T (K) 318.

15 Ethanol (1) Benzene (2)

Datos Experimentales
Pvap (kPa) P (kPa) x1 y1 f1 id f2 id f1 real f2 real γ1 γ2
Ethanol (1) 23.02 36.132 0.0374 0.1965 0.860948 28.58922 7.099938 29.032062 8.24665137 1.01548982
Benzene (2) 29.7 39.534 0.0972 0.2895 2.237544 26.81316 11.445093 28.088907 5.11502478 1.04757914
40.870 0.2183 0.337 5.025266 23.21649 13.77319 27.09681 2.74078825 1.16713638
41.241 0.3141 0.3625 7.230582 20.37123 14.9498625 26.2911375 2.06758771 1.29060138
41.275 0.415 0.3842 9.5533 17.3745 15.857855 25.417145 1.65993479 1.46289936
40.991 0.5199 0.4065 11.968098 14.25897 16.6628415 24.3281585 1.39227148 1.70616521
40.929 0.5284 0.4101 12.163768 14.00652 16.7849829 24.1440171 1.3799164 1.72376987
40.270 0.6155 0.4343 14.16881 11.41965 17.489261 22.780739 1.23434932 1.99487191
38.905 0.7087 0.4751 16.314274 8.65161 18.4837655 20.4212345 1.13298119 2.36039702
36.141 0.8102 0.5456 18.650804 5.63706 19.7185296 16.4224704 1.05724823 2.91330417
30.360 0.9193 0.7078 21.162286 2.39679 21.488808 8.871192 1.01542943 3.70128046
27.102 0.9591 0.8201 22.078482 1.21473 22.2263502 4.8756498 1.00669739 4.01377244

Cálculos con Margules

Ajsute parámetros
A12 2.2956
A21 1.4121
x1 γ1 γ2 Pbur (kPa) y1
0 9.93039246 1 29.7 #DIV/0!
0.01 9.32406967 1.00031619 31.5586979 0.06801297
0.02 8.76488768 1.00125829 33.1779782 0.12162749
0.03 8.24867788 1.00281744 34.5867046 0.16470308
0.04 7.77167934 1.00498586 35.8103192 0.1998352
0.05 7.33049559 1.0077568 36.8712587 0.22883408
0.06 6.92205636 1.01112451 37.7893183 0.25300124
0.07 6.54358355 1.01508414 38.5819697 0.27329684
0.08 6.19256102 1.01963175 39.2646384 0.29044506
0.09 5.86670775 1.02476423 39.850948 0.30500266
0.1 5.56395396 1.03047927 40.3529328 0.31740498
0.11 5.28241977 1.03677531 40.7812251 0.32799758
0.12 5.02039625 1.04365154 41.1452194 0.33705842
0.13 4.77632843 1.05110784 41.4532159 0.34481379
0.14 4.54880023 1.05914472 41.7125477 0.35144996
0.15 4.33652083 1.06776334 41.929692 0.35712178
0.16 4.13831263 1.07696546 42.1103674 0.36195916
0.17 3.95310035 1.0867534 42.2596209 0.36607197
0.18 3.77990129 1.09713002 42.3819035 0.36955393
0.19 3.61781664 1.10809869 42.4811367 0.37248548
0.2 3.4660236 1.11966328 42.5607723 0.37493616
0.21 3.32376831 1.13182811 42.6238437 0.37696649
0.22 3.19035956 1.14459793 42.6730126 0.37862939
0.23 3.06516301 1.15797791 42.7106088 0.37997145
0.24 2.94759609 1.17197358 42.7386666 0.38103385
0.25 2.83712332 1.18659086 42.7589562 0.38185321
0.26 2.73325216 1.20183598 42.7730119 0.38246221
0.27 2.63552915 1.21771546 42.7821568 0.38289018
0.28 2.54353655 1.23423612 42.7875245 0.38316354
0.29 2.4568892 1.25140503 42.7900789 0.38330616
0.3 2.37523172 1.26922947 42.790631 0.38333976
0.31 2.29823598 1.28771691 42.7898542 0.38328412
0.32 2.22559876 1.30687499 42.788298 0.38315735
0.33 2.15703968 1.32671148 42.7863994 0.38297608
0.34 2.09229927 1.34723426 42.7844938 0.38275568
0.35 2.03113728 1.36845125 42.7828245 0.38251035
0.36 1.97333106 1.39037043 42.7815503 0.38225331
0.37 1.91867413 1.41299977 42.7807537 0.38199689
0.38 1.86697489 1.43634719 42.7804467 0.38175267
0.39 1.81805543 1.46042054 42.780577 0.38153151
0.4 1.77175043 1.48522756 42.7810331 0.38134371
0.41 1.72790614 1.51077581 42.7816483 0.38119905
0.42 1.68637954 1.53707267 42.7822057 0.38110686
0.43 1.64703742 1.56412525 42.7824409 0.38107607
0.44 1.60975571 1.59194037 42.7820459 0.38111533
0.45 1.5744187 1.62052452 42.7806714 0.38123299
0.46 1.54091847 1.64988378 42.7779299 0.3814372
0.47 1.50915426 1.68002378 42.7733979 0.38173595
0.48 1.47903194 1.71094966 42.7666179 0.3821371
0.49 1.45046352 1.742666 42.7571004 0.38264846
0.5 1.42336673 1.77517676 42.7443259 0.3832778
0.51 1.39766452 1.80848521 42.7277462 0.38403292
0.52 1.37328476 1.84259389 42.7067864 0.38492168
0.53 1.35015983 1.87750456 42.6808462 0.38595205
0.54 1.32822634 1.91321806 42.6493011 0.38713216
0.55 1.30742477 1.94973434 42.6115044 0.38847033
0.56 1.28769924 1.98705231 42.5667879 0.38997512
0.57 1.26899723 2.02516982 42.5144641 0.39165542
0.58 1.25126937 2.06408357 42.4538266 0.39352043
0.59 1.23446918 2.10378903 42.3841525 0.39557978
0.6 1.21855289 2.14428036 42.3047032 0.39784353
0.61 1.20347925 2.18555037 42.2147262 0.4003223
0.62 1.18920934 2.2275904 42.1134566 0.40302727
0.63 1.17570644 2.27039027 42.0001188 0.40597028
0.64 1.16293585 2.31393818 41.8739283 0.40916394
0.65 1.15086476 2.35822066 41.7340931 0.41262163
0.66 1.13946212 2.40322246 41.5798163 0.41635768
0.67 1.12869852 2.44892651 41.4102975 0.42038744
0.68 1.11854608 2.49531381 41.2247353 0.42472736
0.69 1.10897832 2.54236336 41.0223293 0.42939516
0.7 1.0999701 2.59005212 40.8022826 0.43440997
0.71 1.09149752 2.63835488 40.5638044 0.43979242
0.72 1.0835378 2.68724424 40.306112 0.4455649
0.73 1.07606923 2.73669052 40.0284343 0.45175169
0.74 1.06907111 2.78666169 39.7300141 0.45837921
0.75 1.06252364 2.83712332 39.4101114 0.46547625
0.76 1.05640789 2.88803855 39.068006 0.47307424
0.77 1.0507057 2.93936796 38.7030013 0.48120761
0.78 1.04539965 2.99106962 38.3144269 0.4899141
0.79 1.04047303 3.04309898 37.9016428 0.49923521
0.8 1.03590972 3.09540886 37.4640421 0.50921664
0.81 1.03169421 3.14794942 37.0010551 0.51990886
0.82 1.0278115 3.20066815 36.5121529 0.53136776
0.83 1.02424711 3.25350983 35.9968509 0.54365533
0.84 1.02098699 3.30641656 35.4547126 0.55684053
0.85 1.01801752 3.35932773 34.8853538 0.57100034
0.86 1.01532546 3.41218008 34.2884459 0.58622083
0.87 1.01289791 3.46490768 33.6637201 0.60259863
0.88 1.01072229 3.51744198 33.0109711 0.62024252
0.89 1.00878631 3.56971188 32.3300609 0.63927539
0.9 1.00707793 3.62164376 31.6209225 0.65983655
0.91 1.00558534 3.67316156 30.8835637 0.68208459
0.92 1.00429695 3.72418689 30.1180706 0.7062007
0.93 1.00320133 3.77463908 29.3246107 0.73239288
0.94 1.00228724 3.82443534 28.503437 0.76090098
0.95 1.00154357 3.87349083 27.6548901 0.79200301
0.96 1.00095931 3.92171888 26.779402 0.82602292
0.97 1.00052359 3.96903106 25.877498 0.86334047
0.98 1.0002256 4.01533739 24.9497999 0.90440363
0.99 1.00005463 4.06054653 23.9970273 0.94974451
1 1 4.10456595 23.02 1
 GE/RT (GE/RT)/(x1x2)
0.09370299 2.60277127856
0.20061199 2.2861202457
0.34091425 1.99779675891
0.40313554 1.87120923586
0.4328589 1.78296322012
0.42854652 1.71690574273
0.42694956 1.71332582896
0.39511776 1.66956045623
0.33866001 1.64044245189
0.24805429 1.61308889054
0.11968634 1.61329503162
0.06324207 1.61219992064
 45

40

35
P (kPa)

30

25

20
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1 ó y1
 9

5
gi

1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1
 25

20

15
Fugacidad (kPa)

10

5
Fugacidad real
Fugacidad ideal

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1
 3

2.5

f(x) = − 0.883517239751543 x + 2.29560115144195

R² = 0.760000106924394
2
(GE/RT)/(x1x2)

1.5

0.5

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1
11

10

1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
45

40

35

30

25

20
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1