UN SISTEMA BINARIO EN ELV A UNA T PRESENTA Z1=0.

65 SE SABE QUE:
a) construir un diagrama PT VS X1Y1
b) DETERMINAR EL LIMITE DE PRESIONES EN LA CUAL EL SISTEMA PUEDE EXISTIR EN 2 FASES A T=CTE. CON X1
°CALCULO ANALITICO
°CALCULO GRAFICO

〖𝑝 1 〗^𝑠𝑎𝑡=32.27𝑘𝑝𝑎 ln⁡〖𝑦 2=𝑜.67𝑥_1^2 〗 〖𝑝 2 〗^𝑠𝑎𝑡=73.14𝑘𝑝𝑎

𝑃_𝑇=𝑋_1 𝛾_1 〖𝑃𝐼〗 _𝑆𝐴𝑇

PARA UN SISTEMA BINARIO

𝑃_𝑇=𝑋_1 𝛾_1 〖𝑃𝐼〗 _𝑆𝐴𝑇+𝑋_2 𝛾_2 〖𝑃 2 〗 _𝑆𝐴𝑇 P1SAT

X1 X2 Y1 Y2 P1 P2
0 1 1.95423732 1 0 73.14
0.05 0.95 1.83065715 1.0016764 2.95376531 69.5994816
0.1 0.9 1.72064634 1.0067225 5.55252574 66.268515
0.15 0.85 1.62267334 1.0151892 7.85455031 63.1132974
0.2 0.8 1.53541392 1.02716235 9.90956145 60.1013234
0.25 0.75 1.45772208 1.04276413 11.7601729 57.2008261
0.3 0.7 1.38860549 1.06215515 13.4430898 54.3802191
0.35 0.65 1.3272047 1.08553722 14.9901135 51.6075251
0.4 0.6 1.27277556 1.11315686 16.428987 48.8497758
0.45 0.55 1.22467438 1.14530961 17.7841091 46.0723696
0.5 0.5 1.18234529 1.18234529 19.0771413 43.2383673
0.55 0.45 1.14530961 1.22467438 20.3275276 40.307708
0.6 0.4 1.11315686 1.27277556 21.5529432 37.2363219
0.65 0.35 1.08553722 1.3272047 22.769686 33.9751131
0.7 0.3 1.06215515 1.38860549 23.9930226 30.4687817
0.75 0.25 1.04276413 1.45772208 25.2374987 26.6544483
0.8 0.2 1.02716235 1.53541392 26.5172232 22.4600348
0.85 0.15 1.0151892 1.62267334 27.8461322 17.8023492
0.9 0.1 1.0067225 1.72064634 29.2382414 12.5848073
0.95 0.05 1.0016764 1.83065715 30.7078927 6.69471319
1 0 1 1.95423732 32.27 0
 EXISTIR EN 2 FASES A T=CTE. CON X1=0.75

=73.14𝑘𝑝𝑎 ln⁡〖𝑦 1=𝑜.67𝑥_2^2 〗

p. burbuja= TRASCISION D
P. ROCIO = TRASCISION D

32.27 P2SAT 73.14

PT y1 y2 P. burbuja p.Rocio
73.14 0 1 73.14 73.14
72.5532469 0.04071169 0.95928831 72.5532469 68.7842336
71.8210407 0.07731057 0.92268943 71.8210407 64.9181121
70.9678477 0.11067759 0.88932241 70.9678477 61.4634653
70.0108849 0.14154315 0.85845685 70.0108849 58.3579221
68.960999 0.17053368 0.82946632 68.960999 55.5511103
67.8233089 0.19820752 0.80179248 67.8233089 53.0019043
66.5976385 0.22508476 0.77491524 66.5976385 50.6763959
65.2787628 0.2516743 0.7483257 65.2787628 48.5463779
63.8564787 0.27850125 0.72149875 63.8564787 46.5881942
62.3155085 0.30613794 0.69386206 62.3155085 44.7818575
60.6352356 0.33524282 0.66475718 60.6352356 43.1103647
58.7892651 0.36661358 0.63338642 58.7892651 41.5591597
56.7447991 0.40126472 0.59873528 56.7447991 40.1157091
54.4618043 0.4405477 0.5594523 54.4618043 38.7691618
51.891947 0.48634712 0.51365288 51.891947 37.5100767
48.9772581 0.5414191 0.4585809 48.9772581 36.3302004
45.6484814 0.61001224 0.38998776 45.6484814 35.2222864
41.8230488 0.69909398 0.30090602 41.8230488 34.1799458
37.4026059 0.82100944 0.17899056 37.4026059 33.1975245
32.27 1 0 32.27 32.27
p. burbuja= TRASCISION DE VAPOR A LIQUIDO ( LINEA AZUL)
P. ROCIO = TRASCISION DE UN LIQUIDO-VAPOR ( LINEA ROJA)

intervalo
 Margules Ley de Raoult modificado

ln⁡(𝛾1)=[𝐴_12+2(𝐴_21−𝐴_12 ) 𝑥_1 ] 𝑥_2^2 𝑃_𝑇=𝑋_1 𝛾_1 〖𝑃𝐼〗 _𝑆𝐴𝑇+𝑋_2 𝛾_2 〖𝑃 2 〗 _𝑆𝐴𝑇

ln⁡(𝛾2)=[𝐴_21+2(𝐴_12−𝐴_21 ) 𝑥_2 ] 𝑥_1^2

𝛾1 1.23518308 X1 0.4
𝛾2 1.10540435 X2 0.6

ACETONA(1)/METANOL(2)
A12 0.6184
A21 0.5788
T°C 22

a b c Psat
acetona 7.117714 1210.595 229.664 202.932577268
metanol 8.08097 1582.271 239.726 108.503885625

Pburbuja 172.227955 TORR

x x2 Y1 Y2 P1 P2
0 1 1.85595614 1 0 108.503886
0.1 0.9 1.63965983 1.00652197606 33.2740395 98.2903908
0.2 0.8 1.47055282 1.02601913841 59.6846149 89.0616506
0.3 0.7 1.33826447 1.05874220023 81.4732372 80.4143498
0.4 0.6 1.23518308 1.10540435482 100.263554 71.9644006
0.5 0.5 1.15569281 1.16719099132 117.26386 63.3223789
0.6 0.4 1.09564234 1.24579365411 133.404914 54.0693809
0.7 0.3 1.0519719 1.3434680935 149.435558 43.7314525
0.8 0.2 1.02244989 1.463117744 165.990713 31.7507921
0.9 0.1 1.00548619 1.6084053141 183.641314 17.4518226
1 0 1 1.78389647007 202.932577 0
y de Raoult modificado

𝑃𝐼〗 _𝑆𝐴𝑇+𝑋_2 𝛾_2 〖𝑃 2 〗 _𝑆𝐴𝑇

PT Y1 Y2
108.503886 0 1
131.56443 0.2529106 0.7470894
148.746265 0.40125118 0.59874882
161.887587 0.50327044 0.49672956
172.227955 0.5821561 0.4178439
180.586239 0.64935103 0.35064897
187.474295 0.71159043 0.28840957 Chart Title
193.16701 0.77360807 0.22639193
200
197.741505 0.83943284 0.16056716
201.093137 0.91321523 0.08678477
180
202.932577 1 0
160

140

120

100
0 0.2 0.4 0.6 0.8 1
140

120

100
0 0.2 0.4 0.6 0.8 1
Chart Title

0.6 0.8 1 1.2

0.6 0.8 1 1.2
Wilson
T 308.15 K v_l w 18.07
R 1.987 cal/gmol*k v_lf 37.91

x_w 0.45 A_12 3.48137605

x_f 0.55 A_21 0.06929008

𝜆_12−𝜆_11 -310.106
P_sat w 42.0710872 Torr 𝜆_21−𝜆_22 1180.804
P_sat f 66.832123 Torr
cm^3/g*mol
cm^3/g*mol

cal/mol
cal/mol