Socorro Avila Gil

Maestría en Ingeniería Química

Termodinámica
Ejercicios complementarios Ley de Raoult Modificada

Datos Calculo de presiones de saturación Constantes de Antoine

0.175 - 55.813352 K Componente 1 ACETONA Componente 2 METANOL
0.825 - 64.36197243 K A 14.3145 A 16.5786
100 kPa B 2756.22 B 3638.27
Parametro de Porter C 228.06 C 239.5
A 0.64

A
62.8659639 126.538074 94.2479942 0.64 1.545890315 1.01979334 1.342607612 83.01881485 59.7113332 3.154630662
59.7113332 114.055715 83.0188149 0.64 1.545890315 1.01979334 1.373853807 82.44027956 59.5393514 0.171981777
59.5393514 113.404334 82.4402796 0.64 1.545890315 1.01979334 1.375593761 82.40830056 59.5298156 0.009535811
59.5298156 113.368304 82.4083006 0.64 1.545890315 1.01979334 1.375690348 82.40652609 59.5292864 0.000529219
59.5292864 113.366304 82.4065261 0.64 1.545890315 1.01979334 1.375695709 82.40642761 59.529257 2.93721E-05
59.529257 113.366193 82.4064276 0.64 1.545890315 1.01979334 1.375696007 82.40642214 59.5292554 1.63019E-06
59.5292554 113.366187 82.4064221 0.64 1.545890315 1.01979334 1.375696023 82.40642184 59.5292553 9.0477E-08
59.5292553 113.366187 82.4064218 0.64 1.545890315 1.01979334 1.375696024 82.40642182 59.5292553 5.0216E-09
59.5292553 113.366187 82.4064218 0.64 1.545890315 1.01979334 1.375696024 82.40642182 59.5292553 2.78703E-10
59.5292553 113.366187 82.4064218 0.64 1.545890315 1.01979334 1.375696024 82.40642182 59.5292553 1.54614E-11
59.5292553 113.366187 82.4064218 0.64 1.545890315 1.01979334 1.375696024 82.40642182 59.5292553 8.52651E-13
59.5292553 113.366187 82.4064218 0.64 1.545890315 1.01979334 1.375696024 82.40642182 59.5292553 5.68434E-14
59.5292553 113.366187 82.4064218 0.64 1.545890315 1.01979334 1.375696024 82.40642182 59.5292553 0

L/F

0 1 1.89648088 1 2.149968057 0.82406422 0.886567151 0.132691208 0.86730879 0.132691208

0.13269121 0.86730879 1.61837686 1.01133218 1.834692131 0.83340266 1.117965006 0.166382792 0.83361721 0.033691584
0.16638279 0.83361721 1.5600959 1.01787515 1.768621237 0.83879449 1.175386997 0.173371555 0.82662844 0.006988763
0.17337156 0.82662844 1.5485536 1.01942315 1.755536169 0.84007014 1.187117716 0.174697756 0.82530224 0.0013262
0.17469776 0.82530224 1.54638389 1.01972436 1.753076445 0.84031836 1.189334377 0.1749441 0.8250559 0.000246344
0.1749441 0.8250559 1.54598158 1.01978057 1.752620361 0.84036468 1.189745777 0.174989668 0.82501033 4.55681E-05
0.17498967 0.82501033 1.54590718 1.01979098 1.752536024 0.84037326 1.189821864 0.174998091 0.82500191 8.42247E-06
0.17499809 0.82500191 1.54589343 1.0197929 1.752520437 0.84037484 1.189835927 0.174999647 0.82500035 1.55652E-06
0.17499965 0.82500035 1.54589089 1.01979326 1.752517556 0.84037514 1.189838526 0.174999935 0.82500007 2.87647E-07
0.17499993 0.82500007 1.54589042 1.01979333 1.752517024 0.84037519 1.189839006 0.174999988 0.82500001 5.31573E-08
0.17499999 0.82500001 1.54589033 1.01979334 1.752516925 0.8403752 1.189839095 0.174999998 0.825 9.82347E-09
0.175 0.825 1.54589032 1.01979334 1.752516907 0.8403752 1.189839111 0.175 0.825 1.81538E-09

59.5292553
Calculo de las fracciones de vapor
100 K
0.15 y1 0.307
0.85 y2 0.693
113.366187 K
82.4064218 K
A. 0.64 Porter
1.3

Datos Calculo de presiones de saturación Constantes de Antoine

P1 sat 113.366187
T 59.5292553 °C Kpa Componente 1 Componente 2

P2 sat 82.4064218 A 14.3145 A 16.5786

Parametro de Porter Kpa
A 0.64 B 2756.22 B 3638.27
C 228.06 C 239.5

x1 x2 gamma 1 gamma 2 P(Kpa) y1 y2

0 1 1.89648088 1 82.4064218 0 1
0.1 0.9 1.67933856 1.00642052 93.6799837 0.203224 0.796776
0.2 0.8 1.50621518 1.02593049 101.785383 0.33551747 0.66448253
0.3 0.7 1.36834229 1.05929119 107.641802 0.4323332 0.5676668
0.4 0.6 1.25910355 1.10782651 111.871119 0.51037219 0.48962781
0.5 0.5 1.17351087 1.17351087 114.870642 0.57907073 0.42092927
0.6 0.4 1.10782651 1.25910355 116.857328 0.64483796 0.35516204
0.7 0.3 1.05929119 1.36834229 117.88952 0.71305289 0.28694711
0.8 0.2 1.02593049 1.50621518 117.869023 0.78939029 0.21060971
0.9 0.1 1.00642052 1.67933856 116.52348 0.88123571 0.11876429
1 0 1 1.89648088 113.366187 1 0

x1 x2 T y1 gamma 1 gamma 2 alfa

0 1 64.3619724 0 1.89648088 1 2.60898121
0.1 0.9 61.2041389 0.20124343 1.67933856 1.00642052 2.29552093
0.2 0.8 59.0669047 0.33627785 1.50621518 1.02593049 2.01972185
0.3 0.7 57.5781287 0.43588143 1.36834229 1.05929119 1.77705909
0.4 0.6 56.5211463 0.51595164 1.25910355 1.10782651 1.56355145
0.5 0.5 55.7693853 0.5858736 1.17351087 1.17351087 1.37569602
0.6 0.4 55.254969 0.65209719 1.10782651 1.25910355 1.2104108
0.7 0.3 54.954768 0.71998118 1.05929119 1.36834229 1.06498403
0.8 0.2 54.8878271 0.7950877 1.02593049 1.50621518 0.9370298
0.9 0.1 55.1242604 0.88462904 1.00642052 1.67933856 0.82444883
1 0 55.813352 1 1 1.89648088 0.72539409
1.4
 𝑆
ln ln = ln ( 𝑆 )

𝑆
[𝐴 + 2 (𝐴 𝐴 )] [𝐴 + 2 (𝐴 𝐴 )] = ln ( 𝑆 )

𝑆
(1 ) [𝐴 + 2 (𝐴 𝐴 )] [𝐴 + 2(1 )(𝐴 𝐴 )] = ln ( 𝑆 )

𝑆
(1 2 + )[𝐴 + 2 (𝐴 𝐴 )] [𝐴 + 2(1 )(𝐴 𝐴 )] = ln ( 𝑆 )

3 3
𝐴 2𝐴 +𝐴 + 2𝐴 2𝐴 4𝐴 + 4𝐴 + 2𝐴 2𝐴 𝐴 2𝐴 + 2𝐴
𝑆
3 3
+ 2𝐴 2𝐴 = ln ( 𝑆 )

𝑆
[3𝐴 3𝐴 ] + [2𝐴 4𝐴 ] + [𝐴 ln ( 𝑆 )] = 0

𝑏 ± √𝑏 4 𝑐
=
2
= 3[𝐴 𝐴 ]
𝑏 = 2[𝐴 2𝐴 ]
𝑆
𝑐=𝐴 ln ( 𝑆 )
1.5
 𝑆
ln( ) ln( ) = ln ( )

𝐴′
ln( ) =
𝐴′
[1 + ( )]
𝐴′
𝐴′
ln( ) =
𝐴′
[1 + ( )]
𝐴′

𝐴′ 𝐴′ 𝑆
= ln ( )
𝐴′ 𝐴′
[1 + ( ′ )] [1 + ( ′ )]
𝐴 𝐴

𝐴′ 𝐴′ 𝑆
= ln ( )
𝐴′ + 𝐴′ 𝐴′ + 𝐴′
[ ] [ ]
𝐴′ 𝐴′

𝐴′ (𝐴′ ) 𝐴′ (𝐴′ ) 𝑆
= ln ( )
[𝐴′ + 𝐴′ ] [𝐴′ + 𝐴′ ]

𝐴′ (𝐴′ ) 𝐴′ (𝐴′ ) 𝑆
= ln ( )
[𝐴′ + 𝐴′ ]
𝑆
𝐴′ (𝐴′ ) 𝐴′ (𝐴′ ) = [𝐴′ + 𝐴′ ] ln ( )

=1
𝑆
′ [𝐴′
𝐴 (1 )] 𝐴 (𝐴′
′ ) = [𝐴′ + 𝐴 (1′ )] ln ( )

𝑆
′ ′ ′ ′
𝐴 𝐴 (1 2 + ) 𝐴 𝐴 = [𝐴′ + 2𝐴 𝐴 ′ ′ (1 ) + 𝐴′ (1 ) ] ln ( )

𝑆
𝐴′ 𝐴′ (1 2 + ) 𝐴′ 𝐴′ = [𝐴′ + 2𝐴′ 𝐴′ (1 ) + 𝐴′ (1 ) ] ln ( )

𝑆
1
𝐴′ (1 2 + ) 𝐴′ = [𝐴′ + 2𝐴′ 𝐴′ 2𝐴′ 𝐴′ + 𝐴′ 2𝐴′ + 𝐴′ ] ln ( )
𝐴 𝐴′
′

𝐴′ 𝐴′ 𝐴′ 𝐴′ 𝑆
𝐴′ 2𝐴′ + 𝐴′ 𝐴′ =[ +2 2 + 2 + ] ln ( )
𝐴′ 𝐴′ 𝐴′ 𝐴′

𝐴′ 𝐴′ 𝑆
𝐴′ 𝑆
𝐴′ 𝑆
[𝐴′ 𝐴′ + (2 ) ln ( )] + [2 ( ′ 1) ln ( ) 2𝐴′ ] + [𝐴′ ln ( )]
𝐴′ 𝐴′ 𝐴 𝐴′
 𝐴′ 𝐴′ 𝑆
= 𝐴′ 𝐴′ + (2 ) ln ( )
𝐴′ 𝐴′

𝐴′ 𝑆
𝑏 = 2( ′ 1) ln ( ) 2𝐴′
𝐴

′
𝐴′ 𝑆
𝑐=𝐴 ln ( )
𝐴′
 T
0 1 64.3619683 0 1.85595614 1 2.54965966
0.1 0.9 61.3258225 0.19723666 1.65021239 1.00620316 2.2530388
0.2 0.8 59.2756116 0.33053932 1.48553652 1.02504447 1.99092605
0.3 0.7 57.8411991 0.43004197 1.35393613 1.05723393 1.75930683
0.4 0.6 56.8125487 0.51117623 1.24935073 1.10400447 1.55463359
0.5 0.5 56.0699236 0.58297802 1.16719099 1.16719099 1.37377151
0.6 0.4 55.5502675 0.65157506 1.10400447 1.24935073 1.21395046
0.7 0.3 55.2312566 0.72192946 1.05723393 1.35393613 1.07272258
0.8 0.2 55.1257571 0.79897382 1.02504447 1.48553652 0.94792479
0.9 0.1 55.2849681 0.88872834 1.00620316 1.65021239 0.83764565
1 0 55.813352 1 1 1.85595614 0.74019611
2.1

Psat1= 32.27 Kpa Psat2= 73.14 Kpa

A= 0.67

x1 x2 ϒ1 ϒ2 Ptotal (kPa) y1 y2 alfa

0 1 1.95423732 1 73.14 0 1 0.8622
0.1 0.9 1.72064634 1.0067225 71.8210407 0.07731057 0.922689428 0.7541
0.2 0.8 1.53541392 1.02716235 70.0108849 0.14154315 0.858456846 0.6595
0.3 0.7 1.38860549 1.06215515 67.8233089 0.19820752 0.801792481 0.5768
0.4 0.6 1.27277556 1.11315686 65.2787628 0.2516743 0.748325699 0.5045
0.5 0.5 1.18234529 1.18234529 62.3155085 0.30613794 0.693862062 0.4412
0.6 0.4 1.11315686 1.27277556 58.7892651 0.36661358 0.633386416 0.3859
0.7 0.3 1.06215515 1.38860549 54.4618043 0.4405477 0.559452301 0.3375
0.8 0.2 1.02716235 1.53541392 48.9772581 0.5414191 0.458580895 0.2952
0.9 0.1 1.0067225 1.72064634 41.8230488 0.69909398 0.300906025 0.2581
1 0.00 1 1.95423732 32.27 1 6.14686E-16 0.2258
0.65 0.35 1.08553722 1.3272047 56.7447991 0.40126472 0.598735278 Ejemplo.

Presión de burbuja P 56.7447991

 y1= 0.65 y2= 0.35
Psat= 32.27 Psat= 73.14 A= 0.67

ϒ1, sup ϒ2, sup Ptotal (kPa) x1 x2 ϒ1, N ϒ2, N |ϒ1, N - ϒ1, sup||ϒ2, N - ϒ2, sup|
1 1 40.1157091 0.80803257 0.19196743 1.02499784 1.54875927 0.02499784 0.54875927
1.02499784 1.54875927 43.9732495 0.86413183 0.13586817 1.01244511 1.64922414 0.01255273 0.10046487
1.01244511 1.64922414 43.8663354 0.87271865 0.12728135 1.01091348 1.66578646 0.00153163 0.01656232
1.01091348 1.66578646 43.8638468 0.87399132 0.12600868 1.01069518 1.66826931 0.00021831 0.00248286
1.01069518 1.66826931 43.8637922 0.87417901 0.12582099 1.01066317 1.66863611 3.2007E-05 0.00036679
1.01066317 1.66863611 43.863791 0.87420667 0.12579333 1.01065846 1.66869017 4.7128E-06 5.4069E-05
1.01065846 1.66869017 43.8637909 0.87421075 0.12578925 1.01065776 1.66869814 6.9438E-07 7.9677E-06
1.01065776 1.66869814 43.8637909 0.87421135 0.12578865 1.01065766 1.66869932 1.0232E-07 1.1741E-06
1.01065766 1.66869932 43.8637909 0.87421143 0.12578857 1.01065764 1.66869949 1.5077E-08 1.7301E-07

ϒ2, N= 1.66870 x1= 0.8742

ϒ1, N= 1.01066 x2= 0.1258
Procio= 43.864 kPa suma 1.0000 A= 0.67

y1 y2 Ptotal x1 x2 gamma 1 gamma 2 alfa

0 1 71.1823379 0 1 1.954 1.000 0.8622
0.1 0.9 77.2890246 0.02335756 0.97664244 1.895 1.000 0.8357
0.2 0.8 84.4221785 0.05386812 0.94613188 1.822 1.002 0.8022
0.3 0.7 92.7831934 0.09551188 0.90448812 1.730 1.006 0.7586
0.4 0.6 102.531501 0.15537153 0.84462847 1.613 1.016 0.7002
0.5 0.5 113.56935 0.24736148 0.75263852 1.462 1.042 0.6190
0.6 0.4 124.897974 0.39479576 0.60520424 1.278 1.110 0.5080
0.7 0.3 133.702061 0.5994543 0.4005457 1.113 1.272 0.3862
0.8 0.2 137.436153 0.78493013 0.21506987 1.031 1.511 0.3012
0.9 0.1 136.946581 0.91282268 0.08717732 1.005 1.748 0.2537
1 0 134.051375 1 0.00 1.000 1.954 0.2258
0.65 0.35 43.8637909 0.87421145 0.12578855 1.011 1.669 0.2672
1.000 1 0.44120864
Del intervalo de 43.86 a 56.74 KPa.
2.2