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1. R-PhEtOH S-PhEtOH [Zn2(bdc)(S-lac)(dmf)]

R

K. Suh, M.P. Yutkin, D.N. Dybtsev, V.P. Fedin, K. Kim Chem. Commun., 2012, 48, 513.

 MAS 13C

DMF

S-PhEtOH

CH3

CH3

R-PhEtOH

Lac

PhEtOH

R
S

 1: R- S-PhEtOH

369 K
295 K

Ea = 56.4 kJ/mol
Ea = 53.0 kJ/mol

 1: MOF

[H] = 2 4 %

MAS 1H