kpucrannbr. pacrBoprrM BoAe, O.ieHrMaJIo pacrBopr{M cflEpre96 % r4MeraHo.rre" B JrefKo B

EE

Teunepamypa nrarreHun.Or I25 to 128'C. (M.r. 102, 18).Llzo1yrunlaerurxap6llHoJr. C3H7(OHXCH3)2. 4-Mern.nnenraH-2-o"rr. rHafr neryqat )KrrAKocrb. llpospauHar, 6ecqee , ra c Pacrnopul,r BoAe, B cMelrrllBaercfigraHoJroM aQnporr,r. d]i . O*ono 0,802.
tlr, . OKoJro 1.411. KuneHufl. Oxolo I32"C. Teunepamypa (M.*. 100,I7). I -Merprnnrrepa3l4H. Mernrnnilepa3rrH. CsH12N2. crb. EecueerHaqxu.IIKo CnreuHnaercr c uoAoil I{ cnlrproM 96 %.
20

d,i . o*ono 0,90. n,i .Orcolol,466. KLtneHutt Oxono 138"C. Teunepamype I7 C1 4-(4-MeruJrrrurepnAnHo)nupHgun.rHroNz.(M.rur. 6,26). llpospavHarxr4AKocrb. n;i . Oxoro 1,565. (M.r"r.74,I2).l4zo6yruttonuficrplpr. (CH3)2CHCH2OH. 2-Meru.nnporlaHorr. 2-Merrannponan-I-or. llpo:pavHax,6ecqnerHat)KI{AKocrb. co B cMellrlaBaerct ciluproM96 % u rSupovr. Pacrnopuru BoAe,

dii . onono0,80.
H " . O r I , 3 9 7r c 1 , 3 9 9 .
Teunepamyp(tKuneHun Or<olo 107'C. Or Tennepamypuarc npedenbrnepezoHrcu. 107 ao 109 "C; Aonx{Horepel'oHtrbct He MeHee %. 96 2-Mern.u-2-upouanol. (CH3)3COH. (M.t"r. 74,12). 1,1-lnuerrln3rl4rloBbIficnupr. mpem-Byruno errfr cnl4pr. flpospauuar, 6ecqrerHat xI4AKocrb uIrr4Kplrcrannuq ecKat Macca. Pacrnopul,rB BoAe,cMelrll{Baerctco crll4proM96 % u e$uporr,r. Orono 25 "C. TeunepamypasameepdenaHufl. 'C; Or Teunepamypuue npedenu nepe?oHrcu. 81 Ao 83 AonlKHoneperoH{rbct He MeHee %. 95 29 Meru.ncreap ar. C I 7H35COOCH3. (M. rur. 8,49). MerunorraAeKaHoar. o Ct9H38O2.Onpe4e.ueHr{e ragoeofr npoBoArr MeroAoNr Co4epxnr He MeHee98,0 xpoMarorpa|nu. xenroro IIBera. KpucrarruqecKaq Macca6eroro I4JIX e$upe. PacrnoprauB crupre 96% H rlerponefiuorr,r 'C. TennepamypannozneHun.Orcoto 38 Meru.urprrAeKauoar. CH3(CH2)I I COOCH:. (M.ru. 228,36). Merunosufi e$up rpu.uexanosoftKLIcJIorbI. IIBera )KI4AKocrb. fl EecqserHa vrrrvcna6o )KeJrroro Pacrnopul,rB ctrl4pre96 % u rlerponefinou oQvpe.
l5

d1i. Oxooo 0,86. n'i,. o*onor,441.

TeunepamypamaBneHun.Ot<olo 6"C. MerunrpnKo3aHoar. CH3(CHt2 l Coo CH:. (M. ru. 3 68,62).Merznosrlfi eSraprpzxogaHosofiKucJrorbr. Co4epxur He MeHee99,0 Yo C24H4BO2. Kpncralnu 6eloro rlBera. flpaxrnvecKr{ HepacrBopt4M BoAe,pacrBoprrMB reKcaHe. B Teunepamypenna*neHun.Or 55 ao 56 "C. Mernn$eHrrrloKca3onr.r6eHson.C26H2oNzOz.(M.,ur.392,44).1,4-Eucl2-(4-rr,rerun5-$ennn)orcasolul] -6eHsor. Menxufi nopolxoK 3eneHoBaro-xeJrrororlBera c cunefi $nyopecqenqlrefi r4Jrr,r MeJrKr{e Kpr4cTaJrnbr. Pacrnopuna crrvpTe96 Vo,yMepeHHo B pacrBopr.rM Kcr4JroJre. B Teunepamypa nna*reHun. Oxono 233' C. Merzn$enunoKca3onnn6eu:on, vclonb3yelrufi 4rx )KrdAKocrHofi cqHuru rrrflr\vwt, 6rnr co orBercrnyrorqefi creneHrr qrrcrorbr. AoJrx(eH Mern.nQraJrenH. Cvr. (DranenHonrrfi nypnyponufi .

Mernrue.n,rro.nora 450 flpe4crannser o6ofi qacrrrrrHo uerrznupoBaHHyro c OrleJrJrrono3y.

Eelrtfi, Irnil xeJlTonaro-6erutrt,utu cepoBaro-xenrurfi nopolroK, trJrurpaHyJrrr.fillpocKonr{qHanocne Bbrcyrxr4BaHr,rr. IlparruuecKn HepacrBopl{Man ropxvefi BoAe,arleroHe, gTaHoJre, eQupe r.rroJryoJre, pacrBopt4MaB xoJroAHofino4e, o6pasyx KonJrot4AHbre pacrBopbr. HonuuanuHafl BnsKocmu.450 ufla.c. Mern.rrqr.rHHaMar. C6H5CH:CHCOO CH3. (M. u. | 62,19). BecqserHHe Kpr{craJrnbr. flpaxrz.recKl4 HepacrBopktMB BoAe,JrerKopacrBopt4Mcflrrpre 96 % r4pacrBopr,rMB e$zpe. Ll, "Orono 1,56. Teunepamypa KuneHun Oxono 260"C. TeunepamypanilanneHua. 34 rc 36 oC. Or

MerH.nernJrmeroH. COC2H5. ru.72,1l). 3rzruerzJrKeroH.2-ByraHou. (M. CH3 flpospa.urar,6ecqnerHar,BocrrJraMeHrroularcr )KrrAKo crb. oqesr rerKo pacrBopr{M BoAe, B cMerrrrrBaercr cnr{proM % u e$zpou. co 96 d,, . Oxoro 0.81. Teunepamypa KuneHufl. 79.qo 80 "C. Or Mernnrfi Ko3anoar.Crr.r. MerrrJrapaxrrAar. MeroncuQeHuJryr(cycnar KrrcJrora. C6H4OCH3 OCOCH3.(M. u . | 66,17). -QeHr.rnyKcycHrur (RS)-2-Meroxcu-2 Kr4cJrora. Kpucranlu.Iecrufi nopolroK 6enoro rlBera unr,rKpr4craJrJrbr 6enoro nnu noqrn 6eJIOrOUBeTa.

pacrBopr.rMa vrr,repenuo pacrBopltMa crrrrpre % n e$upe. B BoAe, JrerKo B 96

Te.unepamypama*reHu* Oxono 70 'C. Xpauxr B rrpoxnalHoM Mecre. MerorcnQeHrrJryKcycHofi KncJrorbr peaKTuB 2,7 r rnreroxcn$eHuriyxcycnofi pacrBopqrcr s 6 N,rrI0 % pacrBopa rerpaKr{cJrorbr Merr{JraMMoHr,u rr4ApoKcr4Aa rtpu6avttxtot 20 MJrDTaHona. u Xpauxr B rroJrrrgrrrJreHoBoM xourefiHepe. Mero.u. (4-CH3NHC6H4OH)2' H2SO4. (M.rnr.344,4).Ilapa-(ueurrauuno)$euona cynrSar. BecueerHrreKpucranrrbrvtrvt 6enufi Kpr4crannxqecrzfi [opo[roK. Pacrnopnna xonoAHofisoAe (5:100), n ropxuefi noge (16,6:100),pacrBopr.rM 3raB B
HOJIC.

TeanepamypantazreHun. O"r 250 ao 260 "C c pa3no)KeHr4eM. MuosNrHH.CeH10N2.(M.*. 146,19). 3-(4,5-[urr.r4po-3H-tuppo*2-un)nnpu4vH. EecqeerHHeKpracrannbr. flparrnuecKr{ HepacrBopr,rM BoAe,pacrBopr,rM gTaHone eSupe. B B u Tet'tnepamypannaBneHun.Oxolo 45 "C. Mnpncrn.nonufi crrrpr. CH3(CH2)I2CH2OH. (M.r"r. 214,40). 1-Terpa4eKaHon. 2-OrcurerpaAeKaH. Jlucroqru, KprrcraJrJrrr3yrorrlrle r433TaHona. cr pacrBoprrMB gTaHoJre, pacrBopr4un sSnpe. O.reHr MaJro d,. . Oxono 0.823. Tentnepamypa nra*reHun. Or 38 ao 40 "C. Mupucrnqnn. Cl1Hl2O3. (M.*. 192,2I). 5-Annun-1-ueroxcu-2,3-ruerunenAuorcu6eHsor. 4-Merorcu-6-(npo-2-euul)- 1,3-6ensoAr{oKcon. BecqserHas ilrv c xeJrroBarbrMorrenKoM MacJrrHtrcrar )Kr.t,qKocrb. pacrBopr,rM sTaHoJre, IlparruvecKll HepacrBopktM BoAe,MaJro B pacrBopr{Mn e$upe, B cMelrrprBaeTct ToJIyonoMrI KcrlnonoM. c

dii . o*ono 1,144. nll . Orcono 1,540. Teunepamypa KuneHun. 276zo 277'C. Or Teunepamypa nnasneHun. Oxolo 17 3'C.
XpaHrr B npoxnaAHoM,3arrIHxIeHHoM cBera Mecre. or

-MerrrrreHorra-6-gueH. p-Mupueu. C roHro. (M. r"r.L36,23).7-MerNn-3 1,

Macrxuucraf, xeJrro Barafl )Kr4AKo c rrprrrrHbrM 3a[axoM. crb flpaxtuvecKll HepacrBopr{MB BoAe, cMerrrr.rBaercr crrHproM 96 yo, pacrBopr.rMB co e$zpe pIyKcycHofi rucnore reganofi, pacrBopax rr4ApoKcr{AoB ulenorrHbrxMeriurJroB.

dii . O*ono 0.794.

Z,, . OKoro1.470. Xponratorpa$uue cxax qrlcrora B-rrarapqeua, [crroJrb3yeMoro ragosofrxpoMarorpas o. 90,0 $ur,r,4orxna 6rnr HeMeHee Mo.nercy.rrqpnoe c[To MolercynrpHoe crlTococrorrr u3Harpufr, iurroMocr.rJrr.rKara. BuArrrapr{KoBpa3Irlrraeer c MepaMr.r 0,4 HMr.rAr,raMerpoM rvlrl.r,. nop 2
20

EEq

i,l i:

peaKTrrB Mo,r n6AeHoBaHaArreBbrfi B crarane BMecrrrMocrbro150 un cMerxr.rBaror pacreprbre B nopoilroK 4 | aMMoHlrt MonH6Aara v 0,1 r au*roHvr BaHa!\ara,ilpv'aF..]Iqror70 un BoAbrr{ rer{epes HecKoJrbKo peMerrrr4BaroT cTeKJrrHHofr rlanoqKofi Ao pacTBopeHr4s. Mr{HyT pacrBop, K KoropoMy rpu6anrsror 20 rvt .qonxeH nonyqrrbcr rrpo3paqHbrfi a3orHofi KrrcJrorbr KoHrleHrpr.rpoBaHHofi 4ono4.rrro6beM pacrBopa noAofi Ao u 100 lrn. Monn6geHoBaflKr{cJrora.H2MoOa. (M.u. 161,97). Eenrrfi utm 6e:nwi,t xeJrroBarbrMorreHKoM rropoilroK. c Maro pacrBopuMaB BoAe;pearupyer c pacrBopaMr,r nlenouefi; pacrnoprrMaB fopnueir cepuofi Kr.rcnoreKoHrleHTpuponauHofi . Mo.uoqnan Kr{cJrora.CH3CHOHCOOH. (M.u. 90,08). BecqnerHagfinu cnerKa ]KeJrroBarar, cupoiloo6pasHar xr{AKocrb. CN{enrueaercfl no4ofi, cnuproM 96 % n eSupou. c d" . Ororo 1.205. Moro.rHofi rcnc;roru peanTrrB Pacrnop I. K 60 MJr MoJroqHofi rucnorrr npu6annno'r 45 Mn pacrBopaMoror{HofirucJrorbl, HacbllueHHoro6es HarpeBaHr.rr cyAaHoMKpacHbrM u npe4napr4TenbHo G orSunrrporaHHoro. Mono.{Has Kr4cJroraHacbrulaercr MeAneHuo 6eg HarpeBaHr.rr, rro3ToMyBcerAa neo6xoAr.rrvr g6uror Kpacr.rreJrr. u Pacrrop IL foronqr 10 run HacbrrrleHuoropacrBopaannrrr4na u $unrrpyror. Pacrrop IIL 75 Mr Karuq itoguga pacrBoprrcr B BoAer4AoBoA-f,r reM x<epacrBopr.rrerleM Ao o6beMa70 un. K nonyveuHoMypacrBopy upu6aeraror 10 rr,rn cnr4pra 96% u 0,1 r itoga, Bcrp{x[Baror. CMerrusarcr pacrBopbrI raII, npu6aumor pacrnop III.

i; rdill .:l*i
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(M.u. 87,12).TerparngpoMopQonHH. CaHeNO. 1,4-orca3uu.

EecqeerHa-f,, rr.rrpocKorlrlquat, BocnJIaMeHflroilIaflcfl, xl{AKocrb.

ii,

Pacrnopuu BoAe crrr{pre %. B r4 96 dii .Oxotro1,01.

Teunepamypuute npedenbrnepe?oHrcu. 126 lo 130 "C; AoJrxHorreperoH.rrrbcr Or He Meuee95 %. Xpanm B Bo3AyxoHerrpoHrarlaeMoM xourefiuepe. MoqesuHa. CO(NH)2. (M.vr. 60,06). Kap6al,ru4. Benrrfi Kprrcrannr4qecxufi ropo[roK ur[ 6ecqeerHbre Kpr{crarurbr. O.IeHr JrerKopacrBopr,rMa BoAe,pacrBopnMa B crrrpre 96 o , npaKTuqecKr{HepaB cTBOpr{Ma MeTr.rJreHxnop4{e. B MypanruHafl KucJrora 6ernognas. HCOOH. (M.nr. 46,03). Co4epxur He MeHee98,0 o/o(u/rr,r)CH2O2. Eecqner:Har, npo3paqHafl)Kr.rAKo B rr grrBaer Koppo3r{ro. crr. CMeurusaercs c so.qofiu crrlproM 96 %.

lrr
iil

:l1,

dii .o*ooo 1,22.

MypanrnHafl Kncrrora.HCOOH. (M.u. 46,03).99,7o u 85 o/o HCOOH. Becqsernar,npo3paqHar xr{AKocrbc pe3Kr4M 3anaxoM. CnaeurveaercrnoAofiv cnrrproM %. c 96

Cu. Aunronnil nyprypHooxnc.rrrrft. Myperccng. Mrrunxxosucmtfi aHrpIAplIA. Msrrursra(Ill) oKcItA.As2O3.(M.*. 197,84). [u'
MbrrrrbrKa TprloKcI4A. Macca. Kpucrannuqecxr,tfinopoilroK uttu 6enas, Mano pacrBoprrMB BoAe,pacrBopltM B Kunsrlefi noAe. Pearupycr co ucnoqalavl LI xap6ouaroM Harpxq. Harp eArcufi.Harpux ruApooKrlcr. Cnr. Harpun rlrApoKcnA. Harpnfi. Na. (A.na.22,99). Merann, Ha cBexeM cpe3eLIMeer6lecrxqyro cepe6pucro-cepyronoBepxHocrr. Ha Bo3Ayxe6ucrpo rycKHeer v noJrHocrbrooKr,rcnflercfl Hurpurt oKcr{Aa,roropufi Ao BoAoEypHo pearr4pyer c soAofi c o6pasonaHl4eM rrpeBpaqaercr B Ha'rprrflrap6onar. poAa r{ Ilarpvfl. fl,rApoKclrAa. Merrrc PacrnopuN{s 6essoAuoMMeraHoJre o6pa:onaHlleM BoAopoAau Harpvrfl. HepacrBoplrMn a$upe n nerpoJrefinou a$upe. rrara,npaKTLItIecKI{ napaQune (Hanpul,tep,B KepoXpanxr B lleTpoJlefiuovte$upe [nI4 xIrAKoIra cxue). Harpnr a3ng. NaN3. (M.r"r. 65,02). 6eloro IIBera. Kpucrannu.Iecxufi noporuoK lrnu KpI{cranJIbI HepacrBoB Jlerro pacrBopr.rM BoAe,Mitrlo pacrBoplrM B cnl{pre 96 Yo,rIpaKT}IqecKH pr.rM s$npe. B Harplrfi a3orHoKrlcnufi . Crrl. Harplrr HtITpar. Harpnfi a3orl{cronuc.nrtil. Cu. Harprrfl HlITprIT. Harpnr apceHlrra pacrBop 0,50 r uuurrma(Ill) oxcuaa pacrBoprror B 5 ur pacrnopa Harpl{t rr{ApoKcv[a pa3rn4porap6oHara rr AoBoAtr o6reu paBeAeHHoro oA,upz6anlxror 2,0 r Harpvrs, 8,5 crBopaeoAofi.qo100,0vrn. Harpnr acKop6ara pacrBop pacrBoprrcr s 20 rvrnI M pacrBopa Harpl{t rl{Apo3,5 r acrop6HHonofi Kr.rcJrorbr KCr.rAa. rlepeAIrcrIoJIb3oBaHr{eM. lorosqr HenocpeAcrBeHHo Harpnn allerar. CH3COONa .3H2O. (M.r"r. 136,08). Harpvfi yKcycHoKl4clufi 3-soAHHfi. Harpufi yKcyclroKucrsIfi , rpl,Irl{Apar. BblBerpl4Balorct B TenJIoMBo3Ayxc. EecqserHHe ilpo3paqHbreKpr4crarrJrbr, pacrBopl{MB BoAe,pacrBopuMB cnl{pre 96 %. O'reHr JrerKo Harpnn arlerara pacrBop l0 oh. 10 r narpus arlerara pacrBoptrcr B BoAcIr AoBo4xr o6reu pacrBopa no.qofiao 100 un. Harpnr aqerara pacrnop 5 M BoAbI 410,00 r Harpr4rarlerara 6essoAHoropacrBoprror B AocraroqHoMKoJIlIrIecrBe upas6awtsrcr o6teM pacrBopa soAofi lo 1000,01rn. Harpnr arlerara pacrnop 2 M BoAbI aUerara 6essoAHoropacrBopror B AocraroqHoMKoJILIqccrBe 164,00 r Harpr4q upazflar.nsror o6reu pacrBopa soAofi ao 1000,0 ul. Harpur arlerara pacrBop 0r1 M u 1,36 r Harpru aqerara pacrBoprrcT B BoAen ruepnofiron6e BMecrl4Mocrblo100 rran AoBoArr o6relr pacrBopa eolofi Ao MerKIr.

Harpnr auerar 6emognrrfi. CH3COONa. (M.n. 82,03). Becqnernrre Kpr{cranJrbr r.rJrrr rpaHynbr. Oqesr JrerKo pacrBopr.rM BoAe,yMepeHuopacrBoprrMB cnupre 96 %. B Ilomepn B .L4acce npu rbtcytuunaHuu.He 6oree 2,0 oh. Olpe4eneHue rrpoBoA.rrr rrpr4 reMreparype or 100 ao 105 "C. Harpun 6ensoar. C6H5CooNa. (M.u. 144,11).Harpuii 6ensofiHoxvcmrfi. Fenufi Kpr{crannnqecrnfr [opolxoK. Pacrnopuna Bo.qe, pacrBopr4M cnprpre96 % [pr4 HarpeBa*Hr4. B B Harpur 6nnap6oHar. Cnr. HarpHn rrrApoKap6oHar. Harpnr 6ncy.rrrQnr. Harpnfi cepHncrorcnc.nrrfi. cu. Harprq rnApocy.nr$nr. Harpnr 6yrancy.nrQoHar. CaHeNaO3S. (M.n. 160,16). Kpucra-irnu.recKufi noporxoK 6eroro rlBera. Pacrnopzu B BoAe. TeunepamypannazreHun.Botee 300 "C. Harpur BlrcMyrar. NaBiO3. (M.r'1.279,97). Co4epxur He MeHee 85,0 YoNaBiO3. llopourox )Kenroro I,III4xeJlToBaro-Kop[qHeBororlBera. MeAlenuo pa3naraercq rloA eNa lrnv BbrcoKo re rr,rnep fi x efi crs pr BJrarr4 arypu. llparruvecKr4 HepacrBopr4M xonoAHofieoAe. B Harpnn no.rrrQpauar. Na2wo 4'2H2o. (M.*. 329,87). luuarpuxnonrspaur, AVrrlrApar. Harprar eo.nrSpanoBoKl4cnbr 2-nogustfi. Harpux nonrspauoBoKr{cnbrft, Ikrir rHApar. Kp ucra.iu u\e crcuia nopoilroK 6eroro rIBera uru 6ecqr erHbreKpr.{ crannbr. J-lerxopacrBoplrMB BoAec o6pa:onaHrreM flpo3par{Horo pacrBopa, npaKTur{ecKr4 HepacrBopr4M cnr4pre96 %. B Harpnr reKcaHcyd'mQonar. (M.na.188,21). C6H13NaO3S. liopourox 6eloro r,urrr roqru 6e;roro uBera. ,rierxo pacrBopr.rM BoAe. B Harpnr rerrraHcyrn$oHar. C7H15NaO3S. (M.u. 202,24). KpzcralluqecKar Macca6eroro HJrr{ iloqrr.r 6enoro uBera. Ierxo pacrBopr.rM BoAe,pacrBopr4M MeraHone. B B Harpur rerrraHcyd.rrQouar,MoHortrApar. C7H15NaO3S. HzO. (M.r. 220,26). Co4epxur He MeHee % C7H15NaO3S, nepecr{ere Sesno4Hoe 96 n ua BerrlecrBo. Kpucrarru.recxlrfi rropoilroK6eloro uBera. PacrnopuruB BoAe,oqeHbMaJIo pacrBopr,rM oraHoJre, B npaKTurrecKr{ HepacrBoprrM B rQrape. " Boda. He 6onee 8 %. OnpeAeneHr4e rrpoBoArr ns 0,3 n Harpnr rrrApoKap6onar. NaHCC3. (M.r"r.84,01). HanpuizAByyrneKrrcrrIfi.Harpun 6urap6onar. Benufi Kpkrcrannuqecrufi [oporroK. Pacrnopurr,r BoAe,[paKTuqecKr{HepacrBopr{M crnrpre 96 %. B B oh. Pacreop 42 rln. Harpur rrApoKap6onara pacrBop 4r2 Harpnr rnApoKap6onara pacrnop 5 7o 5 r Harpur ru4porcap6oHarapacrBopnor B BoAe14AoBoArr o6repr pacrBopa nogofi :o 100 nn.

Harpnn ruApor(crl. NaOH. (M.r"r. 40,00).Harp eaxuir.Harpnx oKcHA. HarputruApooKt4cb.

Eelue KycKI4 rtnu qlanvnApuqecKl4e rlanorrKn, r.rMeloulue Ha rr3JIoMe KpllcrilirJrr4qe-

cKyrocrpyKTypy;rr4rpocKonuqeH. O6paularrcfl c ocropoxHocrbro. pacrBoplrM BoAe; O.reHrnerKo pacrBoprrM crnrpre 96 oh,pacrBoprrM rJrr4B JIerKo B B qepLIHe; pacrBopr4MarleroHe a$lrpe. oqeHb MaJro B u pacrBop 30oh Harpur rrrApoKcnAa pacrBopnor B BoAer4rrocJreoxnox.qeHrlrAoBoArro6reu 30 r narput rnApoKcr4Aa pacrBopasoAofiao 100 Mn. PacrsopyAaror orcrorrbcr r{ npo3paqnyro )Kr.rAKocrb
cJII4BaTOTC OCaAKa.

Xpanrr B creKnqHHbrx cocynaxc pe3r.rHoBbrMu npo6rarr.ru. o/o Harpnr rrrApor(cuAa pacrBop 20 20 r Harput rI4IpoKcH.{a pacrBopr}orB BoAe r4.qoBoAsr o6reu pacrBopa reM )KepacrBopl4TeneM 100 vrl. Pacmopy Aaror orcroqrbcr u npo3paqHyro xrlAKocrb cJrr,rAo Balor.Xpanrr B creKJrrHHbtx cocyAaxc pe3r,rHoBbrMr4 npo6KaMv. o/o Harpur rnAporcrrAapacrBop l0 l0 r HarprarnrApoKcuAa pacrBoprror B BoAeH AoBoArro6reu pacrBopanoAofiAo 100 w. PacrnopyAaror orcroflrbcr x rpo3paqHyro )KlrAKocrb cJruBalor. XpaHxr B creKJrrHHbrx cocyAaxc pe3r{HoBbrMr4 npo6xauu. Harpur rrrApor(c[AapacrBop pa3BeAeHnufi oh 8rS 8,5 r uarpzt rvApoKcilp;apacrBoprror BoAe AoBoArro6renrpacrBopareM xe paB rr crBopr.rreneM 100rran. Ao Harpnr rrrApoKcrrAa pacrBop 10 M 400,0 I'HarpI,It rl,rApoKcr.rAa pacrBoprror B AocrarorrHoM KoJrr{trecrBe BoAbr, cso6oAsofi or yrnepoAaAr{oKcn.qa, pas6aBJrrror u o6renapacrBoparofi xe soAofi Ao 1000,0 un. Harpnr rnlporcclrAapacrBop 2 M 80,0 r Harpkrfl rI,IApoKcI{Aa pacrBopqnr B AocraroqnoM KoJrr,rqecrBe Bo,ubr, cso6oAHoft or yrJrepoAa.qvoKorAa,upas6aBJrrror pacrBopa o6reu rofi xe solofi lo 1000,0run. Harpun rrrApoKcrrAa pacrBop 1 M 40,0 r HarpuflrrrApoKclrAa pacrBopflIorB BoAe, cno6ogHofi yrnepoAa or ArroKcv4a,vl pas6amxrorreM xe pacrBopr{reJreM 1000,0rran. ao Harpnn rnApoKcr.rAa pacrBop 0r2 M 16,0r Harprrfl pacrBoprrorB AocraroqHoM rrlApoKcr,rAa KoJrr{qecrBe BoAbr, cno6o4sofi or yrnepoAa ArroKclrAa, paz6aBJrrror n o6reu pacrBopa rofi xe no4ofi ao 1000.0na:r. flarpur rnApoKcnAaMeraHonunrfi pacrBop 40 vr Harpkrfl pacrBopsrors 50 MJr rrrApoKcl4Aa BoAbr, ronyqeHHrrfipacrnop oxnax{u rtpuOannxror MJr MeraHoJra. 50 Aaror H arpnn rrrApor(c[AapacrBop KoHrleHrpuponanHrrfi 42 r narput rrlApoKcvrp. pacraopflrorB BoAe roBoA-sr u o6reu pacrBopareM )r(epacrBoprrreneM 100vrn. Ao Harpnn rr,rApoKcrrAa crrrpronufi pacrnop 10 o . 100rh n cnup're96 oh. Harpnn rnApocyJruQur. NaHSO3.(M.rtl. 104,06). HarprEr6ucynrSur.

l ,

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EEA

Kpractannu.recrufi flopou]oK6eroro uBera.Ha nos4yxeqacrutrHo reprer cepbr Ar,roKnocreleHHo oKr4cJrrercr cynr$ara. cvrr\*r Ao Jlerxo pacrBoprdM BoAe, B B WepeHHopacrBopr.rM crprpre 96 %. Harpnr runo6pour.rrapacrBop 2A wl pacrBopalr'arpufl. r'rrApoKcr4Aa KoHueHTprrpoBaHHoro lln BoAbr rr 500 cMerrr[Balor Ha JIeAtHoit 6aue,, npu6aeraror5 ur pacrBopa6poua 14 ocropo)Kuo nepeMerrrr,rBaroT pacTBopeHur. Ao foronsr HenocpeAcrBeHHo uepeAr4cnonb3oBaHrreM. 'H2O. (M.*. 106,01). Harpufi Harpnr runoQocQnr. NaH2PO2 Soc$opnoBarrcrorracnrrfi. Harpufi Qoc$ranar,MoHorr,rApar. KpracrannnqecrufinopouroK6eroro rlBeranmt 6ecqnerHbre Kpr4craJrnbr. fiarpocroNUTIEH.

Jlerro pacrBopr.rM BoAe, pacrBopr.rM crurpre 96 %. B B XpaHxr B Bo3AyxoHenpoHrlrlaeMoM roHrefinepe. Harpux runoQocQr{ra pacrBop (peaxrunTlue). 20 r Harpur runoSocQurapacrBoprrcrn 40 MJr BoAbr. PacrnopBJruBaror 180 N{r s xJropldcroBogopo4nofi Kr.rcJrorbr KoHueHTpr4ponaunoi u ocraBJurrorsa24.r.llo ocax(BbIAenr4BrUr{XCrKpT,TCTULJTJTOB XnOpr4Aa Xfl.TAKOCTb HaTpr4{ CJrr.rBarOT OCaAKa. C A9HLTId

Pacrrop AoJrxeH 6srrr 6ecqserHrrM. XpaHm B creKJrrHHoM cocyAec rpr.rreprofi upo6rofi. Harpua rrrrroxJroprrra pacrBop KoHrleHrpnponann ufi Co4epxur HeMeHee rltu ne 6olee 30 r/n aKrr.rBHoro 25 xJropa. XzArocrr )KeJrroBaroro rlBera,LrMeer lrlerorrHyropeaKrlr,rn. Xpanm B 3arrlnqeHuoM cBeraMecre. or KonuqecmneHHoe onpedeneuue. Mn pacrBopaHarpvflrr,rnoxiropr{Ta I0 KoHrIeHTpr{poBaHnoro noMexraror MepHyro B ron6y BMecrr{Mocrbro rran, 100 o6reu AoBoA{T pacrBopanoAofiAo MerKrrr,rrepeMerrrrrBaror (pacrnop A). B ron6y.qnr rr4rpoBaHLII nocJleAoBarenbHo noMelllaror50 MJrBoAbr,1 r xarfiq ito1uqa, 12,5 rran yro pa3BeAeHHoit cycaofi Kr.rcJrorhr 12 ,l0 MJrpacrBopaA r{ rlrrpyror 0,1 M pacrBopoM Harpl4{ruocynr$ara, yrcnonb3yr KaqecrBe B r{H.ur.rKaropa pa1 MJr
cTBOpa KpaxMaJra. 1 rran M pacrnopaHarpilfl.ruocynr$ara coorBercrByer 3,546 Mr aKTprBHoro 0,1 xJropa. Harpna rurroKypoHar.CHO(CHOH)4COONa' H2O. (M. rnr. 4,14). Harpnx D-nrro23 KypoHar, MoHofr{ApaT. VuepeHHopacrBopr,rM BoAe,MitJro pacrBoprrMB cnr{pre 96 %. B

Kpucralnnqecrcufi rropolloK HJrr.r xJrorrbx6eroro prrr.rnorrrrr 6eroro rlBera. Jlerxo pacrBoprrMB BoAe,pacrBopr4M MeraHoJre. B Harpnn 4nrugpoQocQar. Harpua 4rrugpoQocQaro ArrrrrApar. Cna. Harpnn Qoco4noraMerqeHHbr 2-soait Qar ogno3aMelrreHHufi. Harpnfi QocQopHomrrcJrbrfi Hrrfi. Harpnn 4nrrgpoQocSar 6esnoAHrrfi. NaH2PO+. (M. rnr.120,02). llopouror 6eloro rlBera, rr{rpocKonr4qeH.

(2o/opawnop). tall . Ororo +21,5o HarpunAeKaHcyrnQonar.6H2NaO3 (M.rra C1 1 S. . 244,3).

Xpanrr B Bo3AyxoHenpoHlruaeMoM rourefiuepe.

Harpnr gnrn4po$ocQar,MoHorl{Apar. NaH2PO4'H2O.(M.rur. 138,02). pacnnbrBaroqnec{ Bo3Ayxe. Kpucra-'l.uu uilvrpaHyilsr 6eroro uBera,cJrerKa Ha Jlerro
pacrBopt4M BoAe,[paKTr4rrecKr4 B HepacrBoplrM cnr4pre96 %. B Xpaum B Bo3AyxoHerrpoHr{rlaeMoM roHreftuepe. Harpnx ArrrlroHrrr. Na2S2Oa.(M.vr. 174,10). Kpucrannuqecxufi noporxoK 6enoro unlr cepoBaro-6eroro rlBera; Ha Bo3AyxeoKr4cnteTcr. O.reHr JrerKo pacrBopr.rMB BoAe,ManopacrBopr{MB crrrrpre 96 %. Xpauxr B Bo3AyxoHerrpoHr{rlaeMoM roHrefi uepe. ' Harpun Ar{)rrrrrAnruorcap6alrar.C5H1sNaS2 3H2O. (M.u. 225,30). EecqnerHue vlwr 6eroro rlBera Kpr.rcrannbr. pacrBopr.rM BoAe,pacrBopr4M cnvpre 96 %. Bo4nufi pacrBop 6ecqserB Jlerr<o B sufi. Harpnr AoAerurJrcy.nrQar. Cna.Harprrfl JrayprrJrcymQar,3a zcKrloqeHlreMcoAep)ir.arrltfl,Koropoe AonxHo 6rrrr He MeHee99,0 o . EyQepuufi pa6o.rufi pacrBop AJrfl sJreKTpoQope:aB cr{creMe Harprq AoAerIHJrcy.rrrQar-norrr aKprrr au uAnuil re.nr (SD S-PAGE) 151,4r rpuc(ru4poKcr{Merul)auuuoMeraHa, n 721,0 r fJrrrqprHa 50,0 | laarpvfl naypuncyrr$ara pacrBop*or B BoAe r.rAoBoAflTreM )rcepacrBopr4reneMAo o6rerr,ra pa3BoArr soAofi n 10 pa: ra 5000 rr,rn. Herocpe4crBeHHo rrepeAIrcnoJIb3oBaHHeM rrepeMeilrnBalor. pH nonyueHHoro pacrBopaAonx{eH 6urr or 8,1 .qo8,8. EySepHufi o6parqonufi pacrnop (rcouqeHTpr{poBanuufi) Arrs srreKTpoQopesa B cucreMe Harpnfl AoAeulJrcy.usQar rroJrrraKprr.ualruAnrrfi reJrb

(sDS-PAGE) 1,89r rpuc(ru4poKcuMerrr.n)auzuoueraHa,uarpvfl rraypvilcynr$ara, rrar 5,0 r 50

6ponQeuonoBoro cr{Herovr 25,A Mn rnuqepvna pacrBop*or n 100 MJrBoAbr, AoBopH pacrBopa4o 6,8 xnoprrcroBo4opo4nofixvcnorofi KoHrleHrpxponaHuofi Aoll 4-rr BoArr noAofi Ao o6reua T25 wl EyQepnufi o6parqonufi pacrnop (ronqeHTpr{poBaHurrfi) AJrflsJreKTpoQope3a B cucreMe Harplrfl AoAeurrJrcy.nrQar- ro,'rrraKprrJraMnAHrrfire.nr (SDS-PAGE) yc.nonnfi AJrffBoccraHoBrrreJrbHbrx 3,78 r rpuc(rn4poKcr4Merv:r)auuuoueraHa,10,0 r Harpnfl AoAeunncyrr$ara, 100 vr 6pou$euonoBoro cr{Hero u 50,0 MJrrJruuepvHa pacrBopr}or e 200 Nar BoAbr. noryueHHoMy pacrBopy npu6avr'xror 25,0 lrn 2-uepxanrogTaHoJra, K AoBoAqr pH pacrnopa Ao 6,8 xnopucroBoAopoAuofi xucnorofi KoHueHTpr.rpoBaHrtoit u AoBo.qrr no4ofi Ao o6seua 250,0 un. Amrepuarr.rBHo B KaqecrBeBoccraHaBnr,rBarouero BeruecrBaBMecro 2-vrepranTooraHoJra Moxer 6urr r4crronb3oBar 4urkrorperrron. B grou cnyqae o6pa:qopacrBop roroBrr sHfi cneAyrcrrlt4 o6pasorra: 3,78 r M 6y$epurrfi -avruHoMeraHa, 10,0 r Harpufl AoAeur4ncynr$ara, 100 rvrr rpnc(ru4poKcr.rMerun) pacrBopnor s 200 nanno4rt. ,{o6pou$eHuJroBoroclrHero n 50,0 Mn rnr,rqepr{Ha BoArr pH pacrnopa Ao 6,8 xroplrcroBoAopoAHofi xucnorofi KoHqeHTpr4poBaHHofi r.r pa3BoArr soAofi Ao o6reua 250,0 MJr. HenocpegcrBeHHo rrepeA

prcIIonb3oBaHrreMnpu6aBnflror ArrrrrorpeI4ToJI Ao KoHeqHor KOHUeHTparil4vrI00 uM. (M.nr. 444,6). llarpun Aorcy3ar.C2gH37NaO7S. no Eera-flrrJrrrrorrrr,r 6e rras. croo6pa3Haq Macca vlrkr xJIorIb{; rrlrpo cKoIIFI eH. VuepeHHo pacrBopr4M B BoAe, JrerKopacrBopl{M B cllllpre 96 o/ou weruneuxnopr,rAe. Harpnn fiolul. NaL (M.u. 149,89). rvrpocKorll4lleH. nopouroK ranu6ecqserHbreKplrcruulnbl; Eenufi Kpr4crannr4qecxufi B Oqesr nerKo pacrBoptrMB BoAe,JIerKopacrBoplaM crllapre 96 %. ' 10H2O. Harpufi yrneKlrcrrblfi 10-soaHarplrr rcap6onar AeKarrrApar. Na2CO3 nrrfi . Harpufi yrnenxcnufi , AeKarl4Apar. Eelrrfi KprrcraJrnr{qecxnfi[oporroK urr.r 6ecqnerHblenpo3paqHbleKpl4crannu. Jlerro B pacrBopr{MB BoAe,[paKTI4qecKI.I HepacrBopLIM cnupre 96 %. (M.rur.105,99). luuarpun rap6onar. Harpnr rcap6ouar deseoAHrrfi. Na2CO3. llopourox 6croro IIBera, rurpocKonl{qeH. B HepacrBopr{M cnl{pre 96 %. Jlerxo pacrBopllM B BoAe,[paKTLIqecKI4 reMneparype oKono 300 "C AoJIXHa6urr se Ilorepx B Macce[pr,r BbrcymkrBanr4vr[prr 6onee I Yo. xourefiuepe. Xpauxr B Bo3AyxoHenpoHr4llaeMoM Harpnx rap6ouara pacrBop t0r6o . Pacrnop 106rh Harpr{txap6ouara6esnoAHoro. Harpna rcapoonara pacrBop 2 o/os Harprrfl rrIApoKcrIAe rplApoKcll.qa. Pacrnop 20 rlnHarpus. xap6ouara 6earo4noro e 0,1 M pacrBope laarpr4fl, o/o Harplra rap6oHara pacrBop l0 10 r uarpux rap6ouara 6egsoAHoropacrBoprror B BoAeH AoBoArr o6teu pacrBopa soAofi ao 100 rr,rn. Harpur rcap6onara pacrBop 0105M pacrBoprror B BoAeB vepnofi ron6e BMecrIrMo5,3 r uarpur rap6onara 6egnoAHoro crbro 1 r z AoeoAsr o6rerr.rpacrBopa soAofi Ao MerKIr. pacrBoptlor HarpHr rcap6onara pacrBop 2 o .20 r Harprrflxap6onara 6essoAHoro e 1 marpe BoAbr,cso6oAHofi or yrnepoAa 4volrlcv4a.

(M.u. 404,0).Tpunarpnt reKcaHl'Irpollarpun KobarbruHrrrprlr. Na3[CoQ.{Oz)o].

ro6anrrar(Ill). llopouror opamreBo-x{eJlTofoIIBera. B Jlerxo pacrBoprrMB BoAe,ManopacrBopl.{M cnupre 96 %. o/o Harpur Ko6arbrrHrrrpllTa pacrBop l0 Pacrnop I 00 r Harpvfl ro6anrrptrr4'rpilTa s 1 r noArt. /lorosqr HerrocpeAcrBeHHo [epeA r.rcnoJlb3oBaHl4eM. rloJryrrlApar. Na3[Co(NOz)o] ' 0,5 H2O. (M.*. 412,99). Harpua xodamrnnrrrpnr Harpnx reKcaHnrporo6anrrar(IlD 0,5 no4nufi. Harpun reKcaHl4rpoxo6anrrar(Ill), feMr4fr4ApaT. OpaHxeeo-xen'rufi loporxoK. Pacrropulr B BoAer4B Kr4cJlorax. Harpnn xodanrrnHrrrprrra pacrBop 20 o 10 r narpns ro6anrrkrnvrrpura noJryrrrApara pacrBop{ror e 50 MJIBoAbI,ecml seo6xo.qr4Mo, Sunrrpyror.
@

Harpnr JIaypllircyJlrQar H3 AoAeIIuJranKrrncynr$aron, cocrotrlnx B ocHoBHoM rl.utpufl, Cuecr Harpr4eBbrx (M.u . 288,37). cyrr$ara C12H25NaOaS. Co4epxur He MeHee 85,0 % :aarpyrr anKl4ncyJrb$aron, paccqnraHHblx KaK C12H25NaOaS. -xenrrrft [opoilroK I'III{ KpI'I craJIJIbI. cBerJIo Eenrrfi r.rJII4 olaJrecqlrpyrcqero pacrBopa, yMepeHHo B JIe6o pacrBopr4M BoAec o6paoonaHueM pacrBopr{MB crlnpre 96 %. Harpnn mera6ncy.nrQnr. Na2S2O5.Harpuitnl4pocepHplcroKllcJlblilHarpur, ilupo-

cynrQur.
rovrl,I 6enufi Kpl{crann[qecxnfi noporloK. Fensrfi r,rJlu pacrBoprlMB cnl{pre 96 %. Jlerxo pacrBoprlMB BoAe,yMepeHHo Harpun MeraHcyrlrQonar. CH3SO3Na.(M.ru. I 18,08). Kpncran.nuqecrufi rropolxoK 6eloro IrBera, rllrpocKorlvqeH. Jlerro pacrBopl{MB BoAe,pacrBopklMB cnupre 96 %. rourefiuepe. Xpauxr B Bo3AyxoHenpoHLtlraeMoM Harpnn ueranepfioAar. Cna.Hatpua nepfiogar. Na2MoOa '2H2O. (M.r"r. 241,95). fiunarput' ruonv6Aar, !.krrlrHatpur rvro.ulr6Aar. apar. Harpufi uonu6AeHoeoxzcmrft ' Kpucranluqecxufi noporxoK 6enoro rlBera ur[ 6ecqserHbleKpI{crtuIJIbI. Jlerro pacrBopl{MB BoAe. (M.r"r.260,19). HarpHr 1,2-uaSHarpur HaQroxnnoncy.nrQonar. C1sH5NaO5S. roxunon-4-cynrQonar. IIBeTa. oT AO KpuCrallu.Iecrzfi nopOIuOK XeJITOTo opaHXeBO-xeJIToIo B B Jlerro pacTBopI.IM BoAe,npaKrr{qecKllHepacrBopl{M cnupTe 96 %. Harpnx HHrp ar. NaNO3. (M. r"r.84,99). Hnpui't asorsoruclufi . KpIrcraJIJIbI, flopouror , HJrLr fpaHynbr 6eloro rlBera, Hru 6ecqserHble,npo3paqHble pacnnbrBaloqvect Ha Bo3,uyxe. pacrBopllM B cnupre 96 %. Jlerro pacrBoplrMB BoAe,MaJIo rourefruepe' XpaHrr B Bo3AyxoHenpoHl{uaeMoM Harpnn HrTpHT. NaNO2. (M.*. 69,00). HaTpui,ta3orrrcroKuclsrft. fpaHynHponasHufi noporroK 6eloro rlBera IIII,I Kpl{crarruqecKl4fi nopouroK cJrerKa xeJrroBaTofouBeTa. Jlerxo pacrBopl{MB BoAe. oh. Pacrnop 100 r/n. Harpnr HI{TprITapacrBop 10 nepeAr{cnoJlb3oBaHr{eM. forostr HenocpeAcrBeHHo oh. Pacraop 2 rl* Harpnn HrlTprra pacrBop 0r2 nepeA I{cnoJIb3oBaHI'IeM. foronsr HenocpeAcrBeHHo Harpnn HrrrporpycclrA. Na2[Fe(CN)sNO)]' 2H2O. (M. iut.297,97). guru4par. Harpur neHraIII4aHoHIdrpo3I4JISeppar(III), IIBel a. KpacHoBaro-KopI4qHeBOro [Iop ourox I{JIHKp}IcraJIJlbI B Jlerxo pacrBopl4M BoAe,Miulo pacrBopnM B cnl4pre 96 %. oh.Pactnop l0 r/n' Harpun HrrporpycclrAa pacrBop 1' Harpur HurponpycclrAa oKltcJreHurrfi pacrnop o% 10 r HarpHt Hl{rporpyccilra pacrBop.f,tors 100 MJIBoAbI, rtpvtflar.nnror5 rran3

il

pacrBopa ld.aJtlrfl, nepMaHraHarakr2 rr,rn10 o/opacrnopaHaTp]/lL rr{ApoKcr{Aa. flonyqenHyro cMecb QrEnrrpyrorr4BbrAepxusarcr24'a. -2wec. CpoxroAHocrr4 Harpnr oKcaJrar. (cooNa)2. (M.r. 134,00). Harpnfi ulaBeJreBoxucrufi. Kpzcrarunqecrnfi noporuoK 6eloro rlBera. Pacrnopnu B BoAe,rpaKTlrrrecrrrHepacrBoprrM crrlrpre 96 % u e$npe. B Harpna oKraHcyJrsQonar.C3H17NaO3S. (M.ru. 216,27). Co4epxur He MeHee % C3H17NaO3S. 98 Kpzcralnuqecrufi nopoilroK r4Jrrr xnorrbs 6eroro Hrpr noqru 6e;roro uBera. Jlerxo pacrBopr.rM BoAe,pacrBopr4M MeraHoJre. B B Harpnn oKrrrJrcyrrrQar.CsH 1TNaOaS. (M.u. 232,27). Kpncrannu'Iecxzfi rloporxoK IrJIlr xJronbq 6eroro rrJrrrrroqrn 6eroro uBera. Jlerro pacrBopr4M BoAe,pacrBopr4M MeraHoJre. B B Harpnn rreHraHcyrnQonar. CsHr 1NaO3S. (M.rr. 174,19). Tnep4oe KprrcrannuqecKoe BerlecrBo 6eloro rlBera. Pacrnopnu B BoAez cru{pre 96 %. Harpur nepfio4ar. NaIOa. (M.rur.2I3,89). Harpur uerauepfiogar. Co4epxur He MeHee99,0 oh NaIOa. Kpucraruru.recxufi noporxoK r{ntr Kpr,rcraJrJrbr 6eloro rlBera. Pacrnopurvr BoAerI MHHepanbHbIX B Kr4cJlorax. Harpnn nepfiogara pacrBop 1,07 r Harpufl nepfio4ara pacrBopsrcT B Bo.ue, npn6aunor 5 ur cepnofi Kr4cnorbr o/o pa3BeAeHHofi 9,8 u Aoso1qr o6reN{pacrBopa eo4ofi 4o 100,0 rr,rn. loroe-sr HenocpeAcrBeHHo rrepeAvcnonb3oBaHzeM. Harpun repxrlopar. NaClOa 'HzO. (M.r. 140,46).Harpufi xnopHoKrrctrsti,r, MoHoflrApar. Co4epxr.rr He MeHee99,0 oANaClOa ' HzO. Kpucramrr 6enoro rlBera, pacnnbrBaroquecr Ha Bo3lyxe. O.reHr JrerKo pacrBopr4M BoAe. B XpaHxr B nnorHo 3aKpbrroM roHrefiHepe. Harpun rrrKpara pacrBop I,8 r nuxpusonofi Kucnorbl pacrBopnor e 180 un BoAbr u rtpu6avlqrcr 20 ra,r l0 Yo pawBopa Harpl{t II{ApoKc]/./la. flpulreHxrcT cBexeilplrroroBJreHnrrfi pacrnop. Harpur nrrxpara Hefirpa.nrnrrfi pacrnop I r nrxpuuonofi xzcnorbl noMeluarorB Mepuyrorol6y BMecrktMocrbro 100 un, npn6anlsrcr 25 wn BoAbr, 4,36 llrt I M pacrnopa Harpvr rr4ApoKcv1a roBorrr o6rev il pacrBopa no4ofi Ao MerKn. 5 un no.rryueHHoro pacrBopa rr4Tpyror 0,1 M pacrBopoM Harpa eAKoro unu 0,1 M pacrnopoM xnopvcroBoAopo.qnofiKkrcnorbr(raH4nxarop-

ffir

Qeuon$raneun). B cnyuae non)^{eHllt qenorrHoro r.rJr}r pacrBopaHarpvflnuKpara K HeMyrrpr4KrrcJroro 6asnsrcr no pacqery 0,1 M pacrBop Harpa eAKorounu0,l M pacrnopa xnoprcroBo4opo4uofr Kr.rcJrorbr. Harpur rrnr(para uleaovHofi pacrBop Crteuunam 20 Mn pacrBopa Harpvfl nr4Kparaz 10 un pacrBopa 50 r/n Hurpzrfl

22.3a(.2769

soAofiao 100un. rvApoKcr,rAa, o6leu pacrBopa AoBoAqr -2cyr. CpoxroAHocrr.r Harpnfi r[pocepHlrcroKrrcd.rufi.Harpr{r rr[pocy.nrQar. Crrr.HarpnR nrera6ucy.rrrQur. ' (M.n. 446,05). Terpauarpux Harpnr nupoQocQar. NaaP2OT 10H2O. 4u$oc$ar, . Harpufi Soc$opnoxucnrrfi(nnpo) qerblpex3aueulessrtfi AeKarprApar. Kpr4craJrnbr. EecrlserHrre, BbrBerpl{Barouluecr cJrerKa pacrBopl4M crrr{pre %. B 96 Jlerro pacrBopr4MBoAe, B oqeHb JrerKo (M.r"r.214,04).f3,4,5,6-rerpaoKcorlr4rnorexc-1-enHarpur poArr3oHar. C6Na2O6. -uteu) gra rc z ] guu arpuir. 1,2 o KpucrartrtrrQuoreroBororlBera. pacrBopa. Pacrnopuru BoAe o6pasonaHrreM PacrnoprtHecraB c opaHxeBo-)KeJrroro
6nlsuu, l,rx roroBrr B AeHb I4cnoJIb3oBau*rfl,.

Harpnr carrnrrrrrrar. C6H4(OH)COONa. (M.t"t. 160, I 1). Eenufi Kpr{craJrnr4.recx[fi [opo[roK unu 6enrre veuryfirN. pacrBopr4M crrr{pre 96 yo, rpaKTI4trecKI4 HepaB Jlerro pacrBopr.rM BoAe,yMepeHHo B n crBopr4M eSupe. Harpnn cynsQar. Na2SOa ' 10H2O. (M.r"r.322,19).tlarpuit cepHoKr{cnrrfi, 4erarnAPar. Bo3.4yxe Kpr,rcrilrnbrullu5etrctfi EecqeerHrre ilpo3paqHbre, BbrBerpr4Baroru[ecfllaa Kpr{crannr4qe crufi floporroK. HepacrBopr{M crrr4pre96 %. B Jlerxo pacrBopr,rM BoAe,[paKTr,rqecKr4 B Harpnn cy;rrQara HacbrrrleHnsril pacrnop 60 r na:rpua cynrSara 3ilrr4Barcr 100 Mn BoAbrrr ocraBn{ror rrpu qacroM ss6anrrlsalg,uuHa 24 \. Harpnn cyrrQara pacrBop 20 oh 20 r narpzr cynrSara pacrBopf,ror B BoAe r.r AoBoArr o6reu pacrBopa eoAofi .uo 100 nrn.

Harpr.rncynrQar 6esno4Hufi.Na2SOa.(M.vr. 142,04). Harpufi cepHoKlrcrrHfi 6eseo,uHrrfi. pacrBopr{M BoAe. B Eenrrfi[oporxoK.furpocrouuqeH.O.reurJIerKo He 6onee0,5 yo. OupegeneHr4e npoBoAtrrIpI4 Ifomepn B Maccenpu 6btcywu6aHuu. reMreparype 130'C. Harpnr cymQn4. Na2S ' 9H2O. (M.u. 240,18).[uuarpur. cynrQug, HoHarI.IApar. Harpuir cepnucrufi. pacnJrbrBa}ouuecflHa Bo3Ayxe. BecqeerHrre, Kpr.rcriurJrbr, Oqesr 6rrcrpo x(eJrrerou{rre pacTBopr4M JrerKo B BoAe. Xpanxr B Bo3AyxoHerrpoHt4 rIaeMoM ronrefi uepe. Harpnr cy.irrQngapacrBop B rJrrrueprlHe pacrnopurenefi 45 12 r uarpwr cyrrQra4apacrBopnor rrpr Har-peBaHrdus Mn cMecr,r - rJruqepriH %) (10:29),3areM (85 BoAa oxnaxAarorr.r AoBoArro6reu pacrnoparofi xe cMecbropacrBopr{Tenefi 100rur. Ao PacreopAonlKeH 6urr 6ecqsernHM. pacrnop Harpur cynrQn4a BoAno-DrrrqepnHoBbrfi tr 5 r narpnr cynr$u4a pacrBop{rcr s 10 Mn BoAbr rodaennror30 Mn urrrlepuHa. EEI

Xpanxr B 3arronHeHHoM roHrefiHepe, 3arrlxilIator cBera. o/o Harpun cy.nQn4a pacrrop 2 B npn6arnxror 2-3 rannlarnl4llepnuav ro2 r uatpnn cynn$ugapacrBopqrcT BoAe, BoArr o6rerupacrBopa eoAoillo 100un. Harpnr cy.nrQur. Na2SO3' 7H2O. (M.pt. 252,15). Harpufi cepuucroxncnufi 7-soAH fi . Harpwit cepHucro Kuc rstit, renr arll.qpar. H reprer BoAyr4oKlrcJrrercr. EecqserHrre Kpncranru. Ha Bo3Ayxe JrerKo pacrBopllMB cnupre 96 %. Jlerro pacrBopr.rMBo,ue, B orreHb MaJro pacrBop Harpnn cyrrQnra 30 r Harpzr cynr$ura pacrBopsrorB BoAeI4 AoBoArr o6teu pacrBopasoAofi .uo100un. (M.pt. 126,04). Na2SO3. Harpur cyrrQur desnoAHrIfi. Eerufi roporroK. pacrBopr{M cnr{pre96 %. B B MaJro JlerxopacrBopr{M BoAe, oqeHb 230,08).fiunarpux (2R, 3R)-2,3Harpnr raprpar. CaHaNa2O6'2H2O. (M.tut. o Arrrr{Ap Kcu6yr auguoar, rrrru4p ar. Kpucrarrbr vtru rpaHynbr 6eroro rlBera. pacrBopr{M BoAe, HepacrBopnMcnr4pre %. B B npaKTurrecKrr 96 O.{eHrJrerKo ' l0H2O. (M.vr.381,37).Harpnfi rerpa6opHoKucHarpranrerpa6opar. Na2B4Oj
nsrfi 10-eoAsufi . Eypa. fiulaarpux rerpa6opar. uru 6emrfi rpuEecqeernrre [po3paqHbre,JrerKoBbrBerpuBarourilecrKpr.rcrannbr craJrJrxqecxufr nopouror. pacrBoprrMB xoJroAHofi noge, JrerKopacrBopr,rM ropxuefi BoAe,pacrBon Vrr,repeuno pr4MB rnuqeprrHe,rrpaKTrrr{ecK}r HepacrBopuM cnr{pre 96 %. B Harpun rerpa6opara (6ypu) pacrnop 9,55 r p;z'Hurpprr rerpa6opara pacrBoprror B cepuofi Kr{cnore KoHrleHTpllponauHofi npr4 HarpeBaruvt Ha BoArHofi 6ave H AoBoArr o6rena pacrBopa rofi xe rucnorofi .qo I n. Harpur rerpadopara (6ypu) nacrrrqeHHsIfi pacrBop 14 5 r uerxo pacreproro Harpu.srerpa6opara 3anuBaror100 Mn BoAbr ocraBJltror rIpH qacroM sg6arrHsanvpt Ha24 \. Pacrnop Sunrrpylor. Harpnr rerpa6opara (6yprr) pacrnop 0,05 M Harpux rerpa6opar ABax{Abr rrepeKpxcraJrJrr3oBbrBaror BoAbr,pacrBopr-s ero rrpr4 rr3 oC, kr cy:ruurMelcAy nxcraMrr TeMneparypeHe Bbrrrre 60 $unrrponanrHofi 6yuaru, MeHrr nocneAHloroAo Tex rrop, rroKaoTAenbHbre KpHcTanJrbr nepecTaHyT He npl4nnrrarb K creKrsHHofi nanoqxe. 19,07 r nepeKpr{crannr{3oBaHHofo laarprrflrerpa6opara pacrBop*or B BoAe14 AoBopacrBopa eo4ofi.qo I n. Aqr o6reNa Harpun rerpagefiTepoAuMerHJIcI{JIareHTaHoar.C6H92H4NaO2Si.

(M.rur. 172,28). TSP.Harpux (2,2,3,3-rerpagefirepo)-4,4-guverun-4-clrrrareHraHoar. - He 99 CreneHr4efirepupoBalavfl. MeHee o/o. Kpncraun.recrufi noporxoK 6eroro uBera. 14 JlerxopacrBopt4M BoAe, B sraHoJre MeraHone. Teunepamypa malreHua. Orcoto300 "C. Boda u deilmepun orccud. 6oree 0,5 yo. He
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Harpur rerpaQeHu.n6opar. NaB(C6H5 (M. u. 342,20). )+. O6rentrrufi [opoilroK 6enoro r{Jrlr cJrerKa xeJrroBarorouBera. Jlemo pacrBopr{M BoAe arleroHe. B rr pacrBop I oh.Pacrnop10 r/n. Harpur rerpaQeHu;rbopara Ecnlr ueo6xoguuo, [epeA r4c rroJrb3oBaHr,reM $ unrrpyror. -7 Cpor roAHocrrr cyr. Harpnn rrrorJrnKo.nrr.C2H3NaO2 (M. u. | | 4,09).Harpux MepKarroarlerar. S. lpany:ruposanHrrfinoporxoKr,rnrr Kpr4craJrJrbr 6eroro rlBera.fnrpocronrrqeu. pacrBoprrM crrr4pre Yo. Jlerro pacrBopl{M BoAe MeraHone, B r4 B 96 Xpauxr B Bo3AyxoHerrpoHr4rlaeMoM Hepe. xourefi ' 5H2O. (M.u. 248,18).Harpui cepuonaulcroHarpur rnocy.rrrQar.Na2S2O3 rucnrril. EecqserHrre, ilpo3paqHbre Kpr4crilrrJrbr. pacrBopr{M BoAe, O.reHrJrerKo B npaKTr,rqecKr{ HepacrBopr{Mcrrrrpre %. B 96 (Dnyopecqer4H (M.na.376,26). Harpnn Qnyopecqel{Har. C2sH1sNa2O5. Harpr.rx. ilu-oxco-6-oxcnAoHurprrfl (3 23H-rcauren-9-nn)6ensoar. floporuox opamKeBo-KpacHoro rlBera. Jlerro pacrBopxM BoAe. B BoAsrrepacrBopbr vMerorr4HTeHcr,rBHyro xenroBaro-3enenyro QnyopecrleHrlr{rc. Harpur Qoprvrnar. 68,01). CHNaOr.(M.rur. KpNcrannll.recrlrfi noporuoK rrnupacnnbrBaroilruecr rpaHyJrbr 6erclrouBera. pacrBoprrM crrr4pre %. PacrnopuuB BoAe rJrrrqepuHe, MaJro v B 96 Teunepamypa 253 nnaBneHua. Orcono "C. Harpun QocQarABy3aMeuleHHnrfi . Hatpnfi QocQopnorcnc.urrfi ABy3aMerrleHuufi 12-nognufi . Crr,r. rrgpoQocQar. lunarpnn Harpna QocQarapacrnop 5 %o pacrBoprrcr B BoAerr AoBoA{ro6rervr pa5 r uarpua Soc$ara ABy3aMenreHHoro crBopa no4ofiao 100nrn. Harpna QocQarapacrBop0,25M pacrBopflror AocrarolrHoM 95,025r Harpr4s B KonuqecrBe BoAbr QocSaral2-soAHoro pacrBopa u pas6au.sroro6seN,r soAofilo 1000,0un. ' Harpnn QocSarAoAeKarlrApar. Na3POa l2H2O.(M.r. 380,13). Tpunarpux $ocHarpufr SocSopnoxncnnrfi rpex3aMerrlesnufi 12-no.qnru.i. $ar, aoaerarrr,{par. BeclfeerHHe vrfir 6eroro rrBeraKpr.{crannbr. pacrBopr4MBoAe. Jlerro B '2H2O.(M.*. 156,01). Harpux QocQaroAHo3aMeulenHrrfi. NaH2POa HarpnfiSocoIso3aMexIeHH 2-r,a4uufi Harpnfi QocQopHorucrufioAHo3aMesrir . Qopnoxuc.nufi uqeHHrifiAr{rr,rApar. , EecqserHrt vilu 6emreKpr{crarrJrbr. e Pacrnoprna ropruefi BoAe, n HepacrBoprrMcnr4pre o/o. B 96 ' 19H2O. Na3Ha[P(MozO)a] (M.vr.2269,5). Harpnn QocQopnouonndAar. Harpufi . Soc$opnoruoru6geuosoxucrHfi Xelrrrfi MenKoKprrcriurn[qecrufi nopouror. Pacrnopul.r Mr,rHepanbHbrx B Kr.rcJrorax.

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pacrBop l0 oh Harpnn SocrpopHoprorlrdAara pacrBoprwrs75,6 MnxnoprdcroBoAopoAHofi 10r Harpnx$ocSopnouo.nu6Aara xucJrorbrKoHrleHTprrponauuofi . HarpHn Qropng. NaF. (M.u . 41,99).Harpuir Sropucrufi . Eenufi noporuoK urn 6ecqrerHbre Kplrcrannbr. Pacrnopvl,r BoAe, B [paKTurrecKu HepacrBopr{Mcrnrpre96 %. B Harpnn xJropr{A. NaCl. (M.r. 58,44).Harpuiaxloptrcrufi. Senrrexy6uuecrue KplrcranJrbr 6e-rurfi r.rJrr.r KpucrannxqecxttfinoporxoK. pacrBopnM BoAe; Oqeur JrerKo B rpaKrnqecK[HepacrBopr.rM B crrrdpre %. 96 Harpux xrropnAapacrBop 20 o/o. Pacrnop20 % (u/u). pacrBop l0 o . Pacrnop100r/n, Harplrx xJropnAa Harpnr xJropngaHacbrxlenHufipacrnop 1 qacrr Harpvflxnopr{Aa ilep[oAxqecK]r cMerrrr4Baror \actxMlr BoAbr, c2 BcrprxupacrBopAeKaHTr4pyrorecrlt ueo6BarorH orcrarrBaror. llepeA rrcnonb3oBaHueM rr, xoAlrMo, $unrrpyror.
Harpua qrlrpar. C6H5Na3O7'2H2O. (M.u. 294,10). Harpufi rruMoHHoKucnstitrpex-

3aMeIIIeHHbr4, AktrlrApaT. Eenuii KprlcraJrJrrrqecxufi nopolroK. JlerxopacrBopr.rMBoAe, B rpaxrurrecKr4 HepacrBopr.rM B cnr{pre96 %. Harpufi uaBeJreBorcHclufi. Harprrfl oKcarar. Cna. '2H2O. (M.vr.372,24). Harpnn sAerar.ClgHt4N2Na2Os Tpu.non F. Eenufi KpucranJrnqecrufi noporxoK. Pacrnopurvr BoAe, yMepeHr{o pacrBoprrM cnr.rpre yo, npaKTr.rqecKu B B 96 HepacTBopr4r\{ sQupe. B (M.ru.128,16). HaQranuu. C1sHs. Kpucran.nrr6enoro rlBera. flpaxruvecKr.rHepacrBoplrM BoAe,nerKo pacrBoprrMr e$npe, pacrBopktM B B cnr{pre96 %. Teunepamypa nnarreHun.Oxono 80 "C. Ha$ranr,rH, rrcnonb3yelrufiArq )KrdAKocrsofi cqrrHTr{nnrur{r4, AoJrxes6rmr coorBercrnyroqefr cre[eH]r rrr4crorbr. (M.r'r. 576,3). TopuH. luuarpnn 4-l(2HaSrapron. CroHrlAsN2Na2OroSz. -3-rr.rApoKcrrua$rarNu - gucyns$oHar. -2,7 apcoHo-$eHran)aso] Itroporuorc KpacHoro rlBera.PacrnopuuB BoAe" HaQraproHapacrBop0,058%o. Pacrsop0,58r/n. qyncmsumenbHocmb. rvrn Irlcnwmauue He K 50 cnupra96o/onpu6aBrsror nan 20 BoAbr, 1 nn 0,05 M pacrnopacepuofi Kucrrorbr, rur pacrropa na$rap3oHa14 I rlrrpyror 0,025M pacrnoporvr pac'rBopa opaHxeBo6apuxnepxnopara rrepexoAa oxpacKr{ or Ao xemofr K opanxeBo-posonofi . - 7 Xpanrr B 3aruuqeHHoM cBeraMecre.Cpox xpaHeHr4-f, cyr. or HaQrnlaNIrIH. C I gHeN.(M.rur. 43,ltt). I -Ha$u4raMnH. I cr-Ha$ruraMr{H. Kpzcra;rnn.lecxufi po3onopourox6e;rorouBera,noA AeficrBr{eM cBerar4Bo3.uyxa
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Xpanx:rB 3arrIHrrIeHHoM cBeraMecre. or p-HaQrnnaMrrH. CtgHeN. (M.r'r.143,18). Jlucronu4Hbre Kpr,rcraurJrhr Kpr,rcraJrJrr4qecKr.rfi r{nr,r nopouror. PacmopulrB crr4pre96 oA,eQupeu 6engole. Tunnepamypa nnaBreHua. Oxono 110'C. HaQrn.irrrrrrreHArraMrrna Cl2Hl4N2 . 2HCI. (M.r'r.259,I8). ArrrrrApoxJropnA. N-(1-Ha$rur)erunerqflaMvHa ALIrrrApoxJIopr,rA. o,-Ha$rnnerrJreHAnaMnua Aurr4ApoxnopHA. Moxer coAepxarbKprrcrannu3arlroHHhrfi rueranon. llopouror 6eroro r,rJrrr )r(eJrronaro-6enoro rlBera. pacrBopr,rM cfir{pre 96 %. Pacreopnrra BoAe, B Marro B a-HaQro.n. ClgHsO.(M.u. 144,17). 1-Ha$ron. KprncrartrluqecrcIafi nopolroK 6eroro rlBeraunu 6ecuserHbre unn 6eroro rlBeraKplnTeMneroulne AeficrsaeldcBera. crrurJrbr, noA pacrBopuM cnr,rpre % u sSupe. Mano pacrBopr.rM BoAe, B JrerKo B 96 oC. Teunepamypa marfleHun. Oxoto 95 Xpanr:r B 3arrluilreHHoM cBeraMecre. or o-HaQro;ra pacrBop 0rl oh 0,10 r o-uaQrola pacrBop{rcts 3 rar 15 o/opacrBopa Harpr.r{rulpoKcv/LavrAoBopacrBopa noAofiao 100 rvrr. A.flr o6reN,r foroesr Herro cpeAcrBeHHo flepeAr,rcnoJrb3oBanl,reM. a-HaQto.iracilrrproBufi pacrnop 01057o pacrBoprrcr B cnr.rpre % Lr AoBoAmo6reu pacrBopa reM )Ke 0,05 r o-uaQro.na 40 crruproM4o 100 rvur. a-HaQro.nacnrrproBufi pacrnop 20 o/o 20 r o-naQronapacrBoptlor B crlrrpre96% rr AoBoArro6rerra pacrBopa reM xe crrproM.IIo100iran. p-Ha$ro.n.C1gH8O. (M.u. 144,17). 2-HaSron. flnacrusru r4rrtr Kpr.rcraJrJrbr 6eloro zln cna6o-po3oBoro rlBera. pacrBopr,rM BoAe, pacrBopr,rM O.IeHr MaJro B oqenbJrerKo cflHpre 96 %. Tettnepamypa ma*reHun. Oxono 122 "C. XpaHxr B 3arrluueHHoM cBeraMecre. or p-HaQrorapacrnop 2 oh pacrBoprror e 40 rar pacrBoparrarpufl. 2 r B-ua$roJra pa3BeAeHHoro rr,rApoKcLrAa r4 pacrBopasoAofi ao 100 run. AoBoArro6reru th B-HaQrona ulerroquofipacrnop 5 pacrBopa:oa5 r ceexenepeKprrcrrurJrr43oBaHHoro B-na$rora pacrBoprm e 40 MJr piBBeAeHHoro AoBoArro6rena rplrr rprApoKcr.rAa pacrBopano4ofi ao 100 rvrn. u loroeqr Heno cpeAcrBeHHo rrepeA r4cnoJrb3oBaHr.reM. pacrBop 0,0037o n cepnofi rcnclore B-HaQro.na 3,0 rrar KoHueHrpr.rponauHofiAo,r B-na$ronapacrBopnor s 50 rur cepHofiKr,rcJrorhr BoArr o6reu pacrBopa rofi xe xlrcnorofi.qo100,0run. lorossr Herro cpeAcrBeHHo rrepe.u LrcrroJrb3oBanr.reM. (Desun6Hc HaQro.n6eu3errH.C21H20O3.(M.u. 392,43). a,-HaQron6eHseraH. (4-rugporcnna$rran)ueraHorr. EEg/

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Kopr.rqHeBaroflopouor KopurrHeBaro-KpacHoro r{Bera utu 6necr,rlrlrre Kpr4craJrJrbr qepHofo rIBeTa. flparruuecKrr HepacrBopr4M BoAe,pacrBopkrM crrapre 96 % r{ yKcycuofi rzcnore B B reAsHofi. HaQror6eH3errHa pacrBop 0r2 o/o.Pacreop 2 rlil s yxcycuofi Kr{cnore6eseoAHofi. IzlcnutmauueHa uyscmsumerbHocmb. 50 nrn yxcycnofi Kr4cJrorbr K reAqHofi npu6arrosBrrercr Kopr{rrHeBaro-xenroe oKpaBJrrFor 0,25 rv'l pacrBopa ua$ron6eH3er{Ha; npu npu1aBJreHr{r{ 6o;ree0,05 rrn se [rr4BaHrre, Koropoe Aonx{Honepefiru B 3eJreHoc 0,1 M pacrBopa xnopuofi KrrcJrorbr. 418,4). 3,3'-6uc-(4-ru4porcn-1o-HaQro.uQra.ueun. C28H18O4. (M.r. Ha$run)$railn1\. rlBera. Meri<orpucraJrJrrrqecrzfi nopouoK or 3eJreHoBaro-ceporo Kopr4rrHeBoro Ao flpanruvecKr4 HepacrBopr4M BoAe,JrerKopacrBopr{MB crrr{pre, e$npe u yrccycHofi B Kr4cJrore :re4xHofi Mano pacrBoprrMs 6eHsore. , pacrBopaor )KeJrroBaro-po3oBofige.neuoBaro-cr4Hefi x n uurepnare flepexog oKpacKra pH 7 ,4-8,6. o-HaQrorQrareuna pacrBop 0rl o/o pacrBoprror e 50 N,{rcrrrpra 96 % r.rAoBoAtr o6relr pa0,1 r o,-uaQronQranelrHa crBopa eoAofi ao 100 ur. 1,2-HaQroxHHon-4-cynrQorcHc"'rorbr KarueBaq cor'rb. ClgHsOsKS.(M.u. 276,31). 1,2-Ha$roxuHoH-4-cynrQoHar Karrufl . llopouror xenro-opaHxeBoro rIBera. HefirpanrHufi xpacHufi. Cl5Hl6N4 ' HCl. (M.vr. 288,78). Toryureuonufi Kpacnrrfi . 3-arra uuo-7-[ntvrernJraMuHo-2-uerunQeuasnHa frrApoxnopr{A. rlBera. Kpzcramrbr urwr [opouroK trepHoror4nr{qepHo-3eneHoro B B Jlerxo pacrBopr4M BoAe,pacrBopt4M cnr4pre96 %. pacrBopa or KpacHofir xerrofi n uureprane pH 6,8-8,0. llepexo4 oKpacKr4 Hefirpa.rrrHoro KpacHoro pacrnop. 0,1 Yo utu 0,5 oh (,urx unrpr4roMerpl{u) pacTBOp. Hefirpa.nrHoro KpacHoro yKcycHoKrrcJrbrfipacrnop. 0,1 yo pacrBop n yrcyfirofi Kr.rcJrore reA-{Hofi. Hepn.naqerar. Cl0Hl7OCOCH3. (M.vr. 196,29). (Z)-3,7-[uMerrrJroKra-2,6-gneuI{JIaIIeTaT.

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20

(Ni, A.u. 58,70). ceporo MenrufiropotrloK uBera.

c KLIcJIorax o6pasoB B llpaxruvecKrr HepacrBopr.rM BoAe,pacrBopr,rM MHHepanbHbIX BaHrreM corefi. Hnrcerq cynrQar. NiSO4 ' 7H2O. (M.r"r. 280,88). Hurels cynr$ar, rerlrarl{Apar. 3eneHoroIIBera. Kpucrarruqecxvfi nopoilroK rlnfi KprrcraJlJrbl Jlerro pacrBopr{MB BoAe,MaJIopacrBoprrMB cnlrpre 96 %. 6eseoAHufi. Hrrcerq xJropHA.NiC12. (M.n. 129,61). Hurens xrropl,IA Kpucra-nnn.recxufi [oporroK xeJlTofo uBera. O.{eHr JrerKopacrBopr{MB BoAe,pacrBoprrMB cnl,Ipre 96 %. Cy6nralrupyercs B orBoAnrrfi pacrBop LIMeerKl{cny}o cyrcrBr,re Bo3Ayxa r nefKo a6cop6upyer aMMIaaK. peaKrlr4ro. H27N7O1 Hnrcornn aMLIA-aAeHlrHa ArIHyKJIeoru4. C21 4P2.(M. r"r.663,4). rxrpocKonl,IqeH.Jlerxo pacrBoplrMB BoAe. floporuon 6eloro IIBera, clrJrbHo pacrBop 0 14 o HurcorunaMlrA-aAeHrlHaAIrHyKJreorIrAa 40 ur HraKorr{HaMVI-aAeHvHa Ar4HyKneor[AapacrBopsrcT B BoAe I,I AoBoA{T o6rerr,t pacrBopa reM xe pacrBopllTeneM 10 rr,rl. Ao ilepeA r{clonb3oBdnueu. loroesr He[ocpeAcrBeHHo (M.,". 415,5). 5-Auuno-9-(.Uuerznaltuno)Hn.nrcrnfi cnnnfi A. C20H2rN3O5S. xncnrrfi cynr$ar. 6euso-[cr]$eHoKca3nHulrvs. [oporroK 3eneHoroIIBera c 6ponronuu 6necrou. Kpucrannra.recrIafi IeAsHofi vnnpilAr4ne. B VvrepeHuopacTBopI4M cIIVpTe 96 oh, yrcycnofi KLIcJIoTe o/o,o6lo6) rdMeer rronlolrleHufl.rrpr4.4nllHe MaKcLIMyM Pacrnop 0,005 r/n n cnzpre (50 BoJrHbr Hu. 640 Hnlrcnoro cr{HeroA pacrnop I oh.Pacrsop 10 r/n n yrcycsofi ruclore 6e:eoAHofi. KI,IcJIorbI 6esnoAuofinpu6aK I'Icnumauue Ha HyncmnumerbHocmb. 50 un yrccycHofi cr4HeroA; noxenxercx rory6oe oKpaIIrI4BaHLre, BJrflror0,25 wrltpacrBopa Hr.rnbcKoro ilpn B Koropoe nepexoAr4r crrHe-3eneHoe npu6anneuvuHe 6onee 0,1 rul 0,1 M pacrBopa xropnofi Kr,IcJIorbI. llepexog oKpacKuor cusefi Ao KpacHofin uurepnane pH 9,0-13,0. MoHorr{Apar. Hnnrn4puH. CgHaO:' HzO. (M.r"r.178,15). 1,2,3-I4HAaHrpr{oH, cJrerKaxeJlToro IIBera. -fAoslar. KprEcralluqecxrafi ilopo[roK 6eroro r4Jr*t

pacrBoprrMn rQnpe. Pacrnopnu B BoAer4cnupre 96 yo, MaJro Xpauxr B 3arrIVqeHHoM cBera Mecre. or Huuru4puHa rr oJroBa(II)xnopnAa peanrnn (1) ropxvefi BoAbI,npv6auxror 5 ur 0,16 o/opa0,2 r uunrv4pr4Ha pacrBopruor s 4 N.ur crBopa o.nona(Il) xnopr,rAa,ocraBJrrror Ha 30 uun, Sumrpyror r,rxpaHtr npI{ reMrle-

parypeor 2 Ao 8 oC. rc 2,5 Henocpe4crBeHHo rrepeAI4cnoJIb3oBaHLIeM npu6aenxrcr rran BoAbr 45 vut2-upouaHo.na. u 5 peaKr*tn(2) Huurn4pnHa r.roJroBa(II) x"uoprrAa

Mn [onyqeHHoro pacTBopa

OcroeSupa grr4JreHrJrr{KoJlt. 4 r snsruAprrnapacrBopsror e 100 Mn MoHo3TrdJroBoro polKHoBcrprxr4Barorc I r cMoJrbr z raruonoo6ltensofi (or 300 ao 840 rrarvr) Qr.rnrpacrBopsror e 100 un 6yQepnoro rpyror (pacrnop A). 0,16 r onosa(Il) xnopprAa pacrBopapH 5,5 (pacrnop E). paBHbIeo6reurr pacrBoHenocpe4crBeHHo[epeA r.rcnoJrb3oBaHr.reM cMerrrr4Baror ponAuE. HnHrngpuHa pacrBop 3'h 3 r HusruApr4napacrBoprrcr s 100 Mn pacrBopa45,5 rlrruarpur' uera6ncynrQr.rra. pacrnopurerefi B HunrngpnHa pacrBop 0r4 oh. Paqsop 4 rlr' Hrrurr4AprrHa cMecLI yKcycHa{ Kr.rcJrora 6essoAHaq 6yraHor (5:95). o/o HuHrngpuHa pacrBop 0125 pacrBoprror B BoAerr AoBoArr o6reu pacrBopa soAofi ao 100 un. 0,25 r :avlrtrr4qpr4Ha HuHrn4puHa pacrBop 0r2 oh pacrBopr4renefi yxcycHar Kr{cnorapa3BeAeHHaq Pacreop 2 rlt uularu4.pvlaa cMecr4 B 12%-6yrauor(5:95). Hr.rHrn4puHa cnnpronrrft pacrnop 1,0 r nnnrv4.puHapacrBop{ror s 50 Mn crrrpra 96 % n npu6awrsror 10 un yxcycHofi KucJrorbr reAsuoft. HnrpoaHnnnH. C6Ho NzOz (M. ru. 13 8, 13). 4-Hurpoa :ailIrvtn. n-HurpoaHLIrILIH. -]KeJrrororIBera. Kpncrannu.re cxlafi noporrroK .rrpKo pacrBoplrMn ruuqIqefi BoAe,pacrBopl4M pacrBopr.rM BoAe,yMepeHHo B Oqeur MaJro MLIHepanbB crrrrpre 96 % u a$npe. O6pasyer BoAopacrBopr4Mbre coJrrlc crrJrbHbrMlr
HbIMI{ KIICJIOTAMI4.

Teunepamypa nna6n eHua. Oxotto147'C. p n-HurpoaHrrJrr.rnaacrBop pacrBoprrcrs 20lrr 0,1 M pacrnopaxnopxcrono4opo4Hofi 0,015r Hr{rpoaHnrruna qeM He KucJrorbr AoBoArrclr4proM96 % ao 100 un. Pearrr{BrrprrMeHrlor paHee, rr rrepe3 q nocnenpr4roroBneHvrfl. 24 Hnrpo6en3arrbAerr.rA tH s NO:. (M.r. | 5 l,l2). 2 -Hurpo6eH3anbAerr4A. .C tr{ronr.rarrreKprrcranJrbr )KenrororlBera. pacrBopr.rMcrnrpre96o6,pacrBopr4MaSnpe,cy6B n Mano pacrBopr4MBoAe, B JrerKo nHMr{pyeTcr [apoM. Teunepamypa ma*neHua. Oxoto 42'C. Hnrpoden3aJrbAerrrAnan 6ylrara pacrBoprrcrs 10 rvrn o/opacrvopaKarpr4fl, 20 rLIApoKcIrAa. 0,2 r nurpo6eugaDAeruAa pacrBopa 1 .r. Cpox roAHocrr4
@

B nonyvenrurlit pacrBop norpylnaror HvrlKHroro norroBuHy rroilocKpr rr3 MeIp,rLrrofi 10 cu u rJtLrpuuoir0,8-1 cu. I,Is6rrrox neHHo @nnrrpyroryefi 6ywarvr peaKrr4Ba yAan;rror, npoMoKar [onocKy rvrexAy AByMr nrrcraMrr QrarrrposarsHofi 6yuaru. tr4cnoru:ylor B TeqeHXe HecKoJrbKlrx MrrHyr nocJlenpr4roroBneHr.rfl. pacrBop Hnrpo6en3aJrbAerr,rAa pacrBopa HarpLrA 0,12 r roporrrKa Hnrpo6eH3anbAerr4Aa npu6ayt{ror K 10 na.n oh, Bcrptxr4Baar B TeqeHr4e wrxn u pa3BeAeHuofo8,5 rnApoKcr4Aa 10 $vtsrpyror. foroesr HenocpeAcrBeHHo nepeA HcnoJrb3oBaHrreM. Hnrpo6en3r,rrrxrropnA. NOz. (M.u. 17 1,58). 4-Hurpo6eH3r4nxnopr{A. C7H6C1 Kpucrarrbr cBerno-xenrofo rlBera. Brrsrrsaer cne3oreqeHr4e. IlparruuecKr4 HepacrBopr4M BoAe, or{eHbJrefKopacrBopr4MB crrr{pre 96 o/ou B

e$upe. Hnrpo6eH3ounxr'ropCTHaCl ug. NO3.(M.u. 185,56). 4-Hurpo6eH3orrnxnopr4A.

Kpncra;trt:slvrrn Kpncrannl4qecKarMacca xeJlToro rlBera, pacnnbrBarorrlarcrHa BO3Ayxe. Pacrnopulr B pacrBope Hanpvrr rr4ApoKcrrAa o6pa:oBanueM c xenroBaro-oparrxeBoro oKparurBaHr4r. Teunepamypanna*neHua.Oxolo 72'C. Hurpo6en:o.n. C6H5NOz.(M.u. 123,1). BecuserHa.fl rrJrucJrefKa xenroBaroro uBera )Kr{nKocrb. flparru.recKrr HepacrBoprrM BoAe,cMerrrr{Baerc.f, crr{proM 96 % n eQupovr. B co TeunepamypaKuneHu,n Ororo 2Il "C. upn6an.nxror5 nrr arreroHa,5 un noArr u K ,{unumpo6eHson. 0,1 Mn Hr4Tpo6ensora o/opaclopa l'1^aTpus, 5 un 20 rI.rApoKcIIAa BcTptXI.IBaroT; II nocJle pa3AeneHl{q cnoeB repxHraficrofi AorxeH 6urr noqrz 6ecqserHHla. 4-(4-Hnrpo6enrur)nrprrAnH. C 1 I 0N2O2.(M. ru. 2 | 4,22) . 2H lloporuor xeJrroro rlBera. Teunepamypa nna*reHun. Oxono 70 "C. Hurporo4rrrporrnJraMrrH. C6H14N2O.(M.,r. 130,19). lznponunHl4rpo3aMlrH. Xra,qrocrr. Kr.rcJrorax. Pacrnopuru B gTaHoJre, sQupe r{ KoHrIeHTpr{poBaHHbrx TeunepamypaKuneHufl. Ororo 78 'C. flpzro4ua Anr onpeAeJreHrlrxeMr{JIroMrIHe clleHqrlr.r. pacrBop Hnrporo4rrnponnJraMrrna rrHbeKrlraonnofiHrnofi npo6ry cocyAa, coAepBeoArr 78,62 r gTaHoJra, npoKaJrbrBuur xarqero Hr{Tpo3oAr4npolr,rJraM pazdawt:trcTgraHoJroM coorHorueurlr.r1: I 00 n nouu, B Merrlaror uo 0,5 MJrB KoHTefiHeprrc o6xarulan KpbIIlKaMIr. Xpanar B 3arrIuxIeHHoM cBera Mecre npu reMneparype 5 "C. or

dii . o*ono 0,915.

(M.u. 377,26). Ilnrporo-P-com. C 1 0H4(NOXOH)(SO:Na)z

Xerrsre r4Jrr)KeJrrbre 3eneHoBarbrM c orreHKoM KpucranJrbr.

Hurpoueran. CH3NO2.(M.u. 61,04).

flpospaunar, 6ecqrernafl,, MacJrrHr.rcras xuAKocrb.

MzuropacrBopr,rMBoAe, B co 96% u eQuporra. cMerrrrlBaercr crrrlproM

dii .o, l,r32ao ,134. 1

lto .Or 1,381 o 1,383. a Tetvtnepamypuarc nepezoHrcu. 100 ao 103 'C; AonxffiorreperoHtrbc{ He Or npedenbt MeHee %. 95 peaKTHB Hnrporvroan64enonanaA[esrrfi I na-n 18%opaPacrnopI.10r aMMourl.f,uonH6AarapacrBoprrorBBoIe,npu6auruor soAofiao l00lrn. crBopaaMMr.raKaAoBoArro6reu pacrBopa n PacrnopII.2,5 r aMMoHr{r BaHaqarapacrBoprrorropxvefi BoAe, r upu6aanxror 14lar pacrBopasoAofiao 500 nan. asorHofi Kr.rcJrorbr AoBoArro6seNr r,r K 96 ir,rn KoHrleurprrponauxofi upu6annxror 100 Mn pacrBopal w agorsofi Kr,rcJrorbr pacrBopa r.r.qoro,uxr soAofiao 500 rr,rn. 100rran II o6reu pacrBopa (M.r"r. 817,6).3,3'-(3,3'-[HnaeHnrpore'rpa3orrr{eBufi cnsnfi. C40H30CI2NI0O6.
'rorcu-4,4' -gnSenuney)pnl2-(4-nurpo$enun)-5-$enux-2H-rerpa:onux],uuxnopl,IA. n -Hurp orerp a3onr4e l'lit cwwuilt. B Kpucrannrr. npo3paqHoro pacrBopa xeJrroro PacrropuM B MeraHoJrec o6pasoBaur,reM uBera. Teunepamypa nna+reHua. Orcoto 189 "C c piBJIox(eHHeM. HurpoQypaHrorrn. C8H6N4O5.(M.u. 238,17). Xenrufi Kpr.rcraJrJrr4.recr[fi nopomoK r,rJrr{ }r(eJrrbre KpncraJrnrr,6es 3aflaxaHJIvnoqrl4 ganaxa. 6eg oqeur MaJropacrBopr4MB BoAe H cflHpre 96 yo, pacrBopr4MB AHMerunoopMAMIIAE.
20

(M.r. 243,17).HnrpoQypSy(5-Hnrpo-2-Qypn.n)nreru.nena Ar{arlerar.CeHeNOT. porraaqerar. 5-Hnrpo$ypQypnrureua Alrarlerar. Kpncranrhr xeJrroro rlBera. Teunepamypa nnaBneHun. Oxono90 'C. Hnrpoxpouonrrfi pearcrrrB pacrBoprror B asorHofiKr4cJrore H KouueuTpuponaunofi Ao0,7 r ranu.rr Ar{xpoMara BoArr o6reu pacrBoparofi xe rucrorofi ao 100 rran. (M.u. 75,07). HnrpoeraH. C2H5NOz. flpoepavuar, 6ecqaerlaafl,MacJrfl HprcrarxIdAKo crb. n Pacrnopurvr BoAe, B xnopo$opMe;cMerrr[Baercr graHoJrorvre$npoivr. c 'C. Teunepamypa KuneHufl. Orono 114 (M.er. HopAareuarvr. 270,71). 7-Xrop-2,3-tururpo-5-Qenun-1H-1,4C15H1lCIN2O. 6eHsograa:enzs-2-os. rlBera. Kpncrarnzqe crnfi nopo[roK 6eroro rrJrr.r cBerJro-)KeJlToro pacrBopr,rM crurpre 96 %. flpaxruuecKr,r HepacrBopprMBoAe, B MaJro B Teunepamypa ruaBneHunOxotro216 "C. (M.u. l3I,I7). (RS)-2-Anar,rHoreKcaHoBar KucJrora. Dol-Hopnefiunn. C6Hl3NO2. AuznoraupoHoBar Kr.rcJlora. Erecrgulue Kpr,rcraJrnbr. pacrBopr.rM BoAe, pacrBopr4M Kr.rcJrorax. B Vrvrepenno B

Eg

HopncengoeQe4pnna rrlApoxJlopul. CeHl4ClNO. (M.u. 187,61). (1R, 2R)-urIE ( I S,2S)-2-Ananno- -$enulnponaHona ruApoxnoprrA. I Kpucranruqecrufi noporuoK. PacrnopuruB BoAe. nrarneHun.Or 180 ao 181 "C. Teunepamypa lrel.fllaaflKLIcJIora pacrBopl{Terefi:yKcycHaq O6ecunequnaroqufi pacrBop. Crraecr - BoAa(1:4:5). MeraHoJr 4-OrcnroJryoJr. Cna.Kperon. u-OrcuxnHoJIrIH. CeH6N(OH). (M.*. 145,16). S-OxcNxunonllH.OxcuH. )Kerroearu fi uerxorpucraxnur{ecnnfi nopotuoK. pacrBopl{M B alleroHe, xnopo$opue, 6eu3olte,MaJro B Jlerro pacrBopr4M crrr{pre 96 o/o, pacrBopl,IM BoAe,e$upe. Pacmoprerct B KI{cJIoraxH Illenoqax. B pacrBoptnr s 100 ul 2 M u-OrccnxnnoJrrrHapacrBop 5 'h. 5 i o-oKclrxIrHoJIItHa pacrBopa yrcycHofi KLtcJIorbI. Orcranor. C1HrcCH2OH. (M.u. 130,22). l-Orrasol. Kanpulorrtfi cnnpr. crb. EecqserHa-r )KITAKO HepacruopplMB BoAe,cMelllrBaerct co cilIrproM 96 % u a$uporu.

dii . o*ono 0,828.

Oxolo 195'C. TeunepamypaKuneHufl. 3-OrcranoH. C2H5COCsH r r . (M. r'1.128,21). SrunneHrI'IrIKeroH. 3arlaxoM. c Becqseruas x{L{AKocrb xapaKTepHbIM u B HepacTBoprrM BoAe,cMellruBaeTctc gTaHoJroM eSuporvl. llqarrrauecKr.r d,' . Oxolo 0,822.

rli . Ororo1,415.
KuneHun Oro.no167'C. Teunepamype qflcrora 3-oxraHosa, s npr{MeHteMoro ra3oeofixpoMarorpaXponaarorpa$uuecxax 98.0%. $uu,4orxna 6rtrr HeMeHee (Z)-Oxraaeu-9-eHaur't4. (M.u. 281,47). O.neaunr.Cl8H35NO. IIBera. nu flopouror unvrrpaHy or 6eloro .{o xeJIToBaroI'o papacrBoprlM MerI4JIeHXJIoprIAe, B JrerKo B BoAe, oqeHb HepacrBopr4M flparrlrvecKla
crBopr{M B STaHoJIe.

Teunepamypa nnarneHun. Or<otto80 "C. AI{rI4Apar.O.iloeo O;rona(II) xJroprlA. SnCl2 ' 2H2O. (M.ror.225,63). Choea AI,IXJroputA xnopl{A. rByxJropucroe 2-noAsoe. Oroea 3aKrrcHoro o/oSnC12' 2H2O. Co4epxut He MeHee97,0 FecqserHHe Kpucrannbl. o/a, yxcycuofi B Oqest nerKo pacTBopuMB BoAe,nerKo pacTBopI4M crII{pTe96 KtrcJrorele4xuofi, xnopncroBoAopoAHofi rncnore pa3BeAeuHofiu KoHIIeHTpI4ponauHofi. Orona(II) xrroprrga pacrnop (1) KoHxnoplrcroBogopo4uoft KI,IcJIorbI 20 r onoea MerarruqecKoro HarpeBalor c 85 rran Bo.{opoAa,oxJla)I{Aator. rleHTprrpoBaunofi .4o npeKparleHl{t BbIAeJTeHI{t 3alqurlaq or Bo3Ayxa. XpaHrr pacrBop HaAus6rtrKoM oJIoBa, Orona(II) xr'ropuAapacrnop (2) pacrBop o.nona(Il)xnopl{Aa ( 1) pa:rogrr Henocpe4crBeHnorrepeAucrroJrb3oBaHrreM

f,

pa3BeAeHHoir % (1 : 10). xnopktcroBoAopoAHofi KracJrorofi 7,3 Orona(II) xrroprrAa pacrnop 8 %o K 8 r onona(Il) xnoprdAanpuiannxror 100 MJrpacrBopa20 % (o6lo6) xnopr{croBoAopoAHofixzcrorbr, Bcrp.f,xr{Baror pacrBopeHr.rr,ecnr ueo6xoAr4Mo, HarpeAo 'C x [poflycKaror a3or B TeqeHLIe Baror Ha BoArHoia6ase npr4 TeMneparype 50 l5 uHu. loros-f,r HerrocpeAcrBeHHo rrepeAucloJrb3oBaHveM. pacrBop. pacrBop ll) o/o.O:rosa 3aKrrcHoroxnopr4Aa O.nona(II) xJropr.rAa 1 r onona(Il) xnopuaa pacrBopqrcr s 5 MJrBoAbr, cnyqae rorBJIeHI4rMyrI4 npu6anB Jr.rrror un xnopucroBoAopoAsofi xucnorbr KoHrleHTpr.rpoBaHHoitupas6aBJrrror 1 o6relr pacrBopa soAofi lo l0 un. O.nono.Sn. (A.u. 118,69). lpanynrr c epe6pncro-6e;ioro rlBera. Pacreopnuo B xJropucroBoAopolnofi Kr4cJrore BbrAeneHr,reN{ c BoAopoAa. Mr'twunx. He 6oree 0,001 % (10 ppm). Opauxenufi III. Cu. Mern.uonuff opaHxenufi. Opanxenrrfi IV. Cu. Tpoueo.rrun OO. Opaqeronufi cnHuft 2R. C20Hl +NzOz. (M.rvr.3 I 4,33). 1-Anuso-4-($eHunanuno)I aHrparleH-9, 0-4lroH. Teunepamypa nna+neHua. Oxono 194 "C. Opaqeronufi cnnufi B (C21H16N2O2l M.u. 328,36) v Cnecs 1-naerurauuuo-4-asunuHaHrpaxrrHoHa (C2gHI aN2O2 M. rrl. 3 | 4,33). 1-anrnuo-4-anyInnHaHrpaxr{HoHa ; llopourox czne-QraoneroBofo rlBera. IpaxruuecKr,r HepacrBoprrM BoAe,nerKopacrBoplrMB aueroHerr yKcycHofixlrcno:re B 6essorHofi. Opaqeronoro crrHero B pacrnop 005 %o flprE I r opaqeroBofo crrHeroB pacrnopnor B 200 un yxcycnofi Kr4cJrorbr.riegxnofi. TlrrpoBaHur.r HeBo.uHofi B oKpacKyor ro.ny6oro r{Bera (ocHonaHue) cpe4e r,r3MeHrer r{epe3rryprypHbrfi (nefirpanbHaqcpeAa)4o posoBoro rlBera (xucnax cpeaa). KoHueHrprrpoBaHHar. H3POa.(M.vr. 98,00). Ooc$opOpro$ocQopHafl Kr.rcrrora Har Kr{cJroTa opTo. paclnbrBarou}Iect Eecqnersar npo3parrHar )Kr4AKo vrru 6ecqserHHe Kpr{cranJrbr, crb (u.a.a.). Ha Bo3Ayxe He Co4epxanue opro$ocSopnofi KrrcJrorbr MeHee85 %. Kncrora oproQocQop Hafl. EecrlserHa-flnpo3parrHaq xuAKo crb. , MeHee 24,8 u se 6oree 25,2o/o. Ccigepxanueopro$oc$opuofi KlrcJrorbr He Ifnomuocmu.I,147 -1,150. Opuun. C6H3CH3(OH)z' HzO. (M.rur.142,15).5-MeuEn6esgor-1 ,3-guoil, MoHorHgpar. 5-Mernnpe3opur,rH. K cBery. FecqserHrrfi rcpucrarnuqecxnfi rropo[roK, rryBcrBLITeJreH Pacrnopuu B BoAe,JrefKopacrBopr4M gTaHoJre e$upe. B n TeunepamypaKuneHufl. Oxoro 290 "C. Teunepamypama*rreHun.Or 58 ao 61 "C. Ocunx(VIII) orcu4. OsOa. (M.u. 254,20). Ocuus rerpaoKcuA.

E4I

l,lronrqatrre Kpl{crannbl cBerJlo-xeJlToro IIBera I4JrrI KpucrannuqecKaq Macca K xeJlToro l{Bera. fizrpocronuqeH, qyBcrBI'ITeJIeH cBery. Pacraopuu B BoAe,cnapre 96 % n e$upe. xoHrefiuepe. Xpauxr B Bo3AyxoHenpoHlruaeMoM o Ocnux(VIII) orcu4a pacrBop 0,25 . Pacrnop 2,5 rln s 0,05 M pacrrope cepnofr
K}ICJIOTbI.

Ilar,ralufi. Pd. (A.u. 106,4). Merarr cepoBaro-6eroro IIBera. rncnote. Pacrnopnu B xnopl{croBoAopoAHofr llar.raAuq xJroplrA.PdC12.(M.rur.177,30). Kpncrannbr KpacHofoIIBera. rucnOre. paCTBopI{M XnopI{CTOBoAOpOAHofi B Pacrnopnvl B BoAe,aUeTOHe; flannaAns xJloprrAapacrBop I r nal;raArrr xnoprrAapacrBop{ror e 10 un renrofi xnopucroBoAopo4HofiKI4cJIorbI o6teMos xrororyrreHHrrfi pacrnop AoBoAtr cMecbropaBHbIX KoHrleHTpr{ponanuofi, o/o r,optst o6reua 250 tul. pa3BeAeHHoi,t tr T,3 KHcJIoTbI pr4cToBoAopo4uofi Ao pacrBop pas6anlxrcr .qByMto6reuaun repeA ncronb3oBaHr{eM Henocpe4crBeHHo
BOAbr.

KI'IcrIora. fla;rrnnu.rHoBafl KncJrora. C l sH3l COOH. (M. u. 256,42). ferc aAexaHoBat ueuryfixra6eloro IIBera. Kpucrannr4qecKl4e o/nvt B B flparruuecKu HepacrBopr{Ma BoAe,JrefKopacrBopt4Ma roptqeM cnl4pre 96

a$upe.

'C. Oxono 63 Teunepamypan.na6neHun. ilapaporaHl{rluHa rl{Apoxrlopu4. C 19H l 8ClN3. (M.rtr. 323,81). 4-[Ettc(4-aur'rnoqurclorexca-2,5-Aueszu rrHlrs. xnopl'IA. Senun)rraernnen] Kpucralnlrqecxxti rtoporxoKcllHeBaro-KpacHoro uBera. gTaHoJIe, HepacrBopl{MB npaKTr{r{ecK}r pacrBoprrM B Malo pacrBoprzMB Bo.Ue, eSnpe. KpacHyrooKpacKy,pacrBopbl B r4Me[orr{HTeHcHBHy}o Pacrnopu B BoAen 3TaHoJre cepHofi KVcnoTeI4 xnopl{cToBoAopoAuo[ xucloTe I{Me}oTx{enTylo oKpacKy' TeunepamypannazreHun.Oxotto 270 "C c pa3noxeHl'IeM. IIapaporaHuJIuHa o6ecqseqeuHufr pacrBop IroMeIIIaror B xon6y c npr{Teprofi creKnqsuofi 0,1 r napapo3auvrlv*a fr4Apoxnopr.rAa npo6rofi, npu6auxror 60 lan BoAbrrr pacrBopa 1,0 r Harpvfl cylrSvra 6esno4Horo, unlr pacrBopa2,0 r Harpr{r cylr$lrra, unz pacrBopa0,75 r Harpl4srlera6ucylrQllra upu6auxror 6 rr,rlKI{cJIorbI rrpu nepeMeilrvrBanvtr s 10 N{nBoAbr,3areMMeAJreHHo pa:re4eHsofi 7 ,3 Yo,3aKpblBalorron6y npo6rofi u rpoAonxnopr.rcroBoAopoAHofi xarcT rrepeMerrr4BaHr{e pacrBopenvfl; o6reru nonyrreHHoro pac'rBopa AoBoAtr Ao soaofi ao 100 vrn. Pacrnop ucnonb3yror qepe3 12 'I nocne npnforoBnennfl,. or Xpaurr B 3anrvrueHHoM cBera Mecre. lapaqeraMoJl, cBo6oAnufi or 4-aputro$eHora r43 flapaqeraMon nepeKprrcrannlr3oBbrBaror BoAbIvr cyurar B BaKyyMerprr reMnepaoC; upoqeAypy noBropnor He rex rrop, noKa napaqeraMoJl 6yAer BbIAepAo rype 70 )KrrBaTb cneAyrouee lIcnbITaHpIe.

u o6reruoe MeraHoJIa 5 r nrrcyureHHoroflaparleraMonapacrBoprror B cMecn paBHbIX BoAbrr{ AoBoArr o6reu pacrBopa rofi xe cMecbro pacrBopl,ITe.nefi 100 nal. Ao flpulantxror 1 ur cBexerpvroroBJreHHoro pacrBopa, coAepxarlero 10 r/n r^arpvs, rap6onara 6esnoluoro, nepeMellrlrBaror rr BbIAepHr.rrponpyccvp.au I 0 r l t :aarpr4fl, or xr,rBarorB TeqeHrre uun B 3auIr4rrIeHHoM cBera Mecre. He Aorxno flotBrtrbcs 30 vJrr4 oKpauuBaHrle. cl4Hee 3eneHoe llenran. C sHn. (M.rur. 72,15). flron\a*cfl.)KI,IAKocrb. flpospaunar, 6ecqnerHas,,BocnJIaMeH u pacrBopr4M BoAe,cMerrrr.rBaercs.arleroHoM,3TaHoJIoM s$upovr. c B Oqeur MaJro

dli . onoro0,63. ,T . O*ono 1,359.

TeunepamypeKuneHufl. Orono 36'C. BbrAep)Kl,rBarb cneAyroqee lleuraH, r4cnonb3yeNmrfi cuexrpo$oroMerpr{r4, AoJr)KeH s rrCnbrraHr{e. AOnOnHI{TeJrbHOe BoJIHrI BoJIHrI 200 nl,r; 50 Yorryu AnI4He MununanuHoenponycKaHue.20 rpr.rAnr{He % BoJIHsI 230 vrrr; BoJIHrI 220 urr1'93% npl,rAnLIHe 210 nu; 85 % rpu AJrraHe 240 svr. 98 % nprl Anr{HeBoJrHbr pacrBopa cpaBHeHrrt eol}. rrpoBoAr! r{cronb3yr B KarrecrBe Onpe4e.uenne fleHraHo.n.CsHl1OH. (M.u. 88,15). I-flesranon u-Av'uloertfi crurpr. BecuserHas)Kr4nKocrb. co B Yuepenno pacrBopr4M BoAe,cMelrrllBaerc,x cnllproM 96% n eSxpolr. llo .Or<ono1,410. Teunepamypa KuneHut Oxoro 137 "C. mpem-fr,eHrrrJroBbrfi cnnpr. C5H1OH. (M.u. 88,15). mpem-Aunanosrrficrll4pr. 2-Meru*2-6yraHon. flrotraflcs.)K{AKocrb. Jleryuar, BocnJraMeH B co Jlerro pacrBopr.rM BoAe,cMerrrr4Baerc.f, crnproM 96 o/o,e$rporra I4 rJIIdIIeprrHoM.

dii . onoro 0,81.

Teunepamypuute npedurbt nepeeoHrcu. 100 ao 104 "C; Aoirx{HorleperoHtrbct He Or MeHee %. 95 Xpanxr B 3aurrruleHHoM cBera Mecre. or Bololleprn4ponr. BogopoAa rreponcuAa pacrBop KoHrleHTprrpoBanHrrfi. Cir.r. POla repoKcrrA.

rIecorc
qaIIBerac pa3MepoM 6eroro r{Jrrr cJIerKa cepoBaroro Kpynunxu KpeMH[qLr4oncv4a .,crr.Iu 150.uo 300 lmrra. or Ilerporefinufi e$np (1) xr.rAKocrb, $nyopecqrpyer.llparne flpospavHar,6ecqnernafl., BocnJraMeHrrrorlarcr
Tr,rqecKr,r HepacTBopr4MB BoAe, cMeIIrLIBaeTct co cnI{pToM 96 %.

dii . o, 0,66r 0,664. to

Or Teunepamypuarc npedanbt nepezoHrcu. 50 ao 70 "C. Ilerpo.nefiHufi rQnp oco6oftoqrcrKrr nnw (2) rpe6oBa:aufl. nerporefisoro sQupa (1) co cneAyrcIqI.IMIr Anr .{orxen BbrAepxo.rBars
U3MCHEHI,IqMI.I:

dii . o, 0,630 0,656. ao

Teunepamypuarc nepezoHrcu. 40 ao 60 "C. npedenbt Or He AonxeHMyrHerbnpr.r reMrreparype "C. 0 ilerpo.nefiunfi eQnp (3) nerporefiuoro eSupa(1) co cneAyroqr4Mr4 rpe6oBanufl An.rr ,{onxeH BbrAepxrrBaru
II3MEHEHUSMH:

dii . o, 0,620 0,630. ao

Tennepamypuute npedenbtnepezoHrcu. 30 ao 40 "C. Or He Aorxeu MyrHerb rpv reMrreparype0 oC. Ilerpo.nefiuufi rQnp (4) rpe6oBannfl.Anr nerporefisoro eSupa (1) co cneAyroilIr{Mt4 .{onxeH BbrAep}rcrrBarr
II3MEHEHI4'MH:

Teunepamypuue nepezoHrcu. 40 ao 80 'C. Or npedenbr -Tprauurpo$enon. (NO2)3 (M. luxpn noBaflKrrcrrora. C6H2OH. u. 229,II). 2,4,6 flpzsuu larrur r'rac'tr,rHKr,r xenroro uBera. flAosura. Pacrnopnma BoAe cnupre 96 %. B r{ Xpanar,yBnaxHrr soAofi . pacrBop I oh. Pacrnop10 r/n. lurcpnHonofi rclrc.uorbr pacrBop IluxpnHonofi xncrorbr HacbrrrleHnsrfi I H 12,3r nnKprrHoBofi rzcnor:br3aJrlrBaror n BoAbr ocraBrqrorflpu qacroMes6arTbrBaHr{H 24'a. ua npo6rauu B 3arlr4rqeHuoM cBera XpaHxr B creKJrrHHbrx or cocyAax c [pr4TeprbrMr{ Mecre. flurcpuHosofi rcucrorbr pacrBop pacrBopa nlrKpzHoBofirncrorrr rpu6auxror 0,25 Mn paK 100 Mn HacbruleHHoro r.rpoBaHH o 20 %o or . crBopa HarpkrsrrrApoKcr{Aa KoHrI eHTp IlurcpuHonofi xlrc.uorr,r Hacbrulennrrfi pacrBop s a6co,rnrupoBaHHoM crrrrpre xncrorbr 3anuBaror100 rrr a6conrornpoBaHHoro clr{pra r4ocraB6,25 r nr{Kpt4HoBofi nrror npu qacroNa ss6arrrrBaHru Ha24'r. Xpaum B creKJrrHHbrx or cocyAax c [prrreprbrMr4npo6rauu B 3axI]rilIeHHoM cBera MecTe.BnaIIu oT orHt. p-IIuHen. CIoHro.(M.*. |36,23).6,6-!uveru*2-vervrres6uqur.uo(3.I.1)renraH. EecuserHat, MacJrrHlzcrat )Io4.{Kocrb 3arraxoM c cKr{ru lapa. B IpaxruuecKr4 HepacrBopr{M BoAe,cMerur4Baercr crnproM 96 % u e$npov. co d,., . Oxono 0,867.

dii . o, 0,659 o,6tl. to

TeunepamypaKuneHun 155ao 156 'C. Or r{HcroraB-unHeua, Xponrarorpa$uuecxar xcrroJrb3yeMororasosofi xpoMarorpas gorxHa 6rrrr HeMeHee 99,0Yo. Qnu, (M.v. 85,I 5). fercal'u4ponupr{Ar{H. Ilnnepn4un. C5H1 1N. peaKqr,rrc. EecqneruaA cJrefKa larrvt xenroBarororlBeraxr.rAKocrb, r4Meer rlenoqHyro o e$zpou r4rrelpoJrefisulr Cuerunnaercrc no4oil,cnuproM96 , s$upou. Teunepamypa KuneHun Oxono 106 "C.
@

nl .O*ono1,474.

flupug-2 -rlrraMr H. C5H6N2.(M. u. 94,12) . 2-Alansonupu4un. Kpynnue Kprrcriurnhr. Pacrnopurr.rBoAe, B cnvpre 96 % u e$npe. Tennepamypa KuneHun Ororo 210 'C. Tennepamypa nna*ileHua. Oxolo 58 'C. IlupugruaronaQro"u.C15H1rN:O.(M.*.249,27).l-(2-IIupugura3o)-2-na$ron. Iloporuox Kt4prr4qHo-KpacHoro rlBera. pacrBoprrM crurpre,MerauoJre roprqux pa3IIparrHvecKV HepacrBoprrMBoAe, B B u pacTBopax BeAeHHbrx rr{Apo Kcr4,qoB nlenoqHhrx MeTannoB. Teunepamypa merreHun. Oxolo 138 "C. pacrBop 0rl o/o. Ilnpn4H.naroHaQroJra Pacrnop1 r/n n oraHoJre. Irlcnatmauue qyscmqumerbHocmb.50 nrnBoAhr Ha K npu6annror 10 nan arlerarHoro pacrBopa pH4,4;0,10nan 6y$epuoro 0,02M pacrBopa laarpkrfl u0,25 MnpaoAerara ohpacrnopa crBopanvptrrr4nasoua$rora; nocneupu6annenun0,I5nrn0,5 ueau(Il) cynrSaraoKpacKa or AonxHau3MeHr.rrbcr cBerno-xenrofix $uoreronofi. Ilnpn4rrH. CsHsN.(M.ru.79,10). flposp auH 6ecqnernafl. rr{rpocKonvr.rrnafl. ar, xrrAKo Hecrb. O6nalaer xapaKTepHbrM )
npl,ItrHbrM 3alaxoM. fl.Aor,ur.. CNrenrrasaercfl nogofi 14 c cnr.rproM %. 96 TeunepamypaKuneHufl. Oxoro 115 'C. Xpanxr B Bo3AyxoHerrpoHrrrlaeMoM ronreiuepe. Ilnpn4un 6esnoAHHfi flupuguu cyrrrar HaA Harpr4xrap6ouaroM 6essoAHbrM, neperoHrfor. Snnrrpyror 14 oA(u/u). Boda. He 6oree 0,01 flnponuHorpaAHafl Krrcrrora. CH3COCOOH. (M.vr. 88,06). 2-OrconporraHoBat
KI,ICNOTA.

XraArocrr xeJrroBaroro rrBera. Cueuunaercqc rogofi, gTaHoJroM z e$zporvr.

d i i . o * o n o1 , 2 6 7 .

,ffi'

2,, . Oxolo 1,413. TeunepamypaKuneHut Oxoro 165 "C. -1,2,4-rpuot. flnporauor. C6H3(OH)s.(M.rnr. 126,11 EeHson ). Kpzcrarrrr 6eroro rlBera, noA AeficrBr.reM Bo3Ayxarr cBera reMHeror. pacrBopr4M yrnepoAa Oqess nefKo pacrBoplrMB BoAe,cnrrpre 96 % u e$npe, MaJro B 4ncynrSu4e. lIoA AeficrBr4eM pacrBopbr, a erle 6ucrpee ulerotrHbrepacrBopbr Bo3AyxaBoAHbre npuo6peraror Kopr.rqHeByro oKpacKyBcneAcrBrre a6cop6qrrr{Kr{cnopoAa. TeunepamypanJta*reHun.Oxolo 131 "C. XpaHxr B 3arquueHHoMor cBera Mecre. fllrpora.rr.lroJra rrleJro.rHofi pacrBop 0,5 r nuporanJronapacrBopsrcr s2 MJrBoAbr,cno6o4nofi or ynrepoAa 4voncvrqa.12 r KarruflrrrApoKcrrAapacrBopnor s 8 MJrBoAbr,cno6ognofi or yrnepoAa 4uoKcv4a. Herocpe4crBeHHonepeA r4cnoJrb3oBaHrreM cMerrrilBaror o6a pacrBopa. lnporcarexnH. C6H4 (OH)2. (M.r. II0,II). Eengon-1,2-puot. Eecqnerurr e vrv cna6o-xenroro uBera Kpr,rcrannbr.

20

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arleroHe, crl{pre 96 % u e$upe. Pacrnopru B BoAe, ntra*reHua.Oxotro102 "C. Teunepamypa or Xpanrr B 3arqnqeHHoM cBeraMecre. (M.t"r.386,37).fluporarexllHcyrrbC19Hr+OzS. fluporcarexHnosrrfi Qno.rreronrrfi. -T puruaporcu$yxcou-2"-cynrQoxplcrrora. So(rraneun.3,3',4'
IIBera. I,IJII,I 3eJIeHo-Kop[tIHeBoro flopomor KpacHo-Kopl,IqHeBoro o/o, yKcycHofi rucnore ne4ffrofi, pacrBopplMB Jlerxo pacrBoplrM B BoAer,rcrrr4pre96 n HepacrBopI,IM e$upe, alleroue, 6ensore. npaKTr,rqecKr,r c xenryro oKpacKy,ero KoMrIJreKchII4oHoM pH B raHrepna-ne 2,0-3,0 un4rararop r,rMeer B BprcMyTa Tex x(e ycnoBl4tx cl4HeroIIBeTa. r4onaBI,IcMyraor cunefi r xelroft. flepexo4 oKpacKrrnpu rprMoM rr{TpoBanvrur B Iqeloqnoil cpege lrH.qnKaroprlMeer xpacHo-QuoneroBylo oKpacKy,ero KoMnJIeKcbI MafHI,Iqr4uIrHKaB TeX)KeycnoBl{tx 3eJreHoBaTo-cI,IHefo c r.roHaMLI uBera. or rroHoBMafHrrr 14UI,IHKa 3eJleHoBaronpu [prMoM TlrrpoBaHr4r,r llepexo4 oKpacKr,r cunefi r rpauro-Suoreroeoft . InporcarexnHoBoro Sno.neronoro pacrBop. 0, I o/opacrnop. iluporcarexrrHoBoro Qnoneronoro HHArIKaropHafl cMecb 0,25 r m,rpoKarexr4HoBoro $uoneronoro u25 r Harpl4t xnoplrAa pacrlrparor B cry[Ke rr nepeMerrrr4BaroT. MononarprleBaf,corlb ll;rroru6on. C l sH t 4AsN6NaOsS. (M. r"r.572,3). CynrSapca3eH. -cytrcQorucnoru. -AlrasoaMuHoaso6ens or4'' (2-apceno-4-nurpo$ euwt)-l,4' Kupnuuno-rpacHufi [opo[roK. B Pacreopnrr,r BoAe,nerKo pacrBopr,rM pacrBope rerpa6oparanarpvrfl,, Miulo pacrBoB o [paKTuqecKr4 B HepacrBopr,rM alleroHe, xnopo$oprue, 6ensone. pLrMB crrprpre96 , B 6oparnorr,r6yQepnoM pacrBope (pH oKoJro9,2) uuauKarop rrMeer )KeJrryrooKpapO3OBO|O yCnOBrr{X IIBeTa. cBI{HIIaB TeX)|Ke c cKy; efo KoMtIJIeKcbI I4oHoM o/opacrnop nrrcrvr6osas2oA pacrBope I'nlP.arpvrfl.rerpaIl.nronoona pacrBop. 0,05 6opara. (Na2BaO7' 10 H2O). IIosnAoH. (C6HeNO)n (M.u. (I 11,I)n). flo.nuerHllnruIpponuAoH. Benufi rrJrrl)Kenroearo-6errtfi nop oruoK LIJIIIxnorrbt ; rl4rpo cKorlutleH. B B 96o/ou MeTaHoJIe, Jlerro pacTBopr,rMBoAe,cIII,IpTe WepeHHo pacTBopI{M aIIeToHe, e [paKTuqecKrr HepacrBopl,rM sQupe.

20 flo.nnnnnnnonufi crrrpr.(M.r"r.or 000ao 150000).

rpaHyJrbl Xerronaro-6enrrfi rropolxoKI{nu nony[po3paqHble HepacTBopacTBopI,IMc[I4pTe96 o , npaKTI,IqecKI{ B yMepeHHo Pacraopul,r BoAe, B pr4M arleToHe. B Bnsrcocma. 3 rc 70 ufla'c. Or qucno. 6oree280. He SQupnoe DB-5, SE5 2. Ilo.nu(4nnetnn)(gnQenun)cnnoKcan. rpyrn u 5 %o Cogepxr,rr95 % MeTI,IJIrHrIX Qenralruux rpyrn. HenoAsraxnarQasa,{nt riBoBofi xporuarorpaQnu. SE54. [onn(lurvrerr"rrxgn$eHnl)(4IlnuHn.rr)cunoKcan. o/o rpyml. rpyrr u I ohBI,IHI4JrbHbIx rpyfln, 5 $ewutbHbrx Co4epxur 94o/overunbHbrx ra3oBofixporraarorpa$nr,r. HenoAnnxHaxSasaAJI.f,

II o,rn (g nrvr ern.u) cnloKc aH Kayuyx cl4JrrrKoHoBufi (rr.rerur). Opranocr4Jrr4KoHoBrrfi nonurraep, r.rMerorquftuugnoryxu4xofi 6ecqnerHofi cvronrr. XapaxmepucmuvecKafl Bt3Kocmb. Orono I I5 rr,rn.r-I. I'IuQpaxpacuait cneKmpnoznou4eHufl,noryqensufi HaHeceHrreM BerrlecrBa, nprr Heo6xognuocrll ArrcneprvpoBaHHoro HecKoJrbKr4x B KanJrrxyrnepoAa rerpaxnopvAa, Ha AIICK HATpI/.flXnOpIrAa, He AOn)KeHVMerb IlornouleHufl npu Lnune BoJrHbr 3053 cu-t, coorBercrByroqero Brrnr.rJrbHhrM rpyrrnaM. Ifomepn 6 Mlcce npu GbtcyuunaHuu.He 6onee 2,0 o . Onpe4eneHr4e npoBoA rr3 flT 1,000 Il cyuar B BaKyyMe npr{ reMneparype 350 "c B reqeHrrel5 rr,run. He 6olee 0,8 o . Oupe4eneHl4enpoBoArr rr3 2,00A q cyrxar rpr{ reMrreparype 200 "C s reqeHze 2 .r. fI o,rn preru.n QeHnn cn JroKcaH Co4epxHr 50 % MertrJIbHhIX rpynn u 50 Yo $eunnruux rpyrr. Cpe4nax MoneKyrl'pHafl Macca - 4000. O.{eHr Br3Kar xktAKocrb (nx:xocru oxono 1300 lalla'c). Heno4nzxnax Sasa Anq ra3oBofixpouarorpa$ura. d,, . Oxono 1,09. r?i, . oKoJro1.540.
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Macn.f,Hncra.a, xeJIToBuras,I4nr.{ KopuqHeBaro-xeJlTa{npo3pa.u:aafl.)r.rJrr4 cJIerKaorraJe crlt4pyrouaq xr,rAKo cTb. Cnaeruznaerc.f, ao4ofi, graHoJIoM,orlrnalleraroM r,IMeraHoJroM, c npaKTvrrecKrr HepacTBOpr.rMa )nr{pHbrxMacJrax. B Ilnomuocma. Orconol. 10. florncop6ar 80. TnnH-8O xrrpHbrx KucJror,B ocHoBHoMoJrer4" CononzMep cMecH e$rpon pa3nr4trHbrx Hosofi KLIcJIorbI, cop6rra E ero aHrurpn1oB c grvneHoKcr4AoM npr{MepHhrM c coorHorueHlreM20 vronefi srI4JIeHoKcu1a KaxAbrfi uonr cop6zra v aHrvrHa A p I { A o Bc o p 6 z r a . -x Macnsnu crat xeJlToBarat ulrpr KopvsHeBaro e Jrr npo3paqnar xu.qKocrb. afl. graHoJIoM,DTr{JraIIeraroM MeraHoJIoM, CNaeruueaerctc noAofi, I,r npaKT}ItrecKLI HepacTBopr4M Xr{pHbrx MacJrax. B Ifnomuocma.Oxono 1.08. Basrcocmu. Oxolo 400 ulla.c npu25 oC.

000 900-1 llo.nucrnpo.n

onrl'I B ra3oBofi xponarorp aSzn' Cran4apr, I4crlonb3yeIurtfiAIs xa,nu6p

M*. Orolo 950. M*/IUn.1,10. iloln(unaHonponrlJr)cnnorccan

flom.rcmoKc aH, 3aMeIIIeHHsit sa | 00 % UIIaHoIIpOIIIJIbHbIMII rpyrnaMll'

IIonr [(qnaHonponu.rr)(Qenn.rr)] lanuerul] culoncan fpyIIII. rpynrt Co4epxlrr 6o/oUuanonponzntfeHllJrbHblx u94Yo ArIMerI'InbHbix ra3oBofixpouarorpaQux" uax Heno.qaux S azaAJUI IIo.nu(qnaHorlporrIrrXTXQeHnr)(7)(ruerun)(86)cuJIoKcaH ua rpyrrilaMvt', 7 Yo Sesa oh utrasonpo[TIJIbHbIMI'I floluculoKcaH, 3aMeuIeHHstit 7
rpyllraMl4 u na 86',/o IuMleruJIbHbIMI'I rpylnaMl'I' Hr,rJrbHbIMI,I

ra3oBofixpouarorpaQun. HenoAwrxnax Sa:a AJLf, rlo.nn(qnaHonponHJr)(QeHn.rrruerun)cnloKcaH rpyml. rpyrr u I0 o/o QeHumueruJlbHblx Cogepxur 90 % qrauonpoilr,rJrbHbrx HenognnxHar $asa Ant ra3oBofixpouarorpaSnu. Crrl. IIo.nr[(quaHorponrn)rvrernnseHnJrMerrl.rrcnnorccanl. flo.nn[(unaHonpocn.rroncaH. nnn)(nernn)l [(r[enn.rr)(nrerul)l Jlo.rrn [(Qenn.[)(uernn)lcHJIoKcaH [(uuaHorrporrHl)(uern"u)l o/o vrerpyril, 25 % $euunsnslx rpyrn u 50 Cogepxur 25 % IIraHonpoflIIJIbHbIx - 8000. Hafl' rpynr. Cpe4HxrMoneKyntp vracca rr.rJrbHblx 9000 ulla'c). O.reHrBr3KatxlrAKocrb(exsrocrr oKoJro

d]l . onono 1,10. nli' . Oxono 1,502. 2 Marcporo.n00. 200. ff o.rrnrrnneHruruKorls Crrl. 300,nnu 400,urH 1000 trlrn 1500,uttn 20 000.cu. Ma, ilonuoruleHgrrrKoJ6
KpofoJrbl

[o.nnernneHnrrrKoJrbaArrrll{Har. (C8HI2O+)n.[M.rur.( 172' 18)n]' Bocxoo6p a3nafl vracca6eloro lrBera' B llpaxruuecKl4 HepacrBopl{M BoAe,pacrBoplrMn xnopoQopue' Teuneparnypa merreHun. Oxotro 43 "C. bcyKII I{Har. (C 6H3O+),r'[M. tnr'(l 4 4,12)n]' flor nrrun eHruLrKorI Kpncrannuqecxufi [opou]oK 6eloro uBera. B llparruvecKl4 HepacrBoprlM BoAe,pacrBoplrMs xnopoQopue' TennepamypannazreHua. Oxono 102'C. agHslfi rens AJIfl xpoMarorpaQun Ilonr.pSupnufr rIIApoKcIrJIIIpoB qacTI4II, nuerctt1ufiru4poQlubHyro rloBepxHocrbK rlIfeln c He6onrruuMpa3MepoM ilo rpyilralr. tr{treer rpeAen gKcKJIIo3HIr AeKcrpaHy c rrlonerynxpuoil ApoKclrnbHbrM uaccoil or 2 x 105 2,5 x 106' ao llponano.rr. C3H7OH. (M.n. 60,10). 1-flponanon. ru-llporaHorl.Cnupr rporunosHfi. llpospaunaq, 6ecqserHat )Io4AKocrb " crrlproM. c noAofi u96 a/o Cl.remzsaercfl

dli . Ononoor 0,802 0,806. ao

Teunepamype KuneHufl. Oxoro 97,2 "C. Teunepamypuarc npedenbt nepezoHrcu. 96 ao 99 "C; AonxHo rreperoHrrbcs Or He Meuee %. 95 2-IlponaHon. C3H7OH.(M.u. 60,10).?Isoupouurosnficnr{pr. llpo:pavHar, 6ecqne rnafl, BocnJraMeH flrourafrcs xr4AKo crb. CMerrneaercr no4ofir4crrproM 96 %. c dii . O^ono 0,785. Tetrnepamypa KuneHutOr 81 ao 83 "C. 2-lponanon oco6ofiqrlcrorbl. fio;rxen BhrAepxrrBaru rpedonanvrfl,n.nfl, r{3onponaHo;ra14 cneAyroqn AorronHlrreJrbHbre e rpe6onaHnx : t?" . Oxono1,378. Boda.He 6onee4,05 Yo.Onpe4eneHrre npoBoArrus 10 r. ohnpuAnr.rHe MuuunanaHoe nponycKaHue. % ilpr4AnrrHe 25 BoJrHbr nrv,;55 210 BoJrHbr 220 r'vr;75 % rpr{ Anr.rHe BorrHbr nu; 95 % npr4.unrrHe 230 BorrHbr una; 250 98 % rpil AnuneBorrHbr lrrtvr. 26A pacrBopacpaBHeHr,rr Onpe4eneHue npoBoArr,r.rcnoJrb3yqKaqecrBe B BoAy. -Aruuno- -nponanor. fiponauonaMnH. H2N(CH2)3 (M.r"r. 5,1l). 3 OH. 7 I flpo:paunax, 6ecqnernafl, Br3Kar)Kkr crb. AKo d,i . Oxoro 0,99. Teanepamypa nna*reHua. Oxonol1 'C. (M.u. |02,13).flpo:paunax,6ecqnerna.fl Ilponu.uallerar. C3H7OCOCH3. xulKoorb. dll . O*ono 0.888. Temnepamypa KuneHuz Oxono 102'C. Tavnepamypa nnasneHua. Oxono-95 "C. Ilponn.rrenrurlrKorrb. (M.r"r. CH3CHOHCH2OH 76,09).(RS)-IIponau-|,2-guon. flpoepaunas,6ecrlsernafl.,Br3Ka.f, xr{AKo crb. Cueruunaercrc rogofi rr cnrdproM %. 96 Tetwnepamypa KuneHufl. 184ao 189'C. Or

n',i.oxonotr,461.

dii " or l,o35 1,040. ao n1l. o, 1,431ao 1.433.

(M.u. 58,08).1,2-enorcznponaH. IIpouuneHoKcHA. C3H6O. EecqserHas)Kr,rAKo crb. CnaenrHeaercr c[HproM 96oh, sQuporrl. co Ilponnnnaparr.rApoxcn6eHsoar. (M.r"r.180,20).flponvnnapaC6HaOHCOOC3HT 6en. flpon un-n -rvrqporcz6ensoar. Eenrrfi Kpr{criurJnr.recrufi noporxoK. pacrBopt4M BoAe, pacrBopr{M cnr,rpre % r.rMeraHoJre. O.IeHr MiIJro B JrerKo B 96 'C. Tentnepamypa ma*neHua.Or 96 ao 99 (M.u. 74,08). lponnonoBafl KrrcJrora. C2H5COOH. Macnguncrasxtr4AKocrb. Pacrnopuir.ra cnr4pre96 % u s$upe, cMerrrr.rBaercrnoAofi. B c

dii . o*ooo 0,993.

/1.o .Oxotro 1,387. TeunepamypaKuneHun Oxolo 141 "C. TettnepamypanilarneHzt. Oxono -21''C. IlponnoHosrrfi arIbAerI{A.C2H5CHO.(M.u. 58,08). flponanalr' B Xurrocs. Jlerro pacrBopr4M BoAe,cMerrrlrBaerctco cnIaproM96% u eQzporvr.

dii .o*ooo0,81.
z, . Orono1,365. 49 Oxono "C. KuneHun Teunepamype
Teunepamypama*neHun. Oxono -81 "C. (M.u. 130,I 5). Ilpounonosrrfi aHrIrApI{l. (C2H5CO)2O. llpospavuas, 6ecqseruafi xI4AKocrb. Pasraraercr B BoAeI{ cnlrpre 96 yo, cMellrlrBaerct c eQupol't.
20

1 dii .O*ono ,01.

Orono 167 "C. TeunepamypaKuneHufl. IlponuouoBoro aHrrIApHAapeaKTlrB reAqHofi 1 r ronyolcynrsonoeofi rucrorbr pacrBopttor n 30 rrln yrcycnofi KI4cJIorbr urrpu6ar.lqrcr 5 Mn nponl,toHoBoroaHrr{ApI'IAa. I,Icnonrsylor qepe3 15 rvrunnocJle npl{roroBJlennfl,. CporroAHocrrl- 1cyr. (M.u. 461,38). llporpannofi .repnsrfi 11. C20H12N3NaO7S. Hurput 2-rugporcu-1-[(1-ruApoxcrlrraQr-2-utr)asol-6-nrErpoHaSrasmu-4-cynr$oHar. Spnoxpol,r uepnrrfi. flopouror KopfitlHeBaro-qepHoroIIBera. PacmopnnaB BoAeIr cilrlpre 96 %. xoHrefinepe, B 3auI[uIeHHoM or cBera Mecre. XpaHrr B Bo3AyxoHenpoHr4rlaeMoM llporpannoro qepHoro 11 [rnA[KaropHar cMecb I r uporpaBHoro qepHoro 11 cMeruusarorc 99 r uarpuq xropl4Aa' cruecu pacrBoprror B Irlcnumauue Ha qyscmsumenbHocmb.50 rur I,IHALIKaropuofi Koropoe AonxHo 100 un BoAbr;floqBrrercr Kopurruenaro-SnoneroBoeoKparupIBaHLIe, 10 pa3BeAeHHoro %. 0,3 upu npz6aBJreHr4r,r ur pacrBopa aMMLIaKa uepefiru B cr,rHee o/opacrnopa MarHLlt{cynrSara oKpacKa IIpu nocneAyrcrqeM upu6annenuu 0,1 rvrl 1 na r43MeHLITbcr SrEoneroByro. AoJDKHa or roureftHepe, B 3aIIInqeHHoM cBera Mecre. Xpamr B Bo3AyxoHerrponktUaeMoM llpounufi cuHnfi B, conr. Cr4HnCl2N+Oz. (M.n. 339,18). 3,3'-,{unerorcu(6uQ enun) - 4,4' -6uc Anasonprs. ALIxnoprIA. IIBera. floporuon reMHo-3eJleHoro xJropI'IAoM. Pacrnopuu B BoAe. Cra6unustlpoBaH IIITHKa or ronrefiuepe IIpH TeMIIepaType 2lo 8 "C. Xpanxr B Bo3AyxoHerpoHl,IqaeMoM llpounrrfi rcpaunrfi B, cols. Cl7Hl3N3OsSz.(M.t"r.467,4).2-Meroxcll-4-nurpoxnclufi na$ra;rzn- 1,5-4r'rcynrQoHar. 6eHsor-Auit3oHl,tt lloporuor opaHxeBo-xeJlroro IIBera. pacrBoplaM cul'Ipre 96 %. B B Pacrnopurra BoAe,MaJro rourefiuepe, B 3aIIIuUeHHoMor cBera Mecre rlpll Xpauxr B Bo3AyxoHerrpoHrrrlaeMoM oC. or TeMrreparype 2.qo 8

il

fly.neroH. Cl0Ht60. (M.rnr. 152,23). (R)-2-I,Isorporu{rrr{Aen-5-uerunqr.rKno(+)-r-Menr-4-es-3-on. reKcaHoH. Eecqneruar, Macrfllavtcra-f, xcI4AKo crb. flpamlruecKra HepacrBoprrMBoAe, B cMerrrr.rBaercr crrr4proM co 96% n e$upolr.

4li . Ororo 0,936. n'i,.or 1,485 1,489. ao

o. Ld], . Or +19,5so-122,5 Tennepamypa KuneHuz. 222 to 224"C. Or qr4croranyJreroHaueroJra, Xporraarorpa$nuecrax [pr4MeHreMoro ragonofi xpoMaB rorpaSuu, AoDKHa 6rrrr HeMeHee 98,0 oh. ' PaMnoga. C6HI2O5 HzO. (M.t"r.182,17). L-(+)-PauHo3a. 6-,{eorcu-L-Mal+rosa. Kplrcrannz.recrufi noporxoK 6eroro rlBera. Jerxo pacrBopr,rMa B BoAe. coAepxauefioxoro 0,05 ohNHr). lal", . Or +7,8 4o *8,3 ' (5 o pacrBopB BoAe, (M.u . 420,4).3-fir4poxcu-512-(3-rn4porcu-4-MeroKcrrPanonrnuuu. C21H2aO9. Senran)erenun] QeHunB-D-rnroKorrprpaHo3r{A. Kpncrarnr,r.recrr4fi rropouroK xeJrroBaro-ceporo rlBera. Pacrnopurvrcnvpre 96 % r{ MeraHoJre. B Pacrnop KpaxMaJra-rrnAuKarop. Kp axua.rrpacrBoprrprrfi. Cna. Pacrropu*rrrfi npacHrrfi 1. Crvr. Clgan rcpaurufi G. Pearcrnnnan-Vprca K 35 run BoAbr npunr{Baror irpu noMerrrrrBasupt un cepnofi Kr4cJrorbr 65 KoHrIeHTprrponauuofiI{ B errleropxuufi pacrBopBHOcsr0,03 vr.u o/o pacrBopa I0 xene3a oKrrcpacrBopa Ao 50 oC upu6aunor 0,2 r Horo xnopr4Aa.flocre oxnaxAeHr{r /r-nHMerr.rJranauuo6eu3aJr bAerHAa. qepe3 Peaxrur r{c[onb3yror 24'r r;.ocile npuroroBJreHr4r. -7 CporfoAHocrr{ cyr" Pearcrun,{pareHgopQa Pacruop 1. K 0,85 r Br{cMyralalaTpara ocHoBHoro npu6aurrror 40 rran BoAbr, yxcycnofi Kr,rcJrorbr 10 rran KoHueHTpr{poBaHHotrt u ss6arrbrBarorB Terreur,re l5 vrun. PacraopII. 8 r KaIrvrs, pacrBoprror s 20 NarBoAbr. iaoguga CueurzrarorpaBHbre I o6reruupacrBopoB u II. K 10 rran ronyqeHHofi cuecu npu6aBiIrIor 100 runBoAbr u20 ul yrcycnofi KLrcJrorbr KoHrleHTpr,rpoeaunofi. Pearcrun,{pareu4opQauo4lr$nqlrponanHrrfi PabrnopI. K 0,85 r BrrcMyraHr.rrpara ocHoBHoro npu6aurrror 40 rran BoAbr, yxcycnofi KrrcJrorbr 10 rran KoHrleHTpnponauHofi sg6arrurBarorB TeqeHr,re ra 15uun. PacrnopII. 8 r Karrutfl. trrotuqapacrBoprrcr s 20 MJr BoAbr. (ocronnofi pacrrop). PacrnoprrI u II cMerur,rBaror Henocpe4crBeHHo pacrBopacMerur.rBaror nepeAnpr,rMeHeHzerr,r ocHoBHoro 5 Mn c o/o 5 prn 1 ao4noro pacrBopa acxop6uuosofirzcroru u 5 MJr cnr{pra 96 %, Pearrus Mafiepa pacrBopnor s 60 MJr 1,358r pryru AprxJropr.rAa BoAhr, npu6auaror pacrBop5 r raru-f,
@
-20

pacrBopa noroft ao 100 rvrn. i'ro4ura s 10 Nan BoAbrrr AoBoArr oGrerra Pearcrus Mnr;rona MeroAoB. loroesr no oAHoMyr.r3 l. 10 r pryrlr Hzrpara sarucHofi pacrBoprrcr n 8,5 Mn a3orHofi rucnorrr upaz6ayJrrror AsofiHHN{o6relrorra BoAbr;rlpo3patlHblfi pacrnop cJrl{Baror. 2. I0 r MeraJrJruqecrofipryrlr pacrBoprrcr s 15 MJra3orHofi rucnorrr KoHIIeHTpt4popacreop cJII,rBaIor. saHHofi urtpu6antrqrcr 30 Mn BoAbr;npo3parrHbrfi ara(Il) rqe.rroqnofip acrBop. PeaKus Hecc.rrepa.Cu. Ka.nnn rerp afi oAoMeprcyp [IAa pacrnop P6. Pearcrrls O.rrnnopra. Crr,r. .{nvreru,r anrnnodeu3aJrbAef Pearcrun Tu.ne. Cna.Harpnr rnnoQoc$ura pacrBop. Pearcrnn (DernHra. Cru. Me,uHo-Taprparnuft peaxrnn. Pearcrun Olrurepa Pacrnop I. B cocya, coAeplKarlrfi 110 r nnpurillna (co4epxarue BoAbIne 6oree JrbAoM, lpoilycKaror o6egsoxennufi cepHrrcrblfiras 4o npz0,1o/o)14 oxna)KAaerr,rnfi seca27r. pacrBopa I - 6 uec. Cpor roAHocrr,r Pacrnop II. B cocya rr3 opaHxeBoro creKJra c rpurreprofi upo6rofi nolteqaror npo6ne 600 nrn MeraHona(co4epxaru4eBoAbr 6oree 0,1o/o)u75 r itoga,3aKpblBaror rofi, nepeueilrvBaror r4ocraBJr{ror croqrb Ao rroJrHoropacrBopelr^ns.fio2'a. pacrBopa II - 6 uec. Cpor roAHocrr.r B rrepeAucrroJrb3oBaHrleM cMerrrlrBaror coorHoPacrnopu I z II HerrocpeAcrBeHHo illeHuvrl:2,17. Turp ronyqeHHoro peaKTIzBa oKoJIo 0,004 r/rvrn. pearcmue Pas6aeneuuurit @uruepac rr4TpoM oKoJro 0,001 r/ur roront! cMeIIrIlBa{rropacrBop c MeraHoJroM coorHorrreHr.ru I:1, u ilprrMeHrlor ronbKo rIpI4 lyueHuufi B rr gneKTpoMerpv ecKoMorrpeAeneHrrr.r HerrHofiroqru rr,rrpoBaHrlr. Ko Vcmauoerca mumpa. Orono 0,04 r (ro.*rar uanecxa)BoAbIBHoc{TB cyxyto ron6y, coOuurepa, npu6awxx B KoHIIerI{ueraHoJra,r,rrr{Tpy[or peaKTr{BoM Aepxauyro 5 rr,rn TpoBaHV-rr 0,1-0,05 rr,rn. no flapannenbHo rrrrpyror 5 lrr MeraHoJra. (Dzurepa (W), e rpaMMax Ha MrrJrJrltJrr{rp, no Bbrtrr4cJrrror Qopuyne: Turp peaKTr,rBa a

vy':_. vr -vz

rAe: a-HaBecKaBoAbr, B fpaMMax; Ouuepa, r{3pacxoAosaHHrrfi Ha rr4TpoBaHrreHaBecKr{ V1 - o6teM peaKTr4Ba BOAbrB MeTaHOne, B Mr4JrJrrInr,ITpaX; V2 - o6reM peaKTXBa (Dvurepa, r43pacxoAosaHHrrfi Ha rr4TpoBaHlre B KoHTponbHoM orrbrTe, B MrrJrJIIlJIIITpax.

Ilpunevanun 1. Pearrxn Oznrepa o[prcaHHofo cocraBa HerrprrMeHr.IM analrv3a coeAI4HeLnfl. pearruna (Hauuit, pearrrpyroqux c oAHr4M r4JruHecKoJrbKr4 KoMloHeHTaMvr Mr4 MepKarrraHbr, nprlMep, acrop6uHoBar Kr4cJrora, cynrQu4rr, rr.rApoKap6ouaruu xap6ouarur rlerorrHbrx MerannoB, oKctrAbllI rr.IApoKcI,IArI MeraJIJroB, anbAerr.rAbr, KeroHbrLr[p.). Kr4cJlorax npu 2. lttx orrpeAeneHrr{ BoAbr rap6oHuJrbHbrx e coegr.rHeHr{qx cr4JrbHbrx u gneKTpoMerpuqecKoM r{cflonb3oKoHeqHofi roqxz rr{TpoBaH[r Mo)KHo orrpeAeJreHr{r4 @

BarbpeaKTr4B Orzrrrepa Br,rAord3MeHeHHoro cocraBa,coAep)Kaxluft sNrecroMeraHoJra guu ernnQoplrarrau4. N,NpacrBopoB H II. 3. lonycxaercs,ucrroJrb3oBaHr{e KoMMepqecKr4x I Peanrun Oo"rrnHa B rpyrno4oHHyro xon6y noMeularcr un BoAbr, r narpux nonr$parrara.2,5 r 10 70 rucrorrr, 5 rran % Qoc$opsofirucnorbr,Kr4rrrrqr o685 c SocSopnouonu64euosofi .r, 3areu oxJrax(Aalor, parHbrM pas6ann*or no4ofi ao 100 MJr, xonoAr{JrbHHKoM xo2 poIIIo [epeMerrrnBaror. Xpauxr B cocyAaxopaHxeBorocreKJra ilpr,rreprrtrr,ru upo6KaMr4. c Pearcrns(Dpe4e. ArrproHuqMorr64ara pacrBop e cepnofi Kr.rcJrore KoHueHCl,r. rpnponauHoft. Pearcurnlllnefiqepa 10 r ue4u(Il) cynr$ara pacrBop*or s 100MrrBoAbr, npz6auxror l0 ohpacrBopHaTpr4flfrrApoKcrrAaB AocTaToqHoM rilI'para oKprcuMeAr4 KoJrr4rIecTBe, AJrr ocax(AeHr4fl peaKrlr,rr co6nparor nocneAHr,rfi $u.rrrrpe r4[poMbrBaror eoAofi Ao Hcqe3HoBeHuq ua Ha cynn$arur. Bnaxurrfi oca4ox pacrtsopfiIorB Mr.IHr.rMaJrbHoM KonrirecrBe l0 oh pacrBopa aMMr.raKa, seo6xoANuoMAnr noJrHoropacrBopeHr.r{ ocaAKa. Xpanxr B creKnqHHbrxcocyAax c rpnreprbrMr.r upo6rarran. Pearcrun IIIrarq. CMeruzsaror5 la.uxnoprrcroBo4opognofiKr.rcJrorbr KoHrIeHTpr.{ponaunofi, 50 un 96 % crrr4prau I r n-guMerr{Jr-aMr{Ho6esgamEerv4a; [ocJre ronHoro pacrBopeHur AoBoAqro6reu pacrBopa 96 % cnrrproM ao 100 rr,rn. Pearcrun 3.urnaHa. Cru. 5r5'-[uruo6nc 2-nnrpo6eHsofiHas Kr{cJrora. Pe:opunH. C6H4(OH)2.(M.r. 110, 11). u-fiuoxcu6eHsor. Berufi uru 6enuil c xeJrroBarbrM otreHKoM Kpr4crannu.recrufi ropo[roK. lloa aeficTBVeM CBeTar{ BO3AyXa KpaCHeeT. pacrBopr.rM o$upe. Oqesr JrefKopacrBoprrMB BoAerr crrr4pre96 oh, JrerKo n TeunepamypannarreHun. Or 109 ao II2'C. TeunepamypaKuneHut Orono 281 'C. PeropuHHapacrnop 2 o/o K 50 r pe3oprlr{Ha Lt npu6aerrrcr 50 nrnBoAbr ocraBmror npr4iracroM sg6anrHsaHrara sa24 v. Pacrnop Qlrnrrpyror. Xpaum B xopomo yKynopeHHbrxcocyAax opaHxeBoro creKJra,B 3auruuleHHoM or cBeTa MecTe. Peropunua pacrBop e 6eHrore K 1,5 r pe3oprluuanpu6anJrrror 1 n 6engonav ocraBmror npr4qacroM eg6anrrrsaHur,r ua24 u. llpospauuufi pacrnop cnrlBaror. XpaHxr B creKJr.f,HHbrx npo6rauz, B 3arrlr4rrleHHoM cBera cocyAax c npr,rreprbrMra or Mecre. Pe:opqnna peaKTHB K 80 rr,rn xnopprcroBo4opo4Hofi Kr,rcJrorbr KoHrleHTprrponanHofi npn6aunor 10 nrn o/opacrnopa pe3opuuHa, 0,25 rran pacrBopa 2,5 %ouelr(Il) cynrQara r AoBoA-sr 2 eoAofi Ao o6rerraa 100,0 lan. tr4cnomsylor trepe34 .r uocre lprlroroBnelevfl. XpaHm rprr reMrreparypeor 2 Eo 8 oC. Cpox roAHocrrr * 7 cyr.

PeropqnHossrfi cnnnfi . Cu. JlanrvronA. Aru*roH[s peftnexar. Pefinerar aMMonltfl. Crra. Pefinexara aMMoHIrnpacrnop 8 7o 8 r pefineKara aMMoHr{r pacrBoprror B BoAe H AoBoAtr o6reru pacrBopa soAofi

ao 100rvrn.
Pacrnop [pLIMeHtIor cBexenpuroroBJleuHhlM. Pr6oga. CsHlgos. (M.r"r.150,13).D-Pu6osa. cr<ufifl opolroK. Eenrrfi Kpl{cranJrl{qe pacrBopl{Ma B cnnpre 96 %. Pacrnopurua B BoAe,MuIJIo Or Teunepamypanna+neHun. 88 ao 92"C. KIrc(M.rtr. 298,45).l2-fia4porcl{oJrellHoBarl Puqnno.ueunoBar KrrcJrora.C18H34O3.
JIOTA.

Macna KacropoBoro. [oJIyqeHHbIxrHApoJIIt3oM Co4epxur cMecb xktpHbrx KHcJror, IIBera. Brsra.f, )KIrAKocrbor x(eJrroro Ao )KeJIToBaro-KopI'ItIHeBoro pacrBoB llpaxruuecKr{ HepacrBopr4Ma BoAe,orreHbJIerKopacrBopl{MaB 9TaHoJIe, pilMa e sQrape.

dii . O*ooo0,942. nll . O*ooo 1,472. 285 Oxotro 'C c piunoxeHveM. ma*neHua. Tetvnepamypa (M.n. PoAannHB. C2sH31C1N2O3. 479,0).[9-(2-Kap6oxcuSenun)-6-(4nerurxJloplrA. arrauno)-3H-rcanres-3 -rnzgeH]AIrorI4JIaMMoHLI-fl Kpucralnbr 3eJreHororlBera rrnrdrroporuoK KpacHonaro-$uoneroBoro IIBera. Oqenr JrerKopacrBopldMB BoAeIr crlvpre 96 %. 2-r'opPryru(I) HIIrpar. Hg2(NO3)2'2H2O. (M.r"r. 561,2). Prym(I) a3orHoKLIcnas, nax. Pryru(I) asornoKplcJlat, Akrru4par.Pryrn sarcucnofi HI4Tpar. BbIBerpLIBaIorctHa Bo3Ayxe.-fl4oeur. 6e cqnerHue KpI,IcranJIbr, Pacrnopnrr.taB a3orHofi ruclore, pacrBopax Pearrnpyer c noAofi rrpu pacrBopeHr4rr. I{ aMMI4aKa aUeTOHe. Pryrr(II) x.ttopltg. Pryru AIrxJIoprIA. Crr,r. Pryrr. Hg. (A.ir,t. 200,59). KanJIlI,KoXnArcocrr cepe6pzcro-6eloro rlBera, paccblnalou\afrcfl na cQepn.recKl4e npI,I TpeHIru o 6ylaary. cJreAa TopbreHe ocraBJltlor MeraJrJrrrtlecKoro

KuneHufl. Orono 357 'C. Teunepamypa Pryru(II) HrlTparapacrBop n asorHofiKllcJrore pryrn ocropoxHo pacrBoprror B 27 mn agornofi KIrcJIorbI Arrlrasuefi;flonyqeH3 nan o6reuoru BoAbI. nufi pacrnop pa3BorflTpaBHbrM or Xpanxr B 3aIIIuueHHoM cBeraMecre.Cpor roAHocrl{- 2 t'aec. Pryru oxHuroil (M.r"r. 318,68).Pryru AI4aIIerar. Pryrn(II) aUerar. (CH3COO)zHg. arleTaT. Kpucrannu 6enoro IIBera.-flAoellr. pacrBopuM cnl{pre 96 %. B pacrBopuM Bo.ue, B Oqeur JrerKo Pryrn(II) arlerara pacrBop 6egeoAHofi, r AoBoAtroGrervr 3,19 r pryru(Il) arlerarapacrBopsror yrcyurofi KLIcJIore pacrBop noJlyqennrrft pacrBoparofi xe ruclorofi lo 100 un. Ecrtt neo6xoAuMo,

d1i. o*ono13,5.

HeI"ITpanH3yIor M pacrropoM xropnofi Kr4cJrorbr, 0,1 trcrronb3yr B KaqecrBe u;g{Er4Karopa 0,05 rran pacrBopa Kpr4craJrnuqecKoro Svroleronoro. Pr1-ru orcucnofi arlerara pacrBop 5 r pryru oxllcnofi auerara noMeqaror B MepHyroxon6y BMecrr.rMocrbro 100 nrn rapar-'rBopf,Iors renrofr yr<cycuofiKkIcJIore re4ruofi. Ilocle oxJrDKIeHur o6reu pacrBopa -foBo,Irr yrcycuofi rracnorofi ne4ruofi .qo MerKr,r. ^\pauxr B cocyAax opagx(eBorocreKna B 3arrluueHHoM cBera Mecre. or Pacreop lrcrronb3yror cBexe[pr4roroBJrenHrrM. Pryrn(II) 6ponn4. HgBr2. (M.r"r.360,39). pryru 4u6pol,rrag. Kpucrallbr vtrvt KprrcranJlrl.recr[fi [oporroK 6eroro r4Jr]r cBerJro-x(eJrroro uBera. \la.'ro pacrBoprrMB BoAe,pacrBoprrMB clupre 96 %. Pryrno-6poMrrAHar 6ynrara B npxvroyfonbHyro qarlKy rroMerrlaror 5 o/opacrnop pryru(Il) oporrazAaB crrHpre 96oA, rlorpyxarcT B pacrBop KycotrKl4lenofi $nnrrponansuofi 6yvaru, c [JrorHocTbro80 r/rvl2 (cr<opocrr SunrrpoBaHrrr, paBHar BpeMeHu SlrnrrponaHr{r, BbrpaxeHHolry B ceKyHAax, [pr4 sunrrpona[Hvt 100 MJr BOAbr trpu reMreparype l0 'C qepe3Snnrrp c noBepxHocrbro10 cnr2 rrocrorHHoMAaBne 14 uuvt6,7 rfla: or 40 :o 60 c), pa:rrepou 1,5 x 20 cw, cnoxeHHbreBABoe. Eyuary roABerrrr.rBaror HeMeHa Ta-uFIecKyIo HI'ITb,[o3BoJrtt cretlb us6rmry xl4AKocrr4, cylrrar B 3aIrIrrUeHHoM or cBera Mecre. Orpesaror no 1 clurc Kax(Aoro KoHrIaxax4ofi rroJrocKLr Hape3aror r4 ocranbHylo qacrb 6yrtaru Ha KBaAparI4KH cropouoft 1,5 cu unv WrcKkr co Ar,raMerpolr 1,5 cu. -\paHxr s xoHrefiHepeco creKJrrHHofi npo6xofi,3aBepHyroMB qepHyro6yrraary. Pryru(II) fiolnl. HgIz.(M.r"r. 454,4). pryrr.r tui.ro1ut. pryrr fiognax. fl-.lorsrrft Kpkrcrannr4.recrufi[opo[roK rpKo-KpacHoro rlBera. \{a,ro pacrBoprrMB BoAe,yMepeHHo pacrBopr,rM arleroHe, cru{pre 96o/o uesupe, paB crBoprrM s ras6Hffie I0 Yo pacrBopa KaJrklxitoliu$a. XpaHxr B 3arrlr4rrleHHoM cBera Mecre. or

pryrz Ar.rHr.rrpar, Pryru(rl) Hrrrpar.Hg(No3)2. Hzo (M.r"r.342,62). MoHoruApar.

Pryrr(II) a3orHoKr4crraq, MoHorr.rApar. Eecqnernrr e vnv cnerKa oKparrr eHHbre Kpr{crarrur. fvrp o cKorrvqeH. Pacrnopnrra BoAeB npl,Icyrcrsuu He6oJrbrrroro B Korr4rrecrBa asorHofi Kr,rcJrorbr. XpaHm B Bo3AyxoHenpoHrrllaeMoM xourefiuepe, B 3aurnqeHHoMor cBera Mecre. Pryrn(II) oKcr.rA. Hgo. (M.,ur. 216,59). pryrN oKcr4A xerrufi. pryru oKcr.rA. flopouror or )KeJrrofoAo opamKeBo-xeJrrofo rlBera. flpaxrz.recKr{ HepacrBopr.rM BoAe14 B cflr4pre 96 %. 'Xpanar B 3arrlrrueHHoM cBera Mecre. or Pryrn(II) cynrQara pacrBop I r pryrn(Il) orcz4a pacrBop{ror B cMecfi 20 wllrBoAbrw 4 w cepHofi KrrcJrorbr KoHueHrpr{poBasuofi.

pryru su(ruoquauar). Pryrn(rr) rrroqrranar. pryrlr poHg(SCN)2. (M.rur. 316,76).

JaHr4n. Kpucrarur.rqecxufi noporroK 6eloro r.IBera. OqeHrMarlo pacrBopllM BoAe, B Miuro pacrBoprrM crnrpre96Youe$upe,pacrBopr,rM B pacTBopax B Harpr,rr xJropr,rAa.

Pryrn(II) rrrour{aHarapacrBop 0,3 r pryrn(Itr) ruounanarapacrBoprrcrB oranoJre AoBoArro6reu pacrBopa r4 reM xe pacrBopr.rreneM 100rran. Ao CporroAnocrr -7 cyr. Pryru(II) xJropuA. HgCl2.(M.rur. 271,49).Pryru gvxnoprA. Cynevra. Tsxerufi 6enrrfi noporuoKunraGenrre Kprlcrannbr. -flAosllr. Pacrnopnna Bo.ue, B pacrBopr4Mclrzpre 96 %. e$upe 14 rJrr{qep[He, JrerKo B oh. Pacrnop54 rl* pacrBop 5,4 Pryrn(II) xJropuAa PyreHnfircpacHufi [(NH3)5Ru(NH3)aORu(NHr)s] 4H1O.(M.r"r. 8,5). . Cl6' 85 flopouror KopurrHeBaro-KpacHoro uBera. Pacrropuu B BoAe. Pyreunr KpacHoro pacrBop0108 Pacrnop r/n BpacrBope 7o. 0,8 arlerara. cnnHrla(Il) Ca6nnen.CroHre.(M.ror. 136,23). Tyfi-a(1O)-en. 4-Meruren-l-u3orporrr4n-6nqurro-(3.1.0)-rercau. EecqserHas MacJrrHrrcrar )Kr,r,uKocrb. dli . Oxoto 0,843. tz,l . Or.ono1,468. Teunepamypa KuneHutt 163lo 165'C. Or qvcrora ca6uHena, Xporraarorpa$uvecrcax np[MeHreMoro rasosofixpoMarorpa$uu, B oh. 99,0 AonxHa6urr HeMeHee (M.rvr. 38,I 2). Ca.rruqr.r.uoBan Krrcrrora.C6H4(OH)COOH. I
Eenlre, MeJrKue lrroJrbqarbre KplrcranJrbr LrJrr{ nerxnfi Kpucranntrqecxufi nopouroK, Ma.uopacrBopr4Ma Bo,qe, pacrBopr4Ma cnrrpre 96% n eQlrpe,yMepeHHo B paJrerKo B cTBOpnMa MeTr4JreHXnOpr4Ae. B Caruqnnonnrfi aJrbgerr,rr. CjH6Oz. (M.r"r.122,I).2-fu4porcr6eHsanrAerr.rA.

d l i . O*o n o 1 ,1 6 7 . n'i, . O*ooo1,574. Teunepamypa KuneHutOxoro 196'C. Teunepamypa nna*reHun.Oxoto -7 "C. (M.u. 240,26).2,2'-AzuuoAr.rMeCa.nnuu.rroBoro aJrbAerrrAa a3rrH. Cl4Hl2N2O2. rrar4u$euol. 0,30 r rl4Apa3r{Ha yKcyccynrSara pacrBoprrorB 5 un eo4u, npu6au.f,ror I MJr nofi rucrorbl neAtHoir MJr n2 cBexenpuroroBneHHoro % (o6lo6)pacrBopa 20 canl4rlr4JroBoro anbAervp.a 2-nponaHone.IlepeMer[r.rBa]or, B BbrAep)Kr{BarcT Ao o6pa:onaHvrxeJrroroocaAKa, 3areM Bcrprxr.rBarorAByMs c nopqlnsMu 15 rvrn uo MeTHJreHXnOpUAa. O6reAr.ur eHHbre opraH ecKr{e}r3BJr eHr.rr, uq eq BbrcylreHHbre HaA Harpufl. cy.ur aS rolr 6essoAHhrM, r{nu Sunrrpyror H Bbrnapr.rBaror OcaAox AeKaHTr4pyror Aocyxa. pacrBopr4renefi nepeKpI4craJIJILr3oBbrBaror rrp*toxJrax(.{eur4r.rcMecr{ rr3 MeraHoJr rorryorr(40:60).Kpwcrannbr cyrrar B BaKyyMe. Teunepamypa ma*reHun. Oxotro2I3 "C. (-)-o-CaHroHr.rH. Canronun. Cl5Ht8O:.(M.u. 246,29). 3,5a,9-Tpulaerun-3a,5,5a,9b-Sypan-2,8-AzoH. rerparrrApo-3H,4H-HaQro [ 1,2] EecqserHHe 6necrsulueKpr4criurJrbr, )rceJrrercrrrrae geficrBrreM ro4 cBera.
@

O'IeHr MaJIo pacrBoplrMB BoAe. pacrBopt4M roprqeM cflr{pre 96a ,yMepeuuo JIerKo B pacTBoprrM 3TaHoJre. B Te"ntnepaml;pa nnerneHua.Or 174 to 176"C.

lafi,,,-173"C (:rauon).

Canapa.n.Cyurraa auuonzfiHux corefr Tpr4rep[eHoBbrx rJrnKo3rlAoB-apano3r4AoB A,BNC. AuopQHrrfi nopouroK KpeMoBoro r4Jrr4 cepoBaro-KpeMoBoro rlBera. fi,rrpocron[qeH. Jlerxo pacrBopl,IMB BoAe,MiLrrO MeAJTeHHO pacrBopr4MB crrr{prc 96 o/o;npaxrnuerr cKr4 HepacrBopr4M xnopoSopne. r Canapa.na pacrBop 016ah.0,06 r cailaparapacrBopsm s 10 MJrMeraHoJra. CaQpannH. Cnaecr 3,7 -Suavuno-2,8-4unaeru-rr-5-$eHun-Sen asvrnvrfl. xnoprrAa, C20Hl9ClN+ (M.rtl. 350,85) u 3,7-guarvruuo-2,8-gtauerun-5-O-ronnn$eHa3uHr.rr xrropura, C2tH2lClN+ (M.vr. 364,87). TerrHo-rpacurrfi ropo[roK. Yuepenno pacrBopl,IMB cnl4pre 70 oA, o1pazynrpo3par{Hbrfipacrrop KpacHororlBera c xeJrroBaro-rpaurofi $nyopecqeuquefi . CaQpanr.rHapacrBop. 0,1 r ca$paHnHapacrBopsror e 10 Nrncrrrpra 50 %. Caxapo:a. CnH22Orr. (M.r"r. 342,30). Caxap. Eemrfi Kp[craJrJllr.Iecrufi [oporroK unn lr'ecrsrrlue, cyxue, 6ecqnerHbrer,rJrr4 6erue Kpr{cTannhr. O'IeHr JIerKopacrBoplrMaB BoAe,yMepeHHo pacrBopr4Ma cnr4pre96 o , [paKTuqeB cKrrHepacrBopvMa oraHoJre B 6e:ro4Horu. Eclu caxapo3y l{crlonb3ylor Ant rroBepKr,r nonrpr.rMerpa, ee xpaHrr B cyxoM BuAe B gana.f,HHofr aMrryJre.

' CnHHqa(rr) auerar. (CH3Coo)2Pb 3H2o. (M.r"r. 379,33). Csranrra Ar.rarrerar. Cnuuqarva\er ar,Tpr4rr4ApCnuueq yKcyc ar. HoKrrcrufi .
Fe cqnerHrre Kpr{crturJrbr, BbrBerprlBarouue Ha Bo3Ayxe cr " Jlerro pacrBopr,rM BoAe,pacrBoptrMB crrr4pre96 %. B Cnnnqono-arlerarHan 6yrrara OulrrponiulbHyro 6yuary, rrJrorHocrb xoropofi 80 r/u2, rrorpy]Karor B cMecb: yKcycHaj[Kr.rcrrora pa3BeAeuyan 12-9,5 %o,pacrnop cBr4HrIa(II) aqerara (l:10), 3areMee BbrHrrMarcT, cyruar 14 Hape3arorHa noJrocKr{pa3Meporrr x 40 l,rnr. l5 CnfiHrloso-arlerarHafl Bara fnrpocronuuHylo Bary rlofpprator B cMecbpacrBopr4relefi: yKcycHar KucJrorapa3BeAeHHar 12-9,5 o/o,pacrnopcnunqa(Il) aqerara (I:10). He orxuuafl.Barbr,yAanf,ror u:6rrrox xfl4AKocrl,I, 3areM noMerrlaror ee Ha HecKoJrbKo cnoeB $ranrrponanrHofi 6yI|{.A|Id CyrrraT Bo3Ayxe. V Ha Xpanxr B Bo3AyxoHerrpoHurlaeMoM xoureffnepe. CnHnqa arlerara pacrBop l0 Vo 10 r cnzuqa(Il) aqerara pacrBopqror B BoAe,npulaytnror yKcycHofi xucnors 98 o/o Ao nonyqeHrrr rpo3paqHoro pacrBopa u pas6annxrornogofi ao 100 rran. Cnnnqa(Il) aqerara pacrllop 9r5 oh. Pacrrop 95 rlnB BoAe,cno6ogHofior yrJrepoAa Ar4OKCr{.4a. Cnnnqa(Il) aqerara ocHoBHoro pacrBop. CnnHqonrrfi yrcyc. Co4epxrar He MeHeeI6,7 % (v.lr,,r) se 6onee I7,4 % (rrr,lrv). (A.u. 207,I9) u Pb

B BHAoco eArrHeHr4r, orBercrByroqero npr4MepHo opiuyne C8H14O0Pb3. co Q I 40,0 r cnnnqa(Il) arlerara pacrBoprrcr n 90 MJrBoAbr, cso6oAHofior yrJrepola ArloKcl'r4a..{onogrr pH pacrnopa lo 7,5 pacrropoM HarpLtr rxApoKcvAa KoHrleHrpr{poBaHHrIM, rlenrpu$yrr4pyror rr r4cnonb3yrorrrpo3pavurrfi, 6ecqserHrrfi pacrnop na4 ocaAKoM. flpu xpaHeuvruBxopono 3aKpbrroM xoHrefiuepe pacrBop AonlKeH6rnr npo:patrHbrM. CnuHqa(II) nnrpar. Pb(NO3)2.(M.r. 331,20). Cnuuqa AWHHrpur. Cnuneq(Il) asornoxucnrrii. Kpucramz.recK[fi [oporuoK 6enoro rlBera urv 6ecqnerHbreKpr4cruurJrbr. Jlerro pacrBoprrMB BoAe. Csnuqa Hrrrpara pacrBop l0 o/o 10 r ceuHrla(Il) Hr'rrparapacrBopslor B BoAer4AoBoArr o6reu pacrBopa roAofi Ao

100rr,rn. CeuHqa(II) nurpara pacrBop 3r3 oh. Pacrnop rlr^ 33 239,19).CnuuqaArroKcrrA. CnnHqa(IV) orccna. PbO2.(M.r'a. flopouor reMHo-Kopr.rqHeBofo rlBera,BbrAenrrcqufixucropoA rrpfi HarpeBaHr,ru. pacrBopt4M xnopr4croBoAopoAHofi flparcruuecKr4 HepacrBopr{MBoAe, B B xucnore KoHrleHTpr4poBannofr c BbrAeJreHr4eM pacrBopr,rMil3orHofi xnopa, B xncnorepasne4eHHofi yo B npr.rcyrcTBrrr4 I2,5 nepoK}v!.aBoAopoAa, ulaBeneBofi xucnorrr vnvr Apyfhrx BocpeareHToB, pacTBopnM foprqr4xKoHrIeHTpr4poBaHHbrx pacTBocTaHaBJ[rBaroxlnx B
pax f r4ApoKcrrAoB [IelorrHblx MeTaJrJroB.

Cnnnqa(Il) oKcns. PbO. (M.u. 223,19). MerxoxpucraJrJrrrqecxuitwnu auopSHrrfi flopoilroK or xenro-3eneHoro c cepe6pucrbrM orreHKoMAo KpacHonaro-6ypororlBera. flparru.recKrr HepacrBopraM BoAe,pacrBoprrMn asorHofi KrrcJrore, B ulenoqax. Ce;reu. Se. (A.u. 78,96). Iloporuor unr4rpaHynbror Kopr{qHeBaro-KpacHoro qepHoro rlBera. Ao flparfirvecKH HepacrBoprrMB BoAe14crrr{pre 96 Yo,pacTBopvMB a3orHofi xncJIOTe.

Teunepamypenfla*reHun. Oxono 220'C. Ce.rrena(IV)orccuq.SeO2.(M.rur.110,96).Ceresa oKrrcb. Eenufi Kpr{crannuqecxufi nopo[roK. Jlerro pacrBopr4MB BoA9,pacrBopr4MB cnlllpre 96 Yo, arleroHe, yr<cycnofi rucnoTe. Ce.nenucrafl Kr{cJrora.H2SeO3.(M.u. 129,00). Kpucrarrbr, pacrrJrbrBaroilIr4ecq Bo3Ayxe.Jlerxo pacrBopr{MaB BoAe. Ha Xp auxr B Bo3ryxoHerrpoHrr rIaeMoMxoHrefi Hepe. Kannfl -Harpun raprpar. C enrerosa cor'rb.Crra. Cepa. S. (A.u. 32,06). Menrrafi anaopQuufi 6reAuo-xelrrrfi ropoilroK 6es ganaxa. C epe6pa Au3rrrJrArrrnorcapdarvrar. 1sAgN 52. (M. r. 256,16). C5H floporuox or 6reAuo-xeJrroro Ao cepoBaro-xeJrroro rlBera. Ilparrn.recKr{ HepacrBopraM BoAe,pacrBopktMB rrr.rpr4ArrHe. B loronrr cneAyrorrlr{rra 1,7 o6pasorvr: r cepe6paHr{TparapacrBoprrcr n 100 MJrBoAbr. OrAelrso pacrBoprlor 2,3 r Harpnr ruorunrlrruorap6arr,rara B 100 rvrnno4rr. O6a

EreI

pacrBopa oxna)I(AarcTAo TeMneparypbl l0 "C, cMellrr.rBaroT npr.r nepeMerrrr4Ba[vrvr 14 co6npalor oca.qoKxeJlTofo rlBera Ha creKJr{HHoM Sunrrpe, lpoMbrBaror 2A0 MJrxoq. ;roAnofi BoAbrr,rcyruar B BaKyyr!{e reqeHue 2-3 B C epe6pa rv:'Tr4rrrvruorap6arr.tarHe AonxeH r,r3MeHrrb oKpacKyurru Lrv,erbcunrHrrfi 3anax. Cepe6pa Hr.rrpar. AgNO3. (M.r"r. 169,87). Eecqneturre, npo3paqHbleKpltcraJrJrbr Br,rAe B [Jracrr.rHoKutu 6enstx rI[JrLrHApr4qecKrlx rraJrovex.IIo4 Aeficrsuel{ cBera flpenapar reMHeer. Oqeur JrefKopacrBopr,rM BoAe,pacrBopr{MB crurpre 96 %. B Cepe6pa Hrrrpara aMMr.rarrHufipacrnop 2rS o/o 2,5 r cepe6pa Hurpara pacrBopstor s 80 MJrB0A6r,rro KarJr.f,M npu6anttrcT pacrBop aMMI,IaKa pa3BeAeHHrrfi Yo AO paCTBOpeHVfl 10 OCAA]KAV O6rerr4 IOBOATT pacrBopano4ofi ao 100 nrn. lorossr HerrocpeAcrBeHHo nepeA r.rcnoJrb3oBaHr4eM. Cepe6pa Hrrrpara aMMr{aqHufi pacrnop 5 o/o 5 r cepe6pa Hurpara pacrBoprror s 100 Mn BoAbr.K pacrnopy npunrBaror no KarInqM, IrpI4 [ocrotHHoM [epeMeIIII,IBaHLIu, Yo pacrzop aMMr.raKa 10 Ao rex rop, noKa ocaAoK He 6yger nolITI4(no ue noJrHocrbro)pacrnopen; Qunr-

rpyror.

XpaHxr B xopomo yKynopeHHbIXcocyAax opaH)KeBoro creKna B 3arrlrlrrreHHoM or cBeraMecTe. Cepe6pa Hrrrpara pacrBop 4125o/o.Pacrnop 42,5 rlrr. Xpanrr B cocyAax opamreBoro creKJrac npr,rrepruuu npo6KaMr B 3anIruIeHHoMor cBeTa MecTe. Cepe6pa Hrrrpara pacrBop lr7 yo. Pacrnop 17 rln Xpanxr B cocyAax opaHlxeBoro creKJrac npr4Teprrrrura upo6KaMrrB 3arluIqeHHoM or cBeTa MecTe. Cepe6pa Hnrpara pacrBop 2 oh.Pacrnop 20 r/n. XpaHxr B cocyAax opaHxeBoro creKJrac flprrreprurnru npo6KaMu B 3arrl[ueHHoM or cBeraMecre. Cepe6pa Hrrrpara cnnproBbrfi pacrnop 2 oh. Pacrnop 20 r/n n cnupre 96 oh. xpaHtr B cocyAax opamKeBorocreKJrac nprrreprulrz npo6KaMr4 3arrluqeHHoMor cBera B MecTe. Cepe6pa Hrrrpara pacrBop B nl{prrArrne 8r5 7o. Pacrnop 85 r/n B rrr,rpnqrrHe. Xpanxr B coc)aax opamKeBorocreKJIac [prrreprbruz upo6xarwr B 3arr{,ruleHuoM cBera Mecre. or Cepedpa Hr{Tpara peaKTrrB K cprecn3 nu pacrnopa aMMr4aKa KoHrIeHrpr.rpoBaHHoro n 40 nrn I M pacrnopa 32o/o Harplr"u fl,IApoKcrlAanpn6anmroTno KarrJrrM npr{ uepeMerrrr,rBaHr.ru 2 %opacryopa 8 un cepe6paHr{rpara r.rAoBoArr o6reu pacrBopa no4oft ao 200 rran. Cepe6pa oKcr{A. Ag2O. (M.r"r. 231,71). [racepe6pa oKcr.rA. Cepe6pa oKncb. llopouror Kopr4qHeBaro-qepHoro rlBera. flpartzuecKl-I HepacrBoprrM BoAer4cnrlpre 96yo,JrefKo pacrBopr,rM pasnegeHuofi B r asorHofi KrlcJrorer.rpacrBopax aMMHaKa. Xpanm B 3arrlr4rrleuHoM cBera Mecre. or

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qacrurl yKirbrBaror rrocJle Ha3BaHilficop6eura B lrcrrblTaHvtflx) B rpyrrrraMra.Pasrraep KOTOpbTX rrcrroJrb3yerct. OH lonaoreHnrrfi nopouror 6eroro rlBera. B flparuruecKra HepacrBopl4M BoAerr cilrrpre 96 %. CurnnareJrb aMrrnorrponnJrcl{;ru;rrnrrfi AJrflxpoMarorpaQnH qacrull or 3 Ao 10 uru 14 noc pa3MepoM Crnurarenb oqenb roHKo r,r3MeJrbqeHnrrfi MoAr,rSlrqnponaHHofi aMl4nonpoilvtrcvrvnbnblMl,IrpynBepxHocrbro, xlrMr{rrecKr4 qacrfirl yKa3brBarorrrocJle Ha3BaHIrtcop6enra B LlcnblTalelzflx, B [aMr.r. Pasrvrep KOTOpbTX rrorroJrb3yercfi OH . loruorennrrfi noporuor 6eroro rlBera. B flpaxruuecKrz HepacrBopI.IM BoAeLI cilrrpre 96 %. Cu.nnrcare.nr6essoaHHfi rracrr,rrrHo o6esnoxeHHat I4 [oJIrIMepLI3oBaHHat, Alaop$nar KpeMHrreBar Kr.rcJrora, nornouarcuar ilpr reMneparype 20 "C oKono 30 % BoAbrorHocr{reJlrno csoefi ro6amra xnopl4A. Maccbr.Co4epxrlr B KaqecrBeIrHAIaKaropa rvrflparrnvecKr4 HepacrBoprrMB BoAe,qacrr,rqHopacrBoprrM B pacrBopax Harpr4fl, ApoKcI,I,qa. Cu.nlrrarem 6yrnncl{JrrlJrbHblfi lnq xpoMarorp aQnu Cunuxare;rb otreHbroHKo u3MerbrreHsufi c pa3MepoMtracrplu or 3 Ao 10 urrra I{ noMoA[Qraquponasnofi 6ytutcunuJrbHblMll rpyilrlaMl4. PasBepxHocrbro, xr,rMrrqecKrr rracrr4rlyKa3brBaror B rrocJreHa3BaHrzr cop6eHra B l,IcrlblTaHvtflx, Koropblx oH Mep rrcrroJrb3yeTcr. folrorenHufi nopourox 6eroro rlBera. B IpaxruuecKr4 HepacrBopr4M BoAer{ cm.rpre96 %. Rpeuuun duorccudc$epoudattuuatil.30 nrr,r. O6tea nop.0,6 cu3/r lr. Vdenuuannnou4adanosepxHocmu.80 rvt2 xpoMarorpaQnn reKcrrJrcr,rJrnJrbHbrfi Cu.trnrcarer'rb A.irq qacrl.Iq or 3 .qo 10 rraru la rroroHKo r,r3MeJrbqeHssfipa3MepoM c Cunxxarenb oqeHb rpylnauu. PagrercHJrcI{JrrrJIbHbIMH BepxHocrblo,xrrMr{lrecru rr,ro4u$r4urapoBaHsofi B nocne Ha3BaHils, cop6enra B HctlblTaHprflx) Koropblx oH Mep qacrl4u yKa3brBaror Hcrronb3yeTcfl. fouoreusrrfi noporuox 6enoro uBera. flpaxrlrvecKr4 HepacrBopuMB BoAer{ cnrlpre 96 %. Cu.nurcare.rrrrngpoQumnufi Arq xpoMarorpaQnn r{acruu or 3 lo 10 rrlrlr, uoc Cnnnrarerb oqeHb roHKo r43MeJrbqeHurrfipa3MepoN{ ru4poSwnbHblxcsoficrs. BepxHocrbKoroporo uo4n$uqupotsaHac rlexbro npn4aHnfl. qacrurl yKa3brBalorrrocne Ha3Banr.rr cop6enra B r{cnbrraHr4flx,B Koropblx oH Pa:ruep r4c[onb3yeTcs. CnnlrrcareJ-rb Ar{MerlrJroKcraAeu["rcnJrl{.urntIfi AJrflxpoMarorpaQuu lr c Cunnxare:rb or{eHbroHKo r.r3MeJrbqeHnufr pa3MepoMqacrl4lr or 3 lo 10 rvlxrvt roBepxuocrblo, xr4Mr.rqecKr4 MoAraQuqupoeanuofiArrMerxnoKTaAeIIuncuJII4JrbHbIMI4 qacrurl yKa3brBaror B cop6erna B I4crIbITaHI4tx, rrocJreHa3BaHrdr rpyflnaMr4.Pa:nrep KOTOpbTX irollonb3yeTct. OH fouoreHurrfi noporuor 6eroro uBera.

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flpaxruuecKr.r HepacrBoprrMB Bo.{e}r cnr{pre 96 %. Pasuep qacrrarlupperympHufi. Y4elbHar nnoilraAb roBepxHocrr.r- 300 u2ln C lururcareJrbArroJrbH A.ns xpoMarorpaQnn ( I ) rIfi qacrl{qbl KpeMHr4s CQepuuecKl4e c Ar4oKcr4Aanpr.rBr{TbrMrr r}rrr{ApoKcrrilporurJrbHbrrvru rpynrlaM[. Pasrraep - 10 Hnr. rop Cn"unxareJrb Hurpr{urnrrfi AJrflxpoMarorp aQnn Cu;umarenb oqeHbrolrKo r43MerbqeHuufi noBepxHocrbro.xr{MrrqecKr{ c nlo4usuqnporaHuofr lll4aHorlponnilcvnvilbHblMlr rpynnaMr4. Pa:rvrepqacrr{rl yKiRbrBarornocJre Ha3Banvrfl, cop6eHra B rrcflbrraHvrfrx,BKoropbrx oH ]rcflonb3yerct. loraorerruxii nopouror denoro rlBera. Ilpaxruuecrr{ HepacrBopr,rM BoAe,cr}rpre 96 % u e$rape. B Cr,r;ruxare,'rr,rrnTprrntnufi Arq xpoMarorp aQu u ( I ) CurruxareJlborleHbroHKo l{3MeJlbqeHuufi, cocroxunfi i43 ilopr4crux c$epuqecKlrx r{acrlrU, c xaMurlecKl4cB.[3aHHbIMI4 HI{TpL{nbHbrMi{ fpynrraMu. Pasuep qaorurl yKa3biBarortlocne Ha3BaHHr cop6eHra B r{orIbITaHI4.rIX" B Koropblx oH r.rcrloJrb3yercf. fonaoreunriil noporuor 6eloro rlBera. flpaxruuecKrr r{epacrBopnlrB BoAe"cnr4pre96 % ra:6zpe. C rarurcareJrbHr{Tprr.n nurr fi AJrflxpoMarorp aQun (2) (ceepx.urcrrrfi ) Cnnnxare;rb cBepxqucrrtii c lionepxHocrbFo.xuMuqecKll laoan$nqupoBauHofi quaFronpofirlJrcnJlu-[bubrMr4 rpynnanrn. Co,lepx{u'rMenee20 ppm il,rerannoB. Fasuep uacraq yKa3blBalor rrocne laagBanlaflcop6eHra B HcnbrraHr{Nx, B Koropbrx oH uorronb3yeTcr. lonorenuufi noponrox 6e.irorouBera. flparruuecKr4 HepacrBopraM BoAe,cnr4pre96 % u :$ilpe. B CrE,rnmareJlb oKTaAeKarroI{JraMrrrroilpoflHJrcrrJrrrJrbHrrfi xpoMarorpaSnn Anq r{acrurr or 3 lo 10 vnna u noBepxHoCil;ruxareirb rol{Kou3MerbqeHHbrff pa:rrepoM c crr,Io, xr{MxqecKu uo4uQnIII4poBaHHofi auunoilporrrrJrcr4JruJrbHbrMr4 rpynrraMu! Koqacruu yKa3brBaror Tophle aqewlpoBaHbloKTaAeKaHonn-rpyrrilaMr{. Fasnrep rrocJre loa3Banvrfl cop6eura B r4crrbrraHnqx, Koropbtx oH r{crroJrb3yercq. B fonoreunuft noporuox 6enoro uBera. IpaxrnvecKrr HepacrBopr{M BoAe14 B cnr4pre96 % u s$rpe. C nrnrcareJrb oKTaAerlnJrcr{JrrrJnnu Aflq xpoMarorpaQnu fi Cunraxarenb or{eHbroHKo Ll3MeJrbqeHssfr pa3MepoMrracrrru or 3 4o 10 rr,rxrra noc r4 BepxHocrblo, xl4MrrqecKI4 MoALIQrarluponassofi oKTaAerlunclrJrlrrbHbrMr4 r'pynrraMr4. Pasuep qacrlru yra3hlBalor nocJle HagBa:avrfl. cop6eHra B r{crrhrraHvrsx) Koropbrx oH B rrcrroJrb3yeTcr. fonroreuuufi uopourox denoro rlBera. flpaxruvecKu HepacrBopr4M BoAerr cnr4pre96 %. B Clr.uuxareJrb oKTaAerluJrcrrnrrJrrnufi AJrflxpoMarorpaQnn (l) (cnepxuucrufi) Cnnuxarenb cBeprllactrtft, oveHbroHKo lr3MeJrbqeHnufi pa3MepoM c nop oKono 10 uu r{ rloBepxHocrblo, xtrMl{qecKu rr,rogn uqup o BaHHofioxraAe \nncvrftrnbubrM}r rpyn (p ilaMu (cogepxaur{e yrnepoAa- 19 %). Co4epxanne MeraJUroB 20 AonxHo 6rrrr MeHee ppm. Cu.nurcareJrb onTaAerluJrcrrJrrr"'rsHufi AJrflxpoMarorpaQnn (2) (cnepxvncrufi) CunurcarenbcBepxtluctntit, oqenb roHKo r{3MeJrbtreHsrrfr pa3MepoMuop 15 Hlr u c

loBepxHocTbro, xr4Mt4qecKr,r MoAr4or4rlr4poBaHHofi fpyflrraMrr oKTaAerluncr.rJrr4JrbHbrMr{ p-ns, (co4epxanue yrJreporc 20 o/o),npegna3HaqeHHbrin anaJrusanoJrrrqvKJrutrecKr4x tracr[rl yKa3brBaror apoMar[qecKrrx yrneBoAopoAoB. Pasrr,rep nocne Ha3BaHHq cop6enra B r,rcrrbrraHr4flx) Koropbrx oH r{cnonb3yerc.f,. B fouorennufi noporuox 6eroro rlBera. flpaxruuecKr4 HepacrBopr,rM Bo,qeprcnprpre 96 %. B Cururcarerrb oKTaAerlrrJrcr{JrrrJrnuufi, AeaKTrrBnponaunrrft no orHorrreH[ro K ocHoBaHrrff AJrflxpoMarorpaQuu Mr qacrrlq or 3 Ao 10 urou; nepeA Craruxarenb orreHbroHKo u3MerbqeHnrrfi c pa3MepoM BBeAeHr,reM oKTaAerlr4ncr4nlrJrbHbrx rpynn ero npeABapr.rreJrbHo o6pa6arunaror [yreM TxlarenbHofo rrpoMbrBannfl. fr4Aponr4sa r4 6omunncrBa rroBepxHocrHbrxcrrJroKcaHoBbrx Mocrr,rKoB K B3arrMoAeitcrswfl. ocHoBHbrMrr c KoMrroAnfl cBeAeHr,rr Mr.rHrrMyMy qacrr4rl yKa3brBaror HeHTaMv. Pasnaep rrocJreHa3BaHr,rfl B cop6eura B r,rcnbrraHytflx)
KOTOpbTXOH r{CilOnb3yeroq.

fouorennrrfi nopouror 6eroro rlBera. flpaxru.recKta HepacrBoprlMB BoAer4crrrrpre 96 %. CnrnrareJrb orcTaAerlrrJrcrrJrnJnnufi, AeaKTnBr{ponannufi [o orHorrreHrrloK ocHoBaHuflM,SHAKenupoBaHHbrfi A.ns xpoMarorpaSun vpagCralraxarenboqeub roHKo pr3MeJrbqeunufi pa3MepoMtracrurl or 3 Ao 10 rr,ffirvr c MepoMrrop oKoJro10 uu, coAep)Kr.rr oKoJro16 Yo ymepola. llepeg BBeAeHrleM oKTa.qeq[ncunnJrbHbrxrpynn ero npeABaprrrenbHoo6pa6arrrBaror flyreM TrrlarenbHoro rrpoMbrBaHrrr rrrAponusa 6onrrrruHcrBa rroBepxHocrHbrxcr.rJroKcaHoBbrx r{ Mocrr.rKoB. K .{rx 4anrnefiurero cBeAeHUq MrrnrrMyMyKaKoro-nz6o sgamuoAeficreuqc ocHoBHbrMr4coeAvHeHuflMvtrrrlarenbHo oHAKerrxpyror Arrr, ycrpaHeHr,rr 6onrrurancrsa ocraBrrruxcr cr,rJraHoJrbHbrx rpyil[. Pasuep qacrrarryKa3brBaror rrocne Ha3BaHnrcop6esra B r.rcnbrraHr4flx, Koropbrx oH rrcrroJrb3yerc{. B lorraorennufi nopourox 6enoro rlBera flparrnvecKr HepacrBopr,rM BoAer4cnnpre 96 %. B Cn.uurareJrb oKTaAerlrrJrcrrJrrrJnnufi snlKennposaHHrrfi AJrqxpoMarorpaQnu Czrurarenb oqeHb roHKo rd3MerbqeHsrrfic piBMepoM qacrrlrl or 3 lo 10 rvmu u noBepxHocrbro, xr.rMr.rqecKr.r MoAr-rQutquponannofi oKTaAerl[ncr.rJrr,rJrbHbrMr,r fpynrraMr,r. cne4eHur K MrlHr,rMyMy B3ar,rMoAeftcrelrs ocHoBubrMr,r c rrrlacoeAr4HeHr4rMrr .{nx gHAKerrlrpyrorAnr ycrpaHeHr.r.s TeJrbHo 6ommnHcrBa ocraBrrr[xcr cr4naHoJlbHblx rpyfln. Pasuep qacrlarl yKa3brBarorrrocJrelna3Banprs, cop6enra B rlcnbrraHr.rrx, B KoTopbrx oH r,rcrroJrb3yeTcq. louoreunrrfi noporuox 6eroro rlBera. flpamrauecKprHepacrBoprrMB BoAeu cnr4pre 96 %. C u.nurcareJr o KTrrJrcrrJr b Hbrfi AJrs xpoM aro rp aQun b rrJr Cunraxarenb oqeHb roHKo r,r3MeJrbqeHnrrfipirMepoM tracrr4rl or 3 4o 10 urlr lr noc BepxHocrbro, xlrMrrqecKrl MoAr,rSraquponassoft oKTr4Jrcr.rJrr4JrbHbrMr.r fpymraMr,r. Pasqacrzrl yKa3brBarorrrocJre laagBaHvrfl, Mep B cop6enra B r.rcrrbrraHurflx, Koropbrx oH [cnonb3yeTcr. fouorensufi noporuor 6enoro uBera. flparrrauecKr4 HepacrBoprrMB BoAer.rcnprpre 96 %.

EN

C n.uur<areJrb oKTnJrcrrJrrrJrbHbrfi xpoMarorpaQnu ( I ) AJlq Crlnurarenb oqenb roHKo l,I3MerbqeHnrrfic prrMepoM qacrr.ru or 3 4o l0 uru n noBepxHocrblo, xt4Ml4tlecKrr MoAr,rQzquponaunoftoKTr.IJIcurJrr.rJrbHbrMr4 [r MerrrJrbHbrMrr qacrilIl yKa3blBarorrrocJreHa3BaHrlf, rpynrlaMl,I. Pasrraep cop6eura B rlcrrbrraHvtflx,B KOTOpbTX r{CrroJrb3yeTor. OH fol,rorennufi nopouor 6eroro rlBera. flparrnvecKn HepacrBoprrM BoAer.rcrr4pre 96 %. B C n.nnrareJrb oKTrrJrcrrJrnJrbHbrfi xpoMarorpaQnn (2) A.rq Cvnuxarenb oqeHbroHKo Ll3MenbrreHnrrfi pi*MepoM nop 10 HM H rroBepxHocrbro, c xI4MI4rrecKLr nao4u$raqupoBaHHofi oxrzncrrJrr4JrbHbrMr4 rpynrraMlr (co4epxur 19 Yoyr,repo4a). C unnrcareJrb oKTlIJrcrIJIrIJrbHbIfi engrennpoBaHHbrfi AJrqxpoMarorp aQun qacruu or 3 4o 10 narrvr rroCunurarenb oqeHbroHKo [3MerbqeHuufi c pa3MepoM v Bepxuocrbro, xLIMLIqecKI{ Moll{Qnquponasnofi oKTkrncr4JrrrJrbHbrMr4 rpynnaMrr. ills cBeAeHI4tK MI4HI{MyMy ar,rMoleit cryus c o cHoBHbrMrr o eAr{H 83 c enprflvrvt rnrarenbHo sHAKerlktpyror 6ommlrrrcrBa ocraBrrruxcr cr,rJraHoJrbHrrx rpynn. PasAnt ycrpaHeHn.f, Mep qacrLIIIyKa3blBarcT nocne Ha3BaHI4t COp6enra lrcnbrraHvrflx,B B KoropbrxoH rzcnonb3yeTcr. fouoresnrrfi noporuox 6eloro qBera. flpaxrxuecKr{ HepacrBoprrM BoAe14 B cnr4pre96 %. C ua nrcareJr rp r.r eruJr cn,rr b M lrJn n u fi AJrfl xp oMaro rp aQn u qacrr.{qor 3 Ao 10 rvrxul,rroCunzxarenb otleHbroHKo r43MeJrbrreHnufi c pa3MepoM BepxHocrbro,xI4MrrqecKLI MoAlr$vquporansofi TprrMerrrncr{JrrrJrbHbrMr.r rpynnaMr4. qacrlall yKa3blBarorlocJre laasBanvrfl. Pasuep cop6enra B r.rcrrbrraHurflx) Koropbrx oH B HCnOnByeTCq. fouoreunrrfi noporuor 6enoro rlBera. flpaxruvecKrr HepacrBoprrM BoIe r crrr4pre96 %. B C n.nurcarenr Qenn.ncrrJrrrJrbHbrA.rrqxpoMarorpaQnn fi Cnnuxarenb oqeHb roHKo r{3MeJrbqeHsrrfi pa3MepoMrracrr4rlor 5 go 10 vrxrvr rroc 14 Bepxnocrbro, xr.rMr.rqecxll ir.rogur$rdrlktpoBaHnofi rpylnaMrr. $euunbHbrMr.r C n.uurcare.nrQeHnlcrrJrlrJrbnbrfiA"rq xpoMarorpa$un (1) qacrrrrl 5 uxu r4 rroBepxHoCunnrarenb oqeHb roHKo [3MenbtreHnufi c pa3MepoM crbro, xr4MuqecKu rrao4uSuqupoBaHHofi rpyrrnaMrr. $eHrlnrHhrMt4 Pasuep qacruq yKa3blBalornocne :aa3Banufl cop6eHra B r4cnbrraHvtflx)BKoropbrx oH i{clonb3yeTcr. fouorennrrfi uoporuor 6eloro rlBera. flparruvecKu HepacrBopr.rM BoAe,cnr{pre 96 % rr MernJreHxnop}rAe. B Rpeuuua duorccudcQepoudanw*rfi. 8 nrvr. Vdenauannnou4adanonepxHocmu. ytzlr. 80 o/o. Codeptrcauue yznepoda. 5,5 Cn.rurcareJrb rlrraHocr{JrrrrrrbHbrfi xpoMarorpaQHu A.ns Cranuxarelb oqeHbroHKo rr3MeJrbrreHHnfirroBepxHocrbro, c xr{Mr4qecKr{ ruo4u$uqnqacrurl yKa3brBaror ponaHHofiUIraHocrrJIuJIbHbrMr4 rpynrraMrr.Pasnaep rrocne Ha3BaHr4Jr cop6eyra B r,rcrrbrraHvrflx) Koropbrx oH r.rcrroJrb3yercs. B folaorennrrft uopouror 6eloro rlBera.

flpaxruuecKr,r HepacrBoplrMB BoAeIr crllpre 96 %.

-fleural{erorcuQlanon. (M. C Cunencermr.. 2gH26O7. u . 372,36). 3',4',5,6,7

flopouroK. Eenrrfi KprrcrtlrrJrr,r.recrlrfi B flparruvecKr,r HepacrBopr4M BoAe,pacrBopl,IMB cnnpre 96 %. Tesunepamypa maBneHu* Ot<ono177 "C. rrornoulenvfl.TrpLr243,268 Iloznou4euue. Pacrsop B MeraHoneuMeer rpr,r MaKcLtMWa

u 330nu.
KonuqecmneHHoe codepcrcauue.He MeHee95,0o4. CnHnfi VS. Cu. CyrrQanosrrfi cnHnft.

-f aKo3 . C rcnaran. C zoH (M.*. 422,8) 2,6,I0,15,19,23 excaMerl{nrerp aH. ez.

)KI,IAKo EecqserHas MacJrrHr4craq crb. Jlerxo pacrBoprrM r eQupe u )Kr{pHbIXMacJIax, MaJro pacrBopllM B aueroHe, MeraHoJre. neAssofi 14 clupre 96 o , yrcycnofi KI,IcJrore

d',i. o, 0,811 0,813. ao

t t u . O r 1 , 4 5 1t o 1 , 4 5 3 . CnnnuAap o.rnrqennufi 3arraxoM. crb flporpavHax, 6ecqnernafl , [oABr{xHar )KrrAKo c xapaKTepHbIM Crremannrrfi ungnmarop rpacHufi u ruerurenosHfi culnui,tB coorHollroauu2 1. CMeuruearcTMerr.rJroBrrfi CueruanHoro rrHAr{KaropapacrBop c KpacHorocMeIrrI,IBaIor50 wt0,l o/o MeTl4noBoro 100 rr,rn 0,1yo cruproBoro pacTBopa c crr,rproBoro pacrBopa Merr,rJreHoBoroLIHero(rony6oro). pacrBopa ot SnoneroBo-KpacHofi senenofi npu pH 5,4. r flepexo4 oKpacKr{ Cuecn AJrs cneKaHlrfl qr,rcroro Harpl{r rap6onara rlqa25 r uemo pacreproro 6esnoguoro xr,rMrlqecKl4 qucroro KiLIIut rcap6oB TeJrbHo cMerrrr,rBaror crynKe c 45 r 6esno4noro xpIMIrqecKLI pacreproro x[MI4iIecKIr qficroro raJwtfl Hrrrpara. Hara vr c 25 r MeJrKo Xpauxr s 6aHre c nprlreproi npo6rcofi. Anuono6lrennafl cMoJra. C uo.na cra6orcauronnTH afl . Crr,r. Cuona nonoo6treHHafl crrJrbHorncJrorHas. Cn. Ilonoo6MeHnas cMoJIaclrJrbHoKIICJIOTHAfl.
20

Crr,r. Co.nsPefiHerce. AnproHnn pefiHeKar. Conornprep crHpoJI-AI{BrIHrIJr6ensora rroJrr.rMepa. CyruecrBylorpa3roprrcrbre rpaHynbr rroreperrHo-c[rrrroro r.r3 TnepArre, pa3MepaMlr yKa3brBalor rlocne HaPasrraep rpaHyJI rpaHyJr. Jrr,rrrHbre MapKrr pa3HbrMrr c
peaKTIrBa r.rcrrbrraHuflx, Koropblx oH I{crloJlb3yeTct. B B | 3BAIJI.J'fl. Cononnlrep STrrJrBrrHu.lr6eusoJr-AI{BIrHrlJr6eHsora TnepArre, rropucrbre rpaHynbr urapoo6pa:uofi $oplabr r.I3nolrepeqHo-cullTofo noJlrrpa3MepaMr4 rpaHyn. Pasnep rpaHyn MapKr.r pa3HbrMr,r c Mepa.Cyutecrnyror pa3nr4qHbre yKa3brBaFor r4cnbrralJr4flx, Koropbrx oH l4crloJlb3yeTct. B B Cop6ur. C6H1406.(M.rur.182,17).D-hroquron. D-Cop6ur. noporroK. O6raAaer nonnuopSrr3MoM. Fenufi r.rJrr{ notrrrr 6enufi Kpr4cra^irnu.recrufi B Oqesr nerKo pacrBoprrMB BoAe,npaKT[irecK]IHepacrBoplrM crlrrpre 96 %. Cnupr 96o . C2H5OH. (M.r"r.46,07).Srasor 96%. CnuprerI,rnosuilper<rra$uxosaHHrrfi. @

o Co4epxur 95,1-96,9 (o6lo6) utru 92,6-95,2 (u/u) C2H6O % npn 20 oC.

Eecqsefirax, [po3parrHafl, Irery,tafl' BocflJlaMeHtloulaflct xrdAKocrb; rr4rpocKorrr{rrHa. Clreruilsaercf c eoAoft 14 Mer[Jrenxnopr.rAoM. lopar 6egAsrrr,rnrrla rony6onarbrM rrJraMEHEM.

Teunepamypa KuneHun Ororo 78'C. o cnodoAnrrfior a.nrAerrrAoB Cnnpr 96 , 1200 rran crrlpra 96 % cMelrrr,rBarot 5 un 40 Yo pacruopacepe6paHvrpara u c 0/opacrYopaKaJwrfl.rr4ApoKcr,rAa,Bc'rpflxprBarc! 10 rvrnoxJraxqeHnoro 50 orcrar.rBaror B TeqeHrde HecKoJrbKr.rx n $ranmpyror. 4nefi (Dumrpar [eperoHnor HenocpeAcrBeHno nepeArrclonb3oBaHveM. oh oqnrueHnufi Cnnpr 96 K 1 n 95 % crrpra upu6aannor 4 r uunronofi urrnu n 4 v'r'cepnofi KrlcJrorbr KoHq, [epuoAprqecKr,r IIeHTpLIpoBasHoff. Crraecr ocraBJrrrorsa 24 nepeMerrrlaeas. 3areN{ crr.rpr rreperoHrror. I n fleperHaHuofo K cnInpranpu6annxror4 r qunrosofi nrrru u 4 r t<anu eAKofo, ilepeMerrr[Baror cHoBa r.r rreperoHrror. Cnupr H-aMlrJroBrrfi . Crvr. flenrano.rr. Cnupr ru-6yrn.uonufi. Cu. EyraHo.n. Cnnpr rr3oaMlrJronrrfi I{goaM[.rosrrfi cnr{pr. . Crr,r. Cunpr rr3onponnnonufi. Crr,r. 2-flporraHoJr. Cnnpr Merr{JroBbrfi . Civr. Meranol. C nnpr rroJrrrBrrHrrnonrrfi [IolnBrrHrrJroBbrfi . Cu. cnnpr. CnHpr nponrrJroBufi.Cu. [ponaHon. Cuupr orn.nonrrfi a6co.rrrornpoBaHHbrfi 3rano.n. . Crra.
EecqserHa-f,, [po3paqHafl, neryrrafl,, BocrrJraMeH{roqatcf, }Kr4.uKocrb,rr4rpocKorrr4rrHa.

louycraerc{ 3arrax6ensora. r C N{eurueaecfl. c soAofi r,rMerr4Jrenxnopr,rAoM. lopur rony6onarrru 6ecqeerH6rM nJraMeHeM. - He MeHee99,8 o no o6leuy. Co4epxaru.regTunoBoroc[r{pra Xpaurr B creKJrrHHrrx 6aurax c ilpr.rreprbrMr{npo6ralru. Cnupr eru.nonsrfi a6corroruponannufi AJrflcrreKTpoQororvrerpr{u A6conrorzponaHHufi cilvp! He coAepxauJuir 6en3ora, neperoHxror HaATBepAbrM HarpoM eAKr4M (10 r uleroql,t Ha 1 r cnnpra). Havanrny]o r{ KoHeqHyro Lrrrulrrartur eAKrrM nopqrrrdorroHa or6pacrrnaror. lleperlrannrrfi cnprpr a6corrcruponaHnrrfi rrpr4rr3MegorxeH r.rMerb peHl{u orHocr.rrenbHo BoAbr KroBerec ronulrrHofi croq I crvr B Benr4quuy orlrlMecKofi nnourocrr{, He rpeBbr[raloruefi 0,01 s o6racrr or 320 ao 350 nrvr 0,05 z s o6racru or 280 ao 300 uu. tunpr g0 oh, coAeprrauuit I oh xJroprrcroBoAopoAHofi rnclorbr KoHueHTpHposaHHofi K 100 Mn cnrrpra 90 % ocropo)KHonplrnnBaror rro KarrqM 1,0 ul xnoprrcroBolopo4uoft KrrcJrorbr KoHrleHTprlponaHuofi . oh, coAepxaquit 5 o/oxJroprrcroBoAopoAHofi Cnnpr 60 rcnc.norrr K 95 un crll4pra 60 % nprrJrr4Baror ur 25 % xJropr4croBo4opognofiKrrcJrorbr. 5 Cu.nan [enapaa Cnlan MeArI,iL'rloMrrHr{r rIr.rHKa MaccoBoM 14 B coorHolrre*vpr I :09:0,1. Fenrrfi xpynrufi MeraJrJr BrlAe rraJroqeK B r4Jrr4 ceporo noporxKa.

(M.vr . 284,47). OxraAexaHoBa.f, Krtcrora. CreapnHoBafl KrlcJrora. C 1gH36O2. Ha llopouror rrnl,rxnonbs 6eroro rlBera, MacJItHLIcrbre olqynb. pacrBopr{Ma roprqeM cn}Ipre 96% lr eSupe. B flpaxruvecKr{ HepacrBopr,rMa BoAe, B TeunepamypaMa*reHua. Oxotro 7 0'C. Crponqun rcap6onar.SrCO3.(M.n. 147,63). Kpucrarn usecrcuir roporxoK 6eroro rlBera. Cogepxnt He MeHee99,5 Yo SrCO3.

Cyaan xpau*rfi

G. ClTHl+NzOz.(M.r. 278,30). PacreopuruufiKpacHufi 1.

1- [(2 -MerorcuQeuun)aso] na$ r atms-2-ol. rlBera. lloporuor KpacHoBaro-KoputrHeBoro llpaxruuecKlr HepacrBopr4M BoAe. B Xp o.nt o zpa Q un. Onp e4eneHr4enpoBoA.rrrMeroAoM roHKocrofi uofi xpoMaroam rpa$uu, ucilonb3yr B KaqecrBeroHKoro cros. curvrKarenb G. Ha xpoMarorpa$uqecKyro rrJracruHKyHaHocrr 10 uxr 0,01 o pacrBopa B MerrIJIeHXnopI,IAe Lr xpoMarorpaSrapyror B roM x<epacrBopllrene. flnuna upo6era Spoura pacrBopr4Tenr oKoJro10 clr or Jrr,rHr4rr crapra. Ha nonyuesnofi xpoMarorpaMMe AonxHo o6HapyxuBarbcr roJrbKooAHo ocHoBHoefltrHo.

Cyaau1
rlBera. flopourox opaHxeBo-KpacHoro flpaxruuecKrr HepacrBoprrM BoAe,pacrBoprrMB MerrrneHxnopuAe. B Tennepamypenna*reHun. Oxolo 131 "C. Cysan lll.. C22HroN+O.(M.r. 3 52,39). MeranruqecKr4M Kopuuuenufi ropouroK c 3eJreHbrM 6recrou. o pacrBopl4M 6eHgorev xnopo$oprvre. s Mano pacrBopr.rM crrvpre 96 , B (M.r. 380,45). Cyaan lV. C24H2oN+O. rlBera. floporuox or Kopr,rqHeBoro KpacHoBaro-KopuirHeBoro Ao o pacrBopl{Me xnopo$oplre. Malo pacrBopr{MB 3TaHoJre 96 , o/o Cyaaua IV pacrrop 0,5 0,5 r peaxurBa pacrBopflror n xnopo$opMe rr AoBoArr o6reu pacrBopa xnopoQoprvrovr ao 100 rran. Cynena. Cu. Pryrn(II) x"ropng. CynrQaurrHoBas KncJrora. NH2SO3H. (M.vt. 97,09). 6eroro rlBera. Kplrcrannraqecrufi nop oruoK nnw KpvrcraJrJrbr pacrBoprrMaB arleroHe,crrrpre 96 % }I MeraJlerro pacrBopr{MaB BoAe,yr!(epeHHo n HoJre, [paKTuqecK]rHepacrBopr{Ma oQupe. TemnepamypamaBreHun. Oxotto 205 "C c piBnox{eHrreM. Cy.nrQarvrunonofiKrrcJrorbrpacrBop 3 oh.Pacrnop 30 r/n. Cy,rrQannrraMrrA. C6HsN2O2S.(M.rr,r.172,20).4-Avrnuo6eH3oncynb$onauu4. floporuor 6eroro rlBera. n Mano pacrBoprrM B BoAe,JrerKopacrBopr,rM rnnxrqefi BoAe,arleroHe, pa3BeAeHHbIx yMepeHHopacTBopI4M B KrrcJroTax pacTBopaxfr{ApoKcrrAoBrleror{Hbrx MeraJrJroB, 14 o eSrpe r4nerponefiuorvr e$upe. crrrpre 96 , TeunepamypannaBneHun. Ot<olo 165 'C.

(M.r"r. 173,19). 4-AiurEno6eH3orlCynrQanrrJroBarKl{crrora. C6H4(NH2)SO:.

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Benrrfi wlnn6enl'l.it cepoBarbrM Kpr{criurnuqecrufinopolroK. c orreHKoM pacrBopr4MaBoAe, VuepeHHo B npaKrr4qecKu HepacrBopraMa o crr{pre. s 96 (M.u. 566,6). lucynrSnw culauir,. Cy.nrQaHonufi cnunfi. CuHz1N2NaO6S2. Kuc:rornuir,cusui,rL CranufiVS. Harpux fila-(grcrr,rrraMrrHo)SeHur](2,4-gucytsexca-2,5gues-l -utwgen]4raerznaruuouufi . SoHaro$enur)uerureu] qux.nor flopouror SuoneronororlBera. pacrBopbr Pacrnopul,r BoAe. B r{Meror PasneAeHHbre crrHrorc oKpacKy, KoroparrrepexoArrr B xenryro npu npu6aBJreur4rr cJrorbrxnopv croBo.4op KLt ognofi KoHrIeHTprrp oeaHHofi.

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x.uopllAa pacrBop B 3rurreHxJlopnAe(orc.20 o/o) Cyprnrr(Ill) pacrBoptlor s 400 MJrerLIrIeHXnopHAa, Pacrnop i. 110 r cypbMbr(iil) xiropr,rAa oKcn.ua6eseoAHoro, nepeMelrrllBalor u $Ianrrpyror npu|antlrior 2 r aJrloMr4HHr qepe3 creKJrrHHsrfiSunrrp (40). ,{ono4xr o6teu Sr.rnr:rparaerrlJreHxnoplrAoM Onr[.{ecKar nJrorHocrb [onyqeHHoro pacrBopa, lo 500,0 Mn rr nepeMerxirBaror. 500 Hnr B KroBere c ronlul{Hofi clos 2 ctvt,ue npil r43MepeHHafl, AnsHe BoJrHbr ronxHa rrpeBbllxam 0,07. Pacrrop 1I. B srrrgxHoM ma$y cMerrruBaror100 MJIcBexenepernaHHoro aIIeTr4n-xnopu u 4AA MJI3THJreHXnopIlAa. rc Mecre. Xpanar B irpoxnaAHoM 90 CNreurusaror ul pacrBopa i rl 10 Mn pacrBopa II. Xpanrr no $laxouax opaiixeBofo creKna c npxreprofi npo6rofi. oKpaItruBaHLIs. rIpI4rrotBneul4l4 Cpox ro4Hocrr{ -- 7 cyr Fearrns HeroAeH pacrBop B xrlopo$opue {= 22'/r\ Cypruu(III) x"rropnAa 2-3 Xnopo$opM rrpoNrbrBaror pa3a paBHuntu o6reMaMrl BoAbII{ Bblcyrrl4BarorHaA tr Karr{x rap6ouaroM; tsLicyuesnrrfi xnopoQopM cJII{Baror [eperrpoKaneHubrM Bo roFrfiror, or6pac;inar [epBbre 10 un A:acrvrlrlrfrra. Bpet\{t Bbtcy[IldBaruflvile' peror{Kr.r xnopo$opnr cne.UyeT3ailIilulaTb Ol no:Aeficrsus cBeTa. Cypruu xnopo$opuoiu Ao rex irop, BbIcyureHFIb,IM Tpr{xnopllAnpoMbrBanr neperHaHHbrM rroKairpoMblBHoiix.rropo$opMHe Syger 6ecqnersu*r. cypbMblTpuxnopuAoM. OqurleHlrufi xnopo$opM Hacbrrualornpr.r20'C npoMblTbiM Cnreruuearcri uri pacrBopa cypbMbrTpnxnopula c 2 | ceHberoBoficolu rr rllTpyror 0,1 M pacrBopoMfroAaAo xeilToro oKpailruBaHtif,. I uri 0,1 M pacrnopa fioga coorBercrnyer 0,0114i r SbCl3, Koroporo B pacrBope 6rrrr He MeHee21,0 oh rl ne 6o,'Iee23,0 yo. nonN{Ho Tararosa. C6trl1206. (M. r"l. 180, I 6). D -nuxco-f eKc,vno3a. B floporuox 6eroro IrBera. Pac'reopnt'aa BoAe.

2,3 % lal", . Mrauyc " (2,1.9 pacrnop).

Ol ntaBneHua. 134 ao 135 "C. Teuneparnype Ta.iuruq cy.nrQar. TI2SO4.(M.rur.504,8). lurannux cynr$ar. [pH3Mu 6eloro IIBera. Porvr6oenrHble B rpaKTnqecKrrHepacrBopnM crllapre 96 %' B Malo pacrBopl4M Bo,qe, or TaHnHon afl KrrcJI 4.,{y6ra.rnnat KLIcJIora. Srecrsqze ueuyfixu nnu auopQnrrfi uopo[IoK or x(eJlToBaroro.IIo cBerno-KoputlrIBeTa. HeBOfO oh, pacrBopl{MaB B B JrerKopacrBopr,rMa BoAe,JrerKopacrBopl4Nla cnl4pre 96 O.{eHr n aqeroHe,npaKTuqecKllHepacrBopl4Ma sQllpe. or XpaHxr B 3anII4uIeHHoM cBera Mecre. Ilonncopdar 80. Tnun-80. Crra. (M.rnr.136,23). 1-Llsonponu;r-4-ueu4nlll4xnorexca-1 y-Tepnnuen. C16H1o. ,4-guen.
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TepnuneH-4-on. CtgHl80. (M.*. 154,24).4-Merun-i-(1-nrernnerun)qur,'rorerc-3-or. n-Menr-l-es-4-on. eH-l BecqeerHas, MacJIfl Hrrcra"f, xt{AKocrb.

d1i. o*oro 0,934. n1l. Onono t.477.

Tunnepamypa KuneHufl. 209 to 212"C. Or trncrora repflrrHeH-4-ota, XporvrarorpaQn.recrax [cnonb3yeMoFo rasosofi xpoMaB oh. rorpaQuu,AoJrxHa 6rrrr HeMeHee 98,0 (M.u. 154,24).(Rs)-2-(4-Merurqvrrorexc-3-enun)-2c-TepnnHeon.C1sH130. npo[IaHon. EecqnersueKprrcraJrnbr. pacrBoprrM cnr,rpre % u sSrape. flqaxrzuecKr.r HepacrBoprrM Bo.{e, B B 96 d,i . Oxono 0,935. n,' . O*ono 1,483. Ldl, . Orolo 92,5o. Te"unepamypa nna*neHua. Oxotro35 'C. Moxer coAeplrarbor 1 Ao 3 o/o BteprrrHeoJra. Xpolrarorpa$xvecrar qr4croraCI,-TepnrrHeoJra, ucrroJrb3yeMororasonofi xpoMaron o, rpaQurE, 6uru HeMeHee 97,0 ,{oJrxHa TerpadyurJr aMMoHnr6ponar.ra.1 6BrN. (M.u. 322,3 . C 6H3 6) Kpucrannu 6enoro r4Jrr,r norrrr46eroro rlBera. Te.tmepamypa nnalreHun. 102ao i04'C. Or (M.n. 800). TerpadyurrraMMoHrrn rrrApoKcu4. 30H2O. C16H37NO' o CI6H37NO 30H2O. ' Co,tepxrEr MeHee He 98,0 KpHcrarmt 6eroro r{Jrrr rroqrr{6eroro rlBera. PacrnopulrB BoAe. pacryop 1014oh Terpa6yrrrJraMMoHrrfl rrrApoKcrrAa (M.u.259,47), rprrroroBneHsufipa3BePacrnop,colepxarl1ufr104 rAr C16H37NO qr.rcrorbr. peaKTnBa :eHr{eM coorBercrnyroqeilcreneHIa pacrBop 40 o/o Terpadyurd'raMMonrrfl rrrApoKcrrAa (M.u. 259,47),ilpr{roroBJreHnuri pa3BePacrnop,coAepx{arr1uir r/n C16H37NO 400 rr4crorbl. peaKTr{Ba coorBercrnytoqefr crerleHrl JeHHeM (M.u. 339,53). Terpa6yuuraMMoHr.rq rr.rgpocynrQar.C I 6H37NOaS. 'KpNcrannu.recr[finopouroK HnrE Kprzcrannbr. 6ecqeerHbre pacrBopr{M BoAe MeraHoJre. -Ierrco B v Te.ttnepamypa marneHua. 169 ao 173'C. Or Onmuqecrcaa nnomHocma. 6onee0,05; uslaepnor onr[qecKyro nJrorHoctt 5 ok He pacrBopa o6racru AnrrH n BoJrH 240 lo 300 nu. or (M. Terpa6yurrraMMoHr.rq C . AnrnApoQocQar. I 6H3 sNOaP. n. 339,44) flopouor 6eroro rrBera, rrrfpocKorrurreH. pF1.Oxono 7,5 (17 Yo pacrnop). Onmuqecrcaa mamHocma. Ororo 0,10;u:rrreprrcT oflTnqecKyro [norHocrs 17 o/opacrBopanpr.r BoJrHbr su. 210 Anr{He E[
. r2o

rourefiuepe. Xpauxr B Bo3AyxoHenpoHt{IlaeMoM Terpa6yrrrrraMMoHus fioAHA.CroH:o IN. (M.u. 369,36). Co4epxur He MeHee 98,0 o Ct6H36IN. cnefKa oKpa[IeHbI. 6eroro IIBera, UJIIr Kpucralluqecxufi rroporxoK,I{nrr Kpr4craJrJrbr B Pacrnopnrvr clrlrpre 96 %. (M.u. 490,7). TerparenrllJlaMMouraa6pomHa.C23H66BrN. Kpr{craJIJIbI 6e:roro IIBera, i4nl4cnerKa oKpalueHbl. r4nr4 Kpucrallu.IecrNfi rropotrroK, Ol Teunepamypan.rra6tteHun. 89 ao 91 "C. TerparenruraMMoHlrfl rnApocl'.nr$ar. CzqHszNO4S.(M.vr. 45 1,8). Benrre Kpncrannbl. TeunepamypanrarneHun. Or 100 ao 102"C. TerparugpoQyp aH. C4H8O.(M. rtr.72,10). TerpaneruneHoKcl4A. BocrlnaMeHqlorlatct )KI4AKocrb. Ilpospauuar, 6ecunerwafl,, CNrenrueaercrc no4ofi, cnuproM 96 % r.r:$uporvl.

dii . onono0,89.
Ha He neperonror, ecnr4Terparuapo$ypaH He BbrAepxuBaerI{crIbITaHLIe nepoKcllAbl fioAtEAouroMenlaror B IIrrnI{HApc rrpuIleporccudal. 8 ul pacrBopa KpaxManac lrlaJrvrfl. oKoJIo1,5 cu, 3alorHqror rroJIHoreprofi npo6rofi eMKocrbro 12 wt rr AraaMerpoM Mecre B crbro rerparr4Apo$ypauorr.l,3areM nepeMerrruBaloru BbIAeplI(I{Baror TeMHoM 30 B TeqeHr4e lrran. He Aolxno sa6lroAarbcs oKparuvtaaHvfl. BbIAepxLIBarb Terparu4po$ypan, rlcnonb3yeuufi n cnerrpoQoroMerpl{I4, AoJIxceH I4cIrbITaHLIe. cneAyrcIqeeAoilonHl,ITenbHoe 255 nrrr;S0 % npia AnIrHeBoJrHbI 20 MuuuttanaHoe nponycKaHue. o/onpn LrruHeBoJrHbI 310 svl. 270 nv';98 % ilpl{ AnuHeBoJIHbI pacrBopa cpaBHeHI4t noAY. Oupe4ereHue npoBo.qtr,I{cnonb3yt B KaqecrBe (M.r'1.198,40). a-Terpa4eran. Terpa4exan. C14H30. 99,5 o Cr+H:0. Cogepxnr He MeHee Becqeerua.fl )Kr.{AKo crb. u B llparruvecKr.r HepacrBopl{M BoAe,JIerKopacrBopuM B 3TaHoire e$upe.

d]i . onono0,76. nli.O*ooo1,429.

KuneHufl. Orolo 252"C. Teunepamypt Oxotto-5 oC. nJla*reHun. Tetrnepamypa Cu. TerpagenaHoJl. Mnpncrulonrrfi crl{pr. (M.na. 659,0).Terpaxuc(..qequn)-arvr6pourua.C+oHs+BrN. TerpageqlrrraMMoHnr
MoHLIt 6porvrz4. Kpucrannuqecxnfi [opo[roK, unv KpMcraJUIbI6eroro UBera, rrJII{ cJrerKa oKpalileHbl.

ma*reHun.Or 88 ao 89 "C. Teunepamypa (M.r"r.727,6). 3,3'-(3,3'-.{uueroxcucunnfi. C40H32Cl2NsOz. Terpa:o.rtnenr'rfi '-6u$enut]-4,4'-tuul)-6uc-(2,5-tu$euun-2H-rerpasonrafi)Al'IxnoprrA. [1,1 Kpracrannbr xeJrrorouBera.

npaKT[r{ecKI'I u nerKo pacrBoplrMB crlrrpre 96 o/o MeTaHoJre, Malo pacrBopuMB Bo,rle, B HepacrBopr.rM alleroHe n e$npe. TeunepamyparutazreHua.Oxotto 245 "C c pa3noxeHrreM.

ryqlil-.*,.

TerpalrerrrrraMMoHrrfl rr.rApor(cnA. C+H13NO . 5H2O. (M.rnr.lgl,23). Terpa_ueru_ .l arrMoHr{r rr,rApoKcr,rA, rreHTarr.rApar. Kram,r$zraqux _ p.nflB OXX. TerpanrerrrJraMMoHnqruApoKcr{Aa pacrnop I 0 yo Colepxur He MeHee10,0 oA(vrlrr,r) C4HI3NO. (M.r. 91,15). flp ospaunax, 6ecqnernat vru cJrerKaoKparrr eHHar xkrlKo crb. Cverursaerc-r c nolofi v cnrrproM 96 %. TerpalreurJraMMoHrrfl rrrAporclrAa pacrBop p a3BeAeHnrrfi 10 nanI0 o/opacrnoparerpaMerrrJraMMoHr4rr rr4ApoKcr{Aa AoBoArr cnr{proM 96Yo, ceoSo,rsrru or iubAerkrAoB, o6reua 100 un. Ao foros-{r HerrocpeAcrBeHHo nepeA vcrroJrb3oBaHrreM. TerpauerrrraMMon rrfl ru2pocylrQar. C4Hl 3NO4S.(M.u. 17l,2l). I-lrrpo cxonu\Hstir nopomoK. l,.,,trtepamypa mA7]reHua.oxotto 295 "C. Terp arrerrrrraMMourrn x.ropug. C aH12ClN. u. 109,60). (M. SecueerHrreKpucrannrr. Pacrsopr,rM BoAeu crrr4pre96 %. B , e.rntepamypa nnazneHua.Orcoto 300 "C c pa3JroxeHr{eM. Terp alreurJraMMoHnff xr'ropuAapacrBop - 1t.96r rerpaMerl4JraMMoHt4t xnoprrAapacrBoprrcT B BoAen rvrepnofi xor6e BMecrrr\,lr'rCTblo n n AoBoAtr o6reu pacrBopa nolofi I Tpe6yeuoe 3HaqeHr4e Ao MerKLr. -.0 ycraHaBnplBaror npz6anreurer,r K pacrBopy no KanJr{M M pacrBopaeAKoro iil 0,1
: iTpa IOTOHULIOMOTpUYOCKI4.

- ;r.'- (N,N-4IrMerI4JraH uluu). :.rlrcra;urr or 6enoro 4o rony6onaro-6enofo uBera r4Jrr4 JlrlcrogKH. *:axruqecKH HepacrBoplaM Bo.qe, B Malro pacrBopkrM crrrrpre 96 oA,pacTBopr4M B B ',1 rHepar.:rbHbrx ; Kr4cnorax,Jref pacrBoprrMr eQupe. Ko -:vrtepamypo nJrarneHun. Orcoto90 "C. T er p atr ern JrA aMrrHogn Qeun.nMer aHa p eaKTHB rr Pacrnop A.2,5 r rerpaMervln[vlaMuuo4u$eHuJrMeraHa pacrBoprrcr s 10 Mn yKcycsoir xucnorbr neArHoia u npu6aBJrrror 50 vrn BoAbr. Pacreop E. 5 r KarwrflirogusapacrBoprrcr s 100 Mn BoAbr. Pacrnop B. 0,30 r HI{HrI{ApuHapacrBopmor n 10 iranyrcycnofi Kr,rcnorbrters;gloit u upu6aunor 90 rran BoAhr. Pacrnoprr A u B cMerrrr,rBaror, [onyqeHHoMy pacrBopy npu6aytxLor 1,5 MJrpaK crnopa B. TerpauerrrJrctrrran.C4H12Si. (M.rur. 88,23). TMS. ilpoepa.rHax,6ecqnerHar xr,rAKocrb. oqenr ManopacrBoprrMB BoAe,pacrBoprrMB arleroHev cflr{pre 96 %. d,i . Oxono 0.64. /t, . Oxoto 1,359. Teunepamypl KuneHut Oxolo 26 "C. Te:rparr,rerr4Ircvlra*,I4crlonb3yermrfi crreKTpocKotIIarI B fAepHoro MarHI,ITHoro pe3OHaHCa, IOJI)KeH BbIAeplKLIBaTb CneAyIOilIee AOIIOnHLITeJIbHOe14CnbrTaHlre.
, o '

Terparrerr{rrAr{aMr{Ho4r.r0ennrMeraH. CI7H22N2. (M.rr. 254,37). 4,4'-Merurlen-

B cuexrpe.f,MP rprlMepHoI0 % (o6lo6) pacrBopa rerpaMerr,rJrcrrrraHa n gefirepI4poBaHHoM xnopoSoprrae I4HTeHcr{BHocrb nrc6oro rrocropoHHero ct{rHaJra, 3a

cBq3euII xJIoooKoBbIX BpaIrIeHI{Io TeX, cooTBeTcTByroT HCKnIOqeHIIeM KOTOpbre 6oxoerrx nuuui,t C-13, pacropo$opMy, He AonxHa npeBbrrxarbIrHTeHcr.rBHocrIr JroxeHHbrx Ha paccrofl:auyt 59,1 fq no o6e cropoHbl ocHoBHoro crrrHaJla TeTpaMeTr4rrcvra}{a. Terpaueulrl3rrlJrenAllaMuH. C6Hl6N2. (M.t"r. 116,21). N,N,N,'N'-TerpaMerI4JISTIiJIEH,iILIAMUH.

xrrAKocrb. EecuserHaq c CNrerursaercr nogofi,cnl{proM96 % u aQupou.

dii . o*ono 0,78.

nT .Oxoto1,418. KuneHufl. Oxolo l2l'C. Teunepamypa VmepoAarerp axJIoprIA. Terpax,ropM eraH. Crvr. erpaxnopsraH. Terpax.rropsraH. 2H2Cl (M.*. | 67,84).1,1,2,2-T C 4. xrlAKocrb. 6ecqnerHat Ilpospauuax, co B cMellrnBaerc-r cnlrproM96 % u eQzporvr. Mano pacrBopr{M BoAe, d i i .o n o n o 1 ,5 9 .
z, . Oxono 1,495. reperoHtrbcq He Or Teunepamypuue npedend nepe?oHrcu. 145 lo 147 "C; AoJDKHo MeHee %. 95 TerparruJraMMoHrlfl rrrApoKcllAapacrBop 20 7o. CsH21NO.(M.u. 147,26). xl.rAKocrb,tBJltercq cumHofi Iqenoqblo. Pacrrop 2A0 rlry 6ecqserHa.f,
20

dii .onono 1,01. ,li .Ononol,372. Knanu$ux a\r4fl. ans B3XX. (M.u. 227,32). ruApocyrrcQar.CsH2 TerparrnJraMMonlrr 1NO4S. fiarpocronv.rnsrfinoporroK. nrarneHua.Oxolo 245 "C. Teunepamype (M.*. 257,17). fiolna. (C2H5)4NL TerparrnrraMMoHr{fi EenueKprrcrannbr. Teunepamypa ruazreHua.Oxolo 320 oC,c pa3nox(eHl{eM. (M.t. 189,31).3,6,9-TpI4a3ayHAeKau-1,11CsH23N5. TerpaerurreHrleHTaMl{H.
trIdAl]MVTH,

PacrnopuM B alleroHe. EecqnerHaq)Kr4AKocrb. /?, . Orolo 1,506. Mecre. XpaHrr B cyxoM u npoxnaAHoM T[asorosrrfi xe.urrrfi. Cvr. Turanonrtfi xelrufi. Tuanalo.rr. C4H6N2S.(M.r"r. ll4,l7). Mernua:on. 1-Mernn-1H-urvrn!.asor-2-rnor. rotITLI 6enoro IrBera. Kpucramraqecxufi ilopouroK 6e.noro I4JII{ yMepeHHo B B Jlerro pacrBopr4M BoAe,pacrBopr4M cnr4pre96 % I,IMerr{JreHxnopl4Ae, pacrBopr4M e$upe. a Teunepamypame*reHua. Oxolo 145 "C. or 2-(2-T*temr.n)yxcyur afl KrrcJI a. C 6H60 25. (M. u. | 42,17). IIBera. lloporuox KopnrrHeBoro TeunepamypennarneHua.Orcoto 65'C. @

T n rr n n. C 5H6N2O2.(M. r. 12 6,12) . 5 -Meruln krpkrukr1Lrla-z,4 3H) -4uon. (IH, Kop or x u e n roJrbq arbl e Kpr.IcraJrlrbt uIrtt nn acrr4HKut. \faro pacrBopplM xonoAHofino4e, pacrBopLtM ropr.refi BoAe,pacrBopr4M pa3BeB n B
.leHHbIX paCTBopaX I'I4ApOKCLIAOB ilIenOqHbIX MeTaJIJIOB.

Tnrro,r.C6H14O. (M.pr.150,22).
becueerHlte Kpllcranlrbrvrrrkr KprrcraJrJur.recrufi nopolroK c xapaKTepHbrM 3anaxoM. OqeHr Mano pacrBopl4MB BoAe,oqeHb JrerKopacrBopr{MB crrr4pre96 % u e$upe, .lerKopacrBopt{Mn eonpnux n x{I4pHbIX yMepeHHo MacJrax, pacrBoprrMB DrrrqeprrHe, pacrBopr,rM pas6aueHHbrx rqenorrax. r \povarorpa$uuecxax qucrora rr4MoJra, ucilonb3yeMoroB raeoeofi xpoMarorpa$uu, o . -lo,rr{iHa 6urr He MeHee95,0 Trtrtona pacrBop crrrproBbrfi 20 o .20 r rnuona pacrBop*or B crruprc 96 %o lou Bo.l;rr 3Tr{Mxe crurproM ao 100 rr,rr. Trrrtorosrrfi cunnfi . C2jH30o5S. (M.u. 466,6). Tuuoncym$o$ranenu. 4,4' ,-1H-2,1-Een:orcaruor-3-nnu4eH)fucf2-usorporun-5-rvrerHn$eno;r]-S,S-trroKclr.q. Kpllcrallnqecxufi [opo[IoK or Kopr4qHeBaro-3eJreHoro rlBera. Ao 3eJreHoBaro-cr{Hero pacrBopl{MB BoAe,pacrBoplrM B crrr4pre96 % r4pa3BeAeHHbrx \laro pacrBopax rkt.lpoKcr{AoB rrlenoqHbrx MeTaJrJroB. Tlrrro.nonoro cnHero pacrBop 0rl oh tt.1 r ruuoJroBorocnHero pacrBop-f,ror cMecr{2,I5 *n 0,1 M pacrBopa :aarpufl B . rr-tpoKcr,rAau20 96 o/ocrtupra, AoBoA-f,T un o6renapacrBopa no4ofi ao 100 nrn. ilcnumauue Ha uyscmrumenbHocmb. 100 MJrBoAbr,cno6o4uofi or yuepoAa K riloKcllAa, npu6antxrcr 0,1 rral pacrBopa rrrMonoBoro czHero u 0,2 rvln0,02 M f acrBopa HarpLrflrLIApoKcIrAa; no-f,Bnfl.ercfl, cuHee oKparurrBaHr{e, KoTopoenepe\o-tnr B xenroe upu npu6aBreHuw ne 6olee 0,1 ul 0,02 M pacrBopa xnopr4.-r o BoAopo4uofi Kr4cJrorhr. flepexo4 oKpacKnor KpacHoi 4o xenrofi n r4HTepBane r,2-2,8Ir or onr.rBpH KoBo-3enenoft culaeitB r4HTepBane 8,0-9,6. pH 4o oh Tnrro.nonoro crruero pacrBop 0104 ',t.1r rurraoJloBoro cLIHeropacrBoprrcr n 10,75 vn 0,02 M pacrnopa Harpqrfl rrr,qpo\cir.rla rr AoBoArr o6reu pacrBopa no4ofi, cno6o4Hofi or yfnepoAa [vroKcwra, :o 250 rr,u. I llreseHue oKpacKr.r Bbrrue. cM. Tnrro,ronoro crrHero cnrrproBbrfi pacrnop 0rl oh r-).1 rzuoJloBoro cLIHero r pacrBopsrcr n 50 Mn cnr4pra96 % [pr{ HarpeBalvnrHa Bo:snofi 6ase unocJle oxnaxcAeHlltAoBoAq:r o6reu pacrBopa noAofi Ao 100 M-rr. ZsNaeHeHHe OKpaCKV Bbrrue. CM. Tsvo.nonoro clrHero MeraHoJrbHrrfi pacrnop. 0,3 Yo pacrnop B MeraHoJre. Tnrro.nonofo crrHero pacrBop I oh, I Yo pacrtop B rnMerl{nsoprvrarrav4e. Turrorosrrft cnnnfi BoAopacrnopnurrfi. C27H33NO5S. (M.u. 483,6). AuuoHufiHar coJrb2,2' -flulaerul- 5,5' -It4rr3onponutrQ euoncylr$ oSraJrer4Ha. \{e,rxorpucraJlJllrqecxufi noponoK KpacHoBaro-Kopr{qHeBoro rlBera c MeraJrJurqecrurlr 6recxorrl. Pacrnopr,rMB BoAe.

23 3ax.2768

pacrBopaor KpacHofi xenrofi n unrepnare pH 1,2-2,8rr or xeJIflepexo4 oKpacKr.r r pH roft r czHefiB r,rHrepBane 8,0-9,6. pacrBop. 0,04 o pacrBop. Tuuoronoro cnHero Bo,[opacrBopnMoro r u flepexog oKpacKr.r KpacHofi xemofi B r4HTepBarrepHl,2-2,8 or xemofi r cunefi or pH B r.rHrepBaJre 8,0-9,6. (M.u. 430,5). 3,3-Buc(4-rl4ApoKcll-5-zsoupout-2Tnno.nQrarrerrH. C28H30O4. 1-os. uerurSeHun)-3 H-uso6enso$ypanlloporuor or 6enoro.{o xeJrroBaro-6erororlBera. papuBBeAeHHbrx pacrBoplrMB crurpre 96 % 14 flparrrvecKr4 HepacrBoplrM BoAe, B
[IenoqHbrx MeTaJrJroB. crBopax f r4ApoKcr4AoB

Trauon$raJrer,rnapacrBop 0rl o/o.Pacrnop 1 r/n s cnrapre96 %. IrlcnutmauueHa qyqcmsumenbHocmb. 100 MJrBoAbr, K cno6o.qnofior )rmepo.qa AI,IoKcw1a,npu6annxror 0,2 tv'npacrBopa ruvronQran evtna,pacrBop 6ecqsetHrtit; rtpu npurrrApoKcrua AoirxcHorrotBlrrbcfi 6asnenmse 6oree 0,05 run 0,1 M pacrBopa Harprrfl. pacTBopa. cr{HeeoKparur{BaH[e pH flepexo4 oKpacKrr 6ecqsersofi Ao czuefi B r{HrepBane 9,3-10,5. or Tuoaueranng. C2H5N5.(M.u . 7 5,13). KpncrarruqecKufi [opolroK Ianu 6ecqeerHbleKplzcrannbl. Jlerro pacrBopnM B BoAer{ crrrpre 96 %. Te.mnepamypa nnerneHua.Orcoto 113 "C. TnoaqeraMrrAa pacrBop 4 a/o.Pacrnop 40 r/n. TuoaqeraMrrAa peaKTr{B K 0,2 rvm4 oh pacrBopa rrroaueraMuga rrpu6aBJu{rorI ur cuecu 5 rur BoAbI, 15 rr,rn 1 M pacraopa Harpr,rrrrrApoKcr4ha u2A tw rJrurlepvHa yo, HarpeBarorna soAsHoft 85 6ane s reqeHNe20 c. lorosrr Herro eAcrBeHHonep eA rrcloJrb3oBaHrreM. cp Tnodap6nrypoBan Krrcrrora. C4H4N2O2S. (M.u. 144,15). 4,6-!urugporcu-2cynr$ anunrurpr4MlrArrH.

(M.r. 92,11).2-MepxauroyKcycHar KrrcJrora. Tuor.nurcoJreBafl Krrcrrora.C2H4O2S. Bec[eerHax xrr.uKo crb. B Crueruznaercfl, c no4ofi,pacrBopraMacnrrpre96 %. Harput Tnonrepca.n.CeHeHgNaO2S.(M.*. 404,8). Harpux MepKyporrloJlar. 2-[(erHnrueprypuo)rr,ro] 6eHsoar. Jlerrv fi Kprrcrannu.re cxufi nopouroKx(eJrroBaro6eroro rlBera. pacrBoprrM cnrlpre 96 o , [paKTuqecKz pacrBopr4M BoAe, HeB B Oqenr JrerKo JrefKo pacrBoprrM eQzpe. n Tnoilro.rennna. H2NCSNH2.(M. pr.76,12).Tuorap6arvrug. Kpucranluqecxufi [opo[rox vnv KprrcrnirJrbr 6enoro rlBera. Pacrnopurua BoAe crutpre 96 %. B r.r Teunepamypa nnazneHua. Oxono 178'C. TupaunH. CsH1tNO. (M.u. 137,I 8). 4-(2-Arvruuoerzn)SeHon. Kpzcrarnu. pacrBopr,rM roprqeM graHoJre. Mano pacrBopr.rM BoAe, B B Tennepamypa nna*neHun. 164xo 165"C. Or

TnpornH.CeHltNO3.(M.u. 181,19).2-Arvrzno-3-(4-ruaporcu$enzn) nponzononax

KHCJIOTA.

Kpucrannr.recxufi noporxoK rlnH KpncruurJrbr 6enoro rrBera, Hru 6ecqserHbre KpLtCTAJIJIbI.

Mano pacrBopr,rM B BoAe,npaKTr.rqecKr{ HepacrBopr,rM arleroHe, oraHoJreu eSzpe, B pacrBopt4MB Kr.rcJrore pasne4ensofi H pacrBopax rr.rApoKcrrxJropr4croBoAopoAHofi IOB nlenoqHbrx MeTaJIJIOB. Turan. Ti. (A.v. 47,90). Cogepxur He Meuee99 %Ti. Mera.nnzqecxufi [opouroK, r4nr4 ToHKar npoBonoKa, rvraMerpoMue 6onee 0,5 ruu, irru ry6ra. Te.vnepamypa ma*neHun. Orcono1668'C. Il:omuocmr'. Oxoro 4,507 r/crra3. Turana ArroKcrrl. TiO2. (M.u. 79,90).Turaua AByoKr.rcb. Ee,'rsrfiLtJrunoqrlr 6enufi noporrroK. llparcruvecKr{ HepacrBopraM BoAe,HepacrBopr,rM pa3BeAeHHbrx B B M}rHepiurbHbrx KrrcpacrBops.ercfl ropxuefi cepnofi KrrcJrore -rorax, Ho MeAneHHo n KoHrleuTpr4ponanHofi. Turana ArroKcrrAapacrBop 0.1 r rvrasa AIroKcIrAa HarpeBarorco 100 ir,rn cepuofi KktcJrorbr KoHrleHTprrponanHofi Ha cerKe rrpu [epr4oAr4qecKoM rrepeMerrruBaHvrvt nonHoro pacrBopenufl. XpaHxr n Ao creKnrHHoMcocyAe c [prrreprofi npo6xofi. Tur aHa(III) xropng. TiCl3 . (M. rnr.| 54,25). Tur a;aa rpr{xnoprtA. Kpucrarru KpacHoBaro-QuoneroBoro rlBera, pacnJrbrBarorluecr Bo3Ayxe. Ha o/o, Pacrnopurr,r BoAe14 B rrpaKTr4qecKu cnr{pTe96 HepacTBopr,rMeSzpe. n Texnepamypama*neHua. Oxoto 440'C. Xpauar B Bo3AyxoHerrpoHrrrlaeMoM xourefiuepe. Tnrana(III) x.nopn4a pacrBop l5 o . Pacrnop 150 r/n B pacrBope 100 r/n (HCl) x-roprrcroBo4opo4Hofi Kr4cJrorbr. d,., . Oxoro 1,19. Tnraua(III) xJroplrg - cepHofi KrrcJrorbrpear$rrB 20 nrn 15 YopacrBoparr{rana(Ill) xnopuAa ocropoxuo cMerrrr{Barcr l3 rr,rrr c cepnoft Kzcnorhl KoHlleHTplrponauuofi npu6 an:lnfor AocrarorrHoe KoJrrlqe crBo pacrBopa Bo, KoHueHTprlp oBaHHoroAo nonyqeHl4r )KeJrToro arrr4BaIJvs., IJaoKp IOpOAarrepoKckrAa rpeBarcT Ao HarraJra BbrAeJreHr{s 6enux [apoB r.r oxnaxAaror. Pagso4xr no4ofi, loBToptrcT Bbrnapr{BaHve upN6annenue BoAhrAo flonyqeHur 6ecunersoro pav crBopa, AoBoArr o6renapacrBopa soAofi ao 100 run.

(M.u. Trranosrrfi xe.urufi. C28H19N5Na2O6Sa. 695,7).Tr.rasorosufi xenrnfi. [zHarpufl2,2'-l(l-rplla3eH1,3-luul)lra-4,1-Qeuzneu]6uc-[6-rvreru;r6ensorraasor-7cynrQoHar]. floporuox xeJrroBaro-Kopr4rrHeBoro rlBera. Jlerro pacrBoprrM BoAe cnrpre 96 %. B rr Turanonoro )r(eJrroro6yrrara florocxz SunrrponanrHofi 6yrr,rarn rolpy)Karor B pacrBoprr.rraHoBoro xeJrroro, BbrHecKoJrbKo MrrHyT cylraT npr.rKoMHaTnofi rr rerr.rueparype. Aep)Kr,rBaroT

o/o. pacrBop 0105 Pacrnop0,5 r/rt. Turanonoro )rceJrroro patr'Icnttmaulte q))6cm6umerbHocmb.10 Mn BoAbr K npn6annrrot 0,1 rr,rn Ha c r Bo p a rv ra H o B o fo xe Jrro ro, 0,2 MJr gr anoHHor o pacr Bopa Mar HLr t (10 ppm Mg) r 1,0 rur 1 M pacrnopaHarpur rr4ApoKcu6a. flory.rennwirpapacrBopoM, rrpuforoBJreHHbrM TaKr.IM o6xe crBop cpaBHr4BarcT c 3TairoHHbrM po3oBoe pa3oM, rrcKJrroqeHr{eM MarHHr;AoJr)KHo na6rroAarbcq 3a orqernrrBoe oKparIInBaHr{e. (M"rur. To:n.uaprrrHrrrra MerrrJroBoro rQupa rr{ApoxJlopug. C1aH23CIN4O4S. 378,9). N-Tosur-L-aprrrHlrH Merr4noBoro eSuparrrApoxnopuA. 3ru;r-(S)-5-ryaHv.Auleo-2(4-uerun6eH3on-cynrQonavrugo)eanepara rrrApoxJropu.u. -12' 4o -16o (4 oh paunop). lal',".Or Te*tnepamypa nna*reHua.Oxono I45 "C. To:nr aprlrHlrHaMerr{JroBoro rQupa rrrApoxJropflla p acrBop K 98,5 Mr ro3unaprvrnvrna Merr{noBoro e$rapa rr{Apoxnopugatpu6aBJrrror ur 6y5 rpzc(rugpoKcr.rMerrrr)aruuxoir,reraHa 8,1, ncrpxxuBarcT c pH Ao $epnoro pacrBopa pacrBopeHux, pacrBopaMerr4JroBofo rtpu6aBrqror vtt cMerrraHHoro 2,5 KpacHoro H eogofiIo 25 rran. AoBoArro6reu pacrBopa (M.na. Tosrr-rr3rrJr-xJropMeranarr.rApoxrropua. C1aH22CL2N2O3S. 369,30). (3 N-Tosur-L-irrr3r{Jr-xJropMeraHa rr{Apoxnopua. S)-7-Aruuno- -xnop-3-(4-Merr{rrI 6eusoncynr$ouavrn4o)renran-2-oH rrrApoxnoprrA. -7 .uo-9 ' (2oA pamnop). lal") . or Teunepamypa nra+teHua.Ot<ono155"C c pa3JrolKeHrreM. A. " . Ol 3 10ao 340. OnpeAeneHr{e rpoBoAflrrpr4AJrr{He BorrHbr uu, ucrorb3yq 230
pacTBopacpaBHeHrrr B KaqecTBe soIY. To:lr"rQenr.rJraJraHnr'rxJropMeran. 7H 1gClNO3S. (M. rur. 5 1,83). C1 3 N-Tosrr-L-SeHuranaHr.rnxJropMeraH. o pacrBopB crr{pre 96 %). tal') . Or -85 ao -89 " (l Te.wnepamypa Or<oiro 105 "C. nira<neHuq. 4,.",,. Ot 290 ao 320. OnpeIeJreHHerpoBoAflr ilpr4 AnlrHe BonHbr 228,5 HM B crr4pre 96 %. o-T onu4*rH. C i aH 16Nz. (M. u. 212,29). 3,3' - Auv'euEn6eHsu.quH. Co4epxnr He MeHee 97,0 oh C14H16N2 . qBera. Kpucrauprqecxnfi rropoilroKcBerJro-KopuqHeBoro TeunepamypanrlerneHua.Oxolo 130'C. o-Tonuauua pacrBop 0,16 r o-ronrrAuHapacrBop-f,rcr 30,0 Mn yKcycHoil rnc.norur ne4xuofi. upu6annxrcr n 1,0 r rca-nlrxfioru1.a AoBoArr o6lelr pacrBopa no4ofi go 500,0 vn. u o-To.nyH4Hu.C6Ha(NH2)CH3. (M. u. 107,15). 2-Meruta*Lrrrvtr. XnAxocrs cBerno-xenroro rlBera,uoA AeicrBrreMBo3AVxa cBeracraHoBr.ITct H KpacHoBaro-Kopnvuenofi. Mano pacrBopl4M B BoAe,pacrBoprrMB crrr4pre96 % u pa3BeAenHbrx KrrcJrorax.

dii .Onotto1,01. nil . g*o,ro1,569.

Te"rwnepamypa KuneHun Oxolo 200'C. Xpaurr tsBo3AyxoHerrpoHrrrlaeMoM xonrerinepe, B 3aurl,ruleHHoM cBera Mecre. or
@

n -TorynAr{H. C6H4(NH2)CH3.(M.rnr.I 07, 15). 4-MerunaHrrJrr.rH. Ere cr.f, Kn ulae rrJIacrI{H urru xroflbq. Mano pacrBoplrM B BoAe,JIerKopacTBopr.rM arleToHe14cfrr4pTe Vo,pacTBoplrMB B 96 eQxpe. Tettnepamypanna*reHun. Oxoto 44'C. o-To.uyrrgr{Ha rrrApoxrropnA. C6H4CH3NH2 ' HCl. (M.r. 143,61). 2-Merutauvrruna rr4ApoxJrop 2 -Merur6ensoraMr4Ha rr{Apoxnopr4A. ul. Co.uepxur He MeHee98,0 o/o C7HlgClN. KpucrarrrEqecrufi nopoilroK. Te.vnepamypa nna*reHun. Or 215 rc 217 "C. T o . n y n 4 H n o n u f i c n n n f i . C t 5 H l 6 C l N : S . ( M . r u r .3 0 5 , 8 2 ) . T o n 4 y u 4 z u o s u f i cr.rHufi O. - A rr.r Ho - 7 - Au u erprJraMHHo - 2 - rr,r un eHor r.r r{n a- 5 - xI op lr g. 3 u er a3 $ llopourox reMHo-3eJreHofo rlBera. Pacrnopurra BoAe,MaJro pacrBoprrMB cnupre 96 %. B To"ryu.ueHonrrfi npacHurfi . Crvl.Hefi rpa.nrHrrfi rcpacHsrfi . To.nyo.rr. C6H5CH3.(M. r"r.92,13). Merur6eHsor. fiporpaunax, 6ecqnernafl.,BocrrJraMeH flrorr\aflct )Kr{AKocrb. pacrBopr{MB BoAe,cMerrrr4Baercr cnr4proM96 %. O.{eHr MaJro co

d.i . Or 0,865 0,870. ao

Te.vnepamypa KuneHufl. Oxolo 110 "C. To.nyonocnodogHufi or cepu u uc{olxen BblAepxuBarr rpe6onaHnfl.Anfi.Tonyona cneAyroqee AorronHr{TeJrbHoe
IIbITAHI4E.

Cepocodepcrau4ue coeduueuua. K 10 vr:r ronyona upv6anrxror 1 MJr 3TaHoJra, 3 vll pacrnopa Kanl4t n;tou6nra v lxvnflTflTc o6parHuM xonoArrJrEHHKoMTerreHue B l5 nrns. r{epee 5 uus soAHsrficlofi ne AonxeH noreMHerb. Bett4ecmea, podcmeeHHbte muoQeuy.2 *rn roriyona Bcrpsxr.rBalorc 5 ur peaKTr{Ba vt3,arlaHaTerreHue nrus u ocraBJltlor Ha 15 rraun;B Hr4x(HeM B 5 cJloeHe AoJDr(Ho Ha6moAarrcq cuHeeoKparlr{BaHr{e.

o-To.rryo.ncynrQoHalrn4. C7H9NO2S. (M.r"r. 17I,2l). 2-Merut6eH3orrcyrrb$ouaura4. Kpucrarruqecxuri uoporroK6eloro uBera. Mano pacrBopr4M BoAe sSupe,pacrBoprrM cnr{pre96 % u pacrBopax B u B ruApoKcI4AOB ilIenOrIHbIX MeTaJIJIOB.

nitaBneHun. Oxono 156 "C. ,Tennepamypo 'Tonyo.ncy.nrQoHarurg. C7HqNO2S.(M.nr. 171,21).4-Mernl6eHeolcy;n$onarrlnl. z - To.rryolcynr QoHauug. Kpucra.,uuqecxufi iloporxoK 6eroro rlBera. Mano pacrBopr{MB Bore u r$upe, pacrBopr.rM crrprpre96 % u pacrBopax rilApoKB
CU.iIOB IUEJIOqHbIX MCTAJIJIOB.

TeanepamltpamarreHua. Oxoto I 36'C. .HzO. (M.r. 190,21).4-lVlerlu6eHsonTo.nyorrcy,nrQononax Krrcrrora. CTHSO3S cynr$onoBar KucJrora. Cogepxur He il,reHee 87,A o/o C7HsO3S.

KpI,IcriLJrJrbI 6eroro uBera. KpucrarnHqecxzft flopo[roK r,rnl,I pacrBopuMa crupre 96% u eQupe. B B Jlerro pacrBoprrMa BoAe, Topnn. Crvr. HaQrap3on. (M.r"r. 394,43). 9-<Drop-11B,16o,17,2l-rerparvpTpnaMquHorroH. C2rH21FOo. - gues-3,20[uou. poKcr{rp ua-I,4 er crIaft Eenufi r.rr[ rrorrrri6enufi Kpr,rcrilrrnrr.re nopolxoK. B MaJIo HepacrBopnM BoAe Merr4JreHxJropraAe, pacrBopl,IM MeraHoJIe. B u llparcru.recKlr Teunepamypa nnarneHun. 262 to 263 "C. Or TpuaTpnaqernH.(CH3COO)3qH7.(M.*. 218,21).llponan-1,2,3-rpuunrpuallerar. rIeTaT rnr4rleprrHa. IIBera)Io.IAKo crb. floqrlr [po3patrHar,6ecqnernafl vrrn xeJlToBaroro co PacrnopuuB BoAe, cMerrrnBaerct cruIproM96% u aSuporra.

dii . o*ooo 1.16. n'] .Orcono 1.43.

TennepamypaKuneHufl. Orono 260'C.

(M.r"r. Tpnrcoran. 324,61). Cz:H+s. Kpncrannu6enororlBera.

pacrBopl,IM s$upe 14 n reKcaHe. B flparruuecKr,rHepacrBopr.rMBoAe, txo . Oxoto 1,447. 48 Tennepamype nna*neHun. Or<o:l.o 'C. Tpn.noH Crra. E. Harpnr sAerar. Tpnnrern;ureHraH. CsHrs. (M.u. I I 4,23).I,Igoorras. -T put"terr,rJrrr 2,2.4 eHTaH.
Eecqnernax, BocllJlaMeHtroilIiuc{ xrlAKocrb. flpaxrnuecxr4 HepacrBopr{MB BoAe,pacrBop[M B sraHoJle.

dXi o, o,6gt 0,696. . ao

ftu . Ol 1,39Iao 1,393. neperoHtrbct He nepezoHrcu. 98 ao 100 "C; Aort>KHo Or Teunepamypuarc npedenbt MeHee %. 95 BbIAep)KIaBarb cJIeTpuruerunfreHTaH, rrclonb3yeMHfi cnerrpo$oroMerpr{}r, s Aon}I(eH
qr4e AO r,rre Hbrer4clrbrT aHvrg. IOJrH Jrb AyIO MuuuuanaHoe nponycKaHue.98 % s o6racrr AILIH BoJIHor 250 lo 420 uv,; B KaqercloJrb3yloT goAY. cTBepacTBopacpaBHeHr.rr BonHor 220 lo 360 uivr;e Onmuqecrcan momHocmo. He 6oree 0,07 n o6racru AJrrrH Kaqe uc[oJrb3ytoT BoAy. cTBep acTBopacpaBHeHr,rr N-TpurvrerrrJrcrrJrrrJrr{MrrAa3oJr. C6Hl2N2Si. (M.u. 140,27). 1-Tplrrr,rernrcvtrvr[rMr,r.tra3on. crb. EecqserHa-f, f r{rpo cKo[r4rrHas)Kr.rAKo ,
20

dii . o*ono0,96. n1]. O*ono1,48.

rourefiuepe. Xpanxr B Bo3AyxoHe[poHr,rqaeMoM C8H2 N,O-6nc(TprrMerr.rJrcn.nn"n)aqeraMrrA. INO Si2. (M.u. 203,43). EecqserHas xr.rAKo crb.

Eq

d1i. o*ooo0.83.
(M.rra TpunroQan. C11H12N2O2. . 204,23). KpucrannnqecrufinopolroK or 6eroro Ao )KenroBaro-6eroro uBerauru 6ecqserHble Kpr.rcTannbr. HeMiuropacrBopr,rM crrrrpre96 yo, npaKTutIecKLI B Mano pacrBopr4M Bo.qe, B orreHb pacrBopr,rMeQupe. n 30'(l o/opaunop). lall)' . Orono MktHyc 103. -Tp n c [3r5-an ( 1r1-4 n lr ern.neru.u)-4-rugporc lr6eHsr.n- 113. 5-rp rIa3I{H5 ] (M. 2r4,,6(llJr3Hr5H)-rpuon.C43HosOoN:. t"t.784,1). Kpucrannu.recrufi ilopoilroK6eroro uBera. Teunepamypa nnaBneHun. 218 ao 222'C. Or (M. T pucl2,4- glr( I o -4nu eruJrsrnJr)QeunrQoc$nr. C 42H 3P. vr.647,0). l I $O lloporuox 6eroro rlBera. Te"vnepamypa rua*neHun. 182ao 186"C. Or (CH2OH)3CNH2. (M.u. l2l,l 4). TpoueraTpuc(rngpoKcnMerrur)aunHoMeraH.
\IOJI.

Ee.irufiKprrcrturJrr4.re [opouroK uru 6ecuserHbre Kpracrannhr. crufi pacrBopt4M o cnrrpre. pacrBoprrM BoAe, ylaepeHHo B 8,96 Oqeur JrerKo Teunepamypa nna*reHun. 168ao 174'C. Or p Tpnc(rrgpoKclrMern.n)alrnHoMeraHaacrBop 24,22 r Pacmop rpuc(rugpoKcr4Merr{r)arranuoueraHa coAepxr{T gKBrrBaJreHT C4HltNO3 1000,0 s Nar. TpucunaHo3roKcrrnponaH.Cl2H17N3O3. (M.u. 251,29). 1,2,3-Tpuc(2rlvaHogroKcu)rporau. Brsxas x{u.{Ko KoplrqneBo-xeJlToro crb IIBera. Pacrnopurr,r MeraHoJre. B I4cronrsyror B KarrecrBe HerroAnnxnofi Sasrr s rasoeofixpoMarorpaQuu.

dii . o*ono 1,11.

Basrcocma. Ororo 172w[Iac. (C6Hs)3 TpuQenr.urMeranorr. COH. (M. u . 260,32).Tpn$eHnnrap6uHor. EecueerHrre Kpvcrannbr. pacrBopr,rMcnr{pre96 %. flparrzuecKr4 HepacrBopr.rM B BoAe, JrerKo B TpuQexnJrrerpa3oJrrrfl xJroprra. 1 15ClNa. (M. rra. 34,80). 2,3.5 -Tpu$eswt-2H3 C 9H TeTpa3onur xnopr{A. Colepxvr Fre MeHee 98,0Cl9Hl5ClN4. -xeJrroro r4Jrr4 -xeJrroro rlBera. IIop oruor cBerJr o cepoBaro B PacrnopuMB BoAe,arleroHer4 crrr4pre Yo,npaKTnqecKrr 96 HepacrBoprrM e$upe. Teunepamypa nna*neHun. Orcono240'C c pa3Jrox{eHpreM. Xpanar B 3arunueHHoM cBeraMecre. or o/o. pacrBop 0oS Pacrnop5 r/n s crrr4pre %o, TpuQenu.rrrerpa3oJrrrfl xJroprrAa 96 cno6oAsorvr anblerr4AoB. or Xpauxr B 3ailIunreHHoM cBeraMecre. or

EEE

TpnQropyKcycnanKr.rcrrora. F3CCOOH.(M.r. 114,03). Co4epxnr HeMeHee % C2HF3O2. 99 Xu4xocrr. Crueurusaercr arleroHoM, c cnuproM 96 % u e$uporr,r.

dii .o*ono1.53.
Tetwnepamypa KuneHutOxono72"C. Irlcnonrsyrorrnanrn$r,rKarl[rc, rpuroAnyro Anr ceKBeHTarIuu nporenHoB. Xpanrr B Bo3AyxoHenponnuaeMoM ronrefiuepe. (M.u. 210,04). TpnQropyrccyumrfiaurrrAprrA. C4F6O3. Eecueernas)Kr.r.uKo crb.

dii . o*ono1,5.
(M.u. 187,37). Tpux;roprpnQroprr C2CI3F3. alr.. 1,1,2-Tpuxnop1,2,2-rpu$'rop3rau.
Eecqneruas, Jreryqar xr4AKo crb. flparruvecKr.r HepacrBoprrMB BoAe,cMelrr.rBaercr c arleroHoM rae$uporr,r.

dii . O*ooo1,58. He Teunepamypuarc nepe?oHrcu. 47 rc 48 'C; AonxHoreperoHtrbc.r Or npedenu

MeHee %. 98 Tpnx.rropyKcycnan Krrcrrora. CC13COOH. (M. ru. I 63,39). EecqserHue Kpr,rcranJrbr rrJrr.r KprrcraJrJrr{qe cKar Macca. Oqenr JrefKo pacrrnbrBaercr Ha Bo3Ayxe, oqeHb refKo pacrBoprrMa B BoAe rr crr.rpre 96 %. Xpanm B Bo3AyxoHenpoHrruaeMoM ronrefinepe. Tpnx.nopyrccycHofi Kr.rcrrorbr parrn,op 4 %o 40,0 r rpr4xnopyrcycHofi KrrcJrorbrpacrBoprrcT B BoAe v AoBoArr o6reu pacrBopa TeM )Ke pacrBopr{reneMAo 1000,0 nrr. KonqeHTparlrrrcorpeAenruor rr.{TpoBaHrIeM ecrvt ueo6xogunao, 0,1 M pacrBopoM:rarpvfl rr{ApoKcrrAavr, AoBoArr Ao KoHueHTpa-

uuu(40+ 1)r/n. (M.u. 133,39). 101.1-TpuxJroperan. Merurxropo$opru. C2H3C13.

Heso cnraMeHrloruarcr xrr.[Kocrb. llparrzuecKu HepacrBoprrM BoAe,pacrBopnM B arleroHe,sSnpe r.rMeraHoJre. B

d]l .o*onoI,34. n | ] . O r o to 1 ,4 3 8 . Teunepamypa KuneHufl. Ororo 74'C. (M.r"r. 1,38). 13 Tpnx.uoperrrrreH. C2HC13. Eecqneruax )Kr{AKo crb. flparruvecKr4 HepacrBopLtM B Bo.ue, cMerrrr{BaercrclrrproM 96 % n eQupor,r. o dii . onono 1,46. llu . Oxolo 1,477. TpnrranoJraMr{H. I C6HI 5NO3.(M. tur. 49,I9). 2,2',2" -Hurpurorpn3raHorr.
xr4gKocrb, troA Aeficrsuel,{ Bo3Ayxa 14 EecueerHag, Bfl3nag,) oqeHb rllfpocKorrvl,'l.Has. cBera upuo6peraer Kopur{HeByro oKpacKy. 85 Clreur[saercfl c nogofi, arleroHoM,cnrrproM 96 yo, rurrrUeprrHou % H MeraHoJroM.
20

d i i . o r c o n1 . 1 3 . o
@

XpaHarB Bo3Ayxone[pouutuaeMoM KoHTefiHepe, B 3arrl[ueHnoM cBeraMecre. or TpurrnnaMr{H. C6HI5N.(M.r. 101,19). N,N-,{nernJreraHaMr4u. 5ecqnernas)Kr.rrKocrb. Ma,ro pacrBopl,IM BoAe B nprr reMneparypeHI/DKe oC,cMerrrr.rBaercr cilrrproM 18,7 co o/o e$upou. 96 u d,i . Ot<otro 0,727.

nii . Oxono 1,401.

TeanepamypaKuneHun Orolo 90'C. Tpnern.ueHAr{aMrrH. C6HI2N2. (M.r"r. 112,18). I,4-!naza6w1uwol2,2,2foxraw. Kpacrannbl, oqeHb rr,rrpocKonr{sHbr. Jlerro cy6nuir,rzpyercf [pr,r KoMuarnofi reune-

parype.
Ierxo pacrBoprerc{B BoAe, arleroHe graHoJre. u Teanepamypa KuneHutOrono 174'C. Te"+rnepamype ma*reHuz Oxoto 158"C. Xpanxr B Bo3AyxoHelpoHrruaeMoM rcourefiHepe. Tp o*reranro.rr. Tpuc (rugporccnnerun) aMunoMeraH. Clr. Tponeonnn OO. Opanxenrrfi IV. Kanuesas (utm HarprleBar) conr 4-l(4anununo$euun)aso] 6eH3orrcynbSorucnoru.1sH1 C 03 aKN3 S. (M. r. 39I,47). (M.,"r. 5,38). C I 8Hr4N3NaO3S. 37 OpaHxero-xer:rrtfi fiopolroK r4Jrrr 3oJrorr.rcro-xeJrrbre r.rrorbtrarbre Kpllcrallu. PacrBopr4M ropxuefiBoAe crr{pre 96 %. n r{ flepexo4oKpacKr.r pacrBopa KpacHofi xenroft n uurepnale pH 1,4-3,2. or r oh Tponeo.nnH OO pacrBop 0rl PacrropenuelrpoBoArrrrpr HarpeBaHr,ru lrvrrtfrlrefi Ha soAsrrofi6aHe. o/o Tponeo.nnH OO pacrBop 0r2 0,2 r rpoueoJlrlHa cueruuBaror 100 MJr OO co MeraHoJra, [epiloAr,rqecKr.r BcrprxrBarorB TeqeHr,rev n SunrrpyrcT. 1 Tpoueo.rrr.rH OOO-1. C 1 I lN2NaOa.(M.rvr3 I 8,21). . 6H llopouor reMHo-KpacHoro KpacHoBaro-KoprdqHeBoro r4nrr uBera. TCX-n.rracrrrnna cJroeM co clrJrrrrcareJrf floAloxrca r.r3 creKJra, MeraJIJIavilvr nJIacrHKa, rroKpblTat cnoeMcunuKarensc rracrr.rq noAxoAsulefi roluzsofi r4pa3MepoM (o6uvHo or 2 ao 10 MKMAnf, tracrr4rl rInacrI.IH MeJIKT4M pa3MepoM c ans BSTCX z or 5 ao 40 MKM AJrro6rrqqacrrlrl yKa3brBaror Hrrx TCX-rIJIacrvH). pa3Mep Ecnu neo6xo4uMo, nocJre Ha3BaHLrr cop6enra B I,IcnbITaHyrsx) oH r{clonb3yercfi. rAe Cop6enr Mo)KercoAepxarb cBr3yronleeopraHr{qecKoe BeilIecrBo. Xp ou amo zp afuuecrcaa p asd ennruul cno co6uo cma. Ha nJracrlrHKy HaHocqr an ueo6xo4ulrufi o6reM pacrBop a l,nfl.oflpeAene:a:arnpr4rolHocrr{ TCX-nnacruHor ( 10 iuxn 4rr o6rr.rrrofi unacu4HKr{u or 1 Ao 2 ruxr Anq lracrraHKr.r c MeJrKr4M pa3MepoM .racruq). XpouarorpaSupyror n cr4creMe pacrBopr4rerefi MeraHon - ronyon (20:80). Kor4a Sponr pacrBopr4renefinpoi4er ABe rperu flpnroAuofr, ecnu sa sefi BIIAHII qerblpe AILIHrI rInacrI,IHKvI,oua cqr4Taerc-rr rreTKopa3AeneHHbrx rrflTHa: ntrHo 6ponarpesoJroBoro 3eneHoroc RgHe 6onee 0,15;

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cKylo xon6y eMKocrbro 250 v'rr, npn6annrror 40 run 3 oh pacrBopa KaJrr.rr rr4ApoKcrlna crll4proBoro I,IHarpeBaror c o6parurrM xonoA[nbHr,rKoM no4xnofi na q. Oxna)KAaror, 6ane r reqeulie I pacrBop noMerrrarcT Aenr4Tenr,Hyro B BopoHKy c noMolllbro 100 MJIBoAbI,floAKucnsrcT xnoprcroBoAopoAnofi rxcnorofi passereHHofi 7,3 oh Ao pH 2-3 u Bcrprxr,rBaror c rpeMf, nopqrrrMr,r,no 10 ul ueTHJIOHXnopu!.a. O6te4uneHHble Merr,rJreHxnopr{Anbre Lr3BJrerreHlafl cytrar HaA Harpufl cynr$arou 6eseognrru, Sunrrpyror r.rBbrrrapuBaror BoArHofi 6ane Ha .locyxa. Cyxofi ocraroK pacrBoptror s 50 MJrMerr,rJreHxnop4a (ucurrryerurrfi p acrnop). OnpegeneHlle rpoBoAtr MeroAonrTCX, rrcronb3ys TCX- nnacrr4HKy co cnoeM cI{JrI4KafeJrs. cuJrarr{3r4poBaHHoro. Ha nlacu.rHKy HaHocrr B Tpr,r T0.IKI,I ueo6xo4nuufi o6reM I,IcnblTyeMoro pacrBopa (oxono 10 uxn Ars o6rrqnofi TCX-rIJIacrIdHKI4 or I lo 2 MKr AJrf,B3TCX-nJracrr,rHKrrc MeJrKlrM H pa3MepoM uacruq). XporraarorpaQrapyror cr,rcreMepacrBopurelefi yKcycHat B - BoAa- Ar4oKcaH Kucrrora ne4flHafl (10:25:65). Koraa Qponr pacrBoprrelefi npofi4er ABe rperl,I AnI,IHhr nJIacrLrHKvr) BhrHuMarorr{3 KaMepbrr{ cyruar rrps ee 'C B TetIeHI4e rr,rnn. reMrleparype 120 30 fhacrusry oxJrax(Aaror,orrphrcKr4oh pacrBopou Balor 3,5 n QocQopuouorH6AeHosofi KracJrorbr 2-npouaHoJre r.r 'C HarpeBarcTrlplr TeMneparype 150 Ao tro{Bnervrs.rrflTen. 3areu nnacrr4HKy o6pa6aruBalor rlapaMil aMMr.raKa rorytretufl. Sona 6enoro rlBera. flnaAo crHHKa cquraerc{ nptaroAHoit, ectu na sefi B[AHbr qerbrpe qerKo pa3AeneHHbIX ['THA.

TCX-n.nacrr{HKa co cfl oeM crrJrrrKareJrfl crrJraHr.r3rrpoBaHnoro F254 BhIAep)KI,IBa:rr rpe6onannfl. Anfl TCX-unacrr.rHKr4 cJroeMcprJrr.rKareJrfl. co cr4{olxHa n aHrr3lrpoBaHHoro cneAyrour.rMr{3MeHeHrreM. co Co4epxur Snyopecqeuuntfi I,IHArKarop c MaKcprMyMoM rronrorrleHr4r npr.r Anr4He BoJrHbr 254 lr'v'. Tyfiott. Ct0H160. (M.r"r. 152,23).4-MerpIn-1(1-rvrerunernn)duquxno[3.1.0]reKcaH3-on. Becqeernar r,urulorrrr.r 6ecqneruar xr.rAKo crb. flparruvecKll HepacrBopl{MB BoAe,pacrBopr{M B cnr.rpre 96 % r{ Apyrr4x opraHr.rtrecKux pacTBopnTeJrrx.

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(1). Ymepoga ArroKcrrA CO2.(M.pt. 44,01).flnyorncr yrJlepoAa. 99,995% (o6lo6) CO2. Co4epxzr HeMeHee Menee5 ppm. Y2nepoda MoHooKcud. Kucnapod Menee25 ppm. CSz.(M.rur. 76,13).Cepoyrnepo4. Vrnepo4a4ncy.rrrQna.
fl fltofiJaflc )Kr{AKo crb. x(eJrroBarorouBera BocnJIaMeH Fe cunern ag r.rJIIa n c gTaHoJIoM e$llporu. flpaxrn.recKrariepacrBopiaM BoAe,cMeruIlBaerct B d', . Oro:ra 1,26. TennepamypaKuneHun Or 46 lo 47 oC. Yruepoga MoHoKcrIA. CO. (M.r"r.28.01). 99,97 % (o6lo5) CO. Co4epxnr He MeHee Vrnepo4a rerpaxrropna. CClo. (M.rur.153,8). TerpaxnopMeraH.Vrnepo4 tlerblpexxropucrrrfi. Ilpospauuax, 6ecqnerHat xLIAKocrb. flpaxrvvecKr4 HepacrBopuMB BoAe,cN{errllBaercsco cullproM 96 %. Or TeanepamypaKuneHlffi. 76 to 77 'C. Yro,rr aKTuBrrponasHsrfi 9epnufi ilopouroK 6es sanaxa. flparrnuecKr4 HepacrBopnM e o6siqHsrx pacrBopvreJltx. pacri{Tenbnoro npoltcxo)Kr,e:avfl cileqilanbu o o 6p aVrolr x(r4Bornoro prnrvl , fioBepxHocrsofi aKTHB6onrruofi 6orausrrfi n olna!,aroqafi B cBr3rl c 3Tr.rM a4cop6rpoBarb fa3br, ToKcrIHhI,T-s)KerbleMeraJIJrbI Hocrblo, cnoco6nsui Ir Ap. or Xpanxr B rrJroruo 3aKpbrrbrxxoHrefinepax, orAeJrbHo BeilIecrB, BblAentrcrullx B a'ruoc$epy ra3brHnr{ napbr. VrccycHrrfiaHru4prrA. (CH3COO)2O.(M.u. 102,09). llpn pacrBopeHnr pealr-TrrBa 3arraxovr. EecqeerHas,rpo3pairHaflxr4AKocrbc pe3Kr{M a I4AerMeAneHHo, Kucrora, [pur{eM peaxqut cHaqaJla B BoAeo6pasyercs yKcycHa"rr 3areMycKopflercr u rpoxoAul6ypno (no:vroxnrt nu6pocu). O6paurarrcfl c ocropolcHocrblo. Or TennepamypaKltneHutr. 136 ao 142"C. Vrccycnoro aHrHApnAa pacrBop 25 o/o(o5lo6) n dessoAHoMnnpuAuHe pacrBopsrcr n 6essoAHoM TeM}Ke nl{prrArlHe, yKcycHoro aHrr4npi{.{a 25.0 rnr"u AoBoAf,T pacrBoprrreneN{ o6r,eua i 00,0 ur. Ao Bo3Ayxa. XpaHxr, 3an\uu\an or cBera 14 pacrBop t2 o/o(o6lo6) s 6ernoAHoMrluplrAnHe Vxcyenoro aurrrAprrga c 6eseo.uHororrnpu4nna. 12 lur yKcycHoro aururyilra cMeurl4Baror 88 Nan Xpanxr s 6aHrax oparrKeBoro creKJIac [pl{reprrtvrn npo6KaMI4.

5 a i i . O r 1 , 5 9a o 1 , 5 9 8 .

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Xpaurr B 3arrir{[IeHHoM or-cBera Mecre. Yrccycrax Krrcirora rreAnnan.CH3COOH. (M.u. 60,05). Cotepxilr He MeHee98,0 (u/nt) C2H4O2.

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300,00r yxcycuofiKrrcnorbr;repsofiocropo)KHo cMerrrrBaroreoAofiu par6anrxror c notofi Ao o6reua 1000,0vr;r. pacrBop 2 M YrccycHofi KrrcJro'rbr 116vn yrcycHoii Kr{cxorbr AoBoArrsolofi Ao o6reua I ri. pacrBop 1 M YrccycHofi KrrcJrorbr 58 lrn yr<cycHofi Kr4cJrorbr AoBoArrsoAofigo o6reua I n. YHunepca.n sHrrfi rrHAr{Karop Cocmae.0,006 r 6povrrpe3oJroBofo nyprypoBoro, 0,0 i r 6porr,rrpesonoBoro 3 e n e H o r o , 0 , A 2 M e r n J r o B o ro p a H ) K e B o r 0 , 0 4 r r p o r r e o n u n a 0 , 0 , 0 4 r r o o 0
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cvHero. 0,1 r 6poururraoJloBoro cI,IHero, 0,05 r rr.rMonoBoro SeHonSraJrer,rHa, PacrnoprEuB cnl{pre 96 %. a\vrr BoAocKoro onp eAeJIeHI{tKoHIIeHTp flpe4naruaqeH Anr Konopr{Merpuqe poAHbrxr{oHoB. pH 1,0-10,0. oKpacKyB I{HrepBarle lln.uHxarop LI3MeHter OrPacxa pH Oxpacra PH 3eneHoBaro-xcerTa.f, 6,0 xpacno-SnoJleroBat 1,0 XEJITO-3CJIEHAg 7,0 po3oBo-opaHx(eBtul 2,0 3eJIeHa.'I 8,0 opaHxeBafl 3,0 cI,IHe-3ereHas 9,0 xeJrro-opaHxeBat 4,0 10,0 cepoBaro-cvtHfls, XEJITA{ 5,0 YHnnepcaJrbHoro lIHArIKaropa pacrBop Co4epxuuoe npo6uprcu(e4unuqHar ynaKonra) pacrnoptlor s 100 Mn crl{pra 80 % 6ane. Ha npr4HarpeBanvrrzr roptqefi (ao 50'C) soA-f,uofi Vpn4nH. C sH n NzOo. (M. t. 244,21). B-D-Ptr6oQypaHo3r{rlypaqun. KpucranrnqecxrEfi nopolxoK 6eloro I{JIII roilTrr 6eloro IIBera' PacrnopuruB BoAe. 'C. TeunepamypannaBreHua.Oxono 165 (M.*. 178,22). @enaHrpeu. C1aH16. Kpzcrannu 6eroro qBera. n B IpaxruuecKu HepacrBopl4M BoAe,nerKo pacTBopI{M e$upe, yMepeHHopacTBoprrM B cnr{pre 96 %. TeunepamypamalneHua. Ot<otto100 "C. OenaHrporIIIHa rllApoxJlopng. C12H9CIN2' HzO. (M.r"r.234,7). 1,1O-OeuaHrpo]J.Pffi . MOHOTI IMIJArrr ApOXnOpI4A, IroqrI,I 6eloro IIBera. floporuor 6eroro rrJII4 B B Jlerxo pacrBopl4M BoAe,pacrBopl4M cnupre 96 %. TennepamypamaaneHua. Oxono 215 "C c pa3noxeHl{eM. 278,28).o-OeHaurponl{Ha 1'l0-(Denanrporluna cynsQar. Cl2H8N2'H2 SO4.(M.rur. cynrQar. floporuox 6eroro lrBera c xenroBarblM orreHKoM. B B Pacrnopuna BoAe,npaKTilqecxll HepacrBoplrM cnl{pre 96 %. ucnonb3yerct KoMl{HAuKaropa B KaqecrseoKr.IcJlr.rreilbHo-BoccraHoBr{TenbHoro (II)-Fe (Cl2H8N2): SO+ - <@epcynrsara c )KerIe3oM rrneKco-QeHanrponlzHa po14H>. o-OeHanrpoJlrHa cylrQara pacrBop 0,7 r xenesa(Il) cylr$ara pacrBopqlor B 100 ua Bo,{bI, npu6annnror 2,2 r o-SenaurpoJlnHacynr$ara u nepeMerurrBalor pacrBopeHnt' Ao (Derur.urnApa3rrHarrlgpoxrlopll4. C6H5NHNH2 ' HCl. (M.r"r. 144,61). @euunruc Apa3I,IH on-tHoxllcmrfi . Kpucran.nuqecxufi noporroK 6enoro [rr4 noqrll 6eroro uBera, noA AeficrBl4eMBo3,uyxa ilpuo6peraer KoprqHeBylo oKpacKy. crll{pre 96 %. Pacrnopuu B BoAe14 Teunepamypa ma*neHun Oxotto 245 "C c pa3nox(eHrreM. or Xpanrr B 3axlr{nreHHoM cBera Mecre.

OeHn.rrruApa3rrHa pacrBop rrrApoxJropuAa 0,9 r Qeuvrnru4pasurna rrrApoxJropvlapacrBop{rcr n 50 MJrBoALr, o6ecune.r[BaroryrneM aKTrrBr4poBaHHbrM z $ranrrpyror. K Sra.urrparynpu6ann-srcr r,rr 30 xnopr{croro4opo4nofi Kr.rcJrorhr % rr AoBoArr o6rerrapacrBopa eoAofi 25 ao 250 u;r. (Denu.nrnApasrrHa pacrBop n cepnofi KrrcJrore 65 rrarSeHIamra4pa3r4Ha rr4Apoxnopv1&, npe4eaprreJrbHo rrepeKpr{craJrJrr.r3oBanoh, o6lo6),pacrBoprrorB cMecr{ Horo r{3crlrlpra (85 pacrBopzrenefi eoAa- cepHat (80:170)u AoBoArrrofi xe cMecbro KlIcJIora KoHrleHrprrpoBaHHax pacrropurenefi ao o6reua 100un. foron-sr Heno cpeAcrBeHHo rrepeA c[oJrb3oB u anLrev'. (Denu,rrnApa3r{Ha pacrBop n cepnofi KrrcJrore oh 0rl pacrBopsrcr 100MnoxJraxqessofi 0,1r $enxnrr4Apa3r4Ha rr4rpoxnopr4Aa n cMecr,r rr3 paBHbrx o6reNroscepnofi Kr.rcJrorbr KoHrleHTpr{ponauuofi r,rBoAbr. PacraopnprrMeurrcT cBex(elpr4foroBJreHHbrM. (M.pt. I51,16). (Rs)-2-Alauno-2-$euNnyxcycnafl. u-(Denulrrruul{H.C8HeNO2.
K'ICJIOTA.

Eenrrfi, rrJII,I norlTr46enufi Kprrcrturnu.recrufi [opoilroK, raru 6ecqserHbreKpr{crarrJrbr. Pacrnopnu B BoAer4oraHoJre, pacrBopr4M eSupe. MaJro n -Oenn"ueHAnaMr{Ha n C6H4(NH2)2 . ZHCL (M. r. 18 1,06). Ar.rrr.rgpoxrroprrA. 1,4-[uav.uHo 6eHsora Ar4rr4ApoxnoprA. Kpucra-nnv.Iecxufi nopoIrroK, lrJrra Kpr,rcralrJrbr 6eroro rlBera, rrJrr,r cJrerKaoKparxeHusre. Ha Bo3AyxeKpacHeer" Ierro pacrBoplrMB BoAe,ManopacrBopr4M crrripre 96 % rae$upe. B OenrnrsorrroqraHar. C7H5NS.(M.rnr. 135,18). EecuserHaq )Kr{AKocrb. llparrnqecKr,r HepacrBopr.rMB BoAe, pacrBoprrM B

crrlfpre %. 96 dr, . Oxono 1,13. nil . Orono1,65. Teunepamypa KuneHun Oxono 221'C.
Teunepamypa nna+neHun. Oxolo -2I "C. @eHorccn6en3aMrrHa rnApoxrroprg. C 13H23C12NO. (M.r"r.3 40,27).N-(2-Xlop-rre^run-2 -Qenorcusrun)6eurun arHn)-N-(1 aMulaa rr,rApoxJropr4A. o Cl8H23CI2NO, nepecqer e cyxoe Ber r l eC o g e p xn r o r 9 7 ,0 A o 1 0 3 ,0 n Ha
CTBO.

Kpracrarnu.recrufinopoilroK6enoro rrJrpr uoqrra6eloro uBera. pacrBoprrM BoAe, YuepenHo B nerKopacrBopr4Mcnr{pre96 %. B Teunepamypa nna*reHun. Ot<ono "C. 138 (DeHorccuyKcycHaq (M.r"r.152,14).2-OenorcvpraKrrcJrora. C6H4OHOCOCH3.
HOB'UI KI4CJIOTA.

Kpncrarnbr rrorrrr.r 6eloro rlBera. pacrBopr,rMacnr,rpre yo,eQr,rpe Kr4cJrore YuepeHnopacrBopr{Ma BoAe, B JrerKo B 96 r4 yrcyurofi re4rHoil. Teunepamypa Ma+neHu* Oxoto 98 oC.

c8H10o2. (M.r*. I 38,I 6). 2-Oesoxcr.reraHorr. @euoxcueraHoJr. llpoapauuaa, 6ecqn ernafl , MacntHr{craq xuAKo crb. Mano pacrBopltM B BoAe,nerKo pacrBopl'IMB crll4pre 96 % u eQupe'

1,11. dli . o*ono n'i,,O, I,537. .

He sameepdenaHufl. snxe 12'C. Teunepamypa (M.rr. 94,11). @eHon. C6H5OH
uJrI{Kpr{po3oBble,IIJII4cJIerKaxenroBarble KpI4craJIJrbI' EecqserHrre, vrvl cJrerKa crtuurnrrecKar Macca, roHloilIaroluat Bnafy. oA,rnuqepl4Heu MerI{JreHPacrnopvu B BoAe,oqeHbJrerKopacrBoptrMB clupre 96 pa3ApalreHr{e. xnoprrAe. flpu uona4annu Ha KoxcyBbI3bIBaer OeHo.uxuarnfi 100 qacrefi $enona pacrnaBnrror Ha eopHofi 6ane, npu6anrt-aror10 'Iacrefi noAu, xopoIIIo nepeMelxuBaroT. Oeno.ironrrfi rcpacnrrfi . CgH I 4O5S. (M. v. 354,4). OeHoircylrSo$ra.rrenu. IIBera. MerxoAncnepcuufi nopomoK reMHo-KpacHoro B cnllpre 96 % u alleroHe, JIerKopacrBoB Vuepeuno pacrBopktM BoAe,pacrBopr4M rlpaKpr{M B pacrBopax eAKktxuleloqefi n yrneKl4cnrrx conefi ilIenoqHblx MeraJrJroB, u B HepacrBopI.IM xnopoSopnae e$upe. rr4irecKr{ pacrBopa or xelrofi r rpacHofi B llHrepBanepH 6,8-8,4. flepexo4 oKpacKI4 (Deno,rosoro KpacHoro pacrBop 0rl o/o 0,1 r QeHo:ronoroKpacHolo pacTBopfltorB cMecl{ 2,82 mt 0,l M pacTBopaHa'rpLrfl,fLIApoKcIr u 20 vrn 96 Yo ctupr4 AoBoAtT o6teu pacTBopa soAofi p,a ao 100un. K IrlcnatmanueHa qyncmsumerbHocmb. 100 un BoAbI,ceo6oAHoftor yruePola npu6auxrcr 0,1 vm pacrBopa $enononoro KpacHoro; rrotBJIflercs' Ar4oKc[rAa, Koropoe AonxHo nepefiTll B KpacHo-St'IoneroBoenpl4 )r(enroe oKparrrr4BaHr.re, rI'IApoKcI{Aa. npn6anneHllldHe 6olee 0,1 nan0,02 M pacTBopalaaTpIlfl llepexog oKpacKr{ or xenrofi ao KpacHoBaro-Suoneronofi B rrHTepBane pH 6,8-8,4. oh OeHo.rosoro KpacHoro pacrBop 0104 0,1 r $eHonoBoro KpacHoropacrBoprrcr y 14,2 Mn pacrBopa Harpl4t rI4ApoKcI4Aa 0,02 M u AoBoAqr o6reu pacrBopa cBexerporunq.IeHHofi rr oxnaxAeunofi soAof ao 250 rr,rl. (Denoronoro KpacHoro pacrBop 1165oh Pacrnop L 33 rrar$enononoro KpacHoropacrBoptror B 1,5 ul pacrBopa learpvs'ruo6reM pacrBopa eoAofi Ao 100 rul. u 8,5 o/o qor;ogrsr ApoKcvAapa3BeAeHHoro Pacrnop ll. 25 Mr aMMoHuxcynr$ara pacrBopstor B 235 wt BoAbI,npu6au*or pa3BeAeHHoro 8,5o u 135 MJIyKcycHofirnc105 runpacrBopa Hurpvrfl,rr{ApoKcr{Aa oh. 12 Jrorbrpa3BeAeHHoia AoBoAtr pH pacrnopa Pacrnop II c1aerrnsarorc 25 ulpacrBopa I. Ecnu neo6xoAntuto, pa:6auegHopo 8,5 oh. go 4,7 c noMoIIIbIopacTBopaHaTpvlnruApoKcl{Aa o/o OeHonosoro KpacHoro pacrBop 3r3 Pacrnop I. 33 rvrrSeuolonoro Kpacnoro pacrBoptlor B 1,5 un pacrBopa Harpvrlrvro/ou Aosoryr o6rerrapacTBopasoAofi .qo 50 rran. ApoKcI{AaptBBeAeHHoro8,5

Pacrnop II. 50 Mr aMMoHwxcytrc$ara pacrBopstor s 235 MJr BoAbr, npn6annxror 105 rran pacrBopa Harpr.rrrnApoKcr.rla pa3BeAeHsoro g,5 o/ou 135 MrryKcycHofi rzcJrorbrpa3BeAeHH 12 yo. oit,

Pacrrop II cMeruusaror 25 vtpacrBopa I. Ecnn Heo6xo4zuo, c AoBorrr pH pacrnopa 4,7 c floMorrlbro lo pacrBopaHarprrflrr4rpoKct4Aa g,s pasdaareuHoro oi. (Deno.nosoro oh KpacHoroc[rrpronrrfi pacrnop 0rl 0,1r $eHoloBoro KpacHoro pacrBoptrcrs 50 MJr g6YorryuHarpeBaHr4rd cnrdpra Haropxueit no4xuofi 6aue u fiocJre oxna)KAeHrrr AoBoAxr o6reu purr"opu soAofi .qo100rran. @eHo.ironrrfi mpacHrrfinogopacrBopuMbrfr. cy'HtTNoss. (M.r"r. 371,41). Anauo_ :uuirle'as colr QeHolcynr$o$raJrerrHa. llopouror KpacHo-KopurrHeBoro qepHororlBera. uJrr4 Pacreopzru BoAe. B flepexogoKpacKu pacrBopa xenrofi r rpacuofi B r4HrepBane 6,g-g,4. or pH (DeHoJrosoro KpacHoroBoAopacrBoprrMoro yo pacrnop. pacrBop. 0,04 Oeno"rr0raJrerrH. C20H14O4. (M.r"r. 319,31).3,3_Euc(4_ru4porcra6eHrao)_3H_uso_ 6eu:o$ypau-1-on. flopouor or 6e.rroro x{enroBaro-6enoro Ao rlBera. flparruvecKpr HepacrBoplrMBoAe, B pacrBoprrM clvpre 96 %. B (Deno.nQrarrerrHa yo pacrBop 0rl 0,1 r Senon$ranezua pacrBoptrorn 80 Mn cnr4pra %r.rAoBoMr o6rena 96 pacrBopa eoAofiao 100rran. tr[cnarmauue qyncmsumerbHocmb.100MJr Ha K BoAbr, cso6orHofior yrnepoAa ALroKcvra' npz6arrarcr 0,1 ltl pacrBopa$enon$raJrerHa;npu npulaBJreHrrr4 ne 6oree 0,2 tvm0,02MpacrBopaHarprrflrlrApoKcl{Aa oKpacKa pacrBopa AonxHa}r3MeHurbcq or 6ecqneruofi posonofi. 4o llepexogoKpacKr.r 6ecqneruofi -rrpKo-po3onofirzHrepBane g,2-10,0. or Ao n pH (Deno.nQraJrerr'a pacrBop I oh.pacrnopl0 r/,r n cnzprc 96 yo. (DeHxoH. c1oHr60.(M.rur. 152,23).1,3,3-Tpzn erun6u4uxno[2.2.1]renraH-2-on. Mac.n*rzcrar xkrAKo crb. cMeilrzsaerc.rr crr4proM % z e$uporr.r, co 96 rpaKrr4qecKn HepacrBoplrMBoAe. B Teunepamypa KuneHu.fl. Oxono 193.C. hn . Oxoto I,46. XporraarorpaQuuecxax qrlcrora $euxona,vcrronmyeMoro rasosofi B xpoMarorp a$uu, AonxHa6urr HeMeHee 98,0o . OeppollH | 0,7 r xenesa(Il) cynr$ar a u 1,76 r Senanrpo rrr4Ha rr4Apoxno purapacrBoptror n 70 Mn BoAbILr AoBoAtr o6teu pacrBopa reM )Ke pacrBopr4TeJreM ao 100 rr,rn. I'Icnutmauue Hy7cmsumert,Hocmb.50 MJr Ha K cepHofirucnorur pasne4enuofi o / o p n 6 a n .rrxro r,1 5 9,8 u 0 u r p acr Bopaocvr zx( vlll) oxcr a u 0,1 un ga Qep_ pol{Ha.rlocre npz6annenux0,1 u:r 0,1 M pacrnopaaMMoHra, rlepu Hvrpara fl oKpacKa pacrBopaAonlr(Ha v3MeHrrrbcr rpacnofi 40 rony60fi. or @eppoqn0eH. c26Hl6FN6. (M.rur. 468,3). fiul,uauo6uc(1,10-SeHanrporzn)xereso(Il).

rlBera. KpucrarnuqecxufinopolroK Quonerono-6ponsoaoro Ir B flparrnuecKlr HepacrBoplrM BoAe crrlpre 96 %. or Xpanxr B cyxoM3aIrIuuIeHHoM cBeraMecre. EeHsoI-1,3,5-rpuoil,IvIrvIC6H3(OH\'2H2O. (M.r"r.162,14). @.nopor.nnqrH.
APar. IIBera. )KeJIToBaroro Kpucrannu 6enoro I,IJII4 B Maro pacrBopklMB BoAe,pacrBopl,IM cnrrpre 96 %. euut') . Teunepamypa nna 6neHua. Oxotro 223' C (rvleroAMf HoBeHHoronJIaBJI (Dnopornroql{Ha pacrnop 1 %o pacrBopa 100 r/n $nopornroqlrHa B crrnpre 96 % upu6annxror9 runxrroprK 1 rr,rn croBoAopolHofi KIrcJIorbI25 %. Xparur B 3aIIIuueHHoMor cBera Mecre. @roporurcql{Ha pacrBop pacrBopruor B cMecr ug 8 ul crll4pra 96 % u 8 un xnoprrcro0,1 r $nopornrcqr,rHa 3TrIMpacrBopoMcocHoBat nyquHKa rucloru 25 %.llpu claavvrBanvlr BoAopoAHofi B AoJrr(HaoKparrrr4Barbcr xpacuufi rleer. loroBtr HenocpeAcrBenHorlepeA I4cnoJIb3oBaH[eM. (Dnopor.nroqlrHapacrBop n eQnpe 0rl oh pacrBoptrcr e eSupe u par6aenruor eSr,rpoM 100 rvu. Ao 0,1 r $.rroporJltoqllHa forossr HenocpeAcrBeHHonep eA I4crIoJIb3oBaHI4eM. (Dnoporrrounua pacrBop n cepnofi KrlcJrore Ha pacrBoprrcr rrpl,tHarpeBaHI,Iu BoA{Hofi6ane B cMecu us75 r 1,5 r $noporJrroqr,rHa BoAbrra50 r cepnofi KLIcnorbIKoHueHrpl{ponaunofi. (D.nyopaHren.C16Ht0. (M.M. 202,24). I,2-(1,8-Ha$runen)6eHron. 1,2-EensaqenaQreH. Kpncrannbl or )KeJIToro xeJrroBaro-KopuqHeBoroIIBera. Ao B HepacrBopr4M BoAe,oqeHbMaJIopacrBoprlM n eQupe, pacrBopllM B flpanrrauecKrr xnopo$opue u 6engone. TeunepamypaKuneHut Orolo 384'C. nnarreHun.Or 105 ao 110'C. Teunepamypa (DnyopecqenH.C26H12O5. (M.rra 332,3). 3' ,6'-fiuru.qpoKcplcnl4po[uso6ensoQypan. -3-on. I (3H),9'-[9H]rcanreHl IIBera. lloporuor opaHlreBo-KpacHoro flparruvecKr{ HepacrBopr{MB BoAeraeQlrpe, pacrBopl4MB rerIJIoMcnupre 96 You paB cTBOp ax f I,IApOKoI4AO qenOtIHbIX MeTZLJTJIOB.

B pacrnope $nyopecqelrH o6uapyxuBaer 3eneHyroSnyopeclleHurro. TeunepamypannnzreHun. Oxono 3 I 5'C. OnySeHaMHHoBan Krlcrrora. C14H10F3NO2.(M.t. 281,23). 2-ll3-(Tpu$ropnrerun)QeHnr]-auuHo] 6ensofinax KI,IcJrora. 6leAno-xeJrroro IIBera. Kpucrannnqecrcui rroporroK r,urlr r4rorbrrarble KpI4craJIJrbI B flpaxruuecKrl HepacrBopl,IMa BoAe,JrerKopacrBopl'IMaB cnl4pre 96 %. 'C. TeunepamypennaareHua.Or 132 to 135 (DopuarHH TexHrlqecnnfi. Pacrnop QopualsAerr{Aa MyrI'I rpl4 xpaHeHIlI,I EecqserHafl, [po3paqHar ]KprAKocrb, AorycKaercx o6pasonaHl'Ie unrz 6eroro oca.IIKa.

(Dopua.rrrAerrrAa pacrBop 35 oh. Oopuannn flpo:pa'*rax, 6ecqnerHatxl4AKocrb,cMerrruBaercf,no4ofi r{ crrrrproM %. c 96

flpn xpaueHr4rr Bo3Mox(Ho [o-f,Br eHVfl Myrkr.

(Doplra.nrAerr{AapacrBop r cepHofi KrrcJrore 2 u:r paurnopa $oprvranbAerllAa % cMerrrr{Ba}or 100 ul cepuofi KrrcJrorbr 35 co KoHueHTpr{poBausofr. (DopnaarvrH4. HCONHz. (M.u 45,04). Anau4 MypaBbr.rHofi rrcnorn. flposp aunax, 6ecqnernas, MacJrrHt4 crat, rlrrpo cKonLIqHarxI4AKocrb. Cveilrusaercr c no4ofi v cnrrproM 96 %. fz4ponusyercr B BoAe. Te-ttnepamypa KuneHu,s. oxoro 103 "C. onpe4eneHze npoBoArr npr{ AaBneuuu 2 xIIa. XpaHxr B Bo3AyxoHelpoHr{rlaeMoM xourefiuepe. (Dopnalru4 o6pa6oraHHufi 1.0 r rucnoru cynrQaNrnHoeofi Aucneprupyror s 20,0 nrn $opnrawura coAepxao/o (o6lo6) no4u. uero 5 @ocQonurnAbr Onpe4eleHHoe KoJII4qecrBo Mo3ra tlenoBeirecKoro r4nrr6rtvrero, xoporilo orAe.leHHofo or KpoBeHocHbIX COCyIOB, rrpoMbrBaror pa3xr{nraror B noAxoArrleM r4 rcrpoficrne. Or 1000 ao 1300 r pa3)KVlKeHHoro BerlecrBa B3Berrrr4Baror, r{3Mepslor o6teu (V nrn), 3areMSKcrparl4pyrorrpeMr [oprluqMrr, rro 4 V vrn arleroHa, rr Qr'rnrrpyror npl{ noHHxeHHoM .qaBneHr4r4; nonyqeHurrfi ocraroK cyuar npfi reMneparype 37 oC s reqesue 18 .r; :areM ocraroK 3Kcrparr4pyrorcMecblo pacrBopr4rerefrnerporefisufi adrHp(3) - nerponefiuufi a$zp (2) (2:3), AByMt iropurrrMH no 2 lrl, $v.nrrpyr raxAufi sKcrpaKr qepe3 Qu:lrrpoaanruyro 6yMary, [peABapI4TeJIbHo yBnaxHeHuyro rofi xte cMecbro pacrBopurerrefi. O6seBbrilapr4BalorAocyxa npH TeMfleparype 45 oc npu rlrHeHHbre n3BJreqeHkrr ne AaBneHvrr 6onee 670 I7a. Ocraror pacrBoprrcr s 0,2 V rran e$upa 14BbrAep)r(rrBaror rpr4 reMrreparype 4 oc lo o6pasonaHr{rocaAKa.IlpospauHyro HaAocaIorrHylo xuAKocrb qeurpnQyrl4pyror, Bblnapr,rBarcT [oHr4xeHHoMAaBneHprH rrpz pa3x(rr)KeHHoro Ao o6reua 100 nanHa KLInorpaMM BerrlecrBa B3Berrrusalor. rr Brroc Aepxr{Baror npu reMneparype 4 oSpa:onaHvfl ocal.rKa (or 12 5o 24 u) u Ao qenrpzQyrl4pyror. K lpospauuofi Ha4ocaAoqsofi )KuAKocrtr rrpu6antxror aqeroH B KoruqecrBe, B rltrb pa3 rlpeBbrlrrarcilIeM o6rerr,r,ueHrpr,r$yrr4pyror z or6paee cbrBarorHaAocaAoqHyro xr{IKocrb. Oca4or cyrxar. Xpauxr B SKcr.rKarope BaKyyMoM, 3arqrzrrleHHoM cBera Mecre. rroA B or @oc0opa(v) orcua. Pzos. (M.r. 141,94).@ocsopa nrrrroKrrcb.lu$oc$opa reHroKcr4A. Antop$nufi lopourox 6enoro uBera, pacnnbrBarouruficg Bo3Ayxe.C solofi o6paHa 3yeTrlrApaTbrc BbrAeneHHeM TenJTa. Xpaurr B Bo3AyxoHerrpoHr{rlaeMoM xourefi uepe. @ocQopHafl KHcJIora KoHIIeHTprrpoBaHHaq. K[crora oproQocQopHar KoHrIeHrplrpoBaHHar. H3PO+.(M.rtl. 98,00). Co4epxur rre MeHee % H3PO4. 85 Eecqneruar, [po3paqHat )KI,IAKocrb 6ecqnelurre Kpr.rcrannbr, vrrpr pacnJrbrBaroilIu ect Ha BO3Ayxe.

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lloporuor Kopr4rrHeBaro-qepHoro rlBera. pacrBopr4Ma arleroHeu 96 o/ocnupte, yrvreMano pacrBopr4Ma BoAe,oqeHbMaJro B B peHHo pacTBopr.rMa pa3BeAeHHbrx pacTBopax Harpvrfl fr{ApoKcr4Aa, pacTBopr{Ma B s 5 0 Y o c r u p r e u 5 0 % oa { e r o H e . llpv pH 6onrme 12,0 zueer rony6yro oKpacKy, ero KoMrroHeHrbr rroHoMKiulbrlut a c - KpaCHOBaTO-Cr4peHeByrO. B TeX)KeyCnOBr{.flX llepexo4 oKpacKr4 rprl rpqMoM rr{rpoBaHr{r.r KpacuoBaro-crapeHeBofirony6ofi. or r Xa.nrrcoHxapbouonofi rcnc.rrorrrr.rHA[KaropHafl cMecb CNreruuearor oAHyr{acrb xrurbKoHKap6oHoeofi KucJlorbrc99 \acrsMuHarprrfl xJropvAa. Irlcnutmanue qyqcmqumerbHocmb.50 rrHAlrKaropnoil nrr Ha cuecv xanbKoHKap6ononofi xucrorbr pacrBoprror B cMecr 2 wt paclopa Harprrr rr4ApoKcuga o/o 100 wt 20 u BoAbr;rrorBnrercx rony6oe oKparxrrBaHr4e, Koropoe lepexoAr{T B $uoneronoe npn o/opacrsopaMarHus cynr$ara n 0,1 rr,tr0,I5 YopacrBopa 1,5 rlt npu6aueuuu I vI I KaJrbrlr4r xnoprrAa;npx upn6aBJreHnu 0,15 rvrn 0,01 M pacrBopalaarpvrfl. olerara BHoBb rrorBJrrercr rony6o e oKparrrr4BaHrre. Xa.usrcoHrcap6ononofircnc.noru - p acrBop HHArrKarop a oh cnupra finrr arreroHa. pacrBoprror s 100 rr,rn 0,025 | rrHAr4Karopa 50 - 2 vec. Cpox roAHocrr4pacrBopa r4HArrKaropa Xraua,rrgnnonrrfi xpaurrrfi. C2IH23IN2.(M.u. 430,3).2-12-14-(W{MerrrJraMuHo)a fio1.u4. $euun] erenun] - 1-eruJrxr4HoJruH flopourox reMHofo, clrHeBaro-irepHoro uBera. pacrBopLtM BoAe,nerKo pacrBopr4M crrr{pre 96 %. V*repeuHo B B XnHa.nn4uHoBoroKpacHoro pacrBop KpacHoropacrBoprrcTB MeraHoner{ AoBoAsro6reu pacrBopa 0,1 r xnuanbAr4HoBofo TeM)KepacrBopr,rreneM 100 rvrn. Ao pH flepexo4 oKpacKrr 6ecqeerHoftAo r<pacuoft r.rHrepBane I,4-3,2. or B XuHrngpoH. C 12H 1sOq.(M. rn{. I 8,20). 3xezN{oreKynspHoe 1,4-6en:o2 coeAr.rHeHr4e xr4 HoHaI4 f rl.qpoxxHoHa. Elecrsque Kpucranlrbr vtrvt Kprrcrannr4.recxnfifloporroK TeMHo-3eJreHoro rlBera. yMepeHHo pacrBopr4M ropruefi BoAe, pacrBoprrMB crrr4pre Maro pacrBopuMB BoAe, n oh,pacrBope aMMrraKa 96 KourleHrpr{poBaHHoro eSupe. r.r Teunepamypama+reHun. Orcoto 170 "C. Xnnn4uH.CzoHz+ NzOz. (M.pr. 324,41). (S)-(6-MeroKcr{xrrHo:l-4-utr)l(2R,4s,5R)-2 5-nununxuHyKnr{Ar{H -unfweraHon. Kpucrannuqecrufi [oporxoK 6eroro rlBera.

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pacrBopacrBopl4M cnl,Ipre 96 Yo,MaJIo B pacrBopr{MB BoAe,yMepeHHo O.{eun MaJro pHM.^B eQupe r4MeraHoJre. o/opacrcopn eranone). lall . Ororo +260" (l TeanepamypanJtarreHua.Oxotto I7 2'C. XpaHxr B 3axI[qeHHoM or cBera Mecre. Xnunn. Czo[z+ NzOz. (M.r"r. 324,41). (R)-(6-MeroKcIrxI{Hol-4-ul)l(2s,4s,5R)-5y BHHrrJrxnHxnugwu-2-ur] nreraHor. MuxporpNcrarrurrecrufi nopourox 6enoro uBera. O.reHn MaJropacrBopr{M B BoAe, MaJropacrBopl4M B Kr{rrtIrlefi eoAe, oqeHb pacrBopllM B e$Lrpe. nefKo pacrBopr4MB 3TaHoJIe, -67 " (I o/opacrcop n erauore). lall . Ororo TeunepamypannartreHun.Oxolo 175 "C. Xpaurr B 3axIHrrIeHHoM cBera Mecre. or (M.u. 172,57). 2-Xrop-4-Hr{rpoaHr{ruH. C6H5CIN2O2. B Kpncralluqecxnfi fioporroK xeJrrofo rlBera. Jlerxo pacrBopl4M MeraHoJIe. Te.ntnepamypa ntraBneHua. Oxolo 107'C. Xpanxr B 3arrl[qeHuoM or cBera Mecre. X"ropa.nruApar.CCl3CH(OH)2. (M.u 165,39). uopotuot<.filEecqserHrre, lpo3paqHbreKpr{crannbrHJrr{MenKoKpr.rcrannuqecxufi nnaxHocru. rpocKonuqeHrrpu rroBblllreHHofi e pacrBopllM B crlrlpre 96 % n eQ*rpe,pacrBopl4M xnopoQoprr.re. Oqeur JrerKo X.nopa.rruApara pacrBop. Pacreop 80 r n 20 wl BoAbI. Xropanrnn. X"ropamun F. C6H5C1NNaO2'3H2O. (M.*. 267,68). xrenroBarbreKpr4cranrrbrulruKpl{crilrnn.{ecxuft [opolroK co cnaEelsre HJrncJrerKa sanaxoMxnopa. 61114 Xropalu.rHa pacrBop 5 "/t pacrBopa eoAofi Ao 100 nal. PapacrBoprror B BoAeH AoBoA-sr o6rerr,r 5 r xnoparr.rr4Ha [pr{MeHtIoT cBexe[puroToBJIeHHbIM. cTBOp X,ropalruua pacrBop 2 "/". Pacrnop 20 rln. nepeA vcnonb3oBaHlleM. forosqr HelocpeAcrBeHHo X,ropanrnHapacrBop 0101o/o.Pacrsop0,1 rAr xnopaMl4Ha. rlepeAI4clonb3oBaHr{eM. forosqr HerrocpeAcrBeHHo X,ropavurHapacrBop 0102o/o.Pacrsop0,2 rln. rlepeAr{c[onb3oBaHlleM. forosqr HerrocpeAcrBeHHo X,ropaHurun. C6H6CIN.(M.vr. 127,57).4-Xnopanvilrr:u. Kpucrarrsr. '' PacrnopuM B ropqqefi soAe,rlerKo pacrBopllM B cnl4pre 96 % u e$rape. TeunepamypannazreHua. Oxolo 7 I'C. (M.r"r. 169,60).4-XnopaqeraHr{nur. ru-XnopaqerX,ropaqeraHrrrrrrA.CSH8C1NO.
aHvItuII.

Kpucrannu'ae cxuir loporxoK. pacrBopl{M crrrpre 96 %. B B flpaxrn.recKn HepacrBopr{MBoAe, Tennepamypa nnaBreHua. Oxolo 178"C. (M.u. 191,63). C6H6CINO2S. 4-X,rop6enro;rcy.rrrQoHaMrrA. flopouox 6e.noro rlBera.PacrnopzuB cnrrpre96 % n eSupe. 4E

Teunepamypa nna*neHun. Oroto 145'C. . Xnopdyrano.rr. C4H7C13O0,5 H2O. (M.rr. 186,45).1,1,1-Tpuxnop-2-laerrnnponas-2-on Eenufi Kpt4crannuqecrnfi noporuoKuru 6ecqnerHbre Kpr.rcrrlrrnbr, 6ucrpo cy6nuuupyrculr4ecs. Vuepenno pacrBopr{M BoAe, pacrBopr.rM crnrpre 96 % u s$Hpe,paB oqeHbJrerKo B oh. crBopr{M rnr4rlepuse B 85 'C. Teunepamypa nnarreHun.Oxono78 X.nopncroBoAopoAnafl KrrcrroraKoHrIeHTpnpoBaHHas. l. (M. r"r.36,46). HC FecqeerHas )Kr.rAKocrbpe3Kr4M c 3arraxoM, AbrMqrla{HaBo3Ayxe. Co4epxurHeMeHee z ne 6olee 38 %HCI. 35 -1,19. ITnomuocma. I,l7 X.rr n croBo4op afl KrrcJrora 25 o/o.XnopucroBoAopoAHar cJrora. op oAH KLt 70 r xnopr{croBoAopo4nofi Kr4cJrorbr KoHueHTpr4poraHnofi soAofi Ao AoBoA-f,T o6reua 100rran. Co4epxlrr HeMeHee 24,8 u se 6olee 25,2 0AHCI. EecqserHar, npo3paqH , rery,rafl, afl )Kr.rAKo crb. Ilnomruocma. 1,122-I,124. X.nopu croBoA oAH KrrcJrora p a3B ennas l0o/o op ar eA 32 r xnopllcroBoAopognofiKr.rcJrorbr KoHrIeHTpr{poBaHHofi 4orogrr soAofi .uo 100 rvu. X.nopncroBoAopoAnafl KncJrorapa3BeAeHHarr oh 813 .racrr xnopr{croBo4opo4nofi CN4erursarcr I Kr{cJrorbr % c 2'racrnNrr{ 25 Bo.qbr. ohHcl. Co4epxnr HeMeHee u ue 6olee 8,4 8,2 Ilnomuocma. 1,0381,039. X.rropncroBoAopoAHar pa3BeAeHHaq oh KrrcJrora 713 Co.qepxur73 rlnHCL 23 r xJropr4croBoAopoAsofi rucnorbr KoHrleHTpr4poBaHsofi AoBoArr no4ofi 4o o6reua 100rr,rn. X.nopncroBoAopoAHafl KlrcJror 2 o/o a 6,5 r xnopl{croBoAopoAHofi xucnorbl KoHrleHTputpoBannofi AoBoArr soAofi a o 1 0 0 n r.n . X.nopucroBoAopoAnas Kucflor a 1 oh 10 rrrnxJlopktcroBogopo4nofi piBBeAeHHofi Yo4orroryrsoAofiAo 100un. Kr4cJrorbr 10 o X.nopncroBoAopoAHafl KrcJrora pa3BeAeHHafl1037 0 Co4epxrEr 0,37 r/rl HCl. 1,0 ira.u xJropncroBoAopoAHofi rrncnorrr pa3BeAeHHotrt o/o Aoso$sr ro4ofi 4o 7,3 o6rerraa 200,0rran. X.nopncroBoAopoAHafl KucJrorapa3BeAenHafl rll o 0 30 rranI M pacrnopaxnopucroBoAopoAHofi xucnorbr AoBoArrro4ofi Ao o6reua 1000lair;pH pacrnopa + 0,1. 1,6 X.uopncroBoAopoAnofi rcucnorbr pacrBop 7 M 721,00 r xJloprlcroBolopoAuofi rucnorbl KoHrleHrpnpoBauHofi ocropoxno pas6aeJrrror eoAofiAo o6rerua1000,0rul.

EIIII

X.ropucroBoAopoAnofi rcuc.norbl pacrBop 6 M ocropoxHo pas6anrzcnorbr KoHrIeHTpr{poBaHHofi 618,00 r xnopncroBoAopoAHoft -r.srorsoAofi Ao o6reua 1000,0 un. rcnc.irorblpacrBop 3 M X,,roplrcroBoAopoAHofi ocropoxHo pa:6anr<ucrorbr KoHrIeHrpI,IpoBaHHofi 309,00 r xnopprcroBoAopo4Hoil .rrror eoAofi Ao o6r,eua 1000,0 ur. X,ropncroBoAopoAHofi rcnc.norr,IpacrBop 2 M ocropoxuo pa:6an206,00 r xnopncroBoAopoAHofixucrorbr KoHrleHrprrpoBal{Hofi .r.f,For soAofi Ao o6rerua 1000,0 nrn. p fi Xrrop ucroBoAopoAHo rcprc,rorbr acrBop B cnllpre 5.0 ir,rn1 M pacrnopa xnopucroBoAopo4Hofi KIrcJTorbI iroBoAflr crli{proM 96 Yo ao o6leua 500,0 nn. X;r op ncroBoAopoAHafl KI{cJIora 6pouupoBanll afi K 100 Mn xnopucroBo/-{opo,luoiiKrrcnorbrKouuelirpnponaHnoli npNSan:rxror I nrn pacrBopa6pona. X",r opu croBoAopoAHafl Kuc.,'rora,cnodognafl or cBItHIIa KoHueHTpI{rpe6onar*rfl.rrrfl xnopHcroBo4opo4uofiK}.rc.rrorbl .]o:rxsa BbrAep)Kr{Bars I{crIbITaHXe. posaHnoii !r cneAyrouee AoiIonHIzTeJIbHoe Ceuuetl.He 6onee20 ppm. cnerrpoMg'rpl4r{. aroMHo-oMI,IccltoHnoil N{ero/IoM npoBoAflT OnpeEe;reHrre rucnorbl KoHlleHrpuporauuofi I [t'nwmyenrtil pacmeop.2A0 r xnoprcroBo,4opoAHofi rure.irn) vcilapflror floqrx Aocyxa, K nonyqer{HoMyocrarKy flo]reqaror B KBaprleBufr rrphroroBnessoii AucrnJlntquefi agornoil rucnpr.iSanlxror5 nrn asoruofi Kr.icJrorbtr, BbIrIaHI4xereMneparypbl Kt{neHlrfl,14 ilpr4 -lorbi KoriUeHTpirpoeaHnofr TeMrreparypg ili{Baror Aocyxa. Ocraror pacrBopr}or e 5 Mir a3oruofi ruc;roru, npuforoBleHHoft npu .lncrunJtsqlrefi asorHofi riac:rorbrKoHrIeHTpIrpoBaHHofr reMrleparype Hr{xe reMn epaTypbrKr4rreHr4rr. Ifr llcnoJrb3yr3TaJIoHHt pacrnop Facnteopat cpazHeHunforosgr pacrBopblcpaBHel{I{fi, (0,1 pprn Pb), pasreAesHrrfiasoruofi ruc.rroroff.rpxro'roBriesuofi Er4crvnilfl.cBHrrrIa reMrleparypbl npu uneff asorsofi xucnorbr KoHrleHTpr4poBar{Hofr reMlreparype HrDI(e
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Pacrnopunra BoAe, B alleroneI43TaHoJIe. Teunepamypa nnazneHua. Oxoto 208 "C. -35,2o. lal') . Ororo XropoQop*r. CHCI:. (M.u. I I 9,38).Tpuxnoprr,rerau. flpospa.rHar, 6ecqr ernafl, Tfl)KeJrar, [oABr,rxHar )KHAKocrb xapaKTepHbrM c 3anaxoM. Mano pacrBopr{M BoAe, B cMerrrrrBaercr cnr4proM %. co 96 Teunepamypa KuneHunOroro 60 oC. XropoSopMcoAepxo,rr 0,4 4o 1,0 % (vlrtr) eraHona. or XnopoQoprvr 6ernognrrfi K 1 n xnopo$oprua npu6aeJrrror100 r 6esnoAHoro xJropr4Aa KaJrbrlur, eHepruqHo es6arrursalor II ocraBJlflrorsa 24 u. flpospavHyro )Kr4lKocrbcJrr4Baror cyxyrc B cKJrrHKy npr{reprofi npo6rofi. c XropoQopM roAKrrcnenuufi K 100lanxnopo$opMa nplE6anmror l0l,ra xnoputcroBo4opogHofi Kr4cJrorbr KoHrIeHTprrpoBaHHofi, ecrpxxrrBaror orcrauBarorAo pa3AeJreHHs nlBa tr Ha cJror. X;ropoQopu, cno6o4nufi or oraHoJra I. 200 nrn xnopoQopMa npoMblBaror no4ofi, BcrprxvBar c rrerbrpbMrnopquf,Mr4 rro 100 un Kax(Aat. Cymar lr'al20 r Harpr{t cynr$ara 6eseoAnoro reqeHr4e B 24'a u (DrEnrrpar rreperoHrrorHaA 10 r narpur cynr$ara 6essoAnoro, or6paQunrrpyror. cbrBar nepBbre vl orroua. 20 11.20nm xnopo$opMa ss6anrHsarcr naus 20 nan 3 c BoAbr, xnopoQopNaHrri clofi orrro Aerqror u npoMbrBaror 20 v'tr eoAofi (2 paza).(Dumrpyror qepe3cyxofi $ulrrp, cMeIIrI,IBaIor5 r 6esro4HoroHarpur cynr$ara, ocraBrrflror 2'rn $rEnrrpyror. c Ha lorossr HerrocpeAcrBeHHo r,rcrroJrb3oBaHr.reM. [epeA XropoQopn, cra6nrrlr3npoBanHufi (M.u. I I9,38). aMlrJrenoM. CHC13. flpospauuax,6ecqnerHar)Kr{AKocrb. Malo pacrBopr.rM BoAe, B cMerur.rBaercr cutrproM96 %. co o/o. Boda. He 6onee0,05 Ocmamorc nocnerunapusauun. 6oreeA,001oh. He MuuuuanuHoe nponycKaHue. uenee 5A % npraAnzHeBoJrHbr yvt; He MeHee He 255 80 % rpu AnxHeBoJrHbr u*r; HeMeHee % npr.r 260 98 BoJrHbr nr"r. 300 AJruHe pacrBopacpaBHeHrlr Onpe4eneHue rrpoBoArr, r{cnonb3yrB KaqecrBe BoAy. oh CHCI3. Onpe4eneHrde RonuuecmreHHae onpedanenue. MeHee He 99,8 npoBoArr MeroAoM rasosofixpoMarorpa$uu" X.nopn.rrarunoBafl KrrcJrora.H2Cl6Pt' 6H2O. (M.r"r.517,9).fexcaxnoprrrrarvHosas(IV) Kr.rcrrora. CogepxurHeMeHee 195,1). 37,0o (vrlu)Pt. (A.rvr. KpHcrannhr r.rJrrd Kpr4crannr4rrecKils MaccaKopr4qHeBaro-KpacHoro rlBera. pacrBopr4MaBoAe, pacrBopnMa crrrpre 96 %. Oqeur JrerKo B B RonuuecmneHHoe onpedaneuue.0,200xJropnnaruHosofi r Kr.rcJrorbr npoKanr.rBaror nprl TeMneparype "C Ao rrocrorHHofiuaccu utB3BeruuBaror 900 ocraror (nnarnnrr). Xpanar B 3arrlurueHHoM cBeraMecre. or

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dli . O*ono 1,322. rr',1ononol,4go" .

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dii . o*ono0,86. n?i. O*ono 1,388.

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. d,i . O*on 1,197 o n\l,. o*ono1,442.

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Oxolo 2II "C. nnaBneHun. Teunepamypa XonuHa xJIopt{A. CsHl4ClNO. (M.r"r. I39,62)" (2-fi,rApoxcuerun)rpl.IMeruJlaMMOHr.rrxJropr,IA. Be cqeerHHe Kpl{craJrnbl, pac[JrblBatolrlue cfl, Ha Bo3Ayxe.

EI

pacrBopr4M BoAer4crrlrpre 96 %. Oqesr JrerKo B Xpaurr B Bo3AyxoHerrpoHr.rqaeMoM roHrefiHepe. Xpoua(III) rpr.rx.noprArerccarr{Apar.[Cr(H1O)oCl2]Cl.2H2O. (M.r"r.266,45). qBera; rr.rrpocKonr4ireH. Kpucrannu'aecxuia[oporxoK TeMHo-3eneHofo Jlerxo pacrBoprlMB BoAer{ cnrrpre 96 %. Xpanxr B cyxoM Mecre, 3arluilIar or Aeficrsvrfl.oKvrcnprrerefi. Xpoua(VI) orccr.rg. CrO3. (M.rur.100,0). Xpouonufi aHrHApr4D* XporrlarprroKcrrA. l{ronr.rarrre Kpl{cranrrbr r4rrvt rpaHynbr reMHoro Kopr4qHeBaro-KpacHoro rlBera, pacnnbrBaroqvecs.Ha Bo3llyxe. Oqesr nerKo pacrBopt4M BoAe. B XpaHxr B Bo3AyxoHenpoHr{qaeMoM xourefinepe. Xpona:ypon S. C23H13Cl2Na3OeS. (M.nr. 605,3).Tpunarpux 5-[(3-rap6orcu-raro5-uerun-4-oxcoquKanoreKc -2,5-guen-l-utlrgeu)(2,6-tn xnop-3-cyrrQonaa -r uAporc n - 3- u erun 6 en: o ar. ro Qennn) laer un]-2 lloporuor Kopr4qHeBaro-r{epHoro rlBera. Pacrnopuu B BoAe,MaJro pacrBopraM cnupre 96 %. B Xpovra-ma"nnxcyun$ar. CrK(SO )t . l2H2O. (M.rur.499,4). Xpouonue KBacrlhr. KpynHue Kpr4clzlJrnbr $uo;reroBo-KpacHoro qepHoro rlBera. or Ao Jlerro pacrBoprrMB BoAe,rrpaKrr4qecKr4 HepacrBoplrM crrr{pre 96 %. B Xpouonax Kr.rcJroTa 40 r xpouoBoro aHrrrApnilapacrBoprror B BoAeH AoBoArr o6reu pacrBopa nogofi 4o 100 nrn. Xpovronar cMecb Hacrtnlenuufi pacreop xponra(Vl) orcn4a n cepnofi Kr.rcirore KoHrIeHrpr4poeanHofi. Xpomonufi reuuo-cuHnfi. Cl6H9C1N2Na2O9S2. (M.rur. 518,8). KvcnorHufi xporvrosl,rfi reuHo-cuuufi. fiunarpueyax coJrb 2-(2-rugpoxcpr-5-x.rrop$eHran)aso-1,8u-3,6- gucylr$oxucloru. nLIrLrApoKcuHaSralu llopourox reMHo-Kopr4qHeBoro qepHoro qBera. r4nr4 Jlerxo pacrBopr4M BoAe. B oApacrBop BHIITHeBo-KpacHoro 0,05 rlBera. B rurepnane pH 9,5-10,0 HMeercrHeero KoMrlneKcbr lroHaMH c KaJrbrluq, MafHr{r x qr{HKa Tex xe B Szonelonyro oKpacKy, ycnoBr{rx KpacHororIBeTa. llepexo4 oKpacKI4 rlpr4rrprMoMrlrrpoBaHnvt o'r xpacuoil r crane-$noreroeofi. IluduxumopHafl cMecb 0,25 r xpoMoBoro reMHo-cLIHero 25 r Harprrr xnopr4ra pacrrrparcTB cryrrKe rr neu peMerrrr4BaloT. Xpouorpon II B. C16HeN3Na2O16S2. (M.rr. 513,4).fiuuarpul. 4,5-ruru11porcx-3(4-nrErpoSeuu,ra:o)H atuu-2, 7 -gucy:n$oHar. a$r floponrox KpacHoBaro-Kopr.rqHeBoro rlBera. Pacrnopul,t B BoAec o6pasonaHr4eM )KeJrroBaro-KpacHoro pacrBopa, [paKTzrrecKu HepacrBoprrMB cnr4pre96 %. Xpo*rorpon II B pacrBop 01005 o/o.Pacrsop 0,05 rh n cepHofi xnclore KoHrIeHrpnponaHuufi. XpovrorporroBafl KlrcJrora. Cl0H8O8S2. (M.rur. 320,28). 4,5-[uruapoxcvr-2,7Ha$rnruu4racynsQoHoBarKucJrora.

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Llronr.rarrreKplrcriurnsr 6enoro uBera. pacrBoprlMa cnl,Ipre96 % u e$ltpe. B PacrnopurvraBoAe, B MaJro oqeHb Teunepamypa nna*teHun.Orcoto300 "C. pacrBop 0rSoh Xporvrorpononofi KrrcJrorbr pacrBoprrcT r,r [prrMepHo 80 MnBoAbr AoBoAtrreM s 0,50 r xpoMorponosofiKrrcJrorbr x(epacrBopr,rreneM o6relua100rvrn. Ao pacrBopa 24 q. Cpor rogHocrr4 ' HarprreBafl corrb.ClsH6Na2OgSz2HzO(M.u. 400,3). Xpo*rorpononofi Kr{crrorbr r ar. r finuarpux 1,8-4uru4poxcnuaQ atmu-3,6 glrcyn Qonar, AI4rI,IAp rlBera. floporuor xeJrroBaro-6enoro HepacrBopl,IMa B crlrlpre96 %. Pacreopuua BoAe, B [paKTr4qecKr4 (M.t. KncJrorbr Harpl{eBaqcorb 6egsoAHas. ClgH6NazOsSz. Xporvrorponosofi IIBera. 364,27 . lloporuor cepoBaro-6eroro ) Ilerun xJroprr. CsCl.(M.u. 168,36). llopourox 6eroro rlBera. pacrBoprrM MeraHoJIe, HepacB npaKTrIqecKV B JrerKo OqermnerKopacrBopr{M BoAe,
TBOprrMB arIeTOHe.

Ile.nmo.no3a xpoMarorpaQHu(1) Arrfl qacrlrrl MeHee pa3MepoM fouoresuufi uoporuor 6eroro rlBera co cpeAHr{M 30 uxu. Ile.nmo.iro3a xpoMarorpaQnn (2) Arq rlennrcnoga. foNaoresnrrfi lopouroK 6enoro IIBera MurporpucraJrJrr.rqecKa{ pa3MepoM rracrr,rrl MeHee naxrr,r. 30 co cpeAHr4M Ile.nmo.no3a xpoMarorpaQun F25a AJrfl fouorennufi nopourox6eroro IIBeraco MurporpucrarrnrrecKar rlennrcnozaF254. qacrr,rq pa3MepoM MeHee uru, coAeplrarrlrnfi 30 cpeAHr4M Qnyopecrleurnufi[H,uI,IKarrpv BoJrHBr IF.rr'I. 254 TOpCOnrr.rMilJrbnofi unrencr,rBHocrbro norJrorrleHufl AnrrHe I f e p u r (III) H n rp a r. C e (N O) t' 6HzO. ( M .u. 434,3) . I{ epua r pr r Hl{ r par , reKcarr.rApaT. Kpucraruuqecxufi[opouroKor 6ecqnerHoro cna6o-xenrororlBera. Ao Jlerro pacrBopr4M BoAe crrr4pre %. B r4 96 qepnfi(Iv) cy.nrQar. Ilepnn aMMoHnfl ArvrrvroHnfi cynrQar. Crr,r. . I{epufi(IV) cepnorncnnfi tetIf epur(I\) cy.irr$ar. Ce(SOa)2'4H2O (M.r"r.404,3). , pafr4Apar. )Kenroro rrJrr.r IIBera. Kpucrannuqecxufi[opolroK unrr KprrcraJrJrbr opaH]r(eBo-)KeJlToro pacrBopr{M pa3BeAeHHbrx pacrBopr4MBoAe, B MeAneHHo B KrrcJrorax. O.{eHrMiuro (M.r"r. 364,44).I{erpnrvrouur'6poIferurrpHMerr{rraMMoHrrr 6porvru4. C19Ha2BrN. ura.q. N-feKcaAerlnn-N,N,N-rpuMerr4JraMMouutx 6portr4. Kpucrannu'aecxuia [opoilroK 6eroro uBera. pacrBopr{M clrrpre 96 %. Pacrnopzru BoAe, B B JrerKo Teunepamypa nna*neHun. Oxono 240 "C. If eQa.rrnna C 7 AuruApoxrroprrA. 28H 4aCl2NzO+'H2O. (M. *. 666,6). (R)-1-[(2S,3R,11bS)-3-3rvr-1,3,4,6,7,11b-rercarn4po-9,10-Aunaeroxcu-2H-2-unverun]-I,2,3,4-Terparr.rApo-7-rr,reroKcr4r43oxrIHornn-6-or 6eHsoIo]xr{HoJrr{3r{H renTarrrApaT. 4,rrr.rApoxnoprrA,
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Kpncrannu.recx[fi noporrroK or 6eroro Ao )KeJrroBarorouBera. Jlerxo pacrBopr{MB BoAe,pacrBop}rMB arlerone r{ crrrpre 96 %. o pacrnop). [a], . Oxors +25' (2 I{nano6poMnAa pacrBop K 6pontrofi nole upu6annxrcTno KanJrrM npn oxJrax,qeHvru 0,1M pacrnop aMMoHI4t Tr4orlr{aHara Lr e3HoBeHr.r-s xenrofi oKpacKI4. Ao crr forossr HenocpeAcrBeHHo nepe.{ ucloJrb3oBaHrreM. IfnanoryaHnArrH. C2H4N4.(M.u. 84,09). fiwluauguaMur.l-I{uanoroyalr.vr4urH. Kprcrarruqecrufi roporuoK 6eroro rlBera. pacrBoplrMB BoAerr clr4pre 96 oh, rpaKTuqecKr4 n Yrraepeuno HepacrBoprrM eQupe z MeTr,rJreHxnopr4Ae. Teanepamypa nna*neHun. Oxono 210 "C.

(M.u. 85,06). IlnaHoyxcycHan Kucrora. C3H3NO2.

rrHbreKpr{crannbr 6eroro HJrH firrpo cro nr4 xeJrrosaro - 6eroro rlBera. Pacrnopuua B BoAe. Xpanxr B Bo3AyxoH roHrefi nepe. errpoHrrrlaeMoM Ifnrc;rorexcaH. C6Hrz. (M.rvr.84,16). llpospavHax, 6ecqnernafl. BocnnaMeH.fllorqascs xraAKocrb. ) pacrBopr4flpaxru.recKr4HepacrBopr4M BoAe,cMerrrr{Baercr opraHuqecKr4Mrr B c
TEJI'MI4.

dii . o*ooo 0,78.

TeunepamypaKuneHut Ororo 80,5 oC. I{urrorexcaH, r{cnomsyeuufi B crreKTpo$orouerpur4,AoJrxeHBbrAep)KuBarb cJrer4cfrbrraHr{e. Ayroqee Ao[oJrHrrreJrbHoe Munu.ntanaHoe nponycKaHue. % trpll An]rHeBoJIHII220 nw;70o/onpu AnIrHeBoJrHbI 45 235 uwr;90 % rprr Anr4He BoJrHbr 240 uw;98 % rprr Anr4He BorrHbr 250 Hrvr. pacrBopa cpaBHeHr{r npoBoA{! r{cilonb3yr B KarrecrBe noAy. Onpe4eneHr{e Ilnrc;rorexcaH ocodofi .rucrorrr rlr4KnoreKcana cneAyroqee AorronHr4TeJrbv ,{onxen BbrAepx[Barr rpe6onaHvrfl,Arrfl,
HOE UCIIbITAHYTE.

ZnrencusHocrb nornorueHlrr, r43MepeHHar Anr.rHe rrpr4 BoJrHbr 460 nu (npu o6ny.renouloHur,r [yrrKoM cBera c Arusofi BoJrHbI 365 nvr), He AonxHa 6rrrr rrHTeHc]rBHee ilIeHr4rpacrBopa 0,002 ppm xr4Hr{ria 0,05 M pacreope cepnofi Krrcrrorbr. n If nx,rorexcrrJraMlrH. C6HI 3N. (M.pr. 99,17). EecqserHaqxkrAKocrb. pacrBopvrenrMr4. PacrnopurvrB BoAe,cMerrrv r cs c sau6onee pacnpo crpaHeHHbrMr4 Bae Z, . Oxono 1,460. TeunepamypaKuneHufl. Or 134 ao 135 'C. I{lrx"uorerccIIJIeHAI{HIrrpHJrrerpayKcycHafl KrIcJrora. Cl4H22N2O8 HrO. (M.*. 364,35). mpauc-l\uKJrofeKcrlneu-I,2-guulrupnno-N,N,N',N'-rerpayKcycHat
KLICJIOTa,MOHOI'LIApaT.

Kpucrarru.recrufi nopolroK 6eroro rlBera. Teunepamypq nna6n eHua. Orcoto204'C. -If urc.rroreKcrrrrrrponroHoBafl Krrcrrora. CgH| 60z. (M. pr. I 56,22). 3
Bec{serHas xr.rAKo crb.

dii . o*ono0,998.
/t, . Oxono1,4648. Teunepamypa KuneHutOxono 130"C. IfnHeo.r. Ct0H180. (M.u. 154,24). 1,8-I{uHeon.Ssxarunror. 1,8-3noxcu-nMEHTAH.
20

EecuserHas xu.rlKo crb. flpaxrrEvecKr{ HepacrBopr{MBoAe, B cMerrrr4Baercfl c oraHoJroM e$uporra. u d,i . or 0,922to 0,927.
7 1 u O r 1 , 4 5 6t o 1 , 4 5 9 . . TeunepamypasameepdenaHun. 0 ao I 'C. Or Tennepamypuarc nepezoHrcu. 174 to 177'C. Or npedenbt If unrc. Zn. (4.u. 65,37). I{nux rpaHynrrpoeaHHufi . Co4epxur He MeHee99,5 Yo Zn. I{nnuH4pu ) ytrrvt crpyx{Ka c lpaHyJrbr, nnu ilrapvrn cepe6pucro-6eroro rlBera, r{Jrr4 cr,rHrrM 6recxol,t. IllrHx aKTlrBrrponaHHufi qrrnnHApoB vtrwtilrapr{KoBrroMeula}or B KoHrrrrecKyro I{uux B Br4Ae xor6y, npu6ay(50 JurrorAocraror{HoeKoruqecrBo pacrBopa xnoprrnar}trosofi KracJrorbr ppm), qro6rr qepe3 10 uun MeraJrJr no4ofi, yAantlor noJrHocrblonoKpbrrb MeraJrJr, rrpoMbrBalor BOAyt4 HeMeAneHHO CyrIar.
20

I{zux Ifunxa auerar. (C2H3O)2Zn' 2H2O.(M.pr.219,50).IJnura aqera! ,qurnApar.

yKcycHoKr4crurfi 2-soAHHfi. BbrBerprrBaroqrrecr Bo3Ayxe. Jlerro Enecrsrque Kpucrannrr 6eroro uBera, cJrerKa Ha pacrBopr{MB BoAe,pacrBoprrMB crrrrpre 96 %. llpu rervrneparype 100 "C reprer Kprrcrannu3arlnoHHylo BoAy.

dli . O*ono 1,735.

Teunepamypa ma*reHun. Oroto 237 "C. IlnHxa arlerara pacrBop B cMecu600 rra.n BoAbI rI 54,9 r qlrHKaarlerara pacrBoprrcr npr{ nepeMerrrraaanuvt 150ur yxcycuofiKucJrorbr reA-sHofi. Ilpra neperuerrvBanr{u npu6annxrcr150Mnpa(32%), oxnolcAarcT KoMHaruofi renuepacrBopaaMMrraKa KoHrleuTprrpoBaHHoro Ao o/opacrnopoMaMMI4aKa, Typbrr,rAoBoArrpH Ao 6,4 25 o6reN{pacrBopa AoBoA.qr so,qofi 1 n. Ao IJuHraoKrlcb. I{uurcaoKcrrA.ZnO. (M.u. 81,37). Benufi urtu6etrctfic xeJrroBarbrM anaopSnrrfi nopouror. flomouaer yrneorreHKorra
Kr4CnOTy BO3AyXa. Kr{cflpaxruuecKr{ HepacrBoprrM B BoAe, cnrrpre 96 %; pearr.rpyer c Mr4HepanbHbrMr.r JroTaMr{, eAKuMr{ IrIeJIOqaMI4.

''

Ifunna ropoiloK. Zn. (Alvr. 65,37). He Co4epxr.m MeHee 90,0o Zn. (A.wr.65,37). Oqeur uerrufi nopouroK cepororlBera. Pacrnopul,r xnopncroBoAopoAHofi B rzcro:re pa3BeAeHsoit oh. 7,3 ' 7H2O.(M.r. 287,54).I{nnr cepHoK}rcJrufi 7-nognufi. Ifnnra cy.nrQar. ZnSOa I{r,rHxcepHoKr{cnufirenrarr,rApar. ,
27.3ax 2769

rrJrrrMeJrKoKpllcrruln[.Iecrnfi nopouror. Ha EecqserHHe, fipo3parrHbreKpracriurJrbr BO3AyXe BbrBeTpr,rBaeTcf . OqeHr nerKo pacrBoprrM B BoAe,oueHb MaJIopacrBopl,IMB crll4pre 96 %.

(M.u. 136,28). ZnCI2. Ifnnra xrroprrA. nopolroKunu 6elue 6pycovrra. Eerrrfi Kp[crannu.recx[fi
pacrBopnM B cnl,Ipre 96% LI DIHIIepI,IHe. Oqenr JrerKopacrBoprrM B Bo,ue, IluHrca xJropnra pacrBop B MypaBbnHofi Kl{cJrore rucnorH 6espacrBoprrcr s 80 r 85 o/opacrBopa MypaBbLIHofi 20 r quuxa xJropr,rAa so,qHofi. IlnHrca xJroprrAapacrBop fi ognponannslfi 20 r qunrcaxnopl4Aau 6,5 | KaJrut itoguga pacrBoptrot s 10,5 ul BoAbI,npu15 6aerqror 0,5 r fio1a r4 BcrprxnBaror B TeqeHI,Ie runs. Ecnz neo6xo4zruo,

Qunrrpyror.
Xpanar B 3arrluqeuHoMor cBera Mecre. Ifnnxonnsun. C1eH22N2O. (M.r"r. 294,39). (R)-(Xunor4-un)l(2R,4S,5R)-5y x;nuguu-2-ur] uerauon. Br4Hr4JrxrrH Kpucrarrla.{ecrufi [opo[roK 6e;ioro IrBera. O.{eHr Mano pacrBopr4MB BoAe r,r nerpoJrefiuou eSzpe, yMepeHHopacrBoprrM B cnrrpre 96o , MaJiopacrBopl{Mn e$upe. o/opacryopng6ohcuvrpre). lall . Or-105 Ao -110'(5 Teunepamypa nnaBneHua.Oxoto 208 "C c pa3JroxeHl{eM. Xpanrr B 3aur4rueHHoM cBera Mecre. or Ifnnxonnn. CeH22NzO. (M.rur.294,39). (S)-(Xunor4-utr)l(2R,4s,5R)-5-euHlarwu-2 xr,rHyKJrrdA -uttlwer aHoJI. Kpucrarnuqecrtlfi loporroK 6enoro uBera. pacrBopr4M crrr{pre 96 % LI MeraHone,MaJIo B Mano pacrBopuM B BoAe,yMepeHHo pacrBopr,rM e$rape. n o/o pacrBop B crrpre 96 %). lal, . or +225 4o +230 " (5 Tennepamypa ma*neHua. Oxotro 263' C. XpaHxr B 3arrluueHHoM cBera Mecre. or IfnprcoHuJra Hlrrpar. OcHosHaqcoJrb,cocraB roropoi rtpudtmsureJlbHocoorBercrByer Qopuyne ZrO(NO3) 2' 2H2O (M.rnr.267,27). Kpr,rcraJrJrbr 6enoro rlBera. firrpocrouuqeH. Kpucrannuqecrufi nopo[roK r4Jrr.r PacrnopuM B BoAe. Bolnrrfi pacrBop npo3paqHstit uttu cJrerKa ouaneclll4pyrorqrfi. xonrefinepe. Xpanxr B Bo3AyxoHe[poHr4rlaeMoM

Ifnpronnrra Hr{TparapacrBop 0rl o KOHpacrnoputerefi BOAa - XJTOpTTCTOBOAOpOAHa{ KTICJTOTa Pacrrop I r/n e cMecr,r (40 rleHrprrpoB anlaas, :60). coorBercoJrb, cocraBroropofi upu6rurureJrbno I{npronnJra xJropnA.OcHoeHar crByerSopuyne ZrCl2O' 8H2O(M.u. ? t ' ) t < \ Co4epxnr HeMeHee 96,0o ZTCI2O'8H2O.
J--.-J L

uotITI,I6eroro IIBera. Jlerrco Kpncra-urrrecxuft uoporroK rrnr{ KplrcraJrJrbl6enoroI,urL{ pacrBoplrM B BoAeH crrpre 96 %.

(M.na.121,1 L-IJncreun. C3H7NO2S. 6). Benufi Kplrcrannuqecxufi roporxoK. JlerrcopacrBopl4MB BoAe,cnhpre 96 % rr Kncnore yrcycHofi, npaKrr4qecKr{ HepacTBOpHM B aqeTOHe.

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s xnoprrcroBogopo4nofi xucloru). tal', . Orono 6,5 " (10 o/opacrnop I M pacrBope (M.u. 240,30). L-Ifucrun. C6H12N2O+Sz. Kpucrarrvqecxuia roporroK 6eroro uBera.Pasnaraerc-s TeMneparype "C. ilpr4 250 flpaxrzvecKnHepacrBopr{MBoAe crzpre 96o/o, pacrBoprercrB pa3BeAeHHbrx B il pacTBopax rr4lpoKc r..rAoB ilIenoqHbrx MeTaJrJr oB. -218 ao -224 '(1 M pacrBop .Or xnopr4croBo4opo4Hofi xucloru). lal',," I{urpa.nr. Cl0Hl6O. (M.r. 152,23).Cnecr (28)- u (22)-3,7-lnnerur-or<ra-2,6,iIHeHant.

Xu.(xocrr cBerno-x{eJrroro uBera. flpaxruuecKr4 HepacrBopr4Ma B BoAe, cMe[r]rBaercr cnr4proM o ,:Snponr vfirvrco 96 uepIrHoM.
I{urponreH. C1lH10O4.(M.r"r. 206,19). Jlurvrerrun.5,7-[r4MeroKcH-2H-1-6eHsonupau-2-ou. I4ronr.r arute Kpr.Icrannbr. llparruvecKu HepacrBopr{M BoAe,e$upe v rerponefiHon eSupe, JrefKo B pacrBopr4M B arleroHe14 cnnpre 96 %. Teanepamypama*neHun. Oxono I45'C. Ilfane.rrenas Klrcrlora. (COOH)2' 2H2O. (M.rta. 126,07). Sran4rarap6oHona.s rr4c".IOTa,AI,Ift4ApaT.

KpHcrarru 6eroro rlBera. Pacrnopurraa pacrBopnMa cnr,rpre o/o. B BoAe, JrerKo B 96 llf ane;renofircuc.norbr pacrBop 5'/, 5 r qaseresofi xucrorbr pacrBoprlorB BoAe npaz6annsror soAofiao 100vln. pacrBop B cepHofinnc.nore Illane.nenofircuc.uorbr 5 r uaeenenofixucnorbrpacrBoprrorB oxnaxAeusoficMecu75 r'r.n BoAbr 450 un c cepuofi Kr4cJrorbr KoHrleHTpr{ponauuofi . pr. | 64,20) 4- Antut-2-rvreroxcu$eHol. 3nreHo.n. rcHnO 2. (M. C .
EecqeerHafl nnv 6re4uo-xenroro rlBera, Macn.f,Ht4cra.fl xuAKocrb; rroA Aeficreuell Bo3Ayxalr cBera reMHeer r4craHoBtrrc-x 6olee eqsrofi. llpaxrzuecKl4 HepacrBopr{M BoAe,cMerrrnBaercr cnr{proM 96o ,e$uporrav}KrrpB co HbrMuu sQupHrrMr.r MacnaMr4.

d]i . Oxoro1,07.
TeunepamypaKuneHufl. Oxolo 250'C. qncrora sBreHoJra, Xponaarorpa$uvecxax ncflonb3yeMoro ra:osofi xpoMarorpa$nn, B o . ronlr(Ha 6uru He MeHee98,0 XpaHm B 3anIHrIeHHoM cBera Mecre. or

(M.rur. 9fi rconoren. HOCI gH5NH2)SO3Na5. 261,24).Harpuenarconb l -arvmvo-2Ha$ron-6-cynrQorncJrorbr. BecqeerHue Kpxcrannbr. PacrnopuuB BoAe.

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SrvroAIaH. C15Hlgos. (M.r"r.270,2). 1,3,8-Tpuru4porcu-6-Merl4rlaHrpaxilHoH. I4ronrqarrre KpHcriLIInbIop aHxeBo-KpacHoro IIBera. s B flpaxruuecKr4 HepacTBopI{M BoAe,MaJIopacrBopl{M n e$zpe, pacTBopI{M 96 Yo c[r,rpre 14 pacTBopaxrr{ApoKcI{AoB[IeroqHblx MeTILIIJIoB. Spnoxporvrvepnufi. Cu. IlporpanHofi, uepnrtfi 11. Spnoxporvruepnufi T. Cru. Knclornrrfi xporvr.repuufi cfleql{aJrbHrrfi. SpHrpuro.rr. C4H10O4. (M.*. I22,1). (R-, S.)-EyraH-I,2,3,4-rerpon. aeso-SpurprlTon. rerparoHanbHblx npLI3M. B EecqeernrIe KprrcraJrnbr BLIAe Oqesr nerKo pacrBopl{M B BoAe, pacrBopl,IM B trlrpr44uHe,MaJlo pacrBopl'IM B cnr.rpre96 %. TeunepamypennarneHun.Oxotto 127,5 "C. (M.u. 337,57).(Z)-[oros- 13-enoauraA. 3pyrcauns. C22H43NO. 6eloro IIBera. rpaHynbl xeJlToBarofo rrJrI,I llopourox r{Jrr.r paB flpaxurvecKr,r HepacrBopr,rM BoAe,oqeHbJrerKopacrBopl4MB MerLIJIeHXJropr{Ae, B crBopI,IM 9TaHOne. 'C. Teunepamypa n.ra*treHua.Oxolo 70 367,30).6-(B-D-fttroKorll4panosunoxcu)-7Scny;rnn. Cl5Hl6oe' 1,5H2O. (M.rur. -2 rrrApoKcr{-2 H-xp orvren - on. lloporuox 6eloro urr4 florrrr4 6e.noro rlBera nru 6ecqnerHble Kpl-Icrannbl. pacrBopxM n ropxvefi BoAerr ropacTBopr{M BoAeu cru{pre 96Ya, JrerKo B YvrepeHuo prqeM cnrrpre 96 %. Scrparon. C10Hl2O. (M.t. 148,2).1-Merorcu-4-rryon-2-enra.n6engon. Hllcras xu.uKocrb. Macn-f, Claeurlreaercr co cnr{proM 96 %.
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n1,i Onono 1,52. . KuneHun Orono216'C. Tentnepamypa

r{Hcrora gcrparona, r{cfionb3yeMoros ragosofi xpoMarorpaXporr,rarorpa$u.recxax o/o. $nvr, 4orxua 6urr He MeHee98,0 l7c-ScrpaArrorr. C nH24O2. (M.*. 272,37). Kpucrannu'aecxuia [oporroK 6eroro r4rprflorrrl4 6eloro IIBera zru 6ecqeerHble KplrCTAJIJIbI.

pacrBoplrM B B flpaxrN.iecKr{ HepacrBopr4M BoAe,pacrBoplaMs 6eugore, yN{epeHHo oA,MaJro pacrBopLtM e$upe. n crrrlpre 96 Teunepaml,pa ma*reuun. Ol 178 ao 179'C. 3cunH fionyqeHHbrxr{3 ceMflHAesculus hippocaCuecr poAcrBeHHbrxcanoHr4rroB, stanum L. O.reHr lrenxufi alropQnrrii nopouroK [oqru 6enoro, uJIIr cJrefKaKpacHoBaTOrO,trJIpI )KeJrroBarofo IIBeTa. 3rauo.n. C2H6O. (M.*. 45,01). Cnupr erunoenfi a6comoruporanunfi. Cnnpr 6eseoAHHfi.Srasor 6esno4urri. Eecqeernar, [po3paq*afl.oJreryqar? BocrrJraMeH{roulatctxI4AKocrn. furpocKoluireH. Claeurueaercr c noAofi Ir MerLIJreHxnopuAoM.

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d,i . o*ono 1,04. n:i.O*ono1,454. Tennepamypa nna*reHun. Oxono 'C. 11

Xpanxr B Bo3AyxoHenpoHrdrlaeMoM rourefinepe. (M.u. 100,11). 3ru.narcplrrar. C5H8O2. Snunupon-2-eHoar. Eecqsernasxr.rAKocrb. pacrBopr{M BoAe, O.ieHrMaJro B cMerrruBaercr3TaHoJroM c u e$lrporra. ty'.,. Oxono0,924. ru,'. o*ono 1,406. Texnepamltpq KuneHufl. Orono 99 "C. Tennepamypa nfla*reHun. OxonoMr4Hyc 7l'C. 3runaqerar" CaH3Oz.(M.rur. 88,10). llporpa.rnax, 6ecqrerHas r{r4AKo crb. Pacruopnru BoAe, B cMerrrrrBaercr cnr4proM %. co 96 d,i " Or 0,90tr 0,904. ao Te.ttnepamypa KLtneHufl. 76 ao 78 oC. Or 3ru.iraqerar o6pa6orannufi 200 r cynr$arraHHosofi KHcJIorhI ts r{ Arrcneprupyror 3Trrnauerare AoBoArrreM }nepacrBoptrreneM ootenaa 1000run.IoryueuHylo cycneH3raro repeMerrrr{Baror B reqeAo Hue3 cyr n Qra;urpyrorrrepe3 6ynraxnufi $lrnrrp. Cpor ro.qHocrr4 I lrec. (M.rur. 3rnn6eH:o.r. CsH1s. 106,16). oh(vr/u) CaHro. Co4epxur HeMeHee 99,5 llpospaunag, cueerHarxr4AKocrb. 6e flparruuecKr{HepacrBoprrMBoAe, pacrBopr4MarleroHe c[]rpre 95 %. B B u d,, . Orcoro 0.87. nil.Ororrol,496. " Teunepamypa KuneHun Orolo 135'C. 2-3rnnrerc an-1r3-gno.rr. sH1gO2.(M. rvr | 46,22). C . Crerxa MacJltHr4craa, 6ecqnerHaq xuAKocrb. graHoJle,2-nponauoJre, PacrnopuuB nponuireHrnrrKoJre r,r Macne KacropoBoM.

dli . o*ono0,942. nii . Ororo1,451.

Tennepamype KuneHutOrono 244'C. 2-SrnnrercaHoBat KrrcJrora. CsHl602.(M.rrr.144,21).2-3rurxanpoHoBaq KrrcJrora. EecuserHag )KHAKocrb.

pacrBoprlMaB sTaHoJre e$upe. flpaxruvecKrr HepacrBopraMa Bo.qe, B JrerKo ra dr" . Oxotto 0,91.

n'i,. Oxoto1,425.
Tennepamypa KuneHufl. Orono 168"C. SrureH6nc[3,3-au(3-(1,1-4nnernrarn.rr)-4-rn4porccnQeHun)6yrnpar]. C50H66O8. (M. r. 795,0). 3rnneu6uc[3,3-av(3-mpem-6yrun-4-ruilpoxcu$eHun)6yrNpar] . Kpzcraru[.recxufi [opouroK. llpaxruvecKr4 HepacrBopr4M B BoAe rerponefisou aQupe,oqeHb H nefKopacrBopr4M B arleroHe, e$zpe u MeraHoJre. Teunepamypa nnazneHua. Oxotro165'C. Srur eH rru{KoJr C2H602. (M. u. 62,07 3r au-1,2 guo b. l. ). Eecqneurax,cJlef Bflgnafl, Ka rxrpo cKorr vrqnafl, xI{AKo crb. oh,Mzuro pacrBopr,rMeQzpe. n Crvrerureaercflnogofiu crrrdproM c 96

d i i . o r 1 , 1 1a o1 , 1 1 5 . 3
n'] . Oxolo 1,432. Teunepamypa 12'C. nna+neHun. Oxolo MrrHyc Teunepamypa KuneHufl. Ororo 198'C. Rucnomuocmb. 10 run tpu1ar:ntror 20 MJIBoAbr 1 rur 0,I ohpacrnopa QeK ra pacrBopaAonxHar{3MeHnrbcfl, po3oBofi nor$ranenHa; oKpacKa uplr [prAo pacrBopalr^arpufl, 6annenprn 6oree 0,15 un 0,02 M He rr,rApoKcprAa. Boda.He 6onee Yo. 0,2 ( S r u r e n u r rrK o rrflMo H o Me rr.ro s r r fi eQnp. C3H8O2.M. vr .76,09) .2- Mer oxCII9TAHON.

llpospauna.a, 6ecqnerHar)Kr,rAKo crb. 96 CMenrnsaercrc eo4ofi,arleroHoM, cnrrproM %u s$upol,r.

dli . o*ono0,97. nil . O*ono1,403. Tuwnepamypa KuneHun Oxono125"C. (M.r. 90,I2). 2-3rorSrn.neHrrrrrKorrfl MoHoorrr.nonsrfi eQnp.C4Hl0O2.
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dii . o*ono0.93.
,ft, .Orcoto1,406. Tettnepamypa KuneHufl. Ororo 135"C. (M. 3rn.nenAnaMr.rH. C2HsN2. r. 60,10). SraH-1,2-guauuu. r,rMeer llpo:pa.rHaa,6ecqnerHarxorAKocrbc aMMrraqHbrM 3arraxoM; curbHollenoqHyropeaKrlr.rrc. pacrBopr{M s$upe. cN{enr[saercr c eo.uofi cnrrproM96 yo, MaJro u n Teunepamypa KuneHutOroro 116"C. (Srn.rreu4nHurpn.rr)rerpayKcycHafl (M.u. 292,25). Krrcrrora. C 1 reNzOs. sH N,N'-1,2-arauguutr6nc[N-(xap6orcurraerun)rnuqun]. 3AerosasKucJrora. 3ITA. Kpzcrannuqecxufi, flopouroK6eroro rlBera.
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dii . onono 1,25.

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(M.t. 434,5). 3,3'-[3ruru.IAeu1,1'-SrnrugeH6nc(rpnnroQau). C2aH2eN+O+.

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Kr4cJlora. 6yran4uxap6onosaq Teunepamype nnarneHua. 104ao 107'C. Or (M.r'r. 166,2). 3runnapa6eu. 3rnrnaparrrApoKcn6ensoar.C6H4OHCOOC2H5. rucnorrr. Srut-n-ru4porcu6eusoar. Srunosrrfi sQzp flaparr,rApoxcr6ensofiHofi 3runnaparra4p oxcu6eH3oar. Eenufi Kpr{crrlrrnra.re [oporuoK Iarn 6ecqserHbleKpI,IcraJrnbI. cKufi pacrBopllM cflrlpre 96 %. pacrBopr{M BoAe, B Mairo B JrerKo Oqesr Teunepamypa nnqrneHun. I 15ao I 18'C. Or Srn.nQopMrrar.C3H602. (M. r. 74,08).3rznueraHoar.
flroxJaflas. )Krr4Kocrb. flpospaunax, 6ecqnerHafl, BocnJraMeH Jlerro pacrBoprrM B BoAe,cMerrrlrBaerct co crlldproM 96 % u eQzporr,r.

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1000,0 Mr. llpr,rroroBJreHnbrfipacreop AonxeH r,rMerbJrr.rMoHno-xenrrrfirlBer. Vcmauoerca mumpa. 25,0 un [puroroBJreHHoro pacrBopa fioAuosoxnoprrAa rroMeIrIaIor e xor6y c npr,rreprofi npo6rofi, npu6annsror I r Krurnr itoplularr ocraBJrrror B 3aruruleHHoMor cBera Mecre ua 15 ruun. BuAenraettrzficxitog rr{Tpyror 0,1 M pacrBopoM Harpr{fl rzocyrr$ara, [c[onb3yr B KaqecrBe uHAr,rKaropa o/opacryopa KpaxMana. 0,5-1 ru.nI 1 ur 0,1 M pacrnopa Harprrr rr{ocyJrb$aracoorBercrByer 12,69 rvrrI. Turp pacrBopa ycraHaBnr{Baror raxArrfi pa3 [epeA npr{MeHeHr,reM. XpaHxr B cocyAax reMHoro creKna c npr4Teprblnan npo6xaMr.r 3arrlrurleHHoM cBera B or Mecre. 01033M pacrnop Ka!'rrrfl6ponara 5,5110 r Kaxr{r 6ponaara pacrnoprror B BoAe14 PO AoBoArr o6reu pacrBopaeolofi Ao

1000,0 rra.u.
VcmaHoerca mumpa. K 10,0 Mn nonyqeHHoro pacrBopa rplr6annrrcr 50 rran BoAbr, o/opacrBopa Railvrfl, l0 rur 16,6 ito!.uha u 5 vr 7 M pacrnopa xnopucronogopo4Hofi KlrcJlorbr.Turpyror 0,1 M pacrBopoM Harpprflruocyrs$ara, ucnoJrb3ya1 rran 0,I oA pacrBopa KpaxMana. I4nAzxarop upu6ann.f,Ior B KoHrIe rr4TpoBaHr.r.f, . 1 ur 0,1 M pac:rnopaHarprls r}rocynbQara coorBercrByer 2,783 ur KBrOj. 0,02 M pacrBop KaJrHr 6pouara 3,340 r KaJIur6porr,rara pacrnoprror B BoAer,rAoBoArr o6reu pacrBopa eoAofi Io PO

i000,0 run.
Vcmauoerca mumpa. K 15,0 Mn nonyqeHHoro pacrBopa npu6an;lr'ror 45 Mn BoAbr. rrprr ycraHoBKe rr4Tpa0,033 M pacrnopa ranzr 6po.{anee [ocrynarcT" KaKyKa3aHo
MATA.

I ur 0,1 M pacrnopaHarpr,u rr.rocynbSara 2,783irarKBrOj. coorBercrByer 010167 pacrnop KaJrr{rdporvrara. u. pacrBopKanrafl M 0,1 6porr,rara. pacrBopa 2,7889r KaJrr{r PO pacrnopsror BoAe AoBoArr B r{ 6ponrara o6sena noAofiAo 1 0 0 0 , 0 1 rn . pacrBopatllpu6ant:.aror MJrBoAbr. Vcmauoerca mumpa.K 20,0 Mn nonyqeHHoro 40 yKa3aHo ycraHoBKe rrpr4 rr4Tpa 0,033M pacrnopa rarzx 6po,{anee[ocryrarcT, KaK
MATA.

1 u.u0,1 M pacrnopaHarpr,rfl rvocynbQara coorBercrByer 2,783rrlr KBrOj. 010083 pacrnop Karrrrfl6po*rara M 250,0rvrn 0,033M pacrnopalrrarrvlfl.6povrara 1000,0un. AoBoArrnoAofiAo o6renaa Vcmauoexa mumpo.K 40,0 Mn ronyqeHHoropacrBopaAo6asrsror 20 rvrn BoAbr. yKa3aHo ycraHoBKe rrprr rrrrpa 0,033M pacrnoparanux 6polanee noclvraror, KaK
MATA.

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1 rran M pacrnopanarpvrfl, 0,1 ruocyrrQara coorBercrByer 2,783rrar KBrO3. 1 M pacrnop KaJrrrfl rrrApoKcrrAa pacrBopruor BoAe, 60 r rcarur rr{ApoKcr4Aa B ceo6oAHofi yrnepoAa or A[oKcr.rAa,u AoBoArr o6reu pacrBopa yuepoAa Ar{oKcr4Aa, 1000,0ul. rogofi, ceo6oAHofi or ao pacrBopalruvrs rr,rApoKcr,rAa Vcmauoerca mumpa.20,0l,rnnplrroroBneHHoro rr.rrpyror I M pacreopoM xJropr{croBo4opo4nofi Kr.rcJrorhr, r{cnon*yr B KaqecrBe uHAuKaropa 0,5 ur 0,I yopacrBopa SeHonQra-nevHa. l iranI M pacrnopaxJroprcroBoAopoAsofi rucrorbr coorBercrByer56,11rrarKOH.
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0rl M pacrBop KaJrHflrnApoKclrAa pacrBoptror B BoAe,cso6oAHofi or yrnepoAa AIroKcvAu rr [o6 r rcalus rr4ApoKcrrAa BoArr o6reu pacrBopa reM xe pacrBopl{TeJleM 1000,0 un. Ao rllTpyror rr4ApoKcuAa Vcmauoercamumpa. 2 0,0 vrn nplrroroBneHHoro p acrBopa lralrvIfl. 0,1 M pacrBopoM xnopncroBoAopoAHoftrucnorur, ucnoJlb3ysB KaqecrBeI.IHAUKa:ropa 0,5 vlrt 0, I o/opacrnopa $enonQraleuHa. rncrorbl coorBercrByer 5,611 rvlrKOH. I rvrn M pacraopa xnopr{croBoAopoAHofi 0,1 0r5 M pacrBop Karrlrfl rrrApoKclrAa B crlrpre 60 oh (o6lo6) or pacrBoprlor B crrr{pre 60 % (o6lo6), cso6oAHoM anbAerl43 r xa.nuqrr4ApoKcr.r.qa o6reu pacrBopa reM )KepacrBopr{reneMAo 100,0 un. AoB,rr AoBoA.rrr pacrBopaKaIrufl. B rI{ApoKcI{Aa crltlpre mumpa.20,0 un npuroroBneHHoro Ycmauoerca LlcroJlb3yt 60 % (o6lo6) rurpyror 0,5 M pacrBopoMxnopr{croBo4opognofiKrrcJlorbl, r4HArrKaropa ur 0,1o pacrBopaQeHolQrarevIHa. 0,5 B KaqecrBe rucrorbl coorBercrByer 28,06 rvrrKOH. 1 vrn 0,5 M pacrnopa xnopucroBoAopoAHofi eAKoI'o c[up0r5 M pacrBop KaJrrrflrrrAponcrrAa c[nprossIfi. 0,5 M pacrBop KaJII{ ronufi. r.r pacrBop*or s 5 Mn BoAbr AoBoAtr o6reu pacrBopa crl4p3 r ranns rrrApoKcrrAa oh, cso6ohHbrMor anbAeruAon,4o 100,0 un. rou 96 pacrBopa KaIwIfl. cnuprrrApoKcrrAa mumpa. 20,0 lln npr4r'oroBneHHofo Vcmauoerca tlclonb3yt B KaxnoprrcroBo4opognofiKI{cJrorbI, ToBororr.rrpyror 0,5 M pacrBopoNr qecrBer{HArrKaropa lrr 0,1oA pacrBopaQenonQraJreuHa. 0,5 xucnorbr coorBercrByer 28,06 ur KOH. 1 un 0,5 M pacreopa xnoplrcroBoAopoAHofi eAKorocnup0rl M pacrBop KaJrrrflrr{ApoKcuAa cn}rprosrrfi. 0,1 M pacrBop Ki}JIIa rosrrfi. cnocnlrproBoro AoBoAtr crrnprov,96 %o, 20,0 un 0,5 M pacrBopa Karwrrrr4ApoKcuAa o6reva 100,0na.u. 6oAnnlr or aJrbAeruAoB,.{o mumpa.20,0 lrn ronyrleHHoropacrBoparl{rpyrot 0,1 M pacrnopoM Vcmauoerca 0,5 B ucrroJrb3yt KaqecrBeI4HA}rKaropa vn 0,1 o/o r<ucnorbr, xnopr{croBoAopoAHofi pacrBopa SeHonQraJrerrHa. c I un 0,1 M pacrBopa xnopr{crono4opo4Hofi Kr4cJrorbr oorBercrByer K 5,61I rvrr OH. 0101M pacrBop KaJrrrflrltApoKclrga cnupronufi rr4ApoKcrrAa cnrrproBoro AoBoAtr crlnprow96 o/o,cno2,0 vn 0,5 M pacrBopa Karrvtfl. 6oAsun or anbAerlrAoB, o6relta 100,0 un. Ao 0rl M pacrBop KaJrrrflrugpoQraJlara 20,42 | KaJrurrrE4po$ranara PO pacrBopnor s 800 Mn yKcycHofi rucloru 6esnognofi, noly.reHHHfi pacrBop HarpeBalorHa BoAtHofi 6ane Ao pacrBopeHvs,,3aqnlllat or Aeficrunfl, r.rarv. OxraxAaror Ao reMleparypbl 20 "C I'I AoBoAqr o6reu pacrBopa yxcycuofi xucrorofi 6essoAHofi.qo 1000,0 nan. 6uxpouara. 010167M pacrnop KaJIHflAuxpoMara. 0,1 H. pacrBop KaJILIx 4,90 r Kalftrs,Ar4xpoMarapacrBoptlor B BoAe I{ AoBoAtr o6reu pacrBopa soAofi

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nan. ao 1000,0
pacrBopa rralr,ulfl. mumpa. K 20,0 MJrnpr4roroBJreHHoro Vcmauoerca AuxpoMara npv7,3 o , 6ausrcr 1 r xalus ito1u1a, T narxropucroBoAopoAnoilxucrorbl pa3BeAeHHofi 250 rr,tnBoAbr 14rr{rpy}or 0,1 M pacrnopoM Harpr4t rl4ocyJlrSara Ao nepexoAa

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oKpacKuor cprHefi cBerno-3eneHofi, K ucnonb3yr B KaqecrBe lrHArdKaropa ur 0,1o 3 pacTBopa KpaxMana. 1 ru 0,1 M pacrnopaHurprrfl rvocyrs$ara coorBercrByer 4,903 ur K2Cr2O7. 0,05 M pacrBop Karnq fioAara 10,7 r Kalrufl fio4ara pacrBoprrcT B BoAe r{ AoBoAf,r o6seru pacrBopa soAofi ao 1000,0nrn. Ycmauoercamumpa. 25,0 rvr.n [prrroroBneHHoro pacrBopa Karwffi, ftogala AoBoArr no4ofi Ao o6reua 100,0 rrnn. 20,0 un [onyrreHHoro pacrBopa upu6aBJrrror 2 r K KaIfirA i,toLuI.a, 10 vrn cepHofi KrrcJrorbrpa3BeAeHHofi o/o,u lurpyror 0,1 M pa9,8 crBopoM laurprrflruocynrQara, r{cloJrb3ysB KaqecrBexHArrKaropa1 rr,rr0,1 %opacrBopa KpaxMulna. IrlHAnrarop npu6annrrcT B KoHrIerr{TpoBaHrrr. 1 ur 0,1 M pacrnopanarprrr rzocyrrSara coorBercrByer 3,567 rrarKIO3. 010167M pacrnop KaJ'rr{fl fioAara. 0,1 u. pacrBop lrarwir,,fiogara. 3,567 | Karufl. i'torara pacrBopxrcT B BoAe n AoBoA.f,ro6rervr pacrBopa noAofi

nrn. ao 1000,0
Vcmauoerca noMerrlaror mumpa. 20,0 un npuroroBneHHoropacrBopa Karwir,,ito4ara n xon6y c npnreprofi npo6xoir,, npudawrqror 100 run BoAbr,25 wl cepnofi Kr{cJrorbr ptBBeAeHHofi o/o,2 r :rrarrvrfl, 9,8 itorup.a u ocraBJlrror Ha 10 rraunB 3arquqeHHoMor ruocynr$ara, cBera Mecre. Bu4enneruui'rcx fiog rr{Tpyror 0,1 M pacrBopoM Harpvrfl Hcrronb3yrB Kar{ecrBe r{HAr.rKaropalrrt 0,1oh pacrBopa KpaxMana. 1 I{n4rararop rpr6anr.f,Ior B KoHrIerr4TpoBaHrrr. 1 un 0,1 M pacrnopaHarpvfl ruocynr$ara coorBercrByer3,567lar KIO3. XpaHrr B cocyAax reMHoro creKna c npr4Teprulru npo6KaMrrB 3arrIr4rIeHHoM or MecTe. cBeTa 01001M pacrnop KaJrrrfl iroiluila 10,0 rranpacrBopa :rtarwffi. itolu4a 166 rlt AoBoAsr soAofi Ao o6relra 100,0 rvrn. 5,0 rur nonyqeHHoro pacrBopa AoBoAxrno4ofi Ao o6reua 500,0 un. 0002M pacrBop KaJrnfl rrepMaHraHara. 0,1 n. pacrBop KarruflnepMaHraHara. pacrBoprrcT B BoAer{ AoBoArr o6reu pacrBopa no4ofi 4o 3,2 r rcalnu-f, nepMaHraHara 1000,0 Mn; ronyqenurrfi pacrBop HarpeBarorHa BoArHofi 6ase B TeqeHVe1 v, oxnaxAaror u Qnnrrpyror qepe3creKJrrHHbrfi Sunrrp. pacrBopa lraJrvrs, Vcmauoerca mumpa. K 20,0 Mn rrpr4roroBJreHHoro ilepMaHraHaranpupa3BeAeHHofi o/ou rurpytor 6aerqlor 2 r rcatus irogwga, 10 rran cepuofi Kr{cJrorbr 9,8 0,1 M pacrBopoM laarpprfr ruocynrQara, r.rcrroJrb3yr KaqecrBer4H.qr4Karopanrn B 1 0,1yo pacrBopa KpaxMana. I4nAurarop npu6annrlor B KoHueril-tpoBaHvfl,. 1 un 0,1 M pacrnopa rr4ocyJrb$ara uarpu{ coorBercrByer 3,161ur KMnOa. Tvrp ycraHaBJrltBaror HenocpeAcrBeHHo rrepeArrcrroJrb3oBaHr{eM. Xpanxr B 3arrluqeHHoM cBera Mecre. or 0r1 M pacrBop Jrrrrrrfl MernJrara. 0,1 M pacrBop rrLrrufl MeroKcuAa. pacrBop.xrors 150 Mn MeraHora 6essoAHoro 0,694 | rvffvtfl.se6onrruraMr.r nopqurMu pacrBopa ronyonoM lo 1000,0 rrar. t4AoBoArr o6reru Ycmauoexamumpa. K 10,0 Mn ArrMerrrn$opvralauganpn6amr.f,ror rr,rn Yopa0,05 0,3 paCTBOpOM TT4MOJTOBOTO B MeTaHOne TrITpyrOT r{ npr{rOTOBJreHHbrM cTBOpa Cr.rHerO IrkrrvrflMer[Jrara,uo nonyqeHr.rr cvHero oKparlrrBannfl.pacrBopa. HerraeAneHHo rrpr46aersror 0,200 r 6engofinofi xucrorrr PO, nepeMerrrr4Baror pacrBopenilfl. Lr Ao

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28.3ax.2768

pacTBopoMrrvrTvtfl. MeTprJraTa noBTopHofo rlonyr{e}{vfl, Tr{TpyroTnpr.rfoToBJreHHbrM Ao pacrBopa. Bo BpeMr TxTpoBaHrrrpacTBop 3alrll{ilIarcT or arctrHefo oKparrrr4BaHlrr ycTaHaBnLIBaroT MeTnJIaTa yrJrepoAa.4r4oKcr{Aa. TIITp pacTBopa ilrrTr4fl. MOCoepHOTO TI{TpoBaHvwI. B r43pacxoAoBaHHoro rIoBTopHoM lro o65eMy TvrrpaETa, MerLIJIara coorBercryyer 12,21rrarC7H6O2. I rvrn M pacrnopa rrr4wIfl 0,1 rlepeALIcrIoJIb3oBaHI4eM. HelocpeAcrBeHHo Turp ycraHaBnrrBalor 0105M pacrBop MarHufl cy;rrQara 12,5 r MarHr4qcynrSara pacrBoprlor B AocraroqHoM KoruilecrBe BoAbIrr AoBoAflT o6renr pacrBopauogofi ao 1000,0vrn. mumpa.40,0 un ronyqeHHoro pacrBopa AoBoAxr eo,qofiAo o6renta Ycmaruoexa 300 rran. flpu6anrrxror 10 MrI aMMoHufiuoro 6yQepa pH 10,0 u 50 rrarrptrrypalquu qepHoro. Harpenaror ao 40 oC H rurpylor rlpu erofi reuueparype 0,1 M opr4oxpoMa pacrBopoM Harpus.3AeraraAo nepexoAaoKpacKuor Suolerosoft r cuHefi. oAerara coorBercryyer 24,65 narMgSOa '7H2O. 1 un 0,1 M pacrnopaHarpvrfl, 0r1 M pacrBop MarHHfl xJIoprIAa 20,33 | MarHuq xnoplrAa pacrBopttor B BoAe I4 AoBoAflTo6reu pacrBopa soAofi ao 1000.0nrr. soAofi ao 300 nrn.flpunonyqeHHoropacrBopaAoBoA-f,r mumpa.25,0 wur Vcmauoerca t{epauuonuilnoro 6y$epa pH 10,0 u 50 ur rplrrypalll4Ir opr{oxpoMa 6aensror 10 rran oC ra rurpyror rpr erofi renneparype 0,1 M pacrBopoM Horo. Harpenaror ao 40 gAerara Ao [epexoAa oKpacKu or Szoneroeofi r cnnefi. laarpurfl 1 ur 0,1 M pacrnopa Harpl{t e.rerara coorBercrvyer 20,33 ur MgC12 ' 6H2O. 0002M pacrBop MeArrcy"urQara 5,0 r MeAr{ cynrQara pacrBoptrcT B BoAe 14 AoBoAflr o6rerra pacrBopa soAofi

,i

un. ao 1000,0
mumpa. K 20,0 Mn ronyqeHHofo pacrBopa MeAIrcynrSara npu6aunor Ycmauoerca rr 2 r uarpux auerara, 0,1 ur 0,1o pacrBopa nvrpur4vna3onaSrona rl4rpyror 0,02 M pacrBopoM :r^arpvfl3Aerara Ao rrepexoAaoKpacKu or QuoneroBo-cllHefi Ao tpKoeHHo. crl4 seleno fi ; n6rusu roq KI4gKBI4BaneHTHo TI{TpyIor MeAn 1 un 0,02 M pacrnopaHarprrfl.3AeraracoorBercrvyer 4,994 rvrrCuSOa' 5H2O. 0rl M pacrBop Harpnfl apceHrra 20 PO 4,946 r Mbrrrb.f,Ka oKcr{Aa pacrropmor B cMecr.r u.n 10 M pacrBopa Harpvls.rr4BoAbr, AoBoArr o6renr pacrBopa nolofi ao 400,0 un n nefirpanlaApoKc[Aa n 20 rvtn T,3 3yror xnop[croBo4opo4nofi rzcrorofi pa3BeAeHHoit oh to naKMycoBofi6yuare. PacrnoprrcT B ronyqeHHoM pacrBope 2 r uarpux rz4poxap6oHara I{ AoBoAtr o6relt pacrBopa nogofi lo 500,0 un. 0,001 M pacrnop Harprrfl AoAerlllJlcy.nrQara 0,2884 r Harpus AoAerlr4ncyrrQara, B flepecqere Ha BbrcyilreHHoeBelrlecrBo (105 'C B reqenr{e 2 u), pacrBoprlor B BoAe I{ AoBoAtr o6reu pacrBopa soAofi ao 1000.0vrn. Vcmauoercamumpa. K 50 un ronyqeHHoro pacrBopa npu6aBJltlor 15 nanxnopoSopna, 10 un 1 M pacrnopa cepHofi rucnoru u I ul pacrBopa, corepxauero no 0,003 Yo AwxrerunoBofoxeJrroro r4 oparleroBoro crrHero B xnopoQopue. Tnrpyror 0,004 M pacrnopola 6eHssroHr,rrxnopvp.anpkr sHeprntlHoM BcrptxuBanr4vIrI pirAe[ocJre Ka]Kroro Ao6asreHnr rlrrpaHTa Ao rex nop, rloKa xnopo$opunrrfi ileHvtucJroeB @

cnofi He nplro6perer rrocroflHHbrfi (Her4cqe3aroqufi)senenrrfi rlBer. I rvrn 0,004 M pacrnopa 6enseroHnrxropurra coorBercrByer 1,154 irarC12H25NaOaS. 1 M pacrnop Harpufl rrrApoKcrraa. I M pacrBop Harpa eAKoro. 42 r uarpu.rrrr,rApoKcvp.apacrBop-sror BoAe,ceo6oAHofi or yrnepoAa rvroncvp.q vr B AoBoArr o6renr pacrBopa noAofi lo 1000,0 rr,u. rvrnI M pacrropa xnopucroBoAopoAIlpoeepxa ua codeptrcaruue rcap6oHamo6.45,0 uofi xncnorbr rr4Tpyror npxroroBJreuHhrMpacrBopoM :aarpvfl.rlrApoKcprAa(nuguxa1 rop - QenonSraneun). K orrurpoBaHHoMy pacrBopy npn6aumor no KanJr-rN.{M pacrBop xJropr{croBo4opo4nofiKr4cJrorbr r,rcqe3HoBeHrrr po3oBoro oKpallrr4BanvrflvI Ao - 20 tvri'. npoqecce KrrrrrrreHufl,npkr po3oBoro Bo3Hr{KHoBeHVr4 Krrnrrrr Ao o6reua B oKparrrrrBauuxtpu6aBJr*or 1 M pacrrop xnopr4croBoAopoAHofirncnorbr Ao o6ecrlBetrnBaHrlx.Pacreop oxnaxAaror vr, rrpu Harvrrtrurpo:orofi oKpacKZ, upv6auxrcr roI M pacrnop xnopucroBoAopoAsofi rucrorbr Ao o6ecqneuuBaHns.. Cyrvrrr,rapnoe npu6aueHuoro 1 M pacrropa xnopr{croBoAopoAHofi rucnorbr He AoJIxHo Jrr{qecrBo rrpeBbrruarr0,1 un. rr4VcmaHoerca mumpa (l). 20,0 rranI M pacrBopa xJropr4croBolopolnofi KncJrorbr pacTBopoMHaTpr4s v}{!JvtIKaTpyroTnonyqeHHbrM llrApoKcv4uucnorb3ys B KaqecTBe ropa 0,5-1 lrr 0,1 %opacryopa$euorQraneulaa. 1 un 1 M pacrropa xnopktcroBoAopogHofi xncrorbr coorBercrByer 40,00 ur NaOH. ru4po$ra.nara PO, npeAVcmauoerca mumpa (2). Oxoro 5 r (rounax Hanecra) :r.larwrr,, Bapr{TeJrbHo roHKo r43MerbrreHHoro BbrcyilreHHoroilpr{ TeMneparype 120 oC s teu pacrBopoM Harpa rreHve2 u,pacryopmor s 75 N,rrBoAbrrr rr4Tpyror npr4roroBneHHbrM eAKoro(uHgNrarop QeHonQraneran). 1 un 1 M pacrnopalaarpvrfl, rr4ApoKcr.rAa coorBercrByer 204,22 rvrrCgH5KOa. Turp ycraHaBnzBarorHerrocpeAcrBeHHo nepeA ucnonb3oBaHlleM. 0r5 M pacrBop Harprfl rrrlpoKcr{ga. 0,5 M pacrnop Harpa eAKoro. pacrBopr}or B BoAe,cso6oAHofi or FnepoAa A}roKclr.ua,kr 2I r nurpufl rr{ApoKcrrAa EoBoArr o6rervrpacrBopa rofi xe eoAofi ao 1000,0 un. Ilpoeeprcaua codepcrcauue rcap6oHamo*. flpono4xr, KaKorrucaHonpr4rrprrroroBneHr4l.I 1 M pacrnopa Harpr.rrrrlApoKcuga.fitrx onpeAeneHux6epyr45,0 ur 0,5 M pacrBopa xnopr4croBo4opo4uofi Kr4cJrorbr. Ycmauoerca mumpa (1). 10,0 ur 0,5 M pacrnopa xnopr{croBolopoAHofirucnorbl rrrTpyror, KaKyKa3aHonpv onpegeneHukrtrrcpa I M pacrnopa Harpr{s rt4ApoKcr4Aa. 1 un 0,5 M pacrnopa xnoprrcroBoAopoAHofirzcrorbr coorBercrByer 20,00 rur NaOH. Vcmauoexamumpa (2). Orono 2,5 r (rovHar Hanecra) Kanl4t rn4poQrarara PO, u roHKo r43MerbqeHHoro BbrcyureHHororrpr reMrreparype 120 oC s IrpeABapr{TeJrbHo TeqeHue2 u, pacryoprror n 50 rr,rn Borbr. .{anee ilocry[arcT, KaKyKa3aHonpn ycraHoBKerurrpa I M pacrnopa Harpr4r rn.{poKcr{Aa. 1 rr,rn M pacrnopalr.urpurfl rr{ApoKcr,rAa coorBercrByer 102,11 rr,rr 0,5 C8H5KO+. 001M pacrBop Harprrfl ruApoKcrrAa. 0,1 M pacrnop Harpa eAKoro. 100,0 rvrnI M pacrBopa Harpkrfl rr4ApoKcr4Aa AoBo.qtrno4ofi, ceo6oAHofior yurepoAa AvroKcvrha, o6rerr,ra1000,0 u.n. Ao Ilpoeepxa ua codepcrcauue xap6oHamo* llpono4xr, KaKoflucaHo rrpr4rrprrroroBneHlau 1 M pacrnopa Harprd-f, rr4ApoKcuga. filt onpeAeneHun6epyr 45 run 0,1 M pacrBopa xnopr4croBo4opo4HofiKr.rcJrorbr.

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EyQepnufi pacrBop, KaKrrpaBrrJro, rrpeAcraBJrrerco6ofi cMecb cna6ofi Kr.rcJrorbr l.t.rtn cna6oro ocHoBauvrs, co6crseHHofi conrro; pH rarofi cMecv MaJro c MeHrercq [pr4 pa:6arneur4r4 AoBonbHo B rrrktpoKrrx [peAenax (1:100), a raKx(e npu 4o6arJreHlrr4 He6onrruoro KoJrr.rtre ceo6o.uHofirucror br wwr rueroqx. crBa EyQepnufi pacrBop xapaKrepu3yercr 6y$epnofi eMKocrblo, ro ecrb KoJurqecrBoM BeIIIecrBa,Koropoe Moxer 6rrrr Ao6asreHo K pacrBopy, He Bbr3brBar 3Haqr,rreJrbHoro rr3MeHeHprr aKTr.rBHocrrr rloHa. Ey$epHax eMKocrb onpe.qeJrrercr KaKorHorrreHrre Ko(n rparr,ru-eKBr,rBaJreHTaxlaa rlrqecrBa Ao6aerseN,rbrx Kr.rcJrorbrvtrv ocHoBaHlrr I nnrp) pH K rr3MeHeHlrro BeJrr.rqlrHu (n e4nnnqax pH). Euxocru 6y$epnoro pacrBopa perynupyercs KoHrleHrpaquefi 6yQepHrrx BerrlecrB. Ey$epnue pacrBopbr Hcnonb3yrorcfl. ArrflycraHoBneHvrs. roAAep)Kaur.r.f, v aKrrlBHocrr.{rroHaB y3KoM4lranasouepH. Halr6olee o6ruve 6y$epuue cr{creMbrr.rcnonb3yrorcr: a) anr ycraHoRnenvfi. aKTvrBHocrr4 HoHaBoAopoAanpr rarN6poBKe pH-rraerpa; 6) n ananurr.rrrecKrrx MeroAHKax; n) n npuroroBJreHr4ra neKapcrBeHHbrx rr3oroHuqHocrrr; Aocrr,rxeHu.r{ Qop* An-f, p r) 4nx rroAAepxa:eus, a6uJrbHo Ao3rr oBalrHbrxneKap cr cln crBeHHbrxSopu. qerefi xuMr4qecKoro KounoHenrrr 6yQepHoii clrcreubr An.rr aHaJrrl3a AoJrxHbrcotleTaTbctc onpeAeJrseMbrM peaKTHBaMu. BerrIecTBoM r{cnoilb3yeMbiMl{ H 3a6y0epennrrfi arleroHoBrrfr pacreop pacrBopqrcr B BoAe,npirdan;r-aror nan 8,15 r Harpur auerara u 42 r Harprls xnopr4Aa 68 pacrBopa xJropr4croBo4opo4Hofi 0,i M Kr.rcJrorbr, un arleroHa r4rIoBoA.f,T 150 o6relr pacrBopa no4ofi ao 500,0 u.rr. BySepurrfi pacrnop pH 2,0 6,57 r Karrvts. xnopr4AapacrBop*or B BoAe,npn6auxror 119,0 uri 0,1 M pacmopa xnoprrcroBo4opo.qHofi Kucnorbr prlloBo.{rr o6ren pacrBopa no4ofi ao 1000,0 prn. OocQarnrrft 6yQepuufi pacreop pH 2,0 8,95 r Arrarptrfl" rz4po$oc$ara u 3,40 r KaJrrrrguru4poSocQara pacrBop t l o r B B o A er { A o B o A r r o 6 r e u p a c r B o p a n o A o i i a o 1 0 0 0 , 0 u l . l o n o g r r p H c lo 2,4 rloreHlrr{oMerpuqecKr{ rroMorrlbro $oc$opHofi xnclorbr KoHueHTpr4ponaHuofi. CynrQarnrrfi SySepnufi pacrnop pH 2.0 I32,I r aMMoHlr-tr cynr$ara pacrBop*or B BoAe,AoBoAqro6teu pacrBopa noAofi Io 500,0 un (pacrnop I). Ocropoxno npu nocrofiHHoM oxJiaxnetvtr H rrepeMeilivrBall-r4rl npu6auxror l4 un cepHoft KrrcJrorbr KoHueHTpr,rpoBaHHofi n 400 Mn Bolbr; oxna)KAaror Aorr pacrBopa eoAofi ao 500,0 iral (pacrnop II). BoAqr o6r,eu paBHhre Cnaeruuearcr o6reuu pacrBopoB I ra II; ecilu seo6xoAr.rMo, AoBoArr pH ao 2,0 noreHql4oMerpurre cKr4. EyQepHufi pacrnop pH 2,5 grarugpo$ocSara pacrBop.f,rors 800 MJrBoAbr,AoBoA-f,r go 2,5 100 r Kailufl, pH noreHlrr{oMerpuqecKr4 rroMorrlb}o c xnopr4croBoAopo4nofiKLrcJrorbr KoHueHTpr4ponauHofi r4AoBoArr o6reu pacrBopa soAoii ao 1000,0 rral.

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pH ao 2,5 noreuqr4oMerplrqecKn noMorubro pacrBopaHarpufl. pa3BernApoKcrrAa c pacrBopa noAofi.qo 500,0un. ,teHnoro8,5 yo rr AoBoArro6rervr EyQepHufi pacrnop pH 3,0 pacrBoprrcr s 200 run 1 M pacrBopaHarpilfl. 21,0 r rnuonnofi Kr.rcrrorbr rprApoKct4Aa H AoBoAflr o6reiupacrBopa soAofiao 1000,0nrn. 40,3 un noryqeHHoropacrBopaAoBoArr0,1 M pacrropoMxnoprcroBoAopoAnofi KucJrorbr 100,0rran. lo 0,25M urrrparHbrfi dy$epurrfi pacrnop pH 3,0 pacrBopqrcrs 80 Mn BoAbr. 4,8 r nrrraonnofi Kr.rcJrorbr AosoArr pH ao 3,0 noreHuuo\{erpr,rqecKr4 noMorrlrro I M pacrBopaHarpvrs c rrlApoKcr{Aa .{oBoAxro6reru par,r crBopa eo4ofilo 100,0nrn. M QocQarHrrfi dyQepnrrfi pacrnop pH 3,0 0,1 pacrBoprrorB BoAe. 12,0r laarpvfl 6esnoAHoro 4urra4poSoc$ara ,{osoAmpH 4o 3,0 roreHunoMerpuqecKra I0 c rroMorrrbro $oc$opsofi xucrorbr piuBeAennofi % u AoBo.urr o6reu pacrBopa soAofiao 1000,0rrar. OocQarHufi 6yQepnrrfi pacrnop pH 3,0 rr 0,7 ur SocSopnorixucnoru roHrleHTpr4ponanuofi cMerrrr.rBaror MJr c 100 BoAbr AopacrBopa BoArro6seMpacrBopa soAofiAo 900 rran. lono4xr pH Ao 3,0 c noMorrlbro pacrBopaeolofi Ao Harpvfl rr4ApoKcrrAa u AoBoA{T KoHrleHTpr,rpoBaHHoro o6rerra 1000,0 un. (DocQarnufi 6yQepurrfi pacrnop pH 3,0 (1) grarr,r4po$ocQara pacrBopflror 900 Mn BoAbl. e 3,40r lrairufl. lono4rr pH ao 3,0 noreHrlr{oMerpnqecKr4 KoHrleHrpr.rpoBaHHofi H Aosoc rloMoulbrc SocSopnofirr.rcrorbr noAofiao 1000,0vrn. :.sr o6reu pacrBopa (DocQarnufi 6yQepnufi pacrnop pH 3,2 2,5 900 un 4 rln pacrBopa Harpvfl.1.trrnrpo$ocQara cMerxrrBaror 100 wrut rlrr pac EcrH crBopa$oc$opuofi rucnorur KoHrleHTpr{ponannofi. seo6xoAurvro, 4ono4xrpH lo 3,2 noreHrlr4oMerpr,rqecKu. @ocQarnrrfi dyQepHrrfipacrnop pH 3,,2(1) rlrApoAnr AosoAsrpH ao 3,2 noreriqrloMerpuqecKlt 35,8 r/n pacrBopaArrna'rpvfl pa3BeAeHHofi %. c xuc;rorbr I0 QocQara roMoulbrcQoc$opHofi pacrBopa 100,0Mn ronyqeHHoro AoBoArrsoAofiao 2000,0nar. FyQepHufi pacrnop pH 3,5 25,Ar aMMoHru BoAbr, npu6auxror 38,0vn 25 ohxnoarlerarapacrBoprrcrs 25 MJr pr,rcroBoAopo4Hofi pH KrrcJlorbr. Eclu ueo6xoAlruo, AoBoArr ao 3,5 norenur4oMerprrqecKr4 rroMoulbro pa3BeAeHHoit YouttupacrBopa c xJroprrcroBogopo4nofi Kr{cJrorbr T,3 p$BeAeHHoro Yo u 4or'o,4gr eo4ofilo 100,0rr,rn. aMMrraKa 17,5 o6reu pacrBopa pacrnop pH 3,5 OocQarnufi dyQepHrrfi pacrBoprrcrB BoAe, 68,0r Karrws.4raru4po$oc$ara soAofi AoBoArro6ren pacrBopa c rroMorrluo ao 1000,0un. [onogar pH Ao 3,5 rroreHrlr4oMerpur{ecKrr QocSopuofi Kr,rcnorbr KoHrleHTprrponanuofi . pacrnop pH 3,6 EyQepnufi 250,0wrt 0,2 M pacrnopaKarrufl rngpoQraJrara cMerrrr{Baror1I,94 rwr0,2 M pacc TBopa xnopr{croBo4opo4Hofi Kr{cnorbr vt AoBoArr o6reu pacrBopa solofi rran. ao 1000.0 itE

EyQepnufi pacrnop pH 3,7 15,0 un 30 % yxcycrofi KrtcJrorbr cMerrrvBalorc 60 Mn crrr4pra96 % u 20 vl BoAbr. r4 ,{ono4xr pH Ao 3,7 norenqvoMerpr{qecKrrc rroMorrlbro17,5 yo pacrBopa aMMr{aKa AoBoArr o6renapacrBopa eoAofi lo 100,0 vrn. 3adyQepennrrfi pacrBop MeArrcynrQara pH 4,0 0,25 r ueaz(Il) cyrr$ara u 4,5 r aMMoHr4r arlerara pacrBoprrcr B yKcycHofixzcnore oh u piBBeAeHH 12 oir Ao [osorqr o6reN{pacrBopa reM xcepacrBopr{TeJreM 100,0 nrn. Auerarnufi 6yQepurrfi pacrnop pH 404 136 r laarptrfl. arlerara u 77 r aMMoHr,rr arlerara pacrBopsrcT B BoAerr AoBoArr o6rena pacrBopa soAofi ao 1000,0 ur; 4o6arJrrror 250,0 Mn yKcycHofi xvcnoru reAxsofi u nepeMerxuBaroT. (Dra.rrarnufi 6y$epuufi pacrnop pH 404 2,042 | Karwffi, rn4po$raJrara pacrBoprror s 50 rar BoAbr, npn6aalxror 7,5 un 0,2M pacrBopa Harpkrfl, rr{ApoKcnAa AoBoArr no4ofi Ao o6reva 200,0 vrn. r{ 0,05 M QocQarnufi 6yQepHrrfi pacrnop pH 4,5 pacrBopnor e 1000,0 MJrBoAbr. 6,80 r Karrvrfl,4urv4po$ocQara Auerarnufi 6yQepHufi pacrnop pH 4,5 77,I r aMMoHr.rr arlerara pacrBoprlor B BoAe,go6anrxrcr 70 rr,rryxcycHofi KncJrorbr neAqnofi r.{AoBoArr o6renr pacrBopa no4ofi ao 1000,0 nan. Harpnr arlerarHbrfi 6yQepHufi pacrnop pH 4,5 pacrBopsror B BoAe,upu6annxror 90 nanyxcycnofi 63 r narpufl arJerara 6egeo.qHoro pa3BeAeHHofi %o.Eonoxxr pH ao 4,5 noreHunoMerprrrecKrrr{ AoBoArr KI4cJIorbr 30 o6revr pacrBopa no.qofilo 1000,0 mn. AqerarHufi 6yQepHufi pacrnop pH 4,6 5,4 r Harpvfl a\era'ra pacrBoprror B 50 rran BoAbr,npn6auxrcr 2,4 r yncycuofi rucJrorbrreA-f,Hofr AoBoArr o6reu pacrBopa no4ofi ao 100,0 Mn; ecnr4neo6xo4zuo, rr AoBoArr pH ao 4,6 noreuqvoMerpr4rrecKr,r. CyxqnnarHufi 6yQepHufi pacrBop pH 4,6 11,8 r rurapHofi Kvcnorhr pacrBoprrcr B cMecr4 600 rran BoAbr 82 put I M pacrnopa u Harpufl i'r{ApoKcr4Aa AoBoArr o6reu pacrBopa noAofi ao 1000,0 un. rr AqerarHrrfi 6yQepnufi pacrnop pH 4,7 136,1 r Harpr,rrarlerara pacrBopqrcr e 500 Mn BoAbr.250 nannonyqeHHoro pacrBopa cMerrrrrBaror 250 Mn yKcycHofi rvcnorbr pa3BeAesuofi12 %. Bcrprxuc Balor ABaxAbr co cBelr(eilpuroroBneHHbrM or$ranrrpoBaHHbrM0,1 r/n pacrBopoM n AI4TX3oHa xnopoSopnae.Bcrpqxr4Baror c yrnepoAa rerpaxnopr{AoM ,uo o6ecqne.ruBalllas. gKcrpaKTa.BoAHrrfi cnofi $nnbrpyror rrr yraileHrrr cneAoB yrnepoAa TeTpaxnopr{Aa. Aqerarnufi OyQepHufi pacrnop pH 5,0 120 vn 6 rltpacrBopa yKcycnofi Kr.rcJrorhr neAsHofi cMerrrr.rBaror 100 un 0,1 M co yut BoAbr,nepeMerrruBaror. pacrBopa Karwtr,. rurApoKcr{Ia v c 250 Aoso.qrr pH ao 5,0 lorenquoMerpnrrecKr4 c rroMorrlbro 6 rl:l pacrBopa yKcycnofi KncJrorbr ilerflrtoirutru 0,1 M pacrBopa Karrvtfl, rrrApoKct4Aa AoBogxr o6reu pacrBopa soAofi Ao r{ 1000,0nan. Ilnrparnrrfi byQepHufi pacrnop pH 5,0 20,1 r nulronnofi KrrcJrorbr 8,0 r Harpufl,rnApoKcr{AapacrBop*or B BoAer{ AoBoArr u

pacrBopa o6rena eoAofi 1000,0 {ono4xr pH 4o 5,0 noreHqr.roMerpnqecKrr un. c roao pa3BeAeHHoir Yo. Morrlbro xnopr4croBo4opo4nofi Kr4cnorbr 7,3 OocQarnsrfi 6yQepuufi pacrnop pH 5,0 pacrBop-rrror800 Mn BoAbr. 2,72 r Kiurrrr4urra4po$oc$ara s ,{ono4xr pH ao 5,0 noTeHIIpIoMerpI4rIecKr4 I c rroMonrbro M pacrBopaKanus, rrrApoKcr4ga AoBoArro6revr 14 pacrBopa soAofi.qo 1000,0 un. ByQepuufi pacrnop pH 5,2 1,02r Kanus. rugpoSranarapacrBopqror 30,0 ul 0,1 M pacrnopaHarpr.rr n rr4.[poKckrlav AoBoA.flr o6reu pacrBopa no4ofilo 100,0un. 0,067M QocQarnufi dyQepnrrfi pacrBop pH 5,4 CvenrunarorcoorBercrByroque o6reuu 23,99 rh pacrnopa 4r4nurprax ru4poQocu 9,12 r In pacrBopaHarpr4fl MoHorr4Apara, uro6rr nonyqurb 4urugpoQocQara $am pH 5,4. lonogxr pH ao 5,4 norenuuoMerprrrrecKrz. EyQepuufi pacrnop pH 5,5 54,4r Harplrt auerarapacrBop.f,ror 50 MJr s BoAbr, ecru ueo6xoAr.rMo, HarpeBaror Io oC.flocne oxnaxAeHr.rr pacrBopa HeMyMeAneHHo TeMrreparypu 35 nonyqeHHofo K rpr.rnr.rBaror MnyKcycHofi 10,0 xracnorrr6esnoAHofi, ueperuenr.rBarcrAoBoAqr 14 o6revr pacrBopa noAofi 100,0un. lo AuerarHo-sAerarHbrfidyQepuufi pacrnop pH 5,5 250 r aMMoHr.rr arleraralr 15 r Harpvrr 3AerarapacrBopqror 400 MJr s BoAbr tpu6anu JItIor 125 vl.ltyxcycnofi Kr,rcJrorbr reA.rsofi. (DocQarHufi6yQepHsrfi pacrnop pH 5,5 gurra4poSocSara pacrBoprrcrB BoAe ,qoBoArr Pacrnopl. 13,6I r KaJrHr par{ o6rerr,r no4ofiao 1000,0 crBopa lrn. gunarpux rz4poSoc@ara pacrBopnor B BoAe AoBoArro6teu PacrnopII. 35,81r r{ pacrBopa no4ofilo 1000,0lrn. CN.reruusarcr MnpacrBopal u 3,6 ur pacrnopaII. 96,4 (DocQaruo-qlrrparHsrfi6yQepuufi pacrnop pH 5,5 56,85 r,rn28,4 r/n pacrnopaAr.rHarprax ru4po$oc$ara 6e:soAHorocMerrrrrBaror c 43,15wt2I r/rt pacrnopanrlMoHHoft rncnorsr. (DocQarnufi 6yQepuufi pacrnop pH 5,8 pa1,19r Aunarpufl rn4poQocQara u 4nrnApana 8,25 | Karrr4.f, 4Hrz4poQocQara crBopqror BoAe AoBoAqr B u soAofiao 1000,0un. o6ren pacrBopa AuerarHufi 6yQepnrrfi pacrnop pH 6,0 100 r aMMoHus arlerarapacrBop*or s 300 MJr BoAbr, npunr{Baror vrn yxcycnofi 4,1 paKrrcJrorbr reAqHofi.Ecrz seo6xoAuruo, AoBoArrpH ao 6,0 c nououlrro 17,5 o/o crBopaaMMlraKa yKcycnofirucrorbr pa3BeAeusofi % 14 l4nr4 30 o6renrpaAoBoAqr crBopano4ofi4o 500,0nn. ,{nrrnnalrMoHnqQoc$ara 6yQepHufipacrBoppH 610 pas6annxrcr 68 un QocQopnofi rncnorrr KoHrleHrpr4ponauHofi no4o[ 4o ocropox{Ho pacrBopacMerrrr4Ba]or450 Mn BoAbr 6 ult Ar4JTuna500 un. 25 v'tt flonyrreHHoro u c pH Ao 6 + 0,05rroreHrlrroMerpr4qecKrr MLIHa. Ecru ueo6xo4ul,ro, c rroMorrlbro AoBoArr gono4xro6relr pavrru n Ar{3rr{JraMvHa Kr.rcJrorbr Qoc$opuofirosrlenrpr{poBaHHofi crBopaeoAofilo 500,0un.

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pacTBopa nurrlonsofi KI4CJIOTbI.

(Doc$arHufi 6yQepusIfipacrnop pH 6,0 (1) soAoil I{ pacrBop{rcrB BoAe AoBoAtro6reu pacrBopa 6,8 r narput Al4rl{Apo$ocsara HapacTBopa c IIoMolUbIo .Uo1000,0un. IonoArr pH 4o 6,0 IIoTeHIII{oMerpI'IqecKI{
rplls r[ApoKcI{Aa KoHIIeHTpIrpoBaHHofo.

OocQarnufi 6yQepurrfi pacrnop pH 6,,0(2) c aflrugpo$oc$ara cMeruI4Balor 28'5 vt 0,2 M pa250,0 ul 0,2 M pacrnopa KaIIvtfl u AoBoArr o6reu pacTBopasoAofi.qo 1000,0 rvrn. HaTpr4flfrr.4poKcrrAa cTBOpa (DocQarHufi byQepnrtfi pacrnop pH 6,4 rugpo$ocsara, 2,5 r Harpvrfl.IuruApo$ocsara u 8,2I Harpl{t 2,5 r Av]Harpvrfl 6,4 xnoplrAa pacrBoptloT B 950 nanBoAbI.Ecnn neo6xoAuMo' AoBoAxr pH Ao I M rroreHlll{oMerpuqecKl4 c noMorqrro 1 M pacrnopa Hurpzlfl'rIIApoKcI{Ia unu pacrBopa xnoprrcroBoAopoAHofi ruclorbl I{ AoBoAtr o6rerr't pacrBopa soAofi a o 1 0 0 0 , 0v r n . (DocQarnrrfi 6yrpepnufi pacrnop pH 614(l) u7,02 f Harpl{fl xno1,36 r Karrl4tAurlr,qpo(bocsara l,J9 r Lv:f{arpvrfl.rur4posocsata, soAofi .qo 1000,0 rr'rl. 14 B pacrBop.rrloT BOAe AoBoArTo6revr paeTBopa pr4Aa 0,5 M Qranarnsrfi 6y$epusrfi pacrnop pH 6'4 pacrBop{ror B BoAeII AoBOAtro6teu pacrBopa soAofi Ao 100 r :Ka]firfl.ru4po$ranara pacrBopaHaTpv1fl' c 1000,0 N,rn. AosoArr pH [o 6,4IIoTeHUI{oMerpuqecKI{ noMolqblo KOHIIeHTpt4poBaHHoro. rrrApoKcl4Aa Ey$epHrrfi pacrnoP PH 6'5 BoAe' 60,5 r Aularpvrfl,ru4po$ocsara u 46,0 r KalIvlfl,guru4posocsara pacrBoptrcr B rI npu6an1rror 100,0 un 0,02 M pacrnopaHaTpltfl 3Aerara,20 rvrrpryru(Il) xnopllAa AoBoAqro6ten pacrBopa eoAofi lo 1000,0 rvrn' (DocQarHsrfi 6yQepnufi pacrnop pH 6'5 2,75 r Harpvrfl4nru4po$ocsara u 4,5 r Hnpr4sxnopllAa pacrBopqrcr s 500 MJIBoAbI' c QocQaruoro 6yQepuofo pa,{ono4xr pH ao 6,5 uoreuqr{oMerpr4qecKr.rrIoMOlIIbro crBopapH 8,5. 0,1 M QocQarHufi dyQepHufi pacrrop pH 6'5 13,80 I Harpl{t gurr4po$oc(para MoHorl4AparapacrBoptlor s 900 Mn BoAbI C IOMOIIIbIO IvtcTvInJlvrponannofi.,{orOgxr PH AO 6,5 nOreuqIIOMeTpI'IqeCKI'I v II4ApoKcI{AaKoHIIeHTpIIpoBaHHoro AoBoAsr o6relt pacrBopa pacTBopa H3p;p1rfl .. nogofi rvrgtvrilvrponaHnofi ao 1000,0 rran. I{MnAasomnrrfi 6yr[epHsrfi pacrBop pH 6'5 cynl$ara pacTBoptlor cynrQara u0,73 r KuUIbIII4q 6,81 r ilMl{Aa3ona,1,23I MarHI4q rucnoru. Ecnu seo6xoAnlro' AoBo1-752ul 0,1 M pacrnopa xnopr{croBoAopoAHofi pacTBopa roAofi vt ;1flT pH Ao 6,5 IIoTeHIII4oMeTpuqecKI'I AoBoAflT o6rerrl ao 1000,0 rr,rl. (DocQarHufi 6yQepnufi pacrrop pH 6'6 c gurra4po$oc$ara cMeIIrI4BaIor 89,0 vn 0,2 M pa250,0 v1 0,2 M pacrnopa Ka;wrfl x HATpvlflfHApoKCr4AaAoBoArr o6reu pacTBopasoAofi ao 1000'0 rvrl. cTBOp\a

Ooc$arHufi ra6yQepeunrrfiQu:lronorn.recxufi pacrBop pH 6,8 u xnopnAa 1,0r ranrx guru4poSoc$ara,2,0 r guxanprsruapo$ocQara 8,5 r lnarprrfl. pH ao 6,8 noreuulroMepacrBopsm s 900 MJrBoAbr. Ecm.rueo6xo4Htuo, AoBoAtr pacrBopa eoAoftao 1000,0un. rpuqecKurr AoBoAflT o6reu OocQarHrrfi 6yQepurrfi pacrnop pH 608 c 77,3 tw Jl,5 rlt pacrBopaLvnarpunrz4po$oc$ara cneuruBaror 22,7 vl2l rlll pacrBopa nuuonnofi KucJrorbr. (DocQarHufi6yQepnufi pacrnop pH 6,8 (1) cMerrrr{Bator ,0 t lt 7 | ,6 rlr, pac 49 KaJil4s.4urra4poQocQara 5 1,0 vrn27,2 rlt pacrBopa ru4poQocQata. Ecrn seo6xoAuuo, crBopap;Lrnurpr4r AoBoAtrpH ao 6,8 norenquoMerpr4qecKn. Xpanxr npn reMneparype or 2 lo 8 oC. I M rpuc-rrrApoxrropuAa 6yQepHufi pacrBop pH 6,8 gono4xr pH pacrBopqror s 400 MJrBoAbI, 60,6 r rpuc(rngpoKcrrMerrrJr)alruuonreraHa rucrorbl KoHIIeHc Ao 6,8 rroreHrrr,roMerpnqecKu noMorrlbroxnopr4croBoAopoAsofr rpr{poBaHHofi Aoso4rr o6relr pacrBopa so,{ofi Ao 500,0 un. n Ma.uearnrrii dyQepnufi pacrnop pH 7,0 v 10,0 r laurpvr xJropr{Aa, 6,06 r rpuc(ru4poKcuMerr4n)artruoue'raHa 4,90 r ManeupacrBopqrcr s 900 Mn Bolbr. loeogm pH ao 7,0 noreuurloMeHoBoro aHrLrqpvqa rpuqecKz c noMorrlbro 170 r/rt pacrnopa Hanptrfl rr{ApoKcr{Aar{ AoBoA.sro6tevt pacrBopano4ofi lo 1000,0u;r. Xpauxr npr.rreMrreparypeor 2 Ao 8'C. OocQarnufi 6yQepHufi pacrnop pH 7,0 82,4 rvut7l,5 rltpacrBopa runurpvrs ru4po$ocSara cnelrnBalor c 17,6 vut2l rltpacrBopa :ruuonnofi KucJrorbr. OocQarHufi 6yQepnufi pacrnop pH 7,0 (l) 250,0 xut0,2 M pacrnopaKarrrrfl.4zrngpoSoc$ara cMerxvBarorco 148,2 rrrn8 r/n papH Ecru Heo6xoAurr,ro, crBopa Hutprrfl rr.rApoKcrrAa. AoBoA.f,T ao 7,0 noreuqploMerpr4qecKr4 AoBoArr o6reu pacrBopa soAofi lo 1000,0 run. 14 @ocQarnmfi 6yQepurrfi pacrnop pH 7,0 (2) c 50,0 un 136 rlt pacrBopa Karvrfl4uru4poQocSara cMeIrII4BaIor 29,5 un 1 M papacrBopa noAofi ao 100,0 vrn. ,{ono4xr o6revr crBopa Harpru rlrApoKcr{Aa, AoBoA-flT pH ao 7,0 + 0,1 noreHquoMerpzqecKu. @ocQaruufi dyQepuufi pacrnop pH 7,0 (3) rrE4po$ocSara pacrBopttor s 900 N{r 5 r xanu-f,4rarngpoSocSara rE 11 r 4vrKan:z.fl BoAbr. .{ono4xr pH ao 7,0 noreuunoMerpuqecKrrc rroMorrlbro $ocQopnofi rucnoru oh ull.u pacrBopa HarpkrflrrlApoKcr4Aa pa3BeAeHuoro8,5 Yo u Aosopa3BeAeHHofi 10 Asr o6reu pacrBopa soAofi ao 1000,0 rvrn. (DocQarnufi 6yQepHufi pacrnop pH 7,0 (4) gurugpo$oc$ara pa28,4 r [lana'rprrs ru4poQocQara 6esnoAHorou 18,2 | Karrvs. B crBop-f,Ior BoAeu AoBoArr o6reu pacrBopa soAofi.qo 500,0 rr.rn. (DocQarnufi 6yQepnufi pacrnop pH 7,0 (5) rra4poQoc$ara 6esno4HoropacrBop.srorn 800 Mn BoAbI..{ono4xr pH 28,4r AuHutpkrfl pacrBopa $oc$opHofi xucnorrr rr AoBoArr o6reu pacrBopa 30 o/o [o 7,0 c noMorUbro soAofi.qo 1000,0rran.

29.3ax.2768

Eq

0,025M Qocr[arnufi 6yQepnrrfi pacrBop pH 7,0 pH c I o6rena 0,063M Soc$arnoro 6yQepa 7,0 cueuruBarcr 1,5 o6teMaMrBoAbI. pacrnop pH 7,0 0,03 M Qoc$arHrrfi 6yQepnsIfi pacrBop.trIor 900 Mn BoAbI xpoMarorpaQuz. a rr.rApoSoc$ata 5,2 r auxanrrs Ant .{oraAopH ao 7,0 +0,1c rroMonlbro xucnorblKoHIIeHTpI{poBaHHofi BoArr QocQopnofi pacrBopa soAofiAnt xpoMarorpaQuu 1000,0rran. BoAfiro6rerr,r lo 0,063M QocQarHrrfi 6yQepnufi pacrBop pH 700 uou ru4po$oc$ara 6e:noAHoro 3,65 r HarpLIt4uIru4poQocQara 5,i 8 r rvnarprrs, c pacrBopflror 950 Mn BoAbI. s Horr.rApara lono4xr pH ao 7,0 norenquoMerpuqecKv pacrBopa v AoBoAtr o6terr.t rroMourbro $oc$opnofi xucriorrr KoHrleHTplrponaHnofi soAofilo 1000,0rr.rn. 0,067QocQarHrrfi dyQepnufi pacrnop pH 700 grar4qpo$oc$ara papacrBopqrcr BoAe AoBoA{ro6serr,r B I4 PacrnopI. 0,908r Kanr.rr soAofi.qo 100,0vrn. crBopa papacrBopruor BoAe AoBoAtro6rerr,r B r{ rragpo$oc$ara PacrnopII.2,38 r Ar{Harpr4x crBopasoAofiao 100,0rr,r:r. II; pacrBopa cnaenrusaror61,1 rrarpacrBopa ecnu neo6xoAutr,to, I c 38,9 ir,rn AoBoAtr pH ao 7,0 norenqr4oMerpuirecKrr. 0,1 M QocQarHrrfidyQepnrtfi pacrnop pH 7,0 1,361 | Karus 4urlr4po$ocSara pacrBoptrcr B BoAe14 AoBoAtr o6reu pacrBopa 35 c rIoMoIIIbro r/n pano4ofiao 100,0nan. lonogxr pH go 7,0 noreHlllroMerpuqecKl4 crBopa Aunarpvflru4po$o c$ara. 6yQepnufi pacrnop pH 7,0 Terpa6yrr{JraMMoHun rerpa6yru.rrB 6,16 r aMMoHr4r arlerarapacrBop.flror cMecv 15 vrn400 r/n pacrBopa pH Ecnu ueo6xoAuruo, u aMMoHr,rr rilApoKcr,rAa 185 MJIBoAbI. AoBoAflr ao 7,0 c noKoHIIeHTp nannofi. I4po Moxrbro orHofi KrrcJlorbl ag EyQepnsrfipacrnop pH 7,2 cMellrvBarcr 175,0w10,2 M pac 250,0wx0,2 M pacrropaKarrufl4zrra4po$oc$ara soAofiao 1000,0Mn 14 rurApoKcr4Aa. crBopaHarpLrfl AoBolono4m o6ren pacrBopa Arr pH go 7,2 rroreHrlrloMerpr{qecKl4. (DocQarnufi dyQepHrrfipacrnop pH 7,2 c rragpoSoc$ara cueurr{Balor 13,0 wt2I rln 87,0 rran 71,5 rlt pacrBopa1vrlarpkrfl. pacrBopa KrrcJrorbr. nnnaonnofi 3a6yQepeHnuficonesofipacrBop pH7 12 xnopl,IAa, r xannwlt xnopuAa6egsoAHofo, 0,1 | 8,0 r narpur xnopr4Aa,0,2 Kanr4{ gnru4po$ocrugpoSoc$arau 0,2 r Kanr4fl 3,18 r AI4HarpI{x 0,1 r uarur4rxnopr{Aa, no4ofi.uo1000,0vrn. B rI o6reu pacrBopa $ara pacrBopqror BoAe AoBoA.xr (DocQ p arno-alr6yvrr.rnosrrfi ra6yQepenHufiQnrnorrorr{qecrcnft acrnop pH 712 6rrlrero u rz4po$ocSara,7,6 r uarprs xnopnAa I0 r a-nr6yruuua 10,7 r Ar{Harpr.rx 5 pacrBopasoAofi lo 1000,0rr,rn. Henocpe4pacrBopsrorB BoAeu AoBoAqr o6rerra c [onepeAr4crroJrb3oBaHr{eM crBeHHo AoBoArrpH ao 7,2 noreullrroMerpldrlecKl,I o/o pa3BeAeHuoro pacrBopa:rrarpurs. 8,5 utu t[ocSopnofi xucnoru rrrApoKcrrAa Morrlbro o/o. pa3BeAeHHoir lA OocQarHo-a;rr6ynuHonsIfiradyQepeHnrrfiQnrno.nornqecrnfi p acrBop pH 712(l) I 10,75r AnHarpr{rru4po$oc$ara, 7,6 r uarprlf,xnopl,IAa, r am6yvluua6H'rrero

il

pacrBop{}or B BoIe rr AoBoArr o6reu pacrBopa BoAofi Ao 1000,0 un. Heuocpe4pH crBeHHorrepeArrcnonb3oBaHr,reM AoBoA-f,T ao 7,2 notewllroMerpurrecKl.rc roMorrlbropacrBopa Hnpkrflrr{ApoKcr{Aapa3BeAeHnoro Youtu $ocQopuofi xucnorrr 8,5 o/o. pa3BeAeHHoit l0 llMrAasornnrrfi 6yQepnufi pacrBop pH 7 13 18,6 nanI M 3,4 r uvuga3oJrau 5,8 r Harpkrsxnopnla pacrBop-{}or B BoAe,npr4nr4Baror pacrBopa xnoprrcroBoAopoAHofirucnorrr u AoBoAqr o6reu pacrBopa soAofi Ao 1000,0 Mn; ecnr4seo6xoAzrr,ro, AoBoArr pH ao 7,3 noresquoMerpl4tlecKll. pacrnop pH7,4 EyQepuufi 0,6 r ranur AlrrrrApo$ocSara, 6,4 r guuarplat rl{ApoQoc$ara u 5,85 I'Harpl{t xnopur4apacrBopnor B BoAeu AoBoA-sr o6reu pacrBopa soAofi ao 1000,0 MJr;ecnl{ Heo6xoAul,ro, AoBoArr pH ao 7,4 roreHqnoMerpuqecKlr. Eap6Hra,r-6yQepHufi pacrnop pH 7,4 pacrBopa, coAepxaqero 19,44 rlr' ruarpunarlerara u 29,46 rln 6ap6ural50,0 rvr.rr Harpvtfl,, cMerrrr{Baror 50,5 rrrr 0,1 M pacrropa xnopncroBogopoAsofi xucnorr,I, npl{c 20,0 run 85 r/n pacrBopa Harpufl.xnopl4AaLrAoBoAsr o6reu pacrBopa eo,qofi Jrr4Barcr ao 250,0 rvln. (DocQarnufi dySepnufi pacrnop pH 7,4 cMerrrr{Baror 250,0 rrm0,2 M pacrnopa c 393,4 nr 0,1 M pacrropanarpLrr rr4ApoKcrrAa
,1

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i!i

Karufl 4urugpoSocSara. Tpnc(rn4poKcnMern.n)auunoMeraHa - Harplrfl xJropuAa 6yQepHufi pacrnop PH 7,4 pacrBopt}or B v xJroprrAa 6,08 r rpuc(ru4poKcr{Merr{n)aunHoueraHa 8,77 r lr'arpvrs tlrpu6aunsror10,0 r aru6yuuna 6uqrero. ,{ono500 ur BoAbrlvrcrrrlrnvrponaHuofi, pH ga T,4 rroreHrlraoMerpxqecKr4 rroMorrlbroxnopucroBoAopo.uuofiKI4cJIorbI c 4rr KoHueHTpuponaHuofivt AoBoArr o6reu pacrBopa soAofi 4vrcrvnnvrponaHHofi ,to 1000,0na.u. Tpuc - Harprrrr arlerara 6yQepHr,rfi pacrBop pH 7 14 6,3 r rpvc(rugpoxcuruerur)alruHoMeraHa u 4,9 r Harpr{r auerara 6essoAHoropacrBopnor n 900 Mn Bolbr. lono4xr pH ao 7,4 c nouorrlbro cepHofi xucnorbl KoHIIeHrpr{poBaHHofi AonoAqr o6rel,r pacrBopa soAoli ao 1000,0 nan. u - Harprrfl arlerara - Harprfl xJroplrAa 6yQepnufi pacrBop pII714 Tpuc r Harpr{r aqerara 6e:soAnoro, 14,6 r 30,0 r rpuc(rra4poKcuMerr.rJr)anauuoueraua,14,5 Harpvfl xnoprrAa pacrBoprrcr s 900 Mn BoAbr n npu6aytrsror 0,50 r a;m6yuzua c 6rrqrero. lonogxr pH ao 7,4 roreurlrroMerpr{qecKr4 noMorrlb}ocepHofi KHcJIorbI KoHrleHrpr4ponauuofi AoBoArr o6reu pacrBopa soAofi ao 1000,0 lrn. r{ (DocQarHsrfi rabyQepenHufi Qlr:uorornqecnnfi pacrBop pH 7,4 ru4po$oc$ara, 0,19 r Karvs.4uru4po$oc$ara u 8,0 r Harpn-sxno2,38 r [v:r^arpvrfl pHAapacrBoprror B BoAer{ AoBoArr o6reu pacrBopa noAofi ao 1000,0 Mn; ecnl{ Heo6xoAzrrao, AoBoArr pH ao 7,4 noresql4oMerpl4trecKl{. Foparnrrfi dyQepnufi pacrnop pH 7,5 parerpa6opara u 10,5 r 6opnofi Kr4cnorbl 2,5 r uatpr4r xnopz.{a,2,85 r A}rHarpr{x crBopqror B BoAeu AoBoAsro6reu pacrBopasoAofi ao 1000,0Mn; ecnu Heo6xo/llal.{o, AoBoArr pH ao 7,5 noresqr4oMerpr4r{ecKr{. Xpanar npr4reMrreparypeor 2lo 8 "C.

r[

FyQepnufi (HEPES) pacrnop pH 7,5 pacrBoKLIcJIoTbI 1-ran]eraucyrm$oHoeofi srrrn)uuuepasun2,38 r 2-14-(2-ruApoKcr,t 20Yopac prror e 90 N{rBoAbr. noeoAsrpH ao 7,5 noresquoMerpurleoKnIroMolubro go 100,0u.n. eoAofi Ir AoBoA-rr o6reu pacrBopa crBopa:arpr4flrr,IApoKcrrAa 0,2 M QocQarnufi 6yQepnufi pacrnop pH 7,5 grarz4poQoc$ara pacrBoptrcre 930 MrrBoAbI. 27,22| Karrnf, ,{onogxr PH lo 7,5 torIrApoKcHAa AoBoAtr Ir 300 TeHurroMerpr.{qecKrr c rroMorrlbro r/n pacrnopa lralrrrfl. noAofiao 1000,0ir.rn. o6reu pacrBopa 0,33 M QocQarHrrfi 6yQepnufi pacrnop pH 7,5 I{ PacrnopI. 119,31r 4vHarpur ru4poSoc$arapacrBoprrcrB BoAe AoBoAfro6rervt pacrBopa nogofi.qo 1000,0 rran. I,I o6ter,r PacrnopIl. 45,36| Kalrrrfl 4nru4poQoc$arapacrBop*or B BoAe AoBoAflr pacrBopa rran. soAofi.qo 1000,0 II; I c 85,0 vrnpacrBopa cueurunarcr 15,0Mn pacrBopa ecln seo6xo.ul,IMo, noBoAtr pH ao 7,5 noresuuoMerpuqecKll. p a anrHnoMeraH6yQepHsrfi acrBop pH 7,5 Tpuc(ru4poKclrMerran) pacrBopflIor B v 5,27 xnopl{Aa 7,27 r rpHc(rragpoKcuMerr4n)arvruuouerana r :aarpufl pH u AoBoA-f,T o6seu BoAe. Ecnu seo6xoAuruo, AoBoArr ao 7,5 noreuluoMerpurrecKr,r pacrBopa un. eogofilo 1000,0 - rr.rApoxrropr{Aa 6yQepuuii pacrBop pH 7,5 0,05 M rpr{c pacrBopflror BoAe. B Ecru neo6xoAuno, 6,057r rpuc(ru4poKcr{Merrrr)alruuolreraHa rncxnopncroBoAopoAsofi c AoBoArrpH ao 7,5 noreHrlr{oMerprrqecK[r]oMorrlbro pacrBopa 1000,0lrn. noAofi.qo KoHrleHrpr{ponauHofi u AoBoArro6reu Jrorbr qr.rrpara6y$epHufi pacrBop pH 7,8 (0,034M pacrnop Harprrflul,Irpara Harpua u 01101 pacrnop Harprrnxnoplrga) M pacrBops}or 900 Mn BoAbI. e 10,0r Harpnflrlrrrparan 5,90 r Harpl{{ xnopnAa [oeoKLIcJrorbI pH Ao 7,8 rroreHrlrloMerpr4qecKu c [oMorubroxJroprrcroBoAopolnofr 4m pacrBopa soAofiao 1000,0un. r{ AoBoA{ro6rervr KoHrleHTplrponauHoii FyQepuufi pacrnop pH 8,0 cMeIIrHBaror46,8 vtt 0,2 M pac 50,0 ur 0,2 M pacrBopaKarrvs.4uru4po$oc$ara pacrBopa soAofi.qo 200,0vrn. rr4ApoKcrrAa r.{ o6rena crBopaHarpfiA AoBoAt{r EyQepnufi pacrnop pH 8,0 (1) pacrBoptrcr s 900 Mn BoAbI. 20 r guxanur rr4Apo$oc$ara ,{oro4xr pH ao 8.0 nou AoeoreHur{oMerpr{qecKr.r c noMorrlbio c$opnofi rzcrorbr KoHrIeHrpHpoBaHHoii r[o pacrBopa noAofiao 1000,0vn. A-sro6reNr 0,0015M 6oparnufi 6yQepnrrfipacrnop pH 8,0 pacrBoprrcr 800 MnBoAbI. s r xJropr4Aa rerpa6opa'rau2,94 Kilrrbrlur 0,572r Ar{Harpr{x pacrnopa xncnorblH Aoxnopr{croBoAopoAHofr [ono4xr pH ao 8,0 c nououtno i M pacrBopa soAoiiao 1000,0un. BoAqro6rerra 0,02 M QocQarnrrfi dyQepuufi pac'rnoppH 8,0 cMeIIrLIBaror c 46,8 vn 4,2 M pa50,0 ur 0,2 M pacrBopa:rlarrvrs.4urz4po$oc$ara no4ofilo 500,0vrn. rr,rrpoKcrrAaAoBoAtro6reu pacrBopa H crBopaHarprrfl 0,1 NI Qoc$arnrrfi dyQepHufipacrnop pH 8,0 gurz4po$oc$ara u 16,73r rr4Kanvfl rugpo$oc$ara pacrBoptror B 0,523 | Karrrrr soAofilo 1000,0rran. BoAe AoBoA{T r{ o6relr pacrBopa
@

1 M QocQarnrrfi 6yQepnufi pacrBop pH 8,0 pacrBoptlorB BoAe. 136,tr Kailvrr r 4urra4po$oc$ara ,{ono4xr pH ao 8,0 norenqno14 rlrApoKcr{Aa AoBoAxr o6reu paMerpuqecxrr noMorrlrro1 M pacrBopaHarpprfl, c crBopasoAofiao 1000,0rr,rn. Tpuc - Harprrfl arlerarHbrfi dyQepnsrfipacrnop pH 800 pau 4,9 6,3 r rpnc(rra4poxcnnaerur)anruHoMeraHa r Harpr{r arlerara 6eeso,uHoro c crBopqrore 900 MJrBoAbr. ,{onogrr pH ao 8,0 norenqr{oMerplillecKl{ rloMonlb}o n cepHofi Kncnorbr KoHrleHTpr{ponannofi AoBoAtr o6rert pacrBopa eoAofi ur. ao 1000,0 I M rpnc - rrrApoxJropu4Hufi 6ySepHrrfi pacrBop pH 8,0 pacrBoptror v 1,47 xnopr{Aa I2l,l r rpuc(rn4poKcnMerr.{Jr)auunorraerama r KaJrburrr xnopucroBoc rroMoulbro e 900 Mn BoAbr. fiorogxr pH ao 8,0 noresqrioMerpurrecKrr u KoHuerrrpr4ponaHnofi AoBoArr o6relr pacrBopa nogofi ,topo"unofiKr4cJrorbr un. ao 1000,0 - rrrApoxrropugHrrfi Tpuc 6yQepHrrfipacrBop pH 8,0 pacrBopsror v 29,4 xnop}rAa | ,27 r rpzc(rx4poKcr{Merr{n)anruHolrerana wr Kanbql4r pH 1 c rroMorrlbro M pacrnopaxnoB BoAe. .4oeoA,sr ao 8,0 noreHrluoMerpr.rqecKr4 pacrBopa pi{croBoAopoanofi soAofilo 100,0un. KucnorhlIr AoBoAtro6serrl 6yQepHuftpacrBoppH 8,1 Tpuc(rlr4poKcr{Meru.n)auunoMeraHa pacrBop{rcrn 40 MnpacrBopa rpnc(ruApoKcl{Merun)anruxnopr4Aa 0,294r Kanbrluq xnoI c noMorqbro M pacrnopa HorvreraHa. ,{ono4xrpH ao 8,1 norenqr4oMerpuqecKn pacrBopa pucroBoAopoaHofi rr eoAofi.qo100,0un. KlrcJrorbr AoBoArro6rena Tpuc - rr'rrqrrHa 6yQepnufi pacrnop pH 8r3 pacrBoprrcT BoAe AoB I{ n28,8 6,0 r rpnc(rrrApoKcrrMerur)aruuuoMeraHa r rnarlr4Ha HenocpeAcrBeHHo nepeAI.IcrroJrb3oBaBoArr o6reu pacrBopa soAofiao 1000,0rr,rn. pacrBopa HraeM o6rerra I flpuroroBneHHoro AoBoAtreoAofiao 10 o6reNaos. Eapdnra.uadyQepnufi pacrnop pH 8,4 8,25 r 1ap6urat-Harpvfl pacrBoptrcr B BoAepIAoBoMr o6reu pacrBopaeoAofiAo run. 1000,0 - EDTA - BSA 6yQepnufi pacrBop pH 8,4 Tpuc 2,8 6,1 r rpuc(rlr4poxcnuerur)auuHoMeraHa, r narpvfl.:,reruta,I0,2 r Harpl{t xnopn4av 10 r zurr6yMlrHa 6rrqrero pacrBoptlorB BoAe. ,{ono4xr pH ao 8,4 norenquoH KucJrorbr IoBoAtr Merpr.rqecKu noMorrlrroI M pacrBopaxnopr{croBogopognofi c pacrBopa soAofiao 1000,0ur. o6reir,r Tpuc(rngpoKcnMernn)aunHoMeraHa EDTA 6yQepusIfipacrBop pH 8,4 1,40 xnopr,rAa, r rpxc(ru4poKcr{Merwr)arunHoueraHau r Harpl{t 3,03 5,12 r Harpkrfl pacrBopnor s250 Mn BoAbr aAerara rr4crilnnuponaHuofi. [ono4rr pH lo 8,4 noreHrucnorbl KoHueHTpraponauu ofi n xnop[croBoAopoAHofi cKr,r ur,roMerpr4qe c rroMoulbro lo AoBoArro6reu pacrBopasoAofi rprcrvrll.ilvpoeauuofi 500,0 rr,rr. Ooc$arnufi 6yQepnufi pacrnop pH 8,5 pacrBoprrcrs 500 Mn BoAbI. 3,5 r gurarHr ru4po$oc$ara u 4,5 r HarprrrxJropr{Aa paBHbIx o6tenaon c noMorrrbro cMecl4 Qoc.{onogrr pH ao 8,5uorenqnoMerpr{qecKr4 pa3BeAenHofi Youno4sr. Kr,rcJrorbr l0 $opnofi Tpnc - arlerarnufi dyQepHufi pacrnop pH 805 pacrBoptror xJropr{Aa l2,ll r rprac(ruApoKcrdMerur)arranHoMeraHa u 0,294r Kuurbrlr.rr
@

B BoAe.,{ono4xr pH Ao 8,5 noreuquoMerputlecK}r c rroMolrlbroyrcycnofi Krrcnorbl pa3BeAeHHofi ohu ror,o1qr o6reN{pacrBopa eoAofi lo 1000,0 un. 30 1r5 M rprlc - rlrApoxlopH4Hstfi dyQepnufi pacrBop pH 8'8 pacrBoprlor e 400 Mn BoAbI. .{onogrr pH 90,8 r rpuc(ru4poKcr4Merr4Jr)auznorvreraHa rucnorbl KOHIIOHc 4o 8,8 rroreHqrloMerpuqecKrr rroMonlblo xJropncroBoAopoAnofi r rpr4poBaHHofi Aoso4xr o6re*t pacrBopa soAofi ao 500,0 lln. ByQepHrrfi (SocQarnrrfi) pacrBop pH 9,0 1,74 r RaIrufl.4uru4poSocsara pacrBopsrcr s 80 Mn BoAbI..{ono4xr PH Ao 9,0 noI4 c TeHrlqoMerprrqecKr,r noMorrrbroI M pacrBopa Kanvfl.rI{ApoKcIaAa AoBoAtr o6leu pacrBopa soAofi lo 100,0 nal. EyQepnufi pacrnop pH 9,0 pacrBopsrcr a 0,1 M pacrnope Kuvrfl.xnopr{Aarr Pacrnop I. 6,18 r 6opuofi KracJrorbr AoBoAtr o6leu pacrBopa reM )KepacrBopl{reneMAo 1000,0 run. Pacrnop II. 0,1 M pacrnop r'arput rIrApoKcI'IAa. 1000,0 Mn pacrBopa I cuerul4Batorc 420,0 MJrpacrBopa II' ByQepuufi pacrnop pH 9,0 (1) pacrBoptrcr s 500 Mn BoAbI.lono4rr pH Ao 9,0 noreuquo6,20 r 6opnofi KXcJrorbI (orono 41,5 vrn) u Aoc Merpr4qecKu rroMorrlrro I M pacrBopa :aarpvfl rI4ApoKcHAa Bogrr o6rel,r pacrBopa eoAofi ao 1000,0 ul' Anrlronnq xrropnAa 6yQepnufi pacrBop pH 9r5 42,0 Mn pacrBopa BoAbI, upr,r6annxrcr xnoprlAapacrBoprrcr s 150 MJr 33,5 r aMMoHrrq r{ AoBoArr o6reru pacrBopanoAofi ao 250,0 rrln.XpaKoHrleHrprdpoBaHHoro aMMr4aKa xonrefiHepe. Hrr B [oJrH3TI{JreHoBOM AMMonuq xrlopnna 6y$epnrrfi pacrBop pH 1010 35,0 nan17,5 Yo pa5,4 r alruoHrrr xnoprAa pacrBoprror e 20 N{r BoAbI,rlpl4n}rBarcr I,I crBopa aMMI4aKa .qoBoAtro6terrl pacrBopa soAofi lo 100,0 rran. [HrraHonaMLIHa 6yQepnufi pacrBop pH 10,0 pacrBopqrcT B BoAe, AoBoAtT o6leu pacrBopa soAofi Ao 96,4 r AI43TaHonaMI4Ha upu6annnor 0,5 ntl 186 r/n pacrBopa MarHI{t xnopl{Aa.,{onogxr pH 4o 10,0 400 nan, c rroreHrlrroMerpuqecKr4 noMorrlbro I M pacrBopa xnopl{croBo4opoguofi Kr{cJrorblI4 pacrBopa eoAofi lo 500,0 un. AoBoAsro6repr 0r1 M aMMoHIrflrcapdonara 6yQepnufi pacrnop pH 10'3 xap6onara pacrBoptrcr r 800 MJIBoAbI. 7,91r aMMoHLI{ ,{onogm PH Ao 10,3 uoren8,5 pa3BeAeHHoro %ou c [oMorrlbro pacrBopa]HaTpvflrpIApoKcI{Aa rlr4oMerpr4qecKr,r AoBoAtr o6reu pacrBopa noAofi ao 1000,0 vrn. Alrlronrq xrroprlAa dyQepHrrfi pacrBop pH 1014 70 r auuoHr,rq xnopuAa pacrBopflror s 200 MJIBoAbI,rlpl4nldBaror330 MJI aMMLIaKa [r AoBoArr o6reu pacrBopa soAofi ao 1000,0 un. Ecnu seo6KoHrIeHTpLrpoBaHHoro o/o pawvopa c pH xoArrMo,AoBoAf,T ao 10,4 noreuulloMerpl,IqecKl4 noMolrlbto 17,5
AMMI4AKA.

pacrnop pH 10'4 Boparnrrfi SyQepHsrfi pacrBop*or s 900 Mn BoAbIAucrr4ilnkrporanuofi. ,{onogxr 24,64r 6opnofi Kr,rcrrorbr u pacrBopaHarprf, rI4ApoKcLIAaAoBoAtro6lenapa400 r/n pH ao 10,4c noMorrlbro crBopaeoAofi[vcrvrr'rruponanuofiao 1000,0n'rn.

EyQepnrrfi pacrnop pH 10,9 pacrBoprrcr n 17,5 o/opauyope aMMr.raKa AoBoAtr o6teu rr xnopr.rAa 6,75 r aMMoHt4r pacTBopa TeMXe pacrBopllTeneM 100,0 run. Ao peryJllrpoBaHl{fl noHHofi cI{JrbI EyQep AJIfl yrcycnofi neg-anofi,61,5 r Hurpkrfi, auerara 58,5 r lrarpurflxnopr{Aa, 57 ,0 vut KrrcJrorbr ruc.rrorrr pacrBoptrcT B BoAe ALIn 5,0 r qr.rKJroreKcr{nen.quur.rrpr{JrrerpayKcycHofi r{ crr,rJrJrlrpoBasHofiAoBoArr o6relr pacrBopa no4ofi 4ucrilnnvposaHHofi.qo 500,0 nan. I4.uoBoAtr AosoArr pH ao 5,0-5,5 c noMorrlbro335 r/rt pacrnopaHarpufl,rlrApoKcr{Aa o6rervrpacrBopa noAofi rtrcrtrnnvrporaHnofi ao 1000,0 rran. EyQep Arrfl peryrrrrpoBaHl{fl nonHofi cu;lu (1) Pacraop (a).210 r Jrr4MoHHofi rracnorrr pacrBoprrcr e 400 MJrBoAbrAprcrvnnvrpoBaHc Hofi. Aosolrr pH go 7 ,0 noreHrlr{oMerpr.rtrecKrl rroMorrlbropacrBopa aMM[aKaKoHrleHTpr{poBaHHoro25 % u .qoBoArr o6reu pacrBopa nogofi 4krcrkrrrrprpoeannofi

un. ao 1000,0 rr Pacrnop(6). 132r aMMoHur QocSarapacrBoprrcr B BoAeAvcrnnnvrponanHofi AoBo,(rr o6rerupacrBopasoAofi rvc'rvurlrvrponanHofi 1000,0rvrn. ao rlrcnorrr s 500 rar 292r Pacrnop(").K cycrreH3r4rr (eruren4r.ruurpNn)rerpayKcycHofi pacrBopaaMMLraKa KoHIIeHTprIpoBaH200 MJr BoAbr rvrcrilnnvponannofirplrnr4Baror pacrBopa aMMI4aKa pH ao 6,0 -T,0rroreHunoMerpuqecKra noMorubro Horo.,{oeo4rr c r4 KoHrleHTprrpoBaHHoro AoBoArr o6rerra pacrBopa noAofi [rrcrvnn rponannofi un. lo 1000,0 gonoAtr pH go 7,5 c noruoqrro (a), paBHbre Crueilrzsaror o6reun pacrBopoB (6), (r) rE pacTBopa aMMr,{aKa KoHrleHrpprpoBaHHoro.

( 38. PMT,TOOAPMAIIEBTnqECKIIE IIPEITAPATbT O<D 42-0073- 07 C )

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Arcrnnnocru o6reuuan (Activity, concentration, Volume activiQ) - orHorrreHr{e aKrllBHocrr{(A) paArloHyKrrrl1aB rrpenapare(o6pa:ue) x o6relry (V) npenapara (o6: A-/V. pasua). O6osHaqaerca:Ay AKrueuocrb, yAeJlblrat (Activity, specific) - grx orpeAeneHHoror43oronarJru cMecl{ H3ororroB:aKrrrBHocrr BeruecrBa(A), orHeceHHarK efo Macce(m). O6osuatraercr: a : A/m. Ieneparop paArroHyK.nnAHufi (Radionuclide generator) - cucreMa, coAep)Kaulat paguouyKnuA (nrareprEncxuil), B pe3ynbrare pacrraAa $urcuponannufi rtepBr,rqHbria Koroporo Bo3HIrKarcT BTopzrrHrre(4ovepuue) pa4zoHyKJrr{Abr, r.r3BJreKaeMbre nocpe.ucrBoM onrol4poBanvrrvtrwr B ApyrHM cnoco6ou rr BBoAr{Mbre cocraB pa4no$apMarleBTuqecKoroilpelapaTa. llsorourl (Isotopes) - HyKnprgbr, rrMeroqr4eoAr4HaKonufi nopr4xosrrfi HoMep,Ho pa3nuqHyro aToMHyroMaccy. IlgoronHrIfi nHglrxarop (Isotope tracer) - HHAr4Karop, KoropHfi ornu.{aercfl TOJTbKO rr3OTO[HbrM COCTaBOM r{HTepecyrcilIefo OT BerrIeCTBa. Ha6op AJrflnpr{roroBJreHrrflpagroQapMarleBTnqecKoro rrperapara (Kitfor radiopharmaceutical preparation) - peareHru (n roru qucJreruo$nnusaru), Koropbre r.rJrrr cMerrraHbr paAr4oHyKnraAoM lonyqeH]rfl foroc AonxHbI 6u:rn coeArrHeHbr Anr paAI4o$aprraaqeBTr4qecKoro Boro npenapara, KaK[paBr,rno,lepeA ero [prrMeHeHr4eM. Hocurem (Carrier) - BerrlecrBo,npucyrcrByrorqee B 3aMerHbrxKor[irecrBax, KoTOpOe, [plcyTcTByr coBMecTHo r{3oTonHbrM r4HAr4KaTopoM c BeuleonpeAeJreHHofo crBa, I,I3BJreKaer B xrrMzqecKux n QuaNr{ecKr{x ero rrpoqeccax Hntr [peAorBpaulaer yqacrIle I43oronHoror{HAr{Karopa uecnequQr{qHbrxlpoqeccax vrg4a ero nusxofi B KOHrIeHTpaU14r.r. Hocnre,rr, rr3ororlustit (Caruier, isotope) - uocureJrb, roropsrfr orruqaerct
TOJTbKO I43OTOrrHbrMCOCTaBOMOT TeX BerrIeCTB, B CneAOBbrX KOIUqeCTBaX, KOTOpbre

oH AonxeH rr3BJreKarb co6ofi. c - pa3HoBr.rAHocrb Hyrc.ullg (Nuclide) aroMa, xapaKTepn3yrouarcr KoJrr4irecrBoM nporoHoB n uefirpouoB B ero a4pe (ra,cneAoBareJrbHo, aroMHbrM HoMepolnt u ero Z gHeprerlrqecKuM arolruofi rraaccofi a raKxe ero A), cocroflHtreM. Ilepnog rorrypacila4a (paguoHyKrr,rAa) [Half-life (radionuclide.)J * An-s orpacilaIa'. BpeMq,3a KoTopoeucxoAHoe AenbHoB3rTofo rrpouecca paAHoaKTrrBHoro qucno flrep pailuoHyKJrrrAa yMeHbilraercqBABoe. O6osHa.{aetcx:T112. paAr{oaKTrrBHoro pacrraAa (Decay constant) - rlrflpaArroHyKnrrAa: flocroqHHafl BepotTHocTbpacrraAaero sApa B eAr4Hr4rly BpeMeHr4 oflpeAen.rreTc.rr BbrpaxeHr,reM: I: -(dNt /dt)Nt , rAe Nt - o6qee irrcno qAepAaHHoropaAHoHyKnr{Aa MoMeHrBpeB MeHlrt. l, csssaHac ileprroAoMrronypacnag.a coorHorrreHr4eM: . ln2 0.693

h = -

T, '2

T,
,/2

Arruenocrb paAHoHyKnI,rAa y6unaer co BpeMeHeM sKcrroHeHrlr4anbHoMy rro 3aKOHy:

wz

-!.Wt

) t IE0 COOTBeTCTBeHHO. BpeMeHI{ B r$e Atu Ao- aKTuBHocTI4MOMeHT 6er .qodasJrenrlflHocureJlfl (Preparation of radioIlpenapar paArroHyKJrHAa nuclide, no carrier added) - rpenapar, cBo6oAHblfior cra6uJrbHblx I43oronoB 3Jreo.qHaKo npelapaTbl, rrpVHaAJre)Kr,rT MeHTa, K KOTOpOMy AaHHhrfi paAr{oHyKJrI,IA. rperapaTaMv paAlroHyKJrHAa6e3 HocHTeJrfl(caffierfree), uuotga coHasbrBaeMbre I,I3oTonOB TO|Ox(e 3JIeMeHTAll1lJr]1l KoJIvqecTBa aTadvrr6,Hbrx AepxaT He3HarrxTenbHble ero xr4MuqecKoroaHanora. I4cro.rHnroM r4x Moryr 6rrTb no60qHbre rAepHble peaKIII4I4, npLIMeCil XLIMLIIIeCKIX 9JIeMeHTOB, COAepXaIIIVIeCflB peaKTI{BaX, [pI'IMeHteMbIX

A , = A o x e - =u * e t4

T.A. nplr xrrMLtqecKr,rx oleparlutx 14 TaK PaAuoaxrusHrrfi npenapar, B KoropoM r,rMelorcr KaKpaAI{oaKTLIBHbIe, vt cragJIeMeHTa vrrv xvrMvlqecKoro anaJlora, Ha3blBaerct tlpe6pr.lrrnrrel,I3oronbl AaHHoro rraparoM c Hocr{TeJreM. noABepPaAnoarcurBHocrb (Radioactivity) - cBoficrBo HeKoropLIXHyKJTLIAoB pacrraAy. rarbcq paAlroaKrr4BHoMy PaAnoarr[sHHfi npeArrrecrBeHHrrK(Radiopharmaceutical precurs or) - paIUerrUt npeAHa3HaqeHHOe BBeAelf'l1'fl,pAA}1lOHyKnUAHOfi BeTIeCTBO, Anr Ar,roaKTHBHOe B.qpyroe BerrlecrBo (paauo$apMarleBrr4qecrufi npeuapar) nepeA ero npI4MeHeHIIEM.

Pagnonroron
MEHTA.

(Radioisotope) - paAproaKrpreHrrfi r43oron onpeAeJleHHorooJIe-

xoropufi pa4noarrvrneH.HyxruiAbl, 06Paguonyrcnng (Radionuclide) - HyKJrrrA, naAarotqueHecra6uJrbnofiroru6uuaquefi nporoHoB v HefirpoHoB, caMorIpoLI3BoJIbHo vnv B Hyc nocrof,HHofi BeporrHocrbro ilpeBparqarorct s cradunsHble HyKJILT[br KJrlrAbr gpyrofi Hecra6r{Jrbuofixona6unarluefinporoHoB u HefirponoB. O raKl{x Hyc paAr4oHyKnI4AaMI4. v Knr4AaxroBoprT, qTo oHr4paArroaKTnBHbre, o}lvt Ha3brBatoTafl. MareprlHcKrrM, o6pa3ylot\uitcs.- AoqepHnM. a Ha3brBaror ZcxoAsrrfi paAr{oHyKJrr.rA rrncrora (Radionuclidic purity) npenapara - orHoIIreHLIe aKPaguonyrnnAnafl e crl{ v[a TtrBHo crr.r o cHoBHoropaALroHyKJr K o6rqefi aKTLrBHo rrpe[apara, BblpaxeHHo flocrorHHofi xapaxrepncrurofi AaHHoronpenapara, avlgB npoqeHTax, He flBnfr,ercfl, BpeMeHil. MeHrrercsc TeqeHr4eM Pa4noHyrcJrrrAnbrerprrMecr{ (Radionuclidic impurities) - npLIMecI{Apyrrx paKonnvecrBo paHyKnH4on (xar roro xe, TaK r.rApyrr.Ix gJIeMeHToB). AiloaKTuBHbrx orHoIIIeHI4eMaKTvBHocrLl npuuecefi Bhrpaxaror EporIeHTHbrM .{LroH}Knr,r.qHbrx onpeAeneHHylo ocHoBHoroHyKJrwAalaa npnuecefi K aKrraBHocru Aary il, npv seo6xoAr,rMocTr{, BpeMr. paAuonyKJru4u, o6pasyrculrect B pe3ynbrare paAl4oalilnBHoropacrla.!.a ,{o.repnr.re rrpu(ocnonHoro) pa4uoHyKnr{Aa,He cqr4Tarorcfl.paAvoHyKJII4AHbIMrI Marepr,rncKoro npuHarrpnMep, rceuou-131m ne paccMarpl{Baerct KaKpa.qvoHyKJII4AHat MecflMpr: MecbK fioay-l31. Paau o QapMarIeBTr q eucnfi np er ap ar (Ra di oph arm a ceuti ca l) - rcxapcrneHnnfi HecoAepxfl4ToArIH I,IJILI <poprrae ilpellapa! roropufi s roronofi Anr r{cnoJrL3oBaHr4r (paa[oaKruBHblx uroronon). paAr,roHyKJrzgon cKoJrbKo @

I ,'$
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ls

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PaAuoxunr[qecKafl qrcrora (Radiochemicalpurity) - orHorrreHrae aKTr{BHocrr4 pa.ul{oHyKIrr44a, roropnrfi npr{cyrcrByer B rrpelapare n ycrofivNeofi xuN{u.{ecrofi paArroHylr.nvraB SToMrrpelax QoprueocHoBHoroBerrrecrBa, o6qefi aKTrrBHocrp{ paTe,BbrpDKeHHoe rrporleHTax. B PagnoxnluqecKrre rprlMecn (Radiochemicalimpurities) - rpr{Mecr xr{MrrqecKxx coeArlHeHvfi, ounvHbrx or ocHoBHoroBeurecrBa, cocraBJlfl]oxlerorrpenapa! Ho conpuuecefi, T.e.aKAep)Kaul4xror xre paAr{oHyKruA.BerxquHy paAuoxrrMr,rqecKr4x TrlBHocrbco.4epx(au1erocq Hr4xpaAr.roHyKrrv4\Bbrpaxaror B nporreHTaxx o6qefi B p AEr4OHy aKTr.rBHO CTI'{ Knljna B npen apaTe. Cporc roAHocrrr pagnoQapMaueBTnqecKororperapara (Storage time of Rad i opharmaceutical) - BpeMq,B reireHr.re Koroporo paguo$apMarleBTr4rrecrufi upenapar yAoBJlerBop.xer rpe6onauuxrr,rSapuaxonefiuoil crarblr (Sapuaxonefinoff crarbvr npegnpuxrvr). YnrrparcoporKolr(r{Byrqnfi paArroHyrcJrrrA paAr4oHyrnr,rA rreprroAoM c flonypacnaAaAo 2'aacos. (Daprraxonefi nag crarbff - locyaapcreeHurrfi craHAapr KatrecrBa neKapcrBeHHoro cpeAcrBarIoA Mex4yHapoAHbrM (ecnu oHo r4MeHerrareHToBaHHbrM Ha3BaHpreM ercx), co,4eplKauluit o6szare,crHHfi ileperreHbrroKa3arenefiu rvreroAoB KoHTpoJrs KatlecrBac yrreroM ero neKapcrsenHofiQopuu. (Dapnrarconefiuascrarbfl rrpeArrprrflTtrfl, locyaapcrseHHrrfi craHAapr KaqecrBa Ha neKapcrBeHHoe cpeAcrBonoA ToproBbrM Ha3BaHrreM, coAepx(arqufi nepeueHbrroxasarerefi u MeroAoBKoHTpon{Kar{ecrBa JreKapcrBeHHoro cpeAcrBarrpor{3BoAcrBa KoHKperHoro yrr4TbrBaroulnfirourperHyro rexHoJrofr4ro [peArrprrflTr4*) IaHHoro npelperrlcrpaufi }o B ycraHoBneHHoMrroprAKe. rrprrflTr4s, ilpoue.uurufi sxcueprr43yr{ I4 Xu*rn.recKrre npllMecn (Chemical impurities) - npvMecr{ rocropoHHr{x xr4Mr{qecKl4xcoeAI{HeHI4fr anerreHToB, u flcroirH[KaMr{Koropblx {Bnr}orcr rrcxoAHbre BetuecrBa r{ peaKTr{Bbr, raK)Ke no6oqnrre npoAyKTbrHerroJrHo a urvt napannenbHo nporeKarculux peaxqufi. .fgepHrre lr3oMepbl (Nuclear isomers) - HyKnr4Abr, nMelorlue oAnHaKosrrfi N{acconrrfi HoMepu arorrHrrft HoMep,Ho ornr4tlarculuecqgHeprerrrqecKl4M cocro.rlHlreM l,rx rAep. EAunuqsr aKTrrBHocrrrn SHeprrrn Pa4IaoaxrzeHrtfi pacnaA r{nu rrepexoAMoxer BKJrroqarb r4crrycKaHrae 3apr]KeHHbrx r{acrllq, 3axBar oJreKrpoHon (33) r4Jrr.r r43oMepusrfi repexoA (I{il). 3apaxeHHbreqacrI,IIIbI, xcnycKaeMbresApoM, - 9To am$a-uacrlrrlhr (qapo aroMa rerrufl c arolruofi uaccofi 4) utm 6era-qacrHrlrr (orprarlarenbuo 3apr)KeHHue,o6rruno Ha3brBaeMhre 3neKTpoHaMvr, Ltrvr rIoJIo)KLITeJIbHo 3apt)KeHHrre,o6rtuHo Ha3bIBaeMbIe no3r4Tpoqacrr4rl rApoM Moxer colpoBo)K1arbcfl rrclycKauanru). llcnycraru{e 3apflxeHHbrx HrIeMraMMa-KBaHToB. farral{a-rsaHTbr raKxe r4crrycKarorcrrrpu r43oMepnoM nepexo.qe. qacr[qHo 3aMeularbcr BbrxoAoM gneKTpoTarcoe[clycKaHlre raMMa-KBaHToB Moxer HoB, Ha3blBaeMbrx 3neKTpoHaMX BHyrpeHsefi KoHBepcurr. llporlecc 3neKTpoHHoro peHTreHoBcKrrx 3axBararIplrBoArITK BTopr,rrrHoMy r{crycKaHr4ro Jrfrefi (6naro4apa ueperpyrrrpoBKe oJIeKTpoHoB aroue). 3ra aropuqHar gMrrccvrflcaMano ce6e Molxer n qacrlltlHo 3aMerrlarbcrBbrxo.[oM H3BecrHbrx 3neKTpoHoB, KaKDneKTpoHbr Oxe. Pac Ar{oHyKnI{.qbI 4eSuqurou uefirponon Moryr r4crycKarb no3r4TpoHbr.Tarue

PaAHoxnunqecrcas qr{crora (Radiochemical purity) - orHorrreHr.re aKrr{BHocrr.r paAIroHyKIrvIa, xoropufi npucyrcrByer B rrpelapare n ycrofiuueofi xfiN,rlrqecxofi pa1voryKJrr.rAa 3ToMrrperraB $oprvreocHoBHoroBerrlecrBa,x o6qefi aKTr.rBHocrv paTe,Bbrpax{eHHoe npoueHTax. B (Radiochemicalimpurities) - npnMecu xrMur{ecKux PagnoxnvrrqecKr.renpr.rMecr.r coeAr4HeHlrfr, orJruuuux or ocHoBHofoBexrecrBa,cocraBnqroqero npetrapar,Ho coBemr.*rHy paArroxr4r,rrrecKr4x rrpr.rMecefi, r.e. axAep)Karllx ror x{e paAr{oHyKJu,rI. TI4BHocrbcoAep>xaIqeroc-f, Hrrx paArroHyKrrwra,Bbrpaxaror B rrpoqeHTaxr o6rqefi B p AAr4OHy aKTrrB CTpr HO KJrrr.{a rrpeflapaTe. B Cporc roAHocrrr pagnoQapMaueBTrrrecKororperapara (Storage time of Rad i opharmaceutical) - BpeM{, B TeireHr.re Koroporo paguo$apMarleBTr,rqecrufi npenaprryAoBnerBoprer rpe6orauuxnr Sapnaaronefinoficrarbn (SapuaxouefiHofi crarbrr npe4nplrxrux). Y.rrrparcoporKolrcrrByutnfi palnoHyKJrrrA - paluoHyKnr{A c nepr4oAoM nonypacnara ro 2 \acos. (DapnraxoneffHaq crarbq - locygapcrnennufi craHAapr KaqecrBaneKapcrBeHHoro cpeAcrBanoA MexgynapoAHbrMHerrareHToBaHHbrM (ecnu oHo r4MeHa3BaHueM ercl), coAepx(arquit o1ssarenrHrrfi neperreHb[oKa3areJrefi u uero.uoB KoHTpoJrt Kar{ecrBa yqeroM ero neKapcrseHuofi$opnau. c (Dapnrarconefinaq crarbr upeArrprrflTrrfl- focygapcrsenurrfi craHAapr KaqecrBa Ha neKapcrBeHHoe Ha3BaHLreM, cpeAcrBorroA ToproBbrM coAeplrarrlufinepeueHbrroxagareneft14MeroAoBKoHTponrKarrecrBa neKapcrBeHHoro cpeAcrBa[por{3BoAcrBa KoHKperHoro ilpeAlpurflTytfl,,yrr4TbrBaroqufi rourperHyro rexHonofr4roAaHHoronpelprp err{crp arlnro B ycraHoBneHHoM rrpvtfl'wrfl 14 oue.uurnfi excueprrd3y rroprAKe. , np XrvruqecKrle npnMec*t (Chemical impurities) - npr4Mecr.r ilocropoHHrrx xr.rMlrqecKrlx coeAr{HeHI4fr areueHToB, HcrorIHuKaMI4 ra Koropbrx qBrrrorc-f, ucxoAHbreBeulecrBa 14peaKTrrBbr, raKxe no6oqHrre [poAyKTbr HenoJrHovrnil flapannenbHo a fiporeKarorqux pearqufi . .fgepnrre rl3oMepbl (Nuclear isomers) - HyKJrrrAbr, r{Meroutle oAHHaKosHfiraaccoerrfi HoMepu arorvltrufi HoMep,Ho orJlrrqarcIufiect gHeprerr'rqecKrrM cocrorHraeMrrx rAep. EAlurnqsr aKTrrBHocrHrr 3Heprurr PaguoarrusHrrfi pacrraArrJrr{ ilepexoA Mo}KerBKnrcqarbr{cnycKaHr4e 3apnrceHHbrx r{acrrrrl, 3axBar sneKrpoHon(33) HJrr.r H3oMepHufirepexoA (I4D. 3apxxeunbre rracrr4rlbr, r4crrycKaeMbre rApoM, - oro anrSa-vacrr.rrlbr (sapo aroMa feJrrr{ c arorvruofi uaccoil 4) unu 6era-qacrurlu (orpzrlarenbHo 3apffKeHHue,o6rruuo Ha3brBaeMbre gIeKTpoHaMv\ vrilvl nonolru4TeJlbHo rro3l,ITpo3aptx(eHHrte, o6rrvHo Ha3brBaeMble qacrr.rqsApoM MoxcercolpoBo}KAarbcr ucnycKauarvru). I4crycxanue 3apsx{eHHbrx Hr{eMf aMMa-KBaHToB. f auua-rnaHTbr raKxe r{cnycKarorcfl rrpv r{3oMepHoM rrepexoAe. rracrr,rrrHo Taroe ucttycKaHlle raMMa-KBaHToB Moxer 3aMelllarbcq BbIxoAoM 3neKTpoHoB, Ha3brBaeMbrx 3neKTpoHaM[BHyrpeHnefi KoHBepcr4r.r. Ilpoqecc gneKTpouHoro 3axBaranpuBoAprrK BTopuqHoMy rrc[ycKaHrrropeHTreHoBcKr4x nyqefi (6laro4apx neperpynruIpoBKe oneKTpoHoB arovre). 3ra nropu.rHaf, oMuccvrfl. n cav'a no ce6e Moxer qacrlrrrHo 3aMeqarbcr BbrxoloM gneKTpoHoB, a3BecrHbrx KaK gJreKTposrrOxe. PaALIoHyKnIlAbrc .qeQraqurou uefirponon Moryr rrcnycKarb no3r4TpoHbr.Tarne

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(2) 3e.26 cyr Pyrenufi-103

(to'Ru) B paBHOBeCnr4 c Poar,reru-103m(r03nRh. (r03mRh) 56.114

a,c*ce 0 . 0 1 7

t2

0.020-0.023 9.0

0.030-0.039 88.3

0.497 0.610

9l
J.d

(20)ruuH) 4.9(1)uac

B-

0) 0.031 (r) 0.064 0.019

6.6 92.2 13.4

x
v

0.023-0.026 70.5 0.642 0.658 0.885 0.938 0.997 25.9 98.3 92.9
68.4

l4tatuir-ll0 (t'oln)

10.5

it'

69.1 (5) tr.tztt

0.019

).J

2 0.023-0.026 7 . 8 0.51I 0.658 2.129 t23.4u) 97.8 2.1

I4naufi-ll0m ("*In)

p'

1 . 0 10 ) 5

6l

rcl

(s) 2.8047 cyr

l4stuir-lll ("'In)

0.019

15.6

0.003

6.9

82.3 0.023-0.026 0.145 7.8 0.171 90.2 94.0 0.t67-0.171 1 . 3 0.219 (l) 49.51 cyr
I4uauir-ll4m
(1r4mln) B paBHOBeCr,ilr

4.9 40 X

0.24s

0.241-0.245 t . 0 0.162 36.3 0.023-0.027 0.190 0.558 0.725

88.0

0.1 86-0.190 40
I

15.6

14 tr{naueu-1
("oln)

B'
(traIn 71.9 (l) c)

9.777 tt)(rvrarcc:

95

1.98s)
9t

3.2

(7) 154.0 cyr

Tennyp-l2lm (trt-Te)
B paBHOBeCIIil

0.003 0.022-0.023 0.050

0.026-0.031 0.5 5 0.212 81.4 2.5

7.4
I

t.t02
40.0 6.1
I1.6

c Terrypou('21Te:19.16 l2l (t2rTe)

(5) cyr)

0.077 8 0.1 0

(5) 19.16 cyr Tennyp-121

(trrTe)

0.022

7 0.026-0.030 5.6 0.470 0.508 0.573

t . a

t7.7 80.3 9.3

( 13.278)vac

0.023
ce

I z.J

0.004

0.027-0.031 . 6 86 0.127 0.t54

ilot-123 (t23I)
I J.O

1.8 0.4

0.159 0.346 0.440 0.505 0.529 0.538

83.3 0.1 0.4 0.3

1.4

0"158

0.4 6.3 47.5 10.73

4.176 tlgs

B-

0.687 (narc:

1.s34)
0.975 (ruarc: 2 .l 3 8 )

n.79
10.89 63.0 8.30

0.004 0.027 0.031 0.51l 0.603 0.723 1.509 1.691

0.003
ilos-124 (t2al)

0.023

4s.96
62.9 10.35 3.13 10.88

art)

59.402 (14)cyr
IzoA-125 (r25I)

9l*ce

0.004 0.023-0.035

80
JJ

0.004 0.027 0.031 0.035

15.5
t14

26 6.7

(5) 13.11 cyr

0.023

A a 0.027-0.031 1

ce

0.354 0.634

0.5 0.1 3.6 32.1 8.0

I

0.388
0.491

34 2.9
2.3 (t)
JJ

ilos-126 (t261)

0.51I

( 0.109 I) 0.2900) 0.4590)

0.666 0.754 0.880 t.420

A"l

0.8 0.3

p8.02070 (11)cyr.

0.530(t) 0.46

3.5 1.6

0.029-0.030 . 9 3 0.080 0.284 0.365 0.637 0.723 2.6 6.1

81.7

0.330

('3'D [oa-131

0.069(D 0.0970) 0.1920)

2.1
t.J

89.9
6.8

7.2 1.8 8.3 44.0

(7) 11.84 cyr

Kcenon-l3lm (,,t.Xe)

9t

0.025 0.129 0.1 9 5 0.163

0.004 0.030 0.034 0.t64 0.530

0.875

61

r0.2
2.0 87 4.5
z.+

28.s
8.3 3.8
J.Z
I

froa-133(t33I) (pacna4aercx go Kceuona133)

2 0 . 8( l ) v a c

0 . 1 4 00 )

a) 0.162
0.299$)

4.2 83 5.8 5 5I . X

t.298 0.004 0.031 0.035 0.080 0.004 0.030 0.034 0.233

0.441u) (l) 5.243 cyr

Qt

0.026 0.045

6.3 40.3 9.4 38.3 7.8

Kcenou-133 ("rXe)

ce

0.075-0.080 9.9
I

p( 2.19l) cyr
Kceuon-133m (,rr.Xe) (pacnagaercx Ao KceHoHal 33)

(r) 0.101 0.025 0.1 99 0.228 0.232

99.0 7 64.0 20.7 4.6 10.0 X

4s.9
10.6

ce

(2) 6.57 wc

p-

(r) 0.140 0 0.237 0) 0.307 0) 0.352

0.3990) 0.444{I) (J) 0.529

t.+

8 8.8

0.527 0.547 0.837 1.039 1.132 1.260 1.458 1.678 t.791

13.8
1 a

6.7 8.0 22.7 28.9 8.7 9.6 7.8

fros-135(135I) (pacnagaerca Ao KcenonaI 35)

21.9 8
t.)

23.8

9.14(2) uac ce Kcenon-135 (tt'Xe)

0.214

).) 3.1
96.0

0.031-0.035. 0 5 0.250 0.608 0.005 0.032-0.036 7 90.2 2.9

p-

0.r71
0.308 0.026

0.8 8.0 1.4 94.4 5.6 32.2 49.6

I/.J

Ilerufi-137 (tttcs)
B paBHOBeCUU

(3) 30.04 rer

ce

0.624 0.656

c Eapuerra- ( r 3 ? m B a . l37m ('37*Ba)2 .ss2 (r)

ftffH)

0.662

85.1

B_ B_

0.174n
0 0.416 ) 0.200 (rvrarc:

46.3 \aca

0.63s)
0.226 (vaxc: 0.705)

0.006 0.041 0.042 0.047 0.070 0.1 3 0

t2.0 t7.5
3l.t

Cauapnf-153 ('trSm) ce

0.265 (rr,rarc: 0.808)

0.021 0.055 0.095 (uarc: 0.651 1.773)

0.694 (rraarc: 1.854)

21.7 43.2 6.44

I

12.4
4.85 29.8

26.8 .q'ac

48.7 50.0 27.8 I1.5 26.5 6.44 11.61

o 1

0.007 0.048 0.049

8.3 3.1 5.5 6.71

lonrrraufi-166 (touHo)

9t

0.006 0.023 0.071 0.078 (uaxc: 0.048 0.r77) (uarc: 0.110 0.385)

ce

v v

0.081

6.65ans

0.208

10.36

Jhoreuuir-177
(tttLu)

0.149(uaxc: 0.498)
9t

79.4 0.27 0.48 0.57

0.044 0.1t2 0.143

ce

31.3ax.2768

Efl

l7.0,rac

9-

(uaxc: 0.528 r.487) (uarc: 0.729 1.96s)

1.748 26.3 70.0

6.8

0.009 0.063

3.2 2.44

88 Penufi-1
(t*Re)

(uarc: 0.795 2.r20) 0.007

ce

0.155

15.6r

0.081 0.142

5.04 5.85
98.7
I

3onoro-198
(tntAu)

2.696cyr
7.42 \ac

B-

0 0.315 )

0.412

95.5

0.144 0.193

t.23 1.19 0.1

9 0.069-0.0804.5

p*
Tamwir-199 ('nrTl)

0.227

0 . 18 5 0.208 0.247 0.334 0.455

4.9 t2.8 9.2 t.6 12.3 32.0 t7.5 87.2 13.8 10.8 29.9 3.4
J.J 1 ^

2 6 . 1( l ) u a c

0.285 0.353

3.4 1.4 0.3

0.010 0.08

6 0.069-0.071 3.3

B*
Tar.r,uir.-200
(rooTl)

0.495(I)

0.368 0.579 0.828 l'206 t.226 t.274 1.363 1.515

J-+

4.0 19 79
9.9

9.33(3)uac
ce

0.055 0.246 0.276 l 0 . 36

6 0.070-0.0739

0.083 8.5 2
z-J

0.331 0.361 0.406 0.585 0.692 0.767 0.826 0.908 0.946 1.099

Csrureq-201 (20'Pb) (pacnagaercr Ao Tarrrtuq201)

2.0 3.6 4.3

3.2

2.4 5.7 7.9 1.8 1.6

.i'

$
,j:

r.277

WE

(t7) 12.9r2
qac

ce

0.016-0.017 t 7 . 7 0.027-4.029 0.052 0.084 0.153

4.1

0.010

46.0

Tannwir-2Ot ('o'Tl)

7.2 15.4 2.6 2.8 2.4

0.069-0.071 . I I J 0.080 24.4

I

0.1 5 3 0,167 0.010

2.6 10.0 31.0

(2) 12.23 cyr

Tunti'r-202 (rotTl) ce

0.054 0.357

0.069-0.07r . 6 61 0.080 r7.l

I

0.440 0.010

91.4 37.0

( 51.8739)uac CsraHeu-203 (rorPb)

0.055

3.0

0.194

13.3

0.071-0.073 69.6 0.083 19.4 0.279 0.401 0.01I 0.077 0.079 0.090
0.687

80.8 3.4 19.7 12.68

a1 aA

7.27\ac Acrar-2ll ('"At)

5.870 0.008 0.06

41.8 26.1 t.34

9.53 0.261 1.15 1.18

45.6 v'uu

5.869 0.320 (rraaxc:

1.94 31.0 65.9

z.J l

0.011 0.077 0.079

B
Bwcuyr-273 (r"Bi)
91

0.e82)
0.492 (ll.axc'.

r.422)
ce I 1 . 4 3a H - q
0

r.98
26.1 25 15.3 25.4
I1.5

Pasuit-226 (rtuRa) ce

0.008 0.347 5.434 5.540 5.607 5.716 5.747 0.009 0.024 0.046 0.056 0.171

3.97 2.22 9.0 25.2 51.6 9.0 28 7.5 12.7 18.5 9.3

0.440 0.012 0.081 0.084 0.095 0.1 4 5 0.269

5.7 13.9

39. OAPMAIIEBTI4TIECKI,IE

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s Ilporpaunocrb pacrBopa. Pacrnop 0,5 r cy6craHrlr,rrl 50 vrr gTaHoJIa AoJrx{eH c r,rJrr{ BhrAepx{r4Barb cpaBHeHrle sranoHola I. 6rrrr npo3patrHbrM IfnerHocrb pacrBopa. Pacrnop, ronfreHHrrfi s rrcnrrranuvtna llpospauHocrb pacpaBHeHr{e erarouou 89. c crBopa, AonxeH 6rrrr 6ecqseruHMulru BbrAepxrrBarb pacrBoprror s 25 wil MeraHorra pas6anu pH. Or 9,0 4o I 1,0 (0,1 r cy6craurlktr4 rurror soAofi 4o 50 un). ilpoBoArr MeroAoMB3XX B ycJIoBI4tx, [ocropoHHne rrprrMecn. Onpe.qeneHr,re aHHbrxB p a3Aene<<Konu.Ie crBeHHo orrpeAeJreHr{e)). e orrr4c A XpolaarorpaSupyror rcnbrryeMrrfi pacrnop A, pacrnop cpaBHerrus, rI pacrBop pacrBopa A cpaBHeHkrrE. Bpeux perkrcrparlr{t4xpoMarorpaMMbr r.rcnblTyeMoro nvtna a3rlTpoMr{Aonx(Ho He MeHeeqeM B 3 paza npeBbrrrrarbBpeMqyAepx{r{BaHvrs. rlr{Ha. B Ha xponaarorpaMMe rrcnbrryeMoro pacrBopa A unorqaAb nI,IKanpLIMecI4 4orxna pacrBopa cpaBHeHI{r (He 6oree E Ha 6uru He 6oree rnoulaAr4nprKa xpoMarorpaMMe o/o);rrJrorrlaAb 2,0 rrr.rKa nro6ofi apyrofi npr{Mecr4AoJrxHa 6nnr ue 6oree nnorlaAl4 nr4KaHa xpoMarorpaMMepacrBopa cpaBHeHlrtA (He 6onee 1,0 oh); cyMMapHat nnorlaAb [prKoBupurr,recefi AonxHa 6urr se 6onee lqrr,rKparHofi nnoIr1aAunuKaHa xpopacrBopa cpaBHeHr{r (He 6onee 5,0 %). MarorpaMMe A BoAbIB TeqeHue I uprH u X.nopn4u . 0,75 r cy6crau\uvr Bcrpflxr{Barorc 25 rrt;lt $Hnrrpyror. 10 un $vnrrpara AoJrxHbrBbrAepxvBarb rrcflbrraHne Ha xnopu4u (ne 6oree 0,01o r cy6crarulr4u). K. rpoBoArr MeroAoM @uBola. He rueuee1,9 oh u He 6oree 6,5 yo. Onpe4eneHr{e ruepa As roqHofi HaBecKr.r oKoJro0,5 r cy6craHlrl4l{. rpoBoA.f,T MeroAoMB3XX. Ko.n[qecrBeHHoe o[peAeJrenne. OnpeAeneur{e pacrBoEyQepuutupacmsop c pH 6,5. 34,84 r Kalwffi, Qoc$ara ABysaMeIrIeHHoro prror s 900 MJrBoAbr, .{oBoArr pH pacrnopa Ao 6,5 85 % Qoc$opnofi x*tcnorofi, pas6asrslor eoAofi,uo 1000 Mn kr repeMerrr,rBalor. pacmeop A. Oxoro 0,1 r (rouuar HaBecKa) I,Icnutmyeuaui cy6crauquu noMexlaror B MepHyro xon6y BMecrr4Mocrbro25 vut, pacrBopsrcT B cMecu aueroHl{TpI{JI- BoAa (2:3), AoBoA-rrr rrepeMerrrr.rBaror. o6reu pacrBopa rofi xe cMecbroAo MerKu 14 I,Icnatmyeuatil pacmeop E. 5 Mn r.rcnbrryeMoropacrBopa A noueqarcr B MepHyro 20 ron6y BMecrr,rMocrbro w1 AoBoArr o6rerrapacrBopa cMecbroarleroHr,ITpl4n BoAa (2:3) ao MerKr{H repeMeIIIIrBaIor. Cmaudapmuutilpacmeop A. Orcolo 0,05 r (rovHar Hanecra) craHAaprHoro o6pa:qa a3r{TpoMrrunHa noMerqaror B MepHyroron6y BMecrrrMocrbro50 rrar,pacrBoptlor B cMecr.r arleroHlrrpr{n - BoAa(2:3), AoBoArr o6reu pacrBopa rofi xe cMecbroAo MerKil r4nepeMerrrr4BaloT. cMecbloaqePacmeop cparHeHutA. I un craHAaprHoropacrBopaA pas6aBJrrror roHr4rprin- BoAa(2:3) ao 25 vnt. Pacmeop cparHeHun E.0,002 r craHAaprHoroo6pa3lla npl{Mecu B asurpoMllql{Ha (3-aesoxcua3nTpoMlrurrH;craHAapr BP unn aHilrorr{rrHoro Kaqecrna) pacrnoptlor B 25 rw cMecr.r aueroHr{rpr{n- BoAa(2:3). r u 0,002 r Pacmeop dna npoeepxu npuzodHocmucucmeJwbt.0,002 a3r4TpoMI{III,IHa cTaHnprrMecu A asurpoMvw]Fla (6-,qesrvrerunrBr,rTpoMr{rll{H; cTaHAapTHOrO O6paSqa 4apr BP uru anarorr{qHoro xauecrna) pacrBopqrcr s 20 MJrpacrBopa cpanneuua E. @

Xporvrarorpa0rqecrreycnonuq - 250 x 4,6 uru c oKTaAerlvJrcvrvrlr (Cl8), Koronra cr.rJrr.rKareJrerr,r 5 vrxrra;

Teuneparypa flognzxuax (rI(D) Sasa CropocrrrroroKa !ererrop O6renr npo6u

-70"c;
- 6y$epnrrfipacrropc pH 6,5- arleroHr{rpvn BoAa (2:7:ll); - 1 rr,rn/ruun: - crreKrpo uue Qorolaerp cxuit,2 | 5 uwt; - 100prrn;

pacrBopAnqrpoBepKurrpr{roAHocrr.r XporvrarorpaSupyror cr4creMbr. Bpeur yAep- 26 wtun.OrnocureJrbHoe yAepx{r.rBa)KuBaHvrfl nr,rKa a3rrrpoMr.rqr{Ha oKono BpeMs - onoro 0,42, uuxa [pr,rMecr{ - ororo 1,7. PaspeureHue (R) lrvtfl, n.uKa rrprrMecr4 A B MexrAy [r.rKaMr{ a3r{TpoMr.rqunau [prrMecr4 Aorxno 6urr ue rraeuee A 7,0. flmr pa3 xpoMarorpa$zpyrorcraHAaprurrfipacrBopA. Ornocr4reJrbHoe craHAaprHoe orKJroHeHr4e Anr nnoulaArl [r4Ka a3r{TpoMr,rqr,rHa AonxHo 6uru He oh. 6oree2,0 pacrnop E u craHAaprnrrfipacrnopA u orpeXporuarorpa$upyrorucrrbrryeMrrfi rrrrKoB a3r{TpoMrrrlr4Ha. AenrroTnnoulaAl1[ (X) CogepxaHue B no C3gHT2NzOrznporleHrax Bbrr{ucnrrcr Soprr,ryne: Sr*aoxPx100

X :
S o* a r x ( 1 0 0 - W ) rAe: 51- nno[aAb nr'rKa iBrrTpoMr4rluKa HaxpoMaTorpaMMe r{cnbrTyeMoro pacrnopaF;
Sg- nno[aAb IIIKa a3I,ITpOMI4UuHa HaXpoMaTOrpaMMeCTaHAapTHoro

&g- H&BeCKa O6paSqa a3r4T'pOMrrrILrHAB fpaMMaX; CTaHAaprHOfO BoAbr, [porleHTax; W- co4epxaHr4e B P - co4epxaHr.re B ocHoBHoroBerrlecrBa craHAaprHoM o6pa:qe a3rrrpoMrrB ur,rHa nporleHTax. XpaHenne. Cnxcor<6. B cyxorvr Mecre.

pacruopaA; &1* H?BeCra cy6craHur'ru fpaMMax; B

(@C AMnOArrrrr{HA EECITJIAT 42-02I 4-07)

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' Co4epxrar He MeHee97,0 o H ue 6onee 102,0 yo Cz'H2sClN2Os C6H6O3SB IIepecrrerena 6egnoAHoe BerlecrBo. Onucanne. Eenufi I{JII{norITI{6enufi ropolroK. pacrBopl4M crlllpre B yMepeHHo PacrnopnMocrb. Jlerxo pacrBopr{MB MeraHoJIe, 96o , MaJIopacrBopl{MB BoAe. c floA.nunnocrr. I,In$paxpacuufi cneKrp cy6crauuuu, cuxtstirB AHcKe ranux 6ponoJrocnorJlorueHrrtAoJr]KeH no s Mr{AoM, o6racr1aor 4000 ao 400 cna-1 noJroxeHl4lo 6eculara (llpunoxeune I ). pI4cyHKy crleKTpaaMno.4rrrnua coorBeTcTBoBarb o/opacrnopa cy6cranllxpl B cMecl4MeraHon Ynrrpa$uonerosrrfi crreKTp0,005 0,1 M pacrnop xnopucroBoAopoAuofi rncnorrr (99:1) n o6lacru or 300 Ao norJrorleHvnnpu 360 uu' 400 nrr.r AonlceHI4MerbMaKcrrMyM ilpoBopr MeroAoMB3XX' flocroponHrle rprMecu. OnpeAeneHl{e EyQepnuil pacmsop c pH 3,0. 7 Mn rpuorr{rlaMl{HapacrBoptrcr s 1000 Mn Bo,ubl r,rAoBoAtr pH pacrnopa oproQocSopnofi xzcnorofi go 3,0 + 0,1. Irlcnarmyeuatilpacmeop. 0,01 r cy6cranqulr pacrBoptlor s 10 N,rrno4uaxnofi Qasu (IIO). Pacmeop cpasHeHun 3 rral ilcrrbrryeMoro pacrBopa ilepeHocsr B MepHyroron6y o6reu pacrBopa fIO ao MerKrrLI ilepeMelrlrrBaror. BMecrnMocrbro100 u.u, ,uoBoAflT / I rvrrilonyqeHHoropacrBopa nepeHoc.rlT MepHyroxon6y BMecruMocrbto10 rrl;r,AoB BoAqr o6reu pacrBopa IIO ao MerKrI H rlepeMellruBaror. npuzodHocmucucmeMbt.0,005r cy6cranqrlu pacrBopqlor Pacmeop dnn npoeeprcu rIpLI TeMneparype 70o C B reqer{ s 5 trr BoAopoAarrepoKcr4Aa BbrAep}s.rBator Hue 45 rvruu. XpoMarorpa0u.Iecxue ycrosuq

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5-uerun 2-l(2-avuHooroKcr{)rraerun]-4-(2-xnop$enun)-6-rraeroKcr{rrr4puguu-3,54Iarap6orcutar) - oKoJIo0,5; auno4vrrruH- 1,0 (ororo 7 ruun). PaspeureHze(R) MexAy nvKaMr{AonxHo 6rnr ue uenee 4,5. XpouarorpaQupyror pacrBop cpaBHeHnq ucnbrryeuufi pacrnop. Bperrax u pernpacrBopa AonxHo He MeHeerreM n 3 pasa crpaul4lr xpoMarorpaMMbr r.rcrrbrryeMoro npeBbIIIIaTb BpeMt yAeplKI{BaHLIt cHoBH o oro nI4Ka. YAnoenHa-f, [nouaAb nr4Ka rrprrMecuD Ha xpoMarorpaMMer{cnbrryeMoro pacrBopa pacrBopa cpanueHur (ue AonxHa 6urr se 6oree nnorlaAr4flkrKaHa xpoMarorpaMMe o/o);cyMManroulaAefi Bcex 6olee 0,3 nocropoHHr4xrrpr{MecefiAolxna Apyrr4x rrr.rKoB 6urr se 6oree nnoilIaAr{ rrvKa Ha xpoMarorpaMMe pacrBopa cpanHeunx (ue 6oree 0,3 oh). He yuuruBalor nrr 6eHsuncynr$onara (orHocr{renbHoeBpeMr yAep>rrvtBarllzfl oKono - 0,2) kr nvrKvt, nnoruaAb Koropbrx cocraBJrrer MeHee0,1 nloqa4u nr4Ka xpoMarorpaMMe Ha pacrBopa cpaBHeHr{.f, (0,03 %). yo. Orono_3,0 r cy6craHrJvrvt Bo.qa.He 6onee 0,5 (rouHax uanecra) Tr.rrpyrorpeaKrraBoM @uurepa. K. Cy.nrQarnafl 3oJraI.rrfl)I(eJlble MeraJrJru. Cynr$aruar 3ona us 1 r cy6craHquu (rouuax Hanecxa)He AoDKHanpeBbrrxars0,2 o/o AonxHa BbrAep)KlrBarb H ucrrbrraHr4e Ha rqxerbre MeraJrJrbr 6onee 0,001 Yos cy6crauquu). (ne Ocraroqnble opraHllqecKr{e pacrBoprrreJru. B coorsercrBtrrr c rpe6onannflMr4 o6uefi crarbr{ <<Ocraro.rHbre aHr{qecKr{e pacrBopureJrrr opf )). Murcpo6uorornqecKar rfncrora. B coorBercrBkrkr rpe6onauuqNruOOC <Muc xpo6uonoruqecKar irr4crora)). Ko;ruqecrBeHHoe o[peAeJreuue. OnpeAeneHr{e rpoBoAf,r MeroAoMB3XX s ycJroBrrrx,onucaHHbrxB pa3Aene<llo cropoHHr{enpr4Me cr4)). I'Icna*nyeuani pacmeop. Oxoro 0,05 r (rovHax uanecra) cy6craHqzr{ rroMerrlaror B MepHyroxo:r6y BMecrr4Mocrbro ul, pacrBopqror a fIO, AoBoAf,T 50 o6reu pacrBopa fIO lo MerKI{14 nepeMelrruBaror. un nonyqeHHoropacrBopa nepeHocrr B MepHyro 5 BMecrlrMocrbro100 rvrn, tr AoBoAf,ro6reu pacrBopa lI(D ao MerKr4 repeMerrrr41or6y
BAIOT.

Cmaudapmnutitpacmeop. Oxono 0,05 r (rovuax Hanecra) craHAaprHoroo6pa:qa aMJloA[nvsa 6ecutara noMerqaror B MepHyro xo.rr6yBMecrrrMocrbro 50 ul, pacrBopttor n fI(D, AoBoAtr o6reu pacrBopa II@ ao MerKr.r rrepeMerur,rBaror. nrn nonyr4 5 qeHHoro pacrBopa lepeHoctr B MepHyro xon6y BMecrrrMocrbro 100 rral, AoBoArr o6reirapacrBopa IIO ao MerKrr r4nepeMerrruBaror. |Isrr pa3 xpoMarorpa$upyror craHAaprnrrfi pacrBop. OrHocurenbHoe craHAaproh. Hoe orKJroHeHr.re nirorrlaAu nr.rKa aMJro4vtwtHa AoJrxHo 6rnr se 6orce 2 XponaarorpaQupyror r{cnbrryeMufi u craH4aprHufi pacrBopbr.

32.3aK.2768

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pacrBopa;
B cy6craHIII4I{, fpaMMaX; a1- HaBecKa craHAaprHoro o6pa3rla aMnoAlrnuna 6ecvna;ra)B rpaMMax; &g- HaBecKa BoAbIu ocrarotlHblx opraHlallecKfix W - cynruapHoe coAep)KaHl4e B pacrBopr,rrenefi cy6craHIII4Ir, npoueHTax; B o6pa3lle ocHoBHoroBetuecrBaB craHAaprHoM P - coAep)KaHl{e 6ecunara, B npoqeHTax. aMJroAunvHa or 3aIITI4IIIeHHoM cBera Mecre. XpaHenue. Cnucor E. B cyxorra,

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0,1 M pacrBope xnopucroBoAopoAHofi Kr,rcJrorbr o6nacru or 245 Ao 280 HMAoJrlKeH B IrMerb MaKcr4MyM 258 urra. npz 0,05 r cy6crauqzu pacrBoprror B I rr,uno4opoAanepoKcu4a.Pacrnop oKpaur.rBaqepe3HecxoJrbKo erct B cJIerKa rorry6ofi rlBer, Koropufi 6rrcrpo vctre3aer,14 Mr{Hyr pacTBOp CTaHOBT.TTC_S KpaCHbrM.

0,1 r cy6craHuuu cMaqrBaror 0,1 un Bo,qbr, rtpu6ar.r'xror 5 nrn cnupra 96 o/ou pa3BeAeHHofi o/o.llocrc pacrBopeHuxcy60,5 nan xnopr{croBo4opo4nofiKktcJrorbr 8,3 craHIIrIu npu6annnor 5 ur 0,1 M pacrBopa KaJrr{ritogara; pacrBop oKparxr{BaercqB qrer MaJlraHoBbrfi ; nprr AuurbH rueu npn6aaren vLrp earTrtBaoKpacKa y clznnBae"rfl u efi c BbrAeJr.f, n 6y p:.;'iro caAoK. erc Cy6crauqkrfl Laer xapaKrepHyro peaKrlr{roB sa uarpwit. Ilporpa.urocrb pacrBopa. Pacrnop 0,5 r cy6crauuuu s 5 N{ncBexenpoKrlnrqeHsofi u oxJraxAeHHofi eoArr AonxeH 6rrrr npo3paqHbrMvrJrvr BbrAepxlrBarb cpaBHeHue I. c grarroHoN,r IdnerHocrb pacrBopa. 6,25 r cy6crauqru noMeuaror B MepHyroron6y BMecrlrMocrbro 25 rw, AoBoArr o6reu pacrBopa cBexenpoKr.rrrrireHHof oxnax4eHHofi u no4ofi Ao MerKr4 nepeMerurrBaror (ucnuryenrufi pacrnop). He 6onee uerrruepes 10 rr
MLIH IIpOBOA'T pICTIbITaHIIe OAHI4M I43 MeTOAOB.

A. Or<pacxa HcnbrryeMoropacrBopa He AonxHa 6rrrr r4HTeHcr4BHee oKpacKrr 3Tanoua GY6. E. OnrprqecKarrrJrorHocrbr{cnbrryeMoropacrBopa, u3MepeHHar KroBerec roJrB rqznofi cros 10 MM rrpu AnrrHeBoJrHbr nu orHocrzTerrbHo 400 BoAbr, AonxHa 6rrrr ue 6 o n e e0 , 1 . pH. Or 6,0 Ao 7,5 (10 % pacreop). flocropoHHr{e [prrMeclr. OnpeAeneHr{e [poBoAflT oAHr{M MeroAoB. r{3 Meroa TCX Irlcnutmyeaarilpacmsop. I r cy6craHqulr noMeruarcre xor6y c rpr{reproii upo6roft nuecu4Mocrbro 50 ur, npz6auxrcr 25 rvrn6e:no.{uoro xnopoQopMa,BcrprxuBalor B TerreHr4e uus lr $z.rnrpyror qepe: 6yuaxHrrfi $r.rnrrp, cnaouenHrrfi 5 xnopo$opnou, or6p acbrBafl ilepBbrenoprrr4nQz:nrpara. 6essoAHrrla Pacmeop cpanHeHun 0,0I r 4-avusoarTnrrlrptrHa pacrBoprror s 50 Nar6esnoAA. Horo xnopoQopua. PacmeopcpasHeHutE. 10 Mn pacrBopacpaBrreHux ApazdaBJrnor6eseoAHErl,r xropo$opruor.r 25 un. lo Pacmeop 4-aemunauuHoaHmunupuHa.0,035 cy6craHrluu pacrBoprror s 5 rar r 'C 0,01 M pacrBopa xnoplrcroBo4opo4Hofi rlpe4Bapr4renbHo oxnaxAeHHoro Ao 10 KI4cJIorbI npn6anruror rro KarrJrrM n npr{ rrepeMerrvBaHrrr4 M pacrBop fio4a 4o no0,1 -sBJIeHIig xe.llrofi oKpacKI,I, [cr{e3arorqefiB TerreHLIe uuH, cneAt 3a reM, qro6lr He 1 reMrreparypapacrBopaHe npeBbrilraJra "C. K nolyreaHoMy pacrBopy npn6anlxrcr 10 pacrBop Harprrfl ruApor(clrAa4o pH 8 u AsaxAbr sKcrparr{pyror rlo KarJItM 0, i M 4-nreru:raur4HoaHTr.{ruprrH xnopotpopMoMnopqLrfllr'rt 5 u,r. OSreAlrseHHbre no xJropoQopnaHrre r43BJreqeHilfl 30 cymar B TerreHp{e nqnurrarq r rrarpar cynrSara 6e:0,5 BoAHoro. I nal no:ryrreHHoropacrBopa pas6au.arol 6e:no4ribrM xJropo$opnaorvr ro 25 rvrn. Ha nuswto crapra rrJracrr4HKr{ cJrocMcr.{Jrr.{KafgJrx F25aFrairocJ{r' urxn co tr0 60

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B PacrropuMocrb. Jlerro pacrBopr.rM BoAe,JIerKopacrBopl,IMLIII4 pacrBopl4MB o MaJropacrBopl,IMB alleroHe. crr,rpre 96 , c iloAnunnocrs. I4n$parpacHrrfi creKrp cy6crauqr.ru, cvrtrrti't B AHcKe ranlrx 6poroJloc noDIoIrIeHnt AonlKeH MrrAoM, o6racru or 4000 ao 400 cM-l uo noJroxeHrrro s coorBercrBoBarb pr{cyHxy cneKrpa aprrrnauna ruApoxnopu4a (flpranoxenue 1). cy6cranquu n 0,1 M Ynrrpa$uonerosrrfi crreKrp rorJronleHus,0,002o/opacrnopa e pacrBope xnoprrcroBo4opo4nofi KracJrorbr o6racru or 200 Ao 350 HMAonxeH LIMerb npll npu272 HM I4MI4HI4MyM 230 nu. MaKcr{MyM peaKIII4roHa xnopLIAbI. Cy6cranqvfl rae't xapaKTepHyro oC (na.ranopa3nox{eHIar, rvrero41a). Or Teuneparypa rrJraBJreHrrfl. 167 rc 172 s Ilporpa.rHocrb pacrBopa. Pacrnop I r cy6craHrlr{r4 20 N,IrBoAbIAonxeH 6rrrs granonou I. c cpaBHeHLIe lpo3parrHbrM rrrru BbrAepr{I4Barb I{nernocrb pacrBopa. Pacrnop, loryqeHHrrfi s ucnrrralarruHa llporpavHocrb paBY6. C CpaBHeHI'IeeralOnOrr'r CTBOpa, AOnXeHBbIAepXI,IBaTb o/opacraop). pH. Or 4,1 go 5,1 (4 I43 npoBoA{r oAHI{M MeroAoB. IlocropoHnrre [prrMecH. OnpeAenenrre Meroa TCX pacmeop. 0,05 r cy6cranqr4r{pacrBopf,rorn 4,8 un MeraHona,nprIrlcnutmyentutil naMvna LrlepeMelxuBaror. 6 aersror 0,2 nm AIrsruI Pacmeop cparHeHufl. 0,5 vl ucrrbrryeMoro pacrBopa pas6aBJr{Ior MeraHonoM ao 100 rr,rn. Pacmeop dna npoeepxu npuzodHocmu cucmembt.K 0,02 r cy6craHryuu npu6annxror 0,1 MtI yKcycHoro a:arvrrpn4a, BblAepxerBaror 30 MrrH, npr6auxrcr rrepeMerrruBaror nonHoro pacrBopenl4fl. I,7 wn MeraHoJra, wn AvrJTvlrav.rrr:'ala 0,2 Ao rIoMeIIIaror B 60 IlodeomoeKa nnacmuurcu.fItacrI,IHKy co cJIoeMcI,IJrI4KareJix F 25a r{ KaMepyc MeraHoJroM xpoMarorpa$zpylor BocxoAtrul4MMeroAoM.KorAa QpoHr I{3 ee rroABr4x{Hofi Qasu lofiAer Ao KoHrIarrJracrLtHKI4, BbIHLIMaror KaMepbI,cylxar Ha oC s teqeHue 15 lrus. a Bo3Ayxe, 3areMnpr{ reMrreparype 100-105 Ha JrnHrrro crapra rroAroroBnessofi nnacrrrHKl't co cnoeM cl{nrrKareJlt pacrBopa, 10 lmn (0,5 rr,trr),5 uxn 60F2s4HaHocrr 5 narn (50 uxr) ucrrbrryeMoro cuu (0,25 urr) pacrBopa cpaBHeHrr.f, 5 rr,mrpacrBopa Anr rrpoBepKl{rIpI4roAHocrI{ rroMelqatorB Kaupo6al,ru cyurar Ha Bo3Ayxe, creMbr. llnacrunry c HaHeceHHbrMrr - Merauon (40:1) u xpovrarorpaQupylor BocxoAtIrILrM Mepy co cMecbroxnopo$opM I,I3 MeroAoM.Kor4a Sponr rroABr4xHofi$asrr npofiger 314 wactuHKI,I, ee BbIHI4Maror KaMepbr,cyrxar Ha Bo3Ayxe B TetreHne 5 unn u lpocMarplaBaror n YO-ceere npu 254 uw. u BerI4qI,IHbI rro [prrMecefi, orleHeHHoe coBoKyrlHocrl4 coAep)KaHr4e Cyruir,rapuoe I4crlblTyeMofopacTBopaB r4X nOrJIOUIeHr4r frrTeH Ha XpOMaTOrpaMMe vHTeHCr,rBHOCTr.r rlpepacTBopacpaBHeH[t, He AOJIXHo cpaBHeHr4r4nsTHaMuHa xpoMaTolpaMMax c o/o. esluram 1 paPesylrrarbr r,rclbrrantrfl, cuv'rarorcr AocroBepHrrun, ecJrl{Ha xpoMarol-paMMe o6HapyxuBaerct He MeHee crBopa Arq rpoBepKr{ npr{roAHocrracr.rcreMbr AByx fltreH, no oTnr4qarcnlr4xcr BerktiruHaMRl or rr{THa Ha xpoMarorpaMMax pacrBopa cpaBHe(0,25 urr) verxo BI4AHo [srHo. pacrBopa cpaBHeHrrt larrfl\14 xpoMarorpaMMe Ha

MeroaB3XX
ferIrIrJIc pH zenmuncyttufuouama 2,0.2,02 r HarpLIs 0,01 M pacmsop Hampufl pacrBoptror B cynr$onara v 4,08 | KarI.Lfl Qoc$ara oAHo3aMeIrIeHHoro, pH rlrcnorofi go 2,0I4 AoBoAsr BoAbr, 900 rvrn AoBoA.xr pacrnopaoproQocQopnofi no4ofilo 1000ul. o6reu pacrBopa rIoABIrxHofi pacmeop.0,01 r cy6ctanquupacrBoptlor n l0 rvrn Irlcnatmyeuwil Sasrr

(ro).

Pacmeop npuueceil.0,01 r craHAaprHoroo6pasqa npr{Mecv A apruranna (<ar1eraMrrAoaprrrKakrH))MernJr3-[[2-(nporr4JraMr.IHo)aqerun]aunHo]--4-rvrerruruoQeHKaqecrna)u 0,005 r cran4aprHoro 2-rap6oxcvrar; craHAapr BP rznu aHanorurqHofo - trerun-4-uerul-3-[[(2R,S)o6pa:qa ilpr{MecrrE aprzrauna (<ra:ouponunaprl4KaplH)) craH4apr BP 2-[(1-naerunerul)auuno]uponnonun]arrauno]ruoSeH-2-xap6oxcnnar; vrrvr a*arorr4qHofo xavecrna) pacrBop{tor s 100 mn lI@. npuzodHocmucucmeMbt.10 vr cy6crauqnu pacrBopttor Pacmeop dna npoeeprcu s 10 NarlIO, npu6aBrqror 0,2 vut pacrBopa npuuecefi lI nepeMel[nBaror. Pacmeop cpasHeHuflA. I wtr r4crrbrryeMoropacrBopa ilepeHoctr B MepHyroxon6y 100 lrl, AoBoAsr o6reu pacrBopa II(D ao MerKlr I{ nepeMelxrBarcT. BMecrr,rMocrbro pacrBopa lepeHocrr B MepHyroxor6y BMecrr{Mocrblol0 ul, Aononyr{eHHoro 1 rr,rn repeMellrlrBaror. BoArr o6rev pacrBopa lI(D ao MerKI4I,I xol6y evrerepeHocqr B MepHyro Pacmeop cpa6HeHufl6.1 ul pacrBopanpunaecefi rrepeMelrrllBalor. crr{Mocrbro 50 vll, AoBoArr o6rerrapacrBopa IIO ao MerKI414 XpouarorpaOuqecxneycronus

Ko;ronra

|Io Teuneparypa
CropocrrnoroKa Iererrop O6reu upo6nr

- l5 x 0,39 crrr oKTaAelrvncvrurcllJrrrKareJleu (C18), c 5 vrxu; - arleroHrrrpl{n 0,01 M pacrBop c rerrrrrncyns$onara pH2,0 (25:750); Harpr4fl - 45' C; - 1,0un/rr,tuu; - crreKTpo$ororraerpnuecxufi 6 ntvr; , 27 - 10 rr,rxn.

rlpr4roAHocrn cl4creMbl.BpervrryAepXporr,rarorpa$upyror pacrBop Anr rrpoBepKr4 aprr,rKarrna oKono 9,3 wun. OrsocnreJrbHoe BpeMt yAepxldBanilfl.nuKa )KilBanuflrrr.rKa (R) E A npr.rMecrr orono 0,8, uura npr.rMecr{ ororo 0,86. PasperreHl4e NaexgyTI4KaMLI 1,2. E nprrMecll A u npurr,recpl Aolxso 6rtrr He IraeHee n E Xpouarorpa$upyror pacrBop cpaBHeHrrrA, pacrnop cpaBHeHr{s u Ncuuryevuft pacrBop. Bpeur perrrcrparlr4r,r xpoMarorpaMMbrr4crlblTyeMoropacrBopa AonlKHoHe qeM B 5 pas npeBblllrarbBpeMt yAep)KLIBaHrrt ocHoBHoro[vKa. MeHee A r{crrbrryeMoro pacrBopa nnoqaAb nrlKa rIpI4MecI4 Aolxsa Ha xporraarorpaMMe 6rrrr se 6olee nnoqaAr{ nrzKa[pr,rMecz A Ha xpoMarorpaMMe pacrBopa cpaBHeHHq 6rnr ue 6olee E (ne 6olee 0,2 o/o);rnouaAb urara mo6ofi 4pyrofi rpl4Mecv ,[ort>ICHa o/o);cywA Ha rnouaArr rrrdKa xpoMarorpaMMepacrBopa cpaBHeHI4t (ne 6onee 0,1 He nro6rrx Apyr[x upurraecefi Aonxua 6olee qeM B 5 pas npeMapHarnnoulaAb rrr,rKoB pacrBopacpaBHeHI,It (ne 6olee 0,5 o/o). A Bbrrrrarb nnouaAb rr4KaHa xpoMarorpaMMe EIIEI

Ha nnorqaAlarII,rKa xpoHe yuntuBalor rrrrKrr,lnoilIaAb Koropblx MeHeerroJroBrrHbr pacrBopa cpannenux A. MarorpaMMe llorepr B Macce rrpu BbrcyrrnBaHurr. Oxoro 0,5 r (rouHa,r HaBecra) cy6cranrlrrr4cyrrrar npr{ reMneparype or 100 Ao 105 oC Ao rrocrotHHofi naaccu.llorepx n MacceHe AonxHa npeBbrrrrars o/o. 0,5 rpoBorflr us oKoJroI r (rouCy;rrQaruaq 3ora. He 6onee 0,1o . Onpe4eneHrre Ha-f, HaBecxa) cy6craurrrru. Tqxemre MeraJrJrbr. CyirrSarHaq 3ora us 0,5 r cy6craurlr4r{AonxHa BbIAep}Krr(ne s Barb r{crrbrraHrre rrxenble MeraJrJrbl 6onee 0,002 o/o cy6cranquu). Ha pacrBopnreJrlr. B coorsercrBvrvrc rpe6onauvfllr'vI Ocraro.urbre opraHrrr{ecKr.re pacrBoprrreJlr{)). OOC <<Ocraro.rHbre opraHrrr{ecKue BaxrepHaJrbHbre sHAoroKcnnrr. He 6oree 0,7 E3 sa I ur cy6craHqzIa. foroBrr ncxoAsrril pacrBop cy6cranqNu (ronqenflnr nponerenvfl. rrcnbrraHrr-f, qeM B 30 pas. Tparlur 40 nr/run), a 3areMpa3BoArr efo He MeHee Llcnsralaue rrpoBo4xT Anfl, cy6cranqnr4, rrpeAHagHa.renuofi Ant rlpuroroBJreHl{s rrHbeKrlr{oHHbrx neKapcrBeHHbrx Soprnr. OOC <MrMnrcpo6uoJrorrrqecKafl rrucrora. B coorBercrBukrc rpe6onauusrr,ru xpo6uonorr4qe cKar rrr{crora>). Ko.unqecrBeHHoe onpeAeJrerure.K oKoJro0,2 r (ro.ruar HaBecxa)cy6craHlrl4rr upu6annxror 10 rvrnyxcycHofi KrrcJrorbr reA.ssofi u 4 wvtpacrBopa pryrll oxucnofi npa6annnor 0,09 ur 0,1 o/opaar\erara, nepeMerxuBarcT pacrBopennfl HaBecKLr, Ao crBopa Kpr4cranJrvqecKoro $raoreroeoro r4Tr{Tpyror0,1 M pacrnopoM xropuofi rncnpu6ann-aror rlBera I,IHArIKaropa) Jrorbr.B roHqe rr{TpoBaHur(npu [epBoM rr3MeHenlrr4 yKcycHoro anfkrrpv!'a r.rnpoAomraror rr4TpoBaHrre norBnenua rony6oBaro10 rr,rn Ao
3eJIeHOrO OKpaUUBaHr4q.

llaparnenbHo npoBoArr KoHTponrurrfi onblT. 1 lan 0,1 M pacrBopa xnopHofi KI,IcJIorbI coorBercrByer

32,08

Mr

.H C c 1 3 H 1 0 N2 O3 S l .
or Xpaxenne. Cnucor E. B cyxorra 3aIIII4ITIoHHoM cBera Mecre.

(@C 42-02 I 8-07) ACKOPBT,THOBA-fl KT,TCJIOTA

- (5 (5R)-5- t( 1.9) 1,2 lur uAp rrert4 -2,3- sunr4porcuSyp au-2 II) -ou oKc rf

cH2oH

c6H8o6
Co4epxzr He MeHee99,0 o C6H8O6.

M.vr.176,12

[oporxoK urv 6ecqnerrroqrpr 6enrrfiKpvcraJrnrr.recrzfi Onncanne. EenrrfivJrr4 reMHeer. r{bre Kpr{crannbr; cBerynocTeneHHo Ha

gtr

HepacrBopI,IM xJropoB B PacrnopnMocrb. Jlerxo pacrBopr,rM BoAe,npaKTr.IqecKI{ $oprr,re. c fioA.lrnHnocrr.IrlnSpaxpacurrft cnercrpcy6cranqu[, cuxrrrfi B Ar4cKe xanux 6ponoJloc uourolrleHrlt AoJIXeH Mr,r,uoM, o6racru or 4000 ao 400 cu-l no ronolKeHr.rro s coorBercrBoBarbprrcyHKycrreKrpaacxop6nuosofi rucroru (llpunoxenue 1). Ynrrpa$uonerosrrfi creKrp nonrouleHr.tr0,001 o/opacryopacy6cranquu n 0,1 M B pacrBope xJroprrcroBo4opogHofi KprcJrorbr o6racru or230 ao 300 HMAoDKeHHMerb tpu243 uu. MaKcrdMyM 0,05 r cy6cranqur{ pacrBopnor B 2 run soAH u nplr6anr*or 0,5 MJrpacrBopa cepe6pa Hr,rrpara;BblnaAaer reunrrfi ocaAoK. K 1 un 5 Yo pacrnopa cy6craHlll{tr npu6annrrct 2 tw 0,1 M pacrBopa irola; peaKTrrB o6ecqee.ruBaercs. Ilporpavnocrb pacrBopa. Pacrnop 1 r cy6craHrlr{Hs 20 ilar BoAbIAonxeH 6urr c cpaBHeHHe gtalouou I. lpo3parrHbr vrrrr4 M BbrAep)KlrBarb I{nerHocrb pacrBopa. Pacrnop, floryqeHHsrfin ucurrranuvt na llpo:pavHocrb paBY7. C BbIAepXI{BaTb CpaBHeHI,Ie eranOnOrvr CTBOpa, AOJIx{eH yo pacrBop; orpeAentrcr rortlac YAemnoe BpaIrIeHrIe.Or +20,5 go +21,5' OA rrocJrerrpr{roroBJleHut l4crlblryeMoro pacrnopa). pH. Or 2,1 go 2,6 (5 % pacmop). Kncnora uaBeJreBa* I'Icnumyeuwil pacmeop. 0,25 r cy6crauquu pacrBoptlor B 5 N{r soArr, Hefirpanu3yror rro naKMyconofi 6yuare 10 o/opacmopoM HarpI,It rllApoo/opalrlcvrila, npu6annxror 1 un 12 % pacrBopa yrcycnofi KrrcJlorblu 0,5 vn 7,35 xnoprrAa. crBopa KaJrbrlr4r Pacmeop cpanHeHun 0,070 r qaBeJreBofixucnorbl rroMelrlarorB MepHylo ron6y BMecrr,rMocrbro 500 l,rn, pacrBop{rcT B BoAe,AoBoAqr o6reu pacrBopa eoAofi Ao K 5 rr,rn [onyqeHHoro pacrBopa upll6auxror MerKr4 u rrepeMerrrr4Baror. o u 1 ur pacrnopa yKcycHofi xnclorbr pinBeAensofi 12 o/o 0,5 rral 7 ,35 pacrBopa KarlbpacrBopoM. qur xnoprd4a.Pacrnop roroBqr oAHoBpeMeHHoI{crIbIryeMbIM c rlpeBblllrarbotlzurec9epes I q onanecUeHrl[r [cnbrryeMoro pacrBopa He Aon)KHa oh). (He pacrBopa cpaBHeHLIt 6onee 0,2 rreHrlr4ro I,'Icxoduuil cmaudapmuatil pacmnop nedu (10 uxz/un). Oxono Melr. cynrQara (ernunareHT oKono0,1 r rue4n)nolreqaror 0,393 r (rouuax nanecra) MeAr4 pacrBopttor B BoAeIr AoBoAtr o6rerrapa100 rran, B MepHyroron6y BMecrr4Mocrbro I rrepeArrcrroJlb3oBaHlleMul nonyveuHenocpe4crBeHHo crBopa eoAofi Ao MerKra. B Horo pacrBopa noMerrlarcT MepHyroxon6y BMecrrrMocrblo100 un, AoBoAqro6reu pacrBopa eoAofi Ao MerKI4LI [epeMellrllBator. CmaudapmHdepacmnoput. 2 urn,4 nn n 6 MJrrrcxoAHorocraHAaprHoropacrBopa o6reruu parroMeularcTB Mepubreror6u BMecrr{Mocrbto 100 rvrn,rloBoA,ar MeAr.r IrlcuonrcrBopoB 0,1 M pacrBopoM agorHofi KrrcJrorbr MerKHI{ flepeMelrrl{Balor. Ao pacTBopbl. 3yroTcBex{elp[foroBJleHHble cy6craHurlu rloMeuaror B pacmeop. Orono 2,0 r (rovuat HaBecKa) I.Icnatmyeuutil 25 MepHyroron6y BMecrr4Mocrbro unt, pacrBopnor n 0,1 M pacrnope asorHofi rucu pacrBopa reM )KepacrBoprrreJleMAo MeTKLI lepeMelrrllBalor. Jrorbr,AoBoAsr o6rerr,r craHAaprHbrx pacrBopoB Ha aroMHo-a6cop6qraoHHoM I4slrepxror nornorrleHr,re cflexTpoMerpe rrpr4 Anr4HeBonHbr 324,8 HM, plcrloJrb3ytB KaqecrBe ucrotIHI,IKa EIII'

BannaM-fl. KaToAoM Bo3AyrxHo-aqerr{JreHoBoe r{ MeAHbrM r43nrreHur JraMnyc noJrbrM no 3oByroJrlrHnroycraHaBJrr,rBaror 0,1 M pactnopy asornofi KLIcJIorbI. Benr4rILIHbI noilIorueHll{ or KoHCrpoxr xarn6ponoqurrfi rpa$ur 3aBr.rcprMocrpr ueHrpaun v MeAII (rraxr/rr,rn). B rex x(e ycnoBr,rrx r{3MepqrornoHIoIueHIderlcrlblTyeMoro pacrBopa. B CogepxaHr4eMeAr.r npeuapare B npolleHrax (X) BbItIHcJItIor no Qoprrayne:

Cx25 x 100

C
ax400

X:
ax1000000 no MeArrB r,rclhrryeMoMpacrBope, onpeAeJreHHat rarur6rAe: C - xouqeHTparlr,rfi poBoqHoMyrpaSury, e urr/ur; a - HaBecKa cybcraHqvw\ B rpaMMax. 6urr He 6onee 0,0005 %. MeAuB npenapare Aonxcrro CogepxaHr.re Xeneso. Irlcxoduanicmaudapmuuil pacmsop ilcer$a (2A uxz/un). Oxolo 0,863 r (srnvnaneHT oKoJIo0,1 r xenesa) no(rounar narecra) KBacrIoB x(eJre3oaMMoHr{eBbrx pacrBopqlor s 50 N,In M pacrnopa I MerrlarorB MepHyroxon6y BMecrr{Mocrbto500 rran, gono4rr o6reu pacrBopa (ecnu seo6xoAuruo,rprr HarpeBaHlru), cepnofi KrrcJrorbr 10 Henocpe4crBeHHonepeA lrcrroJrb3oBaHl{eM rvrn H no.qofiAo MerKr.r nepeMerxr.rBaror. pacrBopa rroMerrlanr B MepHyroron6y BMecruMocrblo 100 lrn, AoBononyqeHHoro gxr o6relr pacrBopa soAofi Ao MerKI{ I{ flepeMeruI,IBalor. pacmsopat 1 tvut,2 tvrnu3 Mn rrcxoAHorocraHAaprHoropacrBopa CmaudapmHbte 100 un, AoBoAsr o6reuu parcon6u BMecrr4Mocrbro xeJre3arroMenrarorB MepHbre llcnolrcrBopoB 0,1 M pacrBopoM agornofi Kr.rcJrorbr MerKr4r{ nepeMelrlldBa}or. Ao pacTBopbr. 3yror cBe)Kenpr4roToBJreHHbre cy6craHllur noMenlator B Irlcnatmyeuait pacmeop. Orono 5.0 r (rovuiur HaBecKa) 25 Mepnyro ron6y BMecrr,rMocrbro rnn,pacrBoptror a 0,1 M pacmope agonrofi xucJrorbr,AoBoArr o6reu pacrBopa reM )KepacrBopr4TeneM MerKrl r{ nepeMellruBaror. Ao pacrBopoBcpaBHeHvflHa cneKaroruHo-a6cop6quoHHoM I,Isuepxror nornouleHr,re u3nytleHllt TpoMerpe flpr.rAnuHe BoJrHbr 248,3 HM, r{cnoJrb3yrB KaqecrBer.rcroqHr4Ka v nraMq. Easonyro )Kene3HbrM Karo.qoM Bo3AylrrHo-arlerl4nenoBoe naMly c noJrbrM ycraHaBJrr4Baror 0,1 M pacrnopy asoruofi KLIcJIorbI. no Jrr4Hr.rrc BeJrrrqraHbr rrouronleHrlt or KoHCrpoxr xarr6ponoqnufi rpaQur 3aBilcr.rMocrr.r rleHrpauuu xeJre3a(rvmr/rvrn). pacrBopa. B rex xe ycJroBr{qxil3Mept}or nornouleHue LIcrIbITyeMoro B Co4epxanue )Kene3a npenapare B nporleHrax (X) BbrrrdcJrrroruo Qoprvryne:

Cx25 x 100

C
:_

X:
ax1000000

ax400

B rAe: C - rosqeHTparlur )KeJre3a lrcnbrryeMoM pacrBope, orpeAeJleHHat rlo Kanu6ponouHoMy rpaQlaKy,n uxr/rul; a - HaBecKa cy6crauqulvt,B rpaMMax. Co4epxaHue xerre3a B npenapare AonxHo 6utr He 6onee 0,0002 yo.

Cy;rrQarHaff 3oJrar{ Tflr(eJrbre MeraJrJrbl CynrQarnat 3oJIaus 1 r (rovuaa HanpeBbrruarr 0,1 oh u Ao:l.xHaBbIAepxLIBarbrrctlblTanecra) cy6cranqrr.r He AoJDKHa (ne 6onee 0,001 %o npenapate). n Hr4e rrxeJrbre MeranJIhI Ha Ocraroqnbre opraH[rrecKne pacrBop[TeJII{. B coorsercrBllu c rpe6onaHlr{Ml4 pacrBopl{TeJll{>. cKr.Ie opraHprrre O OC <<Ocraro.rgbre BarcrepnaJrbuble 3nAoroKcrlnu. He 6onee I,2Eg ua I rr.lrcy6cranquu. lnx npoaeplenvfl,rrcrrbrraHr.rrroroBrr ucxoAsrrfi pacrBop cy6ctanquu (xonqenrparlr4r 50 ur/rran),a 3areMpa3BoAtr ero He MeHeeqeM B 100 pas. Irlcnrrranue npoBoA.rrrAnr cy6cranqnn, flpeAHagnaqennofi Ant [p[roroBJIeHI4t prHbeKrlltoHHhrx JreKapcrBeHHhIX Qopvt. Mr.rnpo6noJlornqecKafl qncrora. B coorBercrBvw c tpe6onannxnru O{DC <Mrarpo6uororuqecKat qtacrora). KonuqecrBeHHoe onpeAeJrenne.Orono 0,1 r (rounax Hanecra) cy6craHquvpacrBoprror s 20 NarBoAbr,npu6annruor 0,5 rranI o/opacrnopa KaJIHt iro u[a, I vttt2Yo pacrBopa xnoprcroBo4opognofi KlrcJrorbrr,rurrpyror 0,0167 M pacmoporu ra-uu.rfio(uHgnrarop - 2 Mn paAara Ao [orBJreHr,rr crofiroro cra6o-cusero oKpalrrvIrlalalafl crBopa rpaxrraa-na). llaparr enbno IIpoBoAtr KoHTponrnrrfi o[bIT. 1 rran 0,0167 M pacrnopa KiuII4t ito4ara coorBercrnyer 8,824 rvr C6C3O6. or 3arrImIeHHoM cBera Mecre, B xopouo yKynopeHsofi HeXpaneHne. B cyxorra, MeraJrJrrrrre crofi Tape.

(@C I ATEHOJIOJT 42-02 9-07) (R^9)-2-t4-[2-fi.r4porcu-3-(2-npotlrlrlaMuHo)nponorcu]-QeHuir]aIreraMI4A

",", NH- Grz-"i *rcHcHH:C

o-\_J\--

cltr- cr

,p
NH2

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EAPr,tfl CyJIbOAT (@C42-0222-07) Bapun cyrr$ar tsaSOa

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M.tur.233,4A

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(ue 6onee0,001 Yov cy6craHqHu). Ha Mrrrursrc. I r cy6craHr\vrr4 ucnbrraHrre uuunax (ne AoJrxeHBLrAep)Kr{Barb o/o cy6cranqrau). 6onee0,00005 t Muxpo6uoJror[qecKafl qucrora. B cooreercrBLtn rpe6onanilr.uvr OOC <Mzc trr.rcrora)). rpo6uororuqecKar KurrKoanqecrBeHHoe onpeAenenue. Orono 2 r (rounar HaBecKa) cy6cranqur.r o/osre'aeuue xJropr4croBoAopoAnofi rncnors25 Trr npn nepeMeruuBanvu 100MJr co n 15 rvrnn. nepeHocrrna AsofiHofiQunrrp ((cr{HrtJIeHTa> OcaAor KoruqecrBeHHo (Dunrrp c Ha rpoMbrBarorroprvefi soAofi Ao orpr.rrlarenssofipeaKr1nn xJropr{Au. npLI nepeHocrrBoB3BeruenHufi TureJrb, ocropo)KHo o3oJurro! [poKiurr,IBaror ocaAKoM oC rrocrorHHofirraaccu B3BerrrraBaror. TeMneparype Lr 800-850 Ao XpaHenne.B cyxoru Mecre.

EPOMTEKCTTHA rrrIPOXJrOPrrA (DC 42-0223-07)

N-(2-Awtuno-3,5-4r.r6porr,l6ensun)-N-rr.reruJrrlr.rKJroreKcvrraMlu]g.a rr{ApoxJropnA

.HCl

C1aH2gBr2N2'HCl

M.wr.412.6

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q

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- 12,5x 0,46 cM c oKTaAerl[ncuJrr4Jr (C18), cr.rJll4Kareneu 3 vrxrr,r; - 6y$epnnfi pacrBopc pH 7,0 (80:20); - arleroHr4rpr.rrr IIo Cropocru rroroKa - 1,0 v'r.lvrwn; - crreKrpo$ororraetp cxnfr, 248 uv.; ute .{eremop - l0 rrarn. npo6rr O6rervr Konouxa
[pr4roAHocru cLIcreMbI.OrsocltXporrlarorpaQnpyror pacrBop AJrr npoBepKr.r 0,4; yAep)KuBaHr{r npllMecb C 6porrarexcvna- orco"uo KoM[oHeHToB: BpeMeHa TeJrbHbre 6pourercun - 1,00 (oxono 11 rranx).Paspeurenue (R) Mex,{y TIIKaMLI AorI}KHo6urr se ruesee12,0.

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BEpArrAMr{JrA rrrApoxJr opI{A (Dc 42-0224-07 )

2-(3,4-[utvreroxcu$enun)-5-[(3,4-AvMeroKcu$euerw)(uerun)-atmno]-2-(2nponur)neHTaHoHrTprdna ru.qpoxnopr4A
H:C_ .Cxl3 O-CH:

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C- w-C}t2CN

cxlz-N- CIrz-clt2

,Grz o

.Hcl

C27H38N2O4.HCl

M.r vr .49l ,1

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'HCl B nepecqere cyxoeBeruecrBo. Ha Cogepxzr HeMeHee 99,0yo C9H9CI2N3 rroqru 6erufi Kpl4craJlnrr.recrnfi noporuoK. Onncanne. Eenrrfi r.rJrkt HepacrBoprrM B PacrnopnMocTb. PacrnopzuB BoAe, cnnpre 96 yo,npaKTuqecKr{ xnopoSopl,re. flo4.nunHocrs.I,IH$parpacHrrfi cleKTpcy6cranqzu,cumrrfi B.ulrcKe rarux 6poc nonoc flonrorrleHrar Mr4AoM, o6racrz or 4000 ao 400 cu-l no noJro)KeHlrrc s AoJrxeH coorBercrBoBarb craHAapruoroo6pasqarnoQeruHa rr{rpoxnopl{Aa. cneKTpy o/o Ynrrpa$uonerosnfi cneKrp norurorrleHus,0,03 pacrnopacy6cranqlln B 0,1 M pacrBope s o6racru or 240 ao 300 HMAortrrcen uMerb xnopxcroBo4opognofi Kr,rcJrorbr MaKcktMyMbr 272 nv n 280 HMri rJreqoB rrHrepBaJre 263 lo 267 lav.. npu or peaKrlnro xnoprdAbr. Ha Cy6crauqur AaerxapaKrepuyro s 6u:rr ilporpavHocrb pacrBopa. Pacrnop0,5 r cy6craHrlt4n l0 r\arBo.qbr AoJrxeH grarosotvtI. [po3patrHbrM BbrAepxrrBarb ulrvt cpaBHeHI4e c ua IfrerHocrb pacrBopa. Pacrnop,[oJl)rqeHHrrfi ucnrrranvtur flpospavHocrbpas BbrAeplru{Barb c crBopa,AoJrxeH cpaBHerrue eranonou Y7. pH. Or 4,5 4o 5,5 (5 Yopacrxop). pacmeop.0,05 r cy6crauquu pacrBoptlor B 2r6-lmxnopaHnJrrrH. I,Icnwmyeuutil o/o 1: 1). 1 ur cuecz xnopoQopM cnupr 96 ( pacrBoptlor B 100 rr,rn clupra PacmeopcpasHeHut0,05 r 2,6-g*txttopaHuJrnna pacrBopapae6annrrcT 96 %. I rvrn nonyqeHHoro cnrnproM % lo 10 rvrn. 96 IfpuzomoeneHue KaMeput duasomuponaHun. rauepy c rpldreprofi xpuurrofi dnn B
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rroMerrlaror6rorc c 10-15 Mn xnopucroBoAopoAnofirprcnorbr KoHrleHrpuponaunofi. flepe4 rroMerleHraeM rrJracrIlHKLI KrrcJroryBHoctr 3-5 r Harpvfl. Hr4tpvra. B Ha lunuro crapra rrnacrLIHKLI cnoeM clrJluKarenx 60 F25a HaHoctr 10 rrarn co (0,5 vmr) pacrBopa cpaBHeHlrt.IIna(500 urr) xcrrbrryeMoro pacrBopa il 10 rr,mn 5 npo6alru cyruar Ha Bo3AyxeB TeqeHlde rtutt, rloMeqalor B crxHKy c HaHeceHHbrMr.r KaMepyco cMecbroyrnepoAa rerpaxnopr4A - Merauon (1:1) u xpouarorpaQnpyror BocxoArrrlr{MMeroAorvr. KorAa $ponr rroABr,rxHofi Qa:rr AofiAer Ao KoHrIarIJIacrr{HKLI, ee BbrHr.rMaror KaMepbr, r43 cyurar Ha Bo3AyxeB TeqeHue5 uun, npocMarplaBarorB noMelrlaror orMer{arorrrrrHo cy6cranqnu. 3areu rrnacrrrHKy VO-cnere npu254 HM14 rura$y s reqeHue 15 na 5 uun B KaMepy Anfl Aila3orrrpoBann4 cyilrar B Bbrr.f,xHorra MrrHr.rorrpbrcKrrBator %o 2 llero.rHbrM pacrBopou B-naorona. rrcnbrryeMoropacrBopa,HaxoflqrHo nocropoHHefi npzuecr4 Ha xpoMarorpaMMe 14 Ha Alr1r1eecr ypoBHe nrrHa 2,6-guxttopanrrnuna. rro coBoKyrrHocrrrBenraqI,IHbI vtHHe TeHCr.rBHOCTt4 OKparIIVtBaIIIdfl. AOIXHO rrpeBbrrrraTbr[flTHO Ha XpOMaTofpaMMe (ne pacrBopa cpaBHeHr4r 6onee 0,I oh). HaBecra) cy6cranllorepr B Macce rpr.r Bbrcy[rr{BaHrr[. Orono 0,5 r (rouHa.f, qur.r cymar npr,rreMrreparype or 100 Ao 105 oC Ao nocro.uHHofirraaccu.llorepx n MacceHe AonlKHa [peBbrrrrarr 0,5 o/o. Cy.urQauraff 3oJrar.rrqr(erbre MeraJrJnr. CynrQarHaq 3ora rs I r (rovuax ua[crIbITaBbIAep)IMBarb necra) cy6crauUurr He AoJrxrHa rrpeBbrllratr 0,I o/ou AoJrlKHa o/o cy6cranqnra). (He Hr4e rrlreJrbre MeraJrJrbr 6onee 0,001 s Ha xnopllAa lnporeHHocrb. Tecr-Aoga 50 ur cy6craHquu s 2 v,rrpacrBopa lr^arptrfl, oA 0,9 AJrr rrHbeKuuit sa 1 xr ruaccrr xr4BorHofo. Cxopocrr BBeAeHIat 1 rr,rn/wrus. r llcnrnasne npoBoAq Anfrcy6craHqzu, flpeAHa:naqennofi Anr [p[roroBJreHl,Ir r4HbeKrl[oHHbrx neKapcrBeHHbrx Sopr. OOC <<MuMurcpoduoJrorrqecKan qncrora. B coorBercrBvrLr rpe6onaulrqN{u c qrrcrora)). xpo6nonorr4qe cKaq Ko,ruqecrBeHnoe o[peAeJrenne. Oxo.no0,2 r (rovuax Harecra) cy6crauquv paxzcnoru, npu6anJrsror 25 wlyKcycHoro aHrI4ApI4Aa crBoprror r 0,5 lrr MypaBbr.rHofi r,rrrarpyror 0,1 M pacrBopoM xropnofi KrrcJrorbr rrorBJleHus3ereHoro oKpalxlaBaAo - 0,15 ur 0,1 o/opacrtopa KprIcraJIJILIqecKoro uttx (uyguKarop $zoneronoro). llapannenbHo rrpoBoArr KoHTponrnrrfi onblT. 1 nrn 0,1 M pacrBopa xnopuofi Kr.rcJrorbr coorBercrByer 26,66 Mf

HCl. ceHecl2N3'
XpaneHne. Cnucor A. B sarq[uleHHoMor cBera Mecre.

(@C42-0 46-07) KOAETTH 2

-MeroKcr{-4, -snorcuuopSuu-7-en-6-ol, MoHorrrApar (5R, 6 S)-N-Merr4n-3 5
Ct13O

N-CFI:

Cr8H21NO:'HzO

M.rv.317,39

Cogepxur He MeHee 99,0 o lr He 6oree 101,0 % CI8H21NO3n nepecrrere Ha cyxoe BerqecTBo.

Onncanne. Eenufi r.rJrr,r rroqrr.r 6enufi Kphcrannu.recrufi nopoilroK unz 6ecqserHbIe KprrcTaJrJrbr.

PacrnopuMocrb.Pacrnopuvr xzn.f,ulefi pacrBoprrM cnnpre 96 %. s BoAe, JrerKo B [oAlnnHocrr.I4HSparpacHufi cneKTp cy6cranquu,cuxrsrir ArrcKe rarur 6poB c MIrAoM, o6racru or 4000 ao 400 cu-l no rroJro)KeHr.rrc nonronregilrAoJrxeH s rroJroc coorBercrBoBarb cneKTpy craHAaprHoro o6pasqaKo,ueHHa. 0,01 r cy6crauqunnoMerrlaror MepHyro B ror6y BMecrr,rMocrbro un, pacrBo100 ptror B BoAe, npn6aenxrorl0 un I M pacrropaHarpvrfr, rr4ApoKcr4Aa r4AoBoArro6rervr pacrBopaso,qofiAo MerKr4. YnrrpaQuonerosHfi cneKTprrorJrorrleHr{r rroJryqeHHoro pacrBopaB rrHTepBane BonH 250 ao 350 nu AonxceH or r,rMerb roJrbKo oArrH MaAnr{H KcrrMyM 284 nu. npr.r K 0,01 r cy6cranquu rtpu6ayJrrrorI rvrn cepuofi xucrorhr KoHrleHTpr,rponanuofi u yo pacrBopaxenesa(Ill) xnopzga u HarpeBaror eo,UsHofi 0,05 un 1,3 Ha 6aue; nofrBrfl,ercs, cr.rHee oKparlr,rBaHne. flpu6aBJrruor 0,05 un asofirofi KLtcJrorbr KoHrIeHTpr{ponauHofi; pacrBopcraHoBt4Tc.rr KpacHbrM. Tervrneparypa nJraBrreHrrfl. 155ao 159'C. Or Ilporpaunocrb pacrBopa.Pacrrop 0,1 r cy6craHrlur420 r,rrBoAbr s 6urr Aonx(eH npo3paqHbrM BhrAep)KktBarb lrJru cpaBHeHue eranoHouI. c IfnerHocrb pacrBopa. Pacrnop,rroJrfreHurrfis r4cnrrranvpr flpospauHocrb paua crBopa,AoJrxeH rrJrpr BbrAepxr{Barb 6rrru 6ecqeerHrrM cpaBHeHr.re c eraronoira B9. -142 rc -146 o n nepecqereHa cyxoe BeruecrBo Vge.rnuoe BparrleHrre. Or (2 Yopacrvop cy6craHrlr,rr4cnr4pre96 %). B IlocroponHrre np[Mecn. OnpegeJreHn e rpoBoArr MeroAoM B3XX. Ifodeucrcnan 1,08 r Harpvrfl oKraHcyJrb$ouara noMerrlaror MepHyro B Qasa @@). pr ron6y BMecrl{Mocrblo1000 nrn,npu6anraror 20 tvtl yrcycnofi Kr4cJrorhr ne,u-rHofi 250 vtt aIIeroHI,ITpvIila, Bcrpflxr.rBaror pacrBopeHvrr.rAoBoArr o6reu pacrBopa Ao goAofiAo MerKrr. pacmeop.0,1 r cy6cran\vu kr0,1 r narplar oKraHcynrSoHara paIzlcnutmyeuatil crBop.rrror ilO u pas6aerqror s fI@.uo 10 run. Pacmeop cpasHeHun 0,005 r craHAaprHoroo6pagqarpr{Mecr4 roAezHa A. A
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- 25 x 0,46 cu c oKraAellvurcr4rtvtr (C I cl4JlrrKafeJlerr,r8), 5 urn; - KOMHATHAq; TeunepaqrpaKoJroHKr4 -2,0 wllwtuu; Cropocrr rroroKa - cneKTpo$oronrerp 24 uuecrcui4 5 urvr; !ererrop - 10 ur<n. npo6u O6rerr.r Konosra
Xpouarorpa$upyror pacrBop Inr rpoBepKr.rnprrroAHocrr{ xpoMarorpaSn.recr<ofi rIpI4MecI4 Aolxuo 6urr ue A 14 KoAeI,IHa rIktKoM Paspeueurre MexAy nr4KoM cr.rcreMbr. rr.teHee 3,0. rrllKa KoAeLIHa 6 uus. OpzenrupoBoqHoe BpeM{ yAep)KI,IBaHLIt B. llqrr pa3 xpoMarorpaQlrpylor pacrBop cpaBueHIas OruocrareJrbHoecraHAaprHoe orKJroHeHr,re nnoulaArr nrrKa KoAeI,IHa AoJIxHo Ant 6nrr se 6oree 5.0 %. Xpolaarorpa$upyror r4cnbrryeMrrfipacrnop u pacrBopbr cpaBHesus E u B. Bpenax xpoMarorpaQuponaHnflvcnbrryeMoro pacrBopa AoJrxHoHe MeHeeqeM B 10 pas 6rrrr yAeplrl4BaHuflnvtlrra KoAeI4Ha. 6olee BpeMeHra IlnorqaAr nr.rKarrptrMecz A Ha xpoMarorpaMMe r,rcrrbrryeMoropacrBopa Aonxua 6urr se 6oree rnoilIaAl,I II,IKa Ha xpoMarorpaMMe pacrBopa cpaBHeHI4tE (ne 6oree 1,0 oA). LlcrblTyeMoropacrBopa llnorqa.qr uuxa nro6ofi apyrofi rprlMecu Ha xpoMarorpaMMe B [r,rKaHa xpoMarorpaMMepacrBopa cpaBHeHI{s (ne 6rrrr ne 6olee rrJroruaAr{ AoJDKHa npvv'ecu C (7,7',8,8'-rerparnApo-4,5a: 4', 6onee 0,2 %).llpu oqeHKecoAepxanvrfl. -17 5'c,-Ausuorcn-3,3'-4I,IMeroKcpl ,I7'-gurrrerut-2,2'-6urraopSuuauun-6o,6'a-Auott; - oKoJro oruocureJrbHoBpeMeHr,r yAep)KI,IBaHvAtruKa xo4euna) yAepxr.rBaHr.rr{ 2,3 BpeMrr hnoqa.ur rr.rKayMHoxalor ua0,25 ($arrop ropperqzrE). Cyurr,rapnoe cogep)Kalvre npvnuecefi (rporvre rpr4Mecr4A) 4onxno 6urr ne 6oree 1,0 Yo. Ilorepn B Macce nprr BbrcyrlrrBaHrrn. Oxono 0,5 r (ro.rHar HaBecra) cy6craHqur cyrrar rpr4 reMneparype or 100 ao 105 oC Ao rlocrotHHofi ruaccrt. llorepr n MacceAoJDKHa 6urr or 4,0 lo 6,0 o/o. CynrQarHafl 3oJla n rrxeJrbre MeraJrJrbl. CyirrQarHat 3oJIalas I r (ro.*rax uaI,IcnbITarrpeBblluatr 0,1 o/ou AottxHa BblAepx(IrBarb necxa) cy6craHqur.r He AoJrx(Ha (se 6onee 0.001 o/os cv6crasuuu). Ha Hr,re rrxeJrbre MeTaJIJIbI

ocraroquble opraHl'rqecKl{e pacrBopureJrlr.B coorsercrBrdr.rrpe6onaHr.rf,Mr4 c OO C <<O craro.rHbre opraHr4qe cKr.re pacrBopr.rreJrrr)). Murcpoduoror[qecKafl rr[crora. B coorBercrBr4vrrpe6onanuxruu c O<pC<Mzqvcrora)). rpo6v onorr.rqecKar Ko'rn'recrBeHHoe o[peAeJleHne. Orono 0,25r (ro.ruarnanecxa) cy6crauquupacrBopfror r 10 rvrn yrcycnofi KrrcJrorbr 6esrognofi, rtpu6awtsrcr20 MJr.4r.roKcaHa r4 rl4rpyror 0,1 M pacrBopoM xropHofi Kr.rcJrorbr (uH4urarop 0,05 ur 0, r %opacrvopa Kpr.rcrilJrnr4qecxoro @zonerororo). 1 ur 0,1 M pacreopaxnopHofirzcnorbr coorBercrByer29,g4rrar c1gH21No:. XpaHenne.cuncor E. B cyxou, 3arrrr4ureHHoM or cBeTa Mecre.

KOAET4HA OOC@AT (<DC 42_0247_07)

JrYrI{npaT

(5R,6s)-N-uerzn-3-neroxcr.r-4,5ouoxoruop$un-7-es-6-or SocQar(1:l), uo_

H3POo

'lrtlro

N-

CFI:

. . c18H2rNO3 H3PO4 ll2H2o

M.u. 406,4

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'ONYqEHHOTO PACTBOPA B IIHTEPBAIIE ANPIH BOJIH OT 250 rc 350 HrrAAO',KCH I,IMCT'

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KOOETTH (@C42-02 48-07) I,3,7-Tp urrrerrt- | H -ny puu-2,6(3H,7 I7) guoH, oHorr4Ap M ar n

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B Co4epxur He MeHee99,0 oh CSH10N4O2 nepec{ere Ha cyxoe BelrlecrBo. rrroJrbrrarbre KpracraJrJrbr 6e.;.l.;'i,t utu Kpl4crannuOnncanue. Ferue [reJrKoBr{crbre qecnufi lopo[roK 6es gauaxa. Ha nos4yxe BbrBerprrBaercfl,, nprr HarpeBanvruBo3roHreTcr. PacrnopnMocrb. Jlerro pacrBopr4Mn ropxvefi BoAev xropo$opMe, yMepeHHo (rrae4reuHo) pacrnopuM B BoAe,MaJro pacrBopr.rM 3TaHoJre %. B 96

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ftro4lnnHocrr. lln$parpacurtfi cnercrpcy6crauquu, uurufi B AncKec xanux 6poMlIAoM,s o6racru or 4000 Ao 400 cu-l .uonxeH coorBercrBoBarb rro rronoxeHxro noJloc rlornoIrleHl{t pucyHKy crreKrparoSenna MoHorr4Apara (flplrnoxenue l). o/opacryopacy6crauquu n 0,1 M YnrrpaQuoneroeHfi cneKrp nonrorrleHras 0,001 pacrBope xnopktcroBo4opogHofiKr{cJrorhr o6racrz or 250 Ao 300 HMAonxeH rrMerb e MaKchMyM npu273 uw. 0,01 r cy6cranqnlr noMelllaror n $ap$opoByro qarrrKy,npn6anrtqror 0,5 lrr BoAopoAa lrepoKcuIa,0,5 vl xnopl4croBo4opo4nofi KlrcJrorbrpa3BeAeHHofi o/ou sst8,3 rlapvBaror Ha BoAtHoia6aue Aocyxa. Ocraror cMarrr.rBaror lrn pacrBopa aMMr4aKa; 0,1 notBJltercx xpacHo-Sl4oJleroBoe oKpamr.rBaHrre. repexoArrrlee trepe3 10 lrun B nypnypHo-KpacHoe. 0,05 r cy6crauqurr pacrBoptror B 5 ur roprvefi nogrr, oxJrax.qaror,npn6arrtarcr 0,2tvttt 0,1 M pacrBopa irola He AoJrxHonorBkrrbcr Hr4ocaAKa,Hv noMyrneuzr. flpu npu6auerull4 HecKoJIbKLIx Kanenb xJropucroBoAopoAHofiKncJrorbrpasne4eunofi o o6pasyercx 6ypufi ocaAoK, pacrBoprlMHfi 8,3 r us6HrKe pacrBopa Harpr,rflruurwt Karlufl rr{ApoKcr,rAa. ApoKcr4Aa Tervrneparypa rrJraBneHnfl.Or235 po238 'C (rraero41). Cy6cranrrurc npeABapurenbHo Bblcymr{Baror rrpu 80'C Ao nocrorssofi Maccbr. llporpauHocrb pacrBopa. 1 r cy6craHrlr.rupacrBopflror e 10 MJrcBelKerrpoKr.rnrqeHHofi roprvefi BoAbILtrorqac EpoBogxToflpeAeneHze.Pacrsop Aonx(eH6urr npogralOHOrvr 3parIHbIM LIII{ BbIAepxs.IBaTb CpaBHeHne C I. Ifnernocrb pacrBopa. Pacrnop, rroJ4rqeHurrfis racnrrranvlrna flpospa.ruocrb pacrBopa, AonxeH 6urr 6ecqserHHM ItJIt4BbrAepxo,rBarb cpaBHenr.re eralonou 89. c Knc.uorHocrb rrJrrluleJroqnocrs.0,2 r cy6cranuprr4 pacrBoprror e l0 NarcsexenpoKu[sqesnofi ropauefi BoAbr. K oxnaxgeH]roMy pacrBopy npu6auxror 0,1 ul pacrBopa 6pournuoJroBoro cl,rHero; norBr.rBrrreecrxeJrro e vnrvr3eJreHoe oKpaI[I,IBaHI{e Aonx(Ho nepexoArrrb B cr{Hee or npu6anrenvfl ne 6onee 0,1 un 0,02 M pacrBopa HarpLrflrlcApoKcr{4a.fIpH rrorBJreHrara cr{Hero oKparrrr4BaHr.rr oHo nepexoAlrrb B xeJIToe or npz6aBrenkrfl, 6olee 0,1 ul 0,02 M pacrBopa AoJIx(Ho ne xnopncroBoAopoAnofi rucnorrr. IlocropoHnrle npnMecn. Irlcnatmyenuil pacmsop. 0,2 r cy6cranrrr4rrpacrBoprror s l0 rar cMecu xnopo$opM - Merauoir (3:2). Pacmeop cpasHeHus.0,5 ur ucnblryeMoro pacrBopa pas6annrror cMecbroxJropo(3:2) ao 100 rran. Soprur MeraHoJr Ha nuuvtto IIJIacr[HKz co cJroeM c]rJrr4Kare 60 F254 HaHocsr 10 urn ns (200 rrarr)ucnuryeMoro pacrBopa, l0 urn (1 narr) n 5 narn (0,5 vrrr) pacrBopa cpaBHeHllq. IlracruHKy c HaHeceuHuuu upo6aMr.r cyruar Ha Bo3Ayxe, floMelqarcT B KaMepy co cMecrro 6yranoJr - arleroH - xJropo$oprvr aMMr,raKa p a c r B o p K o H r l e H r p t 4 p o B a H H b r5r % ( 4 : 3 : 3 : l ) u x p o M a r o r p a $ u p y r o r B o c x o 2I ArrrlrrM MeroAoM. KorAa $ponr roABr.rxHofi $asu Aofiger Ao KoHua rrJracrrrHKr{, ee BbrHr.rMaror KaMepbr,cyrxar Ha Bo3Ayxe u npocMarpuBaror B H3 Y(D-csere npu 254 uv'. flsrHo nocropoHHefi npurraecr{ xpoMarorpaMMencnbrryeMoro pacrBopa rro coHa BOKynHOCTLI BeJIHtrlIHbI I4I{HTeHCr4BHOCTr,I flODIOIIIeHI4' AOIXHOnpeBbrrrrarb He ruITHo Ha xpoMaro{paMMepacrBopa cpaBHeur.ur uxr) (ne 6olee 0,5 Vo). (l EB

Peeylrtarbl I{crIbITaHvs. cquraforc;{ AocroBepHbrMu,ecJrr.r xpoMarorpaMMe paHa rrerKoBr4IHorrrHo. crBopa cpaBHeHuq (0,5 narcr) flocroponHlle aJrKaJrolIAbLK 10 rran2 o/opacrnopa cy6cra*r\Lrv npu6annxror 0,2 vx peaKrr4Ba Mafiepa; He AonxHo ua6nro4arbcr noMyrHeHprr pacrBopa. OprannvecKrle [plrMecfi. Pacrrop 0,5 r cy6craHur{u s 5 Narcepnofi Kr,rcJrorbr KoHrleHTpr4ponauuofi u AorrlreH 6rnr flpo3patrHhrrrl 6ecqnerHbrM. Pacrnop 0,5 r cy6cr:anr].prv 5 N{r asorHofi Kr{cnorbrKoHrleHTpt4porauuofi.4onxeH s 6urr npo3parrr{brNa6ecqserHbrM. u Ilorepn B Macce rrpu Bblcy[rrrBaHr{n. Oxoro 0,5 r (rouHatr HaBecra) cy6cranquv cyrrar npl{ reMneparype 80 "C no rocrorssofi Maccbr.florepx B MacceAonx{Ha 6rrrr He MeHee 4,0 You ue 6olee 8,5 oh. X.nopu4u. I r cy6craHuur4 Bcrptxl4Balor B TeqeHne I rrausc 5 ul ropx.reii BoAbr, par6aelxror roAofi ao 50 rr,rn Sumrpyror. 10 rvrnSllnrrpara IoDnHbr BbrAepx{r.rBarb u r4cnbrraHrre xnopu4sl (ne 6olee 0,01a n cy6crauqur4). Ha Cy.rrrQaru. 10 rvrn B na Sunrrpara, rIoJIyrIeHHoro ucnbrraHr.ru Xnopr4Abr, AoJrxHbr oAn cy6craHw4kr). BbrAepxlrBarbr4ctrrbrra[vre cynr$arrr (ue 6onee 0,05 Ha Cy.nrQarHafl 3ora rI Tfl?I(eJlbre MeraJrJrnr.CynrsarHar 3oJrazs 1 r (rovHax nanecra) cy6crauqurr He Aonlr(Ha[peBbrrrrarl 0,I o/ou AoJrxHaBbrAepxcr,rBaTb r{cflbrTaa/oy cy6craHqura). HIaeHa rnKeJrbreMeraJrJrbr 6onee 0,001 (He Ocraroqnble oprannqecKrle pacrBop[TeJrr.r.B cooreercrBuvt c rpe6onaHvflvtvr O O C <<Ocraroqubr opraHr.rqe p e cKr.re acrBopraTeJrrr). Mnrcpo6uoJlornqecKaff rlncrora. B coorBercrBuvrc rpe6onanusl,rra OOC <Mnxpo6uolorr4rrecKar qrrcroro). Ko.uuqecrBeHuoe o[peAeJlenue. Oxoro 0,15 r (rovHar uanecra) cy6crautTvru, rlpeABapureJlbHo BblcyureHHofi rrocrorHuofi uaccnr, pacrBoprror s 2 Mn xJropoAo npz6auxror 40 rran yKcycHoro aHrr4Apr{Aa rrrrpyror 0,1 M pacrBopoM)sropu Sopua, sofi xucnorbr Ao )KeJrroro oKparrrr4Bayux (uuguKarop - 0,1 rrar 0,I oh pacrnopa KpncrtrJrJrr{qecKoro Sraoneronoro). flapannenbHo rpoBoArr KoHTpolrHufi orrbrr. 1 rr.rn M pacrropa xlopHofi Kr.rcJrorbr 0,1 coorBercryyer 19,42 rvrrC3H1gNaO2. XpaHenne. CuucorcE. B cyxorra Mecre.

(D KOOETTH BE3BOAHbrtrr C 42-024e-07 )

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c8HloN4O2

M.n. 194,19

Co4epxzr He MeHee99,0 yo C8HI0N4O2B repecqere Ha cyxoe BerrlecrBo.

utu 6etrcli.tKpl4crannuOnr.rcanlle. Eenrre uenKoBlrcrbre r{ronbqarbreKpr{craJrJrbr .recrNfi noporroK 6es :anaxa. Ha nos4yxe BbrBerpvtBaercfl., npv HarpeBanuvIBo3roHteTct. PacrnopHMocrb. Jlerro pacrBopr4Mn ropx.reli BoAer4 xnopoQopMe, yMepeHuo (lre4neuuo) pacrnoprzMB BoAe,Mano pacrBoprrMB graHone96 %. flog.nnnnocrs. I4n$parpacHrrfi cneKrp cy6craHqnu, cuxrrtir B AIrcKec xalnx 6pononoc ilorJrouleHll.n Mr.rAoM, o6racru or 4000 Ao 400 cM-rno noJroxeHr.rn e AonxeH xoQeuua 6essoAHoro. coorBercrBoBarbcneKTpycraHAaprHoroo6pa:qa 0,001 ohpacrvopa cy6cranqzu s 0,1 M Ynrrpa$uoneroerIfi crreKrp norurorrleHras pacrBope xnopr4croBogopognofiKr4cnorbr o6racru or 250 ao 300 HMAonxeH LIMerb B npu273 uwl MaKcrrMyM npu6aernor 0,5 ul BoAo0,01 r cy6cranqur4 noMerrlarorn Sap$opoByro qarrrKy, poAa nepoKcilAa, 0,5 nrn xJroprrcroBogopo4nofi KlIcJIorbI pa3BeAeHHofi o/ou sst8,3 0,1 napr,rBaror BoArHoir6ase Aocyxa. Ocrarox cMaqr,rBalor un pacrBopa aMMI4aKa; Ha qepe3 10 rvrIau nypB rtepexoA-f,ulee norBJrrercr rpacHo-$r4oJreroBoeoKpar[r{BaHr,re, nypHo-KpacHoe. 0,05 r cy6craHqur4 pacrBoprror B 5 un ropxvefi no4rr,, oxnaKAalor, npu6anlxror Hr4 norBktrbcqHr{ocaAKa, noMyrueuux. flpu 0,2wtl0,l M pacrBopa itola; He AoJrlKHo pasre4eunofi Kanenb xnopucroBoAopoAnofi KI4cJIoTEI npu6aareHur.r HecKoJrbKr.rx yo o6pasyercx 6ypsti,tocaAoK, pacrBopr4MHfin Irs6HrKe pacrBopa Harplrfl rvt8,3 rLIApoKc}rAa. ApoKcr{AavJrvrKalrvtfl. Terrneparypa rrJraBJreHrfl. 235 to 238 'C (uero4 l). Or oC Cy6cranqr4ro npeABapnrenbHo Bbrcyul4Balor npu 80 Ao nocroxnnofi MaccbI. Ilporpa.rHocrb pacrBopa. 1 r cy6craHtlvtrrpacrBoprrcr e l0 Mn cBexerpoKilntqeusofi ropauefr BoAbr Torqac npoBoArr orrpeAeneHue. 6uru npoPacrsop AoJInreH r4 r{irr4BbrAepxr.rBaTb cpaBHeHr.{e eraronou I. c 3paqHbrM e Ha I-fnerHocrb pacrBopa. Pacrnop, rroJrytreHHrrfi ucultTalavwr flpoepauHocrbpaBbrAepxl{Barb c cpaBHeHI.IearanoHou 89. crBopa, .qonlKeH 6rrrr 6ecqserHHu vrJrvt Knc.norHocrb rrJrrruerorrHocrs.0,2 r cy6cranqxu pacrBopqror e 10 NarcBe)I{eropruefi BoAbr. oxrax4eHHoMy pacrBopy npu6auaror 0,1 un paK ilpoKr4nrtrenHofi xeJrroe vrvt 3eneHoeoKpaIxIdBaHIte crBopa 6polrruuoJloBoro cr{Hero;rrorBplBllreecr He B AonxHo nepexoAt4rb crrHeeor npu6anneHvfl, 6oree 0,1 un 0,02 M pacrBopa Ha'tpr4flrurpoKcr{Aa. flpu nornnela}rvtcuHero oKparrrrlBaHr{r oHo AonxHo nepexoAllTbB xenroe or npu6arJreHru se 6oree 0,1 ur 0,02 M pacrBopa xnopIrcroBo4opo4Hofi
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Ha xpoMarorpaMMe pacrBopa cpaBHeHrar uxr) (ne 6onee 0,5 oh). (1 Pe:ynrrarbl l4cnbrranprfi, ouwrarorcr AocroBepHbrMr.r, ecJrv Ha xpoMarorpaMMepa(0,5 crBopa cpaBHeHrds uxr) qerKo BrrAHo rrrrHo. flocroponnl{e aJrKaJroLrAbI. 10 run 2 oh pacryopa cy6cranr\krr4npra6auxror K 0,2 wn peaKrrrBa Mafiepa; He AonxHo ua6moAarbcqroMyrHeHrarpacrBopa. OpraHn.recKlre npLIMec[. Pacreop 0,5 r cy6cranrp4u n 5 rur cepHofi Kr4cJrorbr KoHrleHTpr4porauuofi 6urr npo3parrubrra 6ecqeernbrM. u AonlKeH Pacrnop 0,5 r cy6cranqmpre 5 N.{rasornofi Kr.rcJrorbr KoHrleHTpr4ponaunofi AonxeH 6rrrr npo3paqHbrNt 6ecqserHbrM. l,t ilorepx B Macce nplr BbIcyIunBaHI{t{. Oxono 0,5 r (rovHar HaBecxa)cy6cranqrur cyurar npLITeMfleparype80'C Ao flocroqnuofi Maccbr.llorepr B MacceAonxHa 6rnr He 6oree 0,5 oA. Xnopngu. I r cy6craHr\prr4 Bcrprx[Baror B Teqeuue 1 uzu c 5 ur ropx.refi BoAbr, pas6annrrcr eoAofi ao 50 mn n Snnrrpyror. l0lrn Sunrrpara AoDKHbrBbrAepxr,rBarb rrcnbrraHr.re xnopugrr (ne 6oree 0,01o n cy6cranqar). Ha CyrrQaru. 10 rran B na $unrrpara, rroJryqeHHoro rrcrrbrraHr.rlr X.noplrAbr,AoJrx(Hbr BbrAep)Kr,rBarb r4crrbrranneHa cynrQarrr (ne 6onee 0,05 oh r cy6cranquu). CymQarHafl 3oJraH TflxeJrbre MeraJrJrbr.Cynr$arHar 3oJrans I r (rounax Harecxa) cy6crauqur4 He AoJrlKHa flpeBbrrrrarr 0,1 o/ou AonxHa BhrAepxr4BaTb LtcrrbrTao/on cyicraHrlura). Hrre Ha rnKeJrbreMerrurrrbr(He 6onee 0,001 Ocraro.rHbre opraH[rrecK[e pacrBopr{TeJrrr.B coorsercrBvrv c rpe6onanvrflMvr O OC <Ocraroqnbre opraHrlqe cKue pacrBoprrrenr,r>. Murcpo6noJror[qecKafl qlrcrora. B coorBercrBvrvc rpe6oranusMlr OOC <Mprxpo6uororrrqecKair qr,rcrora>. Ko.rrnqecrBeHHoe orpeAeJrenne.Oxono 0,15 r (rouuar uaaecra) cy6craHqzu, rlpeABapurenbHoBbrcyilreHHofi.qo ilocroqHHofi ruaccrr, pacrBoprrcr s 2 ur xnopoyKcycHoro anrvqpv4ar.r rr,rrpyror 0,1 M pacrBopoM x.rropnpu6annaror 40 rvrn Qoprvra, nofi rzcnorbr Ao xenroro oKparrr{Bauux (uuanKarop - 0,1 rul 0,1 oh pacrnopa Kpr,rcrannfiqecKoroQuoner:onoro). llapa-unenbHorpoBoA-flr KoHTpoJruufi orrbrr. I ur 0,1 M pacrnopa xnopnofi Kr4cJrorbr coorBercryyer 19,42 nrr C3H1gNaO2. XpaHeHne. Cuucor F. B cyxorr,r Mecre.

(@ JTEBOMT4TIETT4H C 42-02s 0- 0 7 ) 5-N-[(1R,2R)-2-firaporcu-1-(rnApoKcrrMernn)-2-(4-HurpoQeHut)erun]-2,2Ar,rxJropaqeTaMr.rA

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M.rr,r.323,13

Cogepxnr He Menee99,0 o C1H2CI2NZOS B repecqere Ha cyxoe BelrlecrBo. )KeJrroBaroOnncanne. Or 6eroro Ao 6enoro c cepoBarbrM,xeJrroBarbrMLrJur 3eJreHoBarbrM orreHKoM Kpr{crannu.recxufi loporroK, ToHKile KpvcraJrnbrrrnu npoe ,qonroBaTbr rrJracTrrHKr{. PacrnopnMocrb. Jlerro pacrBopr,rM crrr4pre96 o , pacrBopr4M gTr,rJrarlerare, B B pacTBoplrM BoAe. MaJro B fioAnnHnocrr. IrlnSparpacurrfi cneKrp cy6cranqHu, clettttir.B ArrcKec ranlra 6poMriAoM,e o6racru or 4000 Ao 400 cu-l no rroJroxeHr.rrc floJrocnornoqeHr4r Aonx{eH (flpunoxeHze 1). coorBercrBoBarbpHcyHKycneKrpa neBoMr.rqeruna Cnexrp roilrorrleHut 0,002o/opacrcopa cy6craHquu r 0,1 M pacrnope xnoplcrorrpu BoAopoAHofi rucnorur s o6nacru ot 220 ao 400 HM AonxeH rrMerb NraKcr{MyM 278 uwrkl Mr,rHrrMyM rpr{ 237 lnv'. rr{Apo0,1 r cy6craHrlr4rr HarpeBaror Ha BoAsHofi 6ane c 5 rvrnpacrBopa HarpLrfl, Kcr4Aa; norBJrrercq x(erroe oKparrrnBaHr,re, nepexoArnlee B KpacHo-opaHx(eBoe. llpu ocaoKpacKaycvnrrBaerc.f,,BbrilaAaerKuprluqHo-KpacHbrfi AalrHefirueM HarpeBan:aur o6napyNusaeNarrfino 3arraxyu no nocuHeHlaloeraxHofi AoK H BbrAenrercr aMMr,raK, naKMycoBoit6yv'aru. Pacreop, nonyqeHHufi n npe4brAyrrleMr4crbrraHr{u, nefirpanr{3yror agourofi rucyuneepcamHofi u $unrrpyror. (Dumrorofi pa3BeAeHHofi 6yrvrare no r{HAr4KaropHofi peaKrlr.rro xJropHAbL Tpar Aaer xapaKTepHyro Ha oh pacrnop cy6cratr\rrLr B cnr.rpre 96 % Bparqaer rrJrocKocrb iloilflpvsa\flvr 5 pacrBop cy6cranqur,rB 3Tr{Jrarlerare BJreBo. B[paBo, a 5 o/o Tervrneparypa rrrraBrreHnq.Or 149 ao 153 "C. (5 BparrleHrre. +18 ao +21o B nepecqereHa cyxoe BeufecrBo %paYAe.nrHoe Or crBop cy6craHqurr B cnnpre 96 %). rrorurouleHrrfl.Or 290 ao 305 B repecqere Ha cyxoe BeYAe.nrHrrfi norcagareJrb o/opacrnop n 0,1 M pacrBope xnopprcroBogopo4Hofi rrlecrBo (0,002 Kr.rcJrorbr MaB Kcr4MyMe nornouleHvfl npu 278 urvr). Ilpo:paunocrb pacrBopa. 0,5 r cy6cranl\uLr pacrBoprrcr e 10 Mn cnlrpra 96 %. Pacrrop AoJrxeH6uru npo3parrHbrukrrrvt BbrAepxr4Barb cpaBHeHrae sranoHoN{I. c Ifnernocrb pacrBopa. Pacrnop, rroJryqeHHrrfi ucnrrrar'nvt na llpospauHocrb pan crBopa, AonxeH BhrAepxotBarb cpaBHeHr4e erarouoru Y5. c Kuc,rorHocrb rrJrrruerorrHocrr. 0,1 r cy6craHrlr{u BcrprxrrBarcr c 20 MJrBoAbr,

ErcI

cBo6oAHofior yrneKl{cnoro ra3a, B TeqeHr,re tvru:a rtpn6arrrrxror0,1 rran0,4 Yo pa2 u crBopa 6polarnnaonoBorocLIHero.Oxpacra vHAr4Karopa or AonxHa r43MeHurbc.f, rrpu6asreHz.f,ue 6onee 0,1 ul 0,02 M pacrBopa xnopprcroBoAopoAnofixl,tclomr zln 0,02 M pacrBopa Harpufl rrrApoKcrrAa. IlocroponHue nprlMecm.I'Icnutmyeuait pacmnop.0,1 r cy6cranr\uvrpacrBoprlor s l0 r,rr aueroHa. Pacmeop cpasHeHun0,5 na.n pacrBop A pas6annrror arleroHoMAo 100 vrn. Ha nr.rHr.rrccrapra rrnacrr.rHKr4co cnoeM ckrrxKarer-s 60 Fzs+ HaHocrr (200 uxr) vcrhrryeMoro pacrBopa,20 urcn (1 nmr) rE 10 rvmn(0,5 rvmr)pa20 rr,mn crBopa cpaBHeHI{t. IlnacrlrrrKy c HaHeceHHbrMr4 npo6auu cylrar Ha Bo3Ayxe,rroMerrlalor B KaMepy co cMecbro xnoposopu MeraHorr BoAa (90:10:1) vr xpoMarorpaQupyror BocxoAtIrII4MMeroAovr.KorAa Sponr rroABrrxHofi Saerr AofiAer ee r.r3 IO KOHIIanJIaCTLIHKI4, BbIIIIIMaIOT KaMepbr,CyilraT Ha Bo3Ayxe il npocMaTpuBaror s V(D-cnere rpkt 254 lev.. IqrHo rlocropoHHefinpzrvrecr4 xpoMarorpaMMe Ha rrcrrbrryeMoro pacrBopa ilo coBOKyTTHOCTn BenI4qI4HbI I4HTeHCr.IBHOCTr4 H rrOnrOrrIeHvISHe nrTHo AonxHo npeBbrrrlaTb Ha xpoMarorpaMMe pacrBopa cpaBHeHrdr urr) (He 6onee 0,5 %)..{onycraercx (1 I'THO Ha rwrlJvtu cTapTa. Cyl,rrraapHoe coAepx(aHve nprrMecefi4onxHo 6rlrr se 6olee 1,5 o/o. Pesylmarbl LIcrIbITaHur, c-uvrrarorc.x ecJIHHa xpoMarorpaMMe paAocroBepHbrMr{, (0,5 crBopa cpaBHeHr,rr narr) qerKo Br4AHo nrrHo. X.nopugu. 0,3 r cy6cranquuBcrpflxkrBaror B TerreHr{e lrns c 15 rr,rn I BoAbrra$unrrpyror. 10 un $ulrrpara AonxHbI BblAepxr,rBarb r4crrbrra:aue xJroprrAbr (ue 6onee Ha 0,01o n cy6cranqzr4). fforepn B Macce flprl BblcyuruBaHlr[. Orono 1,0 r (rovHar HaBecKa) cy6cranquu cyruar nprr reMreparype or 100 ao 105 oC Ao rocrorHHofi uaccrr. llorepr n MacceHe AonxHa rrpeBbrrrrars Yo. 0,5 CynrQarnafl 3oJralr Tsxerble MerarJnr. Cynr$arnafl 3oJra I r (rounar Hau3 necra) cy6craHquu He lonx(Ha npeBbrrxaru 0,1 oh u 4onxHa BbrleplKrrBarbr.rcrrbrraHr.re rflxeJrbreMeraJrJrbr 6onee 0,001 oh y cy6wauquu). Ha (He Ocraro.I uble opraH[qecKue p acrBopnreJrrr. B coorser crBuvrc rpe6ona HuflM:a O O C << craro.{Hhre opraHrzlre O p cKr4e acrBoprrreJrr4). Mlrrcpo6uoJlornqecKafl qrlcrora. B coorBercrBvtuc rpe6onanzrlaraOOC <<Marpo6uolorr4rrecKat r{ucrora). KolHqecrBennoe o[pereJreHne. Ororo 0,5 r (rouuar Hanecxa)cy6craHquv roMelqalor B KoHl{qecxyro ron6y BMecrr4Mocrbro250 vt, npz6annxrcr 20 lrn xnopucroBoAopo4nofi Kucnorbl KoHlleHTpnponauuofi u ocropoxHo, He6onrruzulE nopqvrlMll, 5 r qunronofi nrrnz. Ocrarru quHxonofi nbrnz cMbrBalorco creHoK ron6u 10 un xJlopl{croBoAopoAHofi rucnorrr KoHueHTpLrpoBaHHofinepeuerxnBaror Ao u noJlHoro pacrBopeHllt IItlHKoBofi nrrnu. Iloryuennrrfi pacrnop Tr4TpyroT HrlrplrToMeTpvrlecKI{. flapannelbHo npoBoArr KoHrponrnufi onhrr.

I nar0,1 M pacrnopalaarpvfl:avrrpvra coorBercrnyer32,31rrar C11Hl2Cl2N2O5. XpaneHue.Cnucox E. B cyxona, 3arrlr{ueHHoM cBeraMecre. or

3 7. 3 a K . 2 7 6 8

EA

rr{APOXJIOPIIA(DC 42-02sI -07 Jrr4IOKAr4HA )

N-(2,6-,{urr,terluSenul)-2-(guerl4JraMl,IHo)aqeralazga ruApoxJlopuA MoHorl4.4par

(-tr
CH3

NH-C-Or-\ bHs

o tl

GHs

HCI

Hzo

.HCl .HzO cl4H22N2O

M .r r l.288,82

Ha B 101,0ohCAH22N2O'HCl nepecqere r,r 99,0Yo He6oiree CogepxurHeMeHee BeulecrBo. 6eseo.uHoe

O n n c anue. Benufi Kpl{criurJrl,I.Iecr[fr ilopo[roK. PacrnopnMocTb. O.IeHr JIerKo pacTBopI4M B BoAe, nerKo pacTBopIIM B crrr4pre96 %. floAnnHnocrr. I,InQparpacnrrfi creKTp cy6craHqrau, cytrtti.t B ArIcKec ra-nux 6pos Mr.rAoM, o6racru or 4000 Ao 400 cM-r Aor)KeHcoorBercrBoBarb no rloJloxeHldto rl,IApoxnopl{Aa. o6parqa nI,IAoKaI4Ha rronoc rornorrlegrlt clreKrpy cTaHAapTHoro 0,2 r cy6craHrlr4r{pacrBoprror s 10 MJrBoAbIu npu6annqrcr 10 tv,l I YopacrBopa xacnoru. llonyvensrrfi oca.qoK(nurpar) npoMblBalor no4ofi I4 cyluar. rrr4KprrHoBofi nrKpara Aonxua 6urr or 227 Ao 233 "C. TeivrnepaqiparJraBJreHr4q 0,25 r cy6craHqnr{ pacrBop*or B 10 vrn BoAbr,roAllenaqllBaror pacrBopoM Hara Tprrr rrrApoKcr4Aa Sunrrpyror. OcaAox na Quru:rpe rpoMblBaror eoAofi. lloloauuy ocaAKapacrBopnor e 1 rv{rcrurpra 96 % u npH6aunor 0,5 Mn pacrBopa ro6alrra Hvrpar a; o6paryercr rory6onaro-3gJleHblfi ocaAor. Cy6cranq vrs.Aaer xap aKrepHylo peaKIII4IoHa xJroprrAbl. roA1,6es npeABapllrenbHoro TervrneparyparrJraBJrenrs.Or 74 rc79"C (rr,rero4 cyruurauua). flpo:pavHocrb pacrBopa. Pacrnop 0,5 r cy6craHl\r4us 10 N{r BoAbI AonxeH 6rnr I. c BbrAepxl{Barb cpaBHeHI4e sraJroHoN{ ilpo3paqHbrMrrJrr.r na Ifnernocrb pacrBopa. Pacreop, noryqeHHrrfi s ucurrralowvl flpospavHocrb pac cpaBHeHI{e eralouou 89. crBopa, AonxeH 6urr 6ecqserrrururrvl BbIAeplKI4Barb pH" Or 4,5 [o 5,5 (0,5 % pacrrop). . ZrG-luwerlrJ'raHHJrHH Irlcnutmyenait pacmeop. 0,25 r cy6cranql4l4 pacrBopttor B " MeraHoJre AoBoAtr o6relr pacrBopa MeraHoJroM 10 prn. rr lo pacrBop.arorB MeraHone n Cmaudapmuutil pacmeop. 0,05 r 2,6-gv*rerilIranprlrr,rHa Ao AoBoArr o6reu pacrBopa MeraHoJroM 100 lrn. 1 Mn nonyqeHHoropacrBopa pa36asrsror MeraHonoM 100 vrn. lo npo6upxr rroMerrlaror: B repBylo upo6upry - 2 vn lrcrlblTyeB rpu oAr.rHaKoBbre Moro pacrBopa; Bo Bropyrc upo6upry - 1 un craHAaprHoropacrBopau I Mn Mera(xonrponrnrtfi pacrnop). B Ka)KAyIo Hona; B rperbrc npo6upry - 2 rvn MeraHoJra cnexe[plrroroBJleHHoro I oh pacrnopa AI,IMeTI{Inpo6upry rtpu6ayxxror rro I rr,trt r{ B auuuo6en3anbAerr4Aa MeraHoJre tro 2 un yxcycsofi xzclorbl neAtHofi u nngepxr,rBaror B Teqeulde10 nrun [pI,I KoMnarnofi reuneparype. @

flossnsmeect xeJIToe oKpalxutBaHr4e npo6upKe c ucrrbrryeMbrMpacrBopoM e qeM 6uru 6olee rrHTeHcLtBHbIM, n npo6upxe c KoHTpoJrbHbrM Aon)KHo pacTBopoMt4 MeHeeuHTeHclIBHhrM, n npo6zpre co craHAaprHhrM rIeM pacrBopoM (He 6onee 0,01 yo r cy6craHrlnr,r). Bola. He uesee 5,5 yo u He 6olee 7,0 o/o.Orono 0,25 r (ro.ruar Hanecra) cy6craHur4t4 TuTpyror peaKTr,rBoM @raruepa. K. CynrQatHafl 3oJra n rflxeJrble MeraJrJrbr.Cyrr$aruar 3oJralas I r (rouuax Hanecra) cy6craHqnl4 He AoJIxHa flpeBblrrrarr 0, I oh u AonxHa BbrAepxraBarb r4cnbrraHrle Ha rflx{eJrbre MeranJrhr(ue 6onee 0,002 %o cy6craHqrau). n EaxrepnaJrbnbre 3nAoroncrunr. He 6oree l,l7 Eo ua I rrarcy6crauqzz. .{nx nponeAeHl{t IrcIrbIraHLIt roroBrr zcxo4uufi pacrBop cy6cranqzu (xonqeHTparlur 2 wl,r:lrv'l), 3areM pa3Bo.qrr ero He MeHeeqeM B 50 pas. a I'Icnrrrauue rpoBoAtr Ant cy6crauquu, lpeAHasHaqeuHofiAJrr npuroroBneHut uHbeKrlr{oHHbrx JreKapcrBeHHbrx Qopvr. Ocraroqnble opraHnrrecKue pacrBoplrreJrn. B coornercrBr4r{c rpe6ona*yrflMyr O OC << Ocraroqnbre opraHz qecKtle pacrBopnTeJrrr). Murcpo6uoflornqecKas qncrora. B coorBercrBvrvr rpe6onauusnauO@C <Muc xpo6uonoruqecKar rrrlcrora)). Ko.nnqecrBenHoeonpeAeJreHue. Oxoro 0,22 r (rounar Hanecra)cy6crauqzupacrBoptlor e 50 N{r cnrlpra 96yo,lpn6annarcr 5 ul0,0l M pacrBopa xnopr4croBoAopo4Hofi KIlcJIorbI 14 TI{TpyIor rroreHrluoMerpurrecxn 0,1 M pacrnopoM Harpr{t rI4ApoKcI'IAa. PacxoA TvrparTa o[peAeJlt]or rro pirHocrra o6reuoB Tr{rpaHTaMe)KAy AByMqrotrKaMu ueperu6a na rpunofi Tr{rpoBaHr{r. I nrn 0,1 M pacrBopa Ha'rpkrfl rr{ApoKcrrAa coorBercrByer 27,08 Mr cl4H22N2O.HCl. XpaHenne. Cuzcor E. B unorHo 3aKpbrrofiynaronKe B 3arqr4rleHHoM cBera or MecTe.

Jrv3r4HorrprlJr 42-02 2-07) (@c s

1- tAP t(,9) 1-Kap6oxcn-3-$ euunnponun] -L - tnsun]-L- nponuH, Aprrv ar Ap

,/-\
(,-

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)-cl;'r-cHz-

| g-M-

mOH

l___

c- b-N
91, I
C}lt

| ll r>
H,"""\

\-,

I
COOH

.2H2O

l -

CHr

CH? I NH2

t M.u.441,5

c2rH31N3O 2H2O s.

Co4epxurHeMeHee 98,0you He6onee102,0 C21H3tN:Os ilepecqere 6es% n na

BOIHOe BeTUeCTBO.

noporroK. Onuc anne. Benrrfi KplacraJrJrl{qecxufi npaKTI,IPacrnopuMocrb. Pacrnopnu B BoAe,yMepeHuopacrBopliM B MerarloJre, qecKrrHepacrBopnM cnrpre 96 You a\etoue. B c floA.uunnocrr. tr{uspaxpacmifi creKrp cy6crauqrEn, curtrrrir.B AI.IcKe ralux 5porIoJIoc [orJroIIIeHI,It AolrlKeH Mr{,rIoM. o6lacru or 4000 ao 400 cu-l no rroJIo}KeHIrIo n c[eKTpy cTaHAaprHoroo6pasqa JII,I3IrHorIpVna cooTBeTcrBoBaTb 4rrrkr4para. nepecqere Ha 6essoAnoeBeIIIecrBo YAenrnoe BparrleHrre.Or 43 rc 47 " B pacrBope UHHKa aUerara). (l Yopacreop cy6crarHl\uvrB quHKaaqemama. Claeruusam 600 MJrBoAbIr.r 150 Mn yKcycHofi rucPacmeop Jrorbr le4xHofi. B nony.reHHoMpacrBope pacrBopflIor rlpfi flepeMeurvtBaHiltr54,9 r pacrBopa aMMI,IaKa rIr{HKaarlerara. llpo4olxax nopeMerrrunarr, npn6aBJltlor 150 rran o oxnax(AaloT, pH pacTBopaAoBoAtr go 6,4 pacTBopoM 25 KoHrIeHTpr4poBaHHoro , r,r aMMrraKa pas6auqrcr soAofi ao 1000 ul. Ilocroponnr.re nprM ecu. ITodeuilcHan$asa (n@ 4. Cnrecr alleroHrlrpun - frocQarHufi 6y$epHufi pacrBop c pH 5,0 (3:97). @ocQamuuil 1y$epuatil pacmsop c pH 5,0. 3,12 r Harpflfl,$ocQata oAHo3aMepacrBopH nleHuoro pacrBoptrcr n 900 MJIBoAbI, pacreopa AoBoAflr4o 5,0 Bo.4HbrM poM Harpr.rsrr,rApoKcr4[a KonrleHrpa\ueit 50 r/n u pas6annsror soAofr ao 1000 ul. c IIO E. CnaecralleroHlrrpul - $oc$ar:erti't 6ySepnufi pacrBop c pH 5,0 (1:a). I,Icnutmyeuwilpacrneop.0,02 r cy6cranqrll4 pacrBopsror s fI@ A u pas6aBJlrlor IIO A lo l0 rr,rn. Pacmeop cpanHeHut 0,5 un ucrrbrryeMoro pacrBopa pas6aBJlttor II(D A ao 50 nan. 0,02 r cranAaprHoro o6pasqanncucmeMbt. npuzodHocmu Pacmeop dna npoaeprcu qHoro cr?I 3Hnonpuna 1r4ril ar a Ar-f,npo BepKrrnpr.rroAHo (crau4apr BP unH aHaJrorI4 [p xa.recrna)pacrBoptm s IIO A n pas6aBrltlor IIO A lo 10 lrn. XpovarorpaSuqecxue ycnonus -25 x 0,46 cv c oKraAellvllrcvrvil cLIJIrIKareJIeu (Cl8), Korosra

3 rrarna; 50'C; TenaneparypaKonoHKl{ - 1,8vrn/rr,tuu; Cropocrr rioroKa - creKTpo$ororraerpnvecrufi, utvt; 2lA .{ererrop - 50 rvlxn. O6revrupo6u lpalxenrrrrIft pexulr
Bpeua(uun) 0-35 35-45 45-50 50-0

rro A (%)
100:>70 7A 70='100 100

rro E (%)
0:-30 30 3 0+ 0 0

rpkrroAHocrl{ xpoMarorpa$nuecrofi Xpolrarorpa$upyior pacrBop Ans npoBepKr4 cricreMbr.XpouarorpaMMa.uonxua coorBercrBoBarb xpoMarorpaMMe,npl{Jro}Kerisofi x craHAaprHouy o6pasqy nr{3pruorpuna EkrrkrlparaAn;{ rpoBepKl4rpl4roAHocru. flux npuuecl.r A r4tiuKrrpr{Mecu E Aorxnsi sa6moAarbct c AByx cropoH or nIrKa nI4A rrpr4Mecl4 IEupnttlecu E or ypoBHs Hyneeofi Bbrcorbrrrr,rKoB 3rrHorrpr4na"klzwrepxror

(cooraercrBeHHo A1 u A2), a raKx(e Bbrcorbr uuxuefi ToqKn rplrnofi, pa3AeIrvlr;.vtu (coornercrBeHHoB1 n B). nsrcuefi nLIKII9Tt4xrrpr4Meceit [r.rKJru3rlHonpuna u Tecr sHAep)Kr{BaeT r4cnbrTaHue, ecJrrrBeJrr.rqr4Hbr *t 42 He MeHee,treM B 9 pag i{1 oonrue BeJrr,rqr4H n 82 cooTBeTcTBerrHo. 81 IIpIa Heo6xoAktMocrunpu noMorrlr 85 % SocSopuofi xucrorrr KoppeKrr4pyror pH nogrzxnofi $asu go 4,5 fl roBroprrcr npoBepKy. C HeKoroplrMr{ KoJroHKaMr4 Ifio)Kernorpe6onarbcf AanrHefimar KoppeKqur pH go 4,0 An.rr AocrnxeHrrr yAospa3.qeneHr{r nerBopr4TeJrbHoro nvKoB npui\4ecr4 rn3rauonpr4Jra upzueciE E. A, u Ecnu [pLI sToM nI{KI,Inpuuecefi C n D cABrrrarorcs s o6racrb, rge vHTerpnpoBaHI,Ie craHoBt4Tcr rpyAHbrM, yBeJrr,rqr4Balor noABt4xnofi $asrr E or coAep)KaHne 30 ao 40 % B r{HrepBaJie BpeMeHnor 35 rc 45 MrrH}r noAAepxrBaror sro coorHoIueHI{e$as n reqeHr.re cJreAyroqux 10 rr{}ru.BosBpaqaror coAepxaHr{e rroAnuxsofi Qasu A ao 100 % B reqeHne cJreAyroqux 10 Mr4H cneAylouero BBo,qa Ao npo6u B xpoMarorpa$. Xporraarorpa$upyror rcnbrryeMufi pacrnop 14 pacrBop cpaBHeHr.rs. Ha xpouarorpaMMe r.rcflbrryeMoropacrBopa nnoqa,qb nr,rKanro6ofi flpprMecrr JrLt3r.rHoflpilna xpoMarorpaMMe paHa .qoJIxHa6rmr se 6oree 0,3 or rrJroulaAurrrdKa o/o). (ue 6onee 0,3 crBopa cpaBr{eHr{r Cyrr,rrraapuar nJlolqa.ub Bcex rrr4KoB npl{Mecefi Ha xpovrarorpaMMerrcnbrryeMoro pacrBopa AoJrx(Ha 6rrrr se 6onee rroJroBr.rHbr nJrorrlaAlrnr{Ka Jrr43r.rHonpuna xpoMaHa pacrBopa cpaBHeHr{r roFpaMMe Q,5 %). flpn oqenKe coAep)KaHr{rnpr{Mecefi ue yarilTbrBarorrrr4KpacrBopr{Terflvr rrr.rKr4, notBJlrroulvecfl.B nepBbre3 ruuH.

llpzrraecrA - (2RS)-2-atvwrno-4-QeHun6yraHorasKncrrora; llprarr,recr - (2S)-2 -l(3S,8aS)- 3- (4 - aunu o6yrz;r) - 1,4-4uorc oreKcarnApoC (I n nppono[ 1,2- afnupasuu-2 t{1-u:i]-4- S eHnr 6yr aH Bar Kr4cn a o or (S,S,S-aureronuuep a:uH); llpurraecrD - ( 2S)- 2 - [ ( 3,S, aR) - 3- ( 4 - aira n o6yrran - 7,4- guorcco KcarrrApo 8 u re ) -a]nup azun-2(l lfi- uI ] -4- S eHnl 6yraHoBar Kr.lJrora nuppoao[ 1,2 c (R,,!,,S-4nneronunepasnu) ; -$enunnponnn]Ilprnaecr E - (2S)-I -i(2S)-6-auuno-2- I R)- I -rcap6oxcu-3 [t( (nnsunolpNn annano]rexcaHonl]nupon-2-rap6oHoeas Kr.icJrora R,S,S-u:oMep).
Bola. He naesee 8,0yo u ne 6oree 9,5 yo. Onpe4enenuenpoBo"qrrMeroAola OnK. tilepa ug roquofi HaBecKLr oKoJro 0,25 r cyScranquu. CyrrQaruaq sora u rff)rceJlble MeraJrJrbr.Cyrr$arHa.f, 3oJraus I r cy6crauqnn (rounar Hanecica) AoirxHa npeBhrrxaTs o/o AoJrxGaBr,rAepxfl{BaTb He 0,1 14 rrcnhrTaHr4e o/ov cy6cranqrau). (ue 6onee 0,001 Ha rsxeJrbre MerairJrbr Ocraro"rHble opraHuqecK[e 1]acrBopnreJrn. B coornercrBvtr4 rpe6oranr{sMu c O OC <<Ocra:r'oqubre opraHr,rqe Krrep acrBopr{reJrr4)). c qucrora. B coorBercravrr c rpe6orauiasharO(DC <MNMnrcpo6uoflol'nqecxafl rpo6uonorr4qecKarqr4crora)). Koru.recrBellHoe oilpeEeJreHse.Oxoro 0,35 r (rounax narecra) cy6crauquu

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B 50 Mn BoAbI I4 TIdrpyIoT 0,1 M pacrnopoM HaTpLIf, rI4ApoKcI,IAa. KoHeuuyro rorrKy rrlTpoBanul orrpeAenf, Ior IIoreHIIuoMerpI,Iqe cKI'I. pacrBoptrcT

coorBercrByer 40,55 rvr C21H31N,OS. 1 rr.rr0,1 M pactnopa Harpl4t rHApoKcLIAa or Xpanenne. B cyxotr,t,3aIIIuqeHHoM cBera Mecre.

MArHI[ff CyJIb@AT (@C42-02s3-07) renrarl,IApar Marnns cynrQar,

MgSOa 7H2O 99,0YoMgSOa 7H2O. Cogepxur HeMenee
nopoilroK firu SecqserHble [pu3MaruqecOnncanne. Eelrrfi Kpr.rcraJrJrlrqecrufi KHeKpr,rcTiurJrbl. PacrnopuMocrb. Jlerro pacrBopr,rMB BoAe, oqeHb JIefKo pacrBopl,IMs rllnrqefi BoAe,[paKr]IqecKu HepacrBoptlM B crll4pre 96 %. peaKIIHI,I ruarHuft u cynrQatrr. Ha IloA.irnnnocrb. flpeuapar Aaer xapaKTepHbre llporpaunocrb pacrBopa. 2 r cy6craurlr{u pacrBoptrcr B BoAe n pas6annxm 6rtrr [po3paqHblMIIJIII BhIIep)K]IBarb rran. Ilonyrennnft pacrBop AoJrlKeH soAofi pLo20 c cpaBHeHrre sra-nouou I. I{nerrrocrb pacrBopa. Pacraop, rroJrfreHHHfi s ucnrrranvuna flpospavHocrb pac cpaBHeHLIe sralonolr 89. crBopa, AonxeH 6urr 6ecqserHrrM r,rJrrBblAepxclaBarb B pacrBopa, rroJr1^reHHoro I,IcrIbITaHr4aHa Knc;rornocrb nJrlr uelorrHocru. K 5 Mrr flpoapavnocrb pacrBopa, npu6annrrcr 5 ur BoAbIn 0,05 utt I Yo pacrBopa QenonpacrBop AonlKeH6urr 6ecqserHrrIu. Pososoe oKpaurnBaHrle AonlKHonoflBQra.neraHa; JrrTbcr or npn6aueHllt He 6onee 0,1 un 0,01 M pacrBopa Harpllt rrrApoKcrlAa. na X.iropn4u. K 5 rvrnpacrBopa, flonfreHHoro B LIcnbITaHI4u flpospatlnocrb paHa I4crIbITaHI,Ie xJIoBbIAep)KI,IBarb crBopa, npu6annaror 5 rral BoAbr.Pacrnop AoJDKeH (ne 6onee 0,004 Yov cy6c'ranqun). pr.rAbr ua Tsrre;rrre MeraJrJrbr. 10 ivrnpacrBopa, [oryqeHHoro B LIcrIbITaHrII,r flpospav(ne 6onee Ha ktctIbITaHLIe rDKeJIbIeMerarIJIbI Hocrb pacrBopa, AoJrxHbrBbrAeplKr,rBarb o/o cy6cranquu). 0,0005 s BblAepxuBarb I,IcrbI)Kerego. Pacrrop 1,5 r cy6craHrlru n l0 rvrnBoAbIAoJDKoH o/oY cy6cranquu). raHr.reHa xeJre3o (He 6onee 0,002 MapraHeq. 1,25 r cy6crauqur,r pacTBoptloT B 5 rran BoAbI, npu6annxrcr un KoHIIeHTpI{ponanHofi,0,2 0,1 M pacTBopacepe6panur0,5 ul cepnofi KI4cJIorbI para u HarpeBaror Ao Kr4neyux. fIpu1aBJItIor 2 vn 20 Yo pacrnopa aMMoHI{t repcynrSara rI cHoBaHarpeBalor Ao KI,IneH[t. )Ke flpono4m KoHTponburrfi onrrr c 5 ul BoAbII{ TeMI,I peaKII4BaMII. npo6uprn. B npo6xpry c O6a pacrropa oxJIaXAaIor I,I nepeHoctr B oAl4HaKonue nepKoHTponbHbrM onbrrou npu6annrror r43nruxpo6roperxn 0,01 M pacrsop KiuII,IrI MaHraHaraAo rex [op, rroKa oKpacKaHe cpaBHterct c orpacrofi flcrlblTyeMoro pacrBopa. Cpanneuue oKpacoKrpoBoAflr sa 6enoru$oHe ro ocu npo6rapox. KoMapraHIIa, nepMauraHaracoorBercrByer 0,11 rr,rr I rr,rn 0,01 M pacrnopaKaJrufl. oh. Toporo r cy6crauqrrll AoJIx(no6rrrr He 6oree 0,404 @

M.u.246.48

Ilpenapar, npeAHa3Haqensufi Anr flpuroroBJreHrrr crepr4Jrbubrx neKapcrBeHHbrx coAepxarb MapraHrla. Sopr"r,He AoJrlKeH Mururrqrc.0,25 r cy6crauqul{ AoJIxHbIBbrAepxr4Barb r{cnbrraHrre narrrurxx(ne Ha o/o cy6wanqnu). 6onee 0,0002 Y Ilorepn B Macce npu npoKaJrrrBaHurr.Orono 1 r (ro.rHax nanecra) cy6claHquu cyllrar B TeqeHue unpu reMrreparypeor 100 Ao 105 oC, a 3areMrrpoKaJrr4Balor 2,5 nprr reMreparype KpacHoro KaJreHr,rr nocro-trHHofi Maccbr.llorepx B Macce AonxHa Ao o . 6r,irr He MeHee48,0 u se 6olee 52,0 EanrepuaJrbrrr,re suAoroKcr,rsu. He 6onee 0,07 E3 sa I rur cy6crauqnu. rorots-flT ucxo4urrfi pacrBop cy6craHqnn (xonqesffnx nponeEenvrfl,IrcrrbrraHr4q - 250 rrr/nan),a 3areMpa3BoArr ero He MeHeerreMB 100 pas. TparJkrfl tr4currranue npoBorsr AJiq cy6craHqrarr,npeAHagsaqessofiAxfl npuroroBJreHrlf, HHbeKurroHHbrx neKapcrBeHHbrx $opr. MuxpoSuoJroruqecKafl qr,rcrora. B coorBercrBvrr4 rpeSonauuqlaz OOC <Mzc rpo6norof xqe cKar qprcrora)). Ko,rlrqecrBeHHoe oilpeAeJrenue"Ororo 15 r cy6craHqnu (ro.ruax nanecra) pacrBopxlor s 50 Mn BoAbr, upu6aerNror 5 uri aMMnaqHoro 6y$epnoro pacrBopaurrrrpyror npl4 3ueprrrqHoMnepeMerrruBanflrr 0,05 M pacrBopoM :aarpvrflgAerara Ao IIosBtIeHvf,cl4Heroorpaur{Bauux (nnguKarop - KncnorHrrfi xporu vepnrrfi crrerlr4anrnufi). llapartrterblro ilpoBoArr KoHTpolrHufi oflbrr. 1 nr"rr 0,05 M pacrnopalaarpprxsAerara coorBercrnyer 12,32 narMgSOa ' 7H2O. XpaneHue. B xoporuo yKynopesnofi rape.

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Cnexrp lorJrorrleHug 0,0015 oh pacruopa cy6craur\r4vrB MeranoJres o6racru or npu 354 nru. 240 lo 450 nu AortlKeH r4MerbMaKcr{MyM npoBoArr MeroAoMB3XX. flocroponnrre npuMecu. OnpeAenenr.re pacrBop.rror B ITodeucrcuan Sasa A @@ A). 1 r xarurs Qoc$ara oAHo3aMeuleHHoro 1000 runBoAbr AoBoArrpH pacrnopapacrBopoM r{ Harpr,urlrApoKclrga 6,0 + 0,05. 4o Ilodeutrcuaa Qasa E (II@.6/. Meranon. pa340 rIaApoKcI,IAa 0,4 M pacm*op Hampunzudporccuda. rvl l M pacrnopamarpkrfl, BoAqr soAofi ao 100 rvrr. Pacmeopumatb. Crraetul,tearor vrn 0,4 M pacrBopa laarpufl rulpoKct{Aa, 300 un 30 BoAbru200 Mn MeraHona. pacrBoprror s 50 Mr pacrBopr,rren{. I'Icnutmyeuutilpacmeop. 0,2 r cy6craHur4r4 5 lrn nonyqeHHoropacrBopa pas6annnor cMecbroMeraHoJr BoAa(2:3) ao 10 rran. Pacmeop cpanHeHun 1 un llcnbrryeMoro pacrBopa rroMeruaror B MepHyIo ror6y * BMecrrrMocrbro100 un, AoBoArr o6revr pacrBopa cMecbroMeraHoJr BoAa(2:3) ao MerK[ 14nepeMerrrr4Balor. rr,rn I nonyqeHHofo pacrBopa [epeHocsr B MepHyroxon6y BMecrrrMocrbro10 rrr, AoBoAfr o6reu pacrBopa rofi xe cMecbroAo MerKI4x [epeMEIIII,IBArcT.

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Ha MeJroKcrzKaMa xpoMarorpaMMepa260 nu AonxHa 6rmr se 6olee nnoulaArl nr,rKa upu 350 nu (ue 6onee 0,1o/o); nnouaAb nzra nrc6ofi selrAesrucrBopa cpaBHeHrr{ Ha Suqnponausofi rpr4Mecr..r xpoMarorpaMMe rrcrrbrryeMoropacrBopa [p]r AnI4He 350 nrvr) nau6onrruero orKJrrrKa(260HMLrJrr{ BoJrHbr Aonxua 6rnr ue 6onee nnouaAr{ (ue 6onee pacrBopa cpaBHeHLIt nplr 350 nrr.r rrr4Ka MenoKcr.rKaMa xpoMarorpaMMe Ha coAepxaHlrerpl'{Mecefi ne AoDKHonpeBblllrars0,3 Yo. 0,1 %). Cyurraapnoe flo:repn B Macce rrplr Bbrcy[rrrBaHur{. Ororo 1 r (rounax Hanecra) cy6crauquu oC or cyrxar rrprr reMnepa.T.vpe 100 ao 105 Ao rrocro{HHofi ruaccu. llorepr B Macce rrpeBbrruars Yo. 0,5 He AonxcHa Cy"rrsQarnafl 3oJrar rfl)KeJrbre MeraJrJru. Cynr$arnafl.3oJIa I43 1 r (rounax uaIIctIbITaBbIAepxo4BaTb neCra) Cy6Crauqzr4He AOnxHa npeBbllrratl 0, I You AOJrxGa oh u cy6crauquu). (ne Hr4e rrxeJrbre MeraJrJrbr 6onee 0,001 Ha Ocraroqnbre opraHrrqecKue pacrBop[TeJru. B coorserc'rBvrilc rpe6oBanvlflMvl ToJIIT)). O O C <<O craro.rHbre opraHurrecKI4ep acrBopl4 O(DC <MvMnrpo6norornqecKafl rr[crora. B coorBercrBnr4c rpe6onaHuxrrau rpo6uonoruqe cKar rrrrcrora)). Ko.un.recrBenHoeo[peAeJrenne. Ororo 0,25 r (ro.ruax uanecra) cy6crauqzvpayxcycnofi Kr4cnorblreAssofi u 5 vrn MypaBbuHofir<ucnoru crBoprror B cMecu 50 ir,rn Koueunyro roqKy rLI6essoAHofir{ rr4rpyror 0,1 M pacrBopoM xnopuofi Kr.rcnorbl. TpoBaHuflorrpeAenffoT [oreHrlr{oMeTpuqecKl,I. llaparrerbHo rrpoBoAqr KoHTponrnrrfi onblT. coorBercrnyer 35,14 rrarCI4H13N3O4S2. 1 run 0,1 M pacrnopa xlopuofi KLIcJIoTbI Xpanenue. B nrorso sarpurofi yrIaKoBKe.

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(1000:1). Izlcnatmyentatil pacmeop. Orono0,01r (:rouuax uaeecxa) cy6crauquu rroMerrlaror

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0,9749 15,27 19,9514,gg 19,37 6 43 19,0515,44 57 4 58 24 t9 77 2 74 43 34 97 ' 0 90 62 49' 20,16 0,9739 16,05 8 t 64 36 6 2 l 20,00 79 56 4 37 t9 94 76 2 52 3 7 16,09 95 0 68 56 23 21,15 0,9729 84 75 38 35 6 99 93 52 54 4 1 7 , 1 521,12 67 74 2 30 3 1 82 94 0 45 49 96 22,13 0,9719 61 68 1 7 , l l 33 6 76 86 25 52 4 92 22,05 40 72 2 19,07 23 55 9l ,69 2 3 , 1 0 0 22 4l 0,9709 37 60 84 3l 6 52 78 98 50 4 67 96 18,12 69 2 83 2 3 , 1 4 26 88 0 98 32 4 l 24,07 0,9699 19,13 50 55 26 6 28 68 69 45 4 43 86 83 64 2 58 24,04 97 83 0 73 22 19,12 25,02 0,96gg 88 40 26 2l 6 20,03 57 39 40 4 18 75 53 59 2 33 93 68 77 0 47 25,11 82 96 0,9679 62 28 95 26,15 6 77 46 20,09 34 4 92 64 24 53 2 21,07 8 1 37 72 0 99 5l 9l 0,9669 2 6 , 1 6 65 27,09 34 79

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Bo3Ayxe

4,9412 36,96 44,09 34,79 46,89 0 37,07 T 9 88 47,07 0,9409 I7 30 96 14 6 27 42 35,06 27 + 37 53 l5 4l 2 47 64 23 53 0 58 75 32 66 0,9399 68 86 79 6 78 98 93 4 88 45,09 49,06 2 98 20 18 0 39,09 3 l 31 0,9399 t9 42 43 6 29 53 56 4 39 64 36,02 69 2 49 75 ll 82 0 59 86 20 95 0,9379 69 97 28 49,07 6 79 46,09 3 7 4 89 . 4 6 2 99 54 0 39,09 63 0,9369 t9 72 6 80 4 88 2 97 50,09 0 37,06 2l 0,9359 47,06 t 4 34 6 t7 23 47 4 27 31 59 2 38 72 0 40,09 49 85 0,9349 t9 59 97 6 29 70 51,10 4 38 81 22 2 48 92 35 0 58 49,02 47 0,9339 68 13 60 6 78 23 39,07 72 a^ 4 88 JJ 15 84 2 98 44 23 97 0 41,07 54 3 1 52,09 0,9329 t7 40 22

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0,8986 60,64 68,3553,95 76,93 A 43 54,01 77,04 72 "t L4 07 5l 81 2 25 l4 59 90 0 36 20 67 98 0,8888 47 26 6 61,07 75 57 33 83 15 4 68 39 9t 24 2 80 69,00 46 33 0 91 52 08 4I 0,8878 59 78,02 t6 50 6 T2 65 24 58 4 23 7T 32 67 2 34 78 40 76 0 45 84 48 84 0,8868 56 90 56 93 6 66 96 4 62,01 64 77 72 55,03 10 2 88 09 80 18 0 99 15 88 0,8858 27 96 . 2 2 79,10 36 6 2L 44 70,05 29 4 31 34 t2 53 2 42 4T 20 61 0 53 47 28 70 0,8848 64 )J 36 79 6 75 60 45 87 4 86 67 53 96 2 97 73 6l 0 63,04 79 80,08 69 l3 0,8838 19 86 77 2T 6 30 92 85 30 4 40 98 93 39 2 51 56,05 47 77,0r 0 62 11 09 56 0,8828 IJ T7 t7 64 6 84 24 25 73 4 95 33 82 2 81,06 4l 90 0 L7 0,8818 99 28 6 64,07 39 t6 4 49 24 2
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0,8724 67,99 7 5 , 1 4 59,31 86,24 2 68,07 22 J I 35 0 t5 29 42 45 0,8719 24 3 7 49 56 6 32 45 55 67 4 4l 52 6l 77 2 49 60 67 89 0 58 68 73 87,00 0,8709 66 75 79 t0 6 75 83 85 2l 4 83 90 9l 31 2 92 98 97 42 0 69,00 76,0660,03 53 1 a 0,8699 08 IJ 09 63 6 t7 2l t5 74 4 25 28 2l 85 2 34 27 96 0 32 ,'88,06 0,g6gg 39 t7 6 44 27 4 51 38 2 57 50 0 62 60 0,8679 69 7l "74 6 70,01 96 8l 4 l 0 77,04 8 1 93 2 l8 l1 86 89,02 0 26 t9 92 14 0,9669 35 26 98 24 6 43 33 61,03 34 4 52 4l l0 46 2 60 15 56 0 68 67 0,8659 77 77 6 85 88 4 94 99 2 71,02 90,09 0 10 0,9649 l 9 78,00 6 07 4 15 2 22 0 29
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90,84 95 91,05 16 26 36 47 57 68 79 90 92,00 10 22 32 42 52 64 74 84 96 93,06 t6 27 37 49 59 70 80 90

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0,9390 82,20 87,2868,89 104,29 0,8379 28 34 93 38 6 36 4l 99 49 4 44 . 4 7 69,04 59 2 52 53 08 68 0 60 60 t4 79 0,8369 68 66 t9 89 6 76 72 23 98 + 84 79 29 105,09 2 92 85 34 t9 0 83,00 92 39 30 0,8359 08 98 44 40 6 t 6 88,04 49 49 4 24 l1 54 6l 2 32 l7 59 70 0 40 23 64 80 0,9349 48 29 68 89 ,56 6 36 74 106,01 4 64 42 79 l0 2 72 48 83 20 0 80 54 88 30 0,8339 88 6 1 94 42 6 96 67 98 5l 4 84,04 73 70,03 6l 2 ll 79 7A 0 86 82 0,8329 92 91 6 98 l07,ol + 89,04 tn 2 0 t6 0,8319 23 6 29 4 35 2 4l 0 98 47 0,8309 85,06 53 6 l4 59 108,00 4 2l l0 2 29 2A 0 37 29 0,8299 45 39 6 53 5l
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