Tabla 11.

1 Constantes para el cálculo de Ki

Compuesto α β γ δ
C1 4.35 0.02542 -0.00002 0.000000008333
C2 0.65 0.008183 0.0000225 -0.00000002333
C3 0.15 0.002383 0.0000235 -0.00000002333
C4 0.0375 0.0005725 0.00001075000 -0.00000000025
C5 0.0105 0.0002692 0.00000255 0.00000001108
AA 0.0000142 0.000000364 0.00000000344 0.000000000015

Tabla 11.2 Constantes para el cálculo de HiG y HiL

Compuesto Ai Bi Ci ai
C1 1604 9.357 0.001782 0
C2 4661 15.54 0.003341 0
C3 5070 26.45 0 0
C4 5231 33.9 0.005812 0
C5 5411 42.09 0.008017 0
AA 8000 74.67 0.03556 0

ITERACION 1

Compuesto K95°F A S фA фS
C1 6.591544506 0.04190870496 23.861391111 0.958091418899891 2.9554520201544E-06
C2 1.610444941 0.17153215664 5.8298106873 0.828590889471428 0.0007173355356592
C3 0.568469941 0.48594142606 2.0578611873 0.528375923863125 0.0294631187099148
C4 0.188691906 1.46399015948 0.6830647006 0.0810466451116974 0.372295401754882
C5 0.068587465 4.02760320596 0.2482866233 0.002859404133415 0.752423328496936
AA 9.268663E-05 2980.39867049 0.0003355256 1.266942236642E-14 0.9996644744175
 ITERACION 2

G2 LI GN
1675.6534 542.5285 1764.0617

𝐺_(𝑁+1) 𝐻_(𝐺,𝑁+1)+𝐿_0 𝐻_(𝐿,0)−𝐺_1 𝐻_(𝐺,1)−𝐿_𝑁 𝐻_(𝐿,𝑁)=0

= 0.75955627744

T1=
 T0 = 90 T1 = ? 94.5993059697676
Compuesto Xo HL0 Y1 HG1
C1 0.0000 0.0000 0.8859 2219.1763
C2 0.0000 0.0000 0.0761 468.8795
C3 0.0000 0.0000 0.0356 269.4856
C4 0.0020 5.8488 0.0019 15.9030
C5 0.0060 21.8168 0.0005 4.4700
AA 0.9920 6475.5141 0.0001 1.5675
Total 1.0000 6503.1797 1.0000 2979.4819
H0 H1
Ecn T :
Ecn H :

T1 =
TN =

T1= 94.59930597 °F

Compuesto K A1 S1 K
C1 6.58278826762 0.0504653497 19.8155765347994 6.896693633683
C2 1.60570874377 0.2068885241 4.83352087463407 1.78063056218158
C3 0.56598179784 0.5869494627 1.70372419352243 0.659594797238528
C4 0.18764851811 1.7703455135 0.564861487421635 0.227672966328358
C5 0.06816617301 4.8734247129 0.205194510824522 0.0846450357741474
AA 9.2117385E-05 3606.2976987 0.000277292692822 0.0001143839039224

ITERACION 3

G2 LI GN
1647.2657 550.9259 1754.0431

= 0.7616501396

T1=
 T0 = 90 T1 = ? 95.0603097659623
Compuesto Xo HL0 Y1 HG1
C1 0.0000 0.0000 0.8935 2242.3938
C2 0.0000 0.0000 0.0739 455.6730
C3 0.0000 0.0000 0.0308 233.6166
C4 0.0020 5.8488 0.0013 11.1207
C5 0.0060 21.8168 0.0004 3.7890
AA 0.9920 6475.5141 0.0001 1.3285
Total 1.0000 6503.1797 1.0000 2947.9216
H0 H1
Ecn T :
Ecn H :

T1 =
TN =

T1= 95.060309766 °F

Compuesto K A1 S1 K
C1 6.59286194576 0.052347248 19.103200994844 6.94150449926637
C2 1.61115824271 0.2142050173 4.66842472938969 1.80646940109241
C3 0.56884490856 0.606699953 1.64826121228682 0.673704185740885
C4 0.18884924691 1.8274797752 0.547201678282449 0.233837114269343
C5 0.06865103362 5.027137409 0.198920363349446 0.0872404917488512
AA 9.2772518E-05 3720.0475772 0.0002688137662871 0.0001178910462281

ITERACION 4

G2 LI GN
1641.2108 552.6898 1751.8914

= 0.7621002814
 T1=

T0 = 90 T1 = ? 95.1541464938361
Compuesto Xo HL0 Y1 HG1
C1 0.0000 0.0000 0.8952 2247.3091
C2 0.0000 0.0000 0.0734 452.6431
C3 0.0000 0.0000 0.0298 225.9517
C4 0.0020 5.8488 0.0012 10.3483
C5 0.0060 21.8168 0.0004 3.6867
AA 0.9920 6475.5141 0.0001 1.2949
Total 1.0000 6503.1797 1.0000 2941.2337
H0 H1
Ecn T :
Ecn H :

T1 =
TN =

T1= 95.154146494 °F

Compuesto K A1 S1 K
C1 6.59491151222 0.0527569308 18.9548554906448 6.95074977063399
C2 1.61226830669 0.2157998697 4.63392309491044 1.81182763110089
C3 0.56942856862 0.6110113009 1.63663094044044 0.676638552593717
C4 0.18909420969 1.839967977 0.543487719609624 0.235123260784649
C5 0.06875002344 5.0607588635 0.197598824006117 0.0877839479272833
AA 9.2906271E-05 3744.9279609 0.0002670278334937 0.0001186254021258

ITERACION 5

G2 LI GN
1639.9236 553.0635 1751.4332
 = 0.7621961375

T1=

T0 = 90 T1 = ? 95.1738652327983
Compuesto Xo HL0 Y1 HG1
C1 0.0000 0.0000 0.8955 2248.3494
C2 0.0000 0.0000 0.0733 451.9920
C3 0.0000 0.0000 0.0296 224.3306
C4 0.0020 5.8488 0.0012 10.1923
C5 0.0060 21.8168 0.0004 3.6653
AA 0.9920 6475.5141 0.0001 1.2878
Total 1.0000 6503.1797 1.0000 2939.8174
H0 H1
Ecn T :
Ecn H :

T1 =
TN =

T1= 95.173865233 °F

Compuesto K A1 S1 K
C1 6.59534216623 0.0528444132 18.9234762984041 6.95269864091463
C2 1.61250160969 0.216140551 4.62661909313738 1.81295831671559
C3 0.56955125596 0.6119326096 1.63416687432704 0.677258127073237
C4 0.18914570979 1.8426375453 0.542700327892933 0.235395005854124
C5 0.06877083783 5.0679473652 0.197318544954205 0.0878988571971732
AA 9.2934395E-05 3750.2475588 0.0002666490636454 0.000118780675721

ITERACION 6

G2 LI GN
1639.6500 553.1429 1751.3358
 = 0.762216517

T1=

T0 = 90 T1 = ? 95.178046456439
Compuesto Xo HL0 Y1 HG1
C1 0.0000 0.0000 0.8956 2248.5704
C2 0.0000 0.0000 0.0732 451.8532
C3 0.0000 0.0000 0.0295 223.9864
C4 0.0020 5.8488 0.0012 10.1595
C5 0.0060 21.8168 0.0004 3.6607
AA 0.9920 6475.5141 0.0001 1.2863
Total 1.0000 6503.1797 1.0000 2939.5165
H0 H1
Ecn T :
Ecn H :

T1 =
TN =

T1= 95.178046456 °F

Compuesto K A1 S1 K
C1 6.59543348171 0.0528630232 18.9168144454359 6.9531121550586
C2 1.61255108158 0.2162130284 4.62506818976423 1.81319828053305
C3 0.56957727266 0.6121286252 1.63364358219239 0.67738963499299
C4 0.1891566311 1.8432055531 0.542533087720505 0.235452693352018
C5 0.06877525195 5.0694769259 0.197259010073357 0.0879232545415059
AA 9.2940359E-05 3751.3794564 0.0002665686080602 0.0001188136431593
 Compuesto g l
C1 1510 0
C2 150 0
C3 110 0
N-C4 30 1
N-C5 10 3
AA 0 496
Total 1810 500

G y HiL T0 = 90 T promedio=
bi ci T N+1 = 100
14.17 -0.001782 N= 4
16.54 0.003341
22.78 0.004899
31.97 0.005812
39.68 0.008017
69.33 0.03556

(lbmol/h)
g1 lN
1446.71804254 63.28195746
124.288633421 25.71136658
58.1213516249 51.87864838
3.0591039516 27.94089605
0.77132405584 12.22867594
0.16642068892 495.8335793
1633.1249 676.8751237
G1 LN
_(𝐿,𝑁)=0

94.5993059698 TN sup= 109.1284094

 TN sup = 109.1284094 T N+1= 100
XN HLN Y N+1 HG N+1 Compuesto HiG
0.0935 142.5862 0.8343 2133.6217 C1 2505.1129
0.0380 70.0744 0.0829 517.8240 C2 6160.9719
0.0766 195.0052 0.0608 468.8674 C3 7572.1516
0.0413 146.8736 0.0166 143.8528 C4 8489.9282
0.0181 79.9561 0.0055 53.5921 C5 9464.4292
0.7325 5852.4702 0.0000 0.0000 AA 15381.9576
1.0000 6486.9658 1.0000 3317.7580
HN HN+1
0
-4.563481E-08 G N+1= 1810
L0= 500
G1= 1633.1249
LN= 676.8751237

94.5993059698
109.128409429

TN= 109.1284094 °F
(lbmol/h)
AN SN Ai,e Si,e фA фS g1
0.05563573624 17.9740589 0.055376821 18.89669859 0.944623671082 7.4275131E-06 1426.3817433
0.21548693822 4.640652507 0.21419095 4.745399092 0.786163470341 0.00155709425 117.92452055
0.58172476428 1.719026009 0.58312871 1.70963128 0.447011094021 0.0521582128 49.171220342
1.6853236207 0.59335785 1.717865806 0.572392878 0.051421201764 0.45560049923 2.0870355537
4.53307892705 0.220600615 4.684081191 0.207432362 0.001634555859 0.79287213736 0.6377291465
3354.51593091 0.000298106 3478.111483 0.000277298 6.83126486E-15 0.99972270154 0.1375400366
1596.3398
G1

95.060309766 TN sup= 111.2305967

 TN sup = 111.2305967 T N+1= 100
XN HLN Y N+1 HG N+1 Compuesto HiG
0.1172 182.0899 0.8343 2133.6217 C1 2509.5823
0.0449 84.5456 0.0829 517.8240 C2 6168.4280
0.0852 221.1373 0.0608 468.8674 C3 7584.3452
0.0405 146.9814 0.0166 143.8528 C4 8506.0644
0.0173 78.1726 0.0055 53.5921 C5 9484.5338
0.6948 5663.8434 0.0000 0.0000 AA 15419.4899
1.0000 6376.7703 1.0000 3317.7580
HN HN+1
0
-6.854534E-07 G N+1= 1810
L0= 500
G1= 1596.3398
LN= 713.660211

95.060309766
111.230596724

TN= 111.2305967 °F
(lbmol/h)
AN SN Ai,e Si,e фA фS g1
0.05861349372 17.06091783 0.058284649 18.0814785 0.941715984863 8.8380405E-06 1421.9911371
0.22522708114 4.439963413 0.223513546 4.564193887 0.776919860056 0.00180036356 116.53797901
0.60392356021 1.655838695 0.60468274 1.651166174 0.430086367218 0.05776288315 47.309500394
1.73995403448 0.574727826 1.773694096 0.554368868 0.046735593937 0.47025328393 1.9318145342
4.66372692574 0.214420787 4.825309664 0.201122688 0.00146287326 0.79914029493 0.6172078478
3451.20213453 0.000289754 3583.085857 0.000268819 6.06526691E-15 0.99973118061 0.1333344186
1588.5210
G1
95.1541464938 TN sup= 111.6652063

TN sup = 111.6652063 T N+1= 100

XN HLN Y N+1 HG N+1 Compuesto HiG
0.1220 190.3042 0.8343 2133.6217 C1 2510.4921
0.0464 87.5929 0.0829 517.8240 C2 6169.9459
0.0869 226.3371 0.0608 468.8674 C3 7586.8272
0.0403 146.7516 0.0166 143.8528 C4 8509.3492
0.0172 77.7631 0.0055 53.5921 C5 9488.6264
0.6873 5625.5874 0.0000 0.0000 AA 15427.1314
1.0000 6354.3363 1.0000 3317.7580
HN HN+1
0
-3.7916E-05 G N+1= 1810
L0= 500
G1= 1588.5210
LN= 721.4790267

95.1541464938
111.665206348

TN= 111.6652063 °F
(lbmol/h)
AN SN Ai,e Si,e фA фS g1
0.05924952694 16.87777189 0.058905493 17.91522692 0.941095174414 9.1657181E-06 1421.0537134
0.2273001188 4.399469764 0.22550083 4.526999865 0.774951041212 0.00185601514 116.24265618
0.60863903514 1.643009965 0.609290027 1.639072669 0.426524960151 0.05900854519 46.917745617
1.75154357087 0.570924992 1.785678816 0.550608605 0.04579653792 0.47334627091 1.9005498667
4.69138886452 0.213156493 4.855686384 0.199798754 0.00142892514 0.80045610559 0.6129209346
3471.67325387 0.000288046 3605.694416 0.000267033 5.91457941E-15 0.99973296656 0.1324485876
1586.8600
G1
95.1738652328 TN sup= 111.7568595

TN sup = 111.7568595 T N+1= 100

XN HLN Y N+1 HG N+1 Compuesto HiG
0.1230 192.0448 0.8343 2133.6217 C1 2510.6833
0.0467 88.2370 0.0829 517.8240 C2 6170.2649
0.0872 227.4192 0.0608 468.8674 C3 7587.3487
0.0402 146.6947 0.0166 143.8528 C4 8510.0395
0.0171 77.6765 0.0055 53.5921 C5 9489.4865
0.6857 5617.5329 0.0000 0.0000 AA 15428.7373
1.0000 6349.6050 1.0000 3317.7580
HN HN+1
0
-8.676201E-05 G N+1= 1810
L0= 500
G1= 1586.8600
LN= 723.1399654

95.1738652328
111.756859534

TN= 111.7568595 °F
(lbmol/h)
AN SN Ai,e Si,e фA фS g1
0.05938481006 16.83932304 0.059037535 17.88020693 0.940963139897 9.2366673E-06 1420.8543412
0.2277408611 4.390955559 0.225923478 4.519153108 0.774532397403 0.00186802789 116.17985961
0.60964154092 1.640308169 0.610270724 1.636516826 0.425769477353 0.05927580345 46.834642509
1.75400785031 0.570122876 1.78823263 0.549812459 0.045599329938 0.47400271219 1.893977186
4.69727026445 0.212889603 4.862162691 0.199518128 0.001421814645 0.80073503511 0.6120130411
3476.02575659 0.000287685 3610.515561 0.000266655 5.8830537E-15 0.99973334533 0.1322607162
1586.5071
G1
95.1780464564 TN sup= 111.7763084

TN sup = 111.7763084 T N+1= 100

XN HLN Y N+1 HG N+1 Compuesto HiG
0.1232 192.4143 0.8343 2133.6217 C1 2510.7239
0.0467 88.3737 0.0829 517.8240 C2 6170.3325
0.0873 227.6483 0.0608 468.8674 C3 7587.4593
0.0402 146.6823 0.0166 143.8528 C4 8510.1859
0.0171 77.6581 0.0055 53.5921 C5 9489.6689
0.6854 5615.8248 0.0000 0.0000 AA 15429.0778
1.0000 6348.6014 1.0000 3317.7580
HN HN+1
0
-0.0001152502 G N+1= 1810
L0= 500
G1= 1586.5071
LN= 723.4929057

95.1780464564
111.776308389

TN= 111.7763084 °F
(lbmol/h)
AN SN Ai,e Si,e фA фS g1
0.05941356422 16.83117337 0.0590656 17.87277872 0.940935076681 9.2518047E-06 1420.8119658
0.22783452862 4.389150345 0.226013307 4.5174882 0.77444342315 0.00187058915 116.16651347
0.60985458621 1.639735148 0.610479192 1.63597434 0.425609000726 0.05933271147 46.81699008
1.75453153526 0.569952708 1.788775612 0.549643411 0.045557529954 0.47414216706 1.8925837316
4.69852006392 0.212832974 4.863539793 0.199458528 0.001420308372 0.80079427639 0.6118202545
3476.95066462 0.000287608 3611.540766 0.000266574 5.87637694E-15 0.99973342579 0.1322208099
1586.4321
G1
95 °F P= 400 psia
 HiL HiG N HiL N HiG N+1 HiL N+1
1260.8658 2646.3364 1525.1277 2557.5200 1399.1800
1515.6621 6160.9719 1844.7719 6248.4100 1687.4100
2089.8819 7572.1516 2544.2874 7715.0000 2326.9900
2924.3772 8489.9282 3558.0504 8679.1200 3255.1200
3636.1377 9464.4292 4425.6898 9700.1700 4048.1700
6527.7360 15381.9576 7989.3570 15822.6000 7288.6000

(lbmol/h)
lN
83.61825667
32.07547945
60.82877966
28.91296445
12.36227085
495.86246
713.660211
LN
 HiL HiG N HiL N HiG N+1 HiL N+1
1260.8658 2666.8320 1554.0902 2557.5200 1399.1800
1515.6621 6168.4280 1881.0897 6248.4100 1687.4100
2089.8819 7584.3452 2594.4446 7715.0000 2326.9900
2924.3772 8506.0644 3627.9497 8679.1200 3255.1200
3636.1377 9484.5338 4512.8184 9700.1700 4048.1700
6527.7360 15419.4899 8151.5743 15822.6000 7288.6000

(lbmol/h)
lN
88.00886286
33.46202099
62.69049961
29.06818547
12.38279215
495.8666656
721.4790267
LN
 HiL HiG N HiL N HiG N+1 HiL N+1
1260.8658 2671.0713 1560.0760 2557.5200 1399.1800
1515.6621 6169.9459 1888.6018 6248.4100 1687.4100
2089.8819 7586.8272 2604.8196 7715.0000 2326.9900
2924.3772 8509.3492 3642.4072 8679.1200 3255.1200
3636.1377 9488.6264 4530.8403 9700.1700 4048.1700
6527.7360 15427.1314 8185.1506 15822.6000 7288.6000

(lbmol/h)
lN
88.94628663
33.75734382
63.08225438
29.09945013
12.38707907
495.8675514
723.1399654
LN
 HiL HiG N HiL N HiG N+1 HiL N+1
1260.8658 2671.9654 1561.3382 2557.5200 1399.1800
1515.6621 6170.2649 1890.1862 6248.4100 1687.4100
2089.8819 7587.3487 2607.0078 7715.0000 2326.9900
2924.3772 8510.0395 3645.4563 8679.1200 3255.1200
3636.1377 9489.4865 4534.6413 9700.1700 4048.1700
6527.7360 15428.7373 8192.2331 15822.6000 7288.6000

(lbmol/h)
lN
89.14565876
33.82014039
63.16535749
29.10602281
12.38798696
495.8677393
723.4929057
LN
 HiL HiG N HiL N HiG N+1 HiL N+1
1260.8658 2672.1551 1561.6061 2557.5200 1399.1800
1515.6621 6170.3325 1890.5224 6248.4100 1687.4100
2089.8819 7587.4593 2607.4721 7715.0000 2326.9900
2924.3772 8510.1859 3646.1034 8679.1200 3255.1200
3636.1377 9489.6689 4535.4479 9700.1700 4048.1700
6527.7360 15429.0778 8193.7361 15822.6000 7288.6000

(lbmol/h)
lN
89.18803421
33.83348653
63.18300992
29.10741627
12.38817975
495.8677792
723.5679059
LN