Вы находитесь на странице: 1из 8

P_sat exp [psi] T [°C] P_sat calc [bar] P_sat calc [psi] %Error

3 61 0.2088957432 3.0289882771 0.9662759


4 70.3 0.3157298003 4.5780821046 14.4520526
5 76 0.4016754548 5.824294095 16.4858819
6 80.4 0.4807986197 6.9715799849 16.1929997
7 84.8 0.5726238317 8.3030455589 18.6149366
8 88.6 0.6633434434 9.6184799299 20.2309991
9 92.4 0.7657776013 11.1037752193 23.3752802
10 94.9 0.8401108399 12.1816071787 21.8160718
11 97.5 0.9236950312 13.3935779523 21.7597996
12 99.7 0.9997150134 14.4958676948 20.7988975
13 102.4 1.1000413517 15.9505995992 22.69692
14 105.2 1.2127567571 17.5849729786 25.6069498
15 107.3 1.30342449 18.8996551045 25.9977007
16 110.5 1.4523033998 21.0583992973 31.6149956
17 112.5 1.552276325 22.5080067124 32.4000395
18 114.8 1.6741833892 24.2756591439 34.864773
19 115.6 1.7183877102 24.9166217985 31.1401147
20 116.3 1.7578493217 25.4888151652 27.4440758
21 117.4 1.821362757 26.4097599769 25.7607618
22 118.5 1.8867484221 27.357852121 24.3538733
23 119.8 1.9664929985 28.5141484786 23.9745586
24 121.3 2.0619183429 29.897815972 24.5742332
25 122.5 2.1409605632 31.0439281658 24.1757127
26 123.7 2.2224657233 32.2257529871 23.9452038
27 125 2.3136088788 33.5473287424 24.2493657
28 126.2 2.400430303 34.8062393933 24.3079978
29 128.2 2.5510340885 36.9899942835 27.5517044
30 129.4 2.6450351352 38.3530094602 27.8433649
31 130.5 2.7336642005 39.6381309079 27.8649384
32 131.5 2.8163205399 40.8366478279 27.6145245
33 132.5 2.900999521 42.064493055 27.4681608
34 133.5 2.9877377713 43.3221976837 27.4182285
35 134.5 3.0765723025 44.6102983862 27.4579954
36 135.5 3.1675405107 45.9293374048 27.5814928
37 136.6 3.2701150379 47.41666805 28.1531569
38 137.5 3.3560294592 48.6624271586 28.0590188
39 138.2 3.4241093066 49.6495849462 27.3066281
40 138.8 3.4833503427 50.5085799686 26.2714499
41 139.7 3.5737662555 51.819610704 26.3892944
42 140.3 3.6350921815 52.7088366314 25.4972301
43 140.9 3.6972670221 53.6103718205 24.6752833
44 141.5 3.7602993988 54.5243412831 23.9189575
45 142.1 3.8241979823 55.4508707428 23.2241572
46 142.8 3.8998527541 56.5478649348 22.9301412
47 143.5 3.9767123303 57.6623287891 22.6858059
48 144.4 4.0773246846 59.1212079272 23.1691832
49 145.9 4.2495709203 61.6187783449 25.7526089
50 145.5 4.2030752948 60.9445917749 21.8891835
51 146.2 4.2847141161 62.128354683 21.8203033
52 146.9 4.3676266867 63.3305869568 21.7895903
53 147.5 4.4397193614 64.3759307398 21.4640203
54 148.8 4.599210653 66.6885544684 23.4973231
55 148.9 4.6116677123 66.8691818284 21.5803306
56 149.1 4.6366633024 67.2316178844 20.0564605
57 149.2 4.6492019192 67.4134278291 18.2691716
58 149.4 4.6743610122 67.7782346775 16.8590253
59 149.5 4.6869815747 67.9612328332 15.1885302
60 149.5 4.6869815747 67.9612328332 13.2687214

Error promedio 22.7719409341 1366.3164560478


Antoine
A B C
5.116 1,687.537 230.170
http://www.fgsalazar.net/html/FQ_ANTOINE.htm
P_sat exp [psi] T [°C] P_sat calc [bar] P_sat calc [psi] %Error
3 61 0.2068965524 3.0000000099 3.288E-07
4 70.3 0.3029999464 4.3934992225 9.83748056
5 76 0.3784959839 5.4881917666 9.76383533
6 80.4 0.4469295455 6.4804784092 8.00797349
7 84.8 0.5253116175 7.6170184539 8.81454934
8 88.6 0.6018370704 8.7266375208 9.08296901
9 92.4 0.6873225593 9.9661771102 10.7353012
10 94.9 0.7488235938 10.8579421099 8.5794211
11 97.5 0.8175033522 11.8537986071 7.76180552
12 99.7 0.879571144 12.7537815876 6.28151323
13 102.4 0.9609599629 13.9339194615 7.18399586
14 105.2 1.0517549035 15.2504461009 8.93175786
15 107.3 1.1243403856 16.302935591 8.68623727
16 110.5 1.2427419586 18.0197584 12.62349
17 112.5 1.3217480253 19.1653463672 12.7373316
18 114.8 1.4175903268 20.5550597392 14.1947763
19 115.6 1.4522162258 21.0571352737 10.8270278
20 116.3 1.483072418 21.5045500604 7.5227503
21 117.4 1.5326304037 22.2231408537 5.82448026
22 118.5 1.5835184209 22.961017103 4.36825956
23 119.8 1.6454091516 23.8584326979 3.73231608
24 121.3 1.7192318158 24.9288613292 3.87025554
25 122.5 1.7801925957 25.812792637 3.25117055
26 123.7 1.8428825966 26.7217976507 2.77614481
27 125 1.912789294 27.735444763 2.72386949
28 126.2 1.9791962237 28.6983452432 2.49409015
29 128.2 2.0939810801 30.3627256621 4.69905401
30 129.4 2.1653759439 31.3979511859 4.65983729
31 130.5 2.2325232214 32.3715867109 4.42447326
32 131.5 2.2950040858 33.2775592446 3.99237264
33 132.5 2.3588770847 34.2037177286 3.64762948
34 133.5 2.4241643914 35.1503836753 3.3834814
35 134.5 2.4908883594 36.1178812106 3.19394632
36 135.5 2.5590715213 37.1065370587 3.07371405
37 136.6 2.6357854792 38.2188894478 3.2942958
38 137.5 2.6999064476 39.1486434895 3.02274603
39 138.2 2.7506330445 39.8841791458 2.26712601
40 138.8 2.7947148801 40.5233657617 1.3084144
41 139.7 2.8618909259 41.4974184257 1.21321567
42 140.3 2.9073845399 42.1570758287 0.37399007
43 140.9 2.9534517608 42.825050532 0.40685923
44 141.5 3.0000977052 43.5014167259 1.1331438
45 142.1 3.0473275118 44.1862489217 1.80833573
46 142.8 3.103173776 44.9960197521 2.18256576
47 143.5 3.1598299995 45.8175349933 2.51588299
48 144.4 3.2338771788 46.8912190932 2.30996022
49 145.9 3.3603429774 48.7249731716 0.56127924
50 145.5 3.3262419395 48.2305081233 3.53898375
51 146.2 3.3861001482 49.0984521484 3.7285252
52 146.9 3.4468088752 49.9787286907 3.88706021
53 147.5 3.4995282869 50.7431601605 4.25818838
54 148.8 3.6159442114 52.4311910659 2.90520173
55 148.9 3.6250246054 52.562856778 4.43116949
56 149.1 3.6432395032 52.826972797 5.66612001
57 149.2 3.6523740573 52.9594238311 7.08873012
58 149.4 3.6706975013 53.2251137687 8.23256247
59 149.5 3.6798864414 53.3583534008 9.56211288
60 149.5 3.6798864414 53.3583534008 11.069411

Error promedio 5.1408865194 308.4531911663


Antoine
A B C
4.716 1,586.598 232.806
http://www.fgsalazar.net/html/FQ_ANTOINE.htm

Minimos^2 -1.068656E-11
SumExp 1827
SumCal 1827

Presión [psi] T [°C] T [K] Ln (P2sat/P1sat) (1/T2 - 1/T1)


4.5 70 343.15 0.1445812288 -8.251953768677E-05
5.2 80 353.15 0.1596301456 -7.797488464054E-05
6.1 90 363.15 0.0635134057 -7.37956063535E-05
6.5 100 373.15 0.0741079722 -6.994355852087E-05
7 110 383.15 0.1082135846 -6.638544795133E-05
7.8 120 393.15 0.025317808 -6.309211058552E-05
8 130 403.15 0.0606246218 -6.003791184E-05
8.5 140 413.15

0.18

0.16

0.14
f(x) = - 4058.0447718241x - 0.1907884602
R² = 0.3769521089
0.12

0.1
Column K
0.08 Linear (Column K)
0.06

0.04

0.02

0
-0.000085 -0.00008 -0.000075 -0.00007 -0.000065
DHvap/R [K^-1] -4058
R [kJ/kmol*K] 8.314
Exp. DHvap [kJ/kmol] 33738.212
Teorico. DHvap [kJ/kmol] 40668.48 http://ri.uaemex.mx/bitstream/handle/20.500.11799/63483/secme-31840.pdf

%Error DHvap 17.0408828


/63483/secme-31840.pdf?sequence=1

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