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T (K) T (K)
Presión (Bar)
2-octanol Hexanol
0.00133 315.14 297.03
0.00667 337.26 315.67
0.01333 347.93 352.78
0.02666 359.40 361.56
0.05333 371.76 389.42
0.07999 379.45 405.85
0.13332 389.66 423.91
0.26664 404.54 439.45
0.53329 420.75 462.84
1.01325 437.11 476.29
1/T
Ln P 2 - octano
2-octanol
7.00000
0.00317319 0.00072
f(x) = − 7481.70027608768 x + 23.7907
0.00296507 1.61016 6.00000 R² = 0.999830760421002
0.00287414 2.30330
5.00000
0.00278242 2.99645
0.00268991 3.68960 4.00000
0.00263539 4.09506
0.00256634 4.60589 3.00000
0.00000
0.00220000 0.00240000 0.00260000 0.0028000
2.00000
1.00000
0.00000
0.00220000 0.00240000 0.00260000 0.0028000
1/T Hexanol
Ln P
Hexanol 7.00000
0.003367 0.00072
6.00000
0.003168 1.61016 f(x) = − 4777.9862179379 x + 16.1748069
R² = 0.975373172637544
0.002835 2.30330 5.00000
0.002766 2.99645
4.00000
0.002568 3.68960
0.002464 4.09506 3.00000
0.002359 4.60589
0.002276 5.29903 2.00000
Rango T° de
ebullición de la 1/T Ln P 2-octanol Ln P hexanol
mezcla
436.05 0.00229331498681 6.6331052631579 5.21754099301
440.05 0.00227246903761 6.789068401318 5.3171429383
444.05 0.0022519986488 6.942221709267 5.41495045603
450.05 0.00222197533607 7.1668471280969 5.55840184424
454.05 0.00220240061667 7.3132993062438 5.65192985354
456.05 0.0021927420239 7.3855619997807 5.6980786098
462.05 0.00216426793637 7.5985965804567 5.83412780002
469.05 0.00213196887325 7.8402484809722 5.98845272359
471.05 0.0021229168878 7.907972720518 6.03170311007
473.05 0.00211394144382 7.9751242997569 6.07458778142
475.05 0.00210504157457 8.0417104515314 6.1171113567
477.05 0.00209621632953 8.1077382873913 6.15927837753
480.05 0.00208311634205 8.2057484637017 6.2218701177
482.05 0.00207447360232 8.2704108494969 6.2631651281
486.05 0.0020574015019 8.3981391832116 6.34473562391
492.05 0.00203231378925 8.5858379229753 6.46460471497
500.05 0.00199980002 8.829096190381 6.61995550445
500.74 0.00199704437433 8.8497131046052 6.63312197947
Se calcula la fracción molar del compuesto en estado líquido con las presiones de
Rango T° de
ebullición de la
mezcla T en °C X Y
436.05 162.9 1 1
440.05 166.9 0.812 0.217
444.05 170.9 0.66 0.195
450.05 176.9 0.483 0.152
454.05 180.9 0.39 0.146
456.05 182.9 0.351 0.123
462.05 188.9 0.252 0.113
469.05 195.9 0.168 0.088
471.05 197.9 0.149 0.081
473.05 199.9 0.131 0.074
475.05 201.9 0.115 0.068
477.05 203.9 0.1 0.062
480.05 206.9 0.081 0.053
482.05 208.9 0.069 0.047
486.05 212.9 0.049 0.036
492.05 218.9 0.025 0.021
500.05 226.9 0.00165 0.00162
500.74 227.59 0 0
or (1 bar)
atura (K) Tutor
Alcohol bencílico 2-octanol Hexanol
326.07 315.14 297.03
350.92 337.27 315.67
363.31 347.94 352.78
376.92 359.41 361.56
391.97 371.77 389.42
401.52 379.45 405.85
414.45 389.66 423.91
433.81 404.54 439.45
455.63 420.75 462.84
478.45 437.11 476.29
1/T 1/T
Presión (mmHg) LnP
2-octanol Hexanol
1.00072 0.00072 0.00317319 0.003367
5.00359 1.61016 0.00296507 0.003168
10.00718 2.30330 0.00287414 0.002835
20.01435 2.99645 0.00278242 0.002766
40.02870 3.68960 0.00268991 0.002568
60.04306 4.09506 0.00263539 0.002464
100.07176 4.60589 0.00256634 0.002359
200.14352 5.29903 0.00247194 0.002276
400.28704 5.99218 0.00237671 0.002161
760.54537 6.63404 0.00228775 0.002100
) = − 7481.70027608768 x + 23.7907073577707
= 0.999830760421002
(∆𝐻_𝑚)/𝑅𝑇=−7481,7𝐾; ∆𝐻_𝑚=7481,7𝐾∗𝑅
𝐿𝑛(𝑃/𝑚𝑚𝐻𝑔)=−7481,7𝐾(1/𝑇_𝐾 )+23,791
𝐿𝑛(𝑃/𝑚𝑚𝐻𝑔)=−4778𝐾(1/𝑇_𝐾 )+16,175
o con las presiones de vapor
,𝟒𝟖 𝒎𝒎𝑯𝒈)/(𝟕𝟔𝟎 𝒎𝒎𝑯𝒈 −𝟏𝟖𝟒,𝟒𝟖 𝒎𝒎𝑯𝒈)=𝟏 𝑦=x 𝑃_(𝑣, 𝑚𝑎𝑠 𝒚_𝟏=𝟏∗(𝟕𝟔𝟎𝒎𝒎𝑯𝒈 )/(𝟕𝟔
𝑣𝑜𝑙𝑎𝑡𝑖𝑙)/𝑃
2-octanol vs hexanol
240
220
200
2-octanol vs hexanol
240
220
200
180
T °C
160
140
120
100
0 0.2 0.4 0.6 0.8 1 1.2
Fracción molar x,y
81,7𝐾(1/𝑇_𝐾 )+23,791
𝐾; ∆𝐻_𝑚=7481,7𝐾∗𝑅
∗1𝐾𝐽/1000𝐽=62,202 𝐾𝐽/𝑚𝑜𝑙
4778𝐾(1/𝑇_𝐾 )+16,175
; ∆𝐻_𝑚=4778𝐾∗𝑅
14 𝐽/𝑚𝑜𝑙𝐾=39724,292 𝐽/𝑚𝑜𝑙
𝑜𝑙∗1𝐾𝐽/1000𝐽=39,724 𝐾𝐽/𝑚𝑜𝑙
𝒚_𝟏=𝟏∗(𝟕𝟔𝟎𝒎𝒎𝑯𝒈 )/(𝟕𝟔𝟎 𝒎𝒎𝑯𝒈)=𝟏