T [K] dias 1/T ln 1/dia

22 295.15 87 0.00338811 -4.46590812

23.4 296.55 85 0.00337211 -4.44265126
26.3 299.45 74 0.00333946 -4.30406509
24.3 297.45 78 0.00336191 -4.35670883
21.1 294.25 90 0.00339847 -4.49980967
22.7 295.85 84 0.00338009 -4.4308168

m ALFA
-3392.763 2.000
b k
7.138 1.26E+03
R2 Ea
0.948 28.207 kJ/mol
Reaccion de A > B + C ALPHA 1.00
Calcular Ko, n y Ea
Ea 0 [kJ/mol]
K0
R 0.008314 kJ/mol

El orden es el que te da las unidades de K

 P, mmHg t1/2,s P, atm CA y
200 265 0.26315789 8.31397252 5.57972983
240 186 0.31578947 9.97676702 5.22574667
280 115 0.36842105 11.6395615 4.74493213
320 104 0.42105263 13.302356 4.6443909
360 67 0.47368421 14.9651505 4.20469262

T 293.15 K
R 0.08206 atm*L/mol*K
x
2.11793754 m a
2.30025909 -2.27102467 3.27102467
2.45440977 b k
2.58794116 10.4058791 5.0978E-05
2.7057242
Presion 1 atm
T1 25 °C 298.15 °K
T2 100 °C 373.15 °K

t (min) P atm PA 1/PA

0 1 1.25155123 0.79900844
1 1.14 1.02844877 0.97233818
2 1.04 0.82844877 1.20707525
3 0.982 0.71244877 1.4036097
4 0.94 0.62844877 1.59121961
5 0.905 0.55844877 1.79067456
6 0.87 0.48844877 2.04729762
7 0.85 0.44844877 2.22990913
8 0.832 0.41244877 2.42454355
9 0.815 0.37844877 2.64236559
10 0.8 0.34844877 2.86986235
15 0.754 0.25644877 3.89941434
20 0.728 0.20444877 4.89120092

R 0.08206 atm*L/mol*K
a (coef react) 2
Delta n -1

Encontrar expresion cinetica que represente los siguientes datos

n=0 n=1 n=2

t (min) PA t (min) Ca mol/L t (min) LN (CO/C) t (min)
0 1.25155123 0 1.25155123 0 0 0
1 1.02844877 1 1.02844877 1 0.20 1
2 0.82844877 2 0.82844877 2 0.41 2
3 0.71244877 3 0.71244877 3 0.56 3
4 0.62844877 4 0.62844877 4 0.69 4
5 0.55844877 5 0.55844877 5 0.81 5
6 0.48844877 6 0.48844877 6 0.94 6
7 0.44844877 7 0.44844877 7 1.03 7
8 0.41244877 8 0.41244877 8 1.11 8
9 0.37844877 9 0.37844877 9 1.20 9
10 0.34844877 10 0.34844877 10 1.28 10
15 0.25644877 15 0.25644877 15 1.59 15
20 0.20444877 20 0.20444877 20 1.81 20
m orden m orden m
-0.046 -0.046 0.089 0.089 0.206
b k b k b
0.901 2.462 0.279 1.322 0.785
R2 Alpha R2 Alpha R2
0.735 1.046 0.923 0.911 1.000
 Para el metodo grafico se aplica el metodo integral

iteracion t (min) Ca (mol/L)

1 0 1.25155123
2 1 1.02844877
3 2 0.82844877
4 3 0.71244877
5 4 0.62844877
6 5 0.55844877
7 6 0.48844877
8 7 0.44844877
9 8 0.41244877
10 9 0.37844877
11 10 0.34844877
12 15 0.25644877
13 20 0.20444877

n=2 n=3
1 / CA t (min) 1 / CA 2
0.79900844 0 0.63841449
0.97 1 0.95
1.21 2 1.46
1.40 3 1.97
1.59 4 2.53
1.79 5 3.21
2.05 6 4.19
2.23 7 4.97
2.42 8 5.88
2.64 9 6.98
 2.87 10 8.24
3.90 15 15.21
4.89 20 23.92
orden m orden
0.206 1.137 1.137
k b k
2.191 -1.706 0.182
Alpha R2 Alpha
0.794 0.949 -0.137
 El orden 2 es el mas beneficioso para

iteracion k a=0 % desviacionC cal %Desv CA iteracion k a=2

1 #DIV/0! #DIV/0! 1.25155123 0 1 #DIV/0!
2 0.22310247 71.4449541 1.12142056 9.04000272 2 0.17332974
3 0.21155123 62.5683129 0.9912899 19.6561495 3 0.2040334
4 0.17970082 38.0925984 0.86115923 20.8731443 4 0.20153375
5 0.15577562 19.7070744 0.73102856 16.3226974 5 0.19805279
6 0.13862049 6.5240765 0.60089789 7.60125626 6 0.19833322
7 0.12718374 2.26458874 0.47076722 3.61993887 7 0.2080482
8 0.11472892 11.8355997 0.34063655 24.0411443 8 0.20441438
9 0.10488781 19.3980871 0.21050588 48.9619318 9 0.20319189
10 0.09701139 25.4507903 0.08037521 78.7619299 10 0.20481746
11 0.09031025 30.6003362 -0.04975545 114.27913 11 0.20708539
12 0.06634016 49.0203462 -0.7004088 373.118411 12 0.20669373
13 0.05235512 59.7672679 -1.35106214 760.831639 13 0.20460962
promedio 0.13013067 33.0561694 113.623644 promedio 0.20117863
k presion

iteracion k a=1 % desviacionC cal %Desv CA iteracion k a=3

1 #DIV/0! #DIV/0! 1.25155123 0 1 #DIV/0!
2 0.19633215 29.2173035 1.07513286 4.53927279 2 0.15351352
3 0.20629202 35.7724596 0.92358238 11.4833435 3 0.20465404
4 0.18781035 23.6086216 0.79339443 11.3616113 4 0.22195095
5 0.17222113 13.3484779 0.68155773 8.45080279 5 0.23669567
6 0.16139523 6.22333933 0.58548551 4.84140145 6 0.25681009
7 0.15681741 3.21041467 0.50295561 2.96998294 7 0.29608442
8 0.14662066 3.50064516 0.43205911 3.65474544 8 0.30957716
9 0.13875338 8.67854514 0.37115616 10.0115736 9 0.32749981
10 0.13289537 12.5340331 0.31883807 15.7513255 10 0.35242675
11 0.12786478 15.8449475 0.27389473 21.3959825 11 0.37988477
12 0.10568068 30.4455646 0.12813011 50.0367613 12 0.48556726
13 0.09059108 40.376881 0.05994027 70.6820079 13 0.5821358
promedio 0.15193952 18.5634361 16.5522162 promedio 0.31723335

k concentraci

-rA = 6.32 CA ^2 mol/L min

 mas beneficioso para este caso

% desviacionC cal %Desv CA

#DIV/0! 1.25155123 0
13.8428696 0.99981296 2.78436869
1.41902295 0.83238601 0.47525428
0.17652027 0.71298994 0.07595932
1.5537636 0.62354909 0.77964596
1.41436892 0.55404682 0.78824464
3.41465954 0.49848455 2.05462331
1.60839766 0.45305062 1.02617175
1.0007313 0.41520696 0.66873482
1.8087554 0.38319812 1.25495332
2.93607717 0.35577126 2.10145542
2.74139198 0.26200728 2.16749247
1.70544589 0.20735784 1.42288648
2.80183369 1.19998388

% desviacionC cal %Desv CA

#DIV/0! 1.25155123 0
51.6086441 0.88635166 13.8166438
35.4878551 0.72407748 12.5983994
30.0354304 0.62723179 11.961137
25.3875212 0.56110033 10.7166162
19.0469456 0.51226524 8.26996753
6.66667941 0.47430055 2.89656122
2.41342631 0.44369217 1.06067861
3.23624765 0.41833505 1.42715472
11.0938501 0.39688118 4.87051846
19.7493168 0.37842206 8.60192186
53.0631164 0.31379872 22.3631208
83.5039711 0.27391865 33.9791159
28.4410837 10.1970643

6.31794336

2 CA ^2 mol/L min
CA,milimol/
0.84 0.68 0.53 0.38 0.27 0.16 0.09
litro
t,h 1 2 3 4 5 6 7

CA,milimol/litro t,h y x m
0.84 1 -0.16 -0.17435339 -0.01269959
0.68 2 -0.16 -0.38566248 b
0.53 3 -0.15666667 -0.63487827 -0.16343279
0.38 4 -0.155 -0.96758403
0.27 5 -0.146 -1.30933332 k
0.16 6 -0.14 -1.83258146 16.3432794
0.09 7 -0.13 -2.40794561 CM
0.04 8 -0.12 -3.21887582 -0.01269959
0.018 9 -0.10911111 -4.01738352
0.006 10 -0.0994 -5.11599581
0.0025 11 -0.09068182 -5.99146455

CA0 1 mmol/L
CE0 0.01 mmol/L
0.04 0.018 0.006 0.0025

8 9 10 11
 T1 100 °C 373.15 °K Reaccion de A > B + 2C
T2 110 °C 383.15 °K Calcular K y n
n
R 0.008314

Prueba t 1/2 [min] CA [g mol/ L]

1 4.1 0.025
2 7.7 0.0133
3 9.8 0.01
4 1.96 0.05
5 1.3 0.075
6 2 0.025

T (°C) mmHg
100
DELTA T 200

Iteracion t 1/2 [min] CA (mol/L) ln t/2 ln CAo CA calc % desv

1 4.1 0.025 1.41098697 -3.68887945 0.0243302 2.6791973
2 7.7 0.0133 2.04122033 -4.31999124 0.0130592 1.81051382
3 9.8 0.01 2.28238239 -4.60517019 0.01029229 2.9229151
4 1.96 0.05 0.67294447 -2.99573227 0.05041976 0.83951421
5 1.3 0.075 0.26236426 -2.59026717 0.07562193 0.82924312

1.81627671
m ALFA k2 21.0769992
-1.013 2.013 t 1/2 0.5 2
b k
-2.353 10.568
R2 Ea
0.999 82.058 kJ/mol
eaccion de A > B + 2C
alcular K y n