Diagrama n-hexano-acetona, a 100 kPa y 20°C

P 100 kPa 14.50326323 psia 1

A B C
n-hexano 6.244412 5356.715 397.529
acetona 6.039243 5085.758 382.794 (Para T[°F] y P [psia]
Pc (psia) n-hexano 440 𝑥_1=(𝑃−𝑃_2^𝑠𝑎𝑡)/(𝑃_1^
Pc (psia) acetona 693.7

T ebu n-hexano 68.7 °C 341.85 K

T ebu acetona 56 °C 329.15 K

α12 0.2
b12 -21.6945
b21 1160.4648

R (cal/molK) 1.987 Para x1=0.1

Para x1=.2

Para x1=0.3

Para x1=0.4

Para x1=0.5
Para x1=0.6

Para x1=0.7

Para x1=0.8

Para x1=0.9

Para x1=1
o-acetona, a 100 kPa y 20°C

bar

ln⁡〖 (𝑃_𝑖^𝑠𝑎𝑡)/
𝑃𝑐 〗 =𝐴−𝐵/(𝑇(°𝐹)−𝐶)

𝑥_1=(𝑃−𝑃_2^𝑠𝑎𝑡)/(𝑃_1^𝑠𝑎𝑡−𝑃_2^𝑠𝑎𝑡 )

𝑦_1=𝑥_1/𝑃 𝑃_1^𝑠𝑎𝑡

Psat1 Psat2 x1 T variable τ12 τ21

psia 9.0637257408 14.7481195 0.1 328.388707 -0.03324785 1.778467326
bar 0.6249438898 1.01688284 0.9 55.23870703
131.4296726

Psat1 Psat2 x1 T variable τ12 τ21

psia 8.9017618631 14.4833619 0.2 327.8664061 -0.03330081 1.781300478
bar 0.6137764805 0.9986278 0.8 54.71640612
130.489531

Psat1 Psat2 x1 T variable τ12 τ21

psia 8.5354974102 13.8846238 0.3 326.6565248 -0.03342416 1.787898118
bar 0.5885225464 0.95734481 0.7 53.50652478
128.3117446

Psat1 Psat2 x1 T variable τ12 τ21

psia 6.6568117623 10.8133647 0.4 319.6973875 -0.03415173 1.826816886
bar 0.458987171 0.95734481 0.6 46.54738747
115.7852974

Psat1 Psat2 x1 T variable τ12 τ21

psia 5.5194197231 8.95419615 0.5 314.6674518 -0.03469764 1.856018417
bar 0.3805639899 0.95734481 0.5 41.51745176
106.7314132

Psat1 Psat2 x1 T variable τ12 τ21

psia 4.9610248394 8.04166799 0.6 311.8825938 -0.03500746 1.872591153
bar 0.3420626627 0.95734481 0.4 38.73259379
101.7186688

Psat1 Psat2 x1 T variable τ12 τ21

psia 4.8546321146 7.86782615 0.7 311.3233206 -0.03507035 1.875955148
bar 0.3347268843 0.95734481 0.3 38.17332059
100.7119771

Psat1 Psat2 x1 T variable τ12 τ21

psia 5.0862171727 8.24623899 0.8 312.5283288 -0.03493513 1.868722071
bar 0.3506946741 0.95734481 0.2 39.37832878
102.8809918

Psat1 Psat2 x1 T variable τ12 τ21

psia 5.5630122299 9.0254428 0.9 314.8750719 -0.03467476 1.854794609
bar 0.3835696933 0.95734481 0.1 41.72507189
107.1051294

Psat1 Psat2 x1 T variable τ12 τ21

psia 6.217718299 10.095579 1 317.8447556 -0.03435079 1.837464912
bar 0.4287116767 0.95734481 0 44.69475555
112.45056
G12 G21 ϒ1 ϒ2 y1 y2 y1+y2
1.00667173 0.70068737 1.016152159 1.023274972 0.063503808 0.93649569 0.9999994942792

G12 G21 ϒ1 ϒ2 y1 y2 y1+y2

1.00668239 0.70029045 1.060904273 1.088703858 0.130231618 0.86976795 0.9999995710647

G12 G21 ϒ1 ϒ2 y1 y2 y1+y2

1.00670722 0.69936701 1.131147965 1.194207553 0.199711824 0.80028788 0.9999997069454

G12 G21 ϒ1 ϒ2 y1 y2 y1+y2

1.00685373 0.69394444 1.228419394 1.348291074 0.225531497 0.77446768 0.9999991749398

G12 G21 ϒ1 ϒ2 y1 y2 y1+y2

1.00696366 0.68990341 1.350756752 1.552157476 0.25702469 0.74297495 0.9999996422026
G12 G21 ϒ1 ϒ2 y1 y2 y1+y2
1.00702606 0.68762047 1.497338115 1.808883529 0.307310078 0.6926901 1.0000001817532

G12 G21 ϒ1 ϒ2 y1 y2 y1+y2

1.00703873 0.687158 1.667744697 2.121261229 0.39076729 0.60923353 1.0000008194139

G12 G21 ϒ1 ϒ2 y1 y2 y1+y2

1.00701149 0.68815277 1.862557129 2.493607424 0.522551092 0.47744843 0.999999517705

G12 G21 ϒ1 ϒ2 y1 y2 y1+y2

1.00695906 0.69007229 2.083398704 2.932946646 0.719215742 0.28078413 0.9999998668931

G12 G21 ϒ1 ϒ2 y1 y2 y1+y2

1.00689381 0.69246819 2.332571294 3.448830559 1.000000551 0 1.0000005505286
 Diagrama T-xy
345
x1 y1

340

335

330

325
T°C

320

315

310

305

300
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

x1,y1

T(K) x y
341.85 0 0
328.388707 0.1 0.063503808
327.8664061 0.2 0.130231618
326.6565248 0.3 0.199711824
319.6973875 0.4 0.225531497
314.6674518 0.5 0.25702469
311.8825938 0.6 0.307310078
311.3233206 0.7 0.39076729
312.5283288 0.8 0.522551092
314.8750719 0.9 0.719215742
317.8447556 1 1.000000551
0.7 0.8 0.9 1
 Diagrama benceno-tolueno, a 100 kPa y 20°C

τ12 τ21 G12 G21 ϒ1 ϒ2 x1 y1

-0.03724448 1.9922517 1.00747671 0.67135962 7.06200324 1 0 0
6.6649205 1.00029018 0.01 0.04160363
6.29912466 1.00114985 0.02 0.07894018
5.96168755 1.00256374 0.03 0.11249579
5.64999399 1.00451792 0.04 0.14269806
5.36170463 1.00699968 0.05 0.16992359
5.09472356 1.00999747 0.06 0.19450456
4.84717011 1.0135008 0.07 0.2167344
4.61735422 1.01750018 0.08 0.23687265
4.40375492 1.02198704 0.09 0.25514919
4.2050014 1.02695368 0.1 0.27176788
4.01985647 1.03239323 0.11 0.28690979
3.847202 1.03829957 0.12 0.30073591
3.6860261 1.04466729 0.13 0.31338957
3.53541179 1.05149166 0.14 0.32499855
3.39452706 1.05876858 0.15 0.33567689
3.262616 1.06649455 0.16 0.3455265
3.13899099 1.07466663 0.17 0.35463855
3.02302582 1.08328242 0.18 0.36309473
2.91414943 1.09234001 0.19 0.37096828
2.81184053 1.10183798 0.2 0.378325
2.71562266 1.11177536 0.21 0.385224
2.62505988 1.1221516 0.22 0.39171851
2.53975286 1.13296658 0.23 0.39785651
2.45933542 1.14422055 0.24 0.40368127
2.38347141 1.15591413 0.25 0.40923191
2.31185195 1.16804832 0.26 0.41454378
2.24419289 1.18062445 0.27 0.41964895
2.18023262 1.19364415 0.28 0.42457646
2.11973 1.20710941 0.29 0.42935271
2.06246257 1.22102247 0.3 0.43400171
2.00822487 1.23538591 0.31 0.43854534
1.95682705 1.25020254 0.32 0.44300355
1.90809341 1.26547548 0.33 0.44739458
1.86186131 1.28120807 0.34 0.45173513
1.81797998 1.29740394 0.35 0.45604049
1.7763096 1.31406692 0.36 0.46032475
1.73672034 1.33120112 0.37 0.46460084
1.69909159 1.34881085 0.38 0.46888072
1.66331121 1.36690063 0.39 0.47317543
 1.6292748 1.38547524 0.4 0.47749522
1.59688518 1.40453962 0.41 0.48184958
1.56605173 1.42409894 0.42 0.48624738
1.53668994 1.44415857 0.43 0.49069689
1.50872094 1.46472407 0.44 0.49520586
1.48207103 1.48580119 0.45 0.49978155
1.45667133 1.50739587 0.46 0.50443083
1.43245742 1.52951422 0.47 0.50916018
1.40936897 1.55216254 0.48 0.51397573
1.38734949 1.5753473 0.49 0.51888332
1.36634603 1.59907514 0.5 0.52388854
1.34630892 1.62335288 0.51 0.52899672
1.32719155 1.6481875 0.52 0.534213
1.30895016 1.67358613 0.53 0.53954233
1.2915436 1.69955608 0.54 0.54498949
1.2749332 1.72610481 0.55 0.55055914
1.25908259 1.75323994 0.56 0.55625581
1.24395751 1.78096922 0.57 0.56208393
1.22952572 1.80930059 0.58 0.56804785
1.21575681 1.83824212 0.59 0.57415185
1.20262213 1.86780202 0.6 0.58040015
1.19009465 1.89798866 0.61 0.58679692
1.17814884 1.92881054 0.62 0.59334631
1.16676061 1.96027632 0.63 0.60005244
1.1559072 1.99239479 0.64 0.60691943
1.14556707 2.02517488 0.65 0.6139514
1.13571989 2.05862565 0.66 0.62115246
1.12634639 2.09275633 0.67 0.62852677
1.11742834 2.12757624 0.68 0.63607847
1.10894849 2.16309486 0.69 0.64381178
1.10089048 2.1993218 0.7 0.65173093
1.09323881 2.23626679 0.71 0.6598402
1.08597877 2.27393971 0.72 0.66814393
1.07909644 2.31235056 0.73 0.67664652
1.07257857 2.35150945 0.74 0.68535242
1.0664126 2.39142664 0.75 0.69426618
1.06058661 2.4321125 0.76 0.7033924
1.05508926 2.47357755 0.77 0.71273577
1.04990977 2.51583239 0.78 0.72230107
1.04503791 2.55888778 0.79 0.73209317
1.04046394 2.60275458 0.8 0.74211705
1.03617858 2.64744379 0.81 0.75237777
1.03217302 2.6929665 0.82 0.76288051
1.02843886 2.73933394 0.83 0.77363057
1.0249681 2.78655745 0.84 0.78463336
1.02175314 2.83464849 0.85 0.79589441
1.01878671 2.88361861 0.86 0.80741938
1.01606189 2.93347952 0.87 0.81921407
1.01357209 2.98424299 0.88 0.83128441
1.01131102 3.03592095 0.89 0.84363648
1.00927268 3.08852539 0.9 0.85627649
1.00745135 3.14206846 0.91 0.86921084
1.00584157 3.19656237 0.92 0.88244604
1.00443812 3.25201948 0.93 0.89598881
1.00323602 3.30845222 0.94 0.90984601
1.00223052 3.36587314 0.95 0.9240247
1.00141708 3.4242949 0.96 0.93853209
1.00079136 3.48373024 0.97 0.95337561
1.00034922 3.54419203 0.98 0.96856286
1.0000867 3.60569322 0.99 0.98410165
1 3.66824686 1 1
 A B C
x2 y2 P n-hexano 6.244412 5356.715 397.529
1 1 0.25287719 acetona 6.039243 5085.758 382.794
0.99 0.99404619 0.25192096 T°C 20 T°F 68
0.98 0.98860351 0.25096472 Pc (psia) n-hexano 440
0.97 0.98364557 0.25000849 Pc (psia) acetona 693.7
0.96 0.97914749 0.24905225
0.95 0.97508576 0.24809601 Psat 1 (psia) 2.28064882 Psat 1 (bar) 0.15725359
0.94 0.97143814 0.24713978 Psat 2 (psia) 3.66747794 Psat 2(bar) 0.25287719
0.93 0.96818354 0.24618354
0.92 0.96530189 0.24522731
0.91 0.96277412 0.24427107
0.9 0.960582 0.24331483 P-x1,y1
0.89 0.95870808 0.2423586
x1 y
0.88 0.95713566 0.24140236
0.87 0.95584865 0.24044613 0.27

0.86 0.95483155 0.23948989

0.85 0.95406941 0.23853365
0.25
0.84 0.95354772 0.23757742
0.83 0.95325239 0.23662118
0.82 0.95316969 0.23566495 0.23
0.81 0.95328623 0.23470871
0.8 0.95358887 0.23375247
Presión (bar)

0.79 0.95406474 0.23279624 0.21

0.78 0.95470112 0.23184
0.77 0.95548548 0.23088377
0.19
0.76 0.95640541 0.22992753
0.75 0.95744859 0.22897129
0.74 0.95860274 0.22801506 0.17
0.73 0.95985563 0.22705882
0.72 0.96119501 0.22610258
0.71 0.9626086 0.22514635 0.15
0 0.2 0.4 0.6
0.7 0.96408407 0.22419011
0.69 0.96560898 0.22323388 x1, y1
0.68 0.9671708 0.22227764
0.67 0.96875684 0.2213214
0.66 0.97035426 0.22036517
0.65 0.97195001 0.21940893
0.64 0.97353084 0.2184527
0.63 0.97508325 0.21749646
0.62 0.97659348 0.21654022
0.61 0.97804749 0.21558399
 0.6 0.97943091 0.21462775
0.59 0.98072904 0.21367152
0.58 0.98192684 0.21271528
0.57 0.98300886 0.21175904
0.56 0.98395926 0.21080281
0.55 0.98476176 0.20984657
0.54 0.98539963 0.20889034
0.53 0.98585566 0.2079341
0.52 0.98611214 0.20697786
0.51 0.98615081 0.20602163
0.5 0.9859529 0.20506539
0.49 0.98549901 0.20410916
0.48 0.98476918 0.20315292
0.47 0.98374279 0.20219668
0.46 0.98239857 0.20124045
0.45 0.98071456 0.20028421
0.44 0.97866811 0.19932798
0.43 0.9762358 0.19837174
0.42 0.97339346 0.1974155
0.41 0.9701161 0.19645927
0.4 0.96637792 0.19550303
0.39 0.96215225 0.1945468
0.38 0.95741153 0.19359056
0.37 0.95212728 0.19263432
0.36 0.94627005 0.19167809
0.35 0.9398094 0.19072185
0.34 0.93271388 0.18976562
0.33 0.92495095 0.18880938
0.32 0.916487 0.18785314
0.31 0.90728725 0.18689691
0.3 0.89731577 0.18594067
0.29 0.88653541 0.18498444
0.28 0.87490775 0.1840282
0.27 0.86239308 0.18307196
0.26 0.84895034 0.18211573
0.25 0.83453709 0.18115949
0.24 0.81910945 0.18020325
0.23 0.80262205 0.17924702
0.22 0.78502802 0.17829078
0.21 0.76627887 0.17733455
0.2 0.7463245 0.17637831
0.19 0.72511313 0.17542207
0.18 0.70259122 0.17446584
0.17 0.67870344 0.1735096
0.16 0.6533926 0.17255337
0.15 0.6265996 0.17159713
0.14 0.59826335 0.17064089
0.13 0.56832073 0.16968466
0.12 0.53670649 0.16872842
0.11 0.50335321 0.16777219
0.1 0.46819122 0.16681595
0.09 0.43114852 0.16585971
0.08 0.39215072 0.16490348
0.07 0.35112094 0.16394724
0.06 0.30797973 0.16299101
0.05 0.26264503 0.16203477
0.04 0.21503203 0.16107853
0.03 0.16505308 0.1601223
0.02 0.11261764 0.15916606
0.01 0.05763217 0.15820983
0 0 0.15725359
 α12 0.2
(Para T[°F] y P [psia] b12 -21.6945
T(K) 293.15 b21 1160.4648

R (cal/molK) 1.987

P-x1,y1
x1 y1

0.4 0.6 0.8 1 1.2

x1, y1
Diagrama equilibro x-y

x1 y1 Reacta
0 0 0 0
0.01 0.04160363 1 1
0.02 0.07894018 Diagrama equilibrio x-y
0.03 0.11249579 1.2
0.04 0.14269806
0.05 0.16992359
1
0.06 0.19450456
0.07 0.2167344
0.08 0.23687265 0.8

0.09 0.25514919
0.1 0.27176788 0.6
0.11 0.28690979 y

0.12 0.30073591
0.4
0.13 0.31338957
0.14 0.32499855
0.15 0.33567689 0.2
0.16 0.3455265
0.17 0.35463855 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
0.18 0.36309473
0.19 0.37096828 x
0.2 0.378325
0.21 0.385224
0.22 0.39171851
0.23 0.39785651
0.24 0.40368127
0.25 0.40923191
0.26 0.41454378
0.27 0.41964895
0.28 0.42457646
0.29 0.42935271
0.3 0.43400171
0.31 0.43854534
0.32 0.44300355
0.33 0.44739458
0.34 0.45173513
0.35 0.45604049
0.36 0.46032475
0.37 0.46460084
0.38 0.46888072
0.39 0.47317543
0.4 0.47749522
0.41 0.48184958
0.42 0.48624738
0.43 0.49069689
0.44 0.49520586
0.45 0.49978155
0.46 0.50443083
0.47 0.50916018
0.48 0.51397573
0.49 0.51888332
0.5 0.52388854
0.51 0.52899672
0.52 0.534213
0.53 0.53954233
0.54 0.54498949
0.55 0.55055914
0.56 0.55625581
0.57 0.56208393
0.58 0.56804785
0.59 0.57415185
0.6 0.58040015
0.61 0.58679692
0.62 0.59334631
0.63 0.60005244
0.64 0.60691943
0.65 0.6139514
0.66 0.62115246
0.67 0.62852677
0.68 0.63607847
0.69 0.64381178
0.7 0.65173093
0.71 0.6598402
0.72 0.66814393
0.73 0.67664652
0.74 0.68535242
0.75 0.69426618
0.76 0.7033924
0.77 0.71273577
0.78 0.72230107
0.79 0.73209317
0.8 0.74211705
0.81 0.75237777
0.82 0.76288051
0.83 0.77363057
0.84 0.78463336
0.85 0.79589441
0.86 0.80741938
0.87 0.81921407
0.88 0.83128441
0.89 0.84363648
0.9 0.85627649
0.91 0.86921084
0.92 0.88244604
0.93 0.89598881
0.94 0.90984601
0.95 0.9240247
0.96 0.93853209
0.97 0.95337561
0.98 0.96856286
0.99 0.98410165
1 1
ilibrio x-y

0.5 0.6 0.7 0.8 0.9 1