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2.
n.
AA B
1 d [ A]
= k[ A]n ;
A dt
(1)
d [ A]
= kdt ; A = 1
n
[ A]
(2)
, t=0
= 0.
d [ A]
1
1 t
0 [ A]n = n 1 [ A]n1 0| = kt
(3)
1 1
1
= kt
n 1
n 1
n 1 [ A]
[ A0 ]
(4)
1
= f (t )
n 1
[ A]
n-1
1/[A]
tg = (n-1)*k, n>1
tg = (n-1)*k, n<1
. 1 n>1.
n < 1.
.
(4):
1
1 [ A0 ]n 1
*
1 = kt
n 1 [ A0 ]n 1 [ A]n 1
(5)
[ A0 ]n 1
n 1
=
t =
n 1
[ A]
(6)
1
1
n 1 1) = k
*
n 1 (
n 1 [ A0 ]
(7)
,
. :
1
n 1
ln
(n 1) * ln[ A0 ] + ln ( 1) = ln k + ln
n 1
(8)
const (n 1) * ln[ A0 ] = ln
(9)
ln
[A0] = ln .
(1-n) - n - .
ln
tg = (1-n), n<1
tg = (1-n), n>1
ln [A0]
. . 48-51, 160-162
. . 22-28, 356-359
.-. . 201-204, 345-346
n=2, (4)
1
1
= kt
[ A] [ A0 ]
(10)
[ A0 ]
1 + k[ A0 ]t
(11)
[ A] =
2
:
I + I = I2
(12)
[ I ](t ) =
[ I 0 ](t )
1 + k[ I 0 ]t
[I2 ] =
1
1
[I0 ]
{[ I 0 ] [ I ](t )} = [ I 0 ]
2
2
1 + k[ I 0 ]t
1
= f (t ) .
[ A]
2
1
1
=
= kt1/2
[A 0 ] [A 0 ] [A 0 ]
(13)
t1/2 =
1
[A 0 ]*k
A+B
(14)
AB, C+D
(15)
(16)
- d[A] = dx
(17)
[A0],[B0] - .
:
dx
= kdt
([ A0 ] x ) * ([ B0 ] x )
(18)
, (18),
.
dx
=
([ A0 ] x ) * ([ B0 ] x )
dx
dx
1
*
([ B0 ] [ A0 ]) ([ A0 ] x ) ([ B0 ] x )
(19)
, :
t
| |
([ B ] x )
1
* ln 0
= kt
([ B0 ] [ A0 ]) ([ A0 ] x ) 0 0
t
(20)
=0 (20) , = 0,
5
([ B0 ] x )
([ B0 ])
1
* ln
ln
= kt
B
A
A
x
A
[
]
[
]
[
]
[
]
( 0
) ( 0 )
( 0
0 )
(21)
([ B])
([ B0 ])
ln
[
B
]
[
A
]
*
k
*
t
ln
=
+
( 0
0 )
[
A
]
[
A
]
(
)
(
)
0
ln
ln [0]/[0]
(22)
{[B]/[A]}= f(t)
tg = k*{[B0]-[A0]}
[B0]>[A0]
ln []/[]
tg = k*{[B0]-[A0]}
ln [0]/[0]
[B0]<[A0]
, . -
.
(21)
[ x] = f (t )
1 exp ({[ B0 ] [ A0 ]} kt )
[ x] = [ B0 ]
[B ]
1 exp ({[ B0 ] [ A0 ]} kt ) 0
[ A0 ]
[ A0 ] > [ B0 ], t ,[ x] [ B0 ] , [ B0 ] > [ A0 ], t ,[ x] [ A0 ]
.
,
(23)
,
.
(23):
(24)
dx
= kdt
([ A0 ] x ) * ([ B0 ] + x )
(25)
dx
=
([ A0 ] x ) * ([ B0 ] + x )
dx
1
dx
+
*
([ B0 ] + [ A0 ]) ([ A0 ] x ) ([ B0 ] + x )
(26)
| |
([ B0 ] + x )
1
* ln
= kt
([ B0 ] + [ A0 ]) ([ A0 ] x ) 0 0
(27)
([ B ])
1
([ B0 ])
* ln
ln
= kt
([ B0 ] + [ A0 ]) ([ A]) ([ A0 ])
(28)
ln []/[]
A +B = 2B
ln [0]/[0]
tg = k*{[B0]+[A0]}
[ x] = g (t )
.
(15) (23).
.
dx
= k ([ A0 ] x )([ B0 ] x )
dt
dx
= k1 ([ A0 ] x )([ B0 ] + x )
dt
d 2x
.
2
dt
2
[ A0 ] ,
[ B0 ] , .
.
.
. ,
[ A0 ] , [ B0 ] , !
.
. . 51-53
C+D
(29)
9
(30)
(31)
[A]
[A0]
tg = - k
2N2O 2N2 + O2
(32)
.
N2O :
r = -d[N2O]/dt = k
(33)
, . N2O
0, N2O
N2O .
d [ N 2O ]gas
dt
10
2 N2O --> 2 N2 + O2
r = k"
p N2O
pN O
2
11