Relative Absolute Pressure Quantity Adsorbed (P/Po)/(V(1-P/Po))

Pressure (P/Po) (mmHg) (cm³/g STP) 300

0.00987066783 7.5017075538635 36.8836598278169 0.00027028416516
0.01997086751 15.177859306336 40.8975186424839 0.00049826569281

Cantidad Adsorbida (Cm3/g STP)

250
0.02990734954 22.729585647583 43.4462516925674 0.00070959802542
0.03984039457 30.278699874878 45.4355645639146 0.00091323862441 200
0.04972317846 37.789615631104 47.120976719948 0.00111043837533
0.05986463145 45.497119903565 48.6515771203559 0.00130882926924 150
0.06998677003 53.189945220947 50.0567260334165 0.00150336481929
100
0.07997122313 60.778129577637 51.3615347576853 0.00169236616611
0.09003753662 68.428649902344 52.6364769374953 0.00187980721995
50
0.10006286621 76.04793548584 53.8340113643955 0.00206539929537
0.11009338379 83.671081542969 55.0225003235366 0.00224841494299
0
0.12011875353 91.290252685547 56.1715297421459 0.00243035941472 0 0.
0.13017147466 98.930320739746 57.323784327535 0.00261064202935
0.14031194386 106.63707733154 58.4596505654499 0.00279188505026
0.15013120551 114.09971618652 59.554557185261 0.00296622498664
0.16020242791 121.75384521484 60.6829567870612 0.00314360336678
0.17029559487 129.42465209961 61.8135165005651 0.00332044711252
0.1803702505 137.08139038086 62.9210987758597 0.0034974450286
0.19043000874 144.72680664063 64.0616302550236 0.00367183366447
0.20025271366 152.19206237793 65.1675474442133 0.00384232642904
0.21021194458 159.76107788086 66.2931906534749 0.00401492934151
0.22037172819 167.48251342774 67.4660863062549 0.00418969858691
0.23028807389 175.01893615723 68.5868167614682 0.0043621699813
0.2403241007 182.64631652832 69.7806909990928 0.00453350095429
0.25032967015 190.25054931641 70.9651747511166 0.0047054019455
0.26033672534 197.85591125488 72.1849778295733 0.00487589735424
0.27031543129 205.4397277832 73.3747268538749 0.00504881176482
0.28040253489 213.10592651367 74.6306593006536 0.00522125654079
0.29037519756 220.68515014649 75.8331289827658 0.0053959977014
0.3005759189 228.43769836426 77.1522146953261 0.00557012838535
0.35050374081 266.38284301758 83.9736374447393 0.00642647818472
0.40090882151 304.6907043457 91.4273878930825 0.00731941506751
0.45092110885 342.7 99.0642378098654 0.00828989282504
0.5010524549 380.79986572266 107.072311923394 0.00937888312614
0.5508294758 418.63040161133 114.564284348272 0.0107042606721
0.60039809378 456.30255126953 122.68546431073 0.01224668768411
0.6503786589 494.28778076172 132.608537452688 0.0140280357037
0.70023145174 532.17590332031 145.166136831267 0.01609126657149
0.75000976563 570.00909423828 162.166965978144 0.018500415531657
0.79995454487 607.96545410156 183.924106083373 0.02174192369412
0.85013034218 646.09906005859 206.390167848359 0.02748418081087
0.90018688001 684.14202880859 223.626179156976 0.04032945974687
0.95009765625 722.07586669922 240.806327576811 0.079064114032367
0.99000488281 752.40472412109 255.507852822084 0.387654825025964
0.99510321366 756.27844238281 263.769920070106 0.77042737563466
0.98907591167 751.69769287109 264.071345657426 0.34286499156829
0.950078125 722.06115722656 255.615828405718 0.07445274036133
0.90021571109 684.16394042969 244.662186971012 0.03687377217021
0.87511460154 665.08709716797 239.187608869629 0.02929642242757
0.85009521484 646.07330322266 233.485844019965 0.024287986919258
0.82519089548 627.14508056641 225.556073955696 0.02092839159812
0.79993342349 607.94940185547 218.084112565628 0.01833391756136
0.77502256695 589.01715087891 209.158035980356 0.016470274449866
0.74997253418 569.97912597656 197.820584698075 0.01516303573628
0.72501461631 551.01110839844 184.369554118382 0.014300392127183
0.70009033203 532.06903076172 171.019643767818 0.01364952746626
0.67511845639 513.09 159.080376364422 0.0130628617679
0.6502085234 494.1584777832 148.729196084188 0.01249819237025
0.62538737247 475.29440307617 140.224836306735 0.01190533865311
0.60027481882 456.20886230469 133.049275244121 0.01128693708235
0.57539933857 437.30349731445 127.852886528468 0.01059932367258
0.55065560592 418.49826049805 122.662235609528 0.00999056066371
0.52567074424 399.509765625 118.252502573413 0.00937181171895
0.50076249775 380.57949829102 114.306976042345 0.00877509565961
0.47584770604 361.6442565918 110.256421580072 0.00823391910718
0.45065211246 342.49560546875 105.690590471814 0.00776171385926
0.42572816548 323.55340576172 100.040863313123 0.00741032807668
0.40055598209 304.42254638672 93.8169664629695 0.00712251225943
0.37545097753 285.34274291992 89.3152111681997 0.00673071617089
0.35017125983 266.1301574707 85.4235224211912 0.00630818044873
0.32517507453 247.13305664063 81.8198635687847 0.00588935023252
0.30018398887 228.13983154297 78.4098722313126 0.0054705740818
0.2749438838 208.95735168457 75.0375703428374 0.00505351639779
0.24990236383 189.92579650879 71.9285770705773 0.00463181386421
0.22484562522 170.8826751709 68.943400201111 0.00420730058899
0.19979430751 151.84367370606 66.0201465338174 0.0037818560122
0.1747876619 132.83862304688 63.1746868894083 0.003352756106303
0.14970423046 113.77521514893 60.3462906273808 0.00291751753413
0.12460067147 94.696510314942 57.5064112715395 0.00247512939292
0.09956259477 75.667572021484 54.5668555112321 0.0020263466885

Log(P/P0)
 Isoterma de adsorción a 77K
300

Adsorción
Cantidad Adsorbida (Cm3/g STP)

250
Desorción

200

150

100

50

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
P/P0

Modelo BET
0.003

0.0025 f(x) = 0.019310285112722 x + 0.000128923378975516

R² = 0.999062124256007
(P/Po)/(V(1-P/Po))

0.002

0.0015

0.001
Modelo BET
0.0005 Linear (Modelo
BET)

0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14
P/P0

A) Intercepto 0.0001
Pendiente 0.0193
C 194.0
Vm 51.546

Área de Molécula de N2 16.2 Å2

Número de Avogadro 6.02E+023 moléculas/mol
V molar 22400 cm3/mol g
 Superficie BET 224.42 m2/g sólido

B)

Q (Licuefacción) 5610 J/mol

R 8.3144 J/mol/K
T 77 K
Q (ads 1ra capa) 8982.52915 J/mol

C)
Log(P/Po) Espesor (Å) Radio (Å) Ln Radio (Å) V poro V acum
-0.0048 43.603 2039.253 7.620 0.4106309 0.4106309
-0.0222 26.100 454.145 6.118 0.3974826 0.8081136
-0.0457 20.537 229.065 5.434 0.3804497 1.1885633
-0.0579 18.969 183.291 5.211 0.3719367 1.5605000
-0.0705 17.765 152.738 5.029 0.3630705 1.9235705
-0.0834 16.797 130.883 4.874 0.3507397 2.2743102
-0.0969 15.978 114.177 4.738 0.3391208 2.6134310
-0.1107 15.287 101.297 4.618 0.3252407 2.9386717
-0.1250 14.682 90.869 4.509 0.3076110 3.2462827
-0.1397 14.147 82.316 4.411 0.2866947 3.5329774
-0.1548 13.669 75.149 4.319 0.2659355 3.7989129
-0.1706 13.234 69.030 4.235 0.2473700 4.0462829
-0.1869 12.837 63.760 4.155 0.2312739 4.2775568
-0.2039 12.472 59.172 4.080 0.2180496 4.4956064
-0.2216 12.128 55.079 4.009 0.2068916 4.7024981
-0.2400 11.811 51.472 3.941 0.1988112 4.9013093
-0.2591 11.513 48.253 3.876 0.1907398 5.0920491
-0.2793 11.229 45.316 3.814 0.1838826 5.2759317
-0.3004 10.960 42.654 3.753 0.1777473 5.4536791
-0.3225 10.703 40.219 3.694 0.1714487 5.6251278
-0.3462 10.454 37.956 3.636 0.1643489 5.7894767
-0.3709 10.216 35.886 3.580 0.1555635 5.9450402
-0.3973 9.984 33.944 3.525 0.1458854 6.0909256
-0.4254 9.759 32.136 3.470 0.1388852 6.2298107
-0.4557 9.538 30.428 3.415 0.1328336 6.3626443
-0.4879 9.324 28.837 3.362 0.1272299 6.4898742
-0.5226 9.112 27.329 3.308 0.1219274 6.6118016
-0.5608 8.901 25.878 3.253 0.1166834 6.7284850
-0.6022 8.692 24.500 3.199 0.1118489 6.8403339
-0.6481 8.482 23.170 3.143 0.1072070 6.9475409
-0.6994 8.269 21.880 3.086 0.1026613 7.0502022
-0.7575 8.052 20.620 3.026 0.0982366 7.1484389
-0.8248 7.827 19.369 2.964 0.0938385 7.2422773
-0.9045 7.590 18.115 2.897 0.0894225 7.3316998
-1.0019 7.335 16.837 2.824 0.0848515 7.4165513

Distribución de tamaños de poros

3.5

d(V acum)/dLn(Radio de poros)

2.5

1.5

0.5

0
0 5 10 15 20 25
Diámetro de Poros (nm)
 d poro (nm) d(V acum)/dLN(Radio de poros)
407.850559077885
22.7072407882924
11.4532370543942
9.16455406820059
7.63692133843779
6.54416040778361
5.70883600097086
5.06483470443656
4.5434711146104
4.11581622244161
3.75746208052209
3.45151731213605
3.18801082537781
2.95862439193583
2.7539558301989
2.57361268912685
2.41264683373079
2.26580157314873
2.13272274614116
2.01097195611616
1.89777846258686
1.79428728298927
1.69718220595943
1.60678400444695
1.52140896497457
1.44183205335291
1.36643224505483
1.29390342401058
1.22498513407868
0.264649195849565
0.555878633198645
1.66840758587196
1.99107835944073
2.27131468629804
2.4833469429068
2.71727657872785
2.83172592368129
2.90017928034225
2.91937174232723
2.91264007244203
2.91215413913505
2.92007034129351
2.88607862394032
2.93544794476339
2.95325848129118
2.92826224396422
2.93655810511666
2.91672328614052
2.83681981284336
2.77415124039258
2.62202050043556
2.53742508071653
2.43294688078943
2.36828853162351
2.27004512258033
2.13942637765871
2.04346837589585
 1.15851770109259 1.92170733459177
1.09401472891998 1.79204725310461
1.03099190498627 1.65568817125926
0.96847487387749 1.50011737243493
0.90575899415363 1.33567486235338
0.84186291400268 1.1598690545085

ños de poros

15 20 25
oros (nm)
 H2 Presure (torr) H2 Uptake
50 40
75 50
100 60
150 65
200 70
250 75
300 80
350 85
400 90

Datos
PM (Rh) 0.015
AM (Rh) 7.58 Å2
D (Rh) 0.69 Rs
 Chart Title
100
90
f(x) = 0.1 x + 50
80 R² = 1
70
60
50
40
30
20
10
0
0 50 100 150 200 250 300 350 400 450