Vad (mL) [H3PO4] [H2PO4] [HPO4] [H+] pH [OH-]

0.00 2.45E-02 1.61

3.50 0.051547234 0.01596595745 2.45E-02 1.61
4.00 0.04824 0.01786666667 2.05E-02 1.69
4.50 0.0450677551 0.01968979592 1.74E-02 1.76
5.00 0.0420224 0.02144 1.49E-02 1.83
5.50 0.0390964706 0.02312156863 1.28E-02 1.89
6.00 0.0362830769 0.02473846154 1.11E-02 1.95
6.50 0.0335758491 0.02629433962 9.69E-03 2.01
14.00
7.00 0.0309688889 0.02779259259 8.45E-03 2.07
7.40 0.0289518248 0.02895182482 7.59E-03 2.12
8.00 0.0260342857 0.03062857143 6.45E-03 2.19
12.00
8.50 0.0236968421 0.03197192982 5.62E-03 2.25
9.00 0.02144 0.03326896552 4.89E-03 2.31
9.50 0.019259661 0.0345220339 4.23E-03 2.37
10.00
10.00 0.017152 0.03573333333 3.64E-03 2.44
10.50 0.0151134426 0.03690491803 3.11E-03 2.51
11.00 0.0131406452 0.03803870968 2.62E-03 2.58
8.00
11.50 0.0112304762 0.03913650794 2.18E-03 2.66
12.00 0.00938 0.0402 1.77E-03 2.75

pH
12.50 0.0075864615 0.04123076923 1.40E-03 2.86
6.00
13.00 0.0058472727 0.04223030303 1.05E-03 2.98
13.50 0.00416 0.0432 7.30E-04 3.14
13.79 0.0032042616 0.04374927493 5.56E-04 3.26
4.00
13.90 0.0028460177 0.04395516224 4.91E-04 3.31
14.00 0.0025223529 0.04414117647 4.33E-04 3.36
14.10 0.0022005865 0.04432609971 3.77E-04 3.42
2.00
14.20 0.0018807018 0.04450994152 3.21E-04 3.49
14.30 0.0015626822 0.04469271137 2.65E-04 3.58
14.40 0.0012465116 0.0448744186 2.11E-04 3.68
0.00
14.50 0.0009321739 0.04505507246 1.57E-04 3.80 0.00
14.60 0.0006196532 0.04523468208 1.04E-04 3.98
14.70 0.0003089337 0.04541325648 5.16E-05 4.29
14.80 0 0.0455908046 2.16E-05 4.67
14.90 0.0451530086 0.000307163324 9.06E-06 5.04
15.00 0.04471771429 0.000612571429 4.50E-06 5.35
15.10 0.04428490028 0.000916239316 2.98E-06 5.53
15.20 0.04385454545 0.001218181818 2.22E-06 5.65
15.30 0.0434266289 0.001518413598 1.76E-06 5.75
15.40 0.04300112994 0.001816949153 1.46E-06 5.84
15.50 0.04257802817 0.002113802817 1.24E-06 5.91
15.60 0.04215730337 0.002408988764 1.08E-06 5.97
15.70 0.04173893557 0.002702521008 9.52E-07 6.02
15.80 0.04132290503 0.002994413408 8.51E-07 6.07
16.00 0.04049777778 0.003573333333 6.99E-07 6.16
16.50 0.03847452055 0.004992876712 4.75E-07 6.32
17.00 0.03650594595 0.006374054054 3.53E-07 6.45
17.50 0.03458986667 0.0077184 2.76E-07 6.56
18.00 0.03272421053 0.009027368421 2.24E-07 6.65
18.50 0.03090701299 0.010302337662 1.85E-07 6.73
19.00 0.02913641026 0.011544615385 1.56E-07 6.81
19.50 0.02741063291 0.012755443038 1.33E-07 6.88
20.00 0.025728 0.013936 1.14E-07 6.94
20.50 0.02408691358 0.015087407407 9.84E-08 7.01
21.00 0.02248585366 0.016210731707 8.55E-08 7.07
21.50 0.02092337349 0.017306987952 7.45E-08 7.13
22.00 0.01939809524 0.018377142857 6.51E-08 7.19
22.50 0.01790870588 0.019422117647 5.69E-08 7.25
23.00 0.01645395349 0.020442790698 4.96E-08 7.30
23.50 0.01503264368 0.02144 4.32E-08 7.36
24.00 0.01364363636 0.022414545455 3.75E-08 7.43
24.50 0.0122858427 0.023367191011 3.24E-08 7.49
25.00 0.01095822222 0.024298666667 2.78E-08 7.56
25.50 0.00965978022 0.02520967033 2.36E-08 7.63
26.00 0.00838956522 0.026100869565 1.98E-08 7.70
26.50 0.00714666667 0.026972903226 1.63E-08 7.79
27.00 0.00593021277 0.027826382979 1.31E-08 7.88
27.50 0.00473936842 0.028661894737 1.02E-08 7.99
28.00 0.00357333333 0.02948 7.47E-09 8.13
28.60 0.00220576132 0.030439506173 4.47E-09 8.35
28.70 0.00198110883 0.030597125257 3.99E-09 8.40
28.80 0.00175737705 0.030754098361 3.52E-09 8.45
28.90 0.00153456033 0.030910429448 3.06E-09 8.51
29.00 0.00131265306 0.031066122449 2.61E-09 8.58
29.10 0.00109164969 0.031221181263 2.16E-09 8.67
29.20 0.00087154472 0.031375609756 1.71E-09 8.77
29.30 0.00065233266 0.031529411765 1.28E-09 8.89
29.40 0.0004340081 0.031682591093 8.45E-10 9.07
29.50 0.00021656566 0.031835151515 4.19E-10 9.38
29.60 1.76E-10 9.76
29.70 4.64E-11 10.33 2.16E-04
29.79 2.44E-11 10.61 4.09E-04
29.90 1.55E-11 10.81 6.44E-04
30.00 1.17E-11 10.93 8.58E-04
30.10 9.35E-12 11.03 1.07E-03
30.20 7.80E-12 11.11 1.28E-03
30.30 6.70E-12 11.17 1.49E-03
30.40 5.88E-12 11.23 1.70E-03
30.50 5.23E-12 11.28 1.91E-03
30.60 4.72E-12 11.33 2.12E-03
30.70 4.30E-12 11.37 2.33E-03
30.80 3.95E-12 11.40 2.53E-03
31.00 3.40E-12 11.47 2.94E-03
33.00 1.45E-12 11.84 6.88E-03
35.00 9.50E-13 12.02 1.05E-02
40.00 5.38E-13 12.27 1.86E-02
 H3PO4 0.079328 NaOH 0.1072 pKa1 2.12 Aluna:
Vi 20 Kw 1.00E-14 pKa2 7.21 Turma:
Ka1 7.59E-03 pKa3 12.3
Ka2 6.17E-08 PE 1 14.80
Ka3 5.01E-13 PE 2 29.60

Curva de Titulação do Ácido Fosfórico

14.00

12.00

10.00

8.00
pH

6.00

4.00

2.00

0.00
0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.

Volume adicionado de NaOH

 Lorena Leonarda Mattos Furtado
QUIM251

30.00 35.00 40.00 45.00