UN SISTEMA BINARIO EN ELV A UNA T PRESENTA Z1=0.

65 SE SABE QUE:
a) construir un diagrama PT VS X1Y1
b) DETERMINAR EL LIMITE DE PRESIONES EN LA CUAL EL SISTEMA PUEDE EXISTIR EN 2 FASES A T=CTE. CON X1
°CALCULO ANALITICO
°CALCULO GRAFICO

〖𝑝 1 〗^𝑠𝑎𝑡=32.27𝑘𝑝𝑎 ln⁡〖𝑦 2=𝑜.67𝑥_1^2 〗 〖𝑝 2 〗^𝑠𝑎𝑡=73.14𝑘𝑝𝑎

PARA UN SISTEMA BINARIO

𝑃_𝑇=𝑋_1 𝛾_1 P1SAT
𝑃_1^𝑠𝑎𝑡+𝑋_2 𝛾_2 𝑃_2^𝑠𝑎𝑡

X1 X2 Y1 Y2 P1 P2
0 1 1.95423732 1 0 73.14
0.05 0.95 1.83065715 1.0016764 2.95376531 69.5994816
0.1 0.9 1.72064634 1.0067225 5.55252574 66.268515
0.15 0.85 1.62267334 1.0151892 7.85455031 63.1132974
0.2 0.8 1.53541392 1.02716235 9.90956145 60.1013234
0.25 0.75 1.45772208 1.04276413 11.7601729 57.2008261
0.3 0.7 1.38860549 1.06215515 13.4430898 54.3802191
0.35 0.65 1.3272047 1.08553722 14.9901135 51.6075251
0.4 0.6 1.27277556 1.11315686 16.428987 48.8497758
0.45 0.55 1.22467438 1.14530961 17.7841091 46.0723696
0.5 0.5 1.18234529 1.18234529 19.0771413 43.2383673
0.55 0.45 1.14530961 1.22467438 20.3275276 40.307708
0.6 0.4 1.11315686 1.27277556 21.5529432 37.2363219
0.65 0.35 1.08553722 1.3272047 22.769686 33.9751131
0.7 0.3 1.06215515 1.38860549 23.9930226 30.4687817
0.75 0.25 1.04276413 1.45772208 25.2374987 26.6544483
0.8 0.2 1.02716235 1.53541392 26.5172232 22.4600348
0.85 0.15 1.0151892 1.62267334 27.8461322 17.8023492
0.9 0.1 1.0067225 1.72064634 29.2382414 12.5848073
0.95 0.05 1.0016764 1.83065715 30.7078927 6.69471319
1 0 1 1.95423732 32.27 0
 EXISTIR EN 2 FASES A T=CTE. CON X1=0.75

=73.14𝑘𝑝𝑎 ln⁡〖𝑦 1=𝑜.67𝑥_2^2 〗

p. burbuja= TRASCISION D
P. ROCIO = TRASCISION D

32.27 P2SAT 73.14

PT y1 y2 P. burbuja p.Rocio
73.14 0 1 73.14 73.14
72.5532469 0.04071169 0.95928831 72.5532469 68.7842336
71.8210407 0.07731057 0.92268943 71.8210407 64.9181121
70.9678477 0.11067759 0.88932241 70.9678477 61.4634653
70.0108849 0.14154315 0.85845685 70.0108849 58.3579221
68.960999 0.17053368 0.82946632 68.960999 55.5511103
67.8233089 0.19820752 0.80179248 67.8233089 53.0019043
66.5976385 0.22508476 0.77491524 66.5976385 50.6763959
65.2787628 0.2516743 0.7483257 65.2787628 48.5463779
63.8564787 0.27850125 0.72149875 63.8564787 46.5881942
62.3155085 0.30613794 0.69386206 62.3155085 44.7818575
60.6352356 0.33524282 0.66475718 60.6352356 43.1103647
58.7892651 0.36661358 0.63338642 58.7892651 41.5591597
56.7447991 0.40126472 0.59873528 56.7447991 40.1157091
54.4618043 0.4405477 0.5594523 54.4618043 38.7691618
51.891947 0.48634712 0.51365288 51.891947 37.5100767
48.9772581 0.5414191 0.4585809 48.9772581 36.3302004
45.6484814 0.61001224 0.38998776 45.6484814 35.2222864
41.8230488 0.69909398 0.30090602 41.8230488 34.1799458
37.4026059 0.82100944 0.17899056 37.4026059 33.1975245
32.27 1 0 32.27 32.27
p. burbuja= TRASCISION DE VAPOR A LIQUIDO ( LINEA AZUL)
P. ROCIO = TRASCISION DE UN LIQUIDO-VAPOR ( LINEA ROJA)

intervalo
 Margules Ley de Raoult modificado

ln⁡(𝛾1)=[𝐴_12+2(𝐴_21−𝐴_12 ) 𝑥_1 ] 𝑥_2^2 𝑃_𝑇=𝑋_1 𝛾_1

𝑃_1^𝑠𝑎𝑡+𝑋_2 𝛾_2 𝑃_2^𝑠𝑎𝑡

ln⁡(𝛾2)=[𝐴_21+2(𝐴_12−𝐴_21 ) 𝑥_2 ] 𝑥_1^2

𝛾1 1.23518308 X1 0.4
𝛾2 1.10540435 X2 0.6

ACETONA(1)/METANOL(2)
A12 0.6184
A21 0.5788
T°C 22

a b c Psat
acetona 7.117714 1210.595 229.664 202.932577268
metanol 8.08097 1582.271 239.726 108.503885625

Pburbuja 172.227955 TORR

x x2 Y1 Y2 P1 P2
0 1 1.85595614 1 0 108.503886
0.1 0.9 1.63965983 1.00652197606 33.2740395 98.2903908
0.2 0.8 1.47055282 1.02601913841 59.6846149 89.0616506
0.3 0.7 1.33826447 1.05874220023 81.4732372 80.4143498
0.4 0.6 1.23518308 1.10540435482 100.263554 71.9644006
0.5 0.5 1.15569281 1.16719099132 117.26386 63.3223789
0.6 0.4 1.09564234 1.24579365411 133.404914 54.0693809
0.7 0.3 1.0519719 1.3434680935 149.435558 43.7314525
0.8 0.2 1.02244989 1.463117744 165.990713 31.7507921
0.9 0.1 1.00548619 1.6084053141 183.641314 17.4518226
1 0 1 1.78389647007 202.932577 0
y de Raoult modificado

𝑋_1 𝛾_1
𝑠𝑎𝑡+𝑋_2 𝛾_2 𝑃_2^𝑠𝑎𝑡

PT Y1 Y2
108.503886 0 1
131.56443 0.2529106 0.7470894
148.746265 0.40125118 0.59874882
161.887587 0.50327044 0.49672956
172.227955 0.5821561 0.4178439
180.586239 0.64935103 0.35064897
187.474295 0.71159043 0.28840957 Chart Title
193.16701 0.77360807 0.22639193
200
197.741505 0.83943284 0.16056716
201.093137 0.91321523 0.08678477
180
202.932577 1 0
160

140

120

100
0 0.2 0.4 0.6 0.8 1
140

120

100
0 0.2 0.4 0.6 0.8 1
Chart Title

0.6 0.8 1 1.2

0.6 0.8 1 1.2
 Vaan Laar Ley de Raoult modificado

ln⁡(𝛾1)=𝐴_12 [(𝐴_21 𝑥_2)/(𝐴_12 𝑥_1+𝐴_21 𝑥_2 )]^2

𝑃_𝑇=𝑋_1 𝛾_1
𝑃_1^𝑠𝑎𝑡+𝑋_2 𝛾_2 𝑃_2^𝑠𝑎𝑡

ln⁡(𝛾2)=𝐴_21 [(𝐴_12 𝑥_1)/(𝐴_12 𝑥_1+𝐴_21 𝑥_2 )]^2

𝛾1 1.86808479 X1 0.4
𝛾2 1.51680956 X2 0.6

ACETONA(1)/METANOL(2)
A12 -0.8643
A21 -0.5899
T°C 22

a b c Psat
Cloroformo 7.11714 1210.595 229.664 202.664542
Acetona 6.95465 1170.966 226.232 172.753077

Pburbuja 308.65793 TORR

x x2 ɣ1 Ɣ2 P1 P2
0 1 4.32825123 1 0 172.753077
0.1 0.9 3.33351729 1.14314232 67.5585755 177.733217
0.2 0.8 2.66736769 1.27797018 108.11617 176.618625
0.3 0.7 2.20295964 1.40282276 133.938542 169.639363
0.4 0.6 1.86808479 1.51680956 151.43782 157.220111
0.5 0.5 1.61962904 1.61962904 164.120688 139.897949
0.6 0.4 1.43076683 1.71140696 173.979422 118.260327
0.7 0.3 1.28419759 1.79256256 182.182922 92.9012092
0.8 0.2 1.1684071 1.8637032 189.435752 64.3920923
0.9 0.1 1.07551648 1.92554475 196.172149 33.264378
1 0 1 1.97885352 202.664542 0
y de Raoult modificado

𝛾_1
𝑋_2 𝛾_2 𝑃_2^𝑠𝑎𝑡

PT Y1 Y2
172.753077 0 1 Chart Title
245.291792 0.27542126 0.72457874
350
284.734795 0.37970832 0.62029168
303.577905 0.4411999 0.5588001 300

308.65793 0.49063317 0.50936683 250

304.018638 0.53983759 0.46016241
200
292.239749 0.59533114 0.40466886
275.084131 0.66228074 0.33771926 150
253.827844 0.74631588 0.25368412 100
229.436527 0.85501708 0.14498292
50
202.664542 1 0
0
0 0.2 0.4 0.6 0.8
 Chart Title

0.4 0.6 0.8 1 1.2

 van laar

ln⁡(𝛾1)=𝐴_12 [(𝐴_21 𝑥_2)/(𝐴_12 𝑥_1+𝐴_21 𝑥_2 )]^2

ln⁡(𝛾2)=𝐴_21 [(𝐴_12 𝑥_1)/(𝐴_12 𝑥_1+𝐴_21 𝑥_2 )]^2

componentes a b c T.sat
Cloroformo 7.11714 1210.595 229.664
Acetona 6.95465 1170.966 226.232

A12 -0.8643
A21 -0.5899
x x2 ɣ1 Ɣ2
0 1 #DIV/0!
0.1 0.9
0.2 0.8
0.3 0.7
0.4 0.6
0.5 0.5
0.6 0.4
0.7 0.3
0.8 0.2
0.9 0.1
1 0
 Ley de Raoult modificado
𝑃_𝑇=𝑋_1 𝛾_1
𝐴_21 𝑥_2 )]^2 𝑃_1^𝑠𝑎𝑡+𝑋_2 𝛾_2 𝑃_2^𝑠𝑎𝑡
 Vaan Laar Ley de Raoult modificado

ln⁡(𝛾1)=−𝐿𝑛(𝑥_1+𝐴_12 𝑥_2 )+𝑥_2 (𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )−𝐴_21/(𝑥_2+𝐴_21 𝑥_1 ))

𝐴_12=(𝑣_2^𝐿)/(𝑣_1^𝐿 ) 𝐸𝑋𝑃(−(𝜆_12−𝜆_11)/𝑅𝑇)
𝑃_𝑇=𝑋_1 𝛾_1
𝑃_1^𝑠𝑎𝑡+𝑋_2 𝛾_2 𝑃_2^𝑠𝑎𝑡

𝐴_21=(𝑣_1^𝐿)/(𝑣_2^𝐿 ) 𝐸𝑋𝑃(−(𝜆_21−𝜆_22)/𝑅𝑇)
ln⁡(𝛾_2 )=−𝐿𝑛(𝑥_2+𝐴_21 𝑥_1 )+𝑥_1 (𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )−𝐴_21/(𝑥_2+𝐴_21 𝑥_1 ))

𝛾_1 𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )

1.16700697 X1 0.45 Ln 1 0.86063392 1.47217771
𝛾_2 𝐴_21/(𝑥_2+𝐴_21 𝑥_1 )
2.32943759 X2 0.55 Ln2 -0.54268342 0.11924489

WILLSON (Cal/mol) AGUA(1)/ACIDO FORMICO(2) VOLUMEN MOLAR (CM^3/GMOL)

𝜆_12−𝜆_11 -310.106 A12 3.4811985968394 AGUA 18.07
𝜆_21−𝜆_22 1180.804 A21 0.0693035294289146 ACIDO f 37.91

T°C 35
a b c Psat
AGUA 8.07131 1730.63 233.426 42.0710872 CONSTANTES A OCUPAR
ACIDO FORMICO 6.94459 1295.26 218 66.832123 T 308.15 K
R 1.9872 Cal/mol*k
𝐴_21/(𝑥_2+𝐴_21 𝑥_1 )
𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )
Pburbuja 107.718456 TORR

x x2 ɣ1 Ɣ2 P1 P2 PT Y1 Y2 Chart Title
0 1 0.72856372 1 0 66.832123 66.832123 0 1 80
0.1 0.9 0.76098695 0.9976595 3.201554843 60.008132 63.2096869 0.0506497501 0.94935025 70
0.2 0.8 0.79555778 0.98979989 6.693996128 52.9203422 59.6143383 0.1122883575 0.88771164 60
0.3 0.7 0.83216578 0.97497583 10.50303572 45.6117932 56.1148289 0.1871704132 0.81282959 50
0.4 0.6 0.87045747 0.95151891 14.64843682 38.1552175 52.8036543 0.2774133158 0.72258668 40
0.5 0.5 0.90963688 0.91769157 19.13470616 30.6656379 49.800344 0.384228393 0.61577161 30
0.6 0.4 0.94810537 0.87219349 23.93269422 23.316217 47.2489112 0.5065237192 0.49347628
20
0.7 0.3 0.98281197 0.81570532 28.94357752 16.3545955 45.298173 0.6389568413 0.36104316
10
0.8 0.2 1.0081427 0.75615971 33.93092764 10.1071517 44.0380794 0.7704906331 0.22950937
0
0.9 0.1 1.0147025 0.73473462 38.42067354 4.91038745 43.331061 0.886677424 0.11332258 0 0.2 0.4 0.6 0.8 1 1.2
1 0 1 1.20690695 42.07108718 0 42.0710872 1 0
Column H Column H
10
0
0 0.2 0.4 0.6 0.8 1 1.2

Column H Column H
1 1.2
1 1.2
 Vaan Laar Ley de Raoult modificado

ln⁡(𝛾1)=−𝐿𝑛(𝑥_1+𝐴_12 𝑥_2 )+𝑥_2 (𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )−𝐴_21/(𝑥_2+𝐴_21 𝑥_1 )) 𝐴_12=(𝑣_2^𝐿)/(𝑣_1^𝐿 ) 𝐸𝑋𝑃(−(𝜆_12−𝜆_11)/𝑅𝑇)

𝑃_𝑇=𝑋_1 𝛾_1
𝑃_1^𝑠𝑎𝑡+𝑋_2 𝛾_2 𝑃_2^𝑠𝑎𝑡
ln⁡(𝛾_2 )=−𝐿𝑛(𝑥_2+𝐴_21 𝑥_1 )+𝑥_1 (𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )−𝐴_21/(𝑥_2+𝐴_21 𝑥_1 )) 𝐴_21=(𝑣_1^𝐿)/(𝑣_2^𝐿 ) 𝐸𝑋𝑃(−(𝜆_21−𝜆_22)/𝑅𝑇) 𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )

𝛾_1 1.0878 X1 0.6627634

𝛾_2 1.4333 X2 0.3372366

𝐴_21/(𝑥_2+𝐴_21 𝑥_1 )
WILLSON (Cal/mol) Acetato de etilo (1)/ Etanol (2) VOLUMEN MOLAR (CM^3/GMOL)
𝜆_12−𝜆_11 58.8869 A12 0.546504801884245 nhexano 98.49
𝜆_21−𝜆_22 570.0439 A21 0.727531058313511 etanol 58.68 Chart Title
750.0000
T°C 70
a b c Psat
700.0000
Acetato de etilo 7.10179 1244.951 217.881 598.7652657 CONSTANTES A OCUPAR
etanol 8.1122 1592.864 226.184 542.3076806 T 343.15 K
R 1.9872 Cal/mol*k 650.0000

𝐴_21/(𝑥_2+𝐴_21 𝑥_1 )
𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )
Pburbuja 693.81004 TORR 600.0000
DESVIACION POSITIVA
550.0000
x x2 ɣ1 Ɣ2 P1 P2 PT Y1 Y2 Volatilidad relativa
0 1 2.4029 1.0000 0.0000 542.3077 542.3077 0.0000 1.0000 2.6531 500.0000
0 0.2 0.4 0.6 0.8 1 1.2
0.1 0.9 1.9787 1.0101 118.4748 493.0207 611.4955 0.1937 0.8063 2.1627
0.2 0.8 1.6841 1.0391 201.6748 450.8276 652.5024 0.3091 0.6909 1.7894 Column H Column H
0.3 0.7 1.4737 1.0863 264.7219 412.3692 677.0911 0.3910 0.6090 1.4979
0.4 0.6 1.3207 1.1522 316.3122 374.9138 691.2260 0.4576 0.5424 1.2655
0.5 0.5 1.2085 1.2389 361.8080 335.9287 697.7367 0.5185 0.4815 1.0770 DE FORMA ANALITICA EL PUNTO AZEOTROPICO SE ENCUENTRA EN ESTOS INTERVALO
0.6 0.4 1.1267 1.3495 404.7863 292.7481 697.5344 0.5803 0.4197 0.9218
0.7 0.3 1.0686 1.4890 447.8706 242.2530 690.1235 0.6490 0.3510 0.7923
0.8 0.2 1.0297 1.6641 493.2150 180.4953 673.7103 0.7321 0.2679 0.6831
0.9 0.1 1.0073 1.8844 542.8188 102.1939 645.0127 0.8416 0.1584 0.5902
1 0 1.0000 2.1632 598.7653 0.0000 598.7653 1.0000 0.0000 0.5104
 0.8 1 1.2

Column H

TRA EN ESTOS INTERVALOS