- (MOF)

.
MOF,
.

[Zn2(bdc)(L-lac)(dmf)] (bdc 1,4-, L-lac
-, dmf ) [1].
1H, 2D
(DS) 110330 K
dmf . [Zn2(bdc)
(L-lac)(dmf)]dmf [1] (1) (2)
dmf. 1
24 , 2 Bruker
Avance 500.
DSC - 245255 K
, 1- .
~ 5 K dmf dmf-d7
( ). MOF
[Zn2(bdc)2dabco] [2].

-30

-20

-10

f,

10

20

30

 1H [Zn2(bdc)(L-lac)(dmf)]
.1.

.

2D 2 (.2).

dmf .
:
.
,
. -,
,
.

:
[1] Danil N. Dybtsev, et. al. Angew. Chem. Int. Ed., V.45, 916 920
[2] Gabuda S. P. et. al. J. Phys. Chem. C, 112, 5074-5077.