Modelo de Wilson Ecuación de Antoine

Presión constante a
ΔT= 0.2449123 °C Cloroformo 13.7324
Λ_12= 1.288 Cloroformo Acetona 14.3145
Λ_21= 1.396 Acetona
P= 101.32 kPa
T Psat1 Psat2 𝑥_1 𝑥_2 ln⁡〖𝛾 _1 〗 ln⁡〖𝛾 _2 〗
56.19728 86.124753 101.32 0 1 -0.64909063 0
56.44219 86.839248 102.1692512 0.055398 0.944602 -0.57453354 -0.0021178
56.6871 87.558383 103.0241414 0.110188 0.889812 -0.50609641 -0.0082896
56.93201 88.282179 103.8846971 0.164377 0.835623 -0.44337165 -0.0182655
57.17693 89.010656 104.7509446 0.217972 0.782028 -0.38599293 -0.0318225
57.42184 89.743836 105.6229104 0.27098 0.72902 -0.33363026 -0.0487615
57.66675 90.481738 106.5006212 0.323407 0.676593 -0.28598581 -0.0689044
57.91166 91.224385 107.3841034 0.37526 0.62474 -0.2427902 -0.0920914
58.15657 91.971796 108.2733838 0.426546 0.573454 -0.20379938 -0.1181794
58.40149 92.723992 109.1684891 0.477271 0.522729 -0.16879192 -0.1470399
58.6464 93.480995 110.0694461 0.527442 0.472558 -0.13756657 -0.1785577
58.89131 94.242825 110.9762816 0.577064 0.422936 -0.10994023 -0.2126292
59.13622 95.009503 111.8890225 0.626145 0.373855 -0.08574607 -0.2491612
59.38114 95.781051 112.8076958 0.674689 0.325311 -0.06483199 -0.2880705
59.62605 96.557489 113.7323285 0.722704 0.277296 -0.04705914 -0.3292821
59.87096 97.338838 114.6629476 0.770195 0.229805 -0.03230072 -0.372729
60.11587 98.125121 115.5995803 0.817169 0.182831 -0.02044086 -0.4183513
60.36078 98.916357 116.5422537 0.86363 0.13637 -0.01137362 -0.4660955
60.6057 99.712568 117.4909952 0.909585 0.090415 -0.00500217 -0.5159141
60.85061 100.51378 118.4458319 0.95504 0.04496 -0.00123794 -0.567765
61.09552 101.32 119.4067913 1 0 0 -0.621611
 b c Tsat(°C)
2548.74 218.552 61.09552161
2756.22 228.06 56.19727627

𝛾_1 𝛾_2 𝑥_1 𝑥_2 𝑦_1 𝑦_2

P
0.522521 1 101.32 0 1 0 1
0.562967 0.997884 99.01338808 0.055398 0.944602 0.027353 0.972647 62
0.602844 0.991745 96.73150317 0.110188 0.889812 0.060127 0.939873
61.5
0.641869 0.9819 94.5517481 0.164377 0.835623 0.098512 0.901488
0.679775 0.968679 92.54125276 0.217972 0.782028 0.142519 0.857481 61
0.716319 0.952408 90.7565905 0.27098 0.72902 0.191942 0.808058 60.5
0.751273 0.933416 89.24376509 0.323407 0.676593 0.246338 0.753662 60
0.784436 0.912022 88.03842059 0.37526 0.62474 0.305021 0.694979

Temperatura (°C)
59.5
0.815626 0.888537 87.16623093 0.426546 0.573454 0.367083 0.632917
0.844685 0.863259 86.64343097 0.477271 0.522729 0.431436 0.568564 59

0.871476 0.836476 86.47745547 0.527442 0.472558 0.496879 0.503121 58.5

0.895888 0.808456 86.66765668 0.577064 0.422936 0.562172 0.437828 58
0.917827 0.779454 87.2060755 0.626145 0.373855 0.626118 0.373882
57.5
0.937225 0.749709 88.07824488 0.674689 0.325311 0.687636 0.312364
57
0.954031 0.71944 89.2640072 0.722704 0.277296 0.745818 0.254182
0.968215 0.688852 90.73833083 0.770195 0.229805 0.79996 0.20004 56.5
0.979767 0.658131 92.47211309 0.817169 0.182831 0.849579 0.150421 56
0 0.1
0.988691 0.627447 94.43295977 0.86363 0.13637 0.894402 0.105598
0.99501 0.596955 96.58593275 0.909585 0.090415 0.934344 0.065656
0.998763 0.566791 98.89425961 0.95504 0.04496 0.969479 0.030521
1 0.537079 101.32 1 0 1 0
 Gráfico T-xy
62

61.5

61

60.5

60
Temperatura (°C)

59.5

59

58.5

58

57.5

57

56.5

56
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Fracción molar acetona (x,y)