VII , , 17-22.06.

2012

-
[Zn2(bdc)(L-lac)(dmf)]
. ., . ., . ., . .,
. ., . .
, 630090, . . 3,
, . E-mail: oihio@yandex.ru
- (MOF)
,

. MOF
[1], . ,
. ,
.

[Zn2(bdc)(L-lac)(dmf)] (bdc 1,4-, L-lac , dmf ) [2].
2
- 1H
D
()
110330 .
[Zn2(bdc)(L-lac)(dmf)]dmf [1] (-H7)
(-D7) . 1 (. 1)
24 , 2
Bruker Avance 500.

. 1. 1 [Zn2(bdc)(L-lac)(dmf)]dmf-h7
: 261 , 244, 234 K,
210 .

VII , , 17-22.06.2012

. 2. 1,
() - H7 (). Ttr 235 K
, .
bdc L-lac .


220 300 (. 2).
2
-D7 . 240255 K ,
1- . ~ 5 K
-7 -D7 ( ).
MOF [Zn2(bdc)2dabco] [3].

.

:
[1] Ma, L., Abney, C. and Lin, W. Chem. Soc. Rev., 2009, 38, 12481256.
[2] Danil N. Dybtsev, D. N., Nuzhdin, A. L., Chun, H., Bryliakov, K. P., Talsi, E. P., Fedin,
V. P. and Kim, K Angew. Chem. Int. Ed., 2006, 45, 916 920.
[3] ] S.P. Gabuda. et. al. J. Phys. Chem. C., 2008. 130, 67816788.