, ,

, 6 2011

PHT3D
3-
PHAST

2-3- Geochemist's

Workbench

(GWB)

Particle Tracking
(ISRFlow , (MODPATH
), MODFLOW,

FEFLOW
)
MODFLOW
HST3D

MODFLOW

:
PHT3D - Prommer, Barry, Chiang and Zheng, 2001
PHAST - Parkhurst, Kipp, and Charlton, 2010
GWB - Bethke and Yeakel, 2010
PHREEQC- Parkhurst and Appelo, 1999
MODFLOW - McDonald and Harbaugh, 1988
MT3DMS - Zheng and Wang, 1998

MT3DMS

PHREEQC

PHREEQC
PHREEQC

GWB ( XT1 XT2)

3-



e,

,
7

,

:

.
.

,
ISRFlow
PHREEQC


-
5

80%

:
:
Rk = rk (A0/v) (mk/m0k) n0
:

rk = k (FeS2, UO2, FeO(OH))

A0/v = ,

m0k =
mk =

:
UO2 + 2Fe+3 UO2+2 + 2Fe+2
:
FeS2 + 14Fe+3 + 8H2O 15Fe+2 + 2SO4-2 + 16 H+

ruraninite = ku1 [Fe+3] 0.11

( )

rpyrite = kp1 (Fe+3)0.30 (Fe+2)-0.47(H+)-0.32

(Langmuir, 1997)

:
UO2 + 2SO4-2 + 4H+ U(SO4)2(.) + 2H2O

ruraninite = ku2 [SO4-2] [H +]

(), Fe+3 :
FeO(OH) + 3H+ == Fe+3 + 2H2O

rgoethite = kg1 * si (goethite)

: si (goethite)

, , . .


PHREEQC


1 2

Kr UO2, FeS2 FeO(OH);

A0/v UO2, FeS 2 FeO(OH);
m/m0 UO2, FeS 2 FeO(OH);
, m0 UO2, FeS 2 FeO(OH);
Kx UO2+2, H+ Fe+2.


3, 5, 6 7

3-
. 1,9 25,4 /2.



20

50 ,

20 ,
15

120

15.
120 ,
8,1
2 /

4 3/
50

100

36 .

 80%

(80% , )

12

10

T 80% = 2.6381 + 0.4012 x P - 0.0033 x P2

8

T 80% = 2.079 + 0.2986 x P - 0.0022 x P2

0
0

10

12

14

16

18

20

22

24

26

28

(/2)
-

80-
3,4 10,7

30



P x A x 0.8
U = ---------------------------

(1)

t80%
:
U , / ( 2 40 /)
P , 3-D
, /2
A , 2
t80% 80% ,

U x 1000
= --------------------------------------

(2)

n x Q x 24 x 365
:
, / (
40 120 /)
n
Q , 3/



900000

()

800000
700000
600000
500000
400000

300000
200000
100000
0

2008

2009 2010 2011

3

2012 2013 2014

7

2015 2016 2017

6

2018

2019 2020
5

2021

2022

:
) ,
)
) .


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,
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.
:
,
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