t (seg) Xa Ca (mol/m3) -dCa/dt log(Ca) log(-dCa/dt) Ordem0

0 0 153.1 1.475843 2.184975 0.169040089402647 1.47584276094276

29.7 0.2863 109.26747 1.087294 2.038491 0.0363467991602925 1.37222962962963
40.5 0.363 97.5247 0.997276 1.989115 -0.00118446301792502 1.31563291404612
47.7 0.4099 90.34431 0.894028 1.955901 -0.048648687442576 1.25443225806452
55.8 0.4572 83.10268 0.729048 1.919615 -0.137244104035658 1.20113236714976
62.1 0.4872 78.50968 0.477526 1.894923 -0.321002804043876 1.04705652724968
78.9 0.5396 70.48724 1.272644 1.05999342891278
83.7 0.5795 64.37855

k média 1.24661712657075
2.537E-05 desvio padrão 0.158044744849665
desvio padrão relativo 12.6778897450592

CONCLUI-SE QUE A MELHOR OPÇÃO É A DE ORDEM 1

k 1.07765652992E-02
 Ordem1 Ordem2
0.011356652 8.8221413E-05 log(-dCa/dt)
0.0111354474916043 9.1904543E-05 0.2
0.0110579300821596 9.5117129E-05 f(x) = 1.4258911177447 x − 2.89819576431301
R² = 0.808385577906106
0.0109500779752943 9.8595477E-05 0.1
0.0107547403120077 9.9929214E-05
0.00983092017914334 9.7025174E-05 0
1.85 1.9 1.95 2 2.05 2.1 2.15 2.2 2.25
0.0103501887642668 1.07544E-04
-0.1

-0.2

1.07765652992E-02 9.69053E-05
-0.3
0.000524577307166155 6.1754254E-06
4.86775974165362 6.37263941954
-0.4

ÃO É A DE ORDEM 1
 t (seg) Xa Ca (mol/m3) -dCa/dt log(Ca) log(-dCa/dt)
0 0 28.6 0.000276 1.456366 -3.55956906817
29700 0.2863 20.41182 0.000203 1.309882 -3.69226235841
40500 0.363 18.2182 0.000186 1.260505 -3.72979362059
47700 0.4099 16.87686 0.000167 1.227292 -3.77725784501
55800 0.4572 15.52408 0.000136 1.191006 -3.8658532616
62100 0.4872 14.66608 8.92E-05 1.166314 -4.04961196161
2.15 2.2 2.25
78900 0.5396 13.16744 0.000238 1.119501 -3.62390230856
83700 0.5795 12.0263

k
1.7934943E-05

Xa de etileno de brometo
-3.3
1.1 1.15 1.2 1.25 1.3 1.35 1.4 1.45 1.5
-3.4

-3.5

-3.6
f(x) = 0.79326206244653 x − 4.74630218713497
R² = 0.292961763430255
-3.7

-3.8

-3.9

-4

-4.1
 Ordem0 Ordem1 Ordem2
0.0002756963 1.13566522897E-05 4.7226218E-07
0.00025634074 1.11354474916E-05 4.9197851E-07
0.00024576813 1.10579300822E-05 5.0917596E-07
0.00023433548 1.09500779753E-05 5.2779607E-07
0.00022437874 1.07547403120E-05 5.3493576E-07
0.00019559645 9.83092017914E-06 5.1939001E-07
0.00019801314 1.03501887643E-05 5.7569963E-07

média 0.00023287557 1.0776565299173E-05 5.187483E-07

dp 2.9523708E-05 5.2457730716616E-07 3.3057959E-08
dp.relativo 12.6778897451 4.86775974165362 6.37263941954

1.45 1.5
 t (kseg) Xa Ordem0 Ordem1 Ordem2 ordem0 ordem1 ordem2
0 0 0.000276 0.011357 0.472262 média 0.0002328756 0.010777 0.518748
29.7 0.2863 0.000256 0.011135 0.491979 dp 2.9523708E-05 0.000525 0.033058
40.5 0.363 0.000246 0.011058 0.509176 dp.relativo 12.677889745 4.86776 6.372639
47.7 0.4099 0.000234 0.01095 0.527796
55.8 0.4572 0.000224 0.010755 0.534936
62.1 0.4872 0.000196 0.009831 0.51939
78.9 0.5396 0.000198 0.01035 0.5757
83.7 0.5795
0.035

0.03

KI(inicial) 0.1531
0.025
EB(inicial) 0.0286
0.02 real
Linear (real)
0.015 teorico
Linear (teorico)

0.01

0.005

0
0 10 20 30 40 50 60 70 80 90
 t (kseg) Xa Ca_pratica Ca_teo k 0.010777 -LN(1-Xa)
0 0 0.0286 0.0286 0
29.7 0.2863 0.02041182 0.020767 0.337293
40.5 0.363 0.0182182 0.018485 0.450986
47.7 0.4099 0.01687686 0.017105 0.527463
55.8 0.4572 0.01552408 0.015675 0.611014
62.1 0.4872 0.01466608 0.014646 0.667869
78.9 0.5396 0.01316744 0.012221 0.77566
83.7 0.5795 0.0120263 0.011605 0.866311

(real)
o
(teorico)
kt
0 teste ordem1
0.320064 1
0.436451 0.9
0.514042 f(x) = 0.0105094589496267 x
0.8 R² = 0.997889077114011
0.601332 0.7
0.669225 0.6
0.850271 0.5
0.901999
0.4
0.3
0.2
0.1
0
0 10 20 30 40 50 60 70 80 90
Exp A NB NC k2/k1
1 0.228 0.172 0.056 0.305333
2 0.315 0.235 0.08 0.311265
3 0.343 0.257 0.086 0.302716
4 0.411 0.307 0.104 0.299447
5 0.508 0.376 0.132 0.300174

0.303787
B=C 1 mol/m^3
B0=C0 0.001 mol/L
t X dx/dt
99 0.000022 4.581356E-05
217 0.000046 6.455769E-05
321 0.000065 9.056667E-05
471 0.000091 0.0001082155
587 0.000109
7.728836E-05
t [H2O2] -dCa/dt ln Ca ln(-dCa/dt) log Ca log(-dCa/dt) k
0 0.1195 0.016 -2.124439 -4.13516656 -0.922632 -1.795880017 ordem
2 0.0875 0.008367 -2.436116 -4.78349972 -1.057992 -2.077447533 k
5 0.0624 0.004975 -2.77419 -5.30332991 -1.204815 -2.303206915
9 0.0425 0.00328 -3.158251 -5.71991186 -1.371611 -2.484126156
14 0.0261 0.002033 -3.64582 -6.19847872 -1.583359 -2.691965103
20.15 0.0136 0.000872 -4.297685 -7.04416713 -1.866461 -3.059242916
26.11 0.0084 0.00054 -4.779524 -7.52375958 -2.075721 -3.26752727
32.22 0.0051

log(-dCa/dt)
0
-2.2 -2 -1.8 -1.6 -1.4 -1.2 -1 -0.8 -5 -4.5 -4
-0.5

-1

-1.5

f(x) = 1.22849462499471 x − 0.756140864843883 -2

f(x) = 1.2284946249
R² = 0.989523994364061 R² = 0.98952399436
-2.5

-3

-3.5
 0.175348 log
1
0.175327 ln

ln(-dCa/dt)
0
5 -4.5 -4 -3.5 -3 -2.5 -2 -1.5
-1

-2

-3

-4
f(x) = 1.22849462499471 x − 1.74107868359315
R² = 0.989523994364061 -5

-6

-7

-8
t(seg) [H2O2] -dCa/dt ln Ca ln(-dCa/dt) log Ca log(-dCa/dt) k (log)
0 0.1195 0.00026666667 -2.124439 -8.229511 -0.922632 -3.5740312677 k (ln)
120 0.0875 0.00013944444 -2.436116 -8.877844 -1.057992 -3.8555987836 ordem
300 0.0624 0.00008291667 -2.77419 -9.397674 -1.204815 -4.0813581653
540 0.0425 0.00005466667 -3.158251 -9.814256 -1.371611 -4.2622774067 0.079317
840 0.0261 0.00003387534 -3.64582 -10.29282 -1.583359 -4.4701163532
1209 0.0136 0.00001454139 -4.297685 -11.13851 -1.866461 -4.8373941665
1566.6 0.0084 0.00000900164 -4.779524 -11.6181 -2.075721 -5.0456785207
1933.2 0.0051

ln(-dCa/dt)
0
-5 -4.5 -4 -3.5 -3 -2.5 -2 -1.5 -2.2 -2 -1.8
-2

-4

-6

-8
f(x) = 1.22849462499471 x − 5.83542324581525 f(x) = 1.22849462499471 x
R² = 0.989523994364061 -10 R² = 0.989523994364061

-12

-14
 0.002922
0.002922
1

log(-dCa/dt)
0
-1.8 -1.6 -1.4 -1.2 -1 -0.8

-1

-2

-3

1.22849462499471 x − 2.53429211522753 -4
0.989523994364061

-5

-6