Tiempo Ca(M) t a

0 0.8 0 0.9216 -0.19942702

0.5 0.67 13.6 0.512 -0.89257421
1 0.6 27.2 0.3072 -1.58572139
1.5 0.563 40.8 0.2048 -2.27886857
2 0.543 equilibrio 0.1024
3 0.527
4 0.522 Chart Title
5 0 0.52
0 5 10 15 20 25 30 35 40 45
6 0.52
f(x) = − 0.0509667044529372 x − 0.199427024696894
-0.5 R² = 1

-1

-1.5

-2

-2.5
Datos
CAO 1.1
k1 0.05
k2 0.01
t 13 minutos

CAO 0.603538844

exp 0.458406011
-0.78
Datos
CAO 1.2
k1 0.005
k2 0.015
t 30 minutos

CA 0.65857396

exp 0.54881164
-0.6
 Datos: Perfil de con
CA0= 1.3 M
k1=
𝐶_𝐴=((𝑘_1 𝐶_𝐴0−𝑘_2 𝐶_𝐵0 ) 𝑒^(−(𝑘_1+
0.05 min-1
k2= 0.01 min-1
CB0= 0.8 M

Avance de reacción:
t (min) CA CB
0 1.3 0.8 𝐶_𝐵=𝐶_𝐵0+𝐶_𝐴0−𝐶_𝐴
2 1.19257441 0.90742559
4 1.09729647 1.00270353
6 1.01279251 1.08720749
1.- a)
8 0.93784422 1.16215578 CA Y C
10 0.87137105 1.22862895 1.2
12 0.81241464 1.28758536
14 0.760125 1.339875 1

16 0.71374824 1.38625176

Concentración (M)
0.8
18 0.67261575 1.42738425
20 0.6361345 1.4638655 0.6
22 0.60377854 1.49622146
0.4
24 0.57508137 1.52491863
26 0.54962927 1.55037073 0.2
28 0.52705528 1.57294472
0
30 0.50703394 1.59296606 0 50 10
32 0.48927661 1.61072339 Tiemp
34 0.47352728 1.62647272
36 0.45955886 1.64044114
CA
38 0.44717 1.65283
40 0.43618206 1.66381794
42 0.42643663 1.67356337 1. - b)
44 0.41779321 1.68220679
𝐶_𝐴𝑒𝑞=((𝑘_1 𝐶_𝐴0−𝑘_2 𝐶_𝐵0 ) 𝑒^(
46 0.41012718 1.68987282
48 0.40332802 1.69667198
50 0.39729771 1.70270229 CAeq (t=200)
52 0.39194931 1.70805069 CAeq=
54 0.3872057 1.7127943
56 0.3829985 1.7170015
58 0.37926704 1.72073296
𝐶_𝐵=𝐶_𝐵0+𝐶_𝐴0
60 0.37595754 1.72404246
62 0.37302227 1.72697773 CBeq=
64 0.37041892 1.72958108
66 0.36810996 1.73189004
68 0.36606209 1.73393791 1.- c) 𝑘_𝑐=𝐶_𝐵𝑒𝑞/𝐶_𝐴𝑒𝑞
70 0.3642458 1.7357542
72 0.36263489 1.73736511
74 0.36120614 1.73879386
76 0.35993896 1.74006104 kc=
78 0.35881506 1.74118494 kc=
80 0.35781826 1.74218174
82 0.35693417 1.74306583
84 0.35615006 1.74384994
86 0.35545461 1.74454539
88 0.35483781 1.74516219
90 0.35429075 1.74570925
92 0.35380556 1.74619444
94 0.35337522 1.74662478
96 0.35299356 1.74700644
98 0.35265505 1.74734495
100 0.35235481 1.74764519
102 0.35208853 1.74791147
104 0.35185236 1.74814764
106 0.3516429 1.7483571
108 0.35145712 1.74854288
110 0.35129235 1.74870765
112 0.35114621 1.74885379
114 0.3510166 1.7489834
116 0.35090164 1.74909836
118 0.35079968 1.74920032
120 0.35070926 1.74929074
122 0.35062905 1.74937095
124 0.35055792 1.74944208
126 0.35049483 1.74950517
128 0.35043888 1.74956112
130 0.35038925 1.74961075
132 0.35034523 1.74965477
134 0.35030619 1.74969381
136 0.35027157 1.74972843
138 0.35024086 1.74975914
140 0.35021362 1.74978638
142 0.35018947 1.74981053
144 0.35016804 1.74983196
146 0.35014904 1.74985096
148 0.35013219 1.74986781
150 0.35011724 1.74988276
152 0.35010398 1.74989602
154 0.35009222 1.74990778
156 0.3500818 1.7499182
158 0.35007255 1.74992745
160 0.35006434 1.74993566
162 0.35005707 1.74994293
164 0.35005061 1.74994939
166 0.35004489 1.74995511
168 0.35003981 1.74996019
170 0.35003531 1.74996469
172 0.35003132 1.74996868
174 0.35002778 1.74997222
176 0.35002464 1.74997536
178 0.35002185 1.74997815
180 0.35001938 1.74998062
182 0.35001719 1.74998281
184 0.35001524 1.74998476
186 0.35001352 1.74998648
188 0.35001199 1.74998801
190 0.35001064 1.74998936
192 0.35000943 1.74999057
194 0.35000837 1.74999163
196 0.35000742 1.74999258
198 0.35000658 1.74999342
200 0.35000584 1.74999416
 Perfil de concentración:

𝐶_𝐵0 ) 𝑒^(−(𝑘_1+𝑘_2 )𝑡)+𝑘_2 (𝐶_𝐴0+𝐶_𝐵0 ))/(𝑘_1+𝑘_2 )

Avance de reacción:

=𝐶_𝐵0+𝐶_𝐴0−𝐶_𝐴

CA Y CB

50 100 150 200

Tiempo (min)

CA CB

𝐴0−𝑘_2 𝐶_𝐵0 ) 𝑒^(−(𝑘_1+𝑘_2 )200)+𝑘_2 (𝐶_𝐴0+𝐶_𝐵0 ))/(𝑘_1+𝑘_2 )

0.35000584

𝐶_𝐵=𝐶_𝐵0+𝐶_𝐴0−𝐶_𝐴𝑒𝑞

1.74999416
=𝐶_𝐵𝑒𝑞/𝐶_𝐴𝑒𝑞
𝑘_𝑐=𝑘_1/𝑘_2

4.99989994
5
_1+𝑘_2 )