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ALUMNO:
ECUACION DE MARGULES
1 2
2,3-dimetilbutano metanol
A 6.80983 7.87863
B 1127.187 1473.11
C 228.9 230
P 101.33
A12 1.1276
A21 1.5408
EXPERIMENTALES CALCULADOS
T(K) X1 Y1 T(K) X1
322.97 0.0627 0.481 293.981299 0
320.18 0.1029 0.5441 279.480943 0.05
319.47 0.1217 0.5547 273.279038 0.1
319.25 0.128 0.5585 270.179316 0.15
318.85 0.1495 0.5731 268.61918 0.2
318.72 0.1557 0.5712 267.97627 0.25
318.17 0.223 0.5864 267.893733 0.3
318.09 0.267 0.5928 268.149088 0.35
318.02 0.3059 0.6034 268.618437 0.4
318.01 0.3631 0.6035 269.17289 0.45
317.92 0.4114 0.6061 269.739546 0.5
317.9 0.4844 0.6097 270.232309 0.55
317.88 0.5808 0.6095 270.588336 0.6
317.93 0.6524 0.6155 270.817659 0.65
317.98 0.7377 0.6155 270.858062 0.7
317.99 0.7951 0.6152 270.708493 0.75
318 0.8403 0.6224 270.465692 0.8
318.03 0.8744 0.6279 270.285141 0.85
318.36 0.9071 0.6309 270.524883 0.9
321.32 0.9616 0.7129 272.08944 0.95
278.87467 1
0
1
Y1
0
1
0.58368823
0.72911573 0.9
0.78581771 0.8
0.81051337 0.7
0.82087658
0.6
0.82246425 X.Y CAL
0.8173764 0.5 X.Y EXP
0.80773325 0.4 LINEA
0.79334063
0.3
0.77520801
0.2
0.75316545
0.72760558 0.1
0.70126392 0
0.67385631 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.64700932
0.62507651
0.61363354
0.62453093
0.69073378
0.99972026
0
1
X.Y CAL
X.Y EXP
LINEA
1
EXPERIMENTALES CALCULADOS
T(K) X1 Y1 T(K) X1
322.97 0.0627 0.481 293.981299 0
320.18 0.1029 0.5441 279.480943 0.05
319.47 0.1217 0.5547 273.279038 0.1
319.25 0.128 0.5585 270.179316 0.15
318.85 0.1495 0.5731 268.61918 0.2
318.72 0.1557 0.5712 267.97627 0.25
318.17 0.223 0.5864 267.893733 0.3
318.09 0.267 0.5928 268.149088 0.35
318.02 0.3059 0.6034 268.618437 0.4
318.01 0.3631 0.6035 269.17289 0.45
317.92 0.4114 0.6061 269.739546 0.5
317.9 0.4844 0.6097 270.232309 0.55
317.88 0.5808 0.6095 270.588336 0.6
317.93 0.6524 0.6155 270.817659 0.65
317.98 0.7377 0.6155 270.858062 0.7
317.99 0.7951 0.6152 270.708493 0.75
318 0.8403 0.6224 270.465692 0.8
318.03 0.8744 0.6279 270.285141 0.85
318.36 0.9071 0.6309 270.524883 0.9
321.32 0.9616 0.7129 272.08944 0.95
278.87467 1
Y1 Chart Title
0
300 324
0.58368823
0.72911573 295 323
0.78581771 290
322
0.81051337
0.82087658 285
321
0.82246425 280 C
0.8173764 320
Axis Title
C
275
0.80773325 E
319
0.79334063 E
270
0.77520801 318
265
0.75316545
317
0.72760558 260
0.70126392 316
255
0.67385631
0.64700932 250 315
0 0.2 0.4 0.6 0.8 1 1.2
0.62507651
Axis Title
0.61363354
0.62453093
0.69073378
0.99972026
324
323
322
321
CALX
320
CALY
EXPX
319
EXPY
318
317
316
315
1 1.2
ECUACION DE VAN LAAR
1 2
2,3-dimetilbutano metanol
A 6.80983 7.87863
B 1127.187 1473.11
C 228.9 230
P 101.33
A12 1.1276
A21 1.5408
T(°C) X1 Y1 T(°C) X1 Y1
49.82 0.0627 0.481 4.62805865 0.0627 0.63007365
47.03 0.1029 0.5441 0.42057234 0.1029 0.72592106
46.32 0.1217 0.5547 -0.88157692 0.1217 0.75076717
46.1 0.128 0.5585 -1.2432162 0.128 0.75769369
45.7 0.1495 0.5731 -2.26636178 0.1495 0.77683798
45.57 0.1557 0.5712 -2.50889946 0.1557 0.78130473
45.02 0.223 0.5864 -4.07414677 0.223 0.81080644
44.94 0.267 0.5928 -4.38073073 0.267 0.81857488
44.87 0.3059 0.6034 -4.36003416 0.3059 0.82105097
44.86 0.3631 0.6035 -4.00096487 0.3631 0.81952209
44.77 0.4114 0.6061 -3.50391595 0.4114 0.81469086
44.75 0.4844 0.6097 -2.58455987 0.4844 0.80287724
44.73 0.5808 0.6095 -1.31134116 0.5808 0.7823307
44.78 0.6524 0.6155 -0.50221954 0.6524 0.76483105
44.83 0.7377 0.6155 0.23863913 0.7377 0.74696539
44.84 0.7951 0.6152 0.62371448 0.7951 0.74132559
44.85 0.8403 0.6224 0.93044994 0.8403 0.7447686
44.88 0.8744 0.6279 1.23385793 0.8744 0.75543098
45.21 0.9071 0.6309 1.67336425 0.9071 0.77645223
48.17 0.9616 0.7129 3.18728411 0.9616 0.85776432
0.8 1
0.9
0.7
0.8
0.6
0.7
0.5
0.6
0 0
0 0.2 0.4 0.6 0.8 1 1.2
EXPERIMENTALES CALCULADOS
T(°C) X1 Y1 T(°C) X1 Y1
49.82 0.0627 0.481 4.62805865 0.0627 0.63007365
47.03 0.1029 0.5441 0.42057234 0.1029 0.72592106
46.32 0.1217 0.5547 -0.88157692 0.1217 0.75076717
46.1 0.128 0.5585 -1.2432162 0.128 0.75769369
45.7 0.1495 0.5731 -2.26636178 0.1495 0.77683798
45.57 0.1557 0.5712 -2.50889946 0.1557 0.78130473
45.02 0.223 0.5864 -4.07414677 0.223 0.81080644
44.94 0.267 0.5928 -4.38073073 0.267 0.81857488
44.87 0.3059 0.6034 -4.36003416 0.3059 0.82105097
44.86 0.3631 0.6035 -4.00096487 0.3631 0.81952209
44.77 0.4114 0.6061 -3.50391595 0.4114 0.81469086
44.75 0.4844 0.6097 -2.58455987 0.4844 0.80287724
44.73 0.5808 0.6095 -1.31134116 0.5808 0.7823307
44.78 0.6524 0.6155 -0.50221954 0.6524 0.76483105
44.83 0.7377 0.6155 0.23863913 0.7377 0.74696539
44.84 0.7951 0.6152 0.62371448 0.7951 0.74132559
44.85 0.8403 0.6224 0.93044994 0.8403 0.7447686
44.88 0.8744 0.6279 1.23385793 0.8744 0.75543098
45.21 0.9071 0.6309 1.67336425 0.9071 0.77645223
48.17 0.9616 0.7129 3.18728411 0.9616 0.85776432
6 51
50
4
49
2 48
CALX-T
47
CALY-T
0
0 0.2 0.4 0.6 0.8 1 1.2 46 EXPX-T
EXPY-T
-2 45
44
-4
43
-6 42
ECUACION DE WILSON
1 2
2,3-dimetilbutano metanol
A 6.80983 7.87863
B 1127.187 1473.11
C 228.9 230
P 101.33
A12 1.1276
A21 1.5408
λ12-λ11 449.08
λ21-λ22 2771.85
V1 126.8
V2 39.556
R 1.9872
T(°C) X1 Y1 T(°C) X1 Y1
49.82 0.0627 0.481 5.22046381 0.0627 0.61077652
47.03 0.1029 0.5441 2.85012839 0.1029 0.66982744
46.32 0.1217 0.5547 2.22374373 0.1217 0.68461591
46.1 0.128 0.5585 2.05368441 0.128 0.68859303
45.7 0.1495 0.5731 1.58348614 0.1495 0.69957384
45.57 0.1557 0.5712 1.47320334 0.1557 0.70214649
45.02 0.223 0.5864 0.71281329 0.223 0.72021862
44.94 0.267 0.5928 0.45955844 0.267 0.72659848
44.87 0.3059 0.6034 0.31481208 0.3059 0.73046561
44.86 0.3631 0.6035 0.18045354 0.3631 0.7343732
44.77 0.4114 0.6061 0.1105247 0.4114 0.7366411
44.75 0.4844 0.6097 0.04811438 0.4844 0.73902122
44.73 0.5808 0.6095 0.00869563 0.5808 0.74104746
44.78 0.6524 0.6155 -0.00382256 0.6524 0.74210619
44.83 0.7377 0.6155 -0.00856093 0.7377 0.74313815
44.84 0.7951 0.6152 -0.0069272 0.7951 0.74384393
44.85 0.8403 0.6224 -0.00151221 0.8403 0.74456659
44.88 0.8744 0.6279 0.00825458 0.8744 0.74540912
45.21 0.9071 0.6309 0.03112509 0.9071 0.74690192
48.17 0.9616 0.7129 0.25169926 0.9616 0.75759733
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.2 0.4 0.6 0.8 1 1.2
EXPXY CALXY
EXPERIMENTALES CALCULADOS
T(°C) X1 Y1 T(°C) X1 Y1
49.82 0.0627 0.481 5.22046381 0.0627 0.61077652
47.03 0.1029 0.5441 2.85012839 0.1029 0.66982744
46.32 0.1217 0.5547 2.22374373 0.1217 0.68461591
46.1 0.128 0.5585 2.05368441 0.128 0.68859303
45.7 0.1495 0.5731 1.58348614 0.1495 0.69957384
45.57 0.1557 0.5712 1.47320334 0.1557 0.70214649
45.02 0.223 0.5864 0.71281329 0.223 0.72021862
44.94 0.267 0.5928 0.45955844 0.267 0.72659848
44.87 0.3059 0.6034 0.31481208 0.3059 0.73046561
44.86 0.3631 0.6035 0.18045354 0.3631 0.7343732
44.77 0.4114 0.6061 0.1105247 0.4114 0.7366411
44.75 0.4844 0.6097 0.04811438 0.4844 0.73902122
44.73 0.5808 0.6095 0.00869563 0.5808 0.74104746
44.78 0.6524 0.6155 -0.00382256 0.6524 0.74210619
44.83 0.7377 0.6155 -0.00856093 0.7377 0.74313815
44.84 0.7951 0.6152 -0.0069272 0.7951 0.74384393
44.85 0.8403 0.6224 -0.00151221 0.8403 0.74456659
44.88 0.8744 0.6279 0.00825458 0.8744 0.74540912
45.21 0.9071 0.6309 0.03112509 0.9071 0.74690192
48.17 0.9616 0.7129 0.25169926 0.9616 0.75759733
6 51
50
5
49
4
48
3 CALX-T
47
CALY-T
EXPX-T
2 46
EXPY-T
45
1
44
0
0 0.2 0.4 0.6 0.8 1 1.243
-1 42