DATOS DE TABLA

DIAGRAMA DE EQUILIBRIO SISTEMA BENCENO-TOLUENO

SUSTANCIA Teb [°C] Pc [psia) A1 A2 A3 PT [psia] 14.696
BENCENO 80.13 714.2 5.658375 5307.813 379.456 1 Atm
TOLUENO 110.60 587.8 5.944251 5836.287 374.745

T T PvA PvB
xA yA xB yB kA kB
[°C] [°F] [psia] [psia]
LI 80.127777778 176.23 14.55183937 5.629297913 1 1 0 0 1 #DIV/0!
81.080034722 177.9440625 14.98560739 5.817297904 0.968412128 0.987496185 0.031587872 0.012503815 1.019706545 0.395842263
82.032291667 179.658125 15.42952634 6.010355446 0.922124108 0.968150395 0.077875892 0.031849605 1.049913333 0.408979004
82.984548611 181.3721875 15.8837609 6.208570318 0.877236434 0.948136484 0.122763566 0.051863516 1.080822053 0.422466679
83.936805556 183.08625 16.34847693 6.412043409 0.833695166 0.92743918 0.166304834 0.07256082 1.112443994 0.436312154
84.8890625 184.8003125 16.82384148 6.620876712 0.791448708 0.906042978 0.208551292 0.093957022 1.14479052 0.450522367
85.841319444 186.514375 17.31002276 6.835173322 0.750447701 0.883932144 0.249552299 0.116067856 1.177873078 0.465104336
86.793576389 188.2284375 17.80719012 7.055037434 0.710644909 0.861090705 0.289355091 0.138909295 1.211703193 0.480065149
87.745833333 189.9425 18.31551404 7.280574339 0.671995123 0.837502457 0.328004877 0.162497543 1.246292463 0.495411972
88.698090278 191.6565625 18.83516614 7.511890417 0.634455061 0.813150958 0.365544939 0.186849042 1.281652568 0.511152043
89.650347222 193.370625 19.36631912 7.74909314 0.597983277 0.788019527 0.402016723 0.211980473 1.317795258 0.527292674
90.602604167 195.0846875 19.90914679 7.992291058 0.562540077 0.762091247 0.437459923 0.237908753 1.354732362 0.543841253
91.554861111 196.79875 20.46382402 8.241593805 0.528087434 0.73534896 0.471912566 0.26465104 1.392475777 0.56080524
92.507118056 198.5128125 21.03052677 8.497112086 0.49458891 0.707775267 0.50541109 0.292224733 1.431037478 0.578192167
93.459375 200.226875 21.60943202 8.758957678 0.462009585 0.679352526 0.537990415 0.320647474 1.470429506 0.596009641
94.411631944 201.9409375 22.20071779 9.02724342 0.430315983 0.650062855 0.569684017 0.349937145 1.510663976 0.614265339
95.363888889 203.655 22.80456312 9.302083212 0.399476009 0.619888124 0.600523991 0.380111876 1.55175307 0.632967012
96.316145833 205.3690625 23.42114805 9.583592008 0.369458883 0.588809961 0.630541117 0.411190039 1.59370904 0.652122483
97.268402778 207.083125 24.0506536 9.87188581 0.34023508 0.556809747 0.65976492 0.443190253 1.636544203 0.671739644
98.220659722 208.7971875 24.69326177 10.16708166 0.311776276 0.523868617 0.688223724 0.476131383 1.680270943 0.69182646
99.172916667 210.51125 25.34915552 10.46929765 0.284055291 0.489967456 0.715944709 0.510032544 1.724901709 0.712390967
100.12517361 212.2253125 26.01851872 10.77865287 0.257046037 0.455086904 0.742953963 0.544913096 1.770449015 0.733441268
101.07743056 213.939375 26.7015362 11.09526748 0.230723473 0.419207347 0.769276527 0.580792653 1.816925435 0.754985539
102.0296875 215.6534375 27.39839366 11.41926262 0.205063553 0.382308924 0.794936447 0.617691076 1.864343608 0.777032024
102.98194444 217.3675 28.10927773 11.75076046 0.180043184 0.344371521 0.819956816 0.655628479 1.912716231 0.799589035
103.93420139 219.0815625 28.83437589 12.08988416 0.155640188 0.305374774 0.844359812 0.694625226 1.962056062 0.822664954
104.88645833 220.795625 29.57387647 12.4367579 0.131833254 0.265298065 0.868166746 0.734701935 2.012375917 0.84626823
105.83871528 222.5096875 30.32796867 12.79150683 0.108601905 0.224120522 0.891398095 0.775879478 2.063688668 0.870407378
 106.79097222 224.22375 31.09684249 13.15425709 0.085926464 0.18182102 0.914073536 0.81817898 2.116007246 0.895090983
107.74322917 225.9378125 31.88068875 13.52513579 0.063788011 0.138378179 0.936211989 0.861621821 2.169344635 0.920327694
108.69548611 227.651875 32.67969906 13.90427101 0.042168359 0.093770364 0.957831641 0.906229636 2.223713872 0.946126226
109.64774306 229.3659375 33.4940658 14.29179181 0.021050017 0.047975684 0.978949983 0.952024316 2.279128049 0.97249536
110.12387153 230.2229688 33.90706817 14.48873738 0.010673555 0.024626358 0.989326445 0.975373642 2.307231095 0.985896664
110.36193576 230.6514844 34.11503468 14.5880136 0.005530101 0.012837479 0.994469899 0.987162521 2.321382327 0.992651987
LS 110.6 231.08 34.32398213 14.68782816 0.000416163 0.00097199 0.999583837 0.99902801 2.335600308 0.999443941
PROMEDIO=
130

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50
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
DATOS DE TABLAS
TebA 635.9
TebB 690.75
PcA 714.2
PcB 587.8

ALPHA 2.44
Alpha

xA yA
2.57604263
2.567157047 0 0.00
2.558360473 0.05 0.11
2.54965163 0.1 0.21
2.541029265 0.15 0.30
2.532492147 0.2 0.38
2.524039069 0.25 0.45
2.515668845 0.3 0.51
2.507380312 0.35 0.57
2.499172325 0.4 0.62
2.491043762 0.45 0.67
2.482993521 0.5 0.71
2.47502052 0.55 0.75
2.467123694 0.6 0.79
2.459301999 0.65 0.82
2.45155441 0.7 0.85
2.443879918 0.75 0.88
2.436277532 0.8 0.91
2.428746281 0.85 0.93
2.421285207 0.9 0.96
2.413893371 0.95 0.98
2.40656985 1 1.00
2.399313736
2.392124138
2.385000179
2.377940996
2.370945743
2.364013588
2.35714371
2.350335305
2.343587582
2.340236232
2.338566142
2.336899761
2.44426
 Diagrama de Equilibrio X-Y
@1atm
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 DIAGRAMA DE EQUILIBRIO SISTEMA BENCENO-TOLUENO
SUSTANCIA Teb [°C] Pc [psia) A1 A2 A3
BENCENO 80.56 714.2 5.658375 5307.813 379.456
TOLUENO 108.89 587.8 5.944251 5836.287 374.745

T T PvA PvB
xA yA xB
[°C] [°F] [psia] [psia]
LI 80.5555556 177 14.7454536 5.7131329 1 1 0
81.4409722 178.59375 15.1526642 5.88987266 0.95069908 0.98024114 0.04930092
82.3263889 180.1875 15.5687045 6.07101747 0.908114 0.96204127 0.091886
83.2118056 181.78125 15.9937073 6.25664784 0.86672493 0.94325972 0.13327507
84.0972222 183.375 16.4278062 6.44684512 0.82648904 0.92388417 0.17351096
84.9826389 184.96875 16.8711356 6.64169147 0.78736522 0.90390211 0.21263478
85.8680556 186.5625 17.3238308 6.8412699 0.74931404 0.88330088 0.25068596
86.7534722 188.15625 17.7860281 7.04566421 0.71229763 0.86206762 0.28770237
87.6388889 189.75 18.2578646 7.25495903 0.67627964 0.84018931 0.32372036
88.5243056 191.34375 18.739478 7.46923981 0.64122515 0.81765274 0.35877485
89.4097222 192.9375 19.2310071 7.68859282 0.60710065 0.79444453 0.39289935
90.2951389 194.53125 19.7325914 7.91310513 0.57387392 0.77055114 0.42612608
91.1805556 196.125 20.2443713 8.14286462 0.54151401 0.74595881 0.45848599
92.0659722 197.71875 20.7664878 8.37795997 0.50999119 0.72065363 0.49000881
92.9513889 199.3125 21.2990829 8.61848066 0.47927687 0.69462151 0.52072313
93.8368056 200.90625 21.8422993 8.86451698 0.44934357 0.66784817 0.55065643
94.7222222 202.5 22.3962805 9.11616 0.42016486 0.64031914 0.57983514
95.6076389 204.09375 22.9611705 9.37350159 0.39171534 0.61201979 0.60828466
96.4930556 205.6875 23.5371146 9.6366344 0.36397056 0.58293528 0.63602944
97.3784722 207.28125 24.1242582 9.90565187 0.33690701 0.5530506 0.66309299
98.2638889 208.875 24.7227478 10.1806482 0.31050205 0.52235057 0.68949795
99.1493056 210.46875 25.3327306 10.4617184 0.28473392 0.49081979 0.71526608
100.034722 212.0625 25.9543544 10.7489582 0.25958165 0.45844271 0.74041835
100.920139 213.65625 26.5877677 11.0424642 0.23502506 0.42520356 0.76497494
101.805556 215.25 27.2331196 11.3423336 0.21104472 0.39108642 0.78895528
102.690972 216.84375 27.8905602 11.6486644 0.18762192 0.35607514 0.81237808
103.576389 218.4375 28.5602398 11.9615555 0.16473863 0.32015343 0.83526137
104.461806 220.03125 29.2423097 12.2811064 0.14237749 0.28330476 0.85762251
105.347222 221.625 29.9369216 12.6074174 0.12052178 0.24551245 0.87947822
106.232639 223.21875 30.644228 12.9405895 0.09915535 0.20675961 0.90084465
107.118056 224.8125 31.3643819 13.2807244 0.07826269 0.16702918 0.92173731
108.003472 226.40625 32.097537 13.6279246 0.05782879 0.12630388 0.94217121
108.446181 227.203125 32.4690381 13.8042065 0.04777935 0.1055627 0.95222065
108.667535 227.601563 32.6560281 13.8930235 0.04279573 0.09509653 0.95720427
LS 108.888889 228 32.8438474 13.9822934 0.03783922 0.08456626 0.96216078

Diagrama de Equilibrio X-Y

@1atm
1

0.9
 Diagrama de Equilibrio X-Y
@1atm
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130

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 DATOS DE TABLAS y DIAGRAMA DE COX
TebA 177
PT [psia] 14.696 TebB 228
1 Atm PcA 714.2
PcB 587.8

ALPHA 2.45
yB kA kB Alpha
0 1 #DIV/0!
xA yA
0.01975886 1.03107404 0.40078067 2.57266414
0.03795873 1.05938381 0.4131068 2.56443085 0 0.00
0.05674028 1.08830344 0.42573815 2.55627418 0.05 0.11
0.07611583 1.11784201 0.43868026 2.54819309 0.1 0.21
0.09609789 1.14800868 0.45193872 2.54018658 0.15 0.30
0.11669912 1.17881266 0.46551918 2.53225367 0.2 0.38
0.13793238 1.21026321 0.47942734 2.52439339 0.25 0.45
0.15981069 1.24236966 0.49366896 2.51660478 0.3 0.51
0.18234726 1.2751414 0.50824985 2.50888691 0.35 0.57
0.20555547 1.30858785 0.52317589 2.50123885 0.4 0.62
0.22944886 1.34271852 0.53845299 2.4936597 0.45 0.67
0.25404119 1.37754295 0.55408714 2.48614857 0.5 0.71
0.27934637 1.41307075 0.57008437 2.47870459 0.55 0.75
0.30537849 1.44931157 0.58645078 2.47132688 0.6 0.79
0.33215183 1.48627513 0.6031925 2.46401461 0.65 0.82
0.35968086 1.52397118 0.62031573 2.45676693 0.7 0.85
0.38798021 1.56240954 0.63782673 2.44958304 0.75 0.88
0.41706472 1.60160007 0.65573179 2.44246213 0.8 0.91
0.4469494 1.64155268 0.67403728 2.43540339 0.85 0.93
0.47764943 1.68227734 0.69274961 2.42840606 0.9 0.96
0.50918021 1.72378406 0.71187523 2.42146936 0.95 0.98
0.54155729 1.76608291 0.73142067 2.41459254 1 1.00
0.57479644 1.80918397 0.7513925 2.40777486
0.60891358 1.85309742 0.77179733 2.40101558
0.64392486 1.89783344 0.79264183 2.39431399
0.67984657 1.94340227 0.81393274 2.38766938
0.71669524 1.98981421 0.83567681 2.38108104
0.75448755 2.03707959 0.85788088 2.37454831
0.79324039 2.08520876 0.88055181 2.36807049
0.83297082 2.13421216 0.90369654 2.36164693
0.87369612 2.18410023 0.92732204 2.35527697
0.8944373 2.2093793 0.93931726 2.35211188
0.90490347 2.22210316 0.94536088 2.35053428
0.91543374 2.23488347 0.95143532 2.34895996
PROMEDIO= 2.44973
7 0.8 0.9 1

7 0.8 0.9 1
 TA= 177
DIAGRAMA DE COX PT= 14.7 TB= 228

T (°F) PvA PvB KA (Pva/Pt) KB (pvb/Pt) αAB (Ka/kb) Xa (Pt-Pvb)/(Pva-Pvb) Y*a (Xa*(Pva-pvb)
177 14.7 5.5 1 0.3741 2.6727 1 1
180 16 5.8 1.0884 0.3946 2.7586 0.87 0.95
185 17.5 6 1.1905 0.4082 2.9167 0.76 0.90
190 18.5 7 1.2585 0.4762 2.6429 0.67 0.84
195 19.5 7.5 1.3265 0.5102 2.6000 0.60 0.80
200 22 8.5 1.4966 0.5782 2.5882 0.46 0.69
210 25 10 1.7007 0.6803 2.5000 0.31 0.53
220 28 12.5 1.9048 0.8503 2.2400 0.14 0.27
225 30 14 2.0408 0.9524 2.1429 0.04 0.09
228 33 14.7 2.2449 1 2.2449 0 0
PROMEDIO 2.5307
XA YA* (con alpha prom)
0 0
0.05 0.1175
0.1 0.2195
0.15 0.3087
0.2 0.3875
0.25 0.4576
0.3 0.5203
0.35 0.5768
0.4 0.6279
0.45 0.6743
0.5 0.7168
0.55 0.7557
0.6 0.7915
0.65 0.8246
0.7 0.8552
0.75 0.8836
0.8 0.9101
 0.85 0.9348
0.9 0.9579
0.95 0.9796
1 1

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230

220

210

200

190

180

170
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1